SULIT

4541/1
Kimia
Kertas 1
September
2006
1 jam

PEPERIKSAAN PERCUBAAN SPM 2006
MAKTAB RENDAH SAINS MARA




KIMIA

Kertas 1

Satu jam lima belas minit



JANGAN BUKA KERTAS SOALAN INI SEHINGGA DIBERITAHU


1. Kertas soalan ini adalah dalam dwibahasa.

2. Soalan di halaman kiri adalah dalam bahasa Melayu. Soalan di halaman kanan
adalah yang sepadan dalam bahasa Inggeris.

3. Calon dikehendaki membaca maklumat di halaman 2 atau halaman 3

















Kertas soalan ini mempunyai 47 halaman bercetak
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4541/1 2006 Hak Cipta MARA [Lihat sebelah
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3
INFORMATION FOR CANDIDATES

1. This question paper consists of 50 questions.

2. Answer all questions.

3. Answer each question by blackening the correct space on the answer sheet.

4. Blacken only one space for each question.

5. If you wish to change your answer, erase the blackened mark that you have made.
Then blacken the space for the new answer.

6. The diagrams in the questions provided are not drawn to scale unless stated.

7. You may use a non-programmable scientific calculator.
































4541/1 2006 Hak Cipta MARA [Lihat sebelah
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Question 1 to Question 50, are followed by four options A, B, C, and D. Choose the best
option for each question and blacken the corresponding space on the objective answer sheet.

1 The diagram shows the apparatus set up to investigate Process X.












What is Process X?

A Diffusion
B Condensation
C Evaporation
D Sublimation

2 Which of the following is the common characteristic for isotope s of an element?

A Physical properties
B Chemical properties
C Nucleon number
D Number of neutrons

3 What is the definition of a mole?

A The volume occupied by 6.02 X 10
23
particles
B The atomic mass of a substance which consist of 6.02 X 10
23
atoms
C The molecular mass of a substance which consist of 6.02 X 10
23
molecules
D The quantity of a substa nce which has the same number of particles as the
number of atoms in 12.00 g of carbon-12




nitrogen dioxide
(brown)
nitrogen dioxide
(brown)

Process
X
Gas jar cover
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4 The diagram shows an electrochemical cell.


What is the energy conversion involved?

A Electrical energy heat energy

B Chemical energy electrical energy

C Electrical energy chemical energy

D Chemical energy heat energy

5 The diagram shows the flow of ammonia gas into distilled water which contains a few
drops of phenolphthalein


Which of the following is the correct observation?
A Solution remains colourless
B Solution turns from red to purple
C Solution turns from green to red
D Solution turns from colourless to pink





4541/1 2006 Hak Cipta MARA [Lihat sebelah
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6 Which of the following is the main usage of the product in Haber Process?

A To produce pesticides
B To produce paint
C To produce detergent
D To produce fertilizers


7 Propane and propene are members of different homologous series.
Which of the following is the general formulae representing the two compounds?

Propane Propene
A C
n
H
2n
C
n
H
2n+2

B CnH2n+2 CnH2n
C C
2n
H
n+2
C
n
H
2n+1

D C
n
H
2n+1
C
n
H
2n+2


8 The equation below represents the fermentation reaction



What is substance Y?

A Ethanol
B Glucose
C Glycerol
D Ethanoic acid

9 Penicillin is used for

A reducing anxiety
B reducing pain
C controlling the level of glucose in blood
D destroying or preventing the growth of bacteria




C
6
H
12
O
6
? Y + CO
2

4541/1 2006 Hak Cipta MARA [Lihat sebelah
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11

10 The diagram shows a label on a bottle of Orange Juice XYZ.









What is the function of sulphur dioxide?

A To make the drink more concentrated
B To give colour to the drink
C To give orange flavour to the drink
D To make the drink last longer

11 Which of the following substance consists of free atoms?

A Nitrogen gas
B Xenon gas
C Glucose powder
D Sodium chloride

12 The diagram shows the molecular formula for glucose.



Which of the following substance has similar empirical formula as that of glucose?









Substance Molecular Formula
A Ethanol C
2
H
6
O
B Ethanal C
2
H
4
O
C Ethanoic acid C
2
H
4
O
2

D Methyl ethanoate C
3
H
6
O
2

Orange Juice XYZ

Ingredients: water, sugar, ascorbic acid, sulphur dioxide,
aspartame, E110, E102, vitamin A and D.

Best before: 15 Dec 2006
C
6
H
12
O
6

4541/1 2006 Hak Cipta MARA [Lihat sebelah
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13

13 The table shows observations for the reaction between ethanoic acid and magnesium.

Reaction Observation
Magnesium powder + glacial ethanoic acid No changes
Magnesium powder + glacial ethanoic acid + water Effervescence

Which of the following explains the observation?

A Acetic acid dissolves in water producing hydrogen gas
B Acetic acid ionises to produce hydrogen ions in the presence of water
C Water ionises to hydrogen ions and react with magnesium
D Acetic acid ionises to hydrogen ions which combine with each other to form
hydrogen gas

14 The table shows information about two acids
Acid Concentration pH
Sulphuric acid 0.01 mol dm
-3
1.1
Hydrochloric acid 0.01 mol dm
-3
2.0
.
Which of the following statement is true?
A Sulphuric acid is more concentrated than hydrochloric acid
B Sulphuric acid is a strong acid while hydrochloric acid is a weak acid
C Concentration of H
+
ions in sulphuric acid is higher than that of
hydrochloric acid
D Sulphuric acid ionises completely while hydrochloric acid ionizes partially in
water









4541/1 2006 Hak Cipta MARA [Lihat sebelah
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15

15 Figure shows the atomic arrangement in an alloy.









This alloy is harder than its pure metal because

A arrangement of atoms in alloy is more orderly
B vibration of atoms in alloy is more vigorous
C layers of atoms in alloy is less able to slide
D absence of empty spaces between atoms in alloy

16 The diagram shows vases made from pewter.









Which of the following is the main metal used to produce pewter?

