CHAPTER # 1 Periodic Classification of Elements & Periodicity 1. Which of the following pairs are chemically dissimilar?

(A) Na and K (C) r and !f #. (B) Ba and Sr (") Ca and n.

11.

Which of the following has highest first ioni;ation potential? (A) Car&on (C) Nitrogen (B) 7.ygen (C) Boron.

1#.

Which of the following has the smallest si;e? (A) Na/ (C) Al*/ (B) 2g#/ (") C5

$he total n%m&er of inner transition elements is 1*. (A) 1' (C) #) (B) 1( (C) *'

Which of the following element has the ma.im%m electron affinity? (A) 0 (C) 5 (B) S (") C5.

*.

$he al+ali metal which is li,%id at 1-oC is (A) K (C) Na (B) Cs (") None 1(.

Which of the following is isoelectronic as well as has the same str%ct%re as that of N#7 ? (A) N*! (B) N7# (B) ! #7 (C) C7#

(.

Which of the following ion will form most water sol%&le hydro.ide? (A) K/ (B) n#/ (B) Ni#/ (C) Al*/ 1-.

$he atomic radi%s increases as we mo<e down a gro%p &eca%se (A) =ffecti<e n%clear charge increases (B) Atomic mass increases (C) Additi<e electrons are accommodated in new electron le<el (") Atomic n%m&er increase.

-.

Which of the following has greatest tendency to lose electron? (A) 0 (B) S (B) 0r (C) Be. 11.

1.

$he o.ide of which of the following elements will &e acidic in character (A) 2g (C) 4i (B) 3& (C) C5

Which one of the following is an incorrect statement? (A) $he ioni;ation potential of nitrogen is greater than that of chlorine (B) $he electron affinity of fl%orine is greater than that of chlorine (C) $he ioni;ation potential of &erylli%m is greater than that of &oron (") $he electronegati<ity of fl%orine is greater than that of chlorine.

6.

Which of the following is isoelectronic with car&on atom? (A) Na/ (C) 7#8 (B) Al*/ (") N/ 16.

).

Which of the following ions are paramagnetic in character? (A) n#/ (C) Ni#/ (B) C%/ (") Ag/

=lectron affinity depends on (A) Atomic si;e (B) N%clear charge (C) Atomic n%m&er (") Atomic si;e and n%clear charge &oth.

9.

Ca#/ ion is isoelectronic with 1). (A) 2g#/ (C) Ar (B) Na/ (") Kr $wo elements whose eletronegati<ities are 1.# and *.'> the &ond formed &etween them wo%ld &e (A) 5onic (C) Coordinate (B) co<alent (C) metallic.

1'.

:rad%al addition of electronic shells in the no&le gases ca%ses a decrease in their (A) 5oni;ation energy (C) Boiling point (B) atomic radi%s (") density.

a) 7nly one one 19. 5onic radii are (A) "irectly proportional to s,%are of effecti<e n%clear charges (B) 5n<ersely proportional to effecti<e n%clear charge (C) 5n<ersely proportional to s,%are of effecti<e n%clear charge (") "irectly proportional to effecti<e n%clear charge. #'. Which of the following o.ides is atmospheric in character? (A) Ca7 (C) Si7# #1. (B) C7# (") Sn7# a. &. c. d. c) ero

&) 2ore than d) 5nfinite

#9. Which of the possess ma.im%m hydration power? a) Na/ c) 2g/#

following

&) K/ d) Ca/# electron

*'. !igher <al%e of affinity meansAAAAAAAAA

2ar+ the correct statement? (A) Na/ is smaller than Na atom (B) Na/ is larger than Na atom (C) C58 is smaller than C5 atom (") C58 and C5 are e,%al in si;e

Atom will lose electron easily Atom will gain electron easily Atom may form di8positi<e ion $he reason is %n+nown gro%p

*1. 2elting points of B558A AAAAAAAAAAA down the gro%p a. 5ncrease c. 3emain constant reg%lar trend & d.

##.

Who introd%ced the ;ero gro%ps? (A) 4othar 2eyer (C) 2endlee< (B) 4oc+ery (") 3amsay

"ecrease No

*#. 7.idation state of an atom representsAAAAAA a. No. of electrons gained &. No. of electrons lost c. No. of electrons gained or lost d. None of a&o<e correctly represent it **. 2endelee<Cs periodic ta&le was &ased on a) Atomic n%m&er c) Atomic <ol%me *(. &) Atomic mass d) =lectronic config%ration

#*.

=lement> of gro%p 58B are called (A) 3epresentati<e elements (B) $ransition elements (C) 3are earth (") Coinage metals

#(.

$he element with (A) (C) *

@ #( is placed in the period (B) # (") (

#-.

Which is the part of metalloids? (A) NA and K (C) None of these (B) 0 and C5 (") C% and A%

=lements present in a same gro%p ha<e the same a) Atomic n%m&er &) 2olec%lar weight c) Chemical properties d) =lectronic config%ration

#1.

Which one of the following has the ma.im%m electron affinity? (A) 5 (B) Br (C) C5 (") 0 7n electrolysis of Na!> hydrogen is li&erated (A) At anode (C) At cathode #). electrons energy. (B) in the electrolyte (") none of them

*-.

DsE and DpE &loc+ elements are also called a) &) c) d) $ransition elements 5nert elements $ypical elements 3are earth elements

#6.

=lements with greater n%m&er of ha<e AAAAAAAAA<al%es of ioni;ation

*1.

What is the sym&ol of the element with only three electrons and three protons? a) 4i c) Ag &) C d) C%

*6.

=lements with se<en electrons in their <alence shell are +nown as a) 5nert c) !alogens &) 4anthanides d) Al+ali metals

(1.

Which of the following is smallest in si;e? a) K/1 c) 081 &) 78# d) Na/

(6.

5oni;ation energy is lowest for a) 5nert gases c) Al+ali metals &) !alogens d) Al+aline earth metals

*).

Which of the following pairs of elements are chemically most similar? a) Na and Al c) S and 0 &) C% and C% d) Sc and n (). An isotope of hydrogen is a) Nept%ni%m c) $hori%m (9. &) Fl%toni%m d) $riti%m

*9.

A st%dent of chemistry will identify positi<ely the following sym&ols as sodi%m 40 23 a)

W
11

&)
32

X
19

With respect to chlorine> hydrogen will &e a) =lectropositi<e c) Ne%tral &) =lectronegati<e d) None of these

c)

Y
13

26

d)

Z
16

-'.

Which of the following has the highest electron affinity? a) 1S# #S# #F* c) 1S# #S# #F&) 1S# #S# #F1 *S1 d) 1S# #S# #F-

('.

5n the periodic ta&le each period &egins with a metal> which is a) &) c) d) 2ost electronegati<e 2ost electropositi<e 4ess electropositi<e 4ess electronegati<e -1.

=.cl%ding hydrogen and heli%m> the smallest elements in the periodic ta&le is a) 4ithi%m c) Cesi%m &) 0l%orine d) 5odine

(1.

Which one of the following is not a coinage metal? a) A% c) Ag &) C% d) Fd

-#.

Which halogen has the smallest electron affinity? a) 0 c) Br &) Cl d) 5

(#.

Which is the most metallic element of #nd period? a) 4ithi%m c) Boron &) Berylli%m d) Car&on

-*.

$he element with atomic n%m&er 6 is li+ely to ha<e same properties to the element whose atomic n%m&er is a) 11 c) 1&) # d) 0

(*.

$he o%ter most or&ital in<ol<ed in chemical &onding is called a) 2olec%lar or&ital c) Balence or&ital &) Complete or&ital d) 0ree or&ital -(.

Which of the following will ha<e largest si;e? a) Br c) 5 &) 5 81 d) 0

((.

=lements> which form &asic o.ides are a) =lectropositi<e c) 5nert &) =lectronegati<e d) None of these --.

5n its chemical properties> calci%m is most similar to a) Cs c) Sc &) C% d) Sr

(-.

Which of the following has the most &asic character? a) Na#7 c) Al#7* &) 2g7 d) F#7* -1.

Which two of the following are iso electronic with one another?

a) Na/ and 7 c) Na/ and Ne -6.

&) Na/ and K/ d) Ne and 7

16.

5onic hydrides are also called a) Saline hydrides c) Both a L & &) Salt li+e hydrides d) None of these

Which of the following is a trans%ranic element? a) Americi%m c) Nept%ni%m &) Fl%toni%m d) All of these 1).

$he hydrides are acts as powerf%l red%cing agents are a) 5onic c) 5nterstitial &) Co<alent d) Comple.

-).

$he hydrogen> which is present in the atmosphere of s%n and stars in a large amo%nt> is a) !# &) ! c) !/ d) !8 Cesi%m and 0ranci%m are li,%ids a&o<e a) 1'oC c) #'oC &) 1-oC d) *'oC 6'. 19.

-9.

$he hydrides which are non stoichiometric in nat%re are a) 5onic c) 5nterstitial &) Co<alent d) Comple.

1'.

5n an a,%eo%s sol%tion the hydrides of al+ali metals are a) Sta&le c) No change &) Gnsta&le d) None of these of the halogen

Which one is the e.ample of comple. hydride? a) F!* c) 4a!* &) Na! d) NaB!(

11.

As the atomic n%m&er increases> the halogens a) &) c) d)

61.

$he adsorption of hydrogen &y platin%m is +nown as a) !ydrogenation c) 7ccl%sion &) "ehydrogenation d) S%&stit%tion

4ose their o%termost electrons less easily Become less dense Becomes lighter in color :ain electrons less easily

6#.

1#.

$he electron affinity of fl%orine is a) H *().) +IJmol c) **6 +IJmol &) H **6 +IJmol d) *().) +IJmol 6*.

0rom left to right in a periodic ta&le charge to mass ratio increases therefore the hydration energy a) "ecreases c) 3emains constant &) 5ncreases d) None of these

1*.

Which ionic halides ha<e high m.p and &.p? a) 0l%oride c) Bromide &) Chloride d) 5odide

AAAAAA elements ha<e &een disco<ered so far. a) 1'' c) 1#' &) 11' d) 1-'

1(.

Which gas is %sed in the ma+ing of t%ngsten &%l& filaments? a) !# c) 7# &) N# d) C7#

6(.

AAAAAAA classified the then +nown elements into metals> non metals and their deri<ati<es. a) "o&reiner c) Newlands &) Al H 3a;i d) 2endelee<e

1-.

$he ionic halides in order of decreasing m.p and &.p can &e arranges as a) &) c) d) 5odideK&romideKchlorideK fl%oride BromideKchlorideKfl%orideKiodide ChlorideK&romideKiodideKfl%oride 0l%orideKchlorideK&romideKiodide

6-.

"o&reinerCs wor+ led to the law of triads which states that AAAAAA a) Atomic weight of any one element was fo%nd to &e appro.imately the mean of the other two elements of triad. &) Atomic weight of the middle element was fo%nd to &e appro.imately the mean of the other two elements of a triad. c) Atomic n%m&er of any one element was fo%nd to &e appro.imately the mean of the other two elements of a triad.

11.

A hydride ion and heli%m atom has same n%m&er of a) Frotons c) =lectrons &) Ne%trons d) All of these

d) Atomic n%m&er of the middle element was fo%nd t &e appro.imately the mean of the other two elements of a triad. 61. $he law of octa<es was gi<en &y AAAAAAA

)#.

Grani%m is a mem&er of a) s H &loc+ c) d H &loc+ &) p H &loc+ d) f H &loc+

)*. a) "o&reiner c) Newlands &) Al H 3a;i d) None of these

!ow many ioni;ation energies can car&on ha<e? a) 1 c) ( &) # d) 1

)(.

Which ion has the ma.im%m polari;ation power? a) 4/ c) Al */ &) 2g #/ d) 7 #8

66.

4aw of octa<e states that AAAAAA )-. a) $he properties of e<ery 1th element from the gi<en one were similar to the first. &) $he properties of e<ery 9th element from the gi<en one were similar to the first. c) $he properties of e<ery )th element from the gi<en one were similar to the first. d) $he properties of e<ery 6th element from the gi<en one were similar to the second. Which of the following halides is not o.idi;ed &y 2n7#? a) 0 c) Br )1. &) Cl8 d) 5

$he process re,%iring a&sorption of energy is a) 0 M 0 c) 7 M 7# &) Cl M Cl d) ! M !

6).

2endelee<Cs Feriodic $a&le was &ased on AAAAAAA a) Atomic n%m&er c) Atomic <ol%me &) Atomic mass d) =lectronic config%ration

)6.

2ost of the +nown elements are metals of AAAAAA of periodic ta&le. a) " H &loc+ c) 555 H gro%p &) F H &loc+ d) ero &loc+

69.

2oseleyCs wor+ led to the periodic law> which states that AAAAAAA a) $he n%m&er of the electrons in the 1st energy le<el increases as the atomic n%m&er increases. &) $he properties of the elements are a periodic f%nction of their atomic mass. c) $he . H rays spectra of the elements are more comple. than the optical spectra. d) $he properties of elements are the periodic f%nction of their atomic n%m&er.

)).

$he <ol%me in c%&ic centimeters occ%pied &y one gram atom of the element is called AAAAAA a) Atomic <ol%me c) 2ass n%m&er &) Atomic weight d) None

)9.

$he lowest ioni;ation energies are fo%nd in the AAAAAAA a) 5nert gases &) Al+ali metals c) $ransition elements d) !alogens

)'.

A pair of elements in the same family in the periodic ta&le classification is AAAAAAAA a) Chlorine and car&on &) Calci%m and al%min%m c) Nitrogen and neon d) Sodi%m and potassi%m

9'.

$he %nit of ioni;ation energy is AAAAAAA a) No%le c) =lectron <olt &) Calorie d) None

91.

$he electropositi<e elements form AAAAA a) Acidic o.ides c) Ne%tral o.ides &) Basic o.ides d) Amphoteric o.ide

)1.

5n the period> the elements are arranged in strict se,%ence in order of AAAAAAA a) 5ncreasing charges in the n%cle%s. &) 5ncreasing atomic weights. c) 5ncreasing n%m&er of electrons in <alence shell. d) 5ncreasing <alency. 9#.

$he electronegati<e elements form AAAAA a) Acidic o.ides c) Ne%tral o.ides &) Basic o.ides d) Amphoteric o.ide

9*.

$he ioni;ation energy of nitrogen is more than

o.ygen &eca%se of AAAAAAA a) 2ore attraction of electrons &y the n%cle%s &) 2ore penetration effect c) $he e.tra sta&ility of half filled p H or&ital d) $he si;e of nitrogen atom is smaller. 9(. AAAAAAA ion has the largest radi%s. a) Al/* c) 081 9-. &) Cl81 d) 78#

5onic hydrides are %s%ally AAAAAAA a) 4i,%ids at room temperat%re &) :ood red%cing agents c) :ood electrical cond%ctors in solid state d) =asily red%ced.

91.

$he hydroni%m ion is aJan AAAAAAA a) 5on with form%la !#7/ &) 5on with the form%la !*7/ c) 0ree radical rather than an ion d) 5on formed &y remo<al of !8 form a water molec%le. CHAPTER # 2 S-Block Elements 1. $he o.ides of &erylli%m are. (A) Acidic (C) Ba/# #. (B) Basic (") 2g/#

96.

When steam is passed o<er red hot co+e at 1'''oC> a mi.t%re of car&on mono.ide and hydrogen gas is prod%ced. 5t is +nown as AAAAAA a) !ea<y water c) Fhosgen gas &) Water gas d) None

Which ion will ha<e the ma.im%m <al%e of heat of hydration? (A) Na/ (C) Ba/# (B) Cs / (") 2g/#

*.

Which one of the following is not an al+ali metal? (A) Sodi%m s%lphate (C) inc s%lphate B) Fotassi%m s%lphate ") Bari%m s%lphate

(.

$he element cesi%m &ears resem&lance with. (A) Ca (C) Both of the a&o<e (B) Cr (") None of the a&o<e

-.

Chile saltpeter had the chemical form%la (A) NaN7* (C) Na#B(76 (B) KN7* (") Na#C7*!#7

1.

$he ore CaS7(#!#7 has the general name. (A) :yps%m (C) Calcite (B) "olomite (") =psom salt

6.

"ownOs cell is %sed to prepare. (A) Sodi%m car&onate (B) Sodi%m &icar&onate (C) Sodi%m metal (") Sodi%m hydro.ide

).

Which element is deposited at the cathode d%ring the electrolysis of &rine in NelsonOs cell? (A) !# (C) C5# (B) Na (") 7# 19.

(A) Be (C) Ca

(B) 2g (") Ba

$he melting point and &oiling point of which al+aline earth metal is high. (A) Sr (C) Be (B) 2g (") Na

9.

5onic radi%s of potassi%m is. (A) 1' pm (C) 99 pm (B) 1** pm (") 119 pm B #'.

$he s%per o.ides are formed &y the elements. (A) K> 3&> Cs (C) K> 4i> Na (B) K> Na> Cs> (") None of the a&o<e

1'.

Among al+aline =arth 2etals> the highest heat of hydration is of. (A) Be (C) 3& (B) Sr (") Cs #1.

Fotassi%m> r%&idi%m and caesli%m are so highly reacti<e that they react with ice e<en at . (A) 81''7C (C) 8-'oC (B) 8#''7C (") 8' oC

11.

$he chemical form%la of syl<ite is. (A) Na#C7*. !#7 (C) KC5. 2gC4#. 1!#7 (B) KC5 (") NaC5 ##.

1#.

$he chemical form%la of Al%mite (Al%m stone) is. (A) KC5. 2gC5#. 1!#7 (B) KC5 (C) Na#B(76. 1'!#7 (") K#S7( Al(S7()*. #Al(7!)*

Among the al+aline earth metal which has least reacti<ity e<en %pto )''oC (A) Ba (C) 4i (B) Cs (") Be

#*.

Flaster of paris is formed after heating %pto 1''7C (A) 2g(N7*)# (C) NaN7# (B) CaS7(> #!#7(gyps%m) (") 4iN7*

1*.

Among al+ali metals the lowest atomic n%m&er is of. (A) 3& (C) Sr (B) K (") 4i #(.

$he root system of se<eral plants ha<e &een greatly enlarged &y the application of. A) S%lph%r C) Both of the a&o<e B) :yps%m ") None of the a&o<e

1(.

"%e to the high reacti<ity nat%re of the al+ali metals> they are fo%nd in. (A) 0ree in nat%re (B) Bo%nded with other elements (C) Not free in nat%re (") All of the a&o<e #-.

When deficiency of calci%m e.ists <ario%s s%&stances are acc%m%lated in plants in harmf%l concentration which are. (A) 4ime (B) Al%mini%m (C) Alimini%m and 2anganese (") None of the a&o<e

1-.

2agnesi%m is an essential constit%ent of. (A) Storaata (C) Chlorophy55 (B) Flants (C) None of the a&o<e #1.

11.

Which of the al+ali earth metal has radioacti<e nat%re. (A) Be (C) Both of the a&o<e (B) 3& (") Na

Which al+ali metal &eha<e different &y from others? (A) 2g (C) 3& (B) Na (") 4i

16.

Calci%m Fhosphate Ca* (F7() and calci%m fl%oride Ca0# are essential part of li<ing organisms. (A) Bones> egg shells (C) Sea8shells (B) teeth (") All of the a&o<e

#6.

Spod%mene> petalite> halite> natron> alinite are the common minerals of. A) Al+ali metals B) Al+aline earth metals C) Both of the a&o<e ") 4i

#). 1). "olomite is a compo%nd of which elements.

Sodi%m is prepared &y the electrolysis of. (A) Simple NaC5 in "own>s cell

(B) 2olten NaC5 in "own>s cell (C) 2olten sodi%m hydro.ide in downOs cell (") None of the a&o<e #9. 4ime is %sed in. (A) :lass ind%stry (B) :lass and paper ind%stries (C) Faper ind%stries (") None of the a&o<e *'. $he elements which are <ery a&%ndant in earth cr%st areAAAAAAAAAA a) Si L AP c) B L AP *1. &) Ca L 2g d) All

crystalli;ation *). 5n diaphragm cell> le<el of &rine in anode compartment is +ept slightly higher which pre<entsAAAAAAAAA a) !ydro.ide ions to reach anode &) Chlorine gas to mi. c) Anode to decay d) All *9. Al+ali metals form &onds a) 5onic c) 2etallic ('. &) Co<alent d) Co8ordinate co<alent

$he o.ides of Be are AAAAAAAAAAA a) Acidic c) Amphoteric &) Basic d) None

$he al+ali metals> which ha<e radioacti<e isotopes a) 4i c) K &) Na d) K and 3&

*#.

Car&onates of lithi%m are not sta&le li+e that of sodi%m d%e to AAAAA a) 4ow electronegati<ity &) 4ow electropositi<ity c) 4ow charge density d) Not +now yet

(1.

!alite is the mineral of a) Sodi%m c) 4ithi%m &) Fotassi%m d) Cesi%m

(#.

Na#S7*.1'!#7 is the mineral of sodi%m and is called a) Spod%mene c) Natron &) !alite d) Syl<ite

**.

Which one of the following is not an al+ali metal? a) 0ranci%m c) 3%&idi%m &) Caesi%m d) 3adi%m (*.

Which one of the following is dolomite? a) 2gC7* c) CaC7* &) 2gC7*.CaC7* d) BaS7(

*(.

Which of the following s%lphates is not sol%&le in water? a) Sodi%m s%lphate c) inc s%lphate &) Fotassi%m s%lphate d) Bari%m s%lphate ((.

$he high electrical cond%cti<ity of al+ali metals is d%e to the a) &) c) d) 0ree motion of <alence electrons !igh 5.F 4esser atomic radii None of these

*-.

$he ore CaS7(.#!#7 has the general nameAAAA a) :yps%m c) Sodi%m metal &) "olomite d) Sodi%m hydro.ide (-.

Sodi%m imparts color to B%nsen flame a) :reen c) Bl%e &) Biolet d) Qellow

*1.

Crystals of Na#C7*. 1'!#7 when e.posed to air> AAAAAAA a) 4ose water and remain solid &) :ain water and remain solid c) :ain water and &ecome li,%id d) 3emains %nchanged. (1.

All al+aline earth metals are white e.cept a) 2g c) Be &) Ca d) Sr

*6.

$he deli,%escence is a process in which a solidAAAAAAAA a) A&sor&s moist%re and remains solid &) A&sor&s moist%re and t%rns to li,%id form c) 4oses water of crystalli;ation d) 5ncreases the n%m&er of water of

(6.

2etals> which are higher that water> are a) &) c) d) Al+aline earth metals Coinage metals Al+ali metals All of these

-6. (). =.cept lithi%m> the hydro.ides of all al+ali metals are a) Strongly acidic c) Wea+ly &asic (9. &) Strongly &asic d) All of these -). $he car&onates and phosphates of which elements are insol%&le in water a) Na and K c) 4i and 2g -'. &) Na and Be d) All of these -9. All al+aline earth metals react with water at room temperat%re to release hydrogen and gi<e &asic sol%tions e.cept a) Be and Ca c) Ca and 2g &) Be and 2g d) 2g and Sr 1'.

Which is man%fact%red &y the electrolysis of f%sed sodi%m chloride? a) Na7! c) Na &) Na!C7* d) Na#C7*

Which of the following does not cond%ct electricity? a) Boron c) 5ndi%m &) :alli%m d) $halli%m

Which al+ali metal is rare and fo%nd in a small amo%nt in all H igneo%s roc+s? a) 4i c) K &) Na d) 0r

$he ingredient of &a+ing powder is a) Na!C7* c) Na#C7* &) Na7! d) NaCl

-1.

4ithi%m only forms normal o.ides when &%rnt on air &%t when sodi%m &%rnt in air it forms 11. a) Normal o.ides c) Fero.ides &) S%& o.ides d) S%per o.ides 1#. $he form%la of plaster of Faris is a) CaS7( c) CaS7(.#!#7 &) CaS7(.!#7 d) #CaS7(.!#7

-#.

$he s%per o.ides of al+ali metals are generally represented &y a) 2#7 c) 27# &) 2#7# d) 2#7*

Which of the following is fl%orspar? a) Ca7 c) Ca0# &) CaC7* d) Na7!

-*.

$he nitrates of which gro%p decompose on heating with the formation of nitrites and e<ol%tion of o.ygen a) 5A c) 555 A &) 55 A d) 5B A

1*.

Fotassi%m is +ept in a) Water c) Ammonia &) Alcohol d) Kerosene oil

1(.

Which one has high m.p? a) NaCl c) Nal &) NaBr d) Na0

-(.

A small amo%nt of calci%m chloride or mi.t%re of KCl and K0 is added to NaCl in "ownCs cell a) &) c) d) $o ma+e it good cond%ctor $o decrease the m.p of NaCl $o increase the ioni;ation of NaCl $o decrease the ioni;ation of NaCl 1-.

Which one of the following is most &asic? a) Al#7* c) F#7&) Si7# d) 2g7

--.

4i,%id sodi%m in the "ownCs cell is collected at a temperat%re of a) 6''oC c) -''oC &) 1''oC d) (''oC

11.

:yps%m is a) CaS7(.#!#7 c) CaS7( &) CaS7(.!#7 d) 2gS7(

16. -1. $he prod%ct> which is o&tained at cathode in the "ownCs cell is a) 4i,%id Sodi%m c) Water &) "ry chlorine d) !ydrogen 1).

Which one is commonly %sed as a la&oratory desicator? a) Na#C7* c) CaCl* &) NaCl d) Na7!

$he radioacti<e al+aline earth metal is

a) Be c) 3a 19.

&) 2g d) Ba 6).

a) Na c) Ca

&) K d) Cs

Which one of the following elements has its compo%nds which are diamagnetic and colo%rless? a) Be c) Na &) Sr d) All of these

Which one is %sed in the man%fact%re of chal+ pencils? a) 2ar&le c) =psom salt &) :yps%m d) Ba+ing soda

6'.

