Potential Energy Questions
Potential Energy Questions
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Practice drawing and interpreting potential energy diagrams. Draw and label potential energy diagrams to answer the following questions.
1. Assume the following reaction has a one-step mechanism:
A+BC Draw a potential energy diagram for the reaction that correctly incorporates each of the following labels: H = 150 kJ/mol Ea(fwd) = 450 kJ Potential energy Reaction progress Transition state A+B C
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(b) Determine Ea(rev) for the reaction. Add this value to your diagram. (c) How would your diagram have been different if the reaction had a two-step
mechanism. On your diagram, sketch a curve to represent the effect of the catalyst on the reaction.
2. Assume the following reaction has a one-step mechanism:
D+EF+G Draw a potential energy diagram for the reaction that correctly incorporates each of the following labels: H = 56 kJ/mol Ea(rev) = 120 kJ Potential energy Reaction progress Transition state D+E F+G
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(b) Determine Ea(fwd) for the reaction. Add this value to your diagram.
mechanism. On your diagram, sketch a curve to represent the effect of the catalyst on the reaction.