A Tin
B Copper
C Antimony
D Aluminium







X Atom
Y Atom
Z Atom
4541/1 2006 Hak Cipta MARA [Lihat sebelah
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17

17 The diagram shows the chemical cha nge that occurs to compound G.








Which of the following is compound G?

A n- butane
B But - 1 - ene
C But - 2 - ene
D Butan - 2 - ol

18 Below is a list of chemicals used by a student to prepare ethyl ethanoate.

2 cm
3
concentrated sulphuric acid
10 cm
3
aqueous solution of ethanoic acid 2.0mol dm
-3

15 cm
3
pure ethanol

The mixture was heated under reflux for 30 minutes. At the end of the preparation the
student failed to detect the presence of ethyl ethanoate.
Which of the following causes the failure?

A Pure ethanoic acid is not used
B The amount of sulphuric acid used is not enough
C 30 cm
3
of pure ethanol should have been used
D Longer duration of heating under reflux is needed

19 Rusting causes a lot of financial loss.
Which of the following is rust?

A Zink oxide
B Iron(II) oxide
C Iron(III) oxide
D Lead(II) oxide



G
Bromine in CCl
4

H Br Br H

H - C - C - C - C - H

H H H H
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19

20 The diagram shows the structure of a soap ion.








Which of the following is true about M when soap is used to clean greasy stain?

A M is alkaline
B M is hydrophilic
C Soluble in grease
D Reduce the surface tension of water

21 The diagram shows the particle arrangement of substance X at 100
O
C.












Which is the most probable melting and boiling points for X?

Melting point /
O
C Boiling point /
O
C
A -123 -78
B -17 135
C 0 78
D 111 400





M N
Particle of X
4541/1 2006 Hak Cipta MARA [Lihat sebelah
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21
22 The diagram shows the position of elements P, Q, R and S in the Periodic Table of
Elements.


R
P S
Q



What characteristics of P, Q, R and S?


P Q R S
A Metal Non-metal Inert gas
Transition
element
B Non-metal Inert gas Metal
Transition
element
C Metal
Transition
element
Non-metal Inert gas
D Inert gas Non-metal
Transition
element
Metal

23 Element T has the following characteristics :





Element T could be

A Rubidium
B Silicon
C Manganese
D Magnesium
24 The table shows information about atoms of elements X, Y and Z.

Element Proton Number
X 11
Y 14
Z 17

Based on the information given, it can be expected that

A the atomic radius decreases from X to Z
B the density of atom decreases from X to Z
C elements X, Y and Z are in Period 2 of the Periodic Table
D X oxide is acidic, Y oxide is amphoteric and Z oxide is basic
High melting and boiling points.
Forms compounds with various oxidation numbers.
T oxide acts as catalyst.
4541/1 2006 Hak Cipta MARA [Lihat sebelah
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25 The diagram shows the formation of a compound.


+

The bond in the compound is formed by

A donation of electrons
B sharing of electrons
C receiving of electrons
D exchanging of electrons

26 M is an ionic compound and dissolves in water to form a solution that conducts
electricity.
Which of the following could be compound M?

A Sodium chloride
B Hydrogen chloride
C Carbon disulphide
D Lead(II) chloride

27 Which of the following equation represents the most suitable reaction to prepare an
insoluble salt?

A

Pb(OH)
2
+ 2HCl PbCl
2
+ 2H
2
O
B Pb + H2SO4 PbSO4 + H2
C AgNO
3
+ NaCl AgCl + NaNO
3

D CaO + H
2
SO
4
CaSO
4
+ H
2
O










Carbon
Chlorine Tetrachloromethane
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25
28 The diagram shows the set-up of the apparatus for a Voltaic cell.


Which of the following is true about the Voltaic cell?

I The aluminium strip becomes thinner
II Aluminium is the positive terminal
III Brown solid deposited at the copper strip
IV Bubbles of colourless gas formed at the copper strip
A I and IV only
B II and IV only
C I and III only
D I, II and III only

29 The diagram shows a sports equipment in which the frame is made from a composite
material.





Which of the following is the property of the composite material?

A High tensile strength
B Hard and brittle
C Heat resistant
D Transparent







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30 The chemical equation shows a reaction between calcium carbonate with hydrochloric
acid.



Which of the following changes cannot be used to determine the rate of reaction?

A Change in the pH of the mixture
B Decrease in mass of calcium carbonate
C Increase in mass of calcium chloride
D Change in volume of carbon dioxide released

31 The equation shows the reaction between zink and hydrochloric acid.

Zn
(p)
+ 2HCl
(ak
) ZnCl
2(ak)
+ H
2(g)

Which of the following statements are true about the reaction?

I The mass of zinc decreases with time
II pH of hydrochloric acid increases with time
III Rate of hydrogen gas released increases with time
IV Frequency of collisions between H
+
ions and zinc atoms decreases with time
A I and III only
B III and IV only
C I, II and IV only
D II, III and IV only












CaCO
3
+ 2HCl ? CaCl
2
+ CO
2
+ H
2
O
4541/1 2006 Hak Cipta MARA [Lihat sebelah
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32 In an experiment, 100 cm
3
of 1.0 mol dm
-3
hydrochloric acid reacts with excess
magnesium to produce hydrogen gas.
The graph of the volume of hydrogen gas against time is drawn and curve X is
obtained.


If the experiment is repeated using another solution, which solution will produce
curve Y?