Which metal is an important component of transistors? a) Ag c) 3a &) A% d) 7s

69.

Flaster of Faris has a str%ct%re a) C%&ic c) !e.agonal &) 2onoclinic d) 7rthorhom&ic

)'. 61. Which imp%rities are present in common salt? a) Na#S7( c) CaCl# &) CaS7( d) All of these

Fotassi%m s%per o.ide (K7#) is %sed in &reathing e,%ipments for mo%ntaineers and space craft &eca%se it a&sor& a) 7.ygen and gi<ing o%t C7# at the same time &) N# and gi<ing o%t C7# at the same time c) C7# and gi<ing o%t 7# at the same time d) Foll%tants and gi<ing o%t 7# at the same time

6#.

K can displace Na from NaCl d%e to a) &) c) d) :reater 5.F of K :reater 5.F of Na 2ore electropositi<ity of K 2ore electropositi<ity of Na

)1.

$he hydro.ide> which is called mil+ of magnesi%m and is %sed for treatment of acidity in stomach> is a) Ca(7!)# c) Sr(7!)# &) 2g(7!)# d) Ba(7!)#

6*.

$he al+ali metal> which is artificially prepared a) Na c) 0r &) 3& d) Cs

)#.

2g/# is smaller the Na/1 &eca%se a) &) c) d) 2g/# has fewer electron than Na/1 2g/# has greater electron than Na/1 2g/# has greater atomic n%m&er than Na/1 2g/# has low 5.F than Na/1 has almost same

6(.

$he chemical %se for the prod%ction of C7# in the fire e.ting%ishers is )*. a) &) c) d) Na7! NaCl Na!C7* and dil%te acid Na!C7* and Na7! )(.

Which of them electronegati<ity? a) Be> B c) Be> Al

&) B> Al d) K> Na

6-.

4iCl is more sol%&le in organic sol<ents than NaCl &eca%se a) &) c) d) 4i/1 has higher heat of hydration than Na/ 4i/1 has lower heat of hydration than Na/ 4iCl is more co<alent than NaCl 4attice energy of NaCl is less than that of 4iCl

A mi.t%re formed &y mi.ing one <ol%me of sla+ed lime Ca(7!)# with three or fo%r <ol%me of sand and water to form a thic+ paste is called a) 4ime water c) R%ic+ lime &) "ead water d) 2il+ of lime

)-. 61. Which compo%nd is %sed for %ric acid treatment in h%man &eings? a) Na#C7* c) 4i#C7* 66. &) Na!C7* d) NaN7* )1.

5f the compo%nd has the same crystal str%ct%re and analogo%s form%lae> they are called a) 5sotopes c) 5somers &) Allotropes d) 5so&ars

Which element is %sed in $.B pict%re t%&e?

7%t of all elements of gro%p 5A> the highest

10

heat of hydration is for AAAAAAA a) K c) Cs )6. &) 3& d) 4i 91. $he nitride ion in lithi%m nitride is composed of a) 6 protons and 6 electrons &) 1' protons and 6 electrons c) 1' protons and 1' electrons d) 1' protons and - electrons )). When N!* is passed o<er heated sodi%m at *''oC> the prod%ct formed is a) NaN!# &) NaN7# c) Na(N!*)# d) Na*N Sodi%m metal can &e stored %nder 9). a) Ben;ene c) Alcohol 9'. Chile s%lph%r is 99. a) NaN7# c) NaN7* &) KN7# d) KN7* &) Kerosene d) Water 96.

c) 5t e.erts considera&le &ea%tif%l force on the <alence electrons d) 5t is a hea<ier metal. A graphite anode is %sed in "ownCs cell for the prod%ction of sodi%m &eca%se AAAAAA a) 5t does not react with sodi%m &) 5t does not react with chlorine c) 5t is easy to fashion in circ%lar form d) 5t floats on the f%sed sodi%m chloride Al+aline earth metals form AAAAAA car&ides on heating with car&on. a) Sta&le c) Sol%&le &) Gnsta&le d) None of these

)9.

When &%rnt in air> 4ithi%m forms AAAAAAA a) Normal o.ide c) S%per o.ide &) Fero.ide d) None of these

Sodi%m &icar&onate is commonly called a) Soda ash c) Ca%stic soda &) Ba+ing soda d) None of these

91.

Al+ali metals do not e.ist in 1''. a) 2onoatomic c) $riatomic &) "iatomic d) None of these 1'1. a) 3ed%cing agents &) 7.idi;ing agents c) Both red%cing and o.idi;ing agents d) None of these 1'#. AAAAAAA is a stronger &ase. a) Na7! c) 4i7! &) K7! d) !Cl

9#.

5n general al+ali metals act as AAAAAAAA =.cess of Na7! reacts with ;inc to form a) n(7!)# c) Na# n7# &) n!# A d) n7

9*.

Sodi%m is not o&ser<ed in / # o.idation state &eca%se of its AAAAAA a) !igh first ioni;ation potential &) !igh second o.idation potential c) !igh ionic radi%s d) !igh electronegati<ity

Which of the following represents calci%m chlorite? a) CaCl7# c) Ca(Cl7*)# &) Ca(Cl7()# d) Ca(Cl7#)#

1'*.

Sodi%m hydro.ide sol%tion reacts with phosphor%s to gi<e phosphine> $o &ring a&o%t we need this reaction a) White phosphor%s and dil%te Na7! &) White phosphor%s and concentrated Na7! c) 3ed phosphor%s and dil%te Na7! d) 3ed phosphor%s and concentrated Na7!

9(.

$he metallic l%ster of sodi%m is e.plained &y the presence of AAAAAAA a) Na/ ions &) Cond%ction electrons c) 0ree protons d) A &ody centered c%&ic lattice

1'(.

Sodi%m reacts with water more <igoro%sly than lithi%m &eca%se it a) !as higher atomic weight &) 5s more electronegati<e c) 5s more electropositi<e d) 5s a metal

9-.

5n the al+ali metal series> Cesi%m is the most reacti<e metal &eca%se AAAAAAA a) 5ts incomplete shell is nearest to n%cle%s &) $he <alence electron has a larger or&it than the or&it of the <alence electron of any of the other.

1'-.

Flaster of Faris hardens &y

11

a) :i<ing off C7# &) Changing into CaC7* c) Gniting with water d) :i<ing o%t water

12

CHAPTER # 3 ro!" ### and #$ Elements 1. Which metal is %sed in the thermal process &eca%se of its acti<ity.

11.

$he increase in the atomic si;e in gro%p is (A) 3eg%lar (C) Both (B) 5rreg%lar (") None of the a&o<e

1#. (A) 5ron (C) Al%min%m #. Al%min%m o.ides is 1*. (A) Acidic o.ide (C) Amphoteric o.ide *. (B) Basic o.ide (") None of these (B) Copper (") inc

7rtho&oric Acid is a mineral of. (A) Al%min%m (C) Calici%m (B) Silicon (") Boron

Al%min%m is the third most a&%ndant elements in earth cr%st after. (A) 7.ygen (B) Silicon (C) None of the a&o<e (") Both of the Both

Chemical composition of colemnite is. (A) Ca#B1711. -!#7 (C) Na#B(76. (!#7 (B) CaB(76. (!#7 (") CaNaB-79. )!#7 1(.

Ba%.ite is an ore of. (A) Al%min%m (C) Car&ono (B) Boron (") :alli%m

(.

Which element forms an ion with charge */. (A) Berylli%m (C) Car&on (B) Al%min%m (") Silicon 1-.

Which of the elements of :ro%p 55A are rare and only o&tained as &y8prod%cts. (A) :alli%m thalli%m (B) $halli%m indi%m (C) :alli%m indi%m (") :alli%m thalli%m indi%m

-.

Which element among the following &elongs to :ro%p 5BA of the periodic $a&le. (A) Bari%m (C) 4ead (B) 5odine (") 7.ygen 11.

1.

Boric acid cannot &e %sed. (A) As antiseptic in medicine (B) 0or washing eyes (C) 5n soda &ottles (") 0or enamels and gla;es

Bora. is the sodi%m salt of tetra&oric acid. 5t is most important of all among. (A) Borates (C) Bicar&onates (B) Car&onates (") None of the a&o<e

16.

Bora. occ%rs as nat%ral deposit called tincal in the dried %p la+es of. (A) $i&et (C) $i&et L California (B) California (") Birginia

6.

Which of the following elements is not present a&%ndantly in earthOs cr%st. (A) Silicon (C) Sodi%m (B) Al%min%m (") C 1).

:ro%p 5B A of the periodic ta&le comprises elements. (A) Car&on silicon (B) $in> car&on > silicon (C) Car&on> silicon> tin and lead (") None of the a&o<e

).

$he chief 7re of al%min%m is. (A) Na*A501 (C) Al#7* (B) Al#7*. #!#7 (") Al#7*. !#7 19.

9.

$he :ro%p 55A of the periodic ta&le comprises the elements. (A) Boron> al%min%m> galli%m> indi%m and thalli%m. (B) Boron galli%m> thalli%m. (C) Al%min%m> calci%m> stronti%m. (") All of the a&o<e

$he non8metals in :ro%p 5B A are. (A) Car&on> silicon (C) All of the a&o<e (B) $in and 4ead (") None of the a&o<e

#'.

$he elements of :ro%p 5B A are character si;ed &y a set of . (A) $hree <alence shell electrons (B) 0o%r <alence shell electrons (C) 0i<e <alence shell electrons (") $wo <alence shell electrons

1'.

Boron is non8metallic &eca%se of (A) 4arge si;e and higher n%clear change (B) Small si;e and higher n%clear charge (C) Small si;e and smaller n%clear charge (") None of the a&o<e

13

#1.

:ro%p 5B A elements form. (A) S%per o.ide (C) "io.ide (B) 7.ides (") All of the a&o<e

#9.

S%&stance which is fo%nd in dried %p la+es of $i&et and California isAAAAAA a) $incal c) Calci%m car&onate &) Boric Acid d) All

##.

$he property of catenation among the car&on and silicon . (A) 5ncrease on mo<ing down the gro%p form car&on to lead (B) "ecrease on mo<ing down the gro%p from lead to car&on. (C) "ecreases on mo<ing down the gro%p from car&on to lead (") Sta&le on mo<ing down the gro%p from car&on to lead.

*'.

Boron is a white crystalline solid and it isAAAAAAAA a) 2ore sol%&le in cold water &) 2ore sol%&le in hot water c) 2ore sol%&le in water d) Sol%&le only in organic sol<ents

*1.

7ne of the o%tstanding feat%res of &oron is a&ility to formAAAAAAAA a) 2olec%lar addition compo%nds &) 2olec%lar crystals c) Semicond%ctors d) All

#*.

$he o.ides of car&on are (A) C7 and C7# (B) C7> C7# and C*7# car&on s%& o.ide (C) C7> C7#> C#C* (") None of the a&o<e

*#.

Which of the following does not gi<e Bora. &ead test? a) C% c) Ni &) Cr d) Al

#(.

China wares are made form a mi.t%re of (A) Kaolin and &one ash (B) Kaolin and feldspar (C) Kaolin feldspar and &one ash (") None of the a&o<e

**.

$he metal which is %sed in thermite process &eca%se of its acti<ity isAAAAAAA a) 5ron c) Al%mini%m &) Copper d) inc

#-.

Bario%s o.ides are %sed as pigments in the pigments of which element. (A) 7.ides of lead> &asic lead car&onate etc. (B) Bario%s o.ides of lead (C) Bario%s o.ides of lead> &asic lead car&onate> lead chromate (") 7.ides of al%min%m *(.

Which of the following shows inert pair effect? a) Boron c) Silicon &) Car&on d) $in

*-. #1. Boron occ%rs in traces and has &een fo%nd to &e important for the growth of. (A) Flants of many +inds (B) Flants and animals (C) Animals (") None of the a&o<e #6. Semicond%ctors cond%ct electricity &etter than. (A) Cond%ctors (C) Both of the a&o<e #). (B) 5ns%lators (") None of the a&o<e *6. *1.

$incal is a mineral ofAAAAAAAAAAAA a) Al c) B &) Si d) C

Beca%se of its a&ility to com&ine with &oth o.ygen and nitrogen> al%mini%m metal is %sedAAAAAAAAA a) As nitrometer &) $o remo<e air &%&&les from molten metal c) $o prod%ce alloy d) All Silicon differ from silica &y a gro%p of AAAAAAAAA a) C!* c) 7C!* &) H7! d) 7#

7.ygen is the a&%ndant element in earth cr%st? (A) 2ost of all (B) #nd in n%m&er (C) $hird most a&%ndant (") (th most a&%ndant

14

*).

Boron in soil has &een considered essential specially forAAAAAAAA a) Soil porosity &) Froper growth of plants c) Al+alinity of soil d) All

().

7rtho&oric acid is wea+ acid &eca%se it a) Accepts 7!81 ion c) Accept !/1 &) "onate 7!81 ion d) "onate !/1

(9.

$he a,%eo%s sol%tion of which acid is %sed for washing eyes? a) !#B(76 c) !*B7* &) !Cl d) !B7#

*9.

Special feat%re of &orate glass is that it is AAAAAA a) !eat resistant &) 4ow melting c) Gsed to prepare chemical garden d) All -'.

$he process in which Ba%.ite is p%rified &y dissol<ing it in (-S a,%eo%s Na7! at 1-'oC to separate insol%&le iron o.ide as red m%d is called a) !allCs process c) Arrheni%s process &) BaeyerCs process d) :rignard process

('.

5n p H &loc+ elements> the S H electrons of o%ter shell of the hea<ier mem&ers are failed to participate in &onding> &eca%se they a) 3emain paired c) Are free &) 3emain %npaired d) None of these -1.

Ba%.ite is an o.ide mineral of a) C% c) Al &) Ag d) n

(1.

$he tendency of the pair of S H electron to remain inert increase with the increase in -#. a) Atomic n%m&er c) =.N &) Atomic weight d) 5.F

AlCl* and :aCl* are co<alent when anhydro%s &eca%se a) &) c) d) $hey &elong to gro%p 555 A $heir ions ha<e small si;e and high charge $hey ha<e high 5.F None of these

(#.

Boron does not easily form cations> &eca%se it has the tendency to form &ond li+e non8metal a) 5onic &ond c) !ydrogen &ond &) 2etallic &ond d) Co<alent &ond -*.

(*.

Boron is metalloid and semicond%ctor li+e a) Be c) Si &) K d) Al

5n the electrolysis of al%mina is mi.ed with Cryolite (Na*Al01) and fl%orspar (Ca0#) in the ratio of #' ? 1' ? #'. the f%nction of the Cryolite and fl%orspar is a) $o decrease the f%sion temperat%re of al%mina and to ma+e good cond%ctor of electricity &) $o dissol<e al%mina c) $o dissol<e sodi%m d) $o increase the ioni;ation of al%mina

((.

Which element is %nsta&le in air and is o.idi;ed s%perficially in air a) Al%min%m c) :alli%m &) $halli%m d) 5ndi%m -(.

$ermite is a mi.t%re of a) &) c) d) 5ron o.ide and al%min%m 5ron o.ide and copper Copper o.ide and al%min%m None of these

(-.

Crystalline &oron has str%ct%re a) C%&ic c) !e.agonal &) 2onoclinic d) $rigonal --. a) 5onic hydrides c) 5nterstitial hydrides &) Comple. hydrides d) Co<alent hydrides

(1.

$he hydrides B#!1 and Si#!1 are said to 5n al%min%m termite process> al%min%m acts as a a) 3ed%cing agent c) A fl%. -1. a) Na7! c) Na#B(76.1'!#7 &) !*B7* d) !#B(76 &) 7.idi;ing agent d) None of these

(6.

$he compo%nd> which is %sed in &ora. &ead test for cations analysis> is

Which al%mini%m alloy is e.tremely light? a) "%ral%min &) Alnico

15

c) 2agnali%m

d) Al%mini%m &ron;e a) C% c) Ft &) Ni d) N#7-

-6.

C%pric o.ide on heating with B #7* yields &l%e colored &eads in the o.idi;ing flame &eca%se a) &) c) d) C%pric &orates are white in color C%pric &orates are &lac+ in color C%pric &orates are green in color C%pric &orates are &l%e in color

16.

$he depositing layer in tin plating is a) C% c) Al &) Sn d) Ni

1).

7rtho &oric acid on heating at 1''oC yields a) &) c) d) 2eta &oric acid Fyro&oric acid $etra &oric acid Boric anhydride acid (B#7*)

-).

5n mordenting al%mini%m ions (Al /*) are precipitated on the cloth as a) Al#7* c) Al(7!)* &) AlN d) AlCl* 19.

-9.

Flatin%m metal can &e dissol<ed in a) &) c) d) !ot con !Cl !ot con !#S7( !ot con !N7* A mi.t%re of Con. !Cl and con !N7*

Which of the following is %sed in photographic film? a) 2gBr# c) AgBr &) NaCl d) Na#S#7*

6'.

1'.

Which of the following can form nitride> which react with water to gi<e ammonia? a) Boron c) 5ndi%m &) :alli%m d) $halli%m 61.

Al%min%m does not react with !N7 * at any concentration and therefore !N7* is transported in al%min%m containers> this is d%e to formation of protecti<e layer of a) C%pric o.ide &) 0erric o.ide c) Al%min%m o.ide d) Al%min%m nitride Action of a,%a regia on no&le metals is d%e to a) !N7* c) !#S7( &) !Cl d) Chlorine

11.

$he wea+ acid> which cannot &e titrated with standard al+ies> is a) !Cl c) !*B7* &) !#S7( d) All of these

6#. 1#. Car&on differs from other mem&ers of its gro%p d%e to smaller atomic si;e> higher electronegati<ity and the a&sence of a) s H electrons c) d H electrons 1*. &) p H electrons d) All of these 6*.

Fhosgene is a poisono%s gas> its chemical name is a) Car&on dio.ide &) Fhosphonyl chloride c) Car&on mono.ide d) Car&onyl chloride $he ma.im%m inert pair effect is shown &y a) B c) :a &) Al d) $l

A,%a regia is a mi.t%re of concentrated !N7 * and concentrated !Cl in the ratio of a) * ? 1 c) # ? * &) 1 ? * d) * ? # 6(.

R%art; is the polymeric form of a) (Si7#)n c) (C!# H C!#)n &) (C7#)n d) None of these

1(.

5n land storage &atteries> the acid %sed is a) Con !Cl c) Con !#S7( &) "il !Cl d) "il !#S7( 6-.

5f a metal is protected &y an o.ide layer from f%rther attac+> the metal is said to &e a) 3eacti<e c) Fassi<e &) Acti<e d) Attracti<e

1-.

$he dry ice is a compo%nd of a) &) c) d) Solid ice with any water Solid S7# Solid C7# Solid C1!1 61.

Car&on reacts with metals to form a) !ydrides c) !ydro.ides &) 7.ides d) Car&ide

11.

5n the contact process for the man%fact%ring of !#S7(> the catalyst %sed is

16

66.

$he control addition of 555 A and 5B A mem&ers in Silicon and :ermani%m is +nown as a) 5nert pair effect c) 4itharge &) "oping d) 3ed lead )6. Boric acid is a) Wea+ mono&asic 4ewis acid &) 7nly wea+ mono&asic Arheni%s acid c) 7nly wea+ mono&asic Bronsted acid d) 7nly wea+ tri&asic Arrheni%s acid )). a) F&7 c) F&*7( &) F&7# d) F&(C!*C77) $he red%ction of metal o.ides is sometimes accomplished &y %sing al%min%m in the AAAAAA a) :oldschmidtCs reaction &) Sil&erchemditCs reaction c) BaeyerCs reaction d) ilchCs reaction )9. !allCs process is &ased on electrolysis of AAAAA a) Al%mina c) Bora. 9'. &) :yps%m d) None of these

6).

F H type of semi cond%ctor are formed &y mi.ing Silicon or :ermani%m with mem&ers of a) 555 A c) B A &) 5B A d) B5 A

69.

4itharge is chemically

)'.

$he 7ctet r%le is not followed &y a) Boron on BCl* &) 7.ygen in !#7 c) Nitrogen in N!* d) Fhosphor%s in F!* Which of the following elements show o.idation state of / * only? a) B c) 5n &) :a d) $i

)1.

)#.

AAAAAA of the following is not metallic in nat%re. a) Boron c) 5ndi%m &) Al%min%m d) $halli%m

AAAAAAA is a &etter cond%ctor of heat. a) 0e c) Al &) Sn d) None of these

)*.

$he o.ides of Boron are AAAAAA in nat%re. a) Acidic c) Ne%tral &) Basic d) None of these

91.

Al#7* formation in<ol<es e<ol%tion of a larger ,%antity of heat which ma+es its %ses in AAAAAAA a) "eo.idi;er c) 5ndoor photography &) Confectionary d) $hermite welding

)(.

7rtho&oric acid on heating to a&o%t 1''oC looses a water molec%le to form AAAAAA 9#. a) 2eta&oric acid &) Fyro&oric acid c) 2eta&oric and pyro&oric acid d) None of these

5n the commercial electrochemical process fro al%min%m e.traction> the electrolyte %sed is a) Al(7!)* in Na7! sol%tion &) An a,%eo%s sol%tion of Al#(S7()* c) A molten mi.t%re of Al#7* and Na*Al01 d) A molten mi.t%re of Al7(7!) and Al(7!)*

)-.

$he f%nction of 0l%orspar in the electrolytic red%ction of al%mina dissol<ed in f%sed cryolite (NA* Al01) is a) As a catalyst &) $o lower the temperat%re of the melt and to ma+e the f%sed mi.t%re cond%cting. c) $o decrease the rate of o.idation of car&on at the anode. d) None of the a&o<e

9*.

Bora. is prepared &y treating colemanite with a) NaN7* c) Na!C7* &) NaCl d) Na#C7*

9(.

=lements> which e.ist in two or more physical or molec%lar forms> are called AAAAAAA a) 5sotopes c) 5so&ars &) Allotropes d) None of these

)1.

Which of the following statements is correct? a) !*F7* is di&asic and red%cing &) !*F7* is tri&asic and red%cing c) !*F7* is tri&asic and non H red%cing d) !*F7* is di&asic and non H red%cing 9-.

F&7 &eha<es as aJan AAAAAAA a) Amphoteric o.ide c) S%per o.ide &) Basic o.ide d) S%& o.ide

17

91.

$he n%m&er and type of &onds &etween two car&on atoms in CaC# are a) 7ne sigma and one pi &ond &) 7ne sigma and two pi &onds c) 7ne sigma and one and a half pi &ond d) 7ne sigma &ond 1.

CHAPTER # % ro!" $ and $# Elements 7%t of all the elements of gro%p BA the highest ioni;ation energy is possessed. (A) N (C) S& #. (B) F (") Bi

96.

Al%min%m is diagonally related to a) 4i c) Be &) Si d) B

5n gro%p BA elements the most electronegati<e elements is. (A) S& (C) F (B) N (") As

9).

Which of the following halides is least sta&le and has do%&tf%l e.istence? a) Cl( c) :e5( &) Sn5( d) F&5( *.

7.idation of N7 in air prod%ced. (A) N7# (C) N#7( (B) N#7* (") N#7-

99.

5n which of the following phosphor%s has an o.idation state of / (? (. a) F(71 c) F(79 &) F(7) d) None of these

$he &rown gas is formed when metal red%ces !N7* (A) N#7(C) N7# (B) N#7 (") N7

-.

4a%ghing gas is chemically (A) N7 (C) N7# (B) N#7 (") N#7(

1.

7%t of all the elements of gro%p 5BA the highest melting and &oiling point is shown &y the elementsT (A) $e (C) S (B) Se (") F&

6.

S7* is not a&sor&ed in water directly to form !#S7( &eca%se. (A) $he reaction does not go to completion (B) $he reaction is ,%ite slow (C) $he reaction is e.othermic (") S7* is insol%&le in water

).

Which catalyst is %sed in contact process? (A) 0e#7* (C) S7* (B) B#7(") Ag#7

9.

Which of the following specie has the ma.im%m n%m&er of %npaired electrons. (A) 7# (C) 7#8 (B) 7#/ (") 7#8#

18

e.cept. 1'. Nitrogen and phosphor%s of gro%p BA show the typical properties of (A) 2etals (C) Both of the a&o<e (B) Non82etals (") None of the a&o<e (A) S (s%lph%r) (C) F7 (pollini%m ) (B) 7 (o.ygen ) (") $e (tell%ri%m)

11.

Arsenic and antimony are #'. (A) 2etals (C) 2etalloids (B) Non82etal (") None of the a&o<e #1. 5n gro%p B5A the radioacti<e metal is (A) $e (tell%ri%m) (C) N (nitrogen) (B) 7 (o.ygen) (") None of the a&o<e

1#.

$he common <alencies of the gro%p BA elements are (A) $wo to three (C) 7ne and fi<e (B) $hree and fi<e (") $wo and fo%r

7.ygen has allotropic forms s%ch as. (A) $hree (C) $wo (B) 0o%r (") 0i<e

1*.

Nitrogen is present in free state in air as a maIor constit%ent a&o%t. (A) -)S (C) 6'S (B) *)S (") 6)S

##.

7.ygen is comprising a&o%t . (A) *'S of earthOs cr%st (B) #'S of earthOs cr%st (C) 1'S of earthOs cr%st (") -'S of earthOs cr%st

1(.

