AMOCO MITSUI PTA INDONESIA

Material Safety Data Sheet

Pengenal Cepat (Nama Umum dalam pabrik)
Perusahaan pembuat :
AJAX CHEMICAL
BAGIAN 1- IDENTIFIKASI PRODUK
Nama Umum (digunakan pada label) (Nama Dagang & Sinonim):
BENSEN;
Benzene D6
CAS No:
71-43-2
UN : 1114
Nama Kimia :
BENSEN
Keluarga Kimia :
HidrokarbonAromatik
Rumus Molekul :
C6H6
URAIAN FISIK / SIFAT
TAMPILAN :
!enin"# $at %air &en"an bau aromatik' AM!AN( !A) * ppm
PERIN(A+AN ,!A)-IRI+A.I/ .e&ikit 0 ti&ak mu&ah &i&eteksi &en"an bau taua iritasi pa&a +L1'
+itik &i&ih '''''': 23 &e" C ,456 &e" 6/
+itik leleh'''''': *'* &e" C ,78 &e" 6/
+ekanan )ap''''': 433 mm H" at 86'4 &e" C
.PECI6IC (RA1I+9''': ,.(/ 3'25: at 4* &e" C ,;ater < 4/
+itik N=ala'''''''': 44 &e" C ,48 &e" 6/
!atas N=ala: No >ata
!atas le&akan ''': ,LEL/ 4'?@ ,)EL/ 5'4@
+emp' n=ala otomatis '': 7:2 &e" C ,:82 &e" 6/
+ekanan uap REL': 8'5 ,air < 4/
!erat MALEK)L''': 52'44
pH''''''''''''''''': +i&ak &i"unakan
!entuk ''''''''''''''': Cairan
OTHER PROPERTIES:
CAN1ER.IAN 6AC+AR 4 ppm < ?'878 m"-m?B 4 m"-m? < 3'?32* ppm at 83 &e" C
.A+' 1APA)R CANC' 4?@ or 4?3333 ppm ,%al%ulate& at 86'4 &e" C/
E1APARA+IAN RA+E Not aCailable
CRI+ICAL +EMPERA+)RE Not aCailable
.AL)!ILI+9 IN DA+ER .li"htl= soluble ,about 3'5 "-litre oE ;ater/
.AL)!ILI+9 IN A+HER LIF)I>. Mis%ible ;ith: al%ohol# %hloroEorm# ether#%arbon &isulEi&e# a%etone# oils# %arbon tetra%hlori&e
an& "la%ial a%eti%a%i&'
AC+ANAL-DA+ER PAR+I+IAN CAE66ICIEN+ ,P/: lo" P < 4'*68'4* 1I.CA.I+9: 3'6762
mPa'. at 83 &e" C !LAA>-AIR PAR+I+IAN CAE66ICIEN+: 5'2
USE:
)se& in the manuEa%ture oE me&i%inal %hemi%als# &=es# plasti%s# teGtiles#&eter"ents# artiEi%ial leather# Carnishes# paints# la%Huers#
;aGes an& man=other materials' .olCent Eor inks# paints# rubber# a&hesiCes# %oatin"s#&eter"ent an& pesti%i&es' !en$ene is Eoun&
in %oal tar &istillates#petroleum naphtha an& "asoline'
No Data in IDENTIFICATION means data not applia!le in t"is #ield$ In all ot"e% #ields& it means not a'aila!le
BAGIAN 2- INFORMASI BAHAYA TERHADAP KESEHATAN
ACUTE EFFECTS
S(ALLO(ED:
Mo&erate &oses %an %ause &i$$iness# eG%itation an& pallor# Eollo;e& b=Elushin"# ;eakness# hea&a%he# breathlessness# an&
Eeelin"s oE %onstri%tionin the %hest' 1isual &isturban%es are EreHuent' Lar"e &oses %an %ausesta""erin" "ait# Comitin"# sleepiness#
shallo; an& rapi& pulse# an&&elirium' In seCere %ases# un%ons%iousness# %onCulsions an& &eath ma= o%%ur'.eCere lun" &ama"e
,%hemi%al pneumonitis/ ma= o%%ur iE in"este& ben$ene isa%%i&entall= &ra;n into the lun"s ,aspirate&/'
E)E:
No human &ata' !en$ene mi"ht irritate the e=es'
S*IN:
!en$ene is absorbe& sli"htl= throu"h the skin' != &eEattin" the skin it %an%ause irritation# inElammation# blisterin"# &r=in" an&
s%alin"'
INHALED:
