Copyright@Dominic Foo H82PLD - Plant Design CC - 2 The The The The Onion diagram Onion diagram Onion diagram Onion diagram Reactor Separation & recycle Heat exchange network Utilities (Linnhoff et al., 1982) Copyright@Dominic Foo H82PLD - Plant Design CC - 3 Lecture outline Lecture outline Lecture outline Lecture outline Single heat transfer unit vs. a network (multiple units) Heat transfer composite curves Hot & cold utility targets The famous name pinch analysis Copyright@Dominic Foo H82PLD - Plant Design CC - 4 Recommended texts Recommended texts Recommended texts Recommended texts Smith, R. (2005). Chemical Process Design and Integration. New York: John Wiley & Sons (heat exchanger network synthesis). Linnhoff, B., Townsend, D. W., Boland, D., Hewitt, G. F., Thomas, B. E. A., Guy, A. R., & Marshall, R. H. (1982). A User Guide on Process Integration for the Efficient Use of Energy. Rugby: IChemE (latest edition by Ian Kemp). Copyright@Dominic Foo H82PLD - Plant Design CC - 5 Evolution of heat recovery Evolution of heat recovery Evolution of heat recovery Evolution of heat recovery pinch analysis pinch analysis pinch analysis pinch analysis 1970s Minimum hot and cold utility targeting 1990 Energy-area trade off (Supertargeting) 1984 Surface area targeting 1993 Distillation column integration 1993 Total site analysis 1983 The pinch design method (PDM) 1989 Heat integration for batch processes Copyright@Dominic Foo H82PLD - Plant Design CC - 6 Some important terms Some important terms Some important terms Some important terms Hot streams Stream to be cooled Sources of heat Cold streams Stream to be heated Sinks of heat Supply temp initial T Target temp final T Supply T Q T Supply T Hot stream Target T Cold stream Target T Copyright@Dominic Foo H82PLD - Plant Design CC - 7 2 stream heat recovery 2 stream heat recovery 2 stream heat recovery 2 stream heat recovery 12 40 160 Hot 2 14 110 40 Cold 1 H (MW) Target temp, T T (C) Supply temp, T S (C) Type Steam Utility available for use: Steam @ 180C Cooling water @ 20C Without heat recovery: Heat Stream 1 with steam: 14 MW Cold Stream 2 with cooling water: 12 MW Comment: high energy cost! Copyright@Dominic Foo H82PLD - Plant Design CC - 8 2 stream heat recovery 2 stream heat recovery 2 stream heat recovery 2 stream heat recovery 12 40 160 Hot 2 14 110 40 Cold 1 H (MW) Target temp, T T (C) Supply temp, T S (C) Type Steam T min = 10C Q Hmin = 3 Q Cmin = 1 Q REC = 11 Copyright@Dominic Foo H82PLD - Plant Design CC - 9 Larger value of Larger value of Larger value of Larger value of T TT T min min min min Important features: Vertical shifting is prohibited Horizontal shifting is allowed Energy targets: Minimum hot utility: Q Hmin Minimum cold utility: Q Cmin Q Hmin = 4 Q Cmin = 2 Q REC = 10 T min = 20C Copyright@Dominic Foo H82PLD - Plant Design CC - 10 A more complex problem A more complex problem A more complex problem A more complex problem 30.0 27.0 31.5 32.0 H (MW) 0.20 180 20 Cold 1. Reactor 1 feed 0.15 40 250 Hot 2. Reactor 1 product 0.25 80 200 Hot 4. Reactor 2 product 0.30 230 140 Cold 3. Reactor 2 feed Heat capacity flowrate, CP (MW.K -1 ) Target temp, T T (C) Supply temp, T S (C) Type Steam Reactor 1 Feed 1 20C Reactor 2 Feed 2 140C Off gas, 40C Product 1, 40C 180C 40C 250C 230C 200C Product 2 80C Note: Heat capacity flowrate, CP = m.C p ( ) S T p p T T mC T mC Q = = Copyright@Dominic Foo H82PLD - Plant Design CC - 11 Hot composite curve Hot composite curve Hot composite curve Hot composite curve H (MW) T (C) 31.5 30.0 250 200 80 40 T (C) 48 7.5 250 200 80 40 6 61.5 H (MW) 61.5 C P
