Reduction Furnace Modeling
Reduction Furnace Modeling
:
.
.
.
.
.
Shooting .
:
.
.
.
] .[
.
Shaft Furnace
.
.
)Fe(s) + HO (g
)(
)FeO (s) + H (g
)FeO (s)+ CO(g
)Fe(s) + CO (g
)(
].[
.
.
.
.
) (
) (
.
:
.
](kg>>D//r) [
.
.
.
:
)(
Cj j ij
i j .
) ( :
i
j Xi
C j = C 0j +
:
)(2
X 1 = C H0 2 C H 2
)(3
0
X 2 = CCO
CCO
:
0
X 2 = 3(C Fe
2O 3
)(
] [ ) (rc
C Fe 2O3 ) = X 3
X rs = X 1 +
) ( .
X 3M W 1 / 3
)
n p 4
)(
rc = (r03
r np Mw
.
:
)(6
)(7
)(8
)(9
)(10
=0
dX 3
+ n p ( R1 ( X 1 , X 3 ) + R 2 ( X 2 , X 3 )) = 0
dz
np
dTsol
dz
) Gmsol ( X 3 )Cpsol ( X 3 , Tsol
u sol
H (T
) sol ) Ri ( X i , X 3 , Tsol
dX 1
+ n p R1 ( X 1 , X 3 ) = 0
dz
dX 2
+ n p R 2 ( X 2 , X 3 ) = 0
u
dz
dTg
) n p Ap h(Tsol Tg
=0
) dz Gmg Cp g ( X 1 , X 2 , Tg
u
Ap h(Tsol Tg )
:
X 2 ( z = L) = 0
X 1 ( z = L) = 0
Tg ( z = L) = Tgin
X 3 ( z = 0) = 0
Ts ( z = 0) = Tatm
)(11
X X Tg ) z= ( )(
) ( z=L .
:
)(12
4rc2Cn
) (1 / kn + rc / Dn rc2 / r0 Dn
= R
n= H CO . :
)(13
R = n p R
.
X :
)(14
/ M wps
rc3 ) ps
:
)(15
wrs
[1 / 2r / M
[r / M
3
wrs + ( r0
3
c rs
3
c rs
L
Gmsol (rc ) = Gmsol
rs
ps
3
3
3
) p rs rc + C p ps ( r0 rc
) rs rc3 + ps (r03 rc3
[C
= C Ps
.
) (h ) ( :
)(16
1
Pr 2 / 3
C p Gmg
=h
Pr .
R [] E a1 / R g = 179.14 R
[] Ea 2 / Rg = 342.43.
z
MATLAB .
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.
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Gas
Gas
Nm/h
rate
flow
,
,
,
,
,
C
,
,
,
,
length
Solid
Production
t/h
Mineral pellet density
g/cm
Sponge iron density
g/cm
Pellet ratio
cm
np
pellets/cm
zone
Reactor
Reaction
cm
Diameter
cm
:
) ( ].[
) :(
(,exp
(,exp
, T, cm/s
, T, cm/s
cal/cm/K
K
/,/T) cm/s
K
/,/T) cm/s
D
D
h
) ( Shooting
.
) :(
data
(Dry
,
,
--,
,
,
siderca
model data
(Dry base) %
(Dry base) %
model data
base) %
orthogonal collocation
Shooting
)outlet gas composition(z=
H
,
,
CO
,
HO
----, ,
CO
,
CH+N
, ,
,
metallization
,
,
)CPU Time(min
---
:
.( )
:()
Gas
Gas flow rate
Nm/h
Inlet composition(at z=L)
H
,%
CO
,%
HO
,%
CO
,%
CH+N
,%
pressure
atm
Solid
Production
t/h
Mineral pellet density
g/cm
Sponge iron density
g/cm
Pellet ratio
cm
np
pellets/cm
Reactor
Reaction zone length
cm
Diameter
cm
,
,
,
,
,
:
) ( ].[
) :(
(,exp
(,exp
, T, cm/s
, T, cm/s
cal/cm/K
K
/,/T) cm/s
K
/,/T) cm/s
D
D
h
) ( .
) :(
model
)(Dry base
gilmore data
model data
(Dry base) %
(Dry base) %
data
%
Orthogonal
,
,
,
,
,
,
collocation
Shooting
)outlet gas composition(z=
H
,
,
CO
,
,
,
HO
,
CO
,
,
,
CH+N
,
metallization
,
)CPU Time(min
--
.
.
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.
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.
[] N.R. Amundson, L.E. Arri, Char gasification in counter current reactor, AIChE J. () .
[] Takenaka Y., Kimura Y., Narita K. and Kaneko D., Mathematical model of direct reduction shaft
furnace and its application to actual operation of a model plant, Comp. and Chem. Engng. (),.
[] Towhidi N. , Direct Reduction, V., Tehran University press,
[] Patisson F. and Ablitzer, Physicochemical and thermal modeling of the reaction between a porous
pellet and a gas, Powder Technology () .
[]
Daniel R. Parisi, Miguel A. Laborde , Modeling of counter current moving bed gas-solid reactor
used in direct reduction of iron ore, Chemical Engineering journal () .