!en$ene a%ts on the nerCous s=stem' It %an %ause &ro;siness# &i$$iness# hea&a%he# li"hthea&e&ness# nausea# an& &e%rease&
%oor&ination' !en$eneCapour %an %ause mil& irritation oE the respirator= tra%t' 1er= hi"h leCels%an %ause &e%rease& Iu&"ement#
Eeelin"s oE ;ellbein"# loss oE balan%e an& rin"in" ears ,tinnitus/' )n%ons%iousness or &eath ma= result'
CHRONIC EFFECTS
HEALTH EFFECTS +LOOD AND +LOOD,FORMIN- S)STEM: !en$ene %an impair thEormation oE re& an& ;hite bloo& %ells
an& platelets' +here ma= be%onsi&erable Cariabilit= Erom person to person in the spe%iEi% t=pes oE %ells aEEe%te& an& the eGtent oE
&eEi%ien%=' +he bone marro; ,;here bloo&%ells are ma&e/ ma= be aEEe%te&' +he seCerit= oE the &isease is not &ire%tl=relate& to
the &uration or intensit= oE eGposure' NER1A). .9.+EM: Prolon"e&lo; leCel eGposure %an &ama"e the nerCous s=stem
%hara%teri$e& b= impairmentoE hearin"# %hroni% hea&a%he# &i$$iness# Eati"ue# Cisual &isturban%es#&e%rease& balan%e an& pallor'
.KIN: Repeate& or prolon"e& %onta%t %an %ause
inElammation# &r= s%alin" an& blisters' Prolon"e& eGposure ma= %ause lesions
resemblin" Eirst or se%on& &e"ree burns'
CARCINA(ENICI+9 !en$ene %an %ause %an%ers oE the ;hite bloo& %ells,leukemias/' Can%er ma= or ma= not be pre%e&e& b=
other bloo& &isor&ers'
+ERA+A(ENICI+9 AN> EM!R9A+AXICI+9 !en$ene %rosses the pla%enta an& is present in the Eoetal bloo&' It %an %ause
menstrual &isor&ers'
M)+A(ENICI+9 !en$ene %an %ause %hromosomal aberrations in heaCil= eGpose& ;orkers' +he si"niEi%an%e oE su%h muta"eni%
eEEe%ts are# at the present notCer= ;ell un&erstoo&'
PA+EN+IAL 6AR ACC)M)LA+IAN .ome absorbe& ben$ene is eGhale& in the breath'Most is transEorme& an& eG%rete& in the
urine' !en$ene is store& temporaril= in Eat' +he elimination oE ben$ene ma= take more than EiCe &a=s aEtereGposure has stoppe&'
FIRST AID
S(ALLO(ED:
NeCer "iCe an=thin" b= mouth iE Ci%tim is rapi&l= losin" %ons%iousness# or is un%ons%ious or %onCulsin"' HaCe Ci%tim rinse mouth
thorou"hl= ;ith ;ater ' >A NA+ IN>)CE 1AMI+IN(' HaCe Ci%tim &rink 873 to ?33 mL ,2 to 43 o$'/ oE;ater' IE Comitin" o%%urs
naturall=# haCe Ci%tim lean Eor;ar& to re&u%e risk oE aspiration' Repeat a&ministration oE ;ater' IE breathin" has stoppe&# traine&
personnel shoul& be"in artiEi%ial respiration or# iE the heart has stoppe&# %ar&iopulmonar= resus%itation ,CPR/ imme&iatel=' Abtain
me&i%al attention imme&iatel='
E)E:
Imme&iatel= Elush the %ontaminate& e=e,s/ ;ith luke;arm# "entl= Elo;in" ;ater Eor 83 minutes# b= the %lo%k# hol&in" the e=eli&,s/
open' +ake %are not to rinse %ontaminate& ;ater into the nonaEEe%te& e=e' Abtain me&i%al attention imme&iatel=' Prote%t the
%ontaminate& e=e,s/ Erom li"ht iE painEul'
S*IN:
RemoCe %ontaminate& %lothin"# shoes an& leather "oo&s ,e'"' ;at%hban&s#belts/' Dash "entl= an& thorou"hl= ;ith ;ater an&