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0 . 1 5 C P
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0 . 2 5 C P
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0 . 1 5 C P
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0 . 1 5 C P
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0 . 4 Copyright@Dominic Foo H82PLD - Plant Design CC - 12 Cold composite curve Cold composite curve Cold composite curve Cold composite curve C P
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0 . 2 C P
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0 . 3 230 180 140 20 32 27 59 T (C) H (MW) T (C) 20 15 24 H (MW) 59 C P
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0 . 2 C P =
0 . 5 230 180 140 20 C P
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0 . 3 Copyright@Dominic Foo H82PLD - Plant Design CC - 13 Hot & cold composite curves Hot & cold composite curves Hot & cold composite curves Hot & cold composite curves H (MW) T (C) Q REC = 51.1 Q Hmin = 7.5 Q Cmin = 10 T min = 10C Pinch 230 20 250 40 Copyright@Dominic Foo H82PLD - Plant Design CC - 14 With larger With larger With larger With larger T TT T min min min min Q Hmin = 7.5 Q Cmin = 10 T min = 10C Q Hmin = 11.5 Q Cmin = 14 T min = 20C Copyright@Dominic Foo H82PLD - Plant Design CC - 15 T TT T min min min min & economic trade & economic trade & economic trade & economic trade- -- -off off off off H T H T H T T min Cost Total Energy Capital min T UA Q = Copyright@Dominic Foo H82PLD - Plant Design CC - 16 A note on A note on A note on A note on T TT T min min min min Care should be taken not to ignore practical constraints in setting T min To achieve pure T min requires heat exchangers that exhibit pure countercurrent flow Shell-and-tube: not possible T min < 10C should be avoided Plate heat exchanger: T min ~ 5C or less Copyright@Dominic Foo H82PLD - Plant Design CC - 20 Additional task Additional task Additional task Additional task Proof that the CP for composite curve is the summation of CP of individual streams. Locate the new energy targets for the following value of T min : 30C 50C Copyright@Dominic Foo H82PLD - Plant Design CC - 22 The heat recovery pinch The heat recovery pinch The heat recovery pinch The heat recovery pinch H (MW) T (C) T min Pinch Q Hmin Q Cmin Heat sink Heat source Copyright@Dominic Foo H82PLD - Plant Design CC - 23 Possible heating Possible heating Possible heating Possible heating H (MW) T (C) Pinch Heat source Possible Copyright@Dominic Foo H82PLD - Plant Design CC - 24 Impossible heating Impossible heating Impossible heating Impossible heating H (MW) T (C) Pinch Heat source Impossible Copyright@Dominic Foo H82PLD - Plant Design CC - 25 Heat transfer across pinch Heat transfer across pinch Heat transfer across pinch Heat transfer across pinch H (MW) T (C) Q Hmin +XP Q Cmin +XP Heat sink Heat source XP Copyright@Dominic Foo H82PLD - Plant Design CC - 26 Cold above the pinch Cold above the pinch Cold above the pinch Cold above the pinch H (MW) T (C) Q Hmin +XP Q Cmin Heat sink Heat source XP Copyright@Dominic Foo H82PLD - Plant Design CC - 27 Heat below the pinch Heat below the pinch Heat below the pinch Heat below the pinch H (MW) T (C) Q Hmin Q Cmin +XP Heat sink Heat source XP Copyright@Dominic Foo H82PLD - Plant Design CC - 28 Heuristic Heuristic Heuristic Heuristic To achieve energy targets, must not transfer heat across the pinch by: Process-process heat transfer Inappropriate use of utility DONT COLD ABOVE THE PINCH! DONT HEAT BELOW THE PINCH!