Chapter1 Measurements 1.

1 Multiple-ChoiceQuestions
1) 5.21cmisthesamedistanceas A) 0.0521m. B) 52.1dm. C) 5.21mm. D) 0.00521km. E) 5210m. Answer: A 2) Howmanycentimetersaretherein57.0in.? A) 22cm B) 0.0445cm C) 145cm D) 22.4cm E) 140cm Answer: C 3) Theamountofspaceoccupiedbyasubstanceisits A) mass. B) density. C) weight. D) length. E) volume. Answer: E 4) Whichofthefollowingisameasurementofmassinthemetricsystem? A) milliliter B) centimeter C) kilogram D) Celsius E) meter Answer: C 5) Avalueof25Cisameasurementof A) distance. B) volume. C) temperature. D) mass. E) density. Answer: C 6) Themeasurementofthegravitationalpullonanobjectisits A) volume. B) weight. C) mass. D) length. E) size. Answer: B

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7) Whichofthefollowingisthebasicunitofvolumeinthemetricsystem? A) liter B) kilogram C) meter D) centimeter E) gram Answer: A 8) Themeasurement0.0000043m,expressedcorrectlyusingscientificnotation,is A) 4.3x10-7 m. B) 4.3x10-6 m. C) 4.3x106 m. D) 0.43x10-5 m. E) 4.3m. Answer: B 9) Thenumber680000000expressedcorrectlyusingscientificnotationis A) 6.8. B) 0.68x106 . C) 6.8x108 . D) 68x107 . E) 680x106 . Answer: C 10) Whichofthefollowingnumbersisthesmallest? A) 4.0x10-6 B) 4.0x10-8 C) 4.0x10-2 D) 4.0x1015 E) 4.0x10-12 Answer: E 11) Whichofthefollowingnumbersisthelargest? A) 2.05x103 B) 2.05x10-12 C) 2.05x105 D) 2.05x108 E) 2.05 Answer: D 12) Whichofthefollowingconversionfactorsisameasurednumber? A) 10cm/dm B) 12in/ft C) 16oz/lb D) 25miles/gallon E) 12eggs/dozen Answer: D

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13) Significantfiguresareimportantbecausetheyindicate A) theaccuracyofameasurement. B) thenumberofdigitsonacalculator. C) thenumberofmeasurements. D) theprecisionofameasurement. E) theaccuracyoftheconversionfactor. Answer: D 14) Whichofthefollowingmeasurementshasthreesignificantfigures? A) 0.005m B) 510m C) 0.510m D) 0.051m E) 5100m Answer: C 15) WhichofthefollowingnumberscontainsthedesignatedCORRECTnumberofsignificantfigures? A) 0.04300 5significantfigures B) 0.00302 2significantfigures C) 156000 3significantfigures D) 1.04 2significantfigures E) 3.0650 4significantfigures Answer: C 16) Thenumberofsignificantfiguresinthemeasurementof45.030mmis A) none. B) three. C) four. D) five. E) six. Answer: D 17) Howmanysignificantfiguresareinthenumber0.00208? A) six B) two C) three D) four E) five Answer: C 18) Whichofthefollowingexamplesillustratesanumberthatiscorrectlyroundedtothreesignificantfigures? A) 4.05438gramsto4.054grams B) 0.03954gramsto0.040grams C) 103.692gramsto103.7grams D) 109,526gramsto109500grams E) 20.0332gramsto20.0grams Answer: E

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19) Acalculatoranswerof423.6059mustberoundedofftothreesignificantfigures.Whatanswerisreported? A) 423 B) 424 C) 420 D) 423.6 E) 423.7 Answer: B 20) Whichoftheanswersforthefollowingconversionscontainsthecorrectnumberofsignificantfigures? 39.4in =100.1942in A) 2.543m 1m B) 2L 1.06qt =2.12qt 1L 1hr =0.4158hr 60min

C) 24.95min D) 12.0ft

2.54cm 12in. x =370cm 1in 1ft 1lb =11lb 2.20kg

E) 24.0kg Answer: C

21) Whatisthecorrectanswerforthecalculationofavolume(inmL)withmeasurednumbers A) 0.22mL B) 0.223mL C) 57mL D) 14mL E) 14.3mL Answer: A

28.58 ? 168.02

22) Aresearcherneededthreesamplesofsodiumchloridesolution,eachwithavolumeof0.03510mL.Thetotal volumeneededshouldbereportedas A) 0.105mL. B) 0.0105mL. C) 0.10mL. D) 0.1053mL. E) 0.1100mL. Answer: D 23) Whatistheanswer,withthecorrectnumberofsignificantfigures,forthisproblem? 4.392g+102.40g+2.51g= A) 109.302g B) 109g C) 109.3g D) 109.30g E) 110g Answer: D

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24) Thecorrectanswerfortheadditionof7.5g+ 2.26g+ 1.311g+ 2gis A) 13.071g. B) 13g. C) 13.0g. D) 10g. E) 13.1g. Answer: B 25) WhichofthefollowingmeasurementsareNOTequivalent? A) 25mg=0.025g B) 183L=0.183kL C) 150msec=0.150sec D) 84cm=8.4mm E) 24dL=2.4L Answer: D 26) Inwhichofthefollowingisthemetricunitpairedwithitscorrectabbreviation? A) microgram/mg B) milliliter/mL C) centimeter/km D) kilogram/cg E) gram/gm Answer: B 27) Whichofthefollowingisthelargestunit? A) millimeter B) micrometer C) meter D) decimeter E) kilometer Answer: E 28) Whatisthemetricrelationshipbetweengramsandmicrograms? A) 1g=100g B) 1g=1000000g C) 1g=0.000001g D) 1g=1000g E) 1g=0.001g Answer: B 29) Whatistheconversionfactorfortherelationshipbetweenmillimetersandcentimeters? A) 1mm/1cm B) 10mm/1cm C) 1cm/1mm D) 100mm/1cm E) 10cm/1mm Answer: B

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30) Whichofthefollowingisthesmallestunit? A) gram B) milligram C) kilogram D) decigram E) microgram Answer: E 31) Thecubiccentimeter(cm 3 orcc)hasthesamevolumeasa A) cubicinch. B) cubicliter. C) milliliter. D) centimeter. E) cubicdecimeter. Answer: C 32) 9.31gisthesamemassas A) 931g. B) 931kg. C) 93.1cg. D) 9310mg. E) 0.0931dg. Answer: D 33) AccordingtotheUnitedStatesFoodandDrugAdministration,therecommendeddailyrequirementofprotein is44g.Thisis________ofprotein. A) 1248.5oz B) 320000oz C) 1.6oz D) 0.0605oz E) 150000oz Answer: C 34) Whichofthefollowingsetupswouldconvertcentimeterstofeet? 2.54in. 1ft A) cm 1cm 12in. B) cm C) cm D) cm E) cm Answer: C 2.54cm 12in. 1in. 1ft 1in. 1ft 2.54cm 12in. 1in. 12in. 2.54cm 1ft 2.54cm 1ft 1in. 12in.

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35) Aconversionfactorsetupcorrectlytoconvert15inchestocentimetersis A) 100cm/1m. B) 1inch/2.54cm. C) 1cm/10mm. D) 2.54cm/1inch. E) 10cm/1inch. Answer: D 36) Howmanypoundsarein3.5kg? A) 7.7lb B) 1.59lb C) 0.629lb D) 1.6lb E) 7.70lb Answer: A 37) Howmanylitersofsoftdrinkaretherein5.25qt? A) 4950L B) 55.7L C) 4.95L D) 5.57L E) 5.0L Answer: C 38) Whatis6.5mconvertedtoinches? A) 1700in B) 1651in C) 39in D) 260in E) 255.9in Answer: D 39) Carrotsare$0.79perpound.Whatisthecostof1.2kgofcarrots? A) $2.10 B) $0.43 C) $1.45 D) $0.79 E) $0.95 Answer: A 40) Howmanykilogramsarein30.4lb? A) 13.8kg B) 14kg C) 67kg D) 66.88kg E) 66.9kg Answer: A

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41) Anuggetofgoldwithamassof521gisaddedto50.0mLofwater.Thewaterlevelrisestoavolumeof77.0 mL.Whatisthedensityofthegold? A) 10.4g/mL B) 6.77g/mL C) 1.00g/mL D) 0.0518g/mL E) 19.3g/mL Answer: E 42) Adoseofaspirinof5.0mgperkilogramofbodyweighthasbeenprescribedtoreducethefeverofaninfant weighing8.5pounds.Thenumberofmilligramsofaspirinthatshouldbeadministeredis A) 19mg. B) 53mg. C) 1.6mg. D) 5.0mg. E) 0.59mg. Answer: A 43) Adoctorsorderis0.125gofampicillin.Theliquidsuspensiononhandcontains250mg/5.0mL.Howmany millilitersofthesuspensionarerequired? A) 0.0025mL B) 3.0mL C) 2.5mL D) 6.3mL E) 0.0063mL Answer: C 44) Whichoneofthefollowingsubstanceswillfloatingasoline,whichhasadensityof0.66g/mL? A) tablesalt (density=2.16g/mL) (density=0.16g/mL) B) balsawood C) sugar (density=1.59g/mL) D) aluminum (density=2.70g/mL) E) mercury (density=13.6g/mL) Answer: B 45) Whatisthemassof2.00Lofanintravenousglucosesolutionwithadensityof1.15g/mL? A) 0.023kg B) 2.30kg C) 1.15kg D) 0.015kg E) 0.58kg Answer: B 46) Mercuryhasaspecificgravityof13.6.Howmanymillilitersofmercuryhaveamassof0.35kg? A) 0.0257mL B) 0.026mL C) 25.7mL D) 26mL E) 4760mL Answer: D

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47) Whatisthedensityofasubstancewithamassof45.00gandavolumeof26.4mL? A) 1.70g/mL B) 1.7g/mL C) 0.59g/mL D) 0.587g/mL E) 45.0g/mL Answer: A 48) Whatisthemassof53mLofethanol,whichhasadensityof0.79g/mL? A) 67.1g B) 41.9g C) 42g D) 67g E) 53g Answer: C 49) Thedensityofasolutionis1.18g/mL.Itsspecificgravityis A) 11.8. B) 0.118. C) 0.847. D) 1.18. E) 1.2. Answer: D 50) Diamondhasadensityof3.52g/mL.Whatisthevolumeincubiccentimetersofadiamondwithamassof15.1 g? A) 4.3cm3 B) 4.29cm3 C) 0.233cm3 D) 53cm3 E) 53.2cm3 Answer: B 51) Theratioofthemassofasubstancetoitsvolumeisits A) specificgravity. B) density. C) buoyancy. D) weight. E) conversionfactor. Answer: B 52) Whichofthefollowingisoftenusedtodetermineanindividualspercentageofbodyfat? A) temperature B) height C) weightloss D) weightgain E) density Answer: E

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53) A50.0mLurinesamplehasamassof50.7g.Thespecificgravityoftheurineis A) 1.014g/mL. B) 0.986g/L. C) 1.01. D) 0.986. E) 50.7. Answer: C 54) Atemperatureof41Fisthesameas A) 5C. B) 310C. C) -9C. D) 16C. E) 42C. Answer: A 55) Ifthetemperatureis20.C,whatisthecorrespondingtemperatureontheFahrenheitscale? A) -22F B) 68F C) 43F D) 239F E) 94F Answer: B 56) Apatienthasatemperatureof38.5C.WhatisthetemperatureindegreesFahrenheit? A) 70.5F B) 311F C) 126.95F D) 101.3F E) 11.7F Answer: D 57) Thetemperatureofliquidnitrogenis-196C.WhatisthecorrespondingreadingontheKelvinscale? A) 77K B) -127K C) -91K D) 48K E) 146K Answer: A 58) Onahotday,thethermometerread95F.WhatisthetemperatureindegreesCelsius? A) 77C B) 113C C) 35C D) 63C E) 178C Answer: C

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59) Absolutezerois A) thefreezingpointofwaterusingtheCelsiusscale. B) theboilingpointofliquidnitrogen. C) thetemperatureontheKelvinscalecorrespondingto32F. D) thecoldesttemperaturepossible. E) thefreezingpointofliquidnitrogen. Answer: D

1.2 ShortAnswerQuestions
Roundoffeachofthefollowingtothreesignificantfigures. 1) 504.85 Answer: 505 2) 8.3158 Answer: 8.32 3) 25,225 Answer: 25,200 4) 58.5422 Answer: 58.5 5) 0.0034088 Answer: 0.00341 Expresseachofthefollowingnumbersusingscientificnotation. 6) 351000000000 Answer: 3.51x1011 7) 0.000860 Answer: 8.60x10-4 8) 5207000 Answer: 5.207x106 9) 0.000000050 Answer: 5.0x10-8 Statethenumberofsignificantfiguresineachofthefollowingmeasurements. 10) 0.705m Answer: 3 11) 680000km Answer: 2 12) 28.050km Answer: 5 13) 0.0005L Answer: 1 Page11

14) 75.00m Answer: 4 15) 2.043x104 mm Answer: 4 16) 6.1x10-5 mL Answer: 2 17) 9.00x106 g Answer: 3 18) Atestperformedtodetermineifahypothesisisvalidiscalleda(n)________. Answer: experiment 19) Ahypothesiscanbetestedbyperforminga(n)________. Answer: experiment 20) Anobservationtakesplacewhena(n)________isnoted. Answer: naturalphenomenon 21) Namethestepsinthescientificmethod. Answer: observation,hypothesis,experiment,theory 22) Whennaturalphenomenaareexamined,anexplanationsupportedbyexperimentsistermeda________. Answer: theory