nonabrasiCe soap' IE irritation persists# obtain me&i%al attention imme&iatel=' Completel=&e%ontaminate %lothin"# shoes an& leather
"oo&s beEore reuse or &is%ar&'
INHALED:
+ake proper pre%autions to ensure =our o;n saEet= beEore attemptin" res%ueB e'"'# ;ear appropriate prote%tiCe eHuipment# use the
Jbu&&=J s=stem' RemoCe sour%e oE %ontamination or moCe Ci%tim to Eresh air' IE breathin" has sour%e oE %ontamination or moCe
Ci%tim to Eresh air' IE breathin" has stoppe&# traine& personnel shoul& be"in artiEi%ial respiration or# iE the heart has stoppe&#
%ar&iopulmonar= resus%itation ,CPR/ imme&iatel=' Abtain me&i%al attention imme&iatel='
FIRST AID FACILITIES:
ProCi&e "eneral supportiCe measures ,%omEort# ;armth# rest/' Consult a ph=si%ian an&-or the nearest Poison Control Centre Eor all
eGposures eG%ept minor instan%es oE inhalation or skin %onta%t' All Eirst ai& pro%e&ures shoul& be perio&i%all= reCie;e& b= a
ph=si%ian Eamiliar ;ith the material an& its %on&itions oE use in the ;orkpla%e'
AD.ICE TO DOCTOR:
No >ata
TO/ICIT) DATA:
ANIMAL +AXICI+9 >A+A L>*3 ,oral# rat/: 72:7 m"-k" L>*3 ,oral# rat/: *'6 "-k"
LC*3 ,rat/: 46333 ppm-7 hr LC*3 ,rat/: 43333 ppm-5 hr .KIN AN> E9E
IRRI+A+IAN: Pure ben$ene applie& to rabbit skin %ause& sli"ht to mo&erate skin irritation' Dhen applie& in the e=es# it %ause& a
mo&erate to seCere e=e irritation an& temporar= %orneal inIur=' REPRA>)C+I1E E66EC+.: In seCeral animal spe%ies# &oses
;hi%h are toGi% Eor the mother haCe not %ause& birth &eEe%ts or Eetal &eath' It ma= %ause re&u%e& Eetal ;ei"ht an& retar&e&
"ro;th' +here is some in&i%ation oE EetotoGi%it= ;ith &oses ;hi%h are not ne%essaril= toGi% to the &am ,4/' E66EC+. AN +HE
!LAA>: Rats eGpose& to 833 ppm# 2 hours per &a=# * &a=s per ;eek Eor :3 &a=s# &eCelope& a seCere &e%rease in the number oE
;hite bloo& %ells ,leukopenia/ ,4/'
Aral Lo;est Lethal >ose,man/: *3 m"-k"
Inhalation LCLo,human/: 8 ppm-* min

No Data in IDENTIFICATION means data not applia!le in t"is #ield$ In all ot"e% #ields& it means not a'aila!le
BAGIAN 3 TINDAKAN PENCEGAHAN
E/POSURE STANDARDS:
,+L1+DA/ * ppm ,46 m"-m?/B DorksaEe Aust'
!IALA(ICAL EXPA.)RE IN>ICE. ,!EIs/: +he AC(IH has a&opte& a !EI Eor this %hemi%al' !EIs proCi&e an in&i%ation oE
;orker eGposure b= measurin" the %hemi%al or its break&o;n pro&u%ts in the bo&= or b= measurin" bio%hemi%al %han"es
resultin" Erom eGposure to the %hemi%al' Consult the !EI &o%umentation Eor Eurther inEormation' .AMPLIN( K ANAL9.I. )se
appropriate instrumentation an& samplin" strate"= ,lo%ation# timin"# &uration# EreHuen%=# an& number oE samples/' Interpretation
oE the samplin" results is relate& to these Cariables an& the anal=ti%al metho&' CALARIME+RICIN>ICA+IN( ,>E+EC+AR/
+)!E.: Commer%iall= aCailable
