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Thermal Applications Note: Literature Values For Water Specific Heat Capacity

The document provides a table of literature values for the specific heat capacity of water at temperatures ranging from 0°C to 100°C. The table lists the specific heat capacity in both cal/g°C and J/g°C units for each 1°C increase in temperature. It notes that measurements of specific heat capacity by DSC require a reference material for calibration, and purified water can be used as a reference for analyzing liquid samples when a suitably sized sapphire reference is not available. The data comes from a literature source from 1939 that is referenced at the bottom.

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45 views

Thermal Applications Note: Literature Values For Water Specific Heat Capacity

The document provides a table of literature values for the specific heat capacity of water at temperatures ranging from 0°C to 100°C. The table lists the specific heat capacity in both cal/g°C and J/g°C units for each 1°C increase in temperature. It notes that measurements of specific heat capacity by DSC require a reference material for calibration, and purified water can be used as a reference for analyzing liquid samples when a suitably sized sapphire reference is not available. The data comes from a literature source from 1939 that is referenced at the bottom.

Uploaded by

Rebecca Francis
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Thermal Analysis & Rheology

THERMAL APPLICATIONS NOTE


Literature Values For Water Specific Heat Capacity
Specific heat capacity measurements by DSC require the use of well-characterized reference material (usually sapphire) to
obtain results. However, when analyzing liquids, suitable sized sapphire reference material may be difficult to obtain. One
alternative is to use purified water. The table below summarizes specific heat capacity data (literature valures) for water as
a function of temperature.
Temperature
C
______
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28

Specific Heat
cal./g/C
_______

J/g/C
______

1.00738
1.00652
1.00571
1.00499
1.00430
1.00368
1.00313
1.00260
1.00213
1.00170
1.00129
1.00093
1.00060
1.00029
1.00002
0.99976
0.99955
0.99933
0.99914
0.99897
0.99883
0.99869
0.99857
0.99847
0.99838
0.99828
0.99821
0.99814
0.99809

4.2177
4.2141
4.2107
4.2077
4.2048
4.2022
4.1999
4.1977
4.1957
4.1939
4.1922
4.1907
4.1893
4.1880
4.1869
4.1858
4.1849
4.1840
4.1832
4.1825
4.1819
4.1813
4.1808
4.1804
4.1800
4.1796
4.1793
4.1790
4.1788

Temperature
C
______
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57

Specific Heat
cal./g/C
_______

J/g/C
_______

0.99804
0.99802
0.99799
0.99797
0.99797
0.99795
0.99795
0.99797
0.99797
0.99799
0.99802
0.99804
0.99807
0.99811
0.99816
0.99819
0.99826
0.99830
0.99835
0.99842
0.99847
0.99854
0.99862
0.99871
0.99878
0.99885
0.99895
0.99905
0.99914

4.1786
4.1785
4.1784
4.1783
4.1783
4.1782
4.1782
4.1783
4.1783
4.1784
4.1785
4.1786
4.1787
4.1789
4.1791
4.1792
4.1795
4.1797
4.1799
4.1802
4.1804
4.1807
4.1810
4.1814
4.1817
4.1820
4.1824
4.1828
4.1832
TN-15

Temperature
C
______
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78

Specific Heat
cal./g/C
_______

J/g/C
______

0.99924
0.99933
0.99943
0.99955
0.99964
0.99976
0.99988
1.00000
1.00014
1.00026
1.00041
1.00053
1.00067
1.00081
1.00096
1.00112
1.00127
1.00143
1.00160
1.00177
1.00194

4.1836
4.1840
4.1844
4.1849
4.1853
4.1858
4.1863
4.1868
4.1874
4.1879
4.1885
4.1890
4.1896
4.1902
4.1908
4.1915
4.1921
4.1928
4.1935
4.1942
4.1949

Temperature
C
______
79
80
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
98
99
100

Specific Heat
cal./g/C
_______

J/g/C
_______

1.00213
1.00229
1.00248
1.00268
1.00287
1.00308
1.00327
1.00349
1.00370
1.00392
1.00416
1.00437
1.00461
1.00485
1.00509
1.00535
1.00561
1.00588
1.00614
1.00640
1.00669
1.00697

4.1957
4.1964
4.1972
4.1980
4.1988
4.1997
4.2005
4.2014
4.2023
4.2032
4.2042
4.2051
4.2061
4.2071
4.2081
4.2092
4.2103
4.2114
4.2125
4.2136
4.2148
4.2160

REFERENCE: Osborne, Stimson, and Ginnings, B. of S. Jour. Res., 23, 238 (1939) in Handbook of Chemistry and Physics,
53rd ed., Cleveland, Ohio, D128 (1972-1973).

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TN-15A

Thermal Analysis & Rheology


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