Common o.ides of nitrogen are #*. (A) N#7> N7 and N7# (B) N7> N7# (C) N#7> N7# (") N#7> N7> N7#> N#7* L N#75n the atmosphere the free o.ygen occ%rs a&o%t (A) 1J* of the atmospheric air (B) 1J# of the atmospheric air (C) 1J( of the atmospheric air (") #J* of the atmospheric air #(. Water contains nearly com&ined form of o.ygen (A) -'S (C) *'S #-. S%lph%r e.ist as (A) 0ree and com&ined state (B) 7nly in free state (C) Com&ined state (") None of the a&o<e #1. Which of the following possesses melting point &elow 'UC? a) Nitrogen c) Car&on #6. &) Fhosphor%s d) Bism%th (B) 6'S (") )9S

1-.

"i8Nitrogen o.ide is a colo%rless gas. (A) With a faint pleasant smell and a sweetish taste. (B) With %npleasant smell and &itter taste. (C) With pleasant smell and &itter taste. (") With %npleasant smell and sweetish

11.

Nitric acid is %sed for. (A) 2a+ing <arnishes and 7rganic dyes (B) 0or ma+ing organic dyes (C) 2a+ing <arnishes (") 0or ma+ing <arnishes> organic dyes> e.plosi<es nitrogen fertili;ers etc.

16.

Allotropes of phosphor%s are of (A) $hree types (C) $wo types (B) 0o%r types (") Si. different types

1).

5n com&ined state nitrogen is fo%nd in all li<ing matter incl%ding. (A) Animals and plants as proteins %rea and amino acids. (B) 5n plants only (C) 5n animals only (") None of the a&o<e

0ormation of !#S7( &y Contact process is an e.ample of AAAAAAAA a) !omogeno%s e,%ili&ri%m &) !eterogeno%s e,%ili&ri%m c) S%lphonation d) "il%tion

#). 19. All the elements of grown B5A are non8metals

Which of the following does not contain phosphor%s?

19

a) Qol+ of egg c) Ner<es #9.

&) Bone d) Steel

*9.

Nitric o.ide has a) &) c) d) Gnpaired electrons 7dd n%m&er of electrons Faramagnetic All of these

Which of the following elements can follow e.tended octet r%le? a) F c) B &) C d) N

*'.

$he composition of &rown ring in nitrate test is AAAAAAAA a) 0eS7(.N7 c) 0eS7(.N7* &) 0eS7(.N7# d) None of a&o<e

('.

2i.t%re of !N7* and N7# is called a) con !N7* c) f%ming !N7* &) dil !N7* d) !N7*

*1.

Which one of the following compo%nds smells li+e garlic? a) F#7* c) !*F7* &) F#7d) All ha<e same smell

(1.

Which one FV- is %n+nown? a) FClc) F0&) FBrd) Fl-

(#. *#. All the elements areAAAAAAAAAAAAAA a) !ygroscopic c) Folymeric **. in gro%p B5A

7rthophosphoro%s acid is a a) 2ono&asic acid c) $ri&asic acid &) "i&asic acid d) Base

&) 2etals d) All of a&o<e

(*.

:alena is an ore of a) S c) Fo &) $e d) 2g

Fhosphoric acid is a wea+ acid and its &asicity isAAAAAAA a) 1 c) ero &) * d) 1 L * ((.

White phosphoro%s occ%rs in the form of a) &) c) d) 2onoatomic molec%le "iatomic molec%les $riatomic molec%les $etra atomic molec%les

*(.

$he nitrogen gas present in air is a) 2ore &) Non reacti<e &) 4ess reacti<e d) 2oderatory reacti<e (-.

*-.

$he properties of Nitrogen is different from other mem&ers of its gro%p to a) &) c) d) Small atomic si;e and high =.N Single screening shell A&sence of d H or&ital in the <alence shell All of these

$he acid which has garlic li+e smell and is crystalline deli,%escent is a) !#S7( &) !*B7* &) !Cl d) !N7*

(1.

$he acid which forms three series of salt is a) !#S7( c) !*F7( &) !*B7* d) !N7*

*1.

Nitrogen can not as a central metal atom in a comple. &eca%se it can not (6. a) "e<ote electrons c) 0orm an ion &) Accepts electrons d) All of these

3emo<al of arsenic o.ide is <ery essential &eca%se it acts as a a) Catalyst c) Catalytic poison &) Acti<ator d) Co8en;yme

*6.

Which o.ides of nitrogen e.ist in solid state? a) N#7 c) N7# &) N7 d) N#7().

$he str%ct%re of !#S7( is a) $rigonal c) $etrahedral &) 7ctahedral d) !e.agonal

*).

$he test which is %sed to confirm the presence of nitrate is (9. a) Sil<er minor test c) $ollenCs test &) 3ing test d) BaeyerCs test

Which pair does not prod%ce !# gas? a) C% and Con !N7*

20

&) C#!-7! and Na metal c) 2g and steam d) Fhenol and sodi%m metal -'. Why it is diffic%lt to form nitrogen compo%nds from gaseo%s nitrogen a) &) c) d) -1. All its reactions are endothermic $he &ond dissociation 5t contain triple &ond 5ts first ioni;ation energy is <ery high 11. 1'.

&) Bir+land8=ydeCs Frocess c) Sol<ayCs Frocess d) "ownCs Frocess 5n 7stwaldCs Frocess the s%&stance %sed to o.ide ammonia is AAAAAA a) n c) C7 &) Ft d) None of these

$he elements which is essential in nitrogen fi.ation is a) n c) 0e &) 2o d) S

Copper reacts with dil%te nitric acid to form a) Nitric o.ide c) Nitro%s 7.ide &) Nitrogen pero.ide d) None of these

-#.

Which one act as a free radical? a) C7# c) N7 &) C!( d) B0*

1#.

By AAAAAAA process the !#S7( prod%ced is p%re and can &e prod%ced of any desired strength. a) 4ead Cham&er Frocess &) Contact Frocess c) "ownCs Cell d) None of these

-*.

$he starting material in Bir+land and =yde process for man%fact%ring of !N7* is a) N!* c) Air &) N7# d) NaN7* 1*.

Concentrated s%lph%ric acid acts as a AAAAAA a) 3ed%cing agent c) "ehydrating agent &) 7.idi;ing agent d) None of these

-(.

5n ma+ing safety matches we %se a) &) c) d) White phosphor%s :ray phosphor%s Biolet phosphor%s 3ed phosphor%s 1(.

5n gro%p B5 A highest electronegati<ity is for a) S c) F& &) 7 d) Se

--.

Which is most sta&le isotope of s%lph%r? 1-. a) Flastic s%lph%r c) 3hom&ic s%lph%r &) 2onoclinic s%lph%r d) Colloidal s%lph%r 11. 3hom&ic s%lph%r consists of AAAAAAA a) S) chain c) S( rings &) S# chains d) S) rings

-1.

Consider heating N!(N7* gentle Frod%ct $he prod%ct formed is a) N#7 c) N7 &) N# d) N#7*

$he n%m&er of hydro.yl gro%p in phrophosphoric acid is a) * c) &) ( d) 6

-6.

$he prod%ct formed &y heating mi.t%re of N7 and N7# are a) N#7c) N#7 &) N#7( d) N#7*

16.

When li,%id s%lph%r at one atmospheric pressre is <ery slowly cooled> %nless s%per cooling occ%rs> the first solid to appear is AAAAAAA a) 2onoclinic s%lph%r c) !e.agonal s%lph%r &) 3hom&ic s%lph%r d) 2etallic s%lph%r

-).

Nitric o.ide is prepared &y the action of !N7* on a) 0e c) n &) C% d) Sn

1).

AAAAAAA is o&tained when ammoni%m dichromate is refrigerant? a) Nitrogen c) Ammonia &) 7.ygen d) None

-9.

7n ind%strial scale Nitric acid is prepared &y AAAAAAA a) "%tch Frocess

19.

Which compo%nd acts as an o.idi;ing as well as a red%cing agent?

21

a) S7# c) Al#7* 6'. in<ol<e S H S &ond? a) Fhyros%lphro%s acid &) "ichotomo%s acid c) "ichotic acid d) Fyros%lph%ric acid 61.

&) 2n7# d) Cr7* Which of the following acids does not

7le%m is formed &y com&ining !#S7( with a) S7# c) S &) S7* d) !#S 1. CHAPTER # & Halo'ens and (o)le ases Which is the most <olatile compo%nd? (A) !5 (C) !Br #. (B) !C5 (") !0

6#.

When S7# is passed thro%gh an acidified K2n7( sol%tion a) K2n7( is o.idi;ed &) K2n7( is red%ced c) S7# is red%ced d) K2n7( sol%tion t%rns green

Which one is the anhydride of !C57( ? (A) C5#7 (C) C5#71 (B) C57# (") C5#76

*.

Which of the following halogens does not form its o.yacids ? (A) 0l%orine (C) Bromine (B) Chlorine (") 5odine

(.

Bromine is o&tained on a commercial scale from (A) Caliche (C) Common salt (B) Carnallite (") Cryolite.

-.

5odine deficiency in diet is +nown to ca%se (A) Beri&eri (C) 3ic+ets (B) :oitre (") Night &lindness

1.

Which one of the halogen acid is a li,%id ? (A) !0 (B) !Br (B) !C5 (") !5.

6.

Which of the following acid is wea+est (A) !C57 (C) !C57* (B) !Br (") !C5.

).

5n which of the following> o.ygen has /# o.idation n%m&er ? (A) 0#7 (C) Na#7# (B) C5#7 (") Na#7.

9.

0l%orine does not show positi<e o.idation states d%e to the a&sence of

22

(A) d8or&itals (C) p8or&itals 1'.

(B) s8or&itals (") None

#'.

As the atomic n%m&er of halogens increases> the halogens (A) 4ose the o%termost electrons less readily (B) Become lighter in colo%r (C) Become less denser (") :ain electrons less readily.

Which of the following has greatest red%cing power? (A) !5 (C) !C5 (B) !Br (") !5.

11.

Bad cond%ctor of electricity is (A) !#0# (C) !Br (B) !C5 (") !5

1#.

Bleaching power is o&tained &y the action chlorine gas and (A) "il%te sol%tion of Ca(7!)# (B) Concentrated sol%tion of Ca(7!)# (C) "ry Ca7 (") "ry sla+ed lime.

#1.

Which statement is correct a&o%t halogens ? (A) $hey are all diatomic and form %ni<alent ions (B) $hey are all capa&le of e.hi&iting se<eral o.idation states (C) $hey are all diatomic and form di<alent ion (") $hey can m%t%ally displace each other from the sol%tion of their compo%nds with metals.

1*.

2ar+ the element which shows only one o.idation state in its compo%nds (A) 0 (C) Br (B) C5 (B) 5. ##.

Which has the highest molar heat of <apori;ation ? (A) !0 (C) !Br (B) !C5 (") !5.

1(.

Which of the following halogens has the highest &ond energy ? (A) 0# (C) Br# (B) C5# (") 5#. #*.

Which one of the following reacts with glass ? (A) !#S7( (C) !N7* (B) !0 (") K#Cr#76

1-.

Which halogen is most electropositi<e ? (A) 0 (C) Br (B) C5 (") 5. #(.

Strongest hydrogen &onding is shown &y (A) Water (B) Ammonia (C) !ydrogen fl%oride (") !ydrogen s%lphide.

11.

Which one of the following is the tr%e co<alent o.ide of iodine ? (A) 5#7( (B) 5#76 (B) 5#7(") 5#79 #-.

0l%orine is a &etter o.idi;ing agent than Br #. 5t is d%e to (A) Small si;e of fl%orine (B) 2ore electron rep%lsion in fl%orine (C) 2ore eletronegati<ity of fl%orine (") Non metallic nat%re of fl%orine.

16.

Which of the following halogen o.ides is ionic? (A) C57# (C) 5#7(B) Br7# (") 5(79 #1.

1).

Which of the following hydrogen halide has the highest &oiling point ? (A) !0 (C) !Br (B) !C5 (") !5.

$he element which li&erated 7# from water is (A) F (C) 0 (B) N (") 5.

#6. 19. Which of the following is a false statement ? (A) !ydrogens are strong o.idi;ing agents (B) !alogens show only H1 o.idation state (C) !0 molec%les form intermolec%lar hydrogen &onding (") 0l%orine is highly reacti<e.

7;onised o.ygen can &e o&tained from !#7 &y the action of (A) Conc. !#S7( (C) 2n7 (B) K2n7( (") 0#

#).

Which one of the following is most &asic ?

23

(A) 08 (C) Br8 #9.

(B) C58 (") 58

*9.

$he lowest &oiling point of heli%m is d%e to its (A) 5nertness (B) :aseo%s nat%re (C) !igh Folaris a&ility (") Wea+ Bander Waals forces &Jw atoms

Which one of the following elements can ha<e &oth positi<e and negati<e o.idation state? (A) 0 (C) 4i (B) 5 (") !e. ('.

*'.

4east chemical acti<ity is shown &y (A) N!* (C) Ar (B) C!( (") !#S7(.

Which mem&er of gro%p B55 A com&ines with one more halogen? a) Cl c) Br &) 0 d) 5

*1.

5n discharge t%&e> noon glows (A) Bl%ish (C) Fin+ish (B) 3eddish (") :reenish

(1.

$he interhalogen formed &y iodine re,%ires fl%orine atoms a) * c) 6 &) d) )

*#.

Vef# molec%le is (#. (A) 4inear (C) Fyramidal (B) $rigonal planar (") S,%are planar. Which one halogen directly reacts with no&le gas? a) 0 c) Br (*. (A) Bander Waals forces (B) 5on8dipole forces (C) 4ondon disperslon forces (") 2agnetic forces. &) Cl d) 5

**.

$he forces acting &etween no&le gas atoms are

Which type of interhalogenis formed &y Bromine? a) Br H Cl &) Br H 0&) Br H 0* d) Br H 5 6

*(.

Fercentage of Ar in air is a&o%t (A) 1S (C' *S (B) #S (") (S

((.

5odine occ%rs as iodate in a) Chile salt peter c) Bl%e <itriol &) Cla%&erCs salt d) 7il of <itriol

*-.

$he str%ct%re of Ve01 is (A) "istorted octahedral (B) Fyramidal (C) $etrahedral (") None of the a&o<e

(-.

Which one hydride has greater ionic character and had ! H &ond? a) !0 c) !Cl &) !Br d) !5

(1. *1. $he no&le gas was first time disco<ered &y (A) Ca<endish (C) 4oc+yer *6. (B) William 3amsay (") 0ran+land. t%&es for (6.

Chlorine reacts with hot sol%tion of Na7! to form a) NaCl c) NaCl7 &) NaCl7* d) All of these

$he colo%red discharge ad<ertisement mainly contain (A) Venon (B) Neon

0l%orine directly com&ines with no&le gases a) Kr c) 3n &) Ve d) All of these

(B) !eli%m (") A3:7N ().

*).

Which of the following no&le gases does not ha<e an octet of electrons in its o%termost shell ? (A) Neon (C) Argon (B) 3adon (") !eli%m

$he density of p%re li,%id !0 is less then water d%e to a) Co<alent &ond formations &) !igh electron affinity c) A&sence of three dimensional net wor+ of ! H &ond

24

d) Fresence of three dimensional net wor+ of ! H &ond (9. $he order of increasing dissociation of !V at 1'''oC is a) !5 (**S) K !Br ('.-S) K !Cl ('.'1(S) K !0 ('S) &) !Br K !5 K !0 K !Cl c) !Cl K !Br K !5 K !0 d) !0 K !Cl K !Br K !5 -'. $he halogen which form %nsta&le o.ides is a) 0 c) Br -1. $he most halogen is a) !7Cl c) !57 -#. recently &) Cl d) 5 prepared &) !Br7* d) !70 o.yacid of 1'.

a) =.cept 0#7> the o.ides of all halogen are endothermic compo%nds &) $he higher o.ides of halogen are more sta&le than lower o.ides c) $he &ond in the halogen o.ides are largely co<alent d%e to similarities in electronegati<ity d) All of these -9. 5odine is highly sol%&le in a) Sol%tion of Kl c) CS# &) Alcohol d) All of these

!0 is not preser<ed in glass &ottle &eca%se a) &) c) d) 5t reacts with Si7# of the glass 5t reacts with the Al#7* of the composition 5t reacts with the Na#7 of the composition 5t reacts with the <isi&le part of light

$he increasing order of acidity and o.idi;ing power of 7.yacids d%e to increasing n%m&er of o.ygen atoms is a) &) c) d) !V7 K !V7# K !V7* K !V7( !V7( K !V7* K !V7# K !V7 !V7* K !V7# K !V7( K !V7 None of these

11.

0l%orine can &e transported in a special container made %p of a) Al%min%m c) :lass &) Steel d) Car&on steel

1#. -*. $he a<erage a<aila&le chlorine in &leaching powder is a) *' H *-S c) (' H (-S -(. &) *- H ('S d) (- H -'S 1*. a) &) c) d) --. !ighly sol%&le in water 4ight yellow color powder 7.idi;ing agent 3elease Cl# gas &y reaction with dil%te acids 1(. a) 0 c) Br -1. &) Cl d) 5

Chlorine can &e easily li,%efied and is %s%ally mar+eted in a) &) c) d) Steel cylinders 5ron cylinders Car&on steel cylinders :lass cylinders

Which one is false for &leaching powder? !alogen do not occ%r free in nat%re &eca%se they a) &) c) d) Are salt prod%cer Are highly reacti<e !as se<en electrons in their <alence shell Are non metals

Sea weeds are important so%rces of Venon trio.ide is formed &y a) &) c) d) 1-. !ydrolysis of .enon he.afl%oride !ydrolysis of &ari%m per .enate !ydrolysis of .eondifloride None of these

$he acid %sed for etching glass is a) !Cl c) !N7* &) !0 d) !Cl7(

$he +nown fl%orides of .enon are a) Ve0# c) Ve01 &) Ve0( d) All of the a&o<e

-6.

Which one interhalogen can f%rther com&ine with fl%orine? a) 0 H Cl c) Br0&) Cl0* d) 5011.

2i.t%re of )'S heli%m and #'S o.ygen is %sed for a) Breathing air &y seas di<ers &) Breathing &y patient

-).

Which statement is tr%e?

25

c) Breathing &y fishes d) All of these 16. $yres of large aeroplane contain a) !e c) Ar 1). &) Ne d) Kr 69. 6).

a) NelsonCs cell c) "ownCs process

&) Contact process d) "eaconCs process

Chlorine gas is AAAAAA in color. a) Qellow c) Biolet &) :reenish Qellow d) Bl%e

Which .enon fl%oride is impossi&le? a) Ve0# c) Ve01 &) Ve0( d) Ve0*

$o +ill &acterial> moist of the drin+ing water is treated with AAAAAAA a) Nitrogen c) Chlorine &) Car&on dio.ide d) !ydrogen s%lphide

19.

$he type of hy&ridi;ation does the o.ygen has in 70# is a) SF# c) SF* &) d#SF* d) dSF*

)'.

Fhosgene is the common name of AAAAAAA a) Car&on dio.ide and phosphate &) Fhosphoryle chloride c) Car&onyle chloride d) Car&on tetrachloride

6'.

$he gas that will li,%efy with most diffic%lty is )1. !ydrofl%oride acid is AAAAAAAAA a) A powerf%l o.idi;ing agent &) A wea+ acid c) A strong acid d) A good red%cing agent )#. Bleaching powder is o&tained &y the interaction of Cl# and AAAAAAA a) Sla+ed lime &) Conc. Sol%tion of 2g(7!)# c) "ry Ca7 d) "ry sla+ed lime )*. a) !0 c) !Br &) !Cl d) !5 )(. $he element which li&erates 7# form water is a) F c) 0 &) N d) 5 a) !e &) C7# c) N!* d) S7# Which of the following is radioacti<e? a) Cl c) 5 &) Br d) At

61.

6#.

$he electron affinity of halogens is of the order a) 0 W Cl K Br K 5 c) Cl W 0 W Br W 5 &) 0 W Cl W Br W 5 d) 5 W Br W 0 W Cl

6*.

Which of the following hydride of halogen is thermally most sta&le?

6(.

5n which of the following &romine has an o.idation state of / (? a) Br#7 c) Br7* &) Br7# d) None

Which forms ma.im%m compo%nds with .enon? a) 0 c) Br &) Cl d) 5

6-.

=lectrolysis of Brine prod%ces AAAAAAA )-. a) Chlorine c) !#S &) 7.ygen d) Nitrogen Which of the following rare gases is not present in the atmosphere? a) !e c) Kr )1. a) !Cl7 c) !Cl7* &) !Cl7# d) !Cl7( )6. &) Ve d) 3n

61.

5n which of the following o.yacids> chlorine has an o.idation state of /*?

$he str%ct%re of Ve70( is a) $etrahedral c) "istorted &) S,%are pyramidal d) 5rreg%lar pentagonal

66.

$he process &ased on the o.idation of hydrochloric acid with o.ygen is AAAAAA

Which of the following fl%orides of .enon is not o&ser<ed?

26

a) Vef c) Ve0(

&) Ve0# d) Ve01

(A) Cast iron K wro%ght iron K steel (B) wro%ght iron K steel K cast iron (C) cast iron K steel K wro%ght iron (") cast iron @ steel K wro%ght iron ). $he colo%r of transition metal comple.es is d%e to. (A) d8d transitions of electrons (B) Fara magnetic nat%re of transition element (C) 5oni;ation (") 4oss of s8electrons

CHAPTER # *+ Transition Elements 1. Which of the following is a non8typical transition element ? (A) Cr (C) n #. (B) 2n (") 0e

9.

Coordination n%m&er of Ft in Xt C5 (N7#)(N!*)(Y8# is. (A) #8 (C) 1 (B) ( (") 1

1'.

$he total n%m&er of transition elements is. (A) 1' (C) (' (B) 1( (") -'

Which of the following is a typical transition metal ? (A) Sc (C) 3a (B) Q (") Co 11.

$ransition metals ha<e <ery high melting and &oiling points d%e to. (A) Wea+ &inding forces (B) Strong &inding forces (C) Both of the a&o<e (") None of the a&o<e

*.

f8&loc+ elements are so called. (A) Non8typical transition element (B) 7%ter transition elements (C) Normal transition elements (") 5nner transition

1#.

(.

$he strength of &inding energy of transition elements depends %pon (A) N%m&er of electron pairs (B) N%m&er of %npaired electrons (C) N%m&er of ne%trons (") N%m&er of protons 1*.

S%&stances which are wea+ly attracted &y which type of force are called as paramagnetic s%&stances. (A) Wea+ magnetic field (B) Strong magnetic field (C) 0ee&le magnetic field (") None of the a&o<e $he diamagnetic s%&stances are (A) Wea+ly repelled &y a strong magnetic field (B) Strongly repelled &y a wea+ magnetic field (C) Strongly repelled &y a wea+ magnetic field (") Wea+ly repelled &y a wea+ magnetic field.

-.

:ro%p B5B of transition elements contains (A) n> Cd > !g (C) Cr> 2o> W (B) 0e> 3%> 7s (") 2n> $e> 3e 1(.

1.

Which is the form%la of tetra8amine chloro nitro platin%m (5B) s%lphate ? (A) XFt(N!*)((N7#)YS7( (B) XFt N7#C5 (N!*)(YS7( (C) XFt C5 (N7#)(N!*)YS7( (") XFt (N!*)((N7#)C5YS7(

Faramagnetic &eha<io%r is ca%sed &y the presence of. (A) Gnparied electrons (B) Faired electrons (C) Faired protons (") Faired electrons in an aton> molec%le or ion

6.

$he percentage of car&on in different types of iron prod%cts is in the order of .

27

1-.

$he transition elements incl%des. (A) $i> 0e> Cr> Ni> C% etc (B) $i> 0e> N&> $a> $h> etc (C) 2o> W> r> N&> etc (") $i> 0e> Ci> Ni> C%> 2o> W> etc (A) 5norganic Nomenclat%re Committee (5GFAC) (B) 7rganic Nomenclat%re Committee (5GFAC) (C) Both of the a&o<e (") None of the a&o<e #*. 5n writing the form%la of a comple. ion the %s%al practice is to place the sym&ol of the (A) Central metal atom second (B) Central metal atom third (C) Central metal atom (rth (") Central metal atom 1st #(. Fig iron or cast iron contains (A) '.#-S to #.-S car&on (B) #.-S to (.-S car&on (C) '.1#S to '.#-S car&on (") None of the a&o<e Wro%ght iron is man%fact%red from (A) Fig iron (B) Cast iron (C) Fig iron or cast iron (") Steel #1. 5n open hearth process for the man%fact%ring of steel. (A) Gsing cast iron> wro%ght iron> or steel scrap (B) Gsing cast iron (C) I%st wro%ght iron (") None of the a&o<e #6. 5n gal<anic cell. (A) Al does not releases electrons and changes to al/* ion (B) Ai releases and changes to Al/* ion (C) Both of the a&o<e (") Both of the a&o<e #). $he amo%nt of iron destroyed each year &y corrosion e,%al to. (A) A&o%t 1J(th of its ann%al prod%ction (B) A&o%t 1J*rd of its ann%al prod%ction (CZ) Both 1J#nd of its ann%al prod%ction (") None of the a&o<e #9. Almost all the chromates are (A) Bl%e in colo%r (C) 3ed in colo%r *'. (B) :reen in colo%r (") Qellow in colo%r

r> N&> $a> $h>

11.

n has (A) ero %npaired electrons (B) 0i<e %npaired electrons (C) $hree %npaired electrons (") 7ne paired electrons

16.

5n transition elements the or&ital which is responsi&le for the colo%r de<elopment is. (A) s8or&ital (C) d8or&ital (B) f8or&ital (") o8or&ital

#-.

1).

5n X$i (!#71)Y*/ which wa<elength of light is a&sor&ed. (A) Qellow light is a&sor&ed while &l%e and red light are transmitted (B) :reen light is a&sor&ed (C) Both of the a&o<e (") None of the a&o<e

19.

