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Set 1 Paper 2

This document provides information about a chemistry exam for SPM (Sijil Pelajaran Malaysia). It includes several chemistry questions and concepts that students need to understand: 1. Questions ask students to write chemical formulas and equations for reactions between silver nitrate, zinc chloride, and other compounds. 2. Calculations are provided to determine moles of substances and gas volumes produced in chemical reactions. 3. The document discusses concepts like electrolytic cells, electrochemical series, and acid-base titration. Diagrams of voltaic cells and tables of experimental results are included. 4. Students are asked to analyze experimental data, predict outcomes, and explain chemical concepts and observations.

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fadliehaliem
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0% found this document useful (0 votes)
403 views

Set 1 Paper 2

This document provides information about a chemistry exam for SPM (Sijil Pelajaran Malaysia). It includes several chemistry questions and concepts that students need to understand: 1. Questions ask students to write chemical formulas and equations for reactions between silver nitrate, zinc chloride, and other compounds. 2. Calculations are provided to determine moles of substances and gas volumes produced in chemical reactions. 3. The document discusses concepts like electrolytic cells, electrochemical series, and acid-base titration. Diagrams of voltaic cells and tables of experimental results are included. 4. Students are asked to analyze experimental data, predict outcomes, and explain chemical concepts and observations.

Uploaded by

fadliehaliem
Copyright
© Attribution Non-Commercial (BY-NC)
Available Formats
Download as DOC, PDF, TXT or read online on Scribd
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Section A [60 marks] Answer all questions in this section. The time suggested to answer this section is 90 minutes.
1

(a) Table 1.1 shows formula of several ions. Jadual 1.1 menunjukkan formula bagi beberapa ion. Ion name Nama ion Formula of ion Formula ion Silver ion ion argentum Ag+ Zinc ion ion zink Zn2+ Nitrate ion ion nitrat NO3Chloride ion ion klorida Cl-

TABLE / JADUAL 1.1 Write the formula for zinc chloride and zinc nitrate. Tuliskan formula kimia bagi zink klorida dan zink nitrat Zinc chloride zink klorida Zinc nitrate zink nitrat : ............................ : ............................ [ 2 marks] (b) When silver nitrate solution is added to zinc chloride solution, a white precipitate silver chloride and zinc chloride solution produced. Apabila larutan argentum nitrat ditambahkan kepada larutan zink klorida, mendakan putih argentum klorida dan larutan zink nitrat terhasil. (i) Name the reactants. Namakan bahan-bahan tindak balas. ............................................................................................................................. [ 1 mark] (ii) Name the products. Namakan hasil-hasil tindak balas. ................... [ 1 mark] (iii) Write the chemical equation for the reaction take place. Tuliskan persamaan bagi tindak balas yang berlaku. .................... [ 1 mark]
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(c) Silver chloride decomposed when it is strongly heated according to equation below: Argentum nitrat terurai apabila dipanaskan dengan kuat mengikut persamaan di bawah : 2AgNO3 2Ag + 2NO2 + O2

(i) When 1 mol of silver nitrate is heated, calculate number of mole of silver and number of mole of oxygen gas produced. Jika 1 mol argentum nitrat dipanaskan, hitungkan bilangan mol argentum dan bilangan mol gas oksigen yang terhasil.

[ 2 marks] (ii) In an experiment, a student heated 85 g of silver nitrate. Dalam satu eksperimen, seorang pelajar telah memanaskan 85 g argentum nitrat. Calculate number of mole of silver nitrate and volume of nitrogen dioxide released at room condition. Hitungkan bilangan mol argentum nitrat dan isipadu gas nitrogen dioksida yang terbebas pada keadaan bilik [ Relative atomic mass / Jisim atom relatif : N, 14; O, 16; Ag, 108 ; 1 mol of gas occupies 24.0 dm3 at room condition. 1 mol gas menempati 24.0 dm3 pada keadaan bilik ]

[ 3 marks]

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Table 2.1 shows proton number and nucleon number for elements of M, N and Q which are placed in the same group in the Periodic Table of element. Jadual 2.1 menunjukkan nombor proton dan nombor nukleon bagi unsur M, N dan Q yang terletak pada kumpulan yang sama dalam Jadual Berkala Unsur. Element Unsur M N Q Proton Number Nombor Proton 3 11 19 TABLE / JADUAL 2.1 (a) State the nucleon number of Q if the number of neutron in an atom Q is 20. Nyatakan nombor nukleon Q jika bilangan neutron dalam satu atom Q ialah 20. ... [ 1 mark ] (b) (i) What is the number of electron for atom M? Berapakah bilangan elektron atom M? ..... (ii) Write the electron arrangement for ion that formed from atom N. Tuliskan susunan elektron bagi ion yang terbentuk daripada atom N .
(iii) State the group for element M in the Periodic Table.