1.3 MatchingQuestions
Arethenumbersineachofthefollowingstatementsmeasuredorexact? 1) Column1: IntheU.S.systemthereare 5280feetinonemile. Column2: exact Answer: exact 2) Column1: Thepatientsbloodsugarlevel is350mg/dL. Column2: measured Answer: measured 3) Column1: Thereare452pagesinabook. Column2: exact Answer: exact 4) Column1: Therabbitweighs2.5pounds. Column2: measured Answer: measured

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5) Column1: Thereare100capsulesinthe bottle. Column2: exact Answer: exact 6) Column1: Thepatientstemperatureis 100.1F. Column2: measured Answer: measured Matchthetypeofmeasurementtotheunitgivenbelow. 7) Column1: milliliter Column2: volume Foil: density Answer: volume 8) Column1: mm Column2: distance Answer: distance 9) Column1: gram Column2: mass Answer: mass 10) Column1: 125K Column2: temperature Answer: temperature 11) Column1: kilometer Column2: distance Answer: distance Selectthecorrectprefixtocompletetheequality. 12) Column1: 1g=________kg Column2: 0.001 Answer: 0.001 13) Column1: 1m=________mm Column2: 1000 Answer: 1000

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14) Column1: 1cm=________mm Column2: 10 Answer: 10 15) Column1: 1dL=________mL Column2: 100 Answer: 100 16) Column1: 1mL=________cc Column2: 1 Answer: 1 Identifyeachactivityinthescientificmethod. 17) Column1: Youseethatstudentswho studyingroupsgetbetter gradesinchemistry. Column2: observation Foil: theory Answer: observation 18) Column1: Youformachemistrystudy group. Column2: experiment Answer: experiment 19) Column1: Youfindthatyourgradehas improvedafterworkingwith thegroup. Column2: observation Foil: theory Answer: observation 20) Column1: Youthinkthatstudyingwitha groupwouldimproveyour grade. Column2: hypothesis Answer: hypothesis

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Chapter2 AtomsandElements 2.1 Multiple-ChoiceQuestions

1) Theprimarysubstancesofwhichallotherthingsarecomposedare A) molecules. B) compounds. C) elements. D) electrons. E) protons. Answer: C 2) Auisthesymbolfor A) gold. B) silver. C) argon. D) aluminum. E) sodium. Answer: A Selectthecorrectsymbolfortheelement. 3) aluminum. A) Al B) Am C) Au D) Sn E) Ag Answer: A 4) iron. A) Ir B) Fs C) Fe D) In E) FE Answer: C 5) sodium. A) So B) Na C) No D) Sm E) Au Answer: B 6) potassium. A) P B) Po C) Pt D) K E) Ko Answer: D

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7) silver. A) S B) Si C) Ag D) Au E) AG Answer: C 8) Caisthesymbolfor A) calcium. B) carbon. C) cobalt. D) copper. E) cadmium. Answer: A 9) Whatelementsareinhydroxyapatite,Ca5 (PO4 )3 OH,amajorcompoundinhumanbonesandteeth? A) carbon,potassium,oxygen,hydrogen B) calcium,phosphorous,oxygen,hydrogen C) carbon,phosphorous,oxygen,helium D) calcium,phosphorous,oxygen,helium E) carbon,potassium,oxygen,helium Answer: B 10) Whichofthefollowingisacharacteristicofthemodernperiodictable? A) Agroupisahorizontalrowontheperiodictable. B) Aperiodisacolumnontheperiodictable. C) Theelementsineachgrouphavesimilarchemicalproperties. D) TheBgroupscontaintherepresentativeelements. E) TheAgroupscontainthetransitionelements. Answer: C 11) WhichofthefollowingpropertiesisNOTacharacteristicoftheGroup1Aelements(alkalimetals)? A) Theyareshiny. B) Theyaregoodconductorsofheat. C) Theyreactvigorouslywithwater. D) Mostofthemareliquidsatroomtemperature. E) Theyaregoodconductorsofelectricity. Answer: D 12) TheGroup8Aelements A) areunreactiveandarerarelyfoundincombinationwithotherelements. B) aregoodconductorsofelectricity. C) meltathightemperatures. D) areliquidsatroomtemperature. E) reactvigorouslywithwater. Answer: A

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13) Whichofthefollowingelementsisametal? A) nitrogen B) fluorine C) argon D) strontium E) phosphorus Answer: D 14) Whichofthefollowingisacharacteristicofnonmetals? A) shiny B) malleable C) goodconductorsofheat D) lowmeltingpoints E) goodconductorsofelectricity Answer: D 15) Whichofthefollowingelementsisanoblegas? A) oxygen B) chlorine C) bromine D) argon E) nitrogen Answer: D 16) Thesmallestparticleofanelementthatretainsthecharacteristicsoftheelementisa(n) A) electron. B) neutron. C) proton. D) atom. E) nucleus. Answer: D 17) AccordingtotheAtomicTheory, A) allatomsaredifferent. B) atomsareneithercreatednordestroyedduringachemicalreaction. C) atomsofthesameelementcombinetoformcompounds. D) allmatterismadeupoftinyparticlescalledelectrons. E) acompoundcancontaindifferentnumbersofatomsaslongasithasthesamekindsofatoms. Answer: B 18) Whichofthefollowingdescriptionsofasubatomicparticleiscorrect? A) Aprotonhasapositivechargeandamassofapproximately1amu. B) Anelectronhasanegativechargeandamassofapproximately1amu. C) Aneutronhasnochargeanditsmassisnegligible. D) Aprotonhasapositivechargeandanegligiblemass. E) Aneutronhasapositivechargeandamassofapproximately1amu. Answer: A

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19) Inanatom,thenucleuscontains A) anequalnumberofprotonsandelectrons. B) alltheprotonsandneutrons. C) alltheprotonsandelectrons. D) onlyneutrons. E) onlyprotons. Answer: B 20) Theatomicnumberofanatomisequaltothenumberof A) nuclei. B) neutrons. C) neutronsplusprotons. D) electronsplusprotons. E) protons. Answer: E 21) Thenumberofneutronsinanatomisequalto A) theatomicnumber. B) themassnumber. C) themassnumber+theatomicnumber. D) themassnumber-theatomicnumber. E) thenumberofprotons. Answer: D 22) Themassnumberofanatomcanbecalculatedfrom A) thenumberofelectrons. B) thenumberofprotonsplusneutrons. C) thenumberofprotons. D) thenumberofelectronsplusprotons. E) thenumberofneutrons. Answer: B 23) Whatisthemassnumberofanatomofpotassiumthathas20neutrons? A) 15 B) 19 C) 35 D) 39 E) 59 Answer: D 24) Consideraneutralatomwith30protonsand34neutrons.Theatomicnumberoftheelementis A) 30. B) 32. C) 34. D) 64. E) 94. Answer: A

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25) Consideraneutralatomwith30protonsand34neutrons.Themassnumberforthisatomis A) 30. B) 32. C) 34. D) 64. E) 94. Answer: D 26) Consideraneutralatomwith30protonsand34neutrons.Thenumberofelectronsinthisatomis A) 30. B) 32. C) 34. D) 64. E) 94. Answer: A 27) Howmanyprotonsareinanisotopeofsodiumwithamassnumberof25? A) 11 B) 14 C) 15 D) 25 E) 32 Answer: A 28) Consideranisotopeofsodiumwithamassnumberof25.Thenumberofneutronsinthisisotopeofsodiumis A) 11. B) 14. C) 16. D) 25. E) 32. Answer: B 29) Whichofthefollowinggivesthecorrectnumbersofprotons,neutrons,andelectronsinaneutralatomof 118 Sn? 50 A) 118protons,50neutrons,118electrons B) 118protons,118neutrons,50electrons C) 50protons,68neutrons,50electrons D) 68protons,68neutrons,50electrons E) 50protons,50neutrons,50electrons Answer: C 30) Isotopesareatomsofthesameelementthathave A) differentatomicnumbers. B) thesameatomicnumbersbutdifferentnumbersofprotons. C) thesameatomicnumbersbutdifferentnumbersofelectrons. D) thesameatomicnumberbutdifferentnumbersofneutrons. E) thesameatomicmassbutdifferentnumbersofprotons. Answer: D

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31) Thecorrectsymbolfortheisotopeofpotassiumwith22neutronsis 41 A) K. 19 B) C) D) E) 19 K. 41 37 P. 15 15 P. 37 22 K. 19

Answer: A 32) Theatomicmassofanelementisequalto A) itsmassnumber. B) itsatomicnumber. C) one-twelfthofthemassofacarbon-12atom. D) aweightedaveragemassofallofthenaturallyoccurringisotopesoftheelement. E) theaveragemassofallofthenaturallyoccurringisotopesoftheelement. Answer: D 33) Asampleofchlorinehastwonaturallyoccurringisotopes.TheisotopeCl -35(mass35.0amu)makesup75.8% ofthesample,andtheisotopeCl-37(mass=37.0amu)makesup24.3%ofthesample.Whatistheaverage atomicmassforchlorine? A) 36.0amu B) 35amu C) 36.6amu D) 35.5amu E) 35.521amu Answer: D 34) WhichofthefollowingisNOTtruefortheatoms 13N,14N,and 15N? A) Theyallhavethesamemassnumber. B) Theyareisotopes. C) Theyallhavethesameatomicnumber. D) Theyallhave7protons. E) Theyallhave7electrons. Answer: A 35) Theelementslithium,sodium,andpotassium A) areisotopesofeachother. B) areinthesameperiodofelements. C) havethesamenumberofneutrons. D) areinthesamegroup. E) havethesamemassnumber. Answer: D

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36) Theelectronarrangementofanyparticularatomshows A) thenumberofisotopespossible. B) adescriptionoftheshapeofeachelectronshell. C) thenumberofelectronsineachshell. D) adiagramofanatomicnucleus. E) themaximumnumberofelectronseachshellcanhold. Answer: C 37) Themaximumnumberofelectronsthatmayoccupythethirdenergylevelis A) 2. B) 8. C) 10. D) 18. E) 32. Answer: D 38) Whatistheelementwiththeelectronconfiguration1s2 2s2 2p 6 3s2 3p 5 ? A) Be B) Cl C) F D) S E) Ar Answer: B 39) Whatistheelectronconfigurationforaluminum? A) 1s2 2s2 2p 6 3s2 3p 1 B) 1s2 2s2 2p 6 3s2 3p 3 C) 1s2 2s2 2p 6 3s2 3p 5 D) 1s2 2s2 2p 6 3s2 3p 6 E) 1s2 2s2 2p 6 3s2 3p 8 Answer: A 40) Whatistheelectronconfigurationforpotassium(atomicnumber19)? A) 1s2 2s2 2p 6 3s2 3p 7 B) 1s2 2s2 2p 6 3s2 3p 5 3d 2 C) 1s2 2s2 2p 8 3s2 3p 5 D) 1s2 2s2 2p 6 3s2 3p 6 4s1 E) 1s2 2s2 2p 6 3s2 3p 5 4s1 Answer: D 41) Whatelementhastheelectronconfiguration1s2 2s2 2p 6 3s2 3p 2 ? A) carbon B) oxygen C) sulfur D) iron E) silicon Answer: E

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42) Thenumberofelectronsintheouterenergylevelofaneutralatomofboron(atomicnumber5)is A) 2. B) 3. C) 5. D) 8. E) 10. Answer: B 43) Whichelementwouldhavephysicalandchemicalpropertiessimilartochlorine? A) Ar B) Br C) S D) O E) P Answer: B 44) WhatisthesymboloftheelementinPeriod4andGroup2? A) Be B) Mg C) Ca D) C E) Si Answer: C 45) Whatisthecorrectelectronconfigurationforthelithiumatom? A) 1s3 B) 2s1 C) 1s1 2s2 D) 1s2 2s1 E) 1s2 2s5 Answer: D 46) Thenumberofelectronlevelsinamagnesiumatomis A) 1. B) 2. C) 3. D) 4. E) 5. Answer: C 47) Theelementinthislistwithchemicalpropertiessimilartomagnesiumis A) sodium. B) boron. C) carbon. D) strontium. E) chlorine. Answer: D

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48) Identifythenoblegasinthefollowinglist. A) helium B) nitrogen C) oxygen D) gold E) chlorine Answer: A 49) Identifythemetalloidinthefollowinglist. A) sulfur B) fluorine C) silver D) copper E) germanium Answer: E 50) Semiconductorsarelocatedintheperiodictableon(orin)the A) leftsideofthetable. B) rightsideofthetable. C) linedividingmetalsfromnonmetalsinthetable. D) firstperiodofthetable. E) lastperiodofthetable. Answer: C 51) Whatistheabbreviatedelectronconfigurationfornickel(atomicnumber28)? A) [He]2s2 2p 3 B) [Ar]4s2 3d 8 C) [Kr]4s2 3d 8 D) [Ar]4s2 4p 4 E) [Ar]3d 8 Answer: B 52) Whatistheelementwiththeabbreviatedelectronconfiguration[Kr]5s2 4d 8 ? A) Ni B) Pd C) Pt D) Kr E) Xe Answer: B

2.2 ShortAnswerQuestions
Writeintheelectronicconfigurationfortheatomshown. 1) Sodium Answer: 1s2 2s2 2p 6 3s1 2) Chlorine Answer: 1s2 2s2 2p 6 3s2 3p 5 3) Argon Answer: 1s2 2s2 2p 6 3s2 3p 6

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4) Sulfur Answer: 1s2 2s2 2p 6 3s2 3p 4 5) Magnesium Answer: 1s2 2s2 2p 6 3s2 6) Phosphorus Answer: 1s2 2s2 2p 6 3s2 3p 3