A 50 cm
3
of 1.0 mol dm
-3
nitric acid
B 50 cm
3
of 1.0 mol dm
-3
ethanoic acid
C 25 cm
3
of 1.0 mol dm
-3
sulphuric acid
D 25 cm
3
of 1.0 mol dm
-3
hydrochloric acid

33 The diagram shows the structural formula for a compound extracted from pineapple.


Which of the following are needed to produce the compound synthetically?

Alcohol Carboxylic acid
A n- butanol Propanoic acid
B Ethanol Butanoic acid
C Ethanol Propanoic acid
D n- butanol Ethanoic acid






Volume of hydrogen, cm
3
4541/1 2006 Hak Cipta MARA [Lihat sebelah
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34 The diagram shows the apparatus set-up of an experiment to study redox reaction.
After 20 minutes, the colourless solution around electrode X changes to brown while
the solution around electrode Y changes from orange to green.


Which of the following statement explains the observation of the experiment?

A Iodide ions are oxidized to iodine molecules.
B Oxidation number of iodine increases from 0 to +1.
C Electron flows from electrode Y to electrode X through the external circuit
D Oxidation number of chromium decreases from +6 to +2

35 The table shows the observations of an experiment involving heating of two
substances.

Substances Observation
Carbon powder and metal P oxide Glow
Hydrogen gas and metal Q oxide Glow
Hydrogen gas and metal P oxide No changes

Which of the following is in ascending order for the reactivity of elements towards
oxygen?

A Carbon, P, hydrogen, Q
B Q, hydrogen, P, car bon
C Hydrogen, P, carbon, Q
D Hydrogen, Q, carbon, P




4541/1 2006 Hak Cipta MARA [Lihat sebelah
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36 Diagram shows an experiment carried out for iron(II) sulphate.

Which of the following is solution X?

A Potassium chloride solution
B Potassium bromide solution
C Sodium hydroxide solution
D Acidified potassium manganate(VII) solution

37 The diagram shows the energy profile for the formation of T from R and S.









What is the activation energy for the reaction?

A y kJ mol
-1

B (x + y) kJ mol
-1

C x kJ mol
-1

D (x-y) kJ mol
-1



x kJ mol
-1
R + S
T y kJ mol
-1
Energy
4541/1 2006 Hak Cipta MARA [Lihat sebelah
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38 The diagram shows the electron arrangement in an atom of elements P and Q.


What is the formula and type of bond for the compound formed when P reacts with
Q?

Formula Bond
A PQ
2
Ionic
B PQ
4
Ionic
C PQ Covalent
D PQ
4
Covalent

39 The equation represents the redox reaction between ammonia and copper(II) oxide.

2 NH
3
+ 3CuO ? N
2
+ 3 Cu + 3H
2
O

Which of the following is true about the reaction?

A Ammonia is an oxidizing agent
B Nitrogen is a reducing agent
C Oxidation number of copper decreases from +2 to 0
D Oxidation number of hydrogen increases from -1 to +1

40 The table shows two experiments carried out to investigate the reaction between
calcium nitrate and sodium carbonate solution.

Calcium nitrate
solution
Sodium carbonate
solution
Experiment
Volume
(cm
3
)
Concentration
(mol dm
-3
)
Volume
(cm
3
)
Concentration,
(mol dm
-3
)
Decrease in
temperature,
0
C
I 100.0 1.0 100.0 1.0 6.0
II 50.0 2.0 50.0 2.0 X

What is the value of X?

A 1.5
0
C

B 3.0
0
C

C 6.0
0
C

D 12.0
0
C
4541/1 2006 Hak Cipta MARA [Lihat sebelah
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37
R
2
_

41 The diagram shows an electron arrangement of R
2-
ion.








How many protons and electrons does anatom of R contain?







42 Nitrogen exists as diatoms.
What is the mass of one nitrogen molecule?
Given that the relative atomic mass of N = 14; Avogadro constant = 6 x 10
23
mol
-1


A 2.1 x 10
-23
g
B 2.3 x 10
-23
g
C 4.7 x 10
-23
g
D 28 x 10
-23
g




















Protons Electrons
A 8 6
B 8 10
C 10 10
D 8 8
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43 An experiment is carried out to study the effect of concentration on the rate of
reaction between sodium thiosulphate and hydrochloric acid.
Graph of the concentration of sodium thiosulphate against 1/time is as shown.



Based on the graph, what is the value of t if the experiment is repeated using sodium
thiosulphate solution 0.025 mol dm
-3
.

A 32.3 s
B 50.0 s
C 0.020 s
D 0.031s

44 What is the volume of distilled water required to be added to 25.0 cm
3
of
0.5 mol dm
-3
sulphuric acid in order to produce a solution of 0.1 mol dm
-3
?

A 75.0 cm
3

B 100.0 cm
3

C 125.0 cm
3

D 150.0 cm
3



4541/1 2006 Hak Cipta MARA [Lihat sebelah
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41
45 The following shows the energy level diagram of a reaction.

Energy
Zn + Cu
2+


H = - 190 kJ/mol

Zn
2+
+ Cu


Which of the following statements are true about the reaction?

I Zinc is oxidized
II The reaction is exothermic
III The temperature decreases during the reaction
IV 95 kJ of heat is released when 0.5 mole of copper is displaced
A I and III only
B II and IV only
C III and IV only
D I, II and IV only

46 4.60 g of sodium is burnt in excess chlorine gas. The equation for the reaction is as
follows:

2Na (p) + Cl
2
(g) 2NaCl (p)

The product is dissolved in water to produce 250.0 cm
3
of solution.
What is the molarity of the solution?
Given that the relative atomic mass of Na = 23.

A 0.05 mol dm
-3
B 0.20 mol dm
-3

C 0.40 mol dm
-3

D 0.80 mol dm
-3











4541/1 2006 Hak Cipta MARA [Lihat sebelah
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47 The table shows the voltmeter readings when a pair of different metal electrodes are
dipped into the copper(II) nitrate solution.