Nucleon Number Nombor Nukleon 7 23 -

Nyatakan kumpulan bagi unsur M dalam Jadual Berkala Unsur . [ 3 marks ] (c ) State one physical property for element of M, N and Q. Nyatakan satu sifat fizik unsur- unsur M, N dan Q . . .. . [ 2 marks ] (d) In an experiment, solid M is heated and then added to gas jar containing chlorine gas. Experiment is repeated by using solid N. Dalam satu eksperimen pepejal M dipanaskan dan kemudian dimasukkan ke dalam balang gas berisi gas klorin. Eksperimen diulangi dengan menggunakan pepejal N. (i) Write the chemical equation for the reaction occurs between solid M and chlorine. Tuliskan persamaan kimia bagi tindak balas yang berlaku antara pepejal M dengan klorin.
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.. [ 1 mark ]
(ii) State the type of bond formed in the both compound.

Nyatakan jenis ikatan yang terbentuk dalam kedua-dua sebatian. .... [ 1 mark ] (iii) The experiment showed N is more reactive than M. Explain. Eksperimen tersebut menunjukkan N lebih reaktif daripada M. Jelaskan. . . ..... [ 3 marks ] 3 Diagram 3.1 shows a simple voltaic cell. Rajah 3.1 menunjukkan satu sel kimia ringkas. 1.8 V V
Aluminum plate Kepingan aluminium Copper plate Kepingan kuprum

Copper (II) nitrate solution Larutan kuprum(II) nitrat

DIAGRAM / RAJAH 3.1 (a) State the energy change occurs in the simple voltaic cell. Nyatakan perubahan tenaga yang berlaku dalam sel kimia ringkas itu. ......................................................................................................................................... [1 mark] (i) Name the negative terminal. Namakan terminal negatif .................................................................................................................................. [1 mark] (ii) Explain your answer in (b) (i).
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(b)

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Terangkan jawapan anda di (b) (i) .................................................................................................................................. [1 mark] (iii) Write the half equation for the reaction occurs at negative terminal. Tuliskan setengah persamaan bagi tindak balas yang berlaku di terminal negatif. .................................................................................................................................. [1 mark] (c) (i) State the observation at copper plate. Nyatakan pemerhatian pada kepingan kuprum ................................................................................................................................ [1 mark] (ii) Write the half equation for the reaction occurs at copper plate. Tuliskan setengah persamaan bagi tindak balas di yang berlaku di kepingan kuprum .................................................................................................................................. [1 mark] (d) Write the ionic equation for the reaction occurs in the cell. Tuliskan persamaan ion bagi tindak balas yang berlaku dalam sel itu ......................................................................................................................................... [1 mark] (e) Mark the movement of electron in the diagram 3.1. Tandakan arah pergerakan elektron pada gambar rajah 3.1 [1 mark] (f) An another experiment is carry out by replacing copper plate with zinc, magnesium and lead alternately. The table below shows the result of experiment. Satu eksperimen lain dijalankan dengan menggantikan kepingan aluminium dengan zink, magnesium dan plumbum secara bergilir-gilir. Jadual di bawah menunjukkan keputusan eksperimen. Pair of metal Pasangan logam Mg/Cu Zn/Cu Pb/Cu Voltage value Nilai voltan (V) 2.7 1.1 0.5 TABLE / JADUAL 3.1 (i) Arrange metal Mg, Zn, Pb and Cu in ascending order of electropositivity. Susunkan logam Mg, Zn, Pb dan Cu mengikut tertib keelektropositifan menaik .................................................................................................................................
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Negative terminal Terminal negatif Mg Zn Pb

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[1 mark] (ii) Predict the voltage cell value for pair of Zn/Pb. Ramalkan nilai voltan sel bagi pasangan Zn/Pb .................................................................................................................................. [1 mark]
4