2.3 True/FalseQuestions
1) Sulfurisanon-metal. Answer: TRUE 2) Iodineisametal. Answer: FALSE 3) Chromuimisametal. Answer: TRUE 4) Radonisametal. Answer: FALSE 5) Mercuryisametal. Answer: TRUE 6) Alithiumatomislargerthanapotassiumatom. Answer: FALSE 7) Asodiumatomislargerthanasiliconatom. Answer: TRUE 8) Chlorinehasahigherionizationenergythanaluminum. Answer: TRUE 9) Chlorinehasahigherionizationenergythanfluorine. Answer: FALSE

2.4 MatchingQuestions
Dothefollowingrepresentelementsinagroup,aperiod,orneither? 1) Column1: Li,Na,K Column2: group Answer: group 2) Column1: Li,C,F Column2: period Answer: period 3) Column1: F,S,P Column2: neither Answer: neither Page24

4) Column1: O,S,Se Column2: group Answer: group 5) Column1: He,H,I Column2: neither Answer: neither Matchthecorrectsymbolswiththenamesofelements. 6) Column1: calcium Column2: Ca Answer: Ca 7) Column1: copper Column2: Cu Answer: Cu 8) Column1: carbon Column2: C Answer: C 9) Column1: chlorine Column2: Cl Answer: Cl 10) Column1: cobalt Column2: Co Answer: Co Givethecorrectnumberofelectrons. 11) Column1: intheouterenergylevelof nitrogen Column2: five Answer: five 12) Column1: inthesecondenergylevelof magnesium Column2: eight Answer: eight 13) Column1: inthehighestoccupiedenergy levelofchlorine Column2: seven Answer: seven Page25

14) Column1: inthefirstenergylevelof chlorine Column2: two Answer: two 15) Column1: inthethirdenergylevelof sodium Column2: one Answer: one Classifythefollowingelements. 16) Column1: sodium Column2: alkalimetal Answer: alkalimetal 17) Column1: argon Column2: noblegas Answer: noblegas 18) Column1: bromine Column2: halogen Answer: halogen 19) Column1: copper Column2: transitionelement Answer: transitionelement 20) Column1: magnesium Column2: alkalineearthmetal Answer: alkalineearthmetal Classifythefollowingelementsasmetals,nonmetalsormetalloids. 21) Column1: phosphorus Column2: nonmetal Answer: nonmetal 22) Column1: chlorine Column2: nonmetal Answer: nonmetal 23) Column1: cobalt Column2: metal Answer: metal

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24) Column1: sulfur Column2: nonmetal Answer: nonmetal 25) Column1: silicon Column2: metalloid Answer: metalloid 26) Column1: nickel Column2: metal Answer: metal

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Chapter3 NuclearRadiation 3.1 Multiple-ChoiceQuestions

1) Whatisthenuclearsymbolforaradioactiveisotopeofcopperwithamassnumberof60? 60 A) Cu 29 B) 29 Cu 60

C) 29Cu 60 D) Cu 31 E) 31 Cu 29

Answer: A 2) Theproductfromthealphadecayof A) B) C) D) E) 235 Np. 93 239 Pu. 94 231 Th. 90 233 Ra. 80 236 U. 92 235 Uis 92

Answer: C 4 3) Thenuclearsymbolofhelium, He,isalsothesymbolfordesignatinga(n) 2 A) proton. B) neutron. C) gammaray. D) betaparticle. E) alphaparticle. Answer: E 4) Thesymbol 0 eisasymbolusedfora(n) -1

A) proton. B) neutron. C) gammaray. D) betaparticle. E) alphaparticle. Answer: D

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5) Thesymbol

0 eisasymbolusedfora(n) +1

A) proton. B) positron. C) gammaray. D) betaparticle. E) alphaparticle. Answer: B 6) Whichofthefollowingtypesofradiationhasthehighestenergy? A) -particles B) -particles C) -rays D) visiblelight E) Allofthesehavethesameenergy. Answer: C 7) Thedamagingeffectsofradiationonthebodyarearesultof A) theformationofunstableionsorradicals. B) theformationofradioactiveatomsinthebody. C) transmutationreactionsinthebody. D) extensivedamagetonervecells. E) theproductionofradioactivesodiumionsinthebody. Answer: A 8) Whichofthefollowingissuitableasaminimumshieldingforbetaparticles? A) air B) 1mofwater C) gloves D) 1mofconcrete E) 1cmoflead Answer: C 9) For 85 Sr,thereare 38

A) 85protonsand38neutrons. B) 47protonsand38neutrons. C) 38protonsand47neutrons. D) 38protonsand85neutrons. E) 85protonsand47neutrons. Answer: C 10) WhichisNOTawaytominimizeyourexposuretoradiation? A) wearingaleadapron B) keepingagooddistance C) standingbehindathickconcretewall D) wearinglead-linedgloves E) stayingalongertime Answer: E

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11) Theprocessinwhichanucleusspontaneouslybreaksdownbyemittingradiationisknownas A) transmutation. B) transformation. C) fusion. D) achainreaction. E) radioactivedecay. Answer: E 12) Anuclearequationisbalancedwhen A) thesameelementsarefoundonbothsidesoftheequation. B) thesumofthemassnumbersandthesumoftheatomicnumbersoftheparticlesandatomsarethesame onbothsidesoftheequation. C) thesameparticlesandatomsareonbothsidesoftheequation. D) differentparticlesandatomsareonbothsidesoftheequation. E) thechargesoftheparticlesandatomsarethesameonbothsidesoftheequation. Answer: B 13) Thenuclearreactionshownbelowisanexampleofwhattypeofprocess? 4 224 220 Th Rn+ He 90 88 2 A) fusion B) fission C) translation D) alphaemission E) betaemission Answer: D 14) Inthenuclearequationofabetaemitter, A) thenewnucleuscontains2fewerprotons. B) thenewnucleuscontains2moreprotons. C) themassnumberofthenewnucleusis4lessthanthatoftheoriginalnucleus. D) thenewnucleuscontains1moreproton. E) thenewnucleuscontains1lessproton. Answer: D 15) Nitrogen-17isabetaemitter.Whatistheisotopeproducedintheradioactivedecay? 18 A) C 6 B) C) D) E) 13 B 5 18 N 7 13 F 9 17 O 8

Answer: E

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16) Thenuclearreaction 126 126 Sn Sb+? 50 51 isanexampleof A) fusion. B) fission. C) translation. D) alphaemission. E) betaemission. Answer: E 17) Whatistheradioactiveparticlereleasedinthefollowingnuclearequation? 90 90 Sr Y+? 38 39 A) alphaparticle B) betaparticle C) gammaray D) proton E) neutron Answer: B 18) Whatistheradioactiveparticlereleasedinthefollowingnuclearequation? 159 155 W Hf+? 74 72 A) alphaparticle B) betaparticle C) gammaray D) proton E) neutron Answer: A 19) Whatismissinginthenuclearreactionshownbelow? 10 4 13 B+ He N+____ 5 2 7 A) gammaradiation B) apositron C) aneutron D) analphaparticle E) abetaparticle Answer: C

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20) Whatistheradiationparticleusedinthebombardmentofnitrogen-14? 14 14 1 N+? C+ H 7 6 1 A) alphaparticle B) betaparticle C) gammaray D) proton E) neutron Answer: E 21) Whenaluminum-27isbombardedwithaneutron,agammarayisemitted.Whatradioactiveisotopeis produced? A) silicon-27 B) silicon-28 C) aluminum-28 D) magnesium-27 E) magnesium-28 Answer: C 22) Theunitusedtomeasuretheamountofradiationabsorbedbyagramofmaterialiscalledthe A) rad. B) RBE. C) curie. D) rem. E) MPD. Answer: A 23) Apatientreceives4.2x103 mradsofiodine-131,whichemits-particles.Ifthefactorthatadjustsfor biologicaldamageis1for-particles,howmanyremsdidthepatientreceive? A) 4 B) 0.4 C) 0.3 D) 2 E) 40 Answer: A 24) Apatientreceives10mradsofgammaradiation.Ifthefactorthatadjustsforbiologicaldamageforforgamma radiationis1,howmanymremsdidthepatientreceive? A) 2mrem B) 5mrem C) 10mrem D) 20mrem E) 200mrem Answer: C

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25) Asampleoftechnetium-99mhasanactivityof1.5Ci.Howmanydisintegrationsoccurinthetechnetium -99m samplein5.0sec? A) 5.6x1010 B) 2.8x1011 C) 1.1x1010 D) 7.5 E) 2.0x10-10 Answer: B 26) Whyisitimportantthatradioisotopesusedindiagnostictestshaveshorthalf -lives? A) Theseradioisotopeshaveagreateractivitysotheyareeasiertomonitor. B) Thisminimizestheharmfulsideeffectsoftheradiation. C) Thisisnecessarysotheradioisotopeswillhavehighenergy. D) Theseradioisotopesarelessexpensive. E) Theseradioisotopesaremoreabundantinnature. Answer: B 27) Apersonbeginstosufferradiationsicknessatanexposurelevelof A) 25rem. B) 5rem. C) 500rem. D) 100rem. E) 600rem. Answer: D 28) Themaximumpermissibledoseofradiationforoccupationalexposureis A) 1remperyear. B) 5remperyear. C) 25remperyear. D) 100remperyear. E) 500remperyear. Answer: B 29) Apositronisaparticleemittedfromthenucleusthathasthesamemassasa(n) A) electronbuthasapositivecharge. B) neutronbuthasapositivecharge. C) alphaparticle. D) betaparticle. E) protonemittedfromthenucleus. Answer: A 30) AnimagingtechniqueinwhichacomputermonitorsthedegreeofabsorptionofX -raybeamsisknownas A) positronemissiontomography(PET). B) magneticresonanceimaging(MRI). C) computerizedtomography(CT). D) radioactiveiodineuptake(RAIU). E) ascan. Answer: C

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31) Animagingtechniquethatdetectstheenergyemittedbyhydrogenatomsinamagneticfieldisknownas A) positronemissiontomography(PET). B) computerizedtomography(CT). C) magneticresonanceimaging(MRI). D) radioactivetracerstudy. E) supermagnetictomography(SMT). Answer: C 32) Thedosageoftechnetium-99mformyocardialimagingis280Ci/kgofbodyweight.HowmanymCishould begiventoapatientweighing65kg? A) 0.0043mCi B) 4.3mCi C) 18mCi D) 230mCi E) 1.8x104 mCi Answer: C 33) Apatientreceives3.0mLofasolutioncontainingtechnetium -99mforabreastimage.Iftheactivityofthe technetium-99mis9.5mCi/mL,whatisthedosereceivedbythepatient? A) 3.2mCi B) 29mCi C) 320Ci D) 9.5mCi E) 28.5mCi Answer: B 34) Sodium-24hasahalf-lifeof15hours.Howmanyhoursisthreehalf-lives? A) 60hours B) 45hours C) 30hours D) 15hours E) 7.5hours Answer: B 35) Thehalf-lifeofaradioisotopeis A) one-halfofthetimeittakesfortheradioisotopetocompletelydecaytoanonradioactiveisotope. B) thetimeittakesfortheradioisotopetobecomeanisotopewithone-halfoftheatomicweightofthe originalradioisotope. C) thetimeittakesfortheradioisotopetobecomeanisotopewithone-halftheatomicnumberofthe originalradioisotope. D) thetimeittakesfortheradioisotopetoloseone-halfofitsneutrons. E) thetimeittakesforone-halfofthesampletodecay. Answer: E 36) Iodine-123,whichisusedfordiagnosticimaginginthethyroid,hasahalf -lifeof13hours.If50.0mgofI-123 werepreparedat8:00A.M.onMonday,howmanymgremainat10:00A.M.onthefollowingday? A) 50.0mg B) 25.0mg C) 12.5mg D) 6.25mg E) 3.13mg Answer: C

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37) Awoodenobjectfromaprehistoricsitehasacarbon-14activityof10countsperminute(cpm)comparedto40 cpmfornewwood.Ifcarbon-14hasahalf-lifeof5730years,whatistheageofthewood? A) 1430yr B) 5730yr C) 11,500yr D) 17,200yr E) 22,900yr Answer: C 38) Krypton-79hasahalf-lifeof35hours.Howmanyhalf-liveshavepassedafter105hours? A) 1half-life B) 2half-lives C) 3half-lives D) 4half-lives E) 5half-lives Answer: C 39) Thehalf-lifeofbromine-74is25min.Howmuchofa4.0mgsampleisstillactiveafter75min? A) 0.50mg B) 1.0mg C) 2.0mg D) 0.25mg E) 4.0mg Answer: A 40) Whenanatomofuranium-235isbombardedwithneutrons,itsplitsintosmallernucleiandproducesagreat amountofenergy.Thisnuclearprocessiscalled A) fission. B) fusion. C) decomposition. D) chainreaction. E) ionization. Answer: A 41) Inthesun,nucleiofhydrogencombinetoformalargernucleusandreleaseagreatamountofenergy.The processisknownas A) fission. B) fusion. C) metathesis. D) chainreaction. E) ionization. Answer: B 42) Whenapositronisemittedfromthenucleusofanatom,thenuclearmass A) increasesbytwounits. B) decreasesbyoneunit. C) increasesbyoneunit. D) decreasesbytwounits. E) remainsthesame. Answer: E