Metal electrode
Positive terminal Negative terminal
Voltmeter reading (V)
P S 2.8
P Q 0.8
R S 1.2
Q R Y

What is the value of Y?

A 0.8
B 1.0
C 1.6
D 2.0

48 Copper(II) carbonate decomposes when heated strongly as represented by the
following equation.

CuCO
3
CuO + CO
2

What is the volume of carbon dioxide gas released when 0.62g copper(II)
carbonate is heated?
Given that the relative atomic mass of Cu = 64, C = 12, O = 16 and 1 mol of gas
occupies 24 dm
3
at room temperature and pressure.

A 120 cm
3
B 240 cm
3

C 480 cm
3

D 640 cm
3











4541/1 2006 Hak Cipta MARA [Lihat sebelah
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45

49 The diagram shows the set-up of apparatus for the electrolysis of sodium chloride
solution 1.0 mol dm
-3
.


Which of the following observations are true about the electrolytic cell?

I Shiny grey solid deposited at the cathode
II Colourless gas is collected in the test tube at the cathode
III A greenish-yellow gas is collected in the test tube at the anode
IV A damp blue litmus paper decolourised when put into the test tube at the
anode
A I and II only
B I and III only
C I, III and IV only
D II, III and IV only

















4541/1 2006 Hak Cipta MARA [Lihat sebelah
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47


50 Information on methane and butane is shown in the following table.

Fuel
Relative
molecular
mass
Chemical equation
Heat of
Combustion
Methane 16 CH
4
+ 2O
2
CO
2
+ 2H
2
O -890 kJ mol
-1

Butane 58 C4H10 + 13/2 O2 4CO2 + 5H2O -2882 kJ mol
-1


Based on the information shown in the table, the conclusions are

I butane is more combustible than methane
II combustion of 1 g of methane produces more heat than 1 g of butane
III energy content of butane is higher than methane
IV combustion of 1 mole of butane produces more carbon dioxide than 1 mole of
methane
A I and III only
B I, II and IV only
C II, III and IV only
D I, II, III and IV















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NAMA: .

ANGKA GILIRAN: .








PEPERIKSAAN PERCUBAAN SPM 2006
MAKTAB RENDAH SAINS MARA


KIMIA

Kertas 2

Dua jam tiga puluh minit

JANGAN BUKA KERTAS SOALAN INI
SEHINGGA DIBERITAHU

1. Tuliskan nama dan angka giliran anda
pada ruang yang disediakan.

2. Kertas soalan ini adalah dalam
dwibahasa.

3. Soalan di halaman kiri adalah dalam
bahasa Mela yu. Soalan di halaman
kanan adalah dalam bahasa Inggeris.

4. Calon dibenarkan menjawab
keseluruhan atau sebahagian soalan
sama ada dalam bahasa Melayu atau
bahasa Inggeris.

5. Calon dikehendaki membaca maklumat
di halaman 2 dan halaman 3.

Kod Pemeriksa

Bahagian


Soalan

Markah
Penuh

Markah
Diperoleh
1 09
2 09
3 10
4 10
5 11


A

6 11
1 20
B 2 20
3 20
C 4 20
Jumlah





Kertas soalan ini mengandungi 51 halaman bercetak


4541/2
Kimia
Kertas 2
Sept
2006
2 jam
4541/2 2006 Hak Cipta

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SULIT 4541/2
4541/2 2006 Hak Cipta MARA [lihat sebelah
SULIT

2
MAKLUMAT UNTUK CALON

1. Kertas soalan ini mengandungi tiga bahagian: Bahagian A, Bahagian B dan
Bahagian C.

2. Jawab semua soalan dalam Bahagian A. Tuliskan jawapan bagi Bahagian A dalam
ruang yang disediakan dalam kertas soalan.

3. Jawap satu soalan daripada Bahagian Bdan satu soalan daripada Bahagian C.
Tuliskan jawapan bagi Bahagian Bdan Bahagian C pada halaman bergaris di
bahagian akhir kertas soalan ini. Jawab Bahagian Bdan Bahagian Cdengan
terperinci. Anda boleh menggunakan persamaan, gambar rajah, jadual, graf dan
cara lain yang sesuai untuk menjelaskan jawapan anda.

4. Tunjukkan kerja mengira, ini membantu anda mendapatkan markah.

5. Sekiranya anda hendak membatalkan sesuatu jawapan, buat garisan di atas jawapan
itu.

6. Rajah yang mengiringi soala n tidak dilukiskan mengikut skala kecuali dinyatakan.

7. Markah yang diperuntukkan bagi setiap soalan atau ceraian soalan ditunjukkan
dalam kurungan.

8. Masa yang dicadangkan untuk menjawab Bahagian A ialah 90 minit, Bahagian B
ialah 30 minit dan Bahagian C ialah 30 minit.

9. Anda dibenarkan menggunakan kalkulator saintifik yang tidak boleh diprogramkan.

10. Serahkan semua kertas jawapan anda di akhir peperiksaan.




















SULIT 4541/2
4541/2 2006 Hak Cipta MARA [lihat sebelah
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4
Bahagian A

[60 markah]

Jawab semua soalan dalam bahagian ini.
Masa yang dicadangkan untuk menjawab bahagian ini ialah 90 minit.

1 Rajah 1 menunjukkan simbol atom bagi unsur karbon dan oksigen.






RAJAH 1

Berdasarkan Rajah 1, jawab soalan-soalan berikut:

(a) Apakah yang diwakili oleh :

(i) nombor 12 bagi atom unsur C?

..................................................................................................................
[1 markah]

(ii) nombor 8 bagi atom unsur O ?

..................................................................................................................
[1 markah]

(b) (i) Apakah yang dimaksudkan dengan isotop?

..................................................................................................................

..................................................................................................................
[1 markah]

(ii) Nyatakan atom-atom yang merupakan isotop isotop bagi unsur yang
sama .