An experiment was carried out to determine the molarity of sulphuric acid solution. 20 cm3 of potassium hydroxide solution, 0.5 mol dm -3 is titrated with sulphuric acid solution using phenolphthalein indicator. Table 4.1 shows the result obtained. Satu eksperimen telah dijalankan untuk menentukan kemolaran larutan asid sulfurik. 20.0 cm3 larutan kalium hidroksida 0.5 mol dm -3 dititratkan dengan larutan asid sulfurik menggunakan penunjuk fenolftalein. Jadual 4.1 menunjukkan keputusan yang diperolehi. Experiment Eksperimen Final reading Bacaan akhir buret / cm3 Initial reading Bacaan awal buret / cm3 Volume of acid Isipadu asid / cm3 TABLE / JADUAL 4.1

1 16.10 1.20

2 31.20 16.10

3 25.20 10.20

(a) Complete the table above. Lengkapkan jadual di atas [1 mark] (b) Calculate the average of volume of acid used in the titration. Hitung purata isi padu asid yang digunakan bagi titratan ini

[1 mark]
(c) State the colour change of phenolphthalein in titration.

Nyatakan perubahan warna penunjuk fenolftalein dalam pentitratan ini .............................................................................................................................................. [1 mark] (d) Write the chemical equation for Tuliskan persamaan kimia bagi mewakili tindak balas yang berlaku. ................................................................................................................................................ [1 mark] (e) Calculate the molarity of sulphuric acid.
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Hitung kemolaran larutan asid sulfurik.

[3 marks] (f) (i) If sulphuric acid in the experiment is replaced by hydrochloric acid with the same molarity as sulphuric acid, predict the volume of hydrochloric acid used to neutralise 20.0 cm3 of potassium hydroxide solution, 0.5 mol dm -3. Jika asid sulfurik dalam eksperimen ini digantikan dengan asid hidroklorik yang mempunyai kemolaran yang sama dengan asid sulfurik, ramalkan isi padu asid hidroklorik digunakan untuk meneutralkan 20.0 cm3 larutan kalium hidroksida 0.5 mol dm -3 ........................................................................................................................................ [1 mark] (ii) Explain your answer in (g) (i). Terangkan jawapan anda di (g) (i) ........................................................................................................................................ ........................................................................................................................................ ........................................................................................................................................ [2 marks] 5 Table 5.1 shows the result obtained from an experiment to determine the rate of reaction between magnesium ribbon with excess hydrochloric acid solution. The volume of gas released during the reaction was recorded every 30 second. Jadual 5.1 di bawah menunjukkan keputusan yang diperolehi daripada satu eksperimen untuk menentukan kadar tindak balas antara pita magnesium dengan larutan asid hidroklorik berlebihan. Isipadu gas yang dibebaskan semasa tindak balas dicatat setiap 30 saat. Time / second Masa/ saat Experiment 1 Eksperimen I Total of gas volume Jumlah Isipadu gas / cm3 0 30 6 0 90 120 15 0 18 0 210 24 0 270 30 0 33 0 360

15

3 0

42

54

66

75

84

90

96

99

99

99

TABLE / JADUAL 5.1


(a) (i) Write the chemical equation for the reaction.

Tuliskan persamaan tindak balas yang terlibat.


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(ii)

.. [1 mark] Draw a graph volume of gas against time on the graph paper. Lukiskan graf isipadu gas melawan masa pada kertas graf. [3 marks]

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(iii) Based on the graph in (b), determine the average of rate of reaction. Berpandukan graf di (b) tentukan kadar tindak balas purata bagi tindak balas tersebut. [2 marks] (b) A student was carried out two experiments to determine the factor that affect the rate of reaction between hydrochloric acid with magnesium. Table 5.2 shows the result. Seorang pelajar telah menjalankan dua eksperimen untuk menentukan faktor yang mempengaruhi kadar tindak balas antara asid hidrokorik dengan magnesium. Jadual 5.2 di bawah menunjukkan keputusan yang diperolehi. Experiment Eksperimen Experiment Eksperimen I
Excess hydrochloric acid + 2 g of magnesium ribbon. Asid hidroklorik berlebihan + 2 g pita magnesium

Time taken for all magnesium dissolve Masa yang diambil untuk semua magnesium melarut/s

40

Experiment Excess Eksperimen II hydrochloric acid +


2 g of magnesium powder Asid hidroklorik berlebihan + 2 g serbuk magnesium

20

TABLE / JADUAL 5.2 (i) Referring to collision theory, explain why there is difference in result in experiment I and Experiment II. Merujuk kepada teori perlanggaran, terangkan mengapa terdapat perbezaan keputusan dalam Eksperimen I dan Eksperimen II. ................................................................................................................................. ................................................................................................................................. .................................................................................................................................. [3 marks]
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(ii) State another method to quicken magnesium dissolving in the hydrochloric acid. Nyatakan satu kaedah lain bagi mempercepatkan magnesium melarut di dalam asid hidroklorik. .................................................................................................................................. [1 mark] 6 Diagram 6.1 shows the set-up of apparatus to study the redox reaction involving the transfer of electron at a distance. Rajah 6.1 menunjukkan susunan radas mengkaji tindak balas redoks yang melibatkan pemindahan elektron pada satu jarak.

