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Initial Conc Adsobent Dosage C Q Sorption%: Soprtion%

The document contains data from several experiments investigating the adsorption of arsenic and cadmium onto an adsorbent material. The data includes the effect of varying adsorbent dosage, pH, time, and initial concentration on the percentage of arsenic or cadmium removed from solution. Graphs of the data show that adsorption generally increased with increasing adsorbent dosage, at pH values between 6-8, and over time up to 90 minutes. Adsorption isotherm models including Langmuir, Freundlich, Temkin and Dubinin-Radushkevich were applied to the data and showed good correlation. Kinetic models including pseudo-first order, pseudo-second order

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Joy Raval
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29 views

Initial Conc Adsobent Dosage C Q Sorption%: Soprtion%

The document contains data from several experiments investigating the adsorption of arsenic and cadmium onto an adsorbent material. The data includes the effect of varying adsorbent dosage, pH, time, and initial concentration on the percentage of arsenic or cadmium removed from solution. Graphs of the data show that adsorption generally increased with increasing adsorbent dosage, at pH values between 6-8, and over time up to 90 minutes. Adsorption isotherm models including Langmuir, Freundlich, Temkin and Dubinin-Radushkevich were applied to the data and showed good correlation. Kinetic models including pseudo-first order, pseudo-second order

Uploaded by

Joy Raval
Copyright
© © All Rights Reserved
Available Formats
Download as XLSX, PDF, TXT or read online on Scribd
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Initial Conc

Adsobent Dosage C
0.1
0.2
0.4
0.6
0.8
1

2 mg/l
q
0.821
0.634
0.419
0.3
0.297
0.267

Sorption%
1.179
58.95
0.683
68.3
Soprtion%
0.39525
79.05
0.283333
85
0.212875
85.15
0.1733
86.65

90
85
80
75
70
65
60
55
50
0

0.2

0.4

0.6

0.8

Adsorbent Dosage in Grams

1.2

1.2

Initial Concentration
pH
C
2
3
4
5
6
7
8
8.5
9

2 mg/l
Removal %
0.764
61.8
0.75
62.5
0.63
68.5
0.62
69
0.54
73
0.49
75.5
0.3
85
0.363
81.85
0.531
73.45

Sorption% of As(III) v/s pH


90
80
Sorption %

70
60
50
1

5
pH

10

s pH

10

Initial Conc
Adsorbent Dosage
Time
C
15
30
45
60
75
90

2 mg/l
0.6
Sorption%
1.35
32.5
0.934
53.3
0.54
73
0.3
85
0.297
85.15
0.267
86.65

Sorption % of Cd v/s Time


100
80
60
Sorption%

40
20
0
10

20

30

40

50

60

Time in minutes

70

80

90

100

70

80

90

100

Initial Conc

50

Adsobent
Dosage (g)

Ce (ppm)

0.25
0.5
0.75
1
1.25
1.5

12.3
6.8
4.6
3.3
3
2.8

Freundlich Isotherm
Slope
0.997859
n
1.002146
Intercept K
0.103321

Langmuir Isotherm
qe(mg/g)

1/qe

1/Ce

log qe

log Ce

0.4

15.08
8.64
6.053333
4.67
3.76
3.146667

0.066313
0.1157407
0.1651982
0.2141328
0.2659574
0.3177966

0.0813008
0.1470588
0.2173913
0.3030303
0.3333333
0.3571429

1.178401
0.936514
0.781995
0.669317
0.575188
0.497851

1.089905
0.832509
0.662758
0.518514
0.477121
0.447158

0.3
1/qe (g/mg)

0.2

f(x) = 0.8342489052x - 0.0


R = 0.9584290408

0.1
0
0.05

0.1

0.15

0.2

0.25

1/Ce (L/mg)

Freundlich isotherm

ngmuir Isotherm

1.5

f(x) = 0.8342489052x - 0.0092600239


R = 0.9584290408

Log qe

0
0.05

0.1

0.15

0.2

0.25

1/Ce (L/mg)

0.3

0.35

0.4

f(x) = 0.99785886x + 0.103320749


R = 0.9825997806

0.5
0
0.4

0.5

0.6

0.7

0.8

Log Ce

0.9

1.1

1.2

Initial Conc

50 mg/l

Temkins Model

Adsobent Dosage
(g)

Ce (ppm)

qe(mg/g)

lnCe

0.25
0.5
0.75
1
1.25
1.5

12.3
6.8
4.6
3.3
3
2.8

15.08
8.64
6.0533333333
4.67
3.76
3.1466666667

2.5095992624
1.9169226122
1.5260563035
1.1939224685
1.0986122887
1.0296194172

20
qe (mg/g)

