Powder Metallurgy
Powder Metallurgy
NANO54
Foothill College
Overview
History
Definitions
Benefits
Process
Applications
Introduction
Earliest use of iron powder dates back to 3000 BC.
Egyptians used it for making tools
Modern era of P/M began when W lamp filaments were
developed by Edison
Components can be made from pure metals, alloys, or
mixture of metallic and non-metallic powders
Commonly used materials are iron, copper, aluminium,
nickel, titanium, brass, bronze, steels and refractory
metals
Used widely for manufacturing gears, cams, bushings,
cutting tools, piston rings, connecting rods, impellers etc.
Powder Metallurgy
. . . is a forming technique
Essentially, Powder Metallurgy (PM) is
an art & science of producing metal or
metallic powders, and using them to
make finished or semi-finished products.
Particulate technology is probably the
oldest forming technique known to man
There are archeological evidences to
prove that the ancient man knew
something about it
Powder Metallurgy
Producing metal or metallic powders
Using them to make finished or semi-finished
products.
The Characterization of Engineering Powders
Production of Metallic Powders
Conventional Pressing and Sintering
Alternative Pressing and Sintering Techniques
Materials and Products for PM
Design Considerations in Powder Metallurgy
Process Capabilities
Contional
HIP
Injection
Molding (IM)
Precision IM
Preform
Forging
Metal
All
All (SA,
SS)
All
Steel, SA
Surface detail
B-C
Mass, kg
0.01-5(30)
0.1-10
10-7000 (e)
0.01-0.2
0.005-0.2
0.1-3
Min. section, mm
1.5
0.1
4-6
0.2
Tolerance +/-%
0.1
0.3
0.1
0.25
Throughput (pc/h)
100-1000
5-20
100-2000
100-2000
200-2000
Min. quantity
1000-50,000
1-100
10,000
10,000
100,000
Eq. Cost
B-C
A-B
A-B
A-B
ME 355 Sp06
W. Li
Design Aspects
(a) Length to thickness ratio limited to 2-4; (b) Steps limited to avoid density variation; (c) Radii provided to
extend die life, sleeves greater than 1 mm, through hole greater than 5 mm; (d) Feather-edged punches with flat
face; (e) Internal cavity requires a draft; (f) Sharp corner should be avoided; (g) Large wall thickness difference
should be avoided; (h) Wall thickness should be larger than 1 mm.
History of Powder
Metallurgy
IRON Metallurgy >
How did Man make iron in 3000 BC?
Did he have furnaces to melt iron air blasts,
and
History of P/M
Going further back in Time . . .
Renaissance of P/M
The modern renaissance of powder
metallurgy began in the early part of last
century, when technologists tried to replace
the carbon filament in the Edison lamp.
The commercially successful method was the
one developed by William Coolidge. He
described it in 1910, and got a patent for it in
1913.
Renaissance of P/M
The Wars and the post-war era brought about
huge leaps in science, technology and
engineering.
New methods of melting and casting were
perfected, thereby slowly changing the
metallurgy of refractory materials.
P/M techniques have thereafter been used
only when their special properties were
needed.
P/M Applications
Powder Metallurgy
Powder production
Blending or mixing
Powder compaction
Sintering
Finishing Operations
1. Powder Production
Many methods: extraction from compounds, deposition,
atomization, fiber production, mechanical powder
production, etc.
Atomization is the dominant process
(a)
(b)
(c)
(a) Water or gas atomization; (b) Centrifugal atomization; (c) Rotating electrode
Powder Preparation
Powder Preparation
2. Blending or Mixing
Blending a coarser fraction with a finer fraction
ensures that the interstices between large particles
will be filled out.
Powders of different metals and other materials may
be mixed in order to impart special physical and
mechanical properties through metallic alloying.
Lubricants may be mixed to improve the powders
flow characteristics.
Binders such as wax or thermoplastic polymers are
added to improve green strength.
Sintering aids are added to accelerate densification
on heating.
Blending
To make a homogeneous mass with uniform distribution
of particle size and composition
Powders made by different processes have different
sizes and shapes
Mixing powders of different metals/materials
Add lubricants (<5%), such as graphite and stearic
acid, to improve the flow characteristics and
compressibility of mixtures
Combining is generally carried out in
Air or inert gases to avoid oxidation
Liquids for better mixing, elimination of dusts and reduced
explosion hazards
Hazards
Metal powders, because of high surface area to volume ratio are
explosive, particularly Al, Mg, Ti, Zr, Th
Blending
3. Powder Consolidation
Cold compaction with 100 900
MPa to produce a Green body.
Die pressing
Cold isostatic pressing
Rolling
Gravity
ME 355 Sp06
W. Li
Die pressing
28
Compaction
Press powder into the desired shape and size in dies
using a hydraulic or mechanical press
Pressed powder is known as green compact
Stages of metal powder compaction:
Compaction
Compaction
W. Li
(a) and (c) Single action press; (b) and (d) Double action press
(e) Pressure contours in compacted copper powder in single action press
Compaction Pressure of
some Metal Powders
Metal Powder
Pressure (MPa)
Al
Al2O3
Brass
Carbon
Fe
W
WC
75-275
100-150
400-700
140-170
400-800
75-150
150-400
4. Sintering
Parts are heated to 0.7~0.9 Tm.
Transforms compacted mechanical
bonds to much stronger metallic
bonds.
Vsintered
Vgreen
green
sintered
green
Linear _ shrinkage
sintered
1/ 3
Promotes solid-state
bonding by diffusion.