Alloy steels are (A) 5ron atoms s%&stit%ted &y Cr> 2n> and Ni atoms (B) 5ron atoms s%&stit%ted &y Cr> and 2n atoms (C) 5ron atoms s%&stit%ted &y 2n and Ni atoms (") None of the a&o<e

#'.

S%ch compo%nds containing the comple. molec%les or comple. ions and capa&le of. (A) "ependent e.istence are called coordination compo%nds (B) 5ndependent e.istence are called coordination compo%nd (C) None of the a&o<e (") A L B

#1.

A comple. compo%nd may contain (A) Simple catoins and a comple.ions (B) A comple. cations and a simple anion (C) Both of the a&o<e (") None of the a&o<e

K#Cr#76(potassi%m dichromate) is %sed e.tensi<ely for. (A) "yeing (B) Chrome tanning (C) As an o.idi;ing agent (") All of the a&o<e are tr%e

##.

$he nomenclat%re of comple. compo%nds is &ased %pon the recommendation &y the

28

prod%ces AAAAA *1. $he location of transition elements is in &etweenAAAAAAAAA a. &. c. d. *#. 4anthanides L actinides s and p &loc+ elements chalcogens and halogens d and f &loc+ elements (1. a) Boltaic cell c) =lectrolytic cell &) :al<anic cell d) a L &

Which element has complete d H or&ital are a) Ni c) n &) 0e d) 2n

Compo%nds attracted &y applied magnetic field are calledAAAAAAAA a) "iamagnetic c) :ood cond%ctor &) Faramagnetic d) 0erromagnetic

(#.

5n Ag#/ the n%m&er of electrons in ( d or&ital is a) 6 c) 1 &) ) d) 9

**.

When light is e.posed to transition element> then electrons I%mps from lower or&itals to higher or&itals inAAAAAAAAAAA a) f8or&itals c) p8or&itals &) s8or&itals d) d8or&itals

(*.

A reg%lar decrease in ionic and atomic radii across the lanthanides is called a) &) c) d) Contraction 5.F 4anthanide Contraction Comple. formation

*(.

$he specie which donates electrons to central metal atom in co8ordination sphere is called AAAAAAAA a) Anion c) 4igand &) Cation d) Acid

((.

$he magnetic moment can &e meas%red &y a) :o%yCs &alance c) "ownCs &alance &) !a&erCs &alance d) All of these

(-. *-. 0ollowing ion is a &identate 4igand? a) Ammonia c) Car&onyl *1. &) 7.alate d) Cyanide (1.

$he magnetic moment is related to the n%m&er of %npaired electrons (n) &y the e,%ation a) n n + 2 c) n n 2 &) d)
n ( n + 2) n( n 2)

$he central atom along with 4igand is called AAAAAAAA a) Comple. ion c) 4igand &) Coordination sphere d) Comple. compo%nd

"iamagnetic compo%nds are those which ha<e a) Faired electrons c) 0ree electrons &) Gnpaired electrons d) No electrons

*6.

:eometry of comple. compo%nds depends %ponAAAAAAAAA a) no. of ligand &) no. of chelates c) hy&ridi;ation of central metal d) All of a&o<e

(6.

An e.treme case of Fara magnetism is called a) "iamagnetism c) 5somerism &) 0erro magnetism d) None of these

().

$he n%m&er of ligands attached to the central metal atom or ion> %s%ally <arying from a) # to * c) # to 1 &) # to ( d) # to 6

*).

0or sp*d# hy&ridi;ation> the geometry will &eAAAAAAAAA

e.pected (9.

a) $etrahydral &) S,%are planar c) $rigonal &ipyramidal d) 7ctahedral *9. Any process of chemical decay of metals d%e to action of s%rro%nding medi%m is called AAAAAAAAA a) S%rro%nding c) Corrosion ('. &) =namel d) Coating

Co8ordinate compo%nd with co8ordinate si. n%m&er ha<e geometry a) &) c) d) $etrahedral S,%are planner 2ay &e tetrahedral or s,%are planner 7ctahedral

-'.

Steel is an alloy of iron and is classified into a) 2ild steel ('.1 H '.#SC) and medi%m car&on steel ('.# to '.6SC)

When an acti<e metal li+e Al come in contact with less acti<e element li+e C%> then it

29

&) 2edi%m car&on steel ('.# to '.6SC) and high car&on steel ('.6 to 1.-SC) c) 2ild and high car&on steel d) 2ild medi%m and high car&on steel -1. 4igands are classified into a) 7ne c) $hree -#. ="$A is a) 2onodentate c) Folydentate -*. &) Bidentate d) None of these &) $wo d) 0i<e

c) 5ntermediate 11.

d) None of these

0inely di<ided iron is %sed in AAAAAAA a) !a&er process &) Catalytic !ydrogenation c) 7.idation of ammonia to nitric o.ide d) Contact process

1#.

AAAAAAAA reagent can &e %sed to identify C%#/ ion. a) Nitric acid &) S%lph%ric acid c) Sodi%m hydro.ide d) Fotassi%m dichromate

Which one is Bidentate ligand a) Cl81 c) N!#(C!#)> N!# &) N!* d) ="$A

1*.

AAAAAAA is the important ore of copper. a) 2alachite c) Bl%e Bitriol &) Ba%.ite d) Al%mina

-(.

Comple.es which are less common ha<e co8 ordination n%m&er a) ( c) 1 &) d) All of these

1(.

$itani%m is %sed as catalyst in AAAAAAA a) !a&er process &) Catalytic hydrogenation c) 7.idation of ammonia to nitric acid d) Folymeri;ation of ethyle into polyethylene

--.

Comple.es which ha<e octahedral geometry hy&ridi;ed 1-. a) SF* c) dSF* &) dSF# d) d#SF*

An adding K5 to a sol%tion of C%S7( a) C%pric o.ide is precipitated &) 2etallic copper is precipitated c) C%pro%s iodide is precipitated with the li&eration of iodine d) No change ta+es place

-1.

$he geometry of a comple. depends %pon a) &) c) d) Co8ordination n%m&er $ype of hy&ridi;ation of central metal atom Chelates Both a L &

11.

5n Cr#76# e<ery Cr atom is lin+ed to a) $wo 7 atoms c) 0o%r 7 atoms &) $hree 7 atoms d) 0i<e 7 atoms

-6.

Brass contain #'S ;inc and a) )'S C% c) 1'S C% &) 6'S C% d) -'S C% 16.

A s%&stance which ha<e e<en n%m&er of electrons and ha<e paired spin is called AAAAAA a) 0erromagnetic c) "imagnetic &) Faramagnetic d) None of these

-).

Bell metal contains a) &) c) d) )'S C% / #'S n )'S C% / #'S Sn #'S C% / )'S n #'S C% / )'S Sn

1).

$he empty spaces &etween atoms of transition metals in their crystal lattices are called AAAAA a) Bacant spaces c) 5nterstices &) Balence spaces d) None of these

-9.

$he form%la of &l%e <itriol is a) C%S7( c) C%S7(.(!#7 &) C%S7(.*!#7 d) C%S7(.-!#7 19.

XNi(CN)(Y#8 is an e.ample of AAAAAAAA a) S,%are planar &) $etrahedral comple.es c) 7ctahedral comple.es d) None of these

1'.

$he transition elements %s%ally ha<e <ery AAAAAA melting and &oiling points. a) 4ow &) !igh

30

6'.

XC%(N!*)(Y#/ is an e.ample of AAAAAAA a) S,%are planar &) $etrahedral comple.es c) 7ctahedral comple.es d) None of these 69.

c) N!* is a stronger &ase than !#7 d) "ipole moment of water is higher than N!* Which of the following is deli,%escent? a) nCl# c) !dCl# )'. &) !g#Cl# d) !gCl#

61.

XCo(N!*)1Y*/ is an e.ample of AAAAAAA a) S,%are planar &) $etrahedral comple.es c) 7ctahedral comple.es d) None of these

Cr7* dissol<es in a,%eo%s Na7! to gi<e

&) Cr(7!)# d) Cr(7!)*

c) Cr2 O )1.

2 7

5ron o&tained from the &last f%rnace is called a) Fig iron c) Wro%ght iron &) Cast iron d) Steel

6#.

$he names of AAAAAA are %s%ally %nchanged. a) Anionic ligands c) Ne%tral ligands &) Cationic ligands d) None of these

6*.

$he s%ffi. DateE at the end of the name of the coordinate comple. ion represents aJan AAAAAA a) Cation c) Cathode &) Anion &) Anode 1.

CHAPTER # , -!ndamental Princi"les of .r'anic C/emistry $he state of hy&ridi;ation of car&on atom in methane is (A) Sp* (C) Sp #. (B) Sp# (") dsF#

6(.

0erric o.ide is AAAAAAA a) A &asic anhydride &) An acid anhydride c) An amphoteric anhydride d) :reen in colo%r

5n t8&%tyl alcohol> the tertiary car&on is &onded to (A) $wo hydrogen atoms (B) $hree hydrogen atoms (C) 7ne hydrogen atoms (") No hydrogen atoms

6-.

$he most strongly ferromagnetic element is AAAAAAA a) 0e c) Ni &) Co d) 7s *.

61.

$he property of a s%&stance which permits it &eing drawn into wire is called AAAAAAAA a) Softness c) Brittleness &) "%ctility d) !ardness (.

Which set of hy&rid or&itals has planar triang%lar shape (A) Sp* (C) Sp# (B) Sp (") dsp#

66.

When potassi%m permanganate is added to a sat%rated a,%eo%s sol%tion of potassi%m hydro.ide> AAAAAAA gas is e<ol<ed. a) !ydrogen c) Car&on dio.ide &) 7.ygen d) None of these -.

$he chemist who synthesi;ed %rea from ammoni%m cyanate was (A) Ber;eli%s (C) Wholer (B) Kol&e (") 4a<oisier

4inear shape is associated with which set of hy&rid or&itals ? (A) Sp (C) Sp* (B) Sp# (") dsp#

6).

AgCl dissol<es in % sol%tion of N!* &%t not in water &eca%seT a) N!* is a &etter sol<ent than !#7 &) Ag/ forms a comple. ion with N!* 1.

A do%&le &ond consists of.

31

(A) $wo sigma &ond (B) 7ne sigma and one pi &ond (C) 7ne sigma and two pi &ond (") $wo pi8&ond 6. =thers show the phenomenon of (A) Fosition isomerism (B) 0%nctional gro%p isomerism (C) 2etamerism (") Cis8trans isomerism. ). Select from the following the one which is alcohol. (A) C!* 88888888C!#888888887! (B) C!*888888888788888888888C!* (C) C!*C77! (") C!*88888888C!#88888888Br

1(.

At what temperat%re coal is heated in the o&ser<e of air for con<erting it into co+e> coal gas> and coal tar (A) $emperat%re ranging from -''81'''oC (B) $emperat%re ranging from 1''81'''oC (C) $emperat%re ranging from *''8#'''oC (") $emperat%re ranging from 1'''8*'''oC

1-.

Crac+ing of petrole%m is ta+en place &y A) $hermal crac+ing C) Steam crac+ing B) Catalytic crac+ing ") All of the a&o<e

11.

$he str%ct%re of al+ynes can &e e.plained &y yet another mode of hy&ridi;ation called as (A) Sp# hy&ridi;ation (B) Sp* hy&ridi;ation (C) Sp- hy&ridi;ation (") Sp hy&ridi;ation

9.

=arly chemists recogni;ed organic compo%nds distinct from inorganic compo%nds &eca%se of 16. (A) $he difference in their origin and properties (B) $he similarities in their origin &%t difference in their propertied (C) Both of the a&o<e (") None of the a&o<e 1). 2etamerism aries d%e to the. (A) =,%al distri&%tion of car&on atoms (B) Gne,%al distri&%tion of car&on atoms (C) Both of the a&o<e are tr%e (") None of the a&o<e are tr%e Cis8trans isomerism is also called as (A) :eometric 5somerism (B) Fosition 5somerism (C) Chain 5somerism (") 2etamerism 19. Coal> petrole%m and nat%ral gas are important so%rces of. (A) 7rganic compo%nds (B) 5norganic compo%nds (C) Both of the a&o<e (") None of the a&o<e #'. (A) 2i.t%re of hydrocar&ons (B) 2ethane (C) Both of the a&o<e (") Nonn of the a&o<e 7rganic compo%nds are classified into (A) Acyclic and cyclic compo%nd (B) Acyclic L !eterocyclic (C) Non8cyclic (") All of the a&o<e #1. (A) 0or power generation only (B) 5n coment and fertili;er ind%stries only (C) As a f%el in general ind%stries and for domestic p%rposes (") All of the a&o<e are tr%ce 3ate of reactions of most organic compo%nds areAAAAAAAAAAA a) Bery slow &) Bery fast c) 2edi%m

1'.

$he <ital force theory was reIected &y A) Nhon "alton C) "mitri 2endelee< B) 0riedric+ Wohler ") None of the a&o<e

11.

We ha<e &ecome dependent for o%r food medicines and clothing to which compo%nds. (A) 5norganic compo%nds (B) 7rganic compo%nds (C) Both of the a&o<e (") None of the a&o<e

1#.

Nat%ral :as is a

1*.

5n Fa+istan the nat%ral gas is %sed for.

32

d) No reg%lar character present *#. ##. Coal is prod%ced after a long time decay of AAAAAAAAAA a) Animals c) Wood #*. &) 0ossils d) 7res **. =ther f%nctional gro%p can &e represented asAAAAAAAAAAAA a) H7! c) 38783 #(. &) 38C783 d) 38C77! *(. Which one is the mi.t%re of #1- organic compo%nds? a) Water gas c) Coal tar &) Coal gas d) Cr%de coal gas

7ctane n%m&er is the percentage of a) &) c) d) n8pentane in a mi.t%re n8&%tane in a mi.t%re n8he.ane in a mi.t%re #> #> ( H trimethyl pentane in a mi.t%re

#8propanol can show isomerism as AAAAAAA a) 2etamerism &) 0%nctional gro%p isomerism c) :eometric isomerism d) None of a&o<e

"%ring the fractional distillation of petrole%m> paraffin oil &oils &etween the ranges a) #-oC c) 16- H #6-oC &) (' H 1)'oC d) ##' H *-'oC

*-. #-. $he hydrocar&ons which gi<e smo+e on &%rning is calledAAAAAAAA a) Aliphatic c) Car&o.ylic acid &) Aromatic d) Aldehydes *1.

$he octane n%m&er of gasoline may increased &y adding a) ="$A c) AgN7* &) Na7! d) FB(C#!-)(

Which process increases the yield of gasoline from petrole%m? a) Crac+ing &) Folymeri;ation c) 3eforming d) S%&limation Consider the reaction tube *C#!# Cu C1!1 $his is the e.ample of a) Fyrolysis c) S%&limation &) Folymeri;ation d) Addition

#1.

5n sp* hy&ridi;ation> the molec%les will &eAAAAAAAAA a) S,%are planar c) $etrahedral

geometry

of

*6.

&) $rigonal pyramidal d) All are possi&le

#6.

7nly sigma &onds are present in AAAAAAA a) Fropene c) B%tanal &) B%tanoic acid d) =tho.y &%tane *).

Which one is acyclic hydrocar&on? a) C1!1 c) C1!1# &) C#!1 d) C!(

#).

5n al+yne> the hy&ridi;ation isAAAAAAAAAAAA a) sp# c) sp &) sp d) All *9.

Which type of isomerism is shown &y the following compo%nds? C!* H C!# H C!7> C!* H C7 H C!* a) &) c) d) Chain isomerism Fosition isomerism 2etamerism 0%nctional gro%p isomerism

#9.

7ctane no. of any f%el can &e impro<ed &y AAAAAA a) Fyrolysis c) Folymeri;ation &) 3eforming d) Condensation ('.

*'.

$he f%el ha<ing ('S n8heptane L 1'S iso8 octane will ha<e octane n%m&er a) (' c) )' &) 1' d) 9' is heterocyclic &) Cresol d) Fyridine organic

$he type of isomerism fo%nd in 1 H &%tene and # H &%tane is a) Fosition c) 0%nctional gro%p &) Chain d) 2etamerism

*1.

Which of them compo%nd? a) Ben;ene c) Naphthalene

(1.

$he mem&ers of which of these ha<e similar methods of preparation and properties a) 5somers c) Folymers &) !omolog%es d) 2onomers

33

(#.

$he ma.im%m n%m&er of isomers for an al+ene with molec%lar form%la C(!) is a) # c) ( &) * d) -*.

a) "imethyl ether c) =thylene glycol

&) "iethyl ether d) 2ethanol

When ethylene is heated %nder press%re> a transparent solid polymer> AAAAAAAA is o&tained. a) Folyethene c) 2ethane &) =thane d) None of these

(*.

Which of the following is most sta&le ion? a) C!* H !#C/ c) (C!*)* C/ &) (C!*)# !C/ d) All of these -(.

((.

Which of the following is not an organic compo%nd? a) Grea c) Nat%ral gas &) 7.alic acid d) Flaster of Faris --.

$he ,%ality of petrole%m is determined &y AAAAAAA a) "ecane n%m&er c) !e.ane n%m&er &) 7ctane n%m&er d) None of these

(-.

Kerosine oil is a mi.t%re of a) Al+ane c) Al+ynes &) Al+ene d) All of these

$wo or more than two different compo%nds ha<ing the same molec%lar form%la &%t different car&on chains or s+eletons are said to &e AAAAAA a) Chain isomers &) Fosition isomers c) 0%nctional gro%p isomers d) 2etamers

(1.

Which of the following compo%nds does not contain an 7! gro%p? a) Alcohol c) Aldehyde &) Fhenol d) Car&o.ylic acid

(6.

$he chemical form%la of chloride is -1. a) C!*7! c) CCl*C!7 &) CCl*7! d) None of these $he +ind of isomerism which depends %pon the relati<e position of the f%nctional gro%p> or the position of do%&le or tripe &ond in case of %nsat%rated compo%nds is termed as AAAAAAAA a) Chain isomerism &) Fosition isomerism c) 0%nctional gro%p isomerism d) 2etamerism -6. 5somerism> which in<ol<es compo%nds ha<ing the same molec%lar form%la> &%t different f%nctional gro%ps are called AAAAAAA a) Chain isomerism &) Fosition isomerism c) 0%nctional gro%p isomerism d) 2etamerism -). AAAAAAA is e.hi&ited &y compo%nds ha<ing the same f%nctional gro%p &%t different al+yl attached to the same m%lti<alent atom. a) Chain isomerism &) Fosition isomerism c) 0%nctional gro%p isomerism d) 2etamerism -9. 5n crac+ing %s%ally catalyst %sed is AAAAAAA

().

Fetrole%m in the %nrefined form is called AAAA a) 3oc+ oil c) Cr%de oil &) Coal gas d) Both a L c

(9.

Nat%ral gas mainly consists of AAAAAAAA a) 2ethane c) Fropane &) =thane d) B%tane

-'.

AAAAAAA is a mi.t%re of methane> ethane> propane and &%tane> %sed as a f%el and for ma+ing other organic chemicals. a) 3efinery gas c) Kerosene oil &) :asoline d) :as oil

-1.

A large n%m&er of organic compo%nds> especially the %nsat%rated ones> show a great tendency to %nit. $his process is termed as AAAAAA a) Fyrolysis c) Folymeri;ation &) Crac+ing d) None of these

-#.

An isomer of ethanol is AAAAAAAA

34

a) Ft c) Ni 1'.

&) Al%%minosilicate d) $etra ethyl lead

6'.

$he isomers m%st ha<e the same AAAAAA a) Str%ct%ral form%la c) Chemical form%la &) 2olec%lar form%la d) Fhysical properties

5n CCl( molec%le the fo%r <alencies of car&on atom are directing towards the corners of a AAAAAAA a) C%&e c) Frism &) !e.agon d) $etrahedron

11.

$he general form%la (3C7)#7 represents AAAAAAAA a) An ether c) An ester &) Ketone d) An acid hydride

1#.

AAAAAA has the longest &ond length. a) C @ C c) C H C &) C [ C d) All of these

1*.

Compo%nds in which two al+yl gro%ps are attached to an o.ygen atom are called AAAAAA a) Al+anes c) Alcohols &) =thers d) 5somer

1(.

AAAAAAAA is the common name of methanol. a) 0ormaldehyde c) Fropionaldehyde &) Acetaldehyde d) None of these

1-.

AAAAAA is the common name of propanone. a) Acetone c) "iethyl +etone &) Ketone d) None to these 1. C/a"ter # 0 Ali"/atic Hydrocar)ons Balencies AAAAAAAAAAAAA a. &. c. d. #. a) 2ethyl alcohol and dimethyl ether &) =thyl alchohol and dimethyl ether c) Acetone and Acetaldehyde d) Froponoic acid and propanone in al+anes are

11.

$he properties of organic compo%nds are d%e to AAAAAAA a) Co<alent &onds c) 5onic &onds &) 0%nctional gro%ps d) None of these

Completely satisfied Fartially satisfied No satisfied No general r%les

16.

AAAAAA of the following are isomers. Al+anes containing one &ranch on main chain are calledAAAAAAAAA a) 5so c) Neo *. &) Normal d) Branched

1).

Which compo%nd contains an sp hy&ridi;ed C atom? a) C!*CN c) C!*N!# &) C!*C!7 d) None

When one hydrogen atom of al+ane is replacedJremo<ed> then it is called AAAAAAAAA a. &. c. d. Al+ene Al+yl Aldehyde Sat%rated hydrocar&on Al+anes are also +nown as AAAAAAA a. Sat%rated hydrocar&on

19.

Which of the following isomeric s%&stances wo%ld &e e.pected to ha<e the lowest &oiling point? (. a) !e.ane &) # H methlypentane c) #> # H dimethyl&%tane d) * H methlypentane

35

&. Gnsat%rated hydrocar&on c. Faraffins d. a L c -. Sa&atierCs SendrenCs reaction in<ol<es AAAAAAAAAin presence of Ni a) al+ene L !# c) al+ene L N# 1. &) al+ene L 7# d) al+ene L Cl#

1(.

5ntrod%ction calledAAAAAA a) Nitration c) S%lphonation

of

nitro

gro%p

is

&) !alogenation d) None

1-.

7rder of halogenation isAAAAAAAAAAA a) 5KClKBrK0 c) 0KClKBrK5 &) 0KClK5KBr d) ClK0KBrK5

n is a goodAAAAAAAAAAA a) 2etal c) Non8metal &) 7.idi;ing agent d) 3ed%cing agent 11.

:as is %sed in fertili;er AAAAAAAAAAAA a) C#!1 c) C#!# &) C#!( d) C!( form%la of al+enes is

6.

3emo<al of 8C77! is calledAAAAAA a) Car&o.ylation c) =sterification &) "ecar&o.ylation d) !ydro.ylation is a mi.t%re 1). 16.

:eneral AAAAAAA a) Cn!#n/# c) Cn!#n

).

Soda lime ofAAAAAAAAAAAAA a. &. c. d. Ca7 and K7! Ca7 and Na7! Na7! and Na7 Nao and K7!

&) Cn!#n8# d) Cn!#n8.

$he order of dehydration of alcohol isAAAA a. &. c. d. secKpriKter priKsecKter terKsecKpri no specificity occ%rs

9.

2alo;onide intoAAAAAAAAAAA a) =po.ide c) 7;onide &) C7# / !#7 d) C7/!#7

changes 19.

3emo<al of halogen and hydrogen atom isAAA a. &. c. d. !alogenation "ehalogenation "ehydrohalogenation Car&onations

1'.

3C77Na/!#7 X=lectrolysisY is +nown as AAAAA a) Bosch reaction &) Kol& reaction c) Sa&atierCs reacti%on d) 0ran+land reaction #'. Al+enes are prod%ced "ehalogenation ofAAAAAAA a) di8halides al+ane c) <ic. "i8halide #1. from

11. a. &. c. d. 1#.

382g8Br is calledAAAAAAAAA :rignard reagent W%rt; reaction $ollenCs reagent Finacol pinacolo%r reagent &) tri8halides al+ane d) <ic. $rihalides

3eacti<ity d%e to pi8 electrons is present in AAAAAAAAAAAA a) Al+ane c) Al+yne &) Al+ene d) & and c

Gpto AAAAA C atoms> al+anes are gases a) # c) ( &) * d) 1 ##.

\8 electrons fa<o%rAAAAAAAAAAAA a. &. c. d. 4ess reacti<ity Addition reactions S%&stit%tion reactions None 3aney nic+el isAAAAAAAAAAAA

1*.

Al+anes are less reacti<e than al+enes d%e toAAAAAAAAAA a. &. c. d. Fresence of sigma &ond A&sence of pi &onds Fresence of sigma and pi &onds No I%stification a<aila&le

#*.

36

a. &. c. d. #(.

An alloy of Ni8C% Alloy of Ni80e Alloy of Ni8Al Alloy of Ni82g

**.

BaeyerCs test is %se to detect the &ond in an organic compo%nd a) Single &ond c) $riple &ond &) "o%&le &ond d) All of these

Which mem&er of 5B A has little tendency to form anions or cations? a) F& c) :e &) Sn d) C

*(.

=thylene reacts with BaeyerCs reagent to form a) C7# and !#7 c) =thylene o.ide &) =thyl alcohol d) =thylene glycol

#-.

Al+anes d%e to little chemical reacti<ity are also called a) 7lefins c) :rignardCs reagent &) Faraffins d) None of these

*-.

When ethylene reacts with chlorine to form an oily prod%ct. $his oily prod%ct is called a) BaeyerCs test c) "%tch H li,%id &) Bromine water d) :lycol

#1.

2ethane and other mem&ers of paraffins do not react with a,%eo%s sol%tion of acids> al+alies> K2n7( or other o.idi;ing agents this lac+ of reacti<ity is d%e to its nat%re a) Folar c) Acidic &) Nonpolar d) Basic

*1.