..................................................................................................................
[1 markah]

(iii) Tuliskan simbol atom bagi isotop lain untuk unsur yang dinyatakan
di (b)(ii).

..................................................................................................................
[1 markah]


Untuk
Kegunaan
Pemeriksa
1(b)(iii)



1(a)(i)



1(a)(ii)



1(b)(i)



1(b)(ii)



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6


(c) (i) Berapakah bilangan elektron bagi atom ?


.................................................................................................................
[1 markah ]

(ii) Tuliskan susunan elektron bagi atom di (c)(i).

..
[1 markah ]

(d) Karbon dan oksigenterletak dalam kala yang sama dalam Jadual Berkala.
Nyatakan kala tersebut dan jelaskan jawapan anda.

.............................................................................................................................

.............................................................................................................................
[2 markah ]































Untuk
Kegunaan
Pemeriksa
1(c)(i)



1(c)(ii)



1(d)


JUMLAH


SULIT 4541/2
4541/2 2006 Hak Cipta MARA [lihat sebelah
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8

2 Rajah 2 menunjukkan susunan radas bagi satu eksperimen untuk menentukan formula
empirik bagi satu oksida kuprum.


RAJAH 2

Berikut adalah data yang diperolehi daripada eksperimen tersebut:

Jisim kuprum oksida = 2.00 g
Jisim logam kuprum = 1.60 g

(a) Apakah yang dimaksudkan dengan formula empirik?

......
[1 markah]

(b) Namakan satu bahan yang boleh digunakan untuk mengeringkan gas hidrogen.

..
[1 markah]

(c) Mengapakah gas hidrogen kering perlu dilalukan ke dalam tabung pembakaran
selama beberapa minit sebelum pemanasan dimulakan?

......
[1 markah]















Untuk
Kegunaan
Pemeriksa
2(a)


2(b)


2(c)


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(d) Bagaimanakah anda boleh memas tikan tindak balas ini telah lengkap?

.....
[1 markah ]

(e) Berdasarkan keputusan di atas,

(i) hitungkan bilangan mol atom kuprum dan bilangan mol atom oksigen
yang bertindak balas.
Diberi jisim atom relatif bagi O = 16 dan Cu = 64.
[2 markah ]










(ii) Tentukan nisbah teringkas bilangan molatom kuprum kepada bilangan
mol atom oksigen.
[1 markah ]





(iii) Apakah formula empirik bagi oksida kuprum ini?

..................................................................................................................
[1 markah ]

(f) Mengapakah formula empirik oksida magnesium tidak boleh ditentukan
dengan kaedah di atas?

...
[1 markah ]










2(d)


2(e)(i)


2(e)(ii)


2(e)(iii)


2(f)


JUMLAH


Untuk
Kegunaan
Pemeriksa
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3 Rajah 3 menunjukkan susunan radas bagi eksperimenpenentuan haba peneutralan.
25.0 cm
3
larutan asid nitrik 2.0 mol dm
-3
ditindakbalaskan dengan 25. 0 cm
3
larutan
kalium hidroksida 2.0 mol dm
-3
.






Sebelum
tindak balas











Selepas
tindak balas








Suhu maksimum = 43.5
o
C

RAJAH 3

(a) Cadangkansatu langkah berjaga-jaga yang perlu diambil semasa eksperimen
ini dijalankan.

..............................................................................................................................
[1 markah ]

(b) Nyatakan jenis tindak balas yang berlaku dari segi perubahan haba.

..............................................................................................................................
[1 markah ]




Larutan asid nitrik
Suhu awal = 30.0
o
C
Larutan kalium hidroksida
Suhu awal = 30.0
o
C
Termometer
Cawan
polistirena
Termometer
Campuran
larutan
Untuk
Kegunaan
Pemeriksa
3(a)


3(b)


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14



(c) Tuliskan persamaan kimia bagi tindakbalas yang berlaku.

..............................................................................................................................
[1 markah ]

(d) Hitungkan
(i) bilangan mol asid nitrik dan bilangan mol ka lium hidroksida






[1 markah ]

(ii) perubahan haba dalam eksperimen itu.
Diberi muatan haba tentu larutan ialah 4.2 Jg
-1

o
C
-1
dan ketumpatan
larutan ialah 1 g cm
-3








[1 markah ]

(iii) haba peneutralan bagi tindak balas itu.








H = _________________


[ 2 markah ]







Untuk
Kegunaan
Pemeriksa
3(c)


3(d)(i)


3(d)(ii)


3(d)(iii)


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16



(e) Lukiskan gambar rajah aras tenaga bagi tindak balas itu.


















[2 markah ]

(f) Ramalkan nilai haba peneutralan sekiranya asid nitrik digantikan dengan asid
etanoik untuk bertindakbalas dengan kalium hidroksida.

..............................................................................................................................
[1 markah ]





















Untuk
Kegunaan
Pemeriksa
3(e)


3(f)


JUMLAH


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18

4 Jadual 4 menunjukkan data yang diperoleh oleh seorang pelajar daripada satu
eksperimen untuk mengkaji kadar penguraian hidrogen peroksida menggunakan
mangkin mangan(IV) oksida.

Masa (s) 0 30 60 90 120 150 180 210 240 270
Isipadu gas
oksigen (cm
3
)
0.00 18.00 31.00 39.00 43.00 46.00 48.00 49.00 50.00 50.00
JADUAL 4

(a) Lukiskan gamba r rajah berlabel susunan radas bagi eksperimen itu.
[2 markah ]














(b) Tuliskan persamaan kimia bagi penguraian hidrogen peroksida.

..............................................................................................................................

[1 markah ]

(c) 2.0 g serbuk mangan(IV) oksida telah digunakan pada awal eksperimen dan
didapati jisim mangan(IV) oksida tidak berubah pada akhir tindakbalas.
Terangkan mengapa.

