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IB Chem 9 Assess Awsm9

The document is a marking scheme for a worksheet on electrochemistry for an IB Diploma chemistry course. It provides the answers and marks for 7 multiple choice and short answer questions testing understanding of concepts such as cell potentials, redox reactions, and half-reactions. Key details assessed include identifying the positive and negative electrodes in electrochemical cells, writing balanced redox equations, determining spontaneity based on cell potential, and performing stoichiometric calculations related to the moles of substances produced in electrolysis reactions.

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Fatima Siddiqui
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0% found this document useful (0 votes)
282 views2 pages

IB Chem 9 Assess Awsm9

The document is a marking scheme for a worksheet on electrochemistry for an IB Diploma chemistry course. It provides the answers and marks for 7 multiple choice and short answer questions testing understanding of concepts such as cell potentials, redox reactions, and half-reactions. Key details assessed include identifying the positive and negative electrodes in electrochemical cells, writing balanced redox equations, determining spontaneity based on cell potential, and performing stoichiometric calculations related to the moles of substances produced in electrolysis reactions.

Uploaded by

Fatima Siddiqui
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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Chemistry for the IB Diploma

Marking scheme for AHL Worksheet Chapter 9


1

+0.57 V

[1]

Ni is the negative electrode

[1]

electrons flow from Ni/Ni2+ to Cu/Cu2+ half cell

[1]

Cu2+(aq) + Ni(s) Cu(s) + Ni2+(aq)

[1]

+0.27 V

[1]

Br2(Pt) is the negative electrode

[1]

electrons flow from Br2/Br to Cl2/Cl half cell

[1]

Cl2(g) + 2Br (aq) Br2(l) + 2Cl (aq)

[1]

+0.93 V

[1]

Pb is the negative electrode

[1]

2+

[1]

2Ag (aq) + Pb(s) 2Ag(s) + Pb (aq)

[1]

+2.09 V

[1]

electrons flow from Pb/Pb to Ag/Ag half cell


+

2+

Zn is the negative electrode

[1]
2

2+

3+

electrons flow from Zn/Zn to Cr2O7 /Cr half cell


2

3+

Cr2O7 (aq) + 14H (aq) + 3Zn(s) 2Cr (aq) + 7H2O(l) + 3Zn (aq)

[1]

spontaneous (cell potential +0.59 V)

[1]

2+

[1]
2+

Cl2 is the oxidising agent and Fe the reducing agent

[1]

not spontaneous (cell potential 0.27 V)

[1]

not spontaneous (cell potential 0.15 V)

[1]

spontaneous (cell potential +0.74 V)

[1]

Fe2+ reducing agent and MnO4 oxidising agent

[1]

anode: iodine

[1]

cathode: hydrogen

[1]

anode: oxygen

[1]

cathode: copper

[1]

anode: chlorine

[1]

cathode: hydrogen

[1]

anode: oxygen

[1]

cathode: hydrogen

[1]

anode: oxygen

[1]

cathode: hydrogen

[1]

a
b
c
d
e

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Page 1 of 2

Chemistry for the IB Diploma


4

cathode: Cu2+(aq) + 2e Cu(s)

[1]

anode: Cu(s) Cu2+(aq) + 2e

[1]

cathode: Cu2+(aq) + 2e Cu(s)

[1]

anode: 2H2O(l) O2(g) + 4H+(aq) + 4e

[1]

spoon as cathode

[1]

silver anode

[1]

electrolyte containing Ag+(aq)

[1]

44.0 cm3 of hydrogen produced

[1]

twice as many electrons required to produce one mole of oxygen

[1]

reference to the appropriate half equations

[1]

number of moles of copper produced =

0.636
= 0.0100 mol
63.55

[1]

Cu2+(aq) + 2e Cu(s) and 2H2O(l) O2(g) + 4H+(aq) + 4e

[1]

number of moles of O2 = 0.00500 mol

[1]

volume of O2 = 0.00500 22.4

[1]

= 0.112 dm3

[1]

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Page 2 of 2

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