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1991 Paper 1 Marking Scheme

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26 views

1991 Paper 1 Marking Scheme

Uploaded by

api-3734333
Copyright
© Attribution Non-Commercial (BY-NC)
We take content rights seriously. If you suspect this is your content, claim it here.
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1. (a) 4) (1) "Halogen(s) 7 . colix Sell sere (2) (1) each has 7 electrons in its outermost shell/ they have the same no. of electrons in their 7 outermost shells. 1 (II) £ has 8 electrons more than b/ £ has one (inner) electron shell more than b/ f£ and b have different numbers of electron shells/E has 3 electron shells and b has 2./e. L ro fe ay Ui (Do not ascept layer of electrons.) (N.B. - 1 mark for (2), if only correct electronic structures of b and £ are given as answers. ] (ii) because the metallic bond in element d is stronger 1 q) (1,05) if 1 40; 194 ay roe ov neko! gc (2) The oxide can dissolve(in dilute acid. . 1 Or —4y0;(8) + GHCL(aq) + 2dCl (aq) + 3H,0(8) or d0;(s) + 6H'(aq) + 24" ead + 3H,0(8 reat [nee Tralie The oxide can dissolve/in dilute alkali. 1 or 0;(s) + 2Na0H(aq) + 2Nad0;(aq) + Hot) or 440)(s) + 20H"(aq) + 3H,0(8) = 24(0H),-(aa) [N.B, award marks for correct balanced equations f with physical states.], accupe #™ a (1) An allotrope is one of the forms acquired by an element if the element can exist in more than one 1 (different) form (or structure). sali Xx popete K [N.B. - do not accept "2 forme” as an alternative to "more than one form".] (2) a and e/carbon and ns au s ; 1 (vy) @) a oo pe 7 | eA OX Sa, te gle 3 “ae Lard & [N.B. accept C for a, Na for c and S for wa (2) Compound formed betweéh ¢ and e has a higher m.p. lz K because it is an ionic compound and the wel ions are held by scone slectrostati c forces/strong 1 ionic bond bre b : compound formed wenceen aande isa covalent BeR nA Mie ue WAtRHNLAM APE Ate BE 13 marks (ii) (iii) (iv) @) (vi) (vii) a CH,- CH CHL CH, -O~C- KR ee Scog 5 rt ot : A a } ° CH~ ond -e cHocoR ° boo 20 c20 | eyo. fig CHOCoR U rt ! < Ra Rk RK RcO6 CHa ch ooce Reoscu duooce J t RCOOCHL Ch, 00cK de net ac. = et accept : CH, COOR bgcoox eu, Cook as a catalyst 1 ‘saponification (Do not’ actept alkaline hydrolysis.) a 29 2° RoC nt RN on, RCOONa, ONe iS i Zo (Do not accept A-C. N0-Na ) Sodium hydroxide reacts with/removes/neutralize! eran! the carboxylic acid/s*The equilibrium (position) is shifted to the right and makes the hydrolysis of ester i go te (Do. not accept saponification is irreversible.) (Do not accept reaction is shifted .to,the right.) sna sash, pwr hd x The hydrocarbon group/covalent end of Y dissolves in peanut oil (is hydrophobic The carboxylate/ionic end dissolves in water (is hydrophilic). After stirring, the oil splits into droplets, due to repulsion of megative: charees/carboxylate ions /(:he Hany 1 (Do not accept hydrophilic ends). jus pei x the droplets cannot, coalesce/stick together and a milky solution is formed. ~ *Emulsification/emuilsitying action 5 1 (Do not accept emulsify, emulsion.) . Soap/deterge: )/removing grease or oil/ emlsifier/salad dressing/mustard/cold cream 1 {2 marks (a) q@) (ii) (iii) (iv) (vy) Use a ‘pipette/pipet to fransfer 25.0 cm of the . solution into a 250.0 cm 1 dard £ then add 1 ed water to the 1 (graduation) mark. inatia. x phenolphthalein 1 colourless to pink 1 After discarding the Ist reading Average « 24:70+ 24.904 24.80 = 24.80(cm') fe CHCO,H + NaOH + CH;CO)Na + 1,0 (nefacegt 10m eh No. of moles of CHjCQH in 25 cm of diluted vinegar =No. of moles of . NaQH used = 24.8 x 9,3 " 1000 3 = 2.48 x 10 No. of moles of CH,CO,H in 250 cm of diluted vinegar . 3 yg 250 1 2.48 x ay x 25 = 2.68 x 107 Conc. of the original solution = 2.48, 10° y 43 0.992 M 0.99 M.- 1.00 M) (acceptable ‘rang * Award the mark if method is correct.

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