..............................................................................................................................

..............................................................................................................................
[1 markah ]

(d) Mengapakah mangan(IV) oksida digunakan dalam bentuk serbuk?

..............................................................................................................................
[1 markah ]




Untuk
Kegunaan
Pemeriksa
4(a)


4(b)


4(c)


4(d)


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20
(e) (i) Gunakan data dalam Jadual 4 untuk melukis graf isipadu gas oksigen melawan
masa pada kertas graf di bawah.
[ 3 markah ]















































Untuk
Kegunaan
Pemeriksa
4(e)(i)


Graf isipadu gas oksigen melawan masa
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22
(ii) Berdasarkan graf di (e)(i), hitungkan kadar tindak balas pada masa 90 saat
dan tunjukkan tangen pada graf di (e)(i).












[ 2 markah ]



































4(e)(ii)


Untuk
Kegunaan
Pemeriksa
JUMLAH


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4541/2 2006 Hak Cipta MARA [lihat sebelah
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24
5 Rajah 5 menunjukkan susunan radas tindak balas melibatkan pemindahan elektron
pada suatu jarak antara larutan kalium iodida dengan air bromin.


RAJAH 5

Merujuk kepada tindakbalas di atas, jawab soalan berikut:

(a) Nyatakan warna air bromin.

..............................................................................................................................

[1 markah ]

(b) Namakan bahan yang dioksidakan dalam tindakbalas.

..............................................................................................................................
[1 markah ]

(c) Nyatakan arah pengaliranelektron bagi tindakbalas ini.

..............................................................................................................................
[1 markah ]

(d) Nyatakan perubahan nombor pengoksidaanbagi

(i) iodin

.................................................................................................................

(ii) bromin

.................................................................................................................
[2 markah ]
Untuk
Kegunaan
Pemeriksa
5(a)


5(c)


5(b)


5(d)


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26
(e) Tuliskan persamaan ion keseluruhan bagi tindakbalas ini.

..............................................................................................................................
[1 markah ]

(f) Satu larutan berwarna perang terbentuk di sekitar elektrod P.
(i) Terangkan dengan ringkas bagaimana anda menentusahkan larutan itu.

..................................................................................................................

..................................................................................................................

..................................................................................................................
[2 markah ]

(ii) Terangkan bagaimana larutan tersebut dihasilkan.


..................................................................................................................

..................................................................................................................

..................................................................................................................
[2 markah ]

(g) Apakah yang akan diperhatikan pada bacaan galvanometer jika air bromin
pada bahagian Q digantikan dengan air klorin?

..............................................................................................................................
[1 markah ]




















Untuk
Kegunaan
Pemeriksa
5(e)


5(g)


5(f)(ii)


5(f)(i)


JUMLAH


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28

6 Rajah 6 menunjukkan carta alir bagi penukaran propena kepada polipropena, propana
dan propanol.











RAJAH 6

(a) Namakan siri homolog bagi propena.

.............................................................................................................................
[1 markah ]

(b) Lengkapkan persamaan kimia untuk Proses I dengan melukis formula struktur
bagi polipropena







[1 markah ]

(c) Tuliskan persamaan kimia bagi mewakili pr oses II.

..............................................................................................................................
[1 markah ]

(d) Propena dan propana terbakar dalam oksigen.

(i) Tuliskan persamaan kimia bagi salah satu tindak balas pembakaran ini
dalam oksigen berlebihan.

..................................................................................................................
[1 markah ]






Polipropena
Propana Propena Propanol
Proses
I
Proses II
Proses III
Untuk
Kegunaan
Pemeriksa
6(a)


6(b)


6(c)


6(d)(i)


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(ii) Bandingkan kejelagaan pembakaran propena dan propana.
Terangkan jawapan anda.
Diberi jisim molekul relatif: propena = 42 dan propana = 44.







..................................................................................................................

..................................................................................................................

..................................................................................................................
[3 markah ]

(e) (i) Terangkan bagaimana anda menjalankan Proses III.
..................................................................................................................

..................................................................................................................

..................................................................................................................
[3 markah ]

(ii) Tuliskan persamaan kimia bagi Proses III.
..................................................................................................................
[1 markah ]















Untuk
Kegunaan
Pemeriksa
6(d)(ii)


6(e)(ii)


6(e)(i)


JUMLAH


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32

Bahagian B

[20 markah]

Jawab mana-mana satu soalan.
Masa yang dicadangkan untuk menjawab bahagian ini ialah 30 minit

7 (a) Unsur-unsur dalam kumpulan yang sama dalam Jadual Berkala Unsur
mempunyai kereaktifan yang berbeza.





Terangkan mengapa dua logam ini mempunyai kereaktifan yang berbeza.
[4 markah ]

(b) Rajah 7.1 menunjukkan susunan radas satu eksperimen yang dijalankan untuk
mengkaji perubahan kimia yang berlaku ke atas logam kalium.






Logam kalium dibakar
dalam balang gas berisi
oksigen
Hasil tindak balas
dicampur air
Larutan X terhasil
RAJAH 7.1

(i) Persamaan kimia di bawah menunjukkan tindakbalas antara logam
kalium dengan gas oksigen.



Diberi, jisim atom relatif K = 39, O = 16.
Hitungkan jisim kalium oksida yang terhasil jika 3.9 g kalium
bertindak balas dengan gas oksigen berlebihan pada keadaan bilik.
[4 markah ]

(ii) Namakan larutan X dan tuliskan persamaan kimia bagi
pembentukannya.
Tindak balas kalium dengan oksigen lebih cergas daripada
tindak balas litium dengan oksigen
4K + O
2
2K
2
O
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34

(c) (i) Jadual 7.2menunjukkan keputusan ujian untuk membezakan
kekonduksian dua sebatian yang berlainan.