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43) Gammaraysrequiretheheaviestshieldingofallthecommontypesofnuclearradiationbecausegammarays havethe A) highestenergy. B) mostintensecolor. C) lowestenergy. D) largestparticles. E) heaviestparticles. Answer: A 44) Ifabsorbedinternally,alphaparticleemittersarethemostdamagingbecausealphaparticles A) havethelargestcharge. B) havethegreatestenergy. C) havethegreatestmass. D) consistofhighenergyelectrons. E) consistofpureenergy. Answer: C 45) Radium-226decaysbyalphaemissionto A) barium-131. B) cobalt-60. C) carbon-14. D) polonium-218. E) radon-222. Answer: E 46) Iodine-131decaysbybetaemissionto A) iodine-132. B) tellurium-131. C) iodine-130 D) bromine-131 E) xenon-131. Answer: E 47) Asampleofcerium-141foradiagnostictestwasdissolvedinsalinesolutiontoanactivityof4.5 millicuries/mL.Ifthepatientundergoingthetestneedsadoseof10millicuries,howmuchofthesolution shouldbeinjectedintothepatient? A) 45mL B) .45mL C) 2.2mL D) 22mL E) 4.5mL Answer: C 48) Themostwidelyusedmedicalisotopeinnuclearmedicineis A) Tc-99m. B) I-131. C) P-32. D) I-125. E) Co-60. Answer: A

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49) TherecommendeddosageofI-131foratestis4.2microcuriesperkgofbodyweight.Howmanymillicuries shouldbegiventoa55kgpatient?(1mCi =1000Ci) A) 230millicuries B) 0.23millicuries C) 0.076millicuries D) 760millicuries E) 13.8millicuries Answer: B 50) Onesymptomofmildradiationsicknessis A) aloweredwhitecellcount. B) araisedwhitecellcount. C) aloweredredbloodcellcount. D) araisedredbloodcellcount. E) awhitecellcountofzero. Answer: A

3.2 ShortAnswerQuestions
1) Onesymbolfortheparticleis Answer: 0 e -1 0 .Anothersymbolforthesameparticleis________. -1

2) Asampleofphosphorus-32withanactivityof2.0mCiproduces________disintegrationspersecond. (1Ci=3.7x1010disintegrations/sec). Answer: 7.4x1010 3) Thecommonunitofradioactivitywhichisusedtomeasurethebiologicaldamageisthe________. Answer: rem 4) Theradioisotopeusedasadiagnostictooltomeasurethyroidfunctionis________. Answer: I-131 5) Thediagnosticimagingtechniquethatdependsonmagneticfieldsandradiowaves,notradioactivity,iscalled ________. Answer: mriormagneticresonanceimaging 6) Thetimeneededforaradioactivesampletodecaytoone-halfofitsoriginalactivityiscalledthe________. Answer: half-life 7) 235 1 91 1 U+ n________+ Kr+3 n+energy 92 0 36 0 Answer: 142 Ba 56

8) Theradiationdoserequiredtoproducedeathinone -halfoftheexposedsubjectanimalsistermedthe ________. Answer: LD50 9) 99 99m Tc Tc+________ 43 43 Answer: Page37

3.3 True/FalseQuestions
1) Exposuretoradiationisunavoidablebecausesomeradioactiveelementsoccurnaturally. Answer: TRUE 2) Onesymptomofradiationsicknessisanincreasedproductionofredbloodcells. Answer: FALSE 3) Ifthehalf-lifeofhydrogen-3is11.8years,aftertwohalf-livestheradioactivityofasamplewillbereducedto one-halfoftheoriginalamount. Answer: FALSE 3 4) Thecorrectsymbolforhydrogen-3is He. 2 Answer: FALSE 5) OnemCiofaradioactivesubstanceemitsmoreradiationthanone Ciofthesamesubstance. Answer: TRUE 6) Onetypeofradiationthatisnotusuallyusedformedicalproceduresisthecosmicray. Answer: TRUE 7) Xraysaregeneratedbythenucleusduringradioactivedecay. Answer: FALSE 8) Irradiationoffoodforsterilizationisusuallycarriedoutusinggammairradiation. Answer: TRUE 9) Nuclearfissionasusedinnuclearpowerplantsproducesradioactivewastewithlonghalf -lives. Answer: TRUE 10) Theproductionofnitrogen-13andaneutronfromboron-10bybombardmentwithahelium-4nucleusisan exampleofradioactivedecay. Answer: FALSE

3.4 MatchingQuestions
Indicatewhethereachofthefollowingischaracteristicofthefissionorfusionprocess. 1) Column1: Alargenucleusissplitinto smallernuclei. Column2: fission Answer: fission 2) Column1: Veryhightemperaturesmust beachievedtoinitiatethe reaction. Column2: fusion Answer: fusion

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3) Column1: Thisnuclearprocessprovides theenergyofthesun. Column2: fusion Answer: fusion 4) Column1: Thisprocessproduces radioactiveby-products. Column2: fission Answer: fission 5) Column1: Largeamountsofenergyare released. Column2: bothfissionandfusion Answer: bothfissionandfusion 6) Column1: Twosmallnucleicombineto formalargernucleus. Column2: fusion Answer: fusion ChoosethetypeofradiationfromColumn2thatbestmatcheseachiteminColumn1. 7) Column1: Column2: alphaparticle Answer: alphaparticle 8) Column1: Column2: betaparticle Answer: betaparticle 9) Column1: Column2: gammaray Answer: gammaray 10) Column1: 1 H 1

Column2: proton Answer: proton 11) Column1: 1 n 0

Column2: neutron Answer: neutron

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Chapter4 CompoundsandTheirBonds 4.1 Multiple-ChoiceQuestions

1) ThenumberofvalenceelectronsfoundinanatomofaGroupAelementisequalto A) itsatomicnumber. B) itsmassnumber. C) itsgroupnumber. D) eight. E) eightminusthegroupnumber. Answer: C 2) Valenceelectronsareelectronslocated A) intheoutermostenergylevelofanatom. B) inthenucleusofanatom. C) intheinnermostenergylevelofanatom. D) throughouttheatom. E) inthefirstthreeshellsofanatom. Answer: A 3) Inanelectron-dotstructureofanelement,thedotsareusedtorepresent A) alloftheelectronsintheatom. B) thevalenceelectrons. C) theelectronarrangement. D) onlytheelectronsthatwillparticipateinbondformation. E) theelectronsthattheelementwillgainwhenitformsacompound. Answer: B 4) Howmanyvalenceelectronsareintheelectron-dotstructuresfortheelementsingroup3A(13)? A) 1 B) 2 C) 3 D) 4 E) 6 Answer: C 5) Thenumberofelectronsinthehigherenergylevelofnitrogenis A) one. B) two. C) three. D) four. E) five. Answer: E 6) Thenumberofelectronsinthehigherenergylevelofcarbonis A) one. B) two. C) three. D) four. E) five. Answer: D

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7) Whichofthefollowingisthecorrectelectron-dotstructureforcarbon? A) B) C) D) E) Answer: C 8) Theoctetruleindicatesthat A) allofthenoblegaseshaveeighttotalelectrons. B) alloftheshellsinanatomholdamaximumof8electrons. C) alloftheGroupAelementshave8valenceelectrons. D) atomslose,gain,orsharevalenceelectronstohave8valenceelectrons. E) thenoblegasesreactwithothercompoundstoget8valenceelectrons. Answer: D 9) Inioniccompounds,________losetheirvalenceelectronstoformpositivelycharged________. A) metals;anions B) nonmetals;cations C) metals;polyatomicions D) nonmetals;anions E) metals;cations Answer: E 10) Howmanyelectronswillaluminumgainorlosewhenitformsanion? A) lose1 B) gain5 C) lose2 D) lose3 E) gain1 Answer: D 11) Whatisthesymbolfortheionwith19protonsand18electrons? A) F+ B) FC) Ar+ D) KE) K+ Answer: E 12) Toformanion,asodiumatom A) gainsoneelectron. B) gainstwoelectrons. C) losessevenelectrons. D) losesoneelectron. E) losestwoelectrons. Answer: D

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13) Ananionalways A) hasapositivecharge. B) containsagroupoftwoormoreatomswithapositivecharge. C) containsametalandanonmetal. D) formscovalentbonds. E) hasanegativecharge. Answer: E 14) Whatistheionicchargeofanionwith18protonsand15electrons? A) 1 + B) 2 + C) 3 + D) 2 E) 3 Answer: C 15) Thenumberofelectronsinanionwith20protonsandanionicchargeof2 - is A) 24. B) 22. C) 20. D) 18. E) 16. Answer: B 16) Elementsingroup2A(2)oftheperiodictableformionswithachargeof A) 1 + . B) 1 - . C) 2 + . D) 3 + . E) 0. Answer: C 17) Theionofaluminumis A) Al+ . B) Al2+ . C) Al3+ . D) Al3- . E) Al2- . Answer: C 18) Howmanyelectronswillchlorinegainorlosewhenitformsanion? A) lose1 B) gain1 C) lose7 D) gain2 E) lose3 Answer: B

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19) Anioniccompound A) hasanetpositivecharge. B) hasanetnegativecharge. C) containsonlycations. D) containsonlyanions. E) hasanetchargeofzero. Answer: E 20) ThecorrectformulaforacompoundformedfromtheelementsAlandOis A) AlO. B) Al2 O. C) Al3 O2 . D) AlO3 . E) Al2 O3 . Answer: E 21) ThecorrectformulaforthecompoundformedfromMgandSis A) MgS. B) MgS2 . C) Mg 2 S. D) Mg 2 S2 . E) Mg 2 S3 . Answer: A 22) Whichoneofthefollowingcompoundscontainsanionwitha3 + charge? A) KCl B) Na2 O C) FeCl 3 D) CuCl E) MgCl 2 Answer: C 23) Whatisthecorrectformulafortheoxideion? A) O2B) O C) O+ D) O2+ E) O3+ Answer: A 24) ThecompoundMgCl 2 isnamed A) magnesiumchlorine. B) magnesiumdichloride. C) magnesium(II)chloride. D) magnesiumchloride. E) dimagnesiumchloride. Answer: D

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25) Whichoneofthefollowingelementsformstwoormoreionswithdifferentioniccharges? A) K B) F C) Ca D) O E) Fe Answer: E 26) Whatisthecorrectformulafortheiron(II)ion? A) Fe + B) Fe 2+ C) Fe 3+ D) Fe 2E) Fe 3Answer: B 27) ThenameoftheCu+ ionis A) copper(II). B) copper(I). C) cobalt. D) copper. E) cuprum. Answer: B 28) Whatisthecorrectformulaforiron(III)sulfide? A) Fe 2 S2 B) Fe 2 S C) FeS D) FeS2 E) Fe 2 S3 Answer: E 29) A(n)________isthesmallestneutralunitoftwoormoreatomsheldtogetherbyacovalentbond. A) ioniccompound B) nucleus C) molecule D) formula E) unit Answer: C 30) Inamoleculewithcovalentbonding, A) oppositelychargedionsareheldtogetherbystrongelectricalattractions. B) atomsofmetalsformbondstoatomsofnonmetals. C) atomsofdifferentmetalsformbonds. D) atomsareheldtogetherbysharingelectrons. E) atomsofnoblegasesareheldtogetherbyattractionsbetweenoppositelychargedions. Answer: D

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31) WhichofthefollowingelementsdoesNOTexistasadiatomicmolecule? A) hydrogen B) nitrogen C) chlorine D) oxygen E) carbon Answer: E 32) Inacovalentlybondedmolecule,thenumberofelectronsthatanatomshareswithothersisusuallyequalto thenumberofelectrons A) intheatom. B) initsnucleus. C) inalltheatoms. D) initsion. E) neededtogiveitanoblegasarrangement. Answer: E 33) Doubleandtriplebondsformbecause A) theatomsinvolvedhavehighelectronegativities. B) singlecovalentbondsdonotgivealloftheatomsinthemoleculeeightvalenceelectrons. C) oneoftheatomsinthemoleculehasmorethaneightvalenceelectrons. D) theionsinvolvedhavechargeslargerthanone. E) thereisatleastonehydrogenatominvolvedinthebond. Answer: B 34) TheformulaforamoleculeformedfromNandClwouldbe A) NCl. B) NCl2 . C) NCl3 . D) N3 Cl. E) NCl5 . Answer: C 35) Thetypesofcompoundthatuseprefixesintheirnamesare A) ioniccompounds. B) ioniccompoundsinvolvingtransitionmetals. C) polyatomicions. D) covalentcompounds. E) compoundsthatcontainpolyatomicions. Answer: D 36) ThecorrectnameforthecompoundN2 O3 is A) nitrogenoxide. B) nitrogentrioxide. C) dinitridetrioxide. D) dinitrogenoxide. E) dinitrogentrioxide. Answer: E

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37) Whatistheformulaofcarbontetraiodide? A) CI B) CI 4 C) C4 I D) CI 3 E) C2 I4 Answer: B 38) ThenameofAl2 (SO4 )3 is A) aluminum(III)sulfate. B) dialuminumtrisulfate. C) dialuminumsulfate. D) dialuminumtrisulfide. E) aluminumsulfate. Answer: E 39) Theabilityofanatomtoattractthesharedelectronsinacovalentbondisits A) electronegativity. B) bondingability. C) polarity. D) ioniccharacter. E) nonpolarity. Answer: A 40) Whichofthefollowingsubstancescontainsanonpolarcovalentbond? A) H2 O B) NaCl C) NH3 D) MgF2 E) N2 Answer: E 41) Whichofthefollowingelementshasthelowestelectronegativity? A) Li B) C C) N D) O E) F Answer: A 42) Whichofthefollowingcompoundscontainsapolarcovalentbond? A) NaF B) HCl C) Br2 D) MgO E) O2 Answer: B