Potassium iodide solution Larutan kalium iodida

Carbon rod Iron(III) sulphate solution Larutan ferum(III) sulfat

Dilute sulphuric acid Asid sulfuric cair

DIAGRAM / RAJAH 6.1 (a) On the diagram 6.1, mark the direction of electron flow by drawing an arrow. Pada rajah 6.1, tandakan arah pengaliran elektron dengan melukis anak panah. [ 1 mark ] (b) What is the function of dilute sulphuric acid? Apakah fungsi larutan asid sulfurik cair? ................................................................................................................................ [ 1 mark ] (c) (i) What is the colour change happen at electrode A? Apakah perubahan warna yang berlaku di elektrod A ... [ 1 mark ] (ii) Write the half equation for the reaction occur at electrode A. Tuliskan setengah persamaan bagi perubahan yang berlaku di elektrod A. ... [ 1 mark ] (iii) Name the type of reaction occur at A. Namakan jenis tindak balas yang berlaku di A

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... [ 1 mark ]
(d) (i) Write the oxidation number change for iron in the reaction.

Tuliskan perubahan nombor pengoksidanan bagi ferum dalam tindak balas di atas. ... [ 1 mark ] (ii) Give one test to determine the product around the electrode B. Berikan satu ujian untuk menentukan hasil yang di sekitar elektrod B. ................................................................................................................................ ................................................................................................................................. [ 2 mark ] (e) An another experiment is carried out to replace iron (III) sulphate with acidified potassium manganate (VII). The reaction occurred at carbon rod B can be represented by the following half equation: Satu eksperimen lain dijalankan menggantikan ferum(III) sulfat dengan larutan kalium mangganat(VII) berasid. Tindak balas yang berlaku di sekitar rod karbon B boleh diwakili oleh setengah persamaan tindak balas saperti berikut: MnO4+ 8H+ + 5eMn 2+ + 4H2O

(i) What is the colour change happen at carbon rod B? Apakah perubahan warna yang berlaku di sekitar rod karbon B? ................................................................................................................................ [ 1 mark ]
(ii) Determine the oxidation number for manganese in MnO4-.

[ Oxidation number for oxygen is -2 ] Tentukan nombor pengoksidaan bagi mangan dalam MnO4-. [ nombor pengoksidaan bagi oksigen ialah 2] [ 1 mark ]

Section B
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Bahagian B [20 marks] Answer any one question from this section Jawab mana-mana satu soalan daripada Bahagian ini 1 (a) What is the meaning of the following terms by giving one suitable example. Apakah yang dimaksudkan dengan istilah berikut dengan memberikan satu contoh yang sesuai. (i) Proton number Nombor proton (ii) Nucleon number Nombor nukleon (iii) Isotope Isotop [ 6 marks ] 2 Diagram below shows the conversion of carbon compounds involved several series of reaction. Rajah dibawah menunjukkan penukaran sebatian karbon yang melibatkan beberapa siri tindak balas.

Propane propana

+ H2 Heat panaskan

Alkane M Alkena M

Porcelain chips Serpihan porselin Heat panaskan

propanol

DIAGRAM/ RAJAH 2.1 (a) Draw structural formula for isomers of propanol. Lukiskan formula struktur bagi isomer propanol Name the isomers. Namakan isomer itu. [ 4 marks]

(b) The following is the information about alkane M.


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Berikut ialah maklumat tentang alkena M :

Carbon Karbon : 85.7 % Hydrogen Hidrogen : 14.3 % Relative atomic mass Jisim molekul relatif : 42 Relative atomic mass for H = 1 and C = 12 Jisim atom relatif bagi H = 1 dan C = 12

Based on the information above: Berdasarkan maklumat di atas : (i) (ii)


(iii) (iv)