Sebatian Kekonduksian Elektrik
Tetraklorometana ( CCl
4
) Tidak mengalirkan arus elektrik
Larutan natrium klorida( NaCl) Boleh mengalirkan arus elektrik
JADUAL 7.2

Terangkan mengapa terdapat perbezaan kekonduksian elektrik itu.
[4 markah ]

(ii) Jadual 7.3 menunjukkan keputusan proses elektrolisis ke atas dua
larutan yang berlainan menggunakan elektrod karbon.






JADUAL 7.3

Terangkan mengapa terdapat perbezaan hasil di katod.
[6 markah ]
























Larutan Hasil di katod Hasil di anod
Natrium klorida 1.0 mol dm
-3
Hidrogen Klorin
Kuprum(II) klorida 1.0 mol dm
-3
Kuprum Klorin
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36


8


(a) Terangkan fungsi steroid anabolik dan nyatakan tiga kesan sampingan yang
mungkin timbul akibat penyalahgunaan bahan ini.
[4 markah]

(b) Rajah 8.1 menunjukkan penghasilan baja Z dalam makmal dari tindakbalas
antara gas ammonia dan asid sulfurik cair.


RAJAH 8.1

(i) Namakan baja Z.
[1 markah]

(ii) Tuliskan persamaan kimia yang seimbang bagi penghasilan baja Z.
[2 markah]

(iii) Hitungkan isipadu gas ammonia yang bertindakbalas lengkap dengan
asid sulfurik jika 13.2 g baja Z dihasilkan,
Diberi jisim molar Z = 132 g mol
-1
dan isipadu molar gas ialah
24.0 dm
3
mol
-1
pada suhu dan tekanan bilik.
[3 markah]

















Steroid anabolik sering digunakan oleh para atlit untuk meningkatkan prestasi
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38


(c) Jadual 8. 2 menunjukkan dua eksperimen yang telah dijalankan ke atas lateks.

Eksperimen Susunan radas Pemerhatian


I




Pepejal putih
terhasil


II




Tiada perubahan
JADUAL 8.2

Huraikan dengan ringkas tentang perbezaan pemerhatian itu.

[5 markah ]

(d) Rajah 8.3 menunjukkan penggunaan beberapa polimer sintetik dalam
kehidupan harian.











RAJAH 8.3

Terangkan punca dan kesan pencemaran penggunaan polimer sintetik secara
berlebihan.
[5 markah ]
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40
[5 marks]
Bahagian C
[ 20 markah ]

Jawab mana-mana satu soalan.
Masa yang dicadangkan untuk menjawab bahagian ini ialah 30 minit

9



(a) Terangkanproses kimia yang berlaku dalam alat itu dan tuliskan persamaan
bagi tindakbalas yang terlibat.
[4 markah ]

(b) Rajah9 menunjukkan dua persamaan bagi tindak balas yang berbeza.














RAJAH 9

(i) Namakan sebatian R dan Q.

(ii) Banding dan bezakan tindakbalas I dan tindak balas II.
[ 6 markah ]

(c) Persamaan berikut menunjukkan pembentukan ester hasil daripada tindak
balas antara asid etanoik glasial dengan suatu alkohol.




Huraikan satu eksperimen bagaimana anda menyediakan suatu ester yang
dinamakan.

Nyatakan bagaimana anda mengesan ester yang terhasil dan tuliskan
persamaan kimia bagi tindakbalas itu.
[10 markah ]
Kandungan alkohol dalam udara hembusan pemandu yang mabuk
boleh dikesan menggunakan sejenis alat pengesan yang
mengandungi kalium dikromat(VI)
R + Br
2

Q + Br
2 + HBr


Tindak balas I


Tindak balas II
R + Br
2

Q + Br
2 + HBr
ALKOHOL + ASID ETANOIK GLASIAL ESTER + AIR
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42

10 (a) Cuka merupakan larutan asid etanoik cair.
Rajah 10 menunjukkan tindak balas apabila sebiji telur ayam dimasukkan ke
dalam cuka.


RAJAH 10

Terangkan pemerhatian ini dan sertakan persamaan bagi tindakbalas yang
terlibat.
[4 markah ]

(b) Label pada satu botol reagen yang mengandungi larutan X telah tertanggal.
Larutan X disyaki larutan plumbum(II) nitrat atau kalsium nitrat.

Huraikan ujian kimia yang sesuai untuk menentusahkanion-ion yang terdapat
dalam larutan X itu.
[6 markah ]

(c) Anda dikehendaki menyediakan garam zink sulfat yang kering.
Bahan kimia yang dibekalkan ialah:

larutan zink klorida
asid sulfurik cair
larutan natrium karbonat

Huraikan satu eksperimen makmal bagaimana anda dapat menyediakan garam
tersebut. Dalam huraian anda sertakan persamaan yang terlibat.
[10 markah ]



KERTAS SOALAN TAMAT


http://cikguadura.wordpress.com/
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44
RUANG JAWAPAN / SPACE FOR YOUR ANSWER

BAHAGIAN / SECTION: ......................... NO. SOALAN / QUESTION NO.: ............

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Untuk
Kegunaan
Pemeriksa/
For
Examiners
Use
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4541/2 2006 Hak Cipta MARA [lihat sebelah
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46
RUANG JAWAPAN / SPACE FOR YOUR ANSWER

BAHAGIAN / SECTION: ......................... NO. SOALAN / QUESTION NO.: ............

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Untuk
Kegunaan
Pemeriksa/
For
Examiners
Use
SULIT 4541/2
4541/2 2006 Hak Cipta MARA [lihat sebelah
SULIT

48
RUANG JAWAPAN / SPACE FOR YOUR ANSWER

BAHAGIAN / SECTION: ......................... NO. SOALAN / QUESTION NO.: ............