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43) Whichofthefollowingcompoundscontainsanionicbond? A) NH3 B) H2 O C) CaO D) H2 E) CH4 Answer: C 44) IftheelectronegativitydifferencebetweenelementsXandYis2.1,thebondbetweentheelementsX -Yis A) ionic. B) nonpolarionic. C) nonpolarcovalent. D) polarcovalent. E) impossible. Answer: A 45) Ionicbondingisexpectedinwhichofthesecompounds? A) Cl2 B) KF C) OF 2 D) HF E) H2 Answer: B 46) Apolarcovalentbondisfoundinwhichofthesecompounds? A) H2 O B) F2 C) NaCl D) H2 E) N2 Answer: A 47) ThebondinCl2 isa(n) A) ionicbond. B) nonpolarcovalentbond. C) metallicbond. D) polarionicbond. E) nobond. Answer: B 48) Agroupofcovalentlybondedatomsthathasanoverallelectricalchargeiscalleda(n) A) ioniccompound. B) anion. C) polyatomicion. D) cation. E) molecule. Answer: C

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49) Whichofthefollowingpolyatomicionshasapositivecharge? A) hydroxide B) sulfate C) hydrogencarbonate D) ammonium E) nitrate Answer: D 50) Whichofthefollowingpolyatomicionshasa3- ioniccharge? A) hydroxide B) nitrate C) sulfate D) phosphate E) bicarbonate Answer: D 51) Whatistheformulaofthenitrideion? A) N3B) NO2 C) NO3 3D) NO3 2E) NO3 Answer: A 52) ThenameoftheHSO4 - ionis A) sulfate. B) hydrogensulfate. C) sulfite. D) hydrogensulfite. E) sulfide. Answer: B 53) WhatistheformulaofacompoundthatcontainsNa+ andPO4 3- ions? A) Na3 PO4 B) NaPO4 C) Na2 PO3 D) Na3 PO3 E) Na3 P Answer: A 54) Fe 2 (SO4 )3 iscalled A) ironsulfate. B) iron(II)sulfate. C) iron(III)sulfate. D) diirontrisulfate. E) irontrisulfate. Answer: C

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55) Whatistheformulaforaluminumnitrite? A) Al2 NO2 B) AlNO3 C) Al(NO2 )3 D) Al2 (NO3 )3 E) Al2 (NO2 )2 Answer: C 56) TheVSEPRtheoryallowsustodeterminethemostfavorable A) shapeofamolecule. B) chargeonanion. C) colorofacompound. D) bondtypeforamolecule. E) formulaforacompound. Answer: A 57) Theshapeoftheammoniamoleculeis A) linear. B) square. C) pyramidal. D) hexagonal. E) octagonal. Answer: C 58) Thewatermoleculehasadipolewiththenegativeportion A) localizedbetweenthehydrogenatoms. B) pointingtowardtheoxygenatom. C) localizedononeofthehydrogens. D) pointingfromtheoxygenthroughthehydrogenatoms. E) surroundingthemolecule. Answer: B 59) Thecarbontetrachloridemolecule,CCl4 ,hastheshapeofa A) tetrahedron. B) square. C) cube. D) circle. E) sphere. Answer: A 60) Hydrogensulfide,H2 S,hasashapesimilarto A) carbondioxide. B) carbonmonoxide. C) hydrogenchloride. D) water. E) carbontetrachloride. Answer: D

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4.2 ShortAnswerQuestions
Identifyeachofthefollowingcompoundsaspolarornonpolar. 1) carbontetrachloride Answer: nonpolar 2) water Answer: polar 3) carbondioxide Answer: nonpolar 4) hydrogensulfide Answer: polar 5) hydrogenfluoride Answer: polar

4.3 MatchingQuestions
Matchthecorrectnameofthepolyatomicionswiththeformulasgiven. 1) Column1: NO3 Column2: nitrate Answer: nitrate 2) Column1: CO 3 2Column2: carbonate Foil: carbonite Answer: carbonate 3) Column1: SO4 2Column2: sulfate Answer: sulfate 4) Column1: SO3 2Column2: sulfite Answer: sulfite 5) Column1: PO4 3Column2: phosphate Foil: phosphite Answer: phosphate 6) Column1: NO2 Column2: nitrite Answer: nitrite

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7) Column1: HCO3 Column2: bicarbonate Answer: bicarbonate 8) Column1: HSO4 Column2: bisulfate Foil: bisulfite Answer: bisulfate 9) Column1: OHColumn2: hydroxide Foil: oxide Answer: hydroxide Givethecorrectchargeforionsofthefollowingelements. 10) Column1: Ca Column2: 2 + Answer: 2 + 11) Column1: Cl Column2: 1 Answer: 1 12) Column1: O Column2: 2 Answer: 2 13) Column1: Al Column2: 3 + Answer: 3 + 14) Column1: K Column2: 1 + Foil: 0 Answer: 1 + Indicatethetypeofbondingyouwouldexpectbetweenthefollowingelements. 15) Column1: NaandF Column2: ionic Answer: ionic

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16) Column1: NandF Column2: polarcovalent Answer: polarcovalent 17) Column1: FandF Column2: nonpolarcovalent Answer: nonpolarcovalent 18) Column1: HeandF Column2: none Answer: none 19) Column1: HandF Column2: polarcovalent Answer: polarcovalent Matchthechemicalnamewiththecorrectformula. 20) Column1: magnesiumsulfate Column2: MgSO 4 Answer: MgSO4 21) Column1: magnesiumhydrogensulfate Column2: Mg(HSO4 )2 Answer: Mg(HSO4 )2 22) Column1: magnesiumsulfide Column2: MgS Answer: MgS 23) Column1: magnesiumsulfite Column2: MgSO 3 Answer: MgSO3 24) Column1: magnesiumhydrogensulfite Column2: Mg(HSO3 )2 Answer: Mg(HSO3 )2

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Chapter5 ChemicalReactionsandQuantities 5.1 Multiple-ChoiceQuestions

1) Whichofthefollowingisanexampleofaphysicalchange? A) grindingcoffeebeans B) bakingacake C) convertingwatertohydrogenandoxygen D) digestingacheeseburger E) burningcoal Answer: A 2) WhichofthefollowingwouldNOTbeaphysicalchange? A) freezingwatertomakeicecubes B) tearingapieceofaluminumfoil C) boilingwaterforsoup D) burninggasolineinalawnmower E) meltinggoldtomakejewelry Answer: D 3) Whichofthefollowingisachemicalchange? A) cuttingarope B) bendingasteelrod C) makingasnowman D) burningsugar E) meltinggold Answer: D 4) Whichofthefollowingisaphysicalchange? A) bakingacake B) dryicesubliming C) fermentinggrapestoproducewine D) digestingameal E) atomatoripening Answer: B 5) Achemicalequationisbalancedwhen A) thetotalnumberofmoleculesisthesameinreactantsandproducts. B) thetotalnumberofionsisthesameinreactantsandproducts. C) thesumofthecoefficientsofthereactantsisequaltothesumofthecoefficientsoftheproducts. D) thenumberofatomsofeachelementisthesameinreactantsandproducts. E) thechargeoneachatomisthesameinreactantsandproducts. Answer: D 6) Whichofthefollowinggivesthebalancedequationforthisreaction? K3 PO4 +Ca(NO3 )2 Ca3 (PO4 )2 +KNO3 A) KPO 4 +CaNO3 +KNO3 B) K3 PO4 +Ca(NO3 )2 Ca3 (PO4 )2 + 3KNO3 C) 2K3 PO4 +Ca(NO3 )2 Ca3 (PO4 )2 + 6KNO3 D) 2K3 PO4 +3Ca(NO3 )2 Ca3 (PO4 )2 + 6KNO3 E) K3 PO4 +Ca(NO3 )2 Ca3 (PO4 )2 + KNO3 Answer: D Page53

7) Whichofthefollowingcorrectlygivesthebestcoefficientsforthereactionbelow? N2 H4 +H2 O2 N2 +H2 O A) 1,1,1,1 B) 1,2,1,4 C) 2,4,2,8 D) 1,4,1,4 E) 2,4,2,4 Answer: B 8) WhatcoefficientisplacedinfrontofO2 tocompletethebalancingofthefollowingequation? C5 H8 +?O2 5CO 2 +4H2 O A) 1 B) 3 C) 5 D) 7 E) 9 Answer: D 9) Whatisthecoefficientofhydrogen,H2 ,whenthefollowingequationisbalanced? Al+H2 SO4 Al2 (SO4 ) 3 +?H2 A) 1 B) 2 C) 3 D) 4 E) 5 Answer: C Pentane(C5 H12)reactswithoxygen(O2 )toformcarbondioxide(CO2 )andwater(H2 O)accordingtothefollowingreaction.Answer thequestion(s)thatfollowaboutthisreaction. C5 H12+?O2 ?CO 2 +?H2 O 10) Whatisthecoefficientforoxygeninthebalancedequation? A) 2 B) 4 C) 5 D) 6 E) 8 Answer: E 11) Whatisthecoefficientforcarbondioxideinthebalancedequation? A) 2 B) 4 C) 5 D) 6 E) 8 Answer: C Page54

12) Whatisthecoefficientforwaterinthebalancedequation? A) 2 B) 4 C) 5 D) 6 E) 8 Answer: D 13) Ina________reaction,twoormoreelementsorcompoundsformoneproduct. A) decomposition B) singlereplacement C) dehydration D) doublereplacement E) combination Answer: E 14) Thefollowingreactiontakesplacewhenanelectriccurrentispassedthroughwater.Itisanexampleofa ________reaction. 2H2 O2H2 +O2 A) combination B) singlereplacement C) dehydration D) decomposition E) doublereplacement Answer: D 15) Whichofthefollowingisanoxidation-reductionreaction? A) CaCl2 +Na2 SO4 CaSO4 +2NaCl B) KOH+HNO3 H2 O+KNO3 C) N2 +O2 2NO D) AgNO3 +NaClAgCl+NaNO3 E) Al2 (SO4 )3 +6KOH2Al(OH) 3 + 3K2 SO4 Answer: C 16) Whatisoxidizedandwhatisreducedinthefollowingreaction? 2Al(s)+3Br2 (g)2AlBr3 (s) A) AlisoxidizedandBr2 isreduced. B) AlBr3 isreducedandBr2 isoxidized. C) AlisreducedandBr2 isoxidized. D) AlBr3 isreducedandAlisoxidized. E) AlBr3 isoxidizedandAlisreduced. Answer: A

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17) Whichofthefollowingdescribesanoxidation? A) lossofelectronsorlossofoxygen B) lossofelectronsorgainofoxygen C) lossofelectronsorgainofhydrogen D) gainofelectronsorgainofoxygen E) gainofelectronsorlossofH Answer: B 18) Inanoxidation-reductionreaction,thesubstanceoxidizedalways A) takesonoxygenatoms. B) showsalossofelectrons. C) givesuphydrogenatoms. D) showsagainofelectrons. E) becomesachargedspecies. Answer: B 19) Inthisreaction,whatisthesubstanceoxidized? Zn(s)+2HCl(aq)ZnCl2 (aq)+H2 (g) A) chlorine B) zincchloride C) hydrogen D) Zn E) oxygen Answer: D 20) Inanoxidation-reductionreaction,thesubstancereducedalways A) takesonoxygenatoms. B) showsalossofelectrons. C) givesuphydrogenatoms. D) showsagainofelectrons. E) becomesachargedspecies. Answer: D 21) Inthisreaction,whatisthecoefficientforcalciumoxide? CaO(s)+CO2 (g)CaCO3 (s) A) 1 B) 2 C) 3 D) 4 E) 5 Answer: A

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22) Inthisreaction,whatisthecorrectcoefficientforsodiumchloride? Pb(NO3 )2 (aq)+NaCl(aq)PbCl2 (s)+NaNO3 (aq) A) 1 B) 2 C) 3 D) 4 E) 5 Answer: B 23) Inthefollowingreaction,whatisthecorrectcoefficientforaluminumchloride? Al(s)+Cl2 (g)AlCl3 (s) A) 1 B) 2 C) 3 D) 4 E) 5 Answer: B 24) Whatistheclassificationforthisreaction? SO3 (g)+H2 O(l)H2 SO4 (l) A) decomposition B) combination C) replacement D) doublereplacement E) oxidationreduction Answer: B 25) Thereactionofcarbonwithoxygentoproducecarbonmonoxideisanexampleofwhichclassofreaction? 2C(s)+O2 (g)2CO(g) A) singlereplacement B) doublereplacement C) combination D) catalytic E) endothermic Answer: C

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26) Forthefollowingreaction,whatisthecorrectcoefficientfortheH2 ? Fe(s)+HCl(aq)FeCl3 (aq)+H2 (g) A) 1 B) 2 C) 3 D) 4 E) 5 Answer: C 27) Whatistheclassificationforthisunbalancedreaction? Fe+HClFeCl3 +H2 A) dehydration B) combination C) decomposition D) singlereplacement E) doublereplacement Answer: D 28) Inanybalancedchemicalequation,thenumberofeachtypeofatomonbothsidesoftheequationis A) doubled. B) thesame. C) decreasedbyone. D) increasedbyone. E) dependentonthetemperature. Answer: B 29) Howmanymolesofwater,H2 O,arepresentin75.0gH2 O? A) 4.41moles B) 4.17moles C) 75.0moles D) 7.50moles E) 1.35x103 moles Answer: B 30) Onemoleofparticlesofanysubstancecontainshowmanyparticles? A) 106 B) 3x10-10 C) 3x1010 D) 6.02x1023 E) 6.02x10-23 Answer: D

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31) Avogadrosnumberisthenumberof A) particlesin1moleofasubstance. B) amuin1moleofasubstance. C) gramsin1moleofasubstance. D) molesin6.02x1023gramsofanelement. E) molesin6.02x1023amuofanelement. Answer: A 32) Themolarmassofpotassiumis A) 19g. B) 31.0g. C) 6.02x1023grams. D) 39.1g. E) 15g. Answer: D 33) Onemoleofheliumgasweighs A) 1.00g. B) 2.00g. C) 3.00g. D) 4.00g. E) 8.00g. Answer: D 34) 0.100moleoflithiumweighs A) 3.00g. B) 0.300g. C) 6.94g. D) 0.694g. E) 0.700g. Answer: D 35) Calculatethemolarmassofpotassiumchloride,KCl. A) 74.6g B) 54.5g C) 6.74g D) 67.4g E) 19.0g Answer: A 36) Whatisthemolarmassofcopper(II)sulfate,CuSO4 ? A) 16.0g B) 63.6g C) 111.6g D) 159.6g E) 319.2g Answer: D

