Dioxin: Pcdds Dan Pcdfs Dioxin: Pcdds Dan Pcdfs
Dioxin: Pcdds Dan Pcdfs Dioxin: Pcdds Dan Pcdfs
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NUMBER OF CONGENERS HOMOLOLOGUE (ABBREVIATION) Monochloro (M) Dichloro (D) Trichloro (Tr) Tetrachloro (T) Pentachloro (P) Hexachloro (Hx) Heptachloro (Hp) Octachloro (O) Total
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PCDDs 2 10 14 22 14 10 2 1 75
PCDFs 4 16 28 38 28 16 4 1 135
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CONGENER 2,3,7,8-TCDF 2,3,4,7,8-PeCDF 1,2,3,7,8-PeCDF 1,2,3,4,7,8-HxCDF 1,2,3,7,8,9-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,4,6,7,8-HpCDD 1,2,3,4,7,8,9-HpCDF OCDF
I-TEF 0.1 0.5 0.05 0.1 0.1 0.1 0.1 0.01 0.01 0.001
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SAMPLING PROTOCOL USEPA METHOD 1 (BAPEDAL,770-0001-96) POINTS USEPA METHOD 2 (BAPEDAL,770-0002-96) USEPA METHOD3 (BAPEDAL,770-0003-96) USEPA METHOD 4 (BAPEDAL,770-0004-96) USEPA METHOD 23
FIELD DATA
FIELD DATA
FIELD DATA
DIOXINS
GC/MS
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PRINCIPLE:
A SAMPLE IS WITHDRAWN FROM THE GAS STREAM ISOKINETICALLY AND COLLECTED IN THE SAMPLE PROBE, ON A GLASS FIBER FILTER, AND ON A PACKED COLUMN OF ADSORBENT MATERIAL. THE PCDDs/Fs ARE EXTRACTED FROM THE SAMPLE, SEPARATED BY HIGH RESOLUTION GC, AND MEASURED BY HIGH RESOLUTION MS.
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SAMPLING PROCEDURE
1. TURNED ON CIRCULATION PUMP; WATER TEMPERATURE MUST BE
KEPT BELOW 20C 2. ADJUSTED THE FLOW THROUGH ROTAMETER INDICATED BY A MANOMETER BASED ON THE FLOW OF STACK GAS THROUGH STYPE PITOT TUBE INDICATED BY ANOTHER MANOMATER --> TO HAVE ISOKINETIC CORRELATION. 3. THERE WERE 12 TRAVERSE POINTS MEASURED DURING THE TESTS. 4. EVERY MOVING FROM ONE SAMPLING PORT TO ANOTHER LEAK CHECK WAS ALWAYS PERFORMED. 5. PERFORMED POST-TEST LEAK CHECKS. 6. DISASSEMBLED PROBE, FILTER, FILTER HOLDER AND IMPINGERS AND CAPED ALL OPENINGS. 7. BROUGHT THESE 3 SECTIONS TO CLEAN ROOM NEAR THE STACK FOR RECOVERY.
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2. 3.
4. 5. 6.
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EXAMPLE OF RESULTS
Run # Test # Total and TEQs of Dioxin in XAD*) Concentration pg
D1
Total PCDD/Fs TEQ (ND=0) TEQ (ND=DL/2) Total PCDD/Fs TEQ (ND=0) TEQ (ND=DL/2) Total PCDD/Fs TEQ (ND=0) TEQ (ND=DL/2)
D3
D4
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EXAMPLE OF RESULTS
Run No. 1 Test No. D1 Sample collected* Weight of TEQ of TCDD, pg 2.57 2.89 1.88 7.34 3.03 Corrected value** 2.57 2.89 1.88 7.34 3.03 2.89 1.88 7.80 7.82 2.89 1.88 12.59 Remark
D3
XAD/D-3 + C1/D-3 C2/D-3 C3/D-3 Total D3 XAD/D-4 + C1/D-4 C2/D-4 C3/D-4 Total D4
D4
7.82
Samples from XAD (adsorbent) and C1 (filter) were combined for analysis. * Liquid samples (C2 and C3) analyzed were only from Dioxin test # 1, therefore they were used for correction of the others.
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**Corrected values of dioxin (as 2,3,7,8 TCDD TEQ) are used in calculation.
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EXAMPLE OF RESULTS
Concentration, and emission rate.
DATA RECOREDED Sampling time, min Gas volume, STD m3 Stack tempereature,K Llinier gas vel, m/s Flow rate, @STD m3, dry basis. O2 content, % Isokinetic value, % Conc. (ng/STDm3 of 2,3,7,8 TCDD TEQ, dry basis @ ACT. O2 Emission rate (mg/h of 2,3,7,8 TCDD TEQ, dry basis @ ACT. Fuel consumed in the kiln 7/1/2006 TEST 1 120 2.887 371.5 16.25 730,564 14.9* 110 0.0025 0.0019 9.8 T/h coal+3.1 T/h HWF TEST 3 120 2.944 366.4 17.45 796,195 15.2 101 0.0026 0.0021 11.3 T/h coal+2.4 T/h HWF TEST 4 120 2.902 368 17.7 804,778 15.5 98 0.0043 0.0035 10.9 T/h coal+2.4 T/h HWF 16
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10
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11
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12
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END
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