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Untuk
Kegunaan
Pemeriksa/
For
Examiners
Use
[Lihat sebelah
Nama : ..... No Giliran : ..

Kelas : ..

SULIT
Kimia
Kertas 3
September
2006
1 jam
PEPERIKSAAN PERCUBAAN SPM 2006
MAKTAB RENDAH SAINS MARA


KIMIA

Kertas 3
Satu jam tiga puluh minit


JANGAN BUKA KERTAS SOALAN INI
SEHINGGA DIBERITAHU

1. Tuliskan nama, angka giliran dan kelas
anda pada ruang yang disediakan.

2. Kertas soalan ini adalah dalam dwibahasa

3. Soalan di halaman kiri adalah dalam
bahasa Melayu. Soalan di halaman kanan
adalah yang sepadan dalam bahasa
Inggeris.

4. Calon dibenarkan menjawab keseluruhan
atau sebahagian soalan sama ada dalam
bahasa Melayu atau bahasa Inggeris.

5. Calon dikehendaki membaca maklumat di
halaman 2 dan halaman 3.











Kod
Pemeriksa


Soalan
Markah
Penuh
Markah
Diperoleh
1 15
2 18
3

17

Jumlah 50


Kertas soalan ini mempunyai 20 halaman bercetak.

INFORMATION FOR CANDIDATES
SULIT 4541/3 2006 Hak Cipta MARA
http://cikguadura.wordpress.com/
SULIT 4541/3

4541/3 SULIT
- 3 -
INFORMATION FOR CANDIDATES

1. This question paper consists of three questions. Answer all questions.

2. Write your answers for Question 1 and Question 2 in the spaces provided in the
question paper.

3. Write your answers for Question 3 on the lined pages at the end of the question
paper in detail. You may use equations, diagrams, tables, graphs and other suitable
methods to explain your answers.

4. Show your working, it may help you to get marks.

5. If you wish to cancel any answer, neatly cross out the answer.

6. The diagrams in the questions are not drawn to scale unless stated.

7. Marks allocated for each question or part question are shown in brackets.

8. The time suggested to complete Question 1 and Question 2 is 45 minutes and
Question 3 is 45 minutes.

9. You may use a non-programmable scientific calculator.

10. Hand in all your answer sheets at the end of the examination.



Marks awarded:

Score Description
3 Excellent: The best response
2 Satisfactory: An average response
1 Weak: An inaccurate response
0 No response or wrong response












SULIT 4541/3

4541/3 SULIT
- 5 -
Answer all questions.
The time suggested to answer Question 1 and Question 2 is 45 minutes.

1 A student has carried out an experiment to compare the products for electrolysis of
aqueous copper(II) chloride of different concentrations.
Figure shows the product at each electrode after the electrolysis has been carried out
for 20 minutes.
Cell I


Cell II



(a) Complete the following table by stating the observation at the anodes and its
corresponding inferences.

Cell Observation at the anode Inference
I










II










[6 marks]
For
Examiners
Use
1(a)

1(a)
SULIT 4541/3

4541/3 SULIT
- 7 -
(b) Identify the variables involved in this experiment.

Manipulatedvariable:



Responding variable:



Controlled variable:


[3 marks]


(c) State the hypothesis for this experiment.






[3 marks]


(d) What will be observed at the anode of Cell II if the exper iment is carried out
for three hours?




[3 marks]

















1(b)

1(c)

1(d)

For
Examiners
Use
SULIT 4541/3

4541/3 SULIT
- 9 -
2 A student carried out an experiment to determine the concentration of sodium
hydroxide. 20.00 cm
3
of aqueous sodium hydroxide and a few drops of
phenolphthalein is titrated using hydrochloric acid 0.50 mol dm
-3
from a burette.
Titration is stopped when the solution in the conical flask changes colour from pink
to colourless.
Experiment was repeated three times.
Figure shows the readings of the burette during titration.































(a) Record the burette readings in the spaces provided.
[3 marks]










Experiment 1 Experiment 2 Experiment 3
Initial
readings
of burette


.. cm
3



.. cm
3



.. cm
3

End point
readings


.. cm
3



.. cm
3



.. cm
3

2(a)

For
Examiners
Use
SULIT 4541/3

4541/3 SULIT
- 11 -
(b) Construct a table and record the initial reading, end point reading and
volume of hydrochloric acid used.















[3 marks]


(c) What is meant by the end point in the above experiment?




[3 marks]

(d) The chemical equation for the reaction is

NaOH + HCl ? NaCl + H
2
O

(i) What is the average volume of hydrochloric acid used?




(ii) Calculate the concentration of sodium hydroxide used in the
experiment.











[3 marks]
2(c)

2(d)

2(b)

For
Examiners
Use
SULIT 4541/3

4541/3 SULIT
- 13 -
(e) The experiment is repeated using aqueous barium hydroxide, Ba(OH)
2
.
Predict the volume of hydrochloric acid required to reach the end point.




[3 marks]


(f) The table shows the concentrations and the pH values of four different acids.
Based on the information, classify the acid into strong acid and weak acid .

Acid Concentration / mol dm
-3
pH
Nitric acid 0.10 1.1
Oxalic acid, 0.05 3.2
Sulphuric acid 0.05 1.0
Methanoic acid 0.10 3.5
























[3 marks]






2(e)

For
Examiners
Use
2(f)

SULIT 4541/3

4541/3 SULIT
- 15 -
3




Refering to the situation above, plan a laboratory exper iment to compare the
elasticity of prepared vulcanized and unvulcanized rubber.

Your planning must include the following items:
(i) Statement of the problem
(ii) All the variables
(iii) Hypothesis
(iv) Lists of substances and apparatus
(v) Procedure
(vi) Tabulation of data


[17 marks]









END OF QUESTION PAPER






















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