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37) Calculatethemolarmassofmagnesiumchloride,MgCl2 . A) 24.3g B) 95.2g C) 125.9g D) 59.8g E) 70.0g Answer: B 38) Whatisthemolarmassofsodiumphosphate,Na3 PO4 ? A) 119.0g B) 308.0g C) 164.0g D) 226.0g E) 354.0g Answer: C 39) Howmanymolesofcarbonatomsaretherein0.500moleofC2 H6 ? A) 0.500moles B) 1.00moles C) 3.00moles D) 6.02x1023moles E) 4.00moles Answer: B 40) Whatisthemolarmassofsucrose(C12H22O11)? A) 29.0g B) 50.2g C) 210g D) 342g E) 182g Answer: D 41) Onemoleofneonatomshasamassof A) 6.02x1023grams. B) 14.0g. C) 10.0g. D) 20.2g. E) 30.2g. Answer: D 42) ThemolarmassofC3 H8 O2 is A) 76.0g. B) 60.0g. C) 29.0g. D) 69.0g. E) 52.0g. Answer: A

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43) Themolarmassofcalciumhydroxide,Ca(OH) 2 ,is A) 58.1g. B) 57.1g. C) 74.1g. D) 114.2g. E) 38.0g. Answer: C 44) WhatisthemolarmassofMg 3 (PO4 )2 ,asubstanceformerlyusedinmedicineasanantacid? A) 71.3g B) 118.3g C) 150.3g D) 214.3g E) 262.9g Answer: E 45) 4.00molesofsodiumhaveamassof A) 4.60g. B) 11.0g. C) 23.0g. D) 44.0g. E) 92.0g. Answer: E 46) HowmanymolesofK2 SO4 arein15.0gofK2 SO4 ? A) 0.172moles B) 2.61x103 moles C) 0.111moles D) 0.0861moles E) 0.119moles Answer: D 47) 3.00molesofNO2 haveamassof A) 138g. B) 46.0g. C) 30.0g. D) 90.0g. E) 45.0g. Answer: A 48) HowmanygramsofFe 2 O3 aretherein0.500moleofFe 2 O3 ? A) 79.8g B) 35.9g C) 63.8g D) 51.9g E) 160.g Answer: A

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49) Howmanygramsofglucose(C6 H12O6 )arein3.55molesofglucose? A) 180.g B) 639g C) 103g D) 426g E) 50.7g Answer: B 50) Giventhefollowingequation,whatisthecorrectformoftheconversionfactorneededtoconvertthenumber ofmolesofO2 tothenumberofmolesofFe 2 O3 produced? 4Fe(s)+3O2 (g)2Fe 2 O3 (s) A) 4molesFe 3molesO2 4molesFe 2molesFe 2 O3 3molesO2 2molesFe 2 O3 2molesFe 2 O3 4molesFe 2molesFe 2 O3 3molesO2

B) C) D) E)

Answer: E Forthequestion(s)thatfollow,considerthefollowingequation. 2Mg+O2 2MgO 51) Thenumberofmolesofoxygengasneededtoreactwith4.0molesofMgis A) 1.0mole. B) 2.0moles. C) 3.0moles. D) 4.0moles. E) 6.0moles. Answer: B 52) ThenumberofmolesofMgOproducedwhen0.20moleof O2 reactscompletelyis A) 0.10mole. B) 0.20mole. C) 0.40mole. D) 0.60mole. E) 0.80mole. Answer: C

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53) Howmanymolesofmagnesiumareneededtoreactwith16gof O2 ? A) 0.50mole B) 1.0moles C) 2.0moles D) 3.0moles E) 4.0moles Answer: B 54) HowmanygramsofMgOareproducedwhen40.0gramsof O2 reactcompletelywithMg? A) 30.4g B) 50.4g C) 60.8g D) 101g E) 201g Answer: D Forthequestion(s)thatfollow,considerthefollowingbalancedequation. Mg 3 N2 (s)+6H2 O(l)3Mg(OH)2 (s)+2NH3 (g) 55) Whatisthecorrectformoftheconversionfactorneededtoconvertthenumberofmolesof H2 Otothenumber ofmolesofNH3 produced? A) B) C) D) E) 2molesNH3 6molesH2 O 6molesH2 O 2molesNH3 1moleMg 3 N2 6molesH2 O 18gH2 O 1moleH2 O 18gH2 O 17gNH3

Answer: A 56) When2molesofMg 3 N2 areallowedtoreact,howmanymolesofH2 Oalsoreact? A) 1mole B) 4moles C) 6moles D) 8moles E) 12moles Answer: E 57) When4molesofaluminumareallowedtoreactwithanexcessofchlorinegas,Cl2 ,howmanymolesof aluminumchlorideareproduced? A) 1mole B) 2moles C) 3moles D) 4moles E) 5moles Answer: D Page63

58) Inthereactionofnitrogengas,N2 ,withhydrogengas,H2 ,toformammoniagas,NH 3 ,howmanymolesof hydrogenareneededtoreactwithtwomolesofnitrogen? A) 2moles B) 4moles C) 6moles D) 8moles E) 10moles Answer: C 59) Howmanygramsofhydrogenareneededtoproduce1.80gofwateraccordingtothisequation? 2H2 +O2 2H2 O A) 0.100g B) 0.180g C) 0.200g D) 2.00g E) 4.00g Answer: C 60) Inthereactionofsilvernitratewithsodiumchloride,howmanygramsofsilverchloridewillbeproducedfrom 100.gofsilvernitratewhenitismixedwithanexcessofsodiumchloride?Theequationforthereactionis below. AgNO3 (aq)+NaCl(aq)AgCl(s)+NaNO3 (aq) A) 107.9g B) 169.9g C) 84.4g D) 0.589g E) 58.9g Answer: C Forthequestion(s)thatfollow,considerthefollowingbalancedequation. Mg 3 N2 (s)+6H2 O(l)3Mg(OH)2 (s)+2NH3 (g) 61) When2.00molesofH2 Oreact,howmanygramsofNH3 areproduced? A) 34.0g B) 10.0g C) 5.67g D) 11.3g E) 102g Answer: D 62) HowmanygramsofH2 Oareneededtoproduce150gofMg(OH)2 ? A) 46g B) 18g C) 130g D) 93g E) 23g Answer: D

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63) FindthemassofAlCl3 thatisproducedwhen25.0gramsofAl2 O3 reactwithHClaccordingtothefollowing equation. Al2 O3 (s)+6HCl(aq)2AlCl3 (aq)+3H2 O(l) A) 155g B) 72.9g C) 65.4g D) 32.6g E) 16.3g Answer: C 64) HowmanygramsofNOarerequiredtoproduce145gof N2 inthefollowingreaction? 4NH3 (g)+6NO(g)5N2 (g)+6H2 O(l) A) 186g B) 155g C) 125g D) 129g E) 145g Answer: A 65) FindthemassofAlCl3 thatisproducedwhen10.0gramsofAl2 O3 reactwith10.0gofHClaccordingtothe followingequation. Al2 O3 (s)+6HCl(aq)2AlCl3 (aq)+3H2 O(aq) A) 16.2g B) 20.0g C) 12.2g D) 10.0g E) 6.10g Answer: C 66) When10.0gofNH3 reacts,theactualyieldofN2 is8.50g.Whatisthepercentyield? 4NH3 (g)+6NO(g)5N2 (g)+6H2 O(l) A) 85.0% B) 51.5% C) 20.6% D) 41.3% E) 8.5% Answer: D

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5.2 BimodalQuestions
1) Inthisreaction,whatisthecorrectcoefficientforhydrogengas? ?H2 +?O2 ?H2 O A) 1 B) 2 C) 3 D) 4 E) 5 Answer: B Bariumchlorideandsodiumsulfatereactaccordingtothefollowingequation. BaCl 2 +Na2 SO4 BaSO4+2NaCl Answerthequestion(s)thatfollowaboutthisreaction. 2) Howmanymolesofbariumsulfateareproducedfrom0.100moleofbariumchloride? A) 0.0100mole B) 0.100mole C) 0.200mole D) 1.00mole E) 2.00moles Answer: B 3) Howmanygramsofbariumsulfatecanbeproducedfrom0.100moleofbariumchloride? A) 1.37g B) 2.33g C) 23.3g D) 137g E) 233g Answer: C 4) Howmanygramsofbariumchlorideareneededtomake100.gramsofbariumsulfate? A) 44.9g B) 89.3g C) 208.3g D) 233.3g E) 46.6g Answer: B

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Answerthequestion(s)thatfollowaboutthefollowingreaction. 2H2 O2 2H2 O+O2 5) Howmanymolesofoxygengascan30.gofhydrogenperoxide(H 2 O2 )produce,ifdecompositionis complete? A) 0.50mole B) 0.88mole C) 1.0mole D) 2.0mole E) 0.44mole Answer: E 6) Howmanygramsofwaterwill100.gramsofhydrogenperoxide(H 2 O2 H2 +O 2 )produce? A) 3600g B) 360.g C) 5.88g D) 52.9g E) 106g Answer: D 7) Howmanygramsofhydrogenperoxide(H 2 O2 )areneededtoproduce5.0molesofwater? A) 90.g B) 180g C) 3060g D) 306g E) 170g Answer: E

5.3 ShortAnswerQuestions
1) Thenumberofparticlesin1moleofhydrogengasis________. Answer: 6.02x1023 2) Themolarmassofcopper(II)nitrate,Cu(NO3 )2 is________. Answer: 187.6g 3) Whatisthemassof1moleofheliumgas? Answer: 4.00g 4) Acetylenegas,C2 H2 ,reactswithoxygenaccordingtothefollowingequation.If2.00molesofacetylenereact completelywithsufficientoxygen,howmanygramsofcarbondioxideareproduced? 2C2 H2 +5O2 4CO2 +2H2 O Answer: 176g

5.4 True/FalseQuestions
1) Themolarmassofsilveris47g. Answer: FALSE 2) Themolarmassofmagnesiumis24.3g. Answer: TRUE Page67

3) Themassofonemoleofwateris18.0g. Answer: TRUE 4) Themolarmassofchlorinegasis35.5g. Answer: FALSE 5) Themolarmassofcopper(II)chlorideis134.6g. Answer: TRUE 6) Inthereactionofhydrogengaswithoxygengastoproducewater,1moleofoxygengascanproduce2moles ofwater,givensufficienthydrogenavailable. Answer: TRUE

5.5 MatchingQuestions
Identifyeachofthefollowingtransformationsasachemicalorphysicalchange. 1) Column1: waterevaporating Column2: physical Answer: physical 2) Column1: abuttonfallingoffofashirt Column2: physical Answer: physical 3) Column1: silvertarnishing Column2: chemical Answer: chemical 4) Column1: cuttingthegrass Column2: physical Answer: physical 5) Column1: anailrusting Column2: chemical Answer: chemical 6) Column1: bakingacake Column2: chemical Answer: chemical 7) Column1: placingphotographsina scrapbook Column2: physical Answer: physical

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8) Column1: formationofgreenleavesona plant Column2: chemical Answer: chemical

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Chapter6 EnergyandMatter 6.1 Multiple-ChoiceQuestions

1) Anexampleofkineticenergyis A) acoiledspring. B) runningwater. C) atree. D) naturalgas. E) chemicalenergy. Answer: B 2) Theenergyassociatedwiththemotionofparticlesinasubstanceiscalled A) temperature. B) electricalenergy. C) heat. D) chemicalenergy. E) potentialenergy. Answer: C 3) Whichofthefollowingisanexampleofpotentialenergy? A) chewingfood B) waterstoredinareservoir C) burningwood D) afanbladeturning E) ridinganexercisebike Answer: B 4) Thephraseabilitytodoworkisadefinitionof A) specificheat. B) energy. C) calorie. D) heating. E) cooling. Answer: B 5) Theenergystoredinthechemicalbondsofacarbohydratemoleculeis A) specificheat. B) kineticenergy. C) potentialenergy. D) work. E) acalorie. Answer: C 6) Theenergyofmotionisreferredtoas A) work. B) freezing. C) specificheat. D) potentialenergy. E) kineticenergy. Answer: E

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7) Globalwarmingisbelievedtoresultfromallofthefollowingexcept A) burningoffossilfuels. B) increasinglevelsofcarbondioxideintheatmosphere. C) deforestation. D) movementoftheearthclosertothesun. E) carbondioxidetrappingtheheatproducedbythesun. Answer: D 8) Inwhichofthefollowingwouldtheparticlesmovemostrapidly? A) iceat-20C B) waterat20C C) steamat110C D) boilingwater E) iceat0C Answer: C 9) Howmanycaloriesarerequiredtoconvert17goficeat0.0Ctoliquidwaterat32.0C?Theheatoffusionof wateris80.cal/g. A) 43000cal B) 540cal C) 1900cal D) 1400cal E) 80.cal Answer: C 10) Thespecificheatofasubstanceistheamountofheatneededto A) change1gofthesubstancefromthesolidtotheliquidstate. B) raisethetemperatureof1gofthesubstanceby1 C. C) change1gofthesubstancefromtheliquidtothesolidstate. D) convert1gofaliquidtogas. E) convert1gofasolidtoagas. Answer: B 11) Akilocalorieofheatisrequiredtoraisethetemperatureof A) 1gofwaterfrom14Cto15C. B) 1gofwaterby10C. C) 10gofwaterby10C. D) 100gofwaterby10C. E) 100gofwaterby100C. Answer: D 12) Howmanycaloriesarerequiredtoraisethetemperatureofa35.0gsampleofironfrom25 Cto35C?Ironhas aspecificheatof0.106cal/gC. A) 37cal B) 1.1cal C) 3.7cal D) 93cal E) 130cal Answer: A