>IREC+ REA>IN( IN.+R)MEN+.: Commer%iall= aCailable &eCi%es: portable Elame ioni$ation meterB portable "as
%hromato"raphB portable spe%trophotometerB )1 air samplin" anal=$er'
EXPA.)RE CAN+RAL Note: EGposure to this material %an be %ontrolle& in man= ;a=s' +he measures appropriate Eor a
parti%ular ;orksite &epen& on ho; this material is use& an& on the eGtent oE eGposure' )se this "eneral inEormation to help
&eCelop spe%iEi% %ontrol measures' Ensure that %ontrol s=stems are properl= &esi"ne& an& maintaine&' Compl= ;it o%%upational#
enCironmental# Eire# an& other appli%able re"ulations' LCate"or= 4 Car%ino"en# DorksaEe Aust' Establishe& human %ar%ino"ens
are those substan%es kno;n to be %ar%ino"eni% to humans' +here is suEEi%ient eCi&en%e to establish a %ausal asso%iation
bet;een human eGposure to these substan%es an& the &eCelopment oE %an%er'
EN-INEERIN- CONTROLS:
Maintain %on%entration belo; re%ommen&e& eGposure limit'
EN(INEERIN( CAN+RAL. En"ineerin" %ontrol metho&s to re&u%e ha$ar&ous eGposures are preEerre&' Metho&s in%lu&e
me%hani%al Centilation ,&ilution an& lo%al eGhaust/# pro%ess or personnel en%losure# %ontrol oE pro%ess %on&itions# an& pro%ess
mo&iEi%ation ,e'"'# substitution oE a less ha$ar&ous material/' A&ministratiCe %ontrols an& personal prote%tiCe eHuipment ma=
also be reHuire&' !e%ause oE the hi"h potential ha$ar& asso%iate& ;ith this substan%e# strin"ent %ontrol measures su%h as
en%losure or isolation ma= be ne%essar=' )se a nonsparkin"# "roun&e& Centilation s=stem separate Erom other eGhaust
Centilation s=stems' EGhaust &ire%tl= to the outsi&e' .uppl= suEEi%ient repla%ement air to make up Eor air remoCe& b= eGhaust
s=stems'
PERSONAL PROTECTION:
RESPIRATOR) PROTECTION
IE en"ineerin" %ontrols an& ;ork pra%ti%es are not eEEe%tiCe in %ontrollin" eGposure to this material# then ;ear suitable personal
prote%tiCe eHuipment in%lu&in" approCe& respirator= prote%tion' HaCe appropriate eHuipment aCailable Eor use in emer"en%ies
su%h as spills or Eire' IE respirator= prote%tion is reHuire&# institute a %omplete respirator= prote%tion pro"ram in%lu&in" sele%tion#
Eit testin"# trainin"# maintenan%e an& inspe%tion'
RESPIRATOR) PROTECT$ RECOMMENDATIONS FOR +EN0ENE .APOUR CONCENTRATIONS:
A+ AN9 >E+EC+A!LE CANCEN+RA+IAN: .elE%ontaine& breathin" apparatus ;ith a Eull Ea%epie%e an& operate& in a
pressure&eman& or other positiCepressure mo&e' .upplie&air respirator ;ith a Eull Ea%epie%e an& operate& in pressure
&eman& or other positiCepressure mo&e in %ombination ;ith an auGiliar= selE%ontaine& breathin" apparatus operate& in
pressure&eman& or other positiCepressure mo&e' E.CAPE: AirpuriE=in" Eull Ea%epie%e respirator ,"as mask/ ;ith a %hinst=le
or Eront or ba%kmounte& or"ani% Capour %anister'Appropriate es%apet=pe selE%ontaine& breathin" apparatus'