Which of them is %sed as general anesthetic? a) =thane c) =thyne &) =thene d) =ther

*6.

$he positi<e part of the adding molec%le will go to that car&on which has greater n%m&er of hydrogen atoms. $his statement is called a) &) c) d) !offmannCs 3%le BaeyerCs Strain theory $hieleCs theory 2ar+owni+offCs r%le

#6.

Which hy&rid or&ital will form the compo%nd C!* H C! @ C! H C!# H C!* a) SF# and SF c) SF &) SF# and SF* d) SF* *).

#).

Which of the following types of reactions occ%r when a reactant has a do%&le &ond? a) S%&stit%tion c) Fhotolysis &) Addition d) Folymeri;ation

Bromo =thane on treatment with alcoholic K7! yields a) Fropane c) =thylene &) =thene d) Acetylene

#9.

Among the following or&ital &onds> the angle is minim%m &etween a) SF* &ond c) ! H 7 H ! in water &) F. and Fy or&itals d) SF &ond

*9.

2etallic car&ide on treatment with water gi<es o%t a colo%rless gas which &%rns readily in air and gi<es a red precipitate with C%#Cl# / N!(7!. $he gas is a) C!( c) C#!( &) C#!1 d) C#!#

*'.

$he compo%nd with highest &oiling point is ('. a) &) c) d) n H he.ane n H pentane # H methyl &%tane #> # H dimethyl propane (1. When acetylene reacts with 1'S ! #S7( in the presence of !gS7( yields a) C!*7! c) C!*C!7 &) C!*C77! d) C!*7C!*

*1.

Alcoholic K7! sol%tion is %sed for a) &) c) d) "ehydrogenation "ehalogenation "ehydrohalogenation "ehydration

"ehydration of =thanol gi<es a) C#!( c) C#!1 &) C#!# d) C#!(7

(#.

Which of the following has acti<e hydrogen? a) C#!# c) C#!1 &) C#!( d) C!(

*#.

Which is least sol%&le in water? a) Fhenol c) Ben;oic acid &) Ben;ene d) =thanol (*.

$reatment of propene with cold concentrated !#S7( followed &y &oiling water forms

37

a) Fropyne c) Fropanal ((.

&) Fropanol d) # H Fropanol

-*.

=thene on interaction with hypochloro%s acid gi<es a) &) c) d) "ichloro acetaldehyde "ichlorohydrin =thylene chlorohydrin =thylene "ichlorohydrin

2ar+owni+offCs r%le pro<ides g%idance for addition of !Br in a) &) c) d) C!# @ C! H C!* C!# @ C!# C!* H C! @ C! H C!* None of these

-(.

$he compo%nds ha<ing Fi &onds are in general a) 2ore reacti<e c) Ne%tral &) 4ess reacti<e d) Both a L &

(-.

$he compo%nd ha<ing &oth SF and SF* hy&ridi;ed car&on atom is a) Fropene c) Fropyne &) Fropane d) All of these --.

Which one will not decolo%ri;e &romine water? a) =thene c) Fropene &) =thyne d) B%tane

(1.

FBC is a polymer of a) C!# @ C!# c) C!# @ C! Cl &) C#!1 d) C#!# -1.

Acetylene adds on to !CN to gi<e a) &) c) d) Acetylene cyanide Cyanoacetylene Binyl ethane Acrylonitrile

(6.

$he str%ct%ral form%la of the compo%nd which yields ethylene %pon reaction with inc is a) C!#Br H C!#Br c) C#!# &) C#!*Br d) C#!-7! -6.

Action of !7Cl with ethene to gi<e ethylene chlorohydrin is an e.ample of a) &) c) d) "isplacement reaction S%&stit%tion reaction Addition reaction Folymeri;ation reaction

().

$he maIor reactions occ%r in al+anes are a) &) c) d) =lectrophilic addition reaction N%cleophilic s%&stit%tion reaction 0ree radical s%&stit%tion reaction 0ree radical addition reaction -).

(9.

Consider a reaction C!* H C! @ C!# / ! H V M prod%ct $he reaction occ%rs &y o&eying a) &) c) d) W%rt;Cs r%le 0ran+landCs r%le 2ar+owni+offCs r%le Ke+%leCs r%le

Chloroform is stored in dar+ colo%red &ottles &eca%se in light it is a) &) c) d) 3ed%ced to CCl( 7.idi;ed to CCl( 3ed%ced to phosgene 7.idi;ed to a poisono%s phosgene

-'.

Acetylene is %sed as a starting material for the preparation of Flastics> Synthetic r%&&er and Synthetic fi&re called a) 7rlon c) Corlon &) Narlon d) 0orlon

-9.

0ormation of al+ane &y the action of ;inc on al+yl halide is called AAAAAAAA a) 0ran+land reaction &) W%rt; reaction c) Canni;;aroCs reaction d) Ko&eCs reaction

-1.

$he high polymer of chloroprene is a) Folythene c) Neoprene &) Ben;ene d) Binyl acetylene 1'.

$he al+ynes ha<e AAAAAAA a) $etrahedral frame wor+ &) Flanar molec%les c) 4inear str%ct%re d) None of these

-#.

Which one of the following gi<es =thyne on electrolysis? a) Sodi%m Acetate c) Sodi%m 0ormate &) Sodi%m S%ccinate d) Sodi%m 0%merate 11.

$he al+enes ha<e AAAAAAA

38

a) $etrahedral frame wor+ &) Flanar molec%le c) 4inear str%ct%re d) None of these 1#. Al+enes %ndergo AAAAAAA a) Addition reaction &) S%&stit%tion reaction c) Both addition L s%&stit%tion reaction d) None of these 1*. AAAAAAA does not react with a,%eo%s sol%tion of acids> al+alies> or potassi%m permanganate or other o.idi;ing agents and most of the %s%al la&oratory reagents. a) Ben;ene c) 2ethane 1(. &) =ther d) Acetic acid

1).

When a mi.t%re of ethane and air is passed o<er heated sil<er %nder press%re> we get AAAAA a) =po.ide c) S%&o.ide &) S%per o.ide d) None

19.

$he process %sed for the preparation of acetylene is AAAAAAA a) Berthelot Frocess &) Sa&atier H Senderns 3eaction c) Kol&eCs Frocess d) !a&erCs process

6'.

A simple chemical test to disting%ish 1> *8 &%tadiene and 18 &%tyne is a) Br#]CCl( c) K2n7( &) Ag(N!*)#7! d) None

$he 5GFAC name for the following compo%nd is C!* C!#C!#C!* ] ] C!* H C! H C! H C! H C! @ C!# ] C!* a) (> - H dimethyl H * H propyl H # H he.ene &) (> - H dimethyl H * H propyl H 1 H he.ene c) *H propyl H * H dimethylpropyl H 1 H he.ane d) #> * H dimethyl H ( H propyl H - H he.ane 2ar+o<ni+o< addition of KCl to propene in<ol<es> a) 5nitial attac+ &y a chloride ion &) 5someri;ation of 1 H chloropropane c) 0ormation of n H propyl cation d) 0ormation of isopropyl cation

1-.

11.

When an a,%eo%s sol%tion of sodi%m or potassi%m salt of mono car&o.ylic acid is s%&Iected to electrolytic> corresponding al+ane is formed. $his reaction is called AAAAAAAA 1. a) Sa&atier Senderens 3eaction &) Kol&eCs =lectrolysis c) Folymeri;ation d) Chlroination #.

C/a"ter # 1 Aromatic Hydrocar)ons $he molec%lar form%la of tol%ene isAAAAAAA a) C6!6 c) C)!) &) C6!) d) C)!6

16.

$he elimination of hydrogen halide (!V) from adIacent car&on atoms is called AAAAAAAA a) Fyrolysis c) "ehydrohalogenation &) Chlorination d) None

5n &en;ene s%lphonic acid> the s%lphonic gro%p is attached with &en;ene ring thro%ghAAAAA a) !ydrogen c) S%lpher &) 7.ygen d) H7!

39

*.

Fhenanthrene AAAAAAAA &en;ene rings a) $wo c) 0o%r &) $hree d) 0i<e 1#.

c. $he a&sence of 7.ygen d. $he presence of e.cessi<e 7.ygen !ow many moles of !# are added %p when &en;ene is heated with hydrogen in the presence of platin%m? a) $wo c) 0o%r 1*. &) $hree d) Si.

(.

Aniline is a deri<ati<e of &en;ene which containsAAAAAA a) !ydro.yl gro%p c) Amido gro%p &) Amino gro%p d) 5mido gro%p

-.

!ow many \ electrons are there in &en;ene? a) * c) 1 &) ( d) ) 1(.

5n &en;ene the C8C &ond length is larger than the C8! &ond length &y a n%merical <al%e ofAAAAAAAAAAAA a) '.*'6Ao c) '.**6Ao &) '.*'6 nm d) '.*'6 nm

1.

$he molec%lar form%la of &iphenyl methane isAAAAAAAAAAAA a) C1#!1' c) C1*!1' &) C1#!1# d) C1*!1#

$he heat of hydrogenation of cyclohe.ene is AAAAAAAAAAAAA a. &. c. d. 8#19.- KNJ mole #19.- caloriesJ mole 8119 KNJ mole 8119 CalJ mole

6.

When two or more different s%&stit%ents are attached with a &en;ene ring> the n%m&er 1 position in the ring is gi<en to a high priority gro%p. Which one of the following gro%ps has highest priority? a) HN!# c) HC77! &) HC!7 d) HCN

1-.

$he resonance energy of &en;ene isAAAAAA a. &. c. d. 1-'.- KNJ mole #-'.- KNJ mole 1-'.- KNJ mole #-'.- KNJ mole

).

When &en;ene is s%&stit%ted &y halogens only> which one of the following halogens is gi<en the n%m&er one position in the ring while writing the name of compo%nd? a) Bromine c) 0lo%rine &) Chlorine d) 5odine

11.

$he resonance &etween different str%ct%res is represented &yAAAAAA a. &. c. d.

9.

Which one of the following is not a meta directing gro%p? a) HCN c) HC77! &) H7! d) HC!7 16.

What catalyst is employed when &en;ene is prepared from acetylene at 6'UC? a. n amalgam &. AlCl* c. 7rgano8nic+el d. 3ancy 3ic+el

1'.

Which pair of gro%ps contains &oth ortho L para directors? a. &. c. d. H7!> H3C7 HN3*> HCN H7C!*> HC!7 HN (C!*)#> HN!#

1).

2i.t%re of catalysts Cr#7* / Al#7* / Si7# at -''UC are %sed when &en;ene is prepared fromAAAAAAAAAAAA a. &. c. d. Cycloal+ene n8he.ane Ben;ene s%lphonic acid Sodi%m &en;oate

11.

2ichael 0araday disco<ered &en;ene in the gas which was prod%ced &y destr%cti<e distillation of <egeta&le oil done inAAAAAAAAA a. $he presence of 7.ygen &. $he presence of !ydrogen

19.

Which one of the following methods will not gi<e &en;ene?

40

a. !eating so. Salt of Ben;oic acid with soda lime &. "istillation phenol with n d%st c. Chloro&en;ene with Na7! at *1' UC L *''atm. d. !ydrolysis of &en;ene s%lphonic acid with s%per heated steam. #'. What is the ratio of conc. !N7* L conc. !#S7( when nitration of &en;ene is done at -'UC? a) 1?1 c) 1?# #1. &) #?1 d) #?*

c) N7#8 #6.

d) N7#/

Nitroni%m ion isAAAAAAAAAAAAA a) N7* c) N7#8 &) N7 d) N7#/

#).

Which compo%nd will readily %ndergo s%lphonation? a) Ben;ene c) :ol<ene &) Nitro &en;ene d) Chloro&en;ene

#9.

Ben;ene is heated in air with B#7- at (-'UC it %ndergo AAAAAAAAAAA a. &. c. d. S%&stit%tion reaction Addition reaction =limination reaction 7.idation reaction

5n 0riedel Craft Al+ylation> AlCl* is %sed to generateAAAAAAAAAAA a. &. c. d. Strong n%cleophile Wea+ n%cleophile Strong electrophite Wea+ electrophite

*'.

Which one of the following statement is not correct a&o%t &en;ene? a. 7n hydrogenation> #') KNJ mole is li&erated &. C8! &ond length in &en;ene is 1.'9Ao c. 2olec%lar mass of &en;ene is 6).1') d. 3esonance energy of &en;ene is 1-'.- K Cal J mole

##.

Acylation of &en;ene is the introd%ction of AAAAAAAAAAAon &en;ene. 7 __ a. 3 ` C ` 7 ` 7 __ &. Cl ` C ` 7 __ c. 3 ` C ` 7 __ d. ! ` C `

*1.

$he preparation of &en;ene from acethylene can also &e said as AAAAAAAA a) 7.idation c) "ehydration &) Folymeri;ation d) Condensation

*#.

#*.

Acetophenone is a AAAAAAAAAAAAAA a) R%inone c) Aldehyde &) Ketone d) 7ther **.

What is re,%ired other then anhydro%s AlCl*> when tol%ene is prepared from 0riedel craft reaction? a) C1!1 &) C1!1 / C!*Cl c) C1!-C#!- d) C1!- ` C!#` 3eplacement of hydrogen of &en;ene &y al+yl gro%p in press%re of al+yl halide L ferric chloride is +nown asAAAAAAAAAAAA a. &. c. d. "owCs process 0riedel L Craft acylation 0riedel L Craft al+ylation Clemenson reaction

#(.

3eacting &romine with &en;ene in the presence of s%nlight will res%lt inAAAAAAAAAA a. &. c. d. $he r%pt%ring of Ben;ene mg S%&stit%tion reaction Addition reaction No8reaction

#-.

Ben;ene does not %ndergo AAAAAAAAAAA *(. a. &. c. d. S%&stit%tion reaction Addition reaction Folymeri;ation reactions 7.idation reactions *-. Which of the following radical is called &en;yl radical? a) C1!-` c) C1!-`C!` &) C1!-`C!@C!# d) C1!-`C!#`

#1.

"%ring s%lphonation of &en;ene> !#S7( generatesAAAAAAAAAAAA electrophile a) !S7(8 &) S7#

Which compo%nd form &en;oic acid on o.idation with strong o.idi;ing agent? a) $ol%ene &) =thyle &en;ene

41

c) n8propyl &e;ene d) all *1. $ol%ene can &e con<erted to &en;oic acid in presence of AAAAAAAAA (-. a. "il Na7( &. 2i.t%re of !N7* L !#S7( c. n d%st d. Acidified K2n7( *6. Which one of the following is &en;al chloride? a. &. c. d. *). C1!- C!#Cl C1!- C!Cl# C1!-`C! @ C!Cl None of the a&o<e (1. a) Acetyl Ben;ene c) Ben;ophenone &) Ben;yl Chloride d) Acetophenone inc

Fassing <apors of Fhenol o<er heated gi<es a) Ben;ene c) Ben;oic Acid &) Acetic Acid d) Ben;aldehyde

Which of the following is not an e.plosi<e? a) Ficric Acid c) $rinitro $ol%ene &) $rinitro&en;ene d) Nitro &en;ene with acidic K2n7 (

(6.

$ol%ene on prod%ces

reaction

What is the molec%lar form%la of Ben;enetrio;onide? a) C1!179 c) C1!-79 &) C1!-7) d) C1!171 ().

a) Fhenol c) Ben;yl alcohol

&) Ben;oic acid d) Ben;ophenone

$he &.p of F H nitro phenol is higher than that of 7 H nitro phenol &eca%se a) &) c) d) Nitro gro%p is 7JF gro%p Nitro gro%p is electron donating gro%p Bonding occ%rs in F H nitro phenol None of these

*9.

$he hydrolysis of Ben;enetrio;onide will yield three moles of AAAAAAAA a) :lyo.ine c) :lycol &) Ben;aldehyde d) :lyo.al (9.

('.

Which of the following will %ndergo nitration more easily and readily? a) C1!1 c) C1!-CCl* &) C1!-C!Cl# d) C1!-C!*

Which of the following can &e easily nitrated? a) Fhenol c) Nitro &en;ene &) Ben;oic acid d) All of these

-'. (1. $he reaction of tol%ene with chlorine in the presence of 0eCl* gi<es a) &) c) d) (#. Ben;yl chloride Ben;al chloride m H Chloro $ol%ene 7JF Chloro $ol%ene

Aspirin is o&tained &y reaction of s%lph%ric acid and a) Fhenol c) Acetyl chloride &) Ben;ene d) None of these

-1.

S%lphonation of &en;oic acid gi<es a) &) c) d) 7 H &en;ene s%lphonic acid F H &en;ene s%lphonic acid m H &en;ene s%lphonic acid 7JF &en;ene s%lphonic acid

Ben;ene is made of a) &) c) d) 1 Fi and 1 sigma &onds * Fi and * sigma &onds * Fi and 1# sigma &onds 1 Fi and * sigma &onds

-#.

Ben;ene can &e o&tained &y a) &) c) d) 3eaction of ;inc and phenol !ydrolysis of &en;ene s%lphonic acid 3ed%ction of &en;ene chloride All of these

(*.

Common reaction deri<ati<es are a) &) c) d)

of

Ben;ene

and

its -*. o H .ylene on o.idation yields a) 7.alic acid c) $ol%ene -(. &) o H Fhthalic acid d) m H Fhthalic acid

=lectrophilic addition =lectrophilic s%&stit%tion N%cleophilic addition N%cleophilic s%&stit%tion

$he resonance energy of &en;ene is a) *1 IJmol c) *1 KcalJmol &) *1 calJmol d) none of these

((.

Ben;ene when treated with acetyl chloride in the presence of AlCl* yields

42

--.

$he catalyst %sed for halogenation of &en;ene is a) C% c) 0eCl* &) Ni d) n 1*.

e,%ili&ri%m. d) Neither of the two str%ct%res descri&es &en;ene ade,%ately $he con<ersion of tol%ene into &en;oic acid can &e achie<ed &y a) Br#> heat and light &) Cl#> 0eCl* c) K2n7(> 7!8> heat (then !*7/) d) None of the a&o<e 1(.

-1.

Which one is nitroni%m ion? a) NO3

+1 &) NO 2

+1 c) NH 4

d) None of these the

-6.

Which s%&stit%ent gro%p decrease reacti<ity of &en;ene> &eca%se they

$he con<ersion of ethyl &en;ene into 1 H chloro H 1 H phenyl ethane can &e achie<ed &y a) Cl#> light c) S7Cl# &) Cl#> 0eCl* d) None

a) 5ncrease the electronic density of &en;ene ring &) "ecrease the electronic density of &en;ene ring c) "ecrease the sta&ility of phenoni%m ion d) Both & L c -). Ben;ene on o;onolysis prod%ces a) Ben;oic acid c) :lyo.al (C!7#)# -9. &) Cyclohe.ane d) None of these

1-.

Ben;ene reacts with chlorine to gi<e a s%&stance with form%la C1!1Cl1. $his reaction is &ro%ght a&o%t &y a) An acid catalyst c) Al%min%m o.ide &) Gltra<iolet radiation d) 5ron fillings

11.

Which of the following will &e least reacti<e to ring &romination %sing &romine water? a) $ol%ene c) Chloro&en;ene &) Nitro&en;ene d) Aniline

2eta orienting gro%ps decrease the reacti<ity of &en;ene &eca%se they a) 5ncrease the electronic density of &en;ene &) "ecrease the electronic density of &en;ene c) "ecrease the sta&ility of phenoni%m ion d) Both & L c 16.

Ben;ene and cyclohe.ene can &e disting%ished &y which of the following test? a) AgNo* ]C#!-7! c) Br# ]CCl( &) Ag(N!*)#7! d) None

1'.

Ben;ene was fo%nd &y AAAAAAA in 1)#- in the gas prod%ced &y the destr%cti<e distillation of <egeta&le oils. a) !ofmann c) Sol<ay &) 2ichael 0araday d) None of these

1).

Which of the following test can &e %sed to disting%ish C1!-C!#Br and C1!-C!*? a) Ag(N!*)#7! c) AgN7* ]C#!-7! &) Br# ]CCl( d) !ot K2n7(

11.

3eplacement of hydrogen atom &y H S7#7! is called AAAAAAA a) Nitration c) Al+ylation &) S%lphonation d) !ydrogenation

1#.

$he Ke+%le str%ct%res of &en;ene are related in which of the following way? a) $hey are eac e,%ally correct as str%ct%re for &en;ene. &) Ben;ene is sometimes one str%ct%res and sometime the other. c) $he two str%ct%res are in a state of rapid 1.

CHAPTER # 12 Alkyl Halides What sho%ld &e the prod%cts when reactants are alcohol L thionyl chloride in the presence of pyridine?

43

11. a) 3Cl/S/!Cl c) 3Cl/S7#/!#7 #. &) 3Cl/S7#/!Cl d) 3Cl/S/!#7

Which al+yl halide o%t of the following may follow &oth SN1 and SN# mechanism? a. C!*`V

Which C8V &on has the highest &ond energy per mole? a) C80 c) C8Br &) C8Cl d) C85

CH3 H 3 3 )+ CH34 C 4 C 45 3 3 CH3 H CH3 c+ CH3 CH 4 5

*.

Which al+yl halides has the highest reacti<ity > for a partic%lar al+yl gro%p? a) 380 c) 38Br &) 38Cl d) 385

(.

#.) is the electronegati<ity ofAAAAAAAA a) 0 c) Br &) Cl d) 5 1#.

CH3 3 d+ CH34 C4 5 3 CH3 5n elimination reaction of al+yl halide> which site is more s%scepti&le for the attac+ of n%cleophile? a) a8car&on c) a8hydrogen 1*. &) b8car&on d) b8hydrogen

-.

Which one is not a n%cleophile? a) C#!-7` c) N!* &) SCN` d) !*C/

1.

$he n%m&er of molec%les ta+ing part in the rate determining step is calledAAAAAAAAA a) 7rder of reaction &) 3ate or reaction c) 2olec%larity of a reaction d) =.tent of a reaction

When two moles of ethyl chloride react with moles of sodi%m in the presence of ether> what will &e formed? a) # moles of ethane c) # moles of &%tane &) 1 mole of ethane d) 1 mole of &%tane and &) !# d) 7# alcohol

6.

"%ring SN# mechanism>car&on atom changes it state of hy&ridi;ation fromAAAAAAAAAAA a) spMsp# c) sp*Msp &) sp#Msp* d) sp*Msp#

1(.

n8C% co%ple generateAAAAAAA a) X!Y c) X7Y

).

What will &e the order of reaction of a reaction whose rate can &e e.pressed 3 @ K XAY XBY? a) ero c) $wo &) 7ne d) $hree

1-.

When C7# is made to react with ethyl magnesi%m iodide> followed &y acid hydrolysis> the prod%ct formed isAAAAAAAAA a) Fropane c) Fropanal &) Fropanoic acid d) Fropanol

9.

Which one among the following is not a good lea<ing gro%p? a) !S7(` c) 7!` &) Cl` d) Br`

11.

:rignard reagent is reacti<e d%e to AAAAAAAA a. &. c. d. $he presence of halogen atom $he presence of magnesi%m atom $he polarity of C82g &ond All

1'.

What is the order of +inetics in the SN1 mechanism? a) ero c) Second &) 0irst d) $hird

16.

SN# reaction can &e &est carried o%t withAAAA a. Frimary al+yl halide &. Secondary al+yl halide

44

c. $ertiary al+yl halide d. All

#-.

Which one of the following molec%les does not form alcohol when reacts with :rignard reagent? a) 0ormaldehyde c) Fropanone &) Acetaldehyde d) C7#

1).

=limination in<ol<eAAAA

&imolec%lar

reactions

a. 0irst order +inetics &. Second order +inetics c. $hird order +inetics d. ero order +inetics 19. 0or which mechanisms> the first step in<ol<ed is the same? a) =1/=# c) S1/SN1 #'. &) =#/SN# d) SN1/SN# #1. 5n primary al+yl halides> the halogen atom is attached to a car&on which is f%rther attached to how many car&ons atoms a)$wo c) 7ne &) $hree d) 0o%r

$he rate of =1 reaction depends %ponAAAAAAAAAAAA a. $he concentration of s%&strate &. $he concentration of n%cleophile c. $he concentration of s%&strate as well as n%cleophile d. No dependence

#6. $he reacti<ity order of al+yl halides for a partic%lar al+yl gro%p is. (A) 0lo%ride K chloride K Bromide K 5odide (B) Chloride K Bromide K 0lo%ride K 5odide (C) 5odide K Bromide K Chloride K 0lo%ride (") Bromide K 5odide K Chloride K 0lo%ride #). When C7# is made to react with ethyl magnesi%m iodide> followed &y acid hydrogen> the prod%ct formed is. (A) Fropane (C) Fropanal (B) Fropanoic acid (") Fropanol

#1.

Al+yl halides are considered to &e <ery reacti<e compo%nds towards n%cleophile &eca%seAAAAAAAAAAA a. $hey ha<e an electrophilic car&on &. $hey ha<e an electrophilic car&on L a good lea<ing gro%p c. $hey ha<e an electrophilic car&on L a &ad lea<ing gro%p d. $hey ha<e a n%cleophilic car&on L a good lea<ing gro%p

#9. :rignard reagent is reacti<e to. (A) $he presence of halogen atom (B) $he presence of 2g atom (C) $he polarity of C82g atom (") None of the a&o<e *'. SN# reactions can &e lest carried o%t with (A) Frimary al+yl halides (B) Secondary al+yl halides (C) $ertiary al+yl halides (") All of these *1. =limination &imolec%lar reactions in<ol<e. (A) 0irst order +inetics (B) Second order +inetics (C) $hird order +inetics (") ero order +inetics *#. 0or which mechanism the 1st step in<ol<ed in the same. (A) =l and =# (C) =l and =# **. (B) =# and SN# (") =l and SN1

##.

