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Question One:: Thermodynamic 2 Test (1) Time 1:30

1) The document contains a thermodynamics test with two questions. The first question includes true/false statements about phase changes, a calculation using Gibbs relation and Maxwell's relations, estimating changes in enthalpy and entropy during compression of liquid ammonia, and determining equilibrium composition of a heated gas mixture. 2) The second question asks about retrograde condensation and preparing phase diagrams for a benzene-ethylbenzene mixture assuming Raoult's law.

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Nihad S Zain
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59 views

Question One:: Thermodynamic 2 Test (1) Time 1:30

1) The document contains a thermodynamics test with two questions. The first question includes true/false statements about phase changes, a calculation using Gibbs relation and Maxwell's relations, estimating changes in enthalpy and entropy during compression of liquid ammonia, and determining equilibrium composition of a heated gas mixture. 2) The second question asks about retrograde condensation and preparing phase diagrams for a benzene-ethylbenzene mixture assuming Raoult's law.

Uploaded by

Nihad S Zain
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as DOCX, PDF, TXT or read online on Scribd
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Thermodynamic 2

Time=1:30

Test (1)

Question One:
1) true or false question:
a. when going through phase change
temperature and pressure are constant
b. Single phase
independent

regions

are

c. Two phase regions are


temperature independent

all

all

both

temperature

pressure

and

2) Use Gibbs relation du = Tds Pdv and one of Maxwells


relations to find an expression for (u/P)T that only has
properties P, v and T involved. What is the value of that
partial derivative if you have an ideal gas?
3) Estimate the change in enthalpy and entropy when liquid
ammonia at 270K is compressed from its saturation
pressure of 381Kpa to 1200Kpa. For saturated liquid
ammonia at 270K, Vt= 1.551 x10-3m3 kg-1and
=
-3 -1
2.095 x 10 K .
4) A mixture of 2 kmol of CO and 3 kmol of O 2 is heated to
2600 K at a pressure of 304 kPa. Determine the
equilibrium composition, assuming the mixture consists of
CO2, CO, and O2.
Note: ln KP = 2.801, or KP = 16.461

Question Two:
1. Talk briefly about Retrograde Condensation?
2. Assuming Raoult's law to be valid, prepare a P-x-y diagram
for a temperature of 363.15 K (90C) and a t-x-y diagram
for a pressure of 90 kPa for Benzene(l)/ethylbenzene(2).

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