15

f(x) = 7.6466824972x - 4.928


R = 0.9731554841

10
5
0
0.8

1.2

1.4

1.6

1.8

Log Ce

ns Model

= 7.6466824972x - 4.9284889241
0.9731554841

1.4

1.6

1.8

Log Ce

2.2

2.4

2.6

Initial Conc
Adsobent
Dosage (g)

0.25
0.5
0.75
1
1.25
1.5

50 mg/l
Ce (ppm)

qe (mg/g)

lnqe

e^2

12.3
6.8
4.6
3.3
3
2.8

15.08
8.64
6.053333
4.67
3.76
3.146667

1.178401
0.936514
0.781995
0.669317
0.575188
0.497851

196.9082
345.6291
495.5412
666.7981
724.712
769.2997

38772.82
119459.5
245561
444619.7
525207.5
591822.1

D-R Model
1.5

1
f(x) = - 1.07716150403134E-006x + 1.1260
Log qe R = 0.9378405313
0.5
0
0

beta=

-1.07716E-006

681.30972821 J
0.6813097282 KJ

200000

400000
e^2

600000

-R Model

716150403134E-006x + 1.1260607176
05313

200000

400000
e^2

600000

800000

Initial Conc
Adsorbent
Dosage
qe
Time (min)
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120

50 mg/l
0.25
18.01
Ct
50
30.1
26.5
22.6
15.8
15.4
12.2
10.2
8.6
6.8
6.9
6.6
5.8
5.2
5.2
5.1
5

Psuedo First order Adsorption Model


qt
0
7.96
9.4
10.96
13.68
13.84
15.12
15.92
16.56
17.28
17.24
17.36
17.68
17.92
17.92
17.96
18

qe-qt
18.01
10.05
8.61
7.05
4.33
4.17
2.89
2.09
1.45
0.73
0.77
0.65
0.33
0.09
0.09
0.05
0.01

log(qe-qt)
1.25551371
1.00216606
0.93500315
0.84818912
0.6364879
0.62013605
0.46089784
0.32014629
0.161368
-0.1366771
-0.1135093
-0.1870866
-0.4814861
-1.0457575
-1.0457575
-1.30103
-2

2
1
log(qe-qt)

f(x) = - 0.035303912x + 1.407956719


R = 0.9428901143

0
-1

10 20 30 40 50 60 70 80 90 100

-2
-3
Time in minutes

Slope
k

-0.035304
0.01533

Initial Conc
Adsorbent Dosage
Time

50 mg/l
0.25
C

0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80

qt
50
30.1
26.5
22.6
15.8
15.4
12.2
10.2
8.6
6.8
6.9
6.6
5.8
5.2
5.2
5.1
5

t/qt
0
#DIV/0!
7.96 0.628141
9.4 1.06383
10.96 1.368613
13.68 1.461988
13.84 1.806358
15.12 1.984127
15.92 2.198492
16.56 2.415459
17.28 2.604167
17.24 2.900232
17.36 3.168203
17.68 3.393665
17.92 3.627232
17.92 3.90625
17.96 4.175947
18 4.444444

Psuedo Second Order Adsorption Model


5
4

f(x) = 0.0483613902x + 0.5163376931


R = 0.9969392778

3
t/qt 2
1
0
0

10

20

30

40

50

60

Time in Minutes

70

80

90

Model

6931

70

80

90

slope
intercept
qe
k

0.516
0.048
1.937984 mg/g
78.2455 min-1

Initial Conc
Adsorbent Dosage
qe
Time
t^0.5
Ct
0
0
5
2.236068
10
3.162278
15
3.872983
20
4.472136
25
5
30
5.477226
35
5.91608
40
6.324555
45
6.708204
50
7.071068
55
7.416198
60
7.745967
65
8.062258
70
8.3666
75
8.660254
80
8.944272

50 mg/l
0.25
18.01
qt
50
0
30.1
7.96
26.5
9.4
22.6
10.96
15.8
13.68
15.4
13.84
12.2
15.12
10.2
15.92
8.6
16.56
6.8
17.28
6.9
17.24
6.6
17.36
5.8
17.68
5.2
17.92
5.2
17.92
5.1
17.96
5
18

Intraparticle Diffusion Model


20
f(x) = 1.5342920779x + 5.7647442603
R = 0.9127941229

15
qt

10
5
0
1

4
5
6
7
Time Function

Slope
Kp

1.877037
1.877037

10

10

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