Which one of the following species in not an electrophile? a) N!* c) !/ &) Br/ d) B0*

#*.

Which one of the following reactants will &e re,%ired to form ethane from ethyl chloride? a) Alcoholic K7! c) Al+aline K2n7( &) A,%eo%s K7! d) A,%eo%s Na7!

#(.

Which one of the following alcohols will &e formed when ethyl magnesi%m &romide reacts with acetone? a) Frimary alcohol c) $ertiary alcohol &) Secondary alcohol d) "ihydric alcohol

Al+yl halides are considered to &e <ery reacti<e compo%nds towards n%cleophilies

45

&eca%se. (A) $hey ha<e an electrophilic car&on (B) $hey ha<e an electrophilic car&on and a good lea<ing gro%p (C) $hey ha<e an electrophilic car&on and a &ad lea<ing gro%p (") $hey ha<e a n%cleophilic car&on and a good lea<ing gro%p (#)

c) 37!

d) B0*

Al+yl halides gi<e reactions a) &) c) d) =lectrophilic s%&stit%tion N%cleophilic s%&stit%tion =lectrophilic addition N%cleophilic addition

*(.

$he rate of => reaction depends %pon (A) $he concentration of s%&strate. (B) $he concentration of n%cleophile (C) $he concentration of s%&stratc as well as %ncleophile (") None of the a&o<e

(*)

When Ammonia reacts with e.cess of al+yl halides gi<es a) Frimary amine c) $ertiary amine &) Secondary amine d) 2i.t%re of amines reactions are

(()

N%cleophilic s%&stit%tion represented &y a) =1 c) 37!

*-. Which one of the following is not a n%cleophile (A) !#7 (C) B0* *1) (B) !#S (") N!* (-) Which 2onohaloal+ane can not &e o&tained &y the direct action of halogen and al+ane? a) &) c) d) *6) 3Cl 3Br 35 None of these (1) &) SN d) 3C!7

SN reactions are classified into types a) ( c) # SN# reactions occ%r in a) &) c) d) Frimary al+yl halide Secondary al+yl halide $ertiary al+yl halide All of these &) * d) 1

0or the preparation of 3V> &y the reaction of Alcohol and $hionyl Chloride re,%ires the presence of a sol<ent (6) a) &) c) d) =ther Water Fyridine Acetone ())

Which SN reaction occ%rs in two steps? a) SN1 c) Both &) SN# d) None of these

*))

$he reaction of Sodi%m metal with al+yl halide in the presence of =ther is called a) W%rt;Cs reaction &) Sa&atier reaction c) 0ran+landCs reaction d) None of these

5n SN# reactions> two reactants are in<ol<ed in the rate determining step while these reactions occ%r in a) $wo steps c) 7ne step &) $hree steps d) 0o%r steps of them is organometallic

*9)

Car&on carrying negati<e charge is +nown as a) Car&oni%m ion c) 7.oni%m ion &) Car&on ion d) 7.ide ion inc on

(9)

Which one compo%nd? a) 32gV c) 37!

&) 3V d) 3C!7 reacts with

(')

0ormation of al+ane &y the action of al+yl halide is called

-')

When :rignard reagent formaldehyde to yield a) C!*7! c) C!*C7C!*

a) W%rt;Cs reaction &) Sa&atier reaction c) 0ran+landCs reaction d) Kol&eCs reaction (1) Which of the following is an electrophile? a) O H &) N!*

&) C#!-7! d) C*!)

46

-1)

$he chemical reaction in which !V is remo<ed from two adIacent car&on atoms of an organic molec%le is called 1#) a) &) c) d) "ehydrogenation "ehydrohalogenation "ehydration "ehalogenation

a) =thyl nitrate c) Nitro methane

&) =thyl nitrite d) None of these

=limination reactions are the re<erse of a) &) c) d) =lectrophilic s%&stit%tion reaction N%cleophilic s%&stit%tion reaction Addition reaction 7.idation reaction

-#)

3eaction of 3V with Ammonia is called a) &) c) d) W%rt;Cs reaction 0ran+landCs reaction !offmannCs reaction 0riedal Craft reaction

-*)

A n%cleophile is a 1*) a) 4ewis acid c) Arrheni%s acid &) 4ewis &ase d) Arrheni%s &ase 5n electron pair donor is a strong &ase (OH , OR ) then the dominant reactions will &e a) &) c) d) 1() SN# and =# is a side reaction =# and SN# is side reaction =1 and SN# is side reaction All of these

-()

An electrophile is a a) 4ewis acid c) Arrheni%s acid &) 4ewis &ase d) Arrheni%s &ase

--)

3ate determining steps in SN1 reaction is always the a) Slow step c) 5ntermediate &) 0ast step d) None of these

=1 reactions occ%r in a) 3C!#V c) 3*CV &) 3#C!V d) All of these

-1)

Which one of the organic compo%nd is witho%t o.ygen? a) =ther c) Al+yl halides &) =ster d) Car&o.ylic acid

1-)

$he remo<al of hydrogen from that &eta car&on which has fewer ! H atoms is called a) W%rt;Cs r%le c) Sayt;eefCs r%le &) 2ar+owni+offCs r%le d) !offmannCs r%le

-6)

2ethyl iodide reacts with sil<er acetate to yield a) 2ethyl acetate c) 2ethylol phenol &) 2ethyl ester d) Acetyl halide

11)

Which of them is organometallic compo%nd? a) 32gV c) $24 &) $=4 d) All of these

-))

:rignard reagent reacts with formaldehyde to form a) Frimary alcohol c) Acetic acid &) $ertiary alcohol d) Ketone

16)

0orm%la of $hionyl chloride is AAAAAAA a) S7Cl# c) C!*Cl &) nCl# d) None

1))

-9)

Both methane ethane may &e prepared in one step reaction from a) C#!( c) C!*7! &) C!*l d) C#!-7! 19)

When metallic sodi%m in ether is heated with an al+yl halide> a higher al+ane is formed. 5t is called AAAAAA a) S%lphonation c) 0riedel8Crafts reacton &) W%rt;Cs reaction d) None

1')

32gV reacts with FCl* gi<ing a) 2ethyl phosphate &)$rimethyl phosphate c) "imethyl phosphate d) None of these

Which molec%le has a ;ero dipole moment? a) C!*Cl c) C!#Cl# &) CCl( d) C!Cl*

11)

=thyl iodide on its interaction with sil<er nitrate to yield

6')

:rignardCs reagent reacts with al+yl halide to form AAAAAAAA a) Al+anes &) Al+ynes

47

c) Al+enes 61)

d) Alcohols

7n passing C7# thro%gh :rignard reagent AAAAAA is formed. a) 2ethanoic acid c) Al+yl sodi%m halide &) =thanoic acid d) None of these

6#)

$he hydrolysis of al+yl halides &y heating with a,%eo%s al+ali is a AAAAAAA s%&stit%tion reaction. a) =lectrophilic c) Both a L & &) N%cleophilic d) None

6*)

=thyl &romide can &e con<erted into ethyl alcohol &y heating with> a) A,%eo%s K7! c) 2oist sil<er o.ide &) =thanoic K7! d) Both a L c

6()

$he maIor prod%ct o&tained &y treating # H chloro&%tane with alcoholic K7! is a) 1 H B%tyne c) 1 H B%tene &) # H B%tyne d) # H B%tene

6-)

Which of the following is a <ic H dihalide? a) ClC!#C!#Cl c) BrC!#C!#C!#Br &) C!*C!Cl# d) BrC!#C!#C!#C!#Br

61)

* H Bromohe.ane can &e con<erted into he.ane %sing a) n> !/ c) (C!*)#C%4i &) C% 5 d) Na

66)

SN# reaction proceeds <ia the formation of a) Car&onation c) 0ree radical &) $ransition sate d) Car&anion

6))

Which of the following al+yl halide reacts fastest with AgN7*? a) (C!*)*C H Cl c) C!*C!#C!#Cl &) (C!*)# C! Cl d) (C!*)#CC!#8Cl

48

9. CHAPTER # 11 Alco/ols P/enols and Et/ers 1. Which one of the following is termed as &en;yl alcohol? a) C1!-7! c) C1!-C!#7! #. &) C1!-C!(7!)# d) None 11.

K#Cr#76J!#S7( generateAAAAAAAAAAA a) 7.ygen &) !ydrogen c) Nascent o.ygen X7Y d)Nascent hydrogen X!Y

1'.

$he o.idation of isopropyl alcohol will yieldAAAAAAAAAAAA a) Fropane c) Fropanone &) Fropanol d) Fropanoic acid

Which one of the following is also +nown as lactic acid? a) *8hydro.y propanioc acid &) #8hydro.y propanioc acid c) #8hydro.y &%tanoic acid d) *88hydro.y &%tanoic acid

Which one is primary alcohol ? a) B%ten8#ol &) Fropan8#8ol c) B%tan818ol d) #>*8"imethythe.ane8(8ol.

1#. *. Which one of the following is also +nown as tartaric acid? a) #>*8dihydro.y &%tanedioic acid &) #>#8dihydro.y &%tanedioic acid c) #>*8dihydro.y &%tanioc acid d) #>#8dihydro.y &%tanioc acid (. Water gas heated at (-'UC and #'' atm press%re in the presence of n7/Cr#7* will prod%ce 1(. a) 2ethanal c) Car&onic acid -. &) 2ethanol d) 2ethane 1*.

Action of nitro%s acid on ethylamine gi<es a) C#!1 c) C#!-7! and C#!( &) C#!-7! d) C#!-7! and N!*.

=thyl alcohol is ind%strially prepared from ethylene &y a) Fermanganate o.idation &) Catalytic red%ction c) A&sor&ing in !#S7( followed &y hydrolysis d) 0ermentation. 0inal prod%ct formed on red%ction of glycerol &y hyddriodic acid is a) Fropane c) Fropene &) Fropanoic acid d) None of these

$he resid%e o&tained after the crystalli;ation of s%gar from concentrated s%gar cane I%ice is calledAAAAAAAA a) 2other li,%or c) =.tract &) 0iltrate d) 2olasses

1-.

Fhenol on treatment with cone. !N7* gi<es a) Ficric acid c) Both &) Styphinic acid d) None

11. 1. $he form%la of starch isAAAAAAAAAAA a) C1#!##711 c) C1!1'76. &) C1!97d) C1!1#71 16. $he process of fermentation of starch in<ol<e many en;ymes> the se,%ence of en;yme %sed areAAAAAAAAAAAA 1). a) "iastase8maltase8;ymase &) ymase8maltase8;ymase c) 2altase8diastase8;ymase d) "iastase8;ymase8maltase 19. ). $he rectified spirit containAAAAAAAAA a) 1#S alcohol c) 91S alcohol &) 9'S alcohol d) 1''S alcohol #'.

Alcohols are a) Basic c) Amphatere &) Strong acid d) Ne%tral

$he form%la of wood spirit is ? a) C!*C77! c) C#!-7! &) C!*7! d) None of these

=thanol containing some methanot is called a) A&sol%te spirit c) Fower alcohol :lyccrol is a a) Frimary alcohol c) Secondary alcohol &) 2onohydric alcohol d) $ri&ydric alcohol. &) 3ectified spirit d) 2ethylated spirit

:lyccrol can &e o&tained from

49

a) 0ats c) Both

&) Fropyiene d) None

a) Fieric acide c) #>("initrophenol

&) #8Nitrophenol d) m8Nitrophenol.

#1.

$he en;yme which can catalyse con<ersion of gl%cose to ethanol is a) ymase c) 2altase &) 5n<ertase d) "iastase.

the *'. Which of the following gro%ps will increase the acidity of phenol ? a) HN7# c) HV(halogens) *1. &) HCN d) A55.

##.

!ydrolytic con<ersion of s%crose into gl%cose and fr%ctose is +nown as a) 5nd%ction c) 5nsertion &) 5n<erslon d) 5nhi&ition.

Which is %sed as an antifree;e ? a) :lyeol c) Water &) =thyl alcohol d) 2ethanol

#*.

3ectified spirit is a mi.t%re of a) 9-S ethyl alcohol /-S water &) 9(S ethyl alcohol /(.-*S water c) 9(.(S ethyl alcohol / -.(*S water d) 9-.)6S ethyl alcohol /(.1*S water

*#.

BaeyerOs reagent is a) Al+aline K2n7( c) Ammonial C%S7( &) Ammonical AgN7* d) CaS7#JCa(7!)#

**.

$he reaction &etween alcohol and car&o.ylic acids is called a) =sterification c) Saponification &) !ydrolyais d) !ydrogenation

#(.

Which of the following is not a characteristic of alcohol ? a) $hey are lighter than water &) $heir &oiling point rise fairly %niformly with rising molcc%lar weight c) 4ower mem&ers are insol%&le in water and organic sol<ents &%t the sol%&ility reg%lary increase with molec%lar mass d) 4ower mem&ers ha<e a pleasant smell and &%rning taste> higher mem&ers are colo%riess and tasteless. *(.

Alcoholic &e<erages are made of a) =thanol c) 0ormic acid &) Acetic acid d) None of these

*-.

=lectrophilic s%&stit%tion in phenol generally occ%rs at a) 78 and F8position &) 2etapositions c) 7nly at ortho positions d) 7nly at para position

#-.

Alcohola of low molec%lar weight are a) Sol%&le in water &) Sol%&le in water on heating c) 5nsol%&le in water d) 5nsol%&le in all sol<ents

*1.

Fhenol is more readily sol%&le in a) dil. !Cl &) Both Na7! and !Cl c) Na7! sol d) Sodi%m &icar&onate sol%tion.

#1.

Which of the following can wor+ as a dehydrating agent for alcohol ? a) !#S7( c) F#7&) A5#7* d) A55. *6.

$he order of reacti<ity of halogen acids for reaction with C#!-7! is a) !Cl K !Br K !5 c) !Br K !5 K !Cl &) !5 K !Br K !Cl d) !Br K !Cl K !5.

#6.

Alcohols reacts with :rignard reagent to form a) Al+anes c) Al+ynes &) Al+enes d) A55. *).

#).

Alcohol fermentation is &ro%ght a&o%t &y the action of a) C7# c) 5n<ertase &) 7# d) Qeast. *9.

$he reaction of =thanol with !#S7( does not gi<e a) =thylene &) "iethyl either c) Acetylene d) =thyl hydrogen s%lphate Which one of them is a monohydric alcohol?

#9.

Amongst the following phenols which is most acidic?

50

a) C!*C!(7!)# c) C#!-7!

&) C!*C(7!)* d) None of these

a) A&sol%te alcohol c) 2ethylated spirit

&) Wood spirit d) Binegar

('.

:lycol is alcohol a) 2onohydric c) $rihydric &) "ihydric d) Both a L &

-'.

Which one of the following will not ta+e place if 1 H Fropanol is %nder test? a) $he formation of !# when sodi%m is added to it &) $he formation of 1 H &romopropane when reacts with NaBr and concentrated !#S7( c) $he formation of sweet smelling compo%nd when reacts with a mi.t%re of C!*C77! and concentrated !#S7( d) $he formation of yellow colored prod%ct when phenyl hydra;ine is added to it

(1.

Wood Naphtha is the commercial name of a) =thyl alcohol c) 2ethyl alcohol &) Aldehyde d) Acetic acid

(#.

=thyl Alcohol is denat%red &y adding a) &) c) d) C!*7! L C!*C77! C!*C77! L C!*C7C!* C!*7! L Fyridine None of these -1.

Ba+elite plastic polymeri;ation of a) Fhenol c) =thane

is

formed

&y

the

(*.

2ethylated spirit is a) &) c) d) F%re methyl alcohol 2ethyl alcohol containing water 2ethanol containing methanal =thanol containing methanol -#.

&) Acetylene d) oJp methylol phenol

Acidified potassi%m dichromate is also called a) Chromic acid c) 5odic acid &) Acetic acid d) !ydrochloric acid inc

((.

Alcohol reacts with car&o.ylic acids> acid an hydrides and acid halides to form a) =ther &) =sters &) Ketone d) Aldehyde

-*.

Fassing <apors of phenol o<er heated gi<es a) Ben;ene c) Ben;oic acid &) Acetic acid d) Ben;aldehyde

(-.

Strongly acidic sol%tion of Na#Cr#76 is re,%ired for the o.idation of a) Frimary alcohol c) $ertiary alcohol &) Secondary alcohol d) All of these

-(.

Fhenol reacts with dil%te !N7* in presence of concentrated !#S7( yields a) oJp nitro phenol c) p H nitro phenol &) o H nitro phenol d) None of these

the

(1.

4ow temperat%re and e.cess of Alcohol fa<ors the formation of a) Faraffins c) =ther &) 7lefins d) =sters

--.

Which of the following is not an e.plosi<e? a) Ficric acid c) $rinitrotol%ene &) $rinitroBen;ene d) Nitro&en;ene

-1. (6. An alcohol prod%ced in the man%fact%re of soap is a) =thanol c) :lycerol (). &) Fropanol d) :lycol -6. $he formation of Acetaldehyde from ethanol is called a) 7.idation c) Addition (9. &) 3ed%ction d) S%&stit%tion -).

Sodi%m salt of &en;ene s%lphonic acid on f%sion with ca%stic soda gi<es a) C1!-7! c) C1!-C77! =ther is sol%&le in a) Water c) Conc. K7! &) "il !Cl d) Conc. !#S7( &) C1!1 d) C1!-C!7

By accepting a proton> o.ygen atom of the =ther forms a) Car&oni%m ion &) Car&on ion

"enat%red Alcohol is +nown as

51

c) 7.oni%m ion -9.

d) 7.ide ion

6'.

=thers ha<e no hydrogen &onding &%t they show wea+ ! H &onding when dissol<e in a) Al+ane c) Water &) 0ormaldehyde d) Kerosene oil

WilliamsonCs synthesis is %sed to prepare a) Alcohols c) =sters &) =thers d) Aldehydes

1'.

Wa. contains 61. a) H 7! :ro%p c) Ketonic :ro%p &) H C!7 :ro%p d) =ster :ro%p 6#. a) Ficric acid c) $ri&romo phenol &) $N$ d) $ol%ene 6*. a) 7lefins c) "imethyl ether &) Faraffins d) "imethyl +etone Al+o.ide ion is a powerf%l a) Base c) Salt Al+o.ide ion is a) A powerf%l acid c) N%cleophile &) =lectrophile d) All of these &) Acid d) None of these

11.

Fhenol reacts with Bromine water to form

1#.

Which one is metho.y methane? $he test which is %sed to disting%ish &etween primary> secondary and tertiary alcohols a) 4%cas $est c) Benedicts test 6(. into 6-. a) 3ed%ction c) 7.idation &) Addition d) S%&stit%tion 61. a) Water c) Conc. !#S7( &) "il !N7* d) None of these &) 5odoform test d) BaeyerCs test

1*.

Alcohol reacts with an organic acid to yield a) An ester c) Al+yl halides &) Ketone d) =ther ethyl alcohol

Fhenol is wea+er acid than a) Water c) !V &) 7rganic acid d) Both a L &

1(.

$he con<ersion of acetaldehyde is called

2ethyl alcohol can ca%se AAAAAAA a) Cancer c) Aneimia &) Blindness d) None

1-.

"iethyl ether is sol%&le in =thyl alcohol is prod%ced on commercial scale &y the &iological &rea+ down of AAAAAAAA a) Starch c) Cell%lose &) Acid d) Ben;ene 66. &) 2inerals d) None of these

11.

Faraffins dissol<e in a) Water c) 2ethyl alcohol

C!*7! and C#!-7! are highly misci&le with water &eca%se they e.hi&its AAAAAAAA a) 5onic &onding c) !ydrogen &onding &) Co<alent &onding d) None of these

16.

Fhenol and &en;yl alcohol can &e disting%ish &y %sing a) dil !Cl c) A,%eo%s &romine &) BaeyerCs test d) $ollenCs test 6).

Alcohols may &e con<erted to the corresponding AAAAAA &y actions of halogen acids in the presence of nCl#. a) Aldehydes c) Acyl halides &) Al+yl halides d) None of these

1).

Which one can &e %sed to differentiate &etween phenol and methyl alcohol? a) &) c) d) A,%eo%s Br# Na#Cr#76 in dil !#S7( A,%eo%s NaCl Both a L & 69.

"%ring the dehydration of alcohols> relati<ely high temperat%re and moderate alcohol concentration yield the corresponding AAAAAAA a) =ther c) Faraffin &) 7lefin d) None

19.

Which one attac+ easily on phenol ring a) =lectrophile c) Acid &) N%cleophile d) None of these )'.

5sopropyl alcohol on o.idation gi<es AAAAAA

52

a) =ther c) =thylene )1.

&) Acetone d) Acetaldehyde

3ectified spirit contains AAAAAA S alcohol. a) 9-.1 c) 1''.' &) 6-.' d) )-.(

)#.

Frimary> secondary and tertiary alcohols may &e disting%ished &y %sing AAAAAAA a) 0ehlingCs sol%tion c) !ofmann set &) Bictor 2eyer test d) Beilstein test 1.

CHAPTER # 12 Alde/ydes and ketones $he car&on atom of a car&onyl gro%p is a) Sp hy&ridi;ed c) Sp* hy&ridi;ed #. &) Sp# hy&ridi;ed d) None of these

)*.

5n cold co%ntries glycerol is added to water in car radiators as it helps to AAAAAAAA a) Bring down the specific heat of water &) 4ower the free;ing point c) 3ed%ce the <iscosity d) 2a+e water a &etter l%&ricant

Aldehydes can &e o.idi;ed &y a) $ollenOs reagent c) Benedict sol%tion &) 0ehling sol%tion d) All.

)(.

Fhenol can &e con<erted into p hydro.y&en;aldehyde &y a) 0riedel crafts reaction &) :attermann synthesis c) !a%&an8!oesch reaction d) None of the a&o<e

*.

$ollenOs reagent is a) Ammonical c%pro%s chloride &) Ammonical c%pro%s o.ide c) Ammonical sil<er &romide d) Ammonical sil<er nitrate.

(. )-. Fhenol on treatment with e.cess of &romine water gi<e a) 7 H &romophenol &) F H &romophenol c) 2 H &romophenol d) #> (> - H tri&romophenol -.

Sil<er mirror is a test for a) Aidehydes c) Acids &) $hioaleohols d) =thers

Aldehydes are prod%ced in atmosphere &y a) 7.idation of secondary alcohols &) 3ed%c%on of al+enes c) 3eaction of o.ygen atoms with hydrocar&ons d) 3eaction of o.ygen atoms with o;one

1.

At room temperat%re formaldehyde is a) :as c) Solid &) 4i,%id d) None

6.

0ormalin isAAAAAAAAAAAAS sol%tion of !8C8! in !#7 a) 1'S c) ('S &) #'S d) 1'S

).

Which does not react with fehiling sol%tion ? a) Acetaldehyde c) :l%cose &) Fropanone d) 0ormic acid.

9.

Aldehydes can &e disting%ished from +etones &y %sing

53

a) SchiffOs reagent c) Anhy. Nci# 1'.

&) Conc. !#S7( d) 3esorcinol.

An aidehyde on o.idation gi<es a) An alcohol c) A +etone &) An acid d) An ether #'.

a) $ollenOs reagent &) 0ehling sol%tion c) Acidic dichromate sol%tion d) Benedicts sol%tion 0ormaldehyde when reacted with methyl magnesi%m &romide gi<es a) C#!-7! c) !C!7 &) C!*C77! d) C!*C!7

11.

Ba+elite is o&tained &y condensation of #1. a) Acetaldehyde and acetone &) 0ormaldehyde and phenol c) Acetaldehyde and phenol d) None of these 5f formaldehyde and K7! are heated them we get a) Acctylenc c) 2ethyl alcohol ##. &) 2ethanc d) =thyl formate.

1#.

Car&onyl gro%p %ndergoes a) eliminatory reaction &) electrophilic addition c) niteophlic adelretion d) None of them

Acetone on red%ction gi<es a) C!*C77! c) (C!*)#C!7! &) C!*C!7 d) C#!-7!

#*.

7n o.idation> +etones yield a) Alcohol c) Car&o.ylic acid &) Amine d) =ther

1*.

A n%cleophilic reagent will readily attac+ a) =thylene c) =thanol &) =thanal d) =thylamine #(.

Acetone is %sed in the preparation of a) &) c) d) Gn&rea+a&le glass Smo+eless g%n powder Chloroform All of these

1(.

Which of the following compo%nds gi<es a +etone with :rignardOs reagent ? a) 0ormaldehyde c) =thyl alcohol &) =thanenitrile d) 2ethyl iodide. #-.

Calci%m acetate on dry distillation gi<es a) 0ormaldehyde c) Acetic acid &) Acetone d) =thanol

1-.

Which of the following has car&on with lowest <alency? a) Car&ides c) Al+ynes &) Al+enes d) Al+anes #1.

A sil<er mirror test is for a) Aldehydes c) Alcohols &) Ketones d) =thers

11.

3ed%ction of aldehydes with !5 and F gi<e a) Frimary alcohols c) Al+anes &) Secondary alcohols d) $ertiary alcohols. #6.

Aldehydes can &e disting%ished from +etones &y the %se of a) BayerCs test c) 5odoform test &) :rignard reagent d) 0ehling sol%tion

16.

Which reaction yields Ba+elite? a) Grea with !C!7 &) $etramethyl glycol with !e.amethylene diisocyanate c) Fhenol and !C!7 d) =thylene glycol and "imethylterephthalate.

#).

When ammonia reacts with formaldehyde and )S C!*7! is called a) &) c) d) Ba+elite Fara 0ormaldehyde 2eta 0ormaldehyde Grotropine

1).

Faraaldehyde is a polymer of a) 0ormaldehyde c) Ben;aldehyde &) Acetaldehyde d) Fropionaldehyde. #9.

19.