Determine the molecular formula Tentukan formula molekul Draw the structural formula Lukiskan formula struktur Name the alkene Namakan alkena itu Write the general formula for the homologous series of the alkene. Tuliskan formula am bagi siri homolog alkena itu [ 8 marks ] ( c) The statement below is about alkane and alkene compounds. Pernyataan di bawah adalah tentang sebatian alkana dan alkena Alkene M and propane can be distinguished through addition reaction. Alkena M dan propana boleh dibezakan dengan tindak balas penambahan Describe the procedure of experiment, observation and conclusion to prove the statement above by using bromine water. Huraikan prosedur eksperimen, pemerhatian dan kesimpulan untuk membuktikan pernyataan di atas, dengan menggunakan air bromin. [ 4 marks ] (d) The conversion of propanol to alkene M is done by dehydration process. Penukaran propanol kepada alkena M dilakukan melalui proses pendehidratan With the help of diagram, describe briefly how the conversion can be done in the laboratory. Dengan bantuan gambar rajah, huraikan dengan ringkas bagaimana penukaran itu dapat dijalankan di makmal. [ 4 marks ]

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Section C Bahagian C [20 marks] Answer any one question from this section Jawab mana-mana satu soalan daripada Bahagian ini 3 (a) What is the meaning of heat of neutralisation? Apakah yang dimaksudkan dengan haba peneutralan? [ 1 mark ] (b) Table 3.1 shows the heat of neutralisation for the reaction I, II and III using different acid reacted with sodium hydroxide solution. Jadual 3.1 menunjukkan haba peneutaralan bagi tindak balas I , II dan III menggunakan asid berlainan yang ditindak balaskan dengan larutan natrium hidroksida. Reaction Tindak balas I II III Chemical Equation Persamaan kimia HCl + NaOHNaCl + H2O CH3COOH +NaOHCH3COONa +H2O H2SO4 + 2NaOHNa2SO4 + 2H2O TABLE / JADUAL 3.1 (i) Explain why there is different in heat of neutralisation value in the reaction I and II. Terangkan mengapa terdapat perbezaan nilai haba peneutralan dalam tindak balas I dan II. [ 3 marks ]
(ii) Reaction III has heat of neutralisation x kJmol-1. Predict the value of x and

Heat of neutralisation Haba peneutralan, H(kJmol-1) -57.0 -55.2 x

explain why. Tindak balas III mempunyai haba peneutralan sebanyak x kJmol-1.Ramalkan nilai x dan terangkan mengapa . [ 3 marks ] (iii) You are given the following substance: Sodium hydroxide 2.0 mol dm-3 , hydrochloric acid 2.0 mol dm-3 and ethanoic acid 2.0 mol dm-3 . Describe an experiment that can be done to compare the heat of neutralisation for the reaction I and reaction II. Your description should included table to record the result and steps of calculation involved. Anda dibekalkan dengan bahan berikut: Larutan natrium hidroksida 2.0 mol dm-3 , asid hidroklorik 2.0 mol dm-3 dan asid etanoik 2.0 mol dm-3. Huraikan satu eksperimen yang dapat dijalankan untuk membandingkan haba peneutralan bagi tindak balas I dan tindak balas II. Huraian anda perlu mengandungi jadual bagi merekod keputusan dan langkah-langkah penghitungan yang terlibat. [ 13 marks ]
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(a) Petronas Twin Tower is one of the tallest buildings in the world. The construction material for this building is made of various type of composite material. Menara Berkembar Petronas merupakan antara bangunan yang tertinggi di dunia. Bahan binaan bangunan ini di perbuat daripada pelbagai jenis bahan komposit. Explain the statement above by giving a suitable composite material used, composition, special characteristics and uses. Terangkan pernyataan di atas dengan memberi satu contoh bahan komposit yang digunakan, komposisinya, sifat-sifat istimewanya dan kegunaannya. [ 5 marks ] (b) Ammonium sulphate is a type of chemical fertiliser. Describe how the ammonium sulphate fertiliser can be prepared in the laboratory starting with dilute sulphuric acid. Ammonium sulfat ialah sejenis baja kimia. Huraikan bagaimana baja ammonium sulfat dapat disediakan dalam makmal bermula dengan asid sulfurik cair . [ 10 marks ] (c) Aspirin is one of the examples of analgesic medicine that cannot be prescribed to children below 12 years old. Aspirin ialah satu contoh ubat analgesik yang tidak boleh digunakan oleh kanak-kanak yang berumur di bawah 12 tahun. Discuss the uses of aspirin and it effect to our health. Bincang penggunaan aspirin dan kesannya ke atas kesihatan kita. [ 5 marks ]

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KERTAS SOALAN TAMAT RUANGAN JAWAPAN Bahagaian:.. No soalan:.

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