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2000 Paper 1 Marking Scheme
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Section A i (a) Any ONE of the following : Substances with colour Substances without colour (white) nitrogen dioxide iron(111) oxide ‘ammonia carbon dioxide magnesium oxide potassium oxide or} Substances with an odour Substances without an odour ‘ammonia carbon dioxide nitrogen dioxide magnesium oxide iron(II) oxide potassium oxide or] Water soluble substances ‘Water insoluble substances ‘ammonia iron(II) oxide carbon dioxide magnesium oxide nitrogen dioxide | potassium oxide (b) Any ONE of the following : (Also accept other correct classifications. Do NOT accept classification based on melting point, boiling point, density or electrical conductivity.) Acidic substances 2°G. °2 Basic substances carbon dioxide nitrogen dioxide ammonia magnesium oxide iron({If) oxide potassium oxide or Can be reduced by Cannot be reduced by heating with charcoal heating with charcoal j carbon dioxide ‘ammonia nitrogen dioxide magnesium oxide iron(II1) oxide potassium oxide or |Can be decomposed by electrolysis Cannot be decomposed by electrolysis magnesium oxide iron(II) oxide potassium oxide ammonia carbon dioxide nitrogen dioxide or| Substances that react with water Substances not react with water ammonia nitrogen dioxide carbon dioxide iron(II) oxide magnesium oxide potassium oxide (Also accept other correct classifications. Do NOT accept classification based on bonding and structure. ) (2/0) (2/0) (2/0) 210 (2/0) (210) (2/0) (210) oOMarks 2. (a) The average isotopic mass of the natural ae onthe 1 2C ( 12.000) scale verge 1 , \Minais of an atom of the element . or, relative atomic mass = ay sx mass of an atom of carbon -12 12 Da (b) (i) Y/potassium (K) 1 Y is a reactive metal and reacts readily with oxygen/waterinair foes with air X 1 X / argon (Ar) 1 X is chemically inert / is a noble gas / will not react with the hot tungsten filament. 1 chemical stable Gi) W/ sulphur (S) 1 Sulphur can form SO,/SO, which, when dissolved in water, give H,SQ,/H,SO,/acidic 1 solution (Only ONE answer should be given. Do NOT mark explanation if the choice is incorrect.) © 3. (a) copper 1 high electrical conductivity / good electrical conductor ince ty xR 1 (6) aluminium Mata Pome mast Be correct 1 low density ther nts with miner errey I (©) bronze inavd X ieee 1 high corrosion resistance / high mechanical strength / 5 ¢r< (Do NOT mark explanation if choice is wrong.) (If more than one explanation is given, mark the correct one. Award 0 marks for explanation if an absurd explanation has been included.) (6)4. Chemical Knowledge (6 marks) 1 < Copper( I) oxide dissolves / a blue solution / green solution is formed 1 - Filter off the copper powder 1 Wash the copper powder with water and allow it to dry . a 1 ae 1 Weigh the copper powder : meek Percentage by mass of copper powder in the sample = 35S 0f copper powder , |, i mass of sample Alternative answer : Heat the sample in a combustion tube a) , Pass hydrogen / town gas / carbon monoxide / ammonia over the heated sample until all black (1) i qa) Allow to cool and weigh the product a) Mass of copper(II) oxide (x) = Change in mass of sample 5 ts mass of CuO a Telative atomic mass of Percentage by mass of copper powder =(-——*—_)x100 a) mass of sample (Accept other correct answers including back titration.) (6) Effective communication (3 marks) General guidelines for marking effective communication : (The mark for effective communication should relate to the candidate’s knowledge in chemistry. A candidate who wrote a paragraph which is torally unrelated to the question should deserve zero marks both in chemical knowledge and in effective communication, (ii) The table below illustrates the relationship between the mark for chemical knowledge and the maximum mark for effective communication, together with the points to be considered in marking effective communication. mark for chemical | maximum mark for effective | points to be considered in paragraph knowledge communication (iii) below 4 or above 3 (A), (B) and (C) 3 or below 2 (B) and (C) (iii) The three marks for effective communication are awarded as follows : (A) _ the ability to present ideas in a precise manner, including the proper use of chemical terms (this mark should not be awarded to answers which contained a lot of incorrect/superfluous materials); 1 (B) the ability to present ideas in a systematic manner (ie, the answer is easy to follow); (C)__ the ability to present answer in paragraph form and to express ideas using full sentences, a (f conc. H;SO, / peHg=:8#63 /HNO, is used, marks for (A) should be 0.)
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