Acetone is o.idi;ed with

When !e.amethylene tetramine (2ethanamine) reacts with f%ming !N7* to yield a powerf%l e.plosi<e +nown as

54

a) Chloropicrin c) Cyclonite *'.

&) Ficric acid d) None of these ('.

a) Salt c) Acids or &ases

&) $ransition element d) All of these

Which one of the following reactions is not gi<en &y formaldehyde? a) &) c) d) 3ed%ction of 0ehlingCs sol%tion 3ed%ction of $ollenCs sol%tion 0ormation of phenol comple.es 5odoform reaction

Aldols are those organic compo%nds which contain f%nctional gro%p a) H N!# and C77! c) H C!7 and H C7 H &) H C!7 and 7! d) None of these

*1.

Which tests are %sed for the identification of H C!7 in an aldehyde? a) BayerCs test c) $ollenCs test &) 0ehlingCs test d) Both & L c

(1.

Canni;;aro reaction do not occ%r in a) ! H C!7 c) C!*C!7 &) C1!-C!7 d) All of these

*#.

Ben;aldehyde on reaction with al+aline K2n7( yields a) Ben;ophenone c) Ben;oic acid &) Ficric acid d) None of these

(#.

3ed%ction of +etone into al+ane in the presence of n H !g is called a) &) c) d) Aldol condensation Canni;;aro reaction ClemmensenCs reaction None of these

**.

Which of the following %ndergoes halform reaction? (*. a) !C!7 c) C#!&) C!*C7C!* d) C#!-7#C!((.

Aldehydes and +etones &oth easily react with a) 0ehling sol%tion c) :rignard reagent &) SchiffCs reagent d) $ollenCs reagent

*(.

$he compo%nd which gi<es &oth positi<e haloform test and 0ehling test is a) Acetone c) 0ormaldehyde &) =thanol d) Acetaldehyde

Ben;aldehyde reacts with aniline to form a) SchiffCs &ase c) BorscheCs &ase &) $ollenCs reagent d) :rignard reagent

*-.

Sil<er mirror is carried o%t for the detection of f%nctional gro%p a) Ketone c) =ther &) =ster d) Aldehyde

(-.

Almost all the aldehydes and small methyl +etones prod%ce a crystalline white precipitate with sat%rated sol%tion of a) 32gV c) Na!S7* &) C%(7!)# / Na7! d) 37!

*1.

$he reagent which is %sed to disting%ish aldehydes and +etones is a) SchiffCs reagent c) $ollenCs reagent &) 0ehling reagent d) All of these

(1.

Which compo%nd gi<es &ric+ red precipitate of c%pro%s o.ide with BenedictCs sol%tion a) Aromatic aldehyde c) Aromatic +etones &) Aliphatic aldehydes d) Aliphatic +etones

*6.

Which one does not pass thro%gh aldol condensation? a) 0ormaldehyde c) Fropanol &) Acetaldehyde d) Acetone

(6.

Ketones prod%ced a wine red or orange red color on adding a) &) c) d) 0ehling sol%tion $ollenCs sol%tion Al+aline sodi%m nitropr%sside sol%tion All of these

*).

Acetaldehyde reacts with moist chlorine to form a) Acetyl chloride c) Chloral &) Acetone d) Chloroform ().

$he 5GFAC name of C!*C! @ C! H C!7 is a) B%t H # H enal c) 2ethacrolein &) B%t8#8en8*8al d) Fropenaldehyde

*9.

$he n%cleophilic addition reaction of car&onyl gro%p are catalysed &y

55

(9.

$he 5GFAC name of 7!C H C!7 is a) :lyo.al c) Both a L & &) =thane81> #8dial d) None is correct

C!*C! @ C! C!7 LiAlH 4 ? a) C!*C! @ C!C!#7! &) C!*C!#C!#C!7 c) C!*C!#C!#C!#7! d) A mi.t%re of a> & and c.

-'.

$he 5GFAC name of 7!C H C!# H C! @C! H C!7 is a) Fent8#8ene81> -8dial &) Fropene dialdehyde c) Frop818en81> *8dial d) None of the a&o<e

-1.

$he 5GFAC name of (C!*)#C @ C!C7C!* is a) (8methlypent8*8en8#8one &) #82ethlypent8*8en8(8one c) Acetyl #82ethyl8&%tene8* d) None of the a&o<e -9. 0or a car&onyl compo%nd which of the following statements is correct? a) $he car&onyl car&on> o.ygen and the other two atoms (attached to car&on) are coplanar. &) $he two gro%ps attached to car&onyl car&on are directed at an angle of 1#'o from each other. c) $he \ electron density aro%nd o.ygen is more than the car&onyl compo%nd. 1'. $he C @ 7 &ond and C @ C &ond are similar in which of the following ways? a) Both are made %p of one sigma &ond and one pi &ond. &) Both are planer in nat%re. c) Both %se sp# hy&rid or&itals of the C atom for their formation. d) All the a&o<e. $he reaction of acetaldehyde with conc. !#S7( at room temperat%re gi<es a) Faraldehyde c) A mi.t%re of a L & 1#. &) 2etaldehyde d) None

-#.

"ry distillation of calci%m format yields AAAAA a) =ther c) Acetic acid &) 0ormaldehyde d) None of these

-*.

When aldehydes are warmed with AAAAAA red precipitates of c%pro%s o.ide are precipitated. a) :rignardCs 3eagent &) 0ehlings sol%tion c) K2n7( d) None of these

-(.

Acetaldehyde reacts with ammonia to form AAAAAAAA a) =limination c) Addition prod%ct &) S%&stit%tion prod%cts d) 3esin li+e prod%ct

11.

--.

Aldol condensation can occ%r &etween AAAAAA a) An aldehyde and +etone &) An aldehyde and ester c) An aldehyde and &en;ene d) None of these

-1.

An a,%eo%s sol%tion containing a&o%t ('S of formaldehyde and a little alcohol is sold %nder the name of AAAAAAA a) 0ormalin c) Fyridine &) 2alt8s%gar d) Starch

$he following reaction C!*C!7 / !CN M C!*C!(7!)CN is an e.ample of a) N%cleophilic addition &) =lectrophilic addition c) Gncleophilic s%&stit%tion d) =lectrophilic s%&stit%tion

-6.

A n%cleophilic addition of car&onion> generated &y the loss of proton from a8position of an aldehyde or a +etone &y a &ase> to the car&onyl gro%p is called AAAAAAA a) Nitration c) =sterification &) Aldol Condensation d) None

-).

$he prod%ct o&tained in the following reaction is AAAAAAAA

56

d) No replacea&le hydrogen )) Which of the following is a mono&asic acid? a) !#S7( c) !*F7( 9) &) !#C7* d) C!*C77!

!ydrolysis of esters in al+aline medi%m is called a) Sponification c) =sterification &) !ydration d) None of these

1')

Which one of the following does not ha<e a car&o.ylic gro%p? a) Ben;oic acid c) Aspirin &) =thanoic acid d) Ficric acid

C/a"ter (o+ 13 Car)o6ylic Acids & T/eir 7eri8ati8es 1) $he f%nction gro%p in Citric acid is a) H 7! c) H C77! #) &) H 73 d) H C773

11)

$wo moles of car&o.ylic acids on heating in the presence of F#7- yields a) Alcohol c) Acetic acid &) =ther d) =ster

1#)

Which of them is a strong red%cing agent? a) 0ormic acid c) 7.alic acid &) Acetic acid d) Chloro acetic acid

=sters ha<e general form%la a) 37! c) 3C773 &) 3C!7 d) 3C77! 1*)

2ethanoic acid acts as a) &) c) d) Fowerf%l o.idi;ing agent 2ild o.idi;ing agent Fowerf%l red%cing agent 2ild red%cing agent

*)

$he acid present in &%tter is called a) 0ormic acid c) Fropionic acid &) Acetic acid d) B%tanoic acid 1()

()

Which one of the following is the strongest acid? a) C!*C77! c) C!Cl#C77! &) C!#ClC77! d) C#!-C77! 1-)

Between acetic acid and formic acid> the former one is a) 4ess acidic c) Same strength &) 2ore acidic d) 2ore &asic

Beta hydro.yl propionic acid is a) Citric acid c) 7.alic acid &) Aspartic acid d) 4actic acid

-)

Anhydro%s acetic is a crystalline> hygroscopic solid and is also +nown as a) &) c) d) "il%te acetic acid :lacial (ice li+e) acetic acid 2ethanoic acid None of these 11)

0ormic acid can red%ce a) 2erc%ric chloride c) K2n7( &) $ollenCs reagent d) All of these

1)

Acetyl chloride is formed &y the reaction of acetic acid with a) $hionyl chloride c) Alcohol &) Ammonia d) Sodi%m hydro.ide

16)

$he n%m&er of ! H &onds formed per molec%le of car&o.ylic acid are a) ( c) # &) * d) 1 electron withdrawing

6)

Acetic acid is a wea+ acid &eca%se in a,%eo%s sol%tion it is a) !ighly ioni;ed &) Wea+ly ioni;ed c) 5nsol%&le in water

1))

$he attachment of gro%ps res%lt into the

a) 5ncrease of acidity &) "ecrease of acidity c) 5ncrease of strength d) All of these

57

19)

$he firs fo%r mem&ers of car&o.ylic acid are completely sol%&le in water. $his is d%e to a) Acidic nat%re c) Folymeri;ation &) ! H &onding d) 3ed%ction #9)

&) =ssential amino acids c) Non essential amino acids d) Acidic amino acid 7n heating ammoni%m acetate yields a) Acetic acid c) =ther *') &) Acetamide d) Amino acid

#')

Sodi%m &i car&onate when reacts with a compo%nd DVE as res%lt C7# li&erates with effer<escence the compo%nd DVE contain a) H 7! c) V &) H C!7 d) H C77!

A car&o.ylic acid contains a) !ydro.yl gro%p &) Car&o.yl gro%p c) A hydro.yl gro%p and car&o.yl gro%p d) A car&o.yl gro%p and aldehydic gro%p

#1)

$he car&o.ylic acid which coag%lating r%&&er late. is a) =thanoic acid c) Fropanoic acid

is

%sed

for *1) 4ong chain mono car&o.ylic acid are called AAAAAAAA a) Aliphatic acid &) Aromatic acid c) Cyclo car&o.ylic acid d) None of these *#) Common name of 1> * Fropanedioic acid is a) S%ccinic acid c) 2elonic acid **) Binegar is a) -S sol%tion of acetic acid in !#7 &) -'S sol%tion of acetic acid in !#7 c) #-S sol%tion of acetic acid in !#7 d) 1'S sol%tion of acetic acid in !#7 *() S%ccinic acid contain total car&on atoms a) ( c) * *-) &) d) # &) 7.alic acid d) Fhthalic acid

&) 2ethanoic acid d) All of these

##)

Acetic acid when reacts with chlorine in the presence of red phosphor%s> the prod%ct formed is a) Acetyl chloride c) 2ethyl ester &) 2ethyl chloride d) Chloro acetic acid

#*)

Which of them has two f%nctional gro%ps? a) Amino acid c) Acetone &) Salicylic acid d) Both a L &

#()

Amino acids ha<ing two N!# gro%p are a) Acidic in nat%re c) Saltish in nat%re &) Ne%tral in nat%re d) Basic in nat%re

#-)

$he compo%nd which occ%r as ;witter ion or dipolar are a) Ketones c) Alcohol &) Aldehydes d) Amino acid

Car&o.ylic acid can &e prepared from a) Alcohol c) :rignardCs reagent &) =ster d) All

#1)

$he dipolar str%ct%re of an amino acid is also called a) Basic salt c) Ne%tral salt &) Acidic salt d) 5nter<al salt

*1)

5n ind%strial preparation of Acetic Acid from acetaldehyde mangano%s acetate is %sed as a) Catalyst &) 7.idi;ing agent c) $o pre<ent o.idation of Acetic acid into peracetic acid d) All a&o<e

#6)

$he test %sed to identify amino acid is a) $ollenCs test c) 2eyerCs test &) 0ehling test d) Ninhydrin test *6)

Which one is not the deri<ati<e of car&o.ylic acid? a) Acid !alid c) =nthanamide &) Amino acid d) Acid amide

#))

A peptide ha<ing molar mass %p to 1'''' is called poly peptide while a poly peptide ha<ing molar mass more than 1'''' is called a) Frotein *))

5n car&o.ylic acid car&onyl car&on is

58

hydridi;ed a) SF* c) SF *9) &) SF# d) None ()) Which one of the following will increase the acidity of car&o.ylic acid? a) 7! c) H CN (') &) N7# d) Both & L c (9) a) C#!- H 7! c) C!*C77! &) C!* H 7 H C!* d) C!*C7N!#

Acetic acid on red%ction with 4iAl!( gi<es a) =thane c) =thanol &) =thanal d) =thyone

Acetic acid %ndergo dehydration reaction with F#7- and forms. a) 2ethyl acetate c) Acetic anhydride &) B%tanoic acid d) Acetaldehyde

Which one will decrease the acidity of car&o.ylic acid? a) 7! c) Al+yl gro%p &) N!# d) All

(1)

Which one is less acidic? -') a) C!# H C77! ] Cl &) Cl# H C! H C77! c) C!* H C77! d) Cl*.C.C77! -1) A compo%nd %ndergo red%ction with (4iAl!() it also dissol<e in a,.Na7! from which it can &e reco<ered &y addition of !Cl the compo%nd in a) Car&o.ylic acid c) An alcohol &) An ester d) Acid anhydride

(#)

Which one is more acidic? a) !C77! c) C#!( H C77! &) C!*C77! d) C#!6 H C77! -#) &) C!*8C!#8C!#87! d) Both a L c

$he sol%tion of which acid is %sed for seasoning of food? a) 0ormic acid c) Acetic acid &) Ben;oic acid d) B%tanoic acid

(*)

Which ha<e higher B.F? a) C!*C77! c) C!*7 H C#!-

Acetamide is prepared &y a) !eating of ammoni%m acetate &) !eating of =thyl acetate c) Amoni%m propionate d) None

(()

Car&o.ylic ion is represented &y how many resonating str%ct%re? -*) a) * c) 1 &) # d) (

3 H C! H C778 is called ] N!* a) witter ion c) 5nternal salt &) "ipolar ionic form d) All

(-)

!igher B.F of car&o.ylic acid as compared to alcohol of the same m.wt is d%e to a) Strong dispersion ferces &) Strong dipole dipole interaction c) $wo ! H &onding per molec%le d) All of these -()

Amino acids are the &%ilding %nit of protein the lin+age &Jw Amino acid molec%les is called a) :lycosidic lin+age c) =ther lin+age &) Feptide lin+age d) All a&o<e

(1)

$he greater acidity of car&o.ylic acid as compared to alcohol is a) =lectron donating effect of H 7! gro%p &) =lectron with drawing effect of C77! gp c) 3esonance sta&ility of car&o.ylic ion d) All

--)

Which of the following is not a fatty acid? a) Acetic acid c) Fhthalic acid &) Fropionic acid d) B%tanoic acid

-1)

$otal n%m&er of amino acids are a) 1' c) *' &) #' d) ('

(6)

Which of the following compo%nds on reaction with Na!C7* li&erates C7#?

59

C!*C!#C77! and C!*C77!C!*? -6) $otal n%m&er of essential amino acids a) 1' c) H *' -)) &) #' d) H (' 16) N!# ] 3 H C! H C778 is called a) a Amino acid c) c amino acid -9) &) b amino acid d) None 1)) a) Conc. !#S7( c) Cr7* ]!#S7( &) Conc. !N7* d) Na!C7* ]!#7

$he 5GFAC nomenclat%re of C1!-C! @ C!C77! is a) * H Fhenyl prop H # H enoic acid &) Cinnamic acid c) Fhenyl acrylic acid d) 1 H Fhynyl H # H ethylene car&o.ylic acid Which of the following car&o.ylic acids has the largest acidity constant> Ka? a) C!*C77! c) Cl#C!C77! &) ClC!#C77! d) Cl*CC77!

$he acid prod%ced in the sting of &ees and ants is a) Acetic acid c) Car&onic acid &) 0ormic acid d) 7.alic acid

1')

$he con<ersion of acetic acid to methane is an e.ample of a) !ydration c) "ecar&o.yletion &) "ehydration d) 7.idation

19)

Which of the following is not a primary amine? a) Cyclohe.ylamine c) 1 H B%tylamine &) * H he.ylamine d) "iethylamine

11)

Which class of compo%nd is commonly %sed for the artificial fla<o%ring in Iams? a) Aldehyde c) Car&o.ylic acid &) =ster d) Ketones

6')

Which statement a&o%t the reaction of 1 H &romo&%tane and N!* is incorrect? a) $he reaction specifically gi<es a primary amine &) $he reaction is a n%cleophilic s%&stit%tion c) $he reaction initially gi<es a primary amine d) $he reaction may lead to the formation of a ,%aternary ammoni%m salt.

1#)

C!* H C! H C778 is called ] N!# a) Baline c) Alanine &) :lycine d) Froline 61)

# H Bromopentanoic acid can &e o&tained &y a) Fentanoic acid / Br# Light &) Fentanoic acid / Br# P c) Fentanoic acid / !Br d) Fentanoic acid / !Br Peroxides

1*)

Which of the following is not an Amino acid? a) Alanine c) :lyine &) Aniline d) Aspartic acid 6#)

1()

=thyl acetate can &e prepared &y the action of AAAAAAA on car&o.ylic acid> in the presence of acidic media. a) Fhenols c) Fyradine &) 0ormalin d) Alcohol

$he prod%ct o&tained in the following reaction 2 P is C!*C!#C77! Br ? a) C!*C!BrC77! &) BrC!#C!#C77! c) BrC!#C!BrC77! d) A mi.t%re of all the a&o<e prod%cts

1-)

Which of the following car&o.ylic acid is the strongest? a) C!0# H C!# H C!# H C77! &) C!*C!#C0#C77! c) C!#0 H C!0 H C!# H C77! d) C!*C!#C!#C77!

6*)

Acetamide can &e prepared &y the reaction of ammonia on a) =thyl acetate c) Acetic anhydride &) Acetyl chloride d) All the a&o<e
+

6()

11)

Which of the following will ser<e as the &asis for simple chemical test to disting%ish &etween

$he prod%cts o&tained in the following reaction H are C!*C77C!* / C!*C!#7!

60

a) C!*C77C#!- / C!*7! &) C!*C!#C77C!* / C!*7! c) A mi.t%re of &oth the a&o<e prod%cts d) None of the a&o<e 6-) Which of the following reaction will gi<e ethyl propionate?
a) C!*C!#C7#! / C#!-7! H OH &) C!*C!#C7#! / C#!-7! 2H5 c) C!#C7#C#!- / C!*5 NaOC d) All the a&o<e reactions
+

61

C/a"ter # 1% 9acromolec!les 1. Which of the following is polymeri;ation process? a. &. c. d. $he crac+ing of petroel%m 0ractional disstillation of cr%de oil 0ormation of polyethen !ydrolysis of protiens

11. 2aIor type of polymers are a. !omopolymer c. $eropolymer &. Copolymer d. All of the a&o<e

1#. $he epo.y resin are f%ndamentally a. Folyethers c. Folyesters 1*. Starch is a polymer of a. Beta8" gl%cose &. Alpha8" gl%cose c. :amma8" gl%cose d. Alpha8&eta8" gl%cose 1(. the most a&%ndant protiens that are present in the connecti<e tiss%es thro%gho%t the &ody are a. 4eg%min c. Both &. Collagen d. None of the a&o<e properties &. Foly<inyls d. None of the a&o<e

#. Which one is addition polymer? a. Nylon81 c. $erylene &. Folystyrene d. =po.y resin

*. Which is synthetically prepared polymer? a. Animal fat c. Cell%lose (. Begeta&le oils are a. &. c. d. Gnsat%rated fatty acids :lycerides of %nsa%rtated faty acids :lycerides of stt%rated fatty acids =ssential oils o&rained from plants &. Starch d. FBC

1-. Based %pon physicochemical proteins may &e classified into a. $wo types c. $hree types

-. $he water sol%&le <itamin is a. A c. K &. " d. C

&. 0o%r types d. 0i<e types

11. $he primary &%ilding &loc+s of lipids are a. &. c. d. 0atty acids and gycerols :lycerols and sterols 0atty acids > :lycerols and sterols None of the a&o<e

1. Which of the following element is not present in all proteins a. Car&on c. Nitrogen &. !ydrogen d. S%lph%r

16. Animal and Begeta&le fats and oils ga<e a. "ifferent str%ct%re &. Similar chemical str%ct%re c. Both the a&o<e depend %pon the circ%mstances d. None of the a&o<e 1). $he en;yme which %se as dr%g in &lood cancer is a. $hrom&in c. Both of the a&o<e &. 4asparaginase d. None of the a&o<e

6. !ydrolysis of fats is catalysed &y a. Grease c. ymase &. 2altase d. 4ipases

). Which of the follwing statement is incorrect for gl%cose and s%crose? a. &. c. d. Bothe are sol%&le in waater Both are nat%rllay occ%ring Both are car&ohydrates Both are disaccharides

19. "ifferent &ases fo%nd in "NA are 9. 2acromolec%les may &e of a. &. c. d. 5norganic and organic nat%re 5norganic nat%re 7rganic nat%re None of the a&o<e a. &. c. d. Cytosine and thiamine Adenine and g%anine All of the a&o<e None of the a&o<e

#'. Folyethylene is prepared from 1'. Str%ct%re wise the polymers are of a. 4inear shaped &. Branched linear shaped c. Cross in+ed linear shaped d. All of the a&o<e a. =thene c. =thyne &. =thylene d. Both a and &

62

#1.

$he gro%p of chemical reagents that ta+e part in life s%staining process is called a. Wa. c. 0ood &. 3efinery gas d. None of these

*#.

$he general form%la of car&ohydrates is a. Cn(!#7)n c. Cn(!#7)#n &. C#n(!#7)n d. None of these

##.

A &alanced diet m%st contain at least a. $wo n%trients c. Si. n%trients &. 0o%r n%trients d. $hree n%trients

**.

Car&ohydrates are a) &) c) d) Folyhydro.y alcohols Folyhydro.y ethers Folyhydro.y ester Folyhydro.y aldehydes or +etones

#*.

Which one of the following is a single n%trient food? *(. a. Starch c. 2il+ &. Boney d. :l%cose

2onosaccharide and "iaccharides are solid> sweet in taste and sol%&le in a. C1!1 c. C!Cl* &. !#7 d. Acetone

#(.

2il+ is a food containing a. Single n%trient c. 2%ltin%trient &. "in%trient d. None of these *-.

Car&ohydrates which contain # H 1' car&on atoms and not are hydrolysa&le are called a. 2onosaccharides c. Folysaccharides &. 7ligosaccharides d. None of these

#-.

Which of these are the so%rces of energy as well as so%rce for &%ilding of tiss%es? a. Froteins c. Car&ohydrates &. 0ats d. All of these *1.

Which of the car&ohydrates is tasteless? a. :l%cose c. S%crose &. 0r%ctose d. :lycogen

#1.

Which n%trients reg%late the &ody processes? a. 2inerals c. Water &. Bitamins d. All of these *6.

S%crose on hydrolysis yields a) &) c) d) :l%cose / 2annose :l%cose / 0r%ctose 0r%ctose / 2annose 2annose / :alactose

#6.

$he prod%ct of o.idation of gl%cose is a. C7# c. =nergy &. Water d. All of these *).

:l%cose is also called a. Starch c. S%crose &. "e.trose d. 2annose

#).

$he o.idation of fats prod%ces? a. C7# c. C7# / !#7 / = &. C7# / !#7 d. None of these *9.

#9.

$he o.idation of protein prod%ces %rea in addition to a. C7# c. Nitrogen &. Water d. Both a L & ('. a. Cell%lose c. :lycerol &. :lycogen d. Starch

$he heterogeneo%s gro%p of organic compo%nds which pro<ides ins%lation for the <ital organs protects from electrical shoc+ and maintains optim%m &ody temperat%re is called a. Froteins c. 4ipids &. Bitamins d. Car&ohydrates

*'.

:l%cose is stored in the li<er as $he n%trients of food which are in<ol<ed in comm%nication> ner<o%s defenses> meta&olic reg%lation> catalysis and o.ygen transport are called a. Froteins c. 4ipids (1. &. Bitamins d. Car&ohydrates

*1.

$he e.cess of amino acids are not stored in the &ody &%t dominated to form intermediates of a) &) c) d) 0at meta&olism Car&ohydrates meta&olism Frotein meta&olism None of these

Steroids &elong to the family of lipids which are a. $ricyclic c. Fentacyclic &. $etracyclic d. 2onocyclic

63

(#.

Cholesterol is a steroid which is the important prec%rsor of a. Se. hormones c. Bitamin " &. Adrenal hormones d. All of these

-#.

$he trade name of polytetrafl%oroethylene (F$0=) plastic is a. "acron c. Saran &. $eflon d. Nylon

(*.

:allstones contain? a) &) c) d) 0ree cholesterol Com&ine cholesterol Starch 2annose

-*.

$he form%la of $eflon is a) &) c) d) (CCl# H CCl#)n (8 C0# H C0# 8)n (8 CBr# H CBr# 8)n (8 Cl# H Cl# 8 )n of the following is addition &. Folystyrene d. All of these polymers among the

((.

=n;yme acti<ators are a. 7rganic salt c. Froteins &. 5norganic salts d. 0ats

-(.

Which one polymer? a. FBC c. Folythene

(-.

Frod%ct of sponification is --. a. :lycerol c. N%cleic acid &. Salt of fatty acids d. Both a L & $he condensation following a. Folyester c. =posy resin -1.

(1.