E)E1FACE PROTECTION :
Chemi%al saEet= "o""les' A Ea%e shiel& ma= also be ne%essar='
S*IN PROTECTION :
ImperCious "loCes# %oCeralls# boots# an&-or other resistant prote%tiCe %lothin"' HaCe a saEet= sho;er-e=e;ash Eountain rea&il=
aCailable in the imme&iate ;ork area' An imperCious Eullbo&= en%apsulatin" suit an& respirator= prote%tion ma= be reHuire& in
some operations' Dork %lothes shoul& be %han"e& at least t;i%e ;eekl='
RESIST$ FOR PROTECTI.E CLOTHIN- 2-3idelines #o% %elated mate%ials$4
1ER9 (AA>: 1iton (AA>: N!R PAAR: !ut=l rubber# natural rubber# neoprene#nitrile rubber# pol=eth=lene# pol=urethane# P1A#
P1C NA+E: Resistan%e oE spe%iEi% materials %an Car= Erom pro&u%t to pro&u%t' ECaluate resistan%e un&er %on&itions oE use an&
maintain %lothin" %areEull='
PERSONAL PROTECTION COMMENTS
RemoCe %ontaminate& %lothin" promptl=' Keep %ontaminate& %lothin" in %lose& %ontainers' >is%ar& or laun&er beEore
re;earin"' InEorm laun&r= personnel oE %ontaminantMs ha$ar&s' >o not smoke# eat or &rink in ;ork areas'
FLAMMA+ILIT):
Hi"hl= Elammable'
EN.IRONMENT:
Pollutant' Contain'
No Data in IDENTIFICATION means data not applia!le in t"is #ield$ In all ot"e% #ields& it means not a'aila!le
SECTION 4 SAFE HANDLING INFORMATION
STORA-E AND TRANSPORT:
STORA-E CONDITIONS .tore in a %ool# &r=# ;ellCentilate& area# out oE &ire%t sunli"ht# a;a= Erom in%ompatible materials an& heat
an& i"nition sour%es'.tore in suitable# labelle& %ontainers' Keep ti"htl= %lose& ;hen not in use an& ;hen empt=' Prote%t Erom
&ama"e' )se suitable# approCe& stora"e tanks# buil&in"s# rooms an& %abinets' Consi&er leak &ete%tion an& alarm s=stems# as
reHuire&' )se nonsparkin" Centilation s=stems an& ele%tri%al eHuipment that &oes not proCi&e an i"nition sour%e' IE storin"
small Huantities un&er reEri"eration# use an approCe&# eGplosionprooE reEri"erator' Limit Huantit= oE material in stora"e' Restri%t
a%%ess to stora"e area' Post ;arnin" si"ns ;hen appropriate' Keep stora"e area separate Erom populate& ;ork areas'
Inspe%t perio&i%all= Eor &eEi%ien%ies su%h as leakin" %ontainers' Compl= ;ith all appli%able re"ulations Eor the stora"e an&
han&lin" oE Elammable materials'
HANDLIN- )se approCe& Elammable liHui& stora"e %ontainers in the ;ork area'
(roun& &rums an& bon& transEer %ontainers' ,(roun&in" %lips must %onta%t bare metal'/ Keep material a;a= Erom sparks# Elames
an& other i"nition sour%es' Post JNA .MAKIN(J si"ns in area oE use' >o not use near ;el&in" operations# Elames# or hot
surEa%es' PreCent release oE Capours into ;orkpla%e air' )se smallest possible amounts in &esi"nate& areas ;ith
a&eHuate Centilation' HaCe emer"en%= eHuipment ,Eor Eires# spills# leaks# et%'/ rea&il= aCailable' Label %ontainers' Keep