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13) Howmanycaloriesarerequiredtoincreasethetemperatureof13gofalcoholfrom11 Cto23C?Thespecific heatofalcoholis0.58cal/gC. A) 83cal B) 0.63cal C) 90.cal D) 0.54cal E) 170cal Answer: C 14) WhichofthefollowingquantitiesisNOTrequiredtocalculatetheamountofheatenergyrequiredtoheat waterfrom25Cto55C? A) themassofthewatersample B) theinitialtemperature C) thefinaltemperature D) thespecificheatofwater E) theheatofvaporizationforwater Answer: E 15) Raisingthetemperatureof10.0gofwaterfrom10.0Cto20.0Crequires100.0calofenergy,whileraisingthe temperatureof10.0gofaluminumfrom10.0Cto20.0Crequires22cal.Morecaloriesarerequiredtoheatthe waterbecause A) waterisaliquidandaluminumisasolidat10.0C. B) tengramsofwateroccupiesalargervolumethan10.0gofaluminum. C) waterhasagreaterpotentialenergythanaluminum. D) waterhasalargerspecificheatthanaluminum. E) 10.0Cisclosertothemeltingpointofwaterthantothemeltingpointofaluminum. Answer: D 16) Thenumberofcaloriesneededtoraisethetemperatureof32gofwaterfrom12 Cto54Cis A) 384cal. B) 1.3cal. C) 1300cal. D) 1700cal. E) 0.76cal. Answer: C 17) A2.5gsampleoffrenchfriesisplacedinacalorimeterwith500.0gofwaterataninitialtemperatureof21 C. Aftercombustionofthefrenchfriesthewaterhasatemperatureof48C.Whatisthecaloricvalue(kcal/g)of thefrenchfries? A) 14kcal/g B) 11kcal/g C) 0.14kcal/g D) 4.2kcal/g E) 5.4kcal/g Answer: E 18) Apotatocontains20gofcarbohydrate.Ifcarbohydratehasacaloricvalueof4kcal/g,howmanykcalare obtainedfromthecarbohydrateinthepotato? A) 5kcal B) 20kcal C) 40kcal D) 60kcal E) 80kcal Answer: E Page72

19) Acheeseburgerfromafastfoodrestaurantcontains19goffat,20gofcarbohydrate,and28gofprotein.How manykcalofenergydoesthecheeseburgercontain?(Theacceptedcaloricvaluesforfoodsare4.0kcal/gfor carbohydrate,9kcal/gforfat,and4kcal/gforprotein.)Reporttheanswerto2significantfigures. A) 70.kcal B) 360kcal C) 17kcal D) 630kcal E) 280kcal Answer: B 20) Aservingoffishcontains50gproteinand4goffat.Ifproteinhasacaloricvalueof4.0kcal/gandfathas9.1 kcal/g,howmanykcalareintheserving? A) 240kcal B) 54.0kcal C) 470kcal D) 220kcal E) 486kcal Answer: A 21) Adiethasatotalcaloricintakeof1400kcal.Thedietconsistsof50%carbohydrate,35%protein,and15%fat. Thenumberofkcalofproteininthedietis A) 700kcal. B) 490kcal. C) 210kcal. D) 460kcal. E) 1200kcal. Answer: B 22) Whichofthefollowingisapropertyofasolid? A) Ittakestheshapeofthecontainer. B) Itfillsthevolumeofthecontainer. C) Theparticlesmoveatarapidrate. D) Theinteractionsbetweenitsparticlesareveryweak. E) Theparticleshavefixedpositionsandareveryclosetogether. Answer: E 23) Whichofthefollowingisaphysicalpropertyofbothliquidsandgases? A) hasitsownshape B) hasadefinitevolume C) hasstronginteractionsbetweenitsparticles D) hasrandomlyarrangedparticles E) haslargespacesbetweenmolecules Answer: D 24) Whichoneofthefollowingpropertiesdescribesaliquid? A) hasitsownshape B) particlesareclosetogetherandmoverandomly C) particlesmoveveryrapidly D) fillstheentirevolumeofthecontainer E) Thereisessentiallynointeractionbetweentheparticles. Answer: B

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25) Thephysicalstate(s)presentwhenasubstanceismeltingis(are) A) solid. B) liquid. C) gas. D) solid+liquid. E) liquid+gas. Answer: D 26) Iftheheatoffusionforwateris80.cal/g,howmanycaloriesareneededtomelt45.0goficeat0 C? A) 3.6cal B) 3.6x103 cal C) 1.8cal D) 80.cal E) 0.56cal Answer: B 27) Theformationofagasresultingfromtheescapeofhigh -energyparticlesfromthesurfaceofaliquidisknown as A) evaporation. B) deposition. C) boiling. D) melting. E) sublimation. Answer: A 28) Whenasolidisconverteddirectlytoagas,thechangeofstateiscalled A) freezing. B) melting. C) boiling. D) condensation. E) sublimation. Answer: E 29) Aburnfromsteamat100Cisexpectedtobemoreseverethanaburnfromboilingwaterat100 Cbecause A) thesteamishotterthantheboilingwater. B) thereismoresteamthanwater. C) thesteamwillgiveoffalargeamountofheatasitcondenses. D) youaremorelikelytocomeintocontactwiththesteamthanwiththeboilingwater. E) Alloftheseanswersarecorrect. Answer: C 30) Theheatoffusionforwateris80.cal/g.Howmanycaloriesofheatarereleasedwhen20.0gofwaterat30. C iscooledto0Candfrozentoiceat0C? A) 600cal B) 1600cal C) 2000cal D) 2200cal E) 11,400cal Answer: D

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31) Iftheheatofvaporizationforwateris540cal/g,howmanykilocaloriesarereleasedwhen5.00gofsteamis convertedtoliquidat100C? A) 540kcal B) 5.0kcal C) 110kcal D) 2.7kcal E) 5.4kcal Answer: D 32) Howmanycaloriesarerequiredtowarm15.0gofwaterfrom75 Cto100.0Candconvertittosteamat 100.0C?Theheatofvaporizationofwateris540cal/g. A) 375cal B) 8500cal C) 8100cal D) 410cal E) 540cal Answer: B 33) Inordertocalculatethetotalnumberofcaloriesneededtomelt1gofasolidandthenconvertittoagas,you mustknow A) thespecificheatofthesubstance. B) theheatoffusionofthesubstance. C) theheatoffusionandthespecificheatofthesubstance. D) thespecificheatandtheheatofvaporizationofthesubstance. E) theheatoffusion,thespecificheat,andtheheatofvaporizationofthesubstance. Answer: E 34) Theheatoffusionforwateris80.cal/g,andtheheatofvaporizationofwateris540cal/g.Howmanycalories arerequiredtoconvert10.0goficeat0Ctosteamat100C? A) 620cal B) 6,200cal C) 720cal D) 7,200cal E) 5,400cal Answer: D 35) WhichofthefollowingdoesNOTinvolveachangeofstate? A) meltingice B) freezingwater C) vaporizationofalcohol D) sublimationofdryice E) pouringwaterintoavacuum-insulatedbottle Answer: E 36) Aheatingcurveillustrates A) whatasubstancelookslikeasitisheated. B) whathappenstotheparticlesofasubstanceasitisheated. C) whathappenstotheheatappliedasthetemperatureisincreased. D) thechangesinthetemperatureandphysicalstateofasubstanceasitisheated. E) thechemicalchangesthatoccurasthesubstanceisheated. Answer: D

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37) WhichofthefollowingdoesNOTrepresentastepontheheatingcurveofwater? A) Thetemperatureofsteamcannotexceed100C. B) Thetemperatureoficeremainsat0Casitmelts. C) Thetemperatureofliquidwaterincreaseslinearlyasitisheated. D) Thetemperatureofliquidwaterremainsat100Casitboils. E) Bothliquidwaterandicearepresentat0C. Answer: A 38) Inwater,themeltingpointisunusuallyhighbecauseof A) covalentbondsintheindividualmolecules. B) ionicbondsintheindividualmolecules. C) hydrogenbondingbetweenthemolecules. D) dispersionforcesbetweenthemolecules. E) theheatcontentofthehydrogen-oxygenbonds. Answer: C 39) Onecupofkidneybeanscontains15gofprotein,1goffat,and42gofcarbohydrate.Howmanykilocalories, totwosignificantfigures,doesthissamplecontain? A) 60kcal B) 88kcal C) 230kcal D) 240kcal E) 520kcal Answer: D 40) Inaliquid,thestrengthoftheintermolecularinteractionsisconsidered A) veryweak. B) weak. C) moderate. D) strong. E) verystrong. Answer: D 41) Inagas,thedistancebetweentheparticlesis A) verycloserelativetothesizeofthemolecules. B) closerelativetothesizeofthemolecules. C) fixedrelativetothesizeofthemolecules. D) smallrelativetothesizeofthemolecules. E) verylargerelativetothesizeofthemolecules. Answer: E 42) Themaininteractionsbetweenmoleculesofhydrogenchlorideareexamplesof A) ionicbonds. B) covalentbonds. C) hydrogenbonds. D) dipole-dipoleinteractions. E) dispersionforces. Answer: D

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43) ThemaininteractionsbetweenmoleculesofhydrogenH2 areexamplesof A) ionicbonds. B) covalentbonds. C) hydrogenbonds. D) dipole-dipoleinteractions. E) dispersionforces. Answer: E 44) Hydrogenbondsareamajorfactorinthestructureof A) DNA. B) hydrogenchloride. C) dryice. D) air. E) tablesalt. Answer: A 45) Thespecificheatofcopperis0.093cal/gC,andthespecificheatofsilveris0.057cal/g C.If100calofheatis addedtoonegofeachmetalat25C,whatistheexpectedresult? A) Thecopperwillreachahighertemperature. B) Thesilverwillreachahighertemperature. C) Thetwosampleswillreachthesametemperature. D) Thecopperwillreachatemperaturelowerthan25C. E) Thesilverwillsoften. Answer: B 46) Waterhasaboilingpointof100C,andalcoholhasaboilingpointof78C,eventhoughwaterisasmaller molecule.Thislargedifferenceinboilingpointisdueto A) weakdispersionforcesinthealcoholmolecules. B) ionicbondsbetweenthewatermolecules. C) covalentbondsintheethanolmolecules. D) strongerhydrogenbondsbetweenthewatermolecules. E) strongerhydrogenbondsbetweenthealcoholmolecules. Answer: D 47) Thedietarycalorie(Cal)isequalto A) 1000kilocalories. B) 1000calories. C) 100calories. D) 10calories. E) 1calorie. Answer: B 48) Inanendothermicreaction, A) heatflowsoutofthesystem. B) energyisabsorbedbythesystem. C) thetemperatureofthesystemincreases. D) theproductshavelessenergythatthereactants. E) theproductshavethesameenergythatthereactants. Answer: B

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49) Forthereaction:2H 2 O(l)+137kcal 2H2 (g)+ O2 (g) howmanykcalareneededtoform2.00molesO 2 (g)? A) 68.5kcal B) 137kcal C) 274kcal D) 190.kcal E) 548kcal Answer: C 50) Forthereaction:2H 2 O(l)+137kcal 2H2 (g)+ O2 (g) howmanykcalareneededtoreact50.0gH 2 O(l)? A) 380.kcal B) 137kcal C) 274kcal D) 190.kcal E) 760.kcal Answer: D

6.2 ShortAnswerQuestions
1) Thechangeofstatefromsolidtogasistermed________. Answer: sublimation 2) Areactioninwhichheatisgivenoffistermed________. Answer: exothermic 3) Theheatoffusionistheamountofheatnecessarytochangeonegramofasubstancefromthesolidtothe ________state. Answer: liquid 4) Theweakesttypeofforcebetweenparticlesofasubstanceistermed________. Answer: dispersionforces 5) Arehydrogenbondsstrongerorweakerthancovalentbonds? Answer: weaker 6) Aredipole-dipoleinteractionsweakorstrongcomparedtoionicbonds? Answer: weak 7) Theamountofheatnecessaryforonegramofasubstancetochangefromthesolidstatetotheliquidstateis the________. Answer: heatoffusion 8) Willthecaloricvalueofa100.ghamburgerbehigherorlowerthanthecaloricvalueof100.gofsugar? Answer: higher. 9) Whenaliquidboils,theprocessbywhichthemoleculesleaveitssurfaceiscalled________. Answer: evaporation 10) Willthecaloricvalueofa100.ghamburgerbehigherorlowerthanthecaloricvalueof100.gofcookingoil? Answer: lower

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Bromine(Br2 )hasafreezingpointof-7C,andaboilingpointof60C. Indicatethestateorchangeofstateoccurringateachtemperature. 11) 30C Answer: liquid 12) 60C Answer: boiling 13) -7C Answer: melting 14) -15C Answer: solid 15) 70C Answer: gas

6.3 True/FalseQuestions
1) Asheatisremovedfromasolid,itstemperaturedecreases. Answer: TRUE 2) Areactioninwhichheatisgivenoffisendothermic. Answer: FALSE 3) Watervaporisagas. Answer: TRUE 4) Whenaliquidisboiling,itstemperaturedoesnotchange. Answer: TRUE 5) Asasolidmelts,itstemperaturedoesnotchange. Answer: TRUE 6) Steamat100Choldsthesameamountofheataswaterat100 C. Answer: FALSE 7) Carbohydratesandproteinshavethesamecaloricvaluepergram. Answer: TRUE 8) Condensationoccurswhenaliquidisconvertedtoasolid. Answer: FALSE

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6.4 MatchingQuestions
Identifythephysicalstate(s)correspondingtolabeledregionsonthecoolingcurveofwatershownbelow.