$he n%m&er of moles of s%&strate transformed per mole of en;yme per min%te at a definite temperat%re is called a. Fotency c. 3ancidity &. $%rn o<er d. None of these

&. Folyamide d. All of these

F$=0 is formed &y the polymeri;ation of a. C!# @ C!# c. C0# @ C0# &. C!# @ C!Cl d. None of these

(6.

=n;ymes are most acti<e at a temperat%re of? a. *'oC c. (-oC &. ('oC d. -'oC

-6.

0l%orine is present in a. Folythene c. $eflon &. Nylon 1> 1 d. Folyester

().

5norganic s%&stances which increase the acti<ity of an en;yme is called a. Acti<ators c. Coen;ymes &. 5nhi&itors d. None of these

-).

A copolymer is formed &y polymeri;ation of a) &) c) d) A single type of monomer $wo types of monomers $hree types of monomers All of these

(9.

$he synthetic fi&er composed of an ester of a dihydric alcohol and terphthalic acid is called a. 3ayon fi&er c. Folyester &. Acrylic fi&er d. Saran fi&er

-9.

A polymer is formed &y polymeri;ation of three different types of monomers is a. Copolymer c. 2onomer &. !omopolymer d. All of these

-'.

"acron is the trade name of 1'. a. Nylon 1> 1 c. Acrylic fi&er &. $erylene fi&er d. Saran fi&er 11. Qeast is a a) Bacteria c) Bir%s &) Anti&iotic d) 0%ngi

-1.

$he plastics which are formed &y plain polymeri;ation are +nown as? a) &) c) d) $hermoplastics $hermosetting plastics Both None of these

Folyester resins are the prod%ct of the reaction of AAAAAAA a) Alcohol and aromatic acids &) Folyamines with aliphatic dicar&o.ylic acids c) Styrene in the presence of catalyst d) =pichlorohydrin with diphenylol propane

64

1#.

=n;yme tripsin con<erts 6*. a) Amino acid into proteins &) :l%cose into glycogen c) Starch into s%gar d) Froteins into amino acids $he protein responsi&le for the clotting of &lood is a) 0i&rinogin c) :lo&%lins 6(. &) Al&%mine d) None of the a&o<e

1*.

$he digestion of fat in intestine is aided &y a) "iff%sion c) =m%lsification &) Feptisation d) Ne%trali;ation

Which hormone controls the meta&olism of car&ohydrates? a) Adrenaline c) $hyro.ine &) 5ns%lin d) 7.ytocin

1(.

Chemical name of Bitamin A is 6-. a) $hiamine c) Ascor&ic acid &) 3etinol d) Nicotinamide Which of the following are re,%ired &y the &ody in small amo%nt only? a) Froteins c) Bitamin 61. &) 0ats d) None

1-.

:l%cose and fr%ctose are a) 7ptical isomers c) Chain isomers &) 0%nctional isomers d) Fosition isomers

Saponification of cocon%t oil yields glycerol and a) Falmitic acid c) 7leic acid &) Sodi%m palmitate d) Satiric acid

11.

Starch is a polymer of AAAAAAAA a) :l%cose c) 4actose &) 0r%ctose d) 2altose

16.

7n heationg gl%cose with 0ehlingCs sol%tion we get a precipitate of color AAAAAAA a) Qellow c) Blac+ &) 3ed d) :reen

1).

$he sweetest of all s%gars is a) :l%cose c) S%crose &) 2altose d) 0r%ctose

19.

Amino acids are least sol%&le in water a) At p! @ 6 c) At p! W 6 &) At p! K6 d) At isoelectric point

6'.

Which of the following is the richest so%rce of energy? a) Adenosine troposphere (A$F) &) Adenosine diphophate (A"F) c) Adenosine monophosphate (A2F) d) All are e,%ally rich so%rce of energy

61.

"igestion of car&ohydrates ta+es place in a) 2o%th c) 5ntestine &) Stomach d) Both a L c

6#.

Brown s%gar can &e decolo%rised &y a) Bleaching powder c) !ypo &) Soap sol%tion d) Animal Charcoal

65

C/a"ter 1& C/emical #nd!stries in Pakistan 1. Which processJ reaction gi<es %rea with ammoni%m car&onat a) !logenation c) !ydrolsis &) "ehrdration d) None of the a&o<e

11. Cement is <ery important &%ilding material which was first of all introd%ce &y =nglish 2ason Noseph Aspdin in a) 1)6c) 1)1' &) 1)#( d) 19#'

1#. Faper cons%mption per person in Fa+istan is a) -+g c) 1+g &) (+g d) )+g

#. Grea as a fertili;er contain a) -6S N c) (1S N &) 6*S N d) -*S N

*. Ammoni%m nitrate is a %sef%l fertili;er e.cept for a) Wheat c) Barley &) S%gar cane d) Faddy rice

1*. $he sl%rry which contains in the ma+ing of cement ddS of water a) *- to (c) (- to -' &) (' to (d) None of the gi<en

(. $he phosphoric acid which is %sed for the preparation of di ammoni%m phosphate fertili;er is ha<ing 1' to 6'oC temperat%re and a) F! -81 c) F! 68) &) F! -.) to 1Z d) F! 1 to 6.-

1(. $he dried paper is wo%nd in the form of a reel ha<ing final moist%re of a&o%t dd.S a) 1 to ) c) # to ) &) ( to 1 d) - to )

1-. N!#8C78N!# is the chemical form%la of a) Ammonia c) Grea &) "iamino +eton d) Both of & and c

-. Which three elements are needed for the healthy growth of plants a) N.S.F c) N.F.K &) N.Ca.F d) N.K.C

11. $he fertility of the soil is impro<ed &y AAAAAA a. &. c. d. 3otation of the crops Adding lime to the acid salts Adding man%re and growing leg%mes All

1. $he nitrogen present in some fertili;er help plants a. &. c. d. $o fight against diseases $o prod%ce fat $o %ndergo photosynthesis $o prod%ce proteins

16. Which of the following is incorrect statement a&o%t nitrogen importance? a. 5t enhances plant growth &. 5t is in<ol<ed in the synthesis of protein and n%cleic acids c. 5t accelerates fr%its and flowers growth d. 5t is in<ol<ed in the chlorophyll synthesis 1). $he fertili;ers> which pro<ide single n%trient from NFK> are called AAAAAAAAAfertili;er a) Straight c) Both a and & &) Compo%nd d) None of the a&o<e

6. phosphor%s help in the growth of a) 3oot c) Stem &) 4ea<e d) Seed

). $he wood paper is deri<ed from the name of which reedy plant a) 3ose c) Fapyr%s &) S%nflower d) Water hyacinth

9. Which is not a calcaro%s material? a) 4ime c) 2ar&le &) Clay d) 2arine shell

19. Which of the following in macron%trient? a) C% c) !# &) Cl# d) n

1'. Ammoni%m nitrate fertili;er is not %sed for which crop a) Cotton c) S%gar cane &) Wheat d) Faddy rice

#'. Addition of %rea of the soil is AAAAAAAAAAAAAA reaction a) =ndothermic &) =.othermic c) Both a and & d) No heat energy is in<ol<ed

66

#1. Which of the following is the most s%ita&le catalyst for ammonia synthesis? a) Ft c) 0e#7* / 27#7* &) n7 / Cr#7* d) All of the a&o<e

*1. $he n%trients which are re,%ired in <ery small amo%nt for the growth of plants are called. a. &. c. d. Nitrogeno%s fertili;ers 2icron%trients Fhosphor%s fertili;er S%rfactant

##. $he cooling of molten %rea &y air in the tower is calledAAAAAAAAA a) Frilling c) Condensation &) =<aporation d) Crystalli;ation

*#. Which one of the following set of raw material is most s%ita&le for man%fact%re of %rea? a) C!(> N# and C7# c) !#> C7# and !#7 &) !#> N# and C7 d) !#7> N# and !#

#*. Which of the following fertili;ers is more %sef%l for paddy rice? a) Grea &) "AF c) Ammoni%m s%lphate d) Ammoni%m nitrate #(. "AF ("iammoni%m hydrogen phosphate) contains AAAAAAA F4AN$ n%trients. a) 1'S c) 6'S &) 1-S d) 6-S

**. Which one of the following statement is correct for %rea? a. &. c. d. 5t is a synthetic fertili;er 5t is a nat%ral fertili;er 5t pro<ides micron%trients to plants 5t is an inorganic water sol%&le compo%nd

#-. Which of the following potassi%m fertili;ers are more %sef%l for hortic%lt%ral crops> to&acco L potatoes? a) KCl c) K#S7( &) KN7* d) K2n7(

*(. Which on the following is an inorganic fertili;er? a) *1S c) -1S &) (1S d) 11S

*-. Which one of the following is an inorganic fertili;er? a) 2an%re c) Ammoni%m nitrate *1. not &) Grea d) All

#1. Calcario%s material incl%desAAAAAAAAAAA a) 4ime stone c) Chal+ &) 2ar&le d) All of the a&o<e does

#6. Argillaceo%s material incl%deAAAAAAAAAAAA a) Clay c) Slated

$here is only one nitrogen fertili;er which is %sed as li,%id is a) N!(N7* a) N!* &) N!(Cl d) (N!()#!F7(

&) 2arine shells d) Blast f%rnace slag *6.

#). Which of the following processes is %sed for the synthesis of cement? a) "ry process c) Both &) Wet process d) None *). #9. Fhosphor%s helps in the growth of AAAAAAAA a) 3oot c) Stem &) 4ea<e d) Seed *9. *'. !ow many ;ones thro%gh which the charge passes in a rotary +iln? a) ( c) # &) * d) ('.

=.cept Ca(N7*)#> NaN7* and KN7*> all nitrogen fertili;ers ma+e the soil a) Acidic c) Ne%tral &) Basic d) None of these

Which fertili;er contain )#S nitrogen? a) N!(N7* c) N!(Cl &) KN7* d) N!*

N!(N7* is %sed as fertili;er for most crops e.cept a) Fotato c) Faddy rice &) S%garcane d) $o&acco

$he percentage of nitrogen in %rea is a) ('S c) ()S &) (1S d) -'S

67

(1.

Fotassi%m fertili;ers are %sed for a) 0r%its c) $o&acco &) Begeta&le d) All of these

-1.

$he final prod%ct which is o&tained from the rotary +iln (cement prod%ction) is called a) Clin+er c) 0i&er &) F%lp d) Folymer

(#.

0rom which of the following nat%ral fi&er is o&tained? a) Animal c) 2ineral &) Begeta&le d) All of these

-#.

$he separation of cell%lose fi&ers &y mechanical method or &y <ario%s chemicals from the matri. res%lt into a) Clin+er c) Folymer &) F%lp d) 5somer a&&re<iation of $ricalci%m

(*.

$he percentage of nitrogen in ammonia nitrate is -*. a) (1S c) )#S &) ** H **.-S d) ()S

$he ind%strial al%minate is a) C#S c) C*A

((.

N!(N7* is %sed as a fertili;er for many crops e.cept paddy rice &eca%se -(. a) &) c) d) 5ts gran%les are solid 5t is poisono%s 5t is ne%tral $he micro&ial &acteria in flooded field decompose N!(N7* into N# gas --.

&) C*S d) C(AF

S%per phosphate fertili;er is formed &y the a) &) c) d) Acylation of phosphate roc+ Al+ylation of phosphate roc+ Acid%lation of phosphate roc+ Aromati;ation of phosphate roc+

(-.

2an%fact%ring of s%per phosphate fertili;er in<ol<es a) Si. steps c) 0o%r steps &) 0i<e steps d) $hree steps

Nat%ral fertili;ers are materials deri<ed from a) Flants c) Algae &) Animals d) All of these

-1. (1. $he percentage of F#7- in triple s%per phosphate fertili;er is a) (- H (1S c) ** H *-S (6. &) (1 H ()S d) ('S -6. $he percentage of nitrogen in ammoni%m s%lphate is a) #1S c) (1S (). &) #-S d) )#S of C7 #JN!* -).

$he fertili;ers> which pro<ide single n%trient from NFK> are called AAAAA fertili;ers. a) Straight c) Both a L & &) Compo%nd d) None

$he s%&stances added to the soil in <ery small amo%nts (a&o%t 1 grams to #'' grams per acre) are called AAAAAAA a) 2acron%trients c) 0ertili;ers &) 2icron%trients d) None of these

$he Stoichiometric ration con<ersion to %rea is a&o%t a) -'S c) 1'S &) --S d) 1-S

A nat%ral fertili;er pro<ide a&o%t AAAAAA +g of nitrogen. a) (.c) #.# &) *.# d) 1.-

(9.

$he chief strength prod%cing constit%ents of cement is a) &) c) d) 4ime 2g7 $ricalci%m silicate (*Ca7.Si7#) All of these

-9.

A nat%ral fertili;er pro<ides AAAAAA +g of F#7a) (.c) #.# &) *.# d) 1.-

1'.

$he percentage of nitrogen in ammoni%m s%lphate is AAAAAAA a) *# H **.c) )' H )# &) -' H -d) #' H #-

-'.

Clin+er is prod%ced &y a) Wet method c) BayerCs method &) "ry method d) Both a L &

68

11.

$he percentage of s%lph%r in ammoni%m s%lphate is AAAAAA S. a) #c) #* &) #1 d) 19

C/a"ter # 1* En8ironmental c/emistry 1. Feeling of o;one %m&rella is d%e to

1#.

Ammoni%m nitrate is sold as a mi.t%re with AAAAAAAAA a) Soda Ash c) inc &) 4imestone d) None of these

a) C0Cs c) C7# #. ""$ is

&) FAN d) Coal &%rning

1*.

Any material> which changes the cleaning effect of water is called AAAAAAA a) 0ertili;ers c) Acid &) "etergent d) None of these

a) Biodegrada&le pol%l%tant &) Nondegrada&le poll%tant c) Not a poll%tant d) An anti&iotic *. 5ncreasing s+in cancer and high m%tation rates are a) Acid rain c) C7 poll%tion &) 7;one depletion d) C7# poll%tion

1(.

Commercial detergents contain mainly AAAAAA a) 3C77N c) 3SNa &) 37Na d) 37S7*Na

1-.

$he principle former of almost all glasses is AAAAAAAA a) (Si7#)n c) (Si7#)V &) (Si7*)n d) None of these

(. Sewage water is p%rified &y a) 2icroorganisms c) 0ishes &) 4ight d) A,%atic plants

11.

Calcario%s material incl%des AAAAAAAA a) 4ime stone c) Chal+ &) 2ar&le d) All of the a&o<e

-. GB radiations &ring a&o%t a) S+in cancer c) 4%ng cancer &) 2o%th cancer d) 4i<er cancer

16.

Cement is a mi.t%re of so many compo%nds roasted in rotary +iln. Which s%&stances has greater percentage? a) 4ime (Ca7) c) Al%mina (Al#7*) &) Silica (Si7#) d) 2agnesia (2g7)

1. Which one is more to.ic? a) Car&on c) C7 &) C7# d) S7#

6. Soil salinity can &e meas%red &y a) Cond%cti<ity meter c) Frotometer &) Fhotometer d) Fotometer

1).

$he important f%nction of &%rning ;one in the rotary +iln is AAAAAA a) $o dry the moist%re of sl%rry &) $o decompose lime stone to %nsla+ed lime c) Com&ination of different o.ides li+e Ca7#> Si7#> 0e#7* and Al#7*. d) $o red%ce the imp%rities

). Biodegrada&le poll%tant is a) Flastic c) Sewage 9. 4ead is &) As&estos d) 2erc%ry

19.

As&estos is a AAAAAAA a) 2ineral fi&er c) Begeta&le fi&er &) Animal fi&er d) None of these a) Air poll%tant &) Soil poll%tant c) 3adioacti<e poll%tant d) Noise poll%tant 1'. Air poll%tion is not ca%sed &y a) Follen grains &) !ydroelectric power c) 5nd%stries and a%tomo&iles

69

a) 7;one and d%st &) S7* and C7

&) C7# and C7 d) S7# and N7#

11. C7 is harmf%l for h%mans as it #'. "etergents are sodi%m salts of a) 5s carcinogenic &) 5s antogonistic to C7# c) !as high affinity for heamoglo&in than o.ygen d) 5s destr%cti<e of 7* 1#. "isease ca%sed &y eating fish in water contaminated with ind%strial waste ha<ing merc%ry a) 2inamat disease c) !ashmitos disease &) Brights dieses d) Arthritis a) Calci%m s%phonates &) Bari%m s%lphonates c) Sodi%m car&onates d) Ben;ene s%lphonates #1. B7" is the amo%nt of a) Car&on disso<ed in water &) Amo%nt of o.ygen in water c) Amo%nt of &acteria in water d) All of the a&o<e ##. $he o.ygen demand in water is determined &y a) "is%lphate ion c) Bicar&onate ion &) "ichromate ion d) Bidentate ion

1*. "raw&ac+s of "$$ as pesticide is a) 5t &ecomes ineffecti<e after some time &) 5t is less effecti<e that others c) 5t is not easily degrades in nat%re d) its high cost 1(. 0ish die in water &odies poll%ted &y sewage d%e to a) Fathogens &) Clogging of gills &y silt c) 3ed%ction in o.ygen d) 0o%l smell 1-. "rained sewage has B7" a) 2ore than that of water &) 4ess than that of water c) =,%al to that of water d) None of the a&o<e 11. Which one of the following forms a to.ic s%&stance &y com&ining with hemoglo&in in &lood. a) C7# c) 7# &) C7 d) C!(

#*. !er&icides are %sed for remo<al of a) 5nsects &) 0%ng%s on the plants c) Gndesited plants d) 3odents #(. ""$ is one of the most powerf%l a) 5nsecticide c) 0%gicied &) !er&icides d) Fastecide

#-. 2ost ha;ardo%s metal poll%tant of a%tomo&iles e.ha%st is a) 2erc%ry c) 4ead &) Cadmi%m d) Copper

#1. Fhotochemical smog is related to poll%tion of a) Air c) Soil &) Water d) Nostic

#6. =n<ironmental poll%tion affects 16. GB radiation from the s%n ca%ses a reaction that prod%ces a) 0lo%rides c) S7# &) C7 d) 7* a) Biotic components &) Flants only c) 2an only d) Biotic and a&iotic components of en<ironment #). 7;one hole refers to a) *.- +m c) -.1 +m &) (.- +m d) 1' +m a) !ole in o;one layer &) 3ed%ction in thic+ness of o;one layer in stratosphere c) 3ed%ction of thic+ness of o;one layer in troposphere

1). $he half of the atmosphere is concentrated in the lower ddd+m

19. Acid rain is d%e to increase ion atmospheric concentration of

70

d) 5ncrease concentration of o;one *).

c) (

d) -

$he main poll%tant of leather tanneries in the waste water isAAAAAAA a) Chromi%m 555 c) Sodi%m &) Chromi%m 55 d) Copper

#9. =%trophication ca%ses red%ction in a) "issol<ed hydrogen &) "issol<ed o.ygen c) "issol<ed salts d) All of the a&o<e *'. $he yellow color in photochemical smog is d%e to presence ofAAAAA a) Car&on dio.ide c) Chlorine gas &) Nitrogen dio.ide d) None ('. *9. Which of the following air poll%tants is ,%iet +iller? a) C7# c) N7# &) C7 d) N#7(

*1. Which one of the following ma+es the &%l+ of hydrosphereCs content? a) 7ceans &) :laciers L ice c) 0resh water la+es and ponds d) All ha<e e,%al distri&%tion *#. Chlorination of water may &e harmf%l if the water containsAAAAAAA a) Ammonia c) Car&on dio.ide **. &) "issol<ed o.ygen d) All

$he o%ter part of the earth is present in a) 4ithosphere c) Biosphere &) !ydrosphere d) Atmosphere

(1.

$he components of lithosphere are a) &) c) d) Soil 2ineral of earth cr%st 7rganic matter of earth cr%st All of these

(#.

$he en<elop of gases s%rro%nding the earthCs s%rface which a&sor& most of the cosmic rays and maintain the &alance is a) Atmosphere c) !ydrosphere &) Bio sphere d) 4ithosphere

Which s%&stance can &e %sed for disinfection water? a) K2n7( c) 7;one &) Al%ms d) All (*.

7;one is located in a) $roposphere c) 2esosphere &) Stratosphere d) $hermosphere

*(.

Which statement is wrong? a) $he amo%nt of o;one layer is greater in the region close to the e,%ator. &) 7;one acts as filter for GB radiations c) 5n the polar region> it acts as poll%tant d) C0Cs play effecti<e role in remo<ing 7* in the stratosphere. ((.

Which f%el on com&%stion prod%ces f%migati<e and s%lph%ro%s emission? a) Coal &) :asoline c) Kerosene oil d) "iesel and f%rnace oil

*-.

Which of the following factors help to meas%re ,%ality of water? a) "7 c) C7" &) B7" d) All of the a&o<e

(-.

$he solid or li,%id particles with diameter ranges from '.'1e or less %p to a&o%t 1'' e are a) Aerosols c) Smo+e &) "%st d) All of these

*1.

5n the p%rification of porta&le water> the coag%lant %sed isAAAAAAAAA a) Al%m c) Copper s%lphate &) Nic+el s%lphate d) Bari%m s%lphate

(1.

$he poll%tants responsi&le for eye> nose> throat> &ronchial tract and respiratory tract irritation are a) !#S c) N!* &) C7# d) Both a L c

*6.

Newspaper can &e recycled again and again how many times? (6. a) # &) *

$he air poll%tant which is responsi&le for corrosion and erosion is

71

-6. a) S7# c) Smo+e &) Car&on d) Aerosol

Fresence of hea<y metals in water ca%ses a) 2ental retardation c) Cancer &) Ner<o%s disorder d) All of these

().

Car&on and soot accelerate the corrosion and erosion d%e to a) Acidic nat%re &) Basic nat%re c) A&sorption or adsorption of the gaseo%s poll%tant %pon these partic%lars mater d) All of these $he poll%tant which adhere to stones &ric+s and s%rface and ca%se fo%ling are a) &) c) d) Smo+e and d%st Smo+e and aerosols Aerosols and d%st None of these

-).

5nd%strial waste water contains a) &) c) d) 7ccl%ded L dissol<ed gases 5norganic salts L organic compo%nds Fathogens All of these

(9.

-9.

"rin+ing water sho%ld ha<e a) $%r&idity less than 1'ppm &) p! &etween 6 to ).c) sho%ld &e free from diseases ca%sing &acteria d) all of these

-'.

Clean rain is a) Basic c) Slightly acidic &) Slightly &asic d) All of these

1'.

$he concentration of dissol<ed molec%lar o.ygen in p%re drin+ing water is a) # to (ppm c) ( to )ppm &) * to (ppm d) ) to 1'ppm

-1.

$he F! of ne%tral rain water is 11. a) -.1 c) *.1 &) (.1 d) #.1 1#. $he content of "7 in poll%ted water is a) 4ess than (ppm c) 1ppm &) (ppm d) )ppm

-#.

$he poll%tant which play an important role in smog formation a) C7 c) !#S &) N!* d) All of these

$he C7" (Chemical 7.ygen "emand) of water can &e determined directly &y treating with a) "ichromate ions c) 7.ide ions &) Chloride ions d) None of these

-*.

Fhotochemical smog is a) 7.idi;ing smog c) Ne%tral smog &) 3ed%cing smog d) Smo+e 1*.

Water ha<ing high <al%e of C7" means the water is a) F%re c) Aerosols &) "%st d) =ffl%ent

-(.

3ed%cing smog is formed &y the com&ination of a) Smo+e c) "%st &) 0og d) Smo+e L fog which res%lts &) N!* d) 0reon into o;one 1-. 1(.

$he techni,%es %sed to +ill pathogens present in drin+ing water are a) Chlorination c) GB irradiation &) 7;one d) All of these

--.

$he poll%tant depletion is a) C7 c) !#S

Fathogens present in poll%ted water can +illed &y chlorination &%t cannot remo<e a) Bir%ses c) 7do%r &) $aste d) All of these

-1.

$he photochemical smog is also called o.idi;ing smog which has high content of o.idant li+e 11. a) 7* c) N!* &) S7# d) All of these

$he process in solid waste is &%rnt at high temperat%re ranging from 9'' to 1'''oC a) Chlorination &) 7;onation

72

c) 5ncineration 16.

d) All of these

66.

$he decrease in the thic+ness of o;one layer present in the stratosphere is termed as a) 7;one hole c) 7;one coag%lation &) 7;one depletion d) Both a L &

$he chief poll%tant which li+ely to deplete o;one layer is a) S7# c) C7# &) N!* d) C0#Cl#

1).

Which one of the following is not a component of en<ironment? a) !ydrosphere c) Biosphere &) 4ithosphere d) Stratosphere

19.

$he yellow color in photochemical smog is d%e to presence of AAAAAAA a) Car&on dio.ide c) Chlorine gas &) Nitrogen dio.ide d) None

6'.

Which statement is wrong? a) $he amo%nt of o;one layer is greater in the region close to the e,%ator. &) 7;one acts as filter for GB radiations. c) 5n the polar region> it acts as poll%tants. d) C0Cs play effecti<e role in remo<ing 7* in the stratosphere.

61.

5n the p%rification of porta&le water> the coag%lant %sed is AAAAAAA a) Al%m c) Copper s%lphate &) Nic+el S%lphate d) Bari%m s%lphate

6#.

$he p! range of acid rain is a) - H 6 c) 1.- H 6 &) 1 H ) d) 4ess than -

6*.

$he Sage of S7# from Bolcanic er%ption is a) (6 c) 16 &) -6 d) 66

6(.

Which layer consist of thic+ layer of o;one? a) Stratosphere c) $roposphere &) $hermosphere d) 2esosphere

6-.

2ain reason of acid rain is a) S7# J C7# c) S7# J N7# &) N7# J F#7d) All

61.

$he thic+ness of o;one layer is a) #- to -' +m c) * +m only &) #- to #)+m d) 1 +m only

73