%ontainers %lose& ;hen not in use' Empt= %ontainers ma= %ontain resi&ues ;hi%h are ha$ar&ous' Not to be loa&e& ;ith Class
4# 8'4# 8'?# 7'8# *'4# *'8# 6L# 5' ,L ;here Elammable liHui& is nitromethane/'
Pa5a6in6 and La!ellin6:
As reHuire& b= the A>( Co&e'
As reHuire& b= the .tan&ar& Eor the )niEorm .%he&ulin" oE >ru"s an& Poisons'
SPILLS AND DISPOSAL:
PRECAUTIONS Restri%t a%%ess to area until %ompletion oE %leanup' Ensure %leanup is %on&u%te& b= traine& personnel onl='
Dear a&eHuate personalprote%tiCe eHuipment' 1entilate area' EGtin"uish or remoCe all i"nitionsour%es' NotiE= authorities'
CLEANUP >o not tou%h spille& material' PreCent material Erom enterin" se;er or %onEine& spa%es' .top or re&u%e leak iE saEe to
&o so' Contain spill ;ith earth# san&# or absorbent material ;hi%h &oes not rea%t ;ith spille& material' .mall spills: .oak up spill
;ith absorbent material ;hi%h &oes not rea%t ;ith spille& %hemi%al' Put material in suitable# %oCere&# labelle& %ontainers' 6lush
area ;ith ;ater' Contaminate& absorbent material ma= pose the same ha$ar&s as the spille& pro&u%t' Lar"e spills: Conta%t Eire
an& emer"en%= serCi%es an& supplier Eor a&Ci%e'
DISPOSAL ReCie; Ee&eral# state an& lo%al "oCernment reHuirements prior to &isposal' >isposal b= %ontrolle& in%ineration ma=
be a%%eptable'
FIRE1E/PLOSION HA0ARD:
6IRE EX+IN()I.HIN( A(EN+. >r= %hemi%al# Eoam# %arbon &ioGi&e Dater ma= be ineEEe%tiCe &ue to the lo; Elash point'
6IRE 6I(H+IN( PRACE>)RE. )se ;ater to keep EireeGpose& %ontainers %ool'
1apours are heaCier than air an& %an a%%umulate at "roun& leCelB Capours ma= traCel %onsi&erable &istan%e to sour%e oE
i"nition an& Elashba%k'
CAM!).+IAN PRA>)C+. Carbon monoGi&e an& %arbon &ioGi&e
PRA+EC+I1E CLA+HIN( 6ireEi"hters to ;ear Eull bo&= prote%tiCe %lothin" ;ith breathin" apparatus'
CAN.I>ER E1AC)A+IN( AREA
Reati'it7 Data:
.+A!ILI+9 Normall= stable
INCAMPA+I!ILI+9 MA+ML. +A A1AI> .+RAN( AXI>ININ( A(EN+. ,e'"' %hlorine#
bromine# pentaEluori&e# %hlorine triEluori&e# &iborane# nitri% a%i&# nitr=l
per%hlorate# liHui& oG="en# o$one# silCer per%hlorate/ Ma= rea%t
eGplosiCel='
HANAR>A). PAL9MERINA+IAN >oes not o%%ur
CARRA.I1I+9 +A ME+AL. Not %orrosiCe
+his M.>. summaries our best kno;le&"e oE the health an& saEet= ha$ar& inEormation oE the pro&u%t an& ho; to saEel=
han&le an& use the pro&u%t in the ;orkpla%e' Ea%h user shoul& rea& this M.>. an& %onsi&er the inEormation in the
%onteGt oE ho; the pro&u%t ;ill be han&le& an& use& in the ;orkpla%e in%lu&in" its use in %onIun%tion ;ith other pro&u%t' IE
%lariEi%ation or Eurther inEormation is nee&e& to ensure that an appropriate risk assessment %an be ma&e# the user shoul&
%onta%t AIaG Chemi%als' Aur responsibilit= Eor pro&u%ts sol& is subIe%t to our stan&ar& term an& %on&itions# a %op= oE
;hi%h is sent to our %ustomers an& is also aCailable on reHuest'