1) Column1: A Column2: gas Answer: gas 2) Column1: B Column2: liquidandgas Foil: solidandgas Answer: liquidandgas 3) Column1: C Column2: liquid Answer: liquid 4) Column1: D Column2: liquidandsolid Answer: liquidandsolid 5) Column1: E Column2: solid Answer: solid Matchthestateofmatterwitheachofthefollowingdescriptionsofasubstance. 6) Column1: Particlesareheldclose togetherinarandompattern. Column2: liquid Answer: liquid

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7) Column1: Greatdistancesexistbetween theparticles. Column2: gas Answer: gas 8) Column1: Thissubstanceisboiling. Column2: liquid+gas Answer: liquid+gas 9) Column1: Thismaterialhasadefinite volume,andadefiniteshape. Column2: solid Answer: solid 10) Column1: Thissubstanceismelting. Column2: solid+liquid Answer: solid+liquid Identifytheenergyassociatedwitheachofthelabeledpartsofthefollowingdiagram.

11) Column1: RegionA Column2: energyofreactants Answer: energyofreactants 12) Column1: RegionB Column2: activationenergy Answer: activationenergy 13) Column1: RegionC Column2: heatofreaction Answer: heatofreaction 14) Column1: RegionD Column2: energyofproducts Answer: energyofproducts Page81

Identifytheletterofthediagramcorrespondingtothegiventypeofreaction.

B
15) Column1: endothermicreaction Column2: DiagramB Answer: DiagramB 16) Column1: exothermicreaction Column2: DiagramA Answer: DiagramA

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Chapter7 Gases 7.1 Multiple-ChoiceQuestions

1) WhichofthefollowingisNOTpartofthekinetictheoryofgases? A) Agasiscomposedofverysmallparticles. B) Thereisverylittleemptyspaceinagas. C) Gasparticlesmoverapidly. D) Gasparticlesdonotattractorrepeloneanother. E) Gasparticlesmovefasterwhenthetemperatureincreases. Answer: B 2) Accordingtothekinetictheoryofgases,agascanbecompressedmuchmorethanaliquidorsolidbecause A) agasiscomposedofverysmallparticles. B) theparticlesofagasareveryfarapart. C) gasparticlesmoverapidly. D) gasparticlesdonotattractorrepeloneanother. E) gasparticlesmovefasterwhenthetemperatureincreases. Answer: B 3) Accordingtothekinetictheoryofgases,particlesofagas A) areverylarge. B) areveryfarapart. C) losetheirvalenceelectrons. D) moveslowly. E) decreasekineticenergyastemperatureincreases. Answer: B 4) Inthekineticmoleculartheoryofgasbehavior,particlesofagastendtomove________andcollisionsbetween themare________. A) rapidly;rare B) slowly;rare C) rapidly;elastic D) slowly;elastic E) slowly;unusual Answer: C 5) Theforceofgasparticlesagainstthewallsofacontaineriscalled A) pressure. B) volume. C) temperature. D) quantityofgas. E) density. Answer: A 6) Whichmeasurementdescribesthepressureofagas? A) 315K B) 1.2g/L C) 2.5L D) 725mmHg E) 0.45moles Answer: D

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7) Theunitof1atmosphereusedtodescribethepressureofagasisequalto A) 1mmHg. B) 100mmHg. C) 200mmHg. D) 600mmHg. E) 760mmHg. Answer: E 8) A5.00-Ltankcontainsheliumgasat1.50atm.WhatisthepressureofthegasinmmHg? A) 1.50mmHg B) 507mmHg C) 760mmHg D) 1140mmHg E) 7.5mmHg Answer: D 9) Theboilingpointofwateratsealevelis100C.Athigheraltitudes,theboilingpointofwaterwillbe A) lower,becausetemperaturesarelower. B) lower,becausetheatmosphericpressureislower. C) higher,becausethealtitudeisgreater. D) higher,becausetherearefewerwatermoleculesintheair. E) thesame,becausewateralwaysboilsat100C. Answer: B 10) Vaporpressurecanbedescribedas A) thetemperatureatwhichbubblesofvaporappearinaliquid. B) thepressureexertedontheearthbytheparticlesintheair. C) thetemperatureatwhichthevaporpressureofaliquidequalsatmosphericpressure. D) thepressureexertedbyagasabovethesurfaceofitsliquid. E) thepressurewithinthelungsduringinhalation. Answer: D 11) Anautoclaveisusedtosterilizesurgicalequipmentbecause A) itallowswatertoboilattemperatureslessthan100 C. B) itallowswatertoboilat100Catpressureslessthan1atm. C) itallowswatertoboilat100Catpressuresgreaterthan1atm. D) itallowswatertoboilattemperaturesabove100C. E) itprovidesveryhightemperaturesandverylowpressures. Answer: D 12) AccordingtoBoyleslaw,thepressureofagasincreasesasthevolumedecreasesbecause A) thegasparticlesgetbigger. B) thekineticenergyofthegasparticlesincreases. C) thetemperatureofthegasincreases. D) thegasparticlesstrikethewallsofthecontainerwithmoreforce. E) thegasparticlesstrikethewallsofthecontainermoreoften. Answer: E

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13) Whichofthefollowingcorrectlydescribestheprocessofinspiration(airenteringthelungs)? A) Thelungsexpand,causingtheirinternalpressuretodecrease. B) Thelungsexpand,causingtheirinternalpressuretoincrease. C) Thelungscontract,causingtheirinternalpressuretodecrease. D) Thelungscontract,causingtheirinternalpressuretoincrease. E) Thereisnochangeintheinternalpressureinthelungs. Answer: A 14) Thevolumeofagaswithapressureof1.2atmincreasesfrom1.0Lto4.0L.Whatisthefinalpressureofthe gas,assumingconstanttemperature? A) 1.2atm B) 0.30atm C) 3.3atm D) 4.8atm E) 1.0atm Answer: B 15) Thepressureof5.0Lofgasincreasesfrom1.50atmto1240mmHg.Whatisthefinalvolumeofthegas, assumingconstanttemperature? A) 4100L B) 5.0L C) 0.0060L D) 5.4L E) 4.6L Answer: E Aballoonisfilledwithheliumgas.Forthequestion(s)thatfollow,selecttheletteroftheballoondiagramthatcorrespondstothegiven changeinconditions.

16) Theballoonisputintoachamberwhosepressureislessthantheatmosphericpressureandatatmospheric temperature. A) A B) B C) C D) AandB E) BandC Answer: C

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17) Thetemperatureischangedfrom50Cto-150Catconstantpressure. A) A B) B C) C D) AandB E) BandC Answer: A 18) Completethefollowingstatement:InCharleslaw,thevolumeofagas________whenthe________decreases. A) increases;temperature B) increases;quantityofgas C) increases;pressure D) decreases;temperature E) decreases;pressure Answer: D 19) Whatunitoftemperatureisusedingaslawcalculations? A) Fahrenheit B) Celsius C) Kelvin D) eitherCelsiusorFahrenheit E) eitherCelsiusorKelvin Answer: C 20) Thetemperatureofa500.mLsampleofgasincreasesfrom150.Kto350.K.Whatisthefinalvolumeofthe sampleofgas,ifthepressureinthecontaineriskeptconstant? A) 210.mL B) 1170mL C) 0.0095mL D) 0.0470mL E) 110.mL Answer: B 21) InGay-Lussacslaw,thepressureofagasincreasesduetoanincreaseintemperaturebecause A) themoleculesstrikethewallsofthecontainerlessoften. B) themoleculesstrikethewallsofthecontainermoreoften. C) themoleculesgetbigger. D) thereisadecreaseinthevolumeofthecontainer. E) thereisanincreaseinthenumberofgasparticles. Answer: B 22) Agascontainedinasteeltankhasapressureof1.5atmatatemperatureof320K.Whatwillbethegas pressurewhenthetemperaturechangesto450K? A) 1.5atm B) 0.94atm C) 0.47atm D) 2.1atm E) 1.1atm Answer: D

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23) WhenthecombinedgaslawisrearrangedtosolveforV 2 ,thefollowingisthecorrectexpression:V 2 = A) T2 T1 V 1 /P2 P1 B) P1 V 1 T2 /P2 T1 C) P1 V 1 T1 /P2 T2 D) P2 T2 /P1 V 1 T1 E) P1 V 1 /T1 -P2 /T2 Answer: B 24) At570.mmHgand25C,agassamplehasavolumeof2270mL.Whatisthefinalpressure(inmmHg)ata volumeof1250mLandatemperatureof175C? A) 1560mmHg B) 210.mmHg C) 700.mmHg D) 690.mmHg E) 470.mmHg Answer: A 25) AccordingtoAvogradoslaw, A) thevolumeofagasisinverselyrelatedtothenumberofmolesatconstanttemperatureandpressure. B) thevolumeofagasisinverselyrelatedtothenumberofmolesatstandardtemperatureandpressure. C) thevolumeofagasdependsonlyonthetemperatureandpressure. D) thevolumeofagasdependsonlyonthenumberofmolesinthesample. E) thevolumeofagasisdirectlyrelatedtothenumberofmolesatconstanttemperatureandpressure. Answer: E 26) AtSTP,temperatureandpressurehavethevaluesof A) 0Kand1atm. B) 273Kand1mmHg. C) 273Kand760mmHg. D) 0Kand760mmHg. E) 760Kand273atm. Answer: C 27) Agassamplecontains4.0gofCH4 and2.0gofHe.WhatisthevolumeofthesampleatSTP? A) 130L B) 11L C) 17L D) 30.L E) 5.6L Answer: C 28) Adiverexhalesabubblewithavolumeof250mLatapressureof2.4atmandatemperatureof15 C.Whatis thevolumeofthebubblewhenitreachesthesurfacewherethepressureis1.0atmandthetemperatureis 27C? A) 580mL B) 630mL C) 100mL D) 110mL E) 1100mL Answer: B

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29) Howmanymolesofneonoccupyavolumeof14.3LatSTP? A) 36.7moles B) 32.0moles C) 6.45moles D) 0.638moles E) 1.57moles Answer: D 30) 1moleofagasoccupies22.4Lat A) 0Cand0.50atm. B) 0Cand760mmHg. C) 100Cand1atm. D) 100Cand10atm. E) 0Kand1atm. Answer: B 31) AtSTPconditions,11gofSO2 haveavolumeof A) 250L. B) 3.8L. C) 22L. D) 0.0076L. E) 130L. Answer: B 32) Thetotalpressureinamixtureofgasesisequaltothepartialpressure(s)of A) thegaswiththegreatestnumberofmoles. B) thegaswiththesmallestnumberofmoles. C) thegaswiththehighestmolecularweight. D) thegasthatoccupiesthelargestvolume. E) allthegasesaddedtogether. Answer: E 33) Acyclopropane-oxygenmixtureisusedasananesthetic.Ifthepartialpressureofcyclopropaneinthemixture is330mmHgandthepartialpressureoftheoxygenis1.0atm,whatisthetotalpressureofthemixtureintorr? A) 330torr B) 430torr C) 760torr D) 1.4torr E) 1100torr Answer: E 34) Atankcontainsheliumgasat490mmHg,nitrogengasat0.75atm,andneonat520torr.Whatisthetotal pressureinatm? A) 2.1atm B) 0.55atm C) 1.0x103 atm D) 1.5atm E) 1600atm Answer: A

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35) Whichofthefollowingcorrectlydescribesthepartialpressuresofgasesinthebody? A) highO2 ,lowCO 2 ,oxygenatedblood B) highO2 ,lowCO 2 ,deoxygenatedblood C) highO2 ,highCO 2 ,oxygenatedblood D) highO2 ,highCO 2 ,tissue E) lowO2 ,lowCO 2 ,deoxygenatedblood Answer: A 36) WhichofthefollowingisNOTapotentialuseforahyperbaricchamber? A) treatmentforburnsandinfections B) counteractingcarbonmonoxidepoisoning C) increasingtherateatwhichabrokenboneheals D) treatingadiverwiththebends E) treatingsomecancers Answer: C 37) Inthekineticmoleculartheoryofgasbehavior,theassumptionismadethatgasmolecules A) moverapidlyinrandomdirections. B) areattractedtoeachotherbystrongforces. C) areclosetogetherintheircontainer. D) movewithakineticenergyequaltotheircentigradetemperature. E) occasionallycometorest. Answer: A 38) Thepressureexertedbyagasonitscontainerisdirectlyproportionalto A) thevolumeofthecontainer. B) themassoftheindividualgasmolecules. C) thecentigradetemperatureofthegas. D) thenumberofmoleculesofgasinthesample. E) theFahrenheittemperatureofthegas. Answer: D 39) AsyourisehigherinEarthsatmosphere,theatmosphericpressure A) increases. B) decreases. C) remainsthesame. Answer: B 40) Theairpressureonarainydayisusually________airpressureonasunnyday. A) higherthan B) lowerthan C) thesameas Answer: B 41) Atconstanttemperature,asampleofheliumat760.torrinaclosedcontainerwascompressedfrom5.00Lto 3.00L.Whatwasthenewpressureexertedbytheheliumonitscontainer? A) 800.torr B) 2280torr C) 15.0torr D) 3800torr E) 1270torr Answer: E

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42) Agassampleinaclosed,expandablecontainerofinitialvolume5.00Lwasallowedtowarmfrom25 Cto 35C.Whatwasitsnewvolume? A) 4.84L B) 5.