Scribd
Upload
51 views

Perhitungan PH Metri

The document discusses the results of several experiments involving the titration and pH determination of various solutions. It finds that: 1) The measured pH values of HCl, NaOH, and NH4OH solutions match closely with the theoretical pH values calculated. 2) The normality of HCl was determined to be 0.06658 N by titrating with sodium borate. 3) Various samples including NaOH and NH4OH were found to have a concentration of 0.06658 N by titrating with HCl.

Uploaded by

luchuns
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
51 views

Perhitungan PH Metri

The document discusses the results of several experiments involving the titration and pH determination of various solutions. It finds that: 1) The measured pH values of HCl, NaOH, and NH4OH solutions match closely with the theoretical pH values calculated. 2) The normality of HCl was determined to be 0.06658 N by titrating with sodium borate. 3) Various samples including NaOH and NH4OH were found to have a concentration of 0.06658 N by titrating with HCl.

Uploaded by

luchuns
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
You are on page 1/ 5

LAMPIRAN

1. Perhitungan

pH hasil pengukuran

pH NaOH = 12,06
pH HCl = 2,35
pH NH4OH = 10,98
pH Aquades = 7,24
pH Air Keran = 6,54

Na
2
B
4
O
7
+ 2HCl +5H
2
O 4H
3
BO
3
+ 2NaCl
NaOH + HCl NaCl + H
2
O

Standarisasi HCl dengan Boraks
Massa boraks = 0,1526 gram
Berat molekul boraks = 382 gram/mol
Elektron valensi oksalat (n) = 2
BE Oksalat =

= 191 gram/mol

Mencari Normalitas HCl secara teoritis
Ek (titran) = Ek (analit)
V x N =


0,012 liter x N =



0,012 liter x N = 0,0007989 mol
N = 0,06658 N
Penentuan pH HCl secara teoritis

V
1
= 5 mL
N
1
= 0,1 N
V
2
= 100 mL

V
1
x M
1
= V
2
x M
2
5 ml x 0,1 N = 100 ml x N
2
M
2
= 5x10
-3
N

HCl H
+
+ Cl
-
5x10
-3
5x10
-3
5x10
-3

[H
+
] = 5x10
-3

pH = -log[H
+
]
= -log 5x10
-3

= 2,3010

Penentuan pH NaOH
V
1
= 5 mL
N
1
= 0,1 N
V
2
= 100 mL

V
1
xN
1
= V
2
xN
2
5 ml x 0,1N = 100 ml x N
2
M
2
= 5x10
-3
N

NaOH Na
+
+ OH
-
5x10
-3
5x10
-3
5x10
-3


pOH = -log[OH
-
]
= -log 5x10
-3

= 2,3010

pH = 14 pOH
= 14 2,3010
= 11,699

Penentuan pH NH
4
OH
V
1
= 5 mL
N
1
= 0,1 N
V
2
= 100 mL

V
1
xM
1
= V
2
xM
2
5 ml x 0,1N = 100 ml x N
2
M
2
= 5x10
-3
N

[OH
-
] =


= 0,0003


pOH = -log[OH
-
]
= -log 0,0003
= 3,5229

pH = 14 pOH
= 14 3,5229
= 10,477


Larutan pH
Teori Praktikum
HCl 2,301 2,35
NaOH 11,699 12,06
NH
4
OH 10,477 10,98
Aquades 7 7,24
Air keran >7 6,54
Penentuan Konsentrasi Sampel

1. Penentuan Konsentasi NaOH (volume HCl didapat dari titik ekivalen)
V
NaOH
= 5 mL
N
HCl
= 0,06658 N
V
HCl
= 5 mL

V
NaOH
x N
NaOH
= V
HCl
x N
HCl
5 ml x N
NaOH
= 5 ml x 0,06658

N
NaOH
= 0,06658 N

2. Penentuan Konsentasi NH
4
OH (volume NaOH didapat dari titik ekivalen)
V
NH4OH
= 5 mL
N
HCl
= 0,06658 N
V
HCl
= 5 mL

V
NH4OH
x N
NH4OH
= V
HCl
x N
HCl
5 ml x N
NH4OH
= 5 ml x 0,06658 N

N
CH3COOH
= 0,06658 N

Jadi, konsentrasi HCl sebesar 0,06658 N dan konsentrasi CH3COOH sebesar 0,06658 N.

Potensio titrasi Fe
2+
dengan K
2
Cr
2
O
7

Reaksi:

Anoda : 2Fe
2+
2Fe
3+
+ 2e E= -0.77 v
Katoda : Cr
2
O
7
+ 2e Cr
3+
+7H
2
O E = 1,33 v

+
Total : 2Fe
2+
+ Cr
2
O
7
2Fe
3+
+ Cr
3+
+7H
2
O Etotal = 0,56 v

E yang didapat dari percobaan adalah dari titik ekivalen : 0,59 Volt

Penentuan ekivalenFeSO
4
dengan titrasi K
2
Cr
2
O
7

Vol FeSO
4
= 5 ml
Vol K
2
Cr
2
O
7
= 10 ml
N K
2
Cr
2
O
7
= 0.1 N



Berat FeSO4 yang didapat :


1 x 10
-3

You might also like