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Chapter Summary Worksheet

This document contains a worksheet with questions and answers about chemical equilibria. It includes questions about equilibrium expressions for different chemical reactions, how changing temperature and pressure can affect equilibrium constants, and calculating equilibrium constants based on initial concentrations and reaction extents.

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SahanNivantha
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37 views

Chapter Summary Worksheet

This document contains a worksheet with questions and answers about chemical equilibria. It includes questions about equilibrium expressions for different chemical reactions, how changing temperature and pressure can affect equilibrium constants, and calculating equilibrium constants based on initial concentrations and reaction extents.

Uploaded by

SahanNivantha
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
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Unit 4 Rates, equilibria and further organic chemistry

Chapter Summary Worksheet


Chapter 3 Equilibrium
Print out and complete this worksheet to generate a summary for Chapter 3.

1 Consider the equilibrium:


CH4(g) + H2O(g)  CO(g) + 3H2
The expression for Kp is:
A
p[CO] p[H2]3
Kp =
p[CH4] p[H2O]
B
p(CO) p(H2)3
Kp =
p(CH4)

p(CO) p(H2)3
p(CH4) p(H2O)
D
p(CH4) p(H2O)
Kp =
p(CO) p(H2)3

Kp =

2 Consider the equilibrium:


CH3OOCCH2COOCH3(l) + 2H2O(l)  2CH3OH(l) + HOOCCH2COOH(l)
The correct expression for Kc is:
C
[CH3OH] [HOOCCH2COOH]
A
[CH3OH] [HOOCCH2COOH]
Kc =
Kc =
[CH3OOCCH2COOCH3]]
[CH3OOCCH2COOCH3] [H2O]
D
[CH3OH]2 [HOOCCH2COOH]
B
[CH3OH]2 [HOOCCH2COOH]
Kc =
Kc =
[CH3OOCCH2COOCH3]
[CH3OOCCH2COOCH3] [H2O]2

3 Consider the equilibrium


Fe3O4(s) + 4CO(g)  3Fe(s) + 4CO2(g)
The correct expression for Kp is:
A
p(Fe)3 p(CO2)4
Kp =
p(Fe3O4) p(CO)4
B
p(CO2)

Kp =
p(CO)

p(CO)
p(CO2)
D
p(CO2)4
Kp =
p(CO)4
Kp =

4 The value of the equilibrium constant Kp for a given reaction is altered by:
A temperature only
B pressure only

C temperature and pressure only


D temperature, pressure and a catalyst

5 Consider the equilibrium:


A(aq) + B(aq)  C(aq) + D(aq) Kc = 3
When 1.0 mol of A and 1.0 mol of B are mixed with 1.0 mol of C and 2.0 mol of D in a vessel
of volume 10 dm3:
A the system is at equilibrium so there is no change in the concentrations of any
substance
B the system is not at equilibrium because the fraction is smaller than Kc and reacts
so that the value of Kc is lowered in order to equal the fraction
C the system is not at equilibrium because the fraction is smaller than Kc and reacts
by the position moving to the right so that the fraction gets bigger and becomes
equal to 3
D the system is not at equilibrium because the fraction is smaller than Kc and reacts
so that the fraction gets bigger and becomes equal to 3 by the position moving to
the left
Edexcel A2 Chemistry

Philip Allan Updates

Chapter Summary Worksheet: Chapter 3

6 In a particular reversible reaction, H = +40 kJ mol1 and Ssystem = +150 J K1 mol1.

(The gas constant R = 8.31 J K1 mol1) At a temperature of 25C, the numerical value
of the equilibrium constant is:
A 0.64
C 79
B 6.67
D 7.1 1014

7 Consider the equilibrium reaction:


A(g) + 2B(g)  C(g) + 3D(g)
When 0.10 mol of A and 0.20 mol of B were allowed to reach equilibrium, 80% of A
reacted and the total pressure was 2.0 atm. The value of Kp/atm2 is:
A 182
C 16.5
B 11.6
D 0.95

8 An equilibrium reaction has H = 75 kJ mol1 and Ssystem = 100 J K1 mol1.

(The gas constant R = 8.31 J K1 mol1.) An increase in temperature from 200C to 300C
causes the value of Stotal to:
A decrease from +58.6 to +30.9
B increase from +58.6 to +650
C decrease from 258.6 to 850
D increase from 258.6 to 100.13

Edexcel A2 Chemistry

Philip Allan Updates

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