Diffusion is timetemperature sensitive.
Needs sufficient time
Promotes vapor-phase
transport
Because material
heated very close to MP,
metal atoms will be
released in the vapor
phase from the particles
Vapor phase resolidifies
at the interface
Steps in HIP
Combined Stages
Simultaneous compaction + sintering
Container: High MP sheet metal
Container
subjected
to
elevated
temperature and a very high vacuum to
remove air and moisture from the powder
Pressurizing medium: Inert gas
Operating conditions
100 MPa at 1100 C
Combined Stages
Produces compacts with almost 100%
density
Good metallurgical bonding between
particles and good mechanical strength
Uses
Superalloy
components
for
aerospace
industries
Final densification step for WC cutting tools
and P/M tool steels
Slip-Casting
5. Finishing
The porosity of a fully sintered part is still significant (4-15%).
Density is often kept intentionally low to preserve
interconnected porosity for bearings, filters, acoustic barriers,
and battery electrodes.
However, to improve properties, finishing processes are
needed:
Cold restriking, resintering, and heat treatment.
Impregnation of heated oil.
Infiltration with metal (e.g., Cu for ferrous parts).
Machining to tighter tolerance.
Characterization of Powders
Atomization
Produce a liquid-metal
stream
by
injecting
molten metal through a
small orifice
Stream is broken by jets
of inert gas, air, or water
The size of the particle
formed depends on the
temperature of the metal,
metal flowrate through
the orifice, nozzle size
and jet characteristics
Electrode Centrifugation
Variation:
A consumable electrode
is rotated rapidly in a
helium-filled chamber.
The centrifugal force
breaks up the molten tip
of the electrode into
metal particles.
Finished Powders
P/M Summarizing:
Powder Metallurgy is sought when a) It is impossible to form the metal or
material by any other technique
b) When p/m gives unique properties which
can be put to good use
c) When the p/m route is economical
There may be over-lapping of these
three points.
Summary
Powder metallurgy
Metals and ceramics
Particles and heat
Compaction and fusion
Interesting chemistry
References
Wikipedia Powder Metallurgy
(http://en.wikipedia.org/wiki/Powder_metallurgy)
Wikipedia Sintering
(http://en.wikipedia.org/wiki/Sintering)
All about powder metallurgy http://www.mpif.org/
Powder Metallurgy http://www.efunda.com/processes/metal_proces
sing/powder_metallurgy.cfm
John Wiley and Sons Fundamentals of Modern
Manufacturing Chapter 16 (book and handouts)
Appendix 1
Powder Metallurgy
John Wiley and Sons
Powder Metallurgy (PM)
Metal processing technology in which parts
are produced from metallic powders
In the usual PM production sequence, the
powders are compressed (pressed) into
the desired shape and then heated
(sintered) to bond the particles into a
hard, rigid mass
Pressing is accomplished in a press-type
machine using punch-and-die tooling
designed specifically for the part to be
manufactured
Sintering is performed at a temperature
below the melting point of the metal
PM Work Materials
Largest tonnage of metals are alloys of
iron, steel, and aluminum
Other PM metals include copper, nickel,
and refractory metals such as molybdenum
and tungsten
Metallic carbides such as tungsten
carbide are often included within the scope
of powder metallurgy
Engineering Powders
A powder can be defined as a finely
divided particulate solid
Engineering powders include metals and
ceramics
Geometric features of engineering
powders:
Particle size and distribution
Particle shape and internal structure
Surface area
Observations
Smaller particle sizes generally show
greater friction and steeper angles
Spherical shapes have the lowest
interpartical friction
As shape deviates from spherical, friction
between particles tends to increase
Porosity
Ratio of the volume of the pores (empty
spaces) in the powder to the bulk volume
In principle, Porosity + Packing factor =
1.0
The issue is complicated by the possible
existence of closed pores in some of the
particles
If internal pore volumes are included in
above porosity, then equation is exact
Compaction
Application of high pressure to the powders
to form them into the required shape
The conventional compaction method is
pressing, in which opposing punches
squeeze the powders contained in a die
The workpart after pressing is called a
green compact, the word green meaning
not yet fully processed
The green strength of the part when
pressed is adequate for handling but far
less than after sintering
Sintering
Heat treatment to bond the metallic
particles, thereby increasing strength and
hardness
Usually carried out at between 70% and
90% of the metal's melting point (absolute
scale)
Generally agreed among researchers that
the primary driving force for sintering is
reduction of surface energy
Part shrinkage occurs during sintering
due to pore size reduction
Impregnation
The term used when oil or other fluid is
permeated into the pores of a sintered PM
part
Common products are oil-impregnated
bearings, gears, and similar components
An alternative application is when parts
are impregnated with polymer resins that
seep into the pore spaces in liquid form
and then solidify to create a pressure tight
part
Infiltration
An operation in which the pores of the PM
part are filled
with a molten metal
The melting point of the filler metal must
be below
that of the PM part
Involves heating the filler metal in contact
with the
sintered component so capillary action
draws the filler
into the pores
The resulting structure is relatively
nonporous, and
the infiltrated part has a more uniform
density, as well
as improved toughness and strength
PM Products
Gears, bearings, sprockets, fasteners,
electrical contacts, cutting tools, and various
machinery parts
Advantage of PM: parts can be made to
near net shape or net shape
They require little or no additional shaping
after PM processing
When produced in large quantities, gears
and bearings are ideal for PM because:
The geometry is defined in two dimensions
There is a need for porosity in the part to
serve as a reservoir for lubricant