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Lampiran B BT

The document describes calculations related to determining the density, distribution coefficient, and mass percentages of components in a two-layer system. In the first layer, the density was calculated to be 0.2972 g/ml and the distribution coefficient was 0.8262. The mass percentages of acetic acid, water and diethyl ether in this layer were 43.98%, 9.87% and 46.15% respectively. In the second layer, the density was 0.6145 g/ml and the distribution coefficient was 6.1776. The mass percentages of acetic acid, water and diethyl ether were 43.94%, 9.88% and 46.18% respectively.

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Muhammad Reza Rahmadhan
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27 views5 pages

Lampiran B BT

The document describes calculations related to determining the density, distribution coefficient, and mass percentages of components in a two-layer system. In the first layer, the density was calculated to be 0.2972 g/ml and the distribution coefficient was 0.8262. The mass percentages of acetic acid, water and diethyl ether in this layer were 43.98%, 9.87% and 46.15% respectively. In the second layer, the density was 0.6145 g/ml and the distribution coefficient was 6.1776. The mass percentages of acetic acid, water and diethyl ether were 43.94%, 9.88% and 46.18% respectively.

Uploaded by

Muhammad Reza Rahmadhan
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as DOC, PDF, TXT or read online on Scribd
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LAMPIRAN B

PERHITUNGAN
L.B.1 Pembuatan NaOH0,9 M
MNaOH

= 0,9N

Vair

= 100ml

0,9 M

massa

= 3,6gram

massa 1000
x
Mr
V

Maka, 3,6 gramNaOHdilarutkandengan air hingga volume 100 ml


L.B.2 Perhitungan Densitas Praktek
Lapisan Atas
m1

= berat piknometer kosong = 20,92gr

m2

= 33,42gr

= 33,42gr20,92gr= 12,5 gr

V = 13 ml
aquadestpadasuhu 30oC=0,99568 g/ml

(Geankoplis, 1993)

= 0,2972gr/ml
Lapisan Bawah
m1

= berat piknometer kosong = 20,92 gr

m2

= 46,76 gr

= 46,76 gr 20,92 gr= 25,84gr

V = 44 ml
aquadestpadasuhu 30oC=0,99568 g/ml

(Geankoplis, 1993)

=0,6145 gr/ml
L.B.3 Menentukan Koefisien Distribusi dan Koefisien Distribusi Rata-rata
Lapisanatas
NaOH = 0,9 M
Volume NaOH yang diperlukan = 36 ml
mmol NaOH = 0,9 M x 36 ml = 32,4 mmol
CH3COOH + NaOH CH3COONa + H2O
32,4 mmol
maka CH3COOH yang bereaksi : 32,4mmol
= 32,4x 10-3 mol x 60 gr/mol
= 1,944 gr.
Volume larutan yang dititrasi
Volume lapisan atas

massa CH3COOH yang dititrasi


massa CH3COOH lapisan atas

x = 5,0544
Massa CH3COOHatas= 5,0544 gr
LapisanBawah
NaOH = 0,9M
Volume NaOH yang diperlukan = 13 ml
mmol NaOH = 0,9 M x 13 ml = 11,7 mmol
CH3COOH + NaOH CH3COONa + H2O
11,7 mmol
maka CH3COOH yang bereaksi : 11,7 mmol
= 11,7x 10-3 mol x 60 gr/mol

= 0,702 gr.
Volume larutan yang dititrasi
Volume lapisan bawah

massa CH3COOH yang dititrasi


massa CH3COOH lapisan bawah

x = 6,1776
Massa CH3COOHbawah = 6,1776gr
Kd1 =

massa CH 3 COOH pada lapisan atas


massa CH 3 COOH pada lapisan bawah

=
= 0,8262
L.B.4 Perhitungan Indeks Bias dan Fraksi Mol Masing-Masing Lapisan
Lapisan Atas
I lapisan = IAs. Asetat.XAs.Asetat +IAquadest.XAquadest + IDietileter.XDietileter
lapisan =As. Asetat.XAs.Asetat +Aquadest.XAquadest + Dietileter.XDietileter
1= XAs. Asetat +XAquadest+ XDietileter
Persamaan

di

atasdisusundalambentukmatriks,

dandiselesaikandengan

program Matlab :
>> a=[1.3715 1.3290 1.3530; 1.08721.0432 0.7312; 1 1 1]
a=
1.3715
1.0872

1.3290

1.0000

1.0432

1.3530

1.0000

0.7312
1.0000

>> b= [4.35400.2972 1]
b=
4.3540
>> c=a/b
c=

0,2972

1.0000

0.3851
0.2881
0.2819
Lapisan Bawah
I lapisan = IAs. Asetat.XAs.Asetat +IAquadest.XAquadest + IDietileter.XDietileter
lapisan =As. Asetat.XAs.Asetat +Aquadest.XAquadest + Dietileter.XDietileter
1= XAs. Asetat +XAquadest+ XDietileter
Persamaan

di

atasdisusundalambentukmatriks,

dandiselesaikandengan

program Matlab :
>> a=[1.3715 1.3290 1.3530; 1.0872 1.0432 0.7312; 1 1 1]
a=
1.3715
1.0872

1.3290
1.0432

1.3530

1.0000

0.7312

1.0000

1.0000

>> b=[4.2250 0.6145 1]


b=
4.2250

0.6145

1.0000

>> c=a/b
c=
0.4142
0.3103
0.3037
L.B.5 Perhitungan Massa Zat dari Masing-Masing Lapisan
Lapisan Atas
Fraksimolmasing-masingkomponen :
X AsamAsetat

=0.3851

X Aquadest

=0.2881

X Dietileter

=0.2819

Massa masing-masing komponen :


Massa Asam Asetat

0,3851x 60

= 23,1060

Massa Aquadest

0,2881x 18

5,1858

Massa Dietileter

0,2819 x 86

Massa Total

= 24,2434+
= 52,5352

% Berat untuk masing-masing komponen :


23,1060

% Massa Asam Asetat

= 52,5352 x 100% = 43,98%

% Massa Aquadest

= 52,5352 x 100% = 9,87%

% Massa Dietileter

= 52,5352 x 100% = 46,15%

5,1858

24,2434

B.5.1.2Lapisan Bawah
Fraksimolmasing-masingkomponen :
X AsamAsetat
X Aquadest

=0.4142
=0.3103

X Dietileter

=0.3037

Massa masing-masing komponen :


Massa Asam Asetat

0,4142x 60

= 24,8520

Massa Aquadest

0,3103x 18

Massa Dietileter

0,3037x 86

26,1182+Massa Total

5,5854
=

56,5556
% Berat untuk masing-masing komponen :
24,8520

% Massa Asam Asetat

= 56,5556 x 100%

= 43,94%

% Massa Aquadest

= 5,5854 x 100%

= 9,88%

% MassaDietil Eter

= 26,1182 x 100%

= 46,18%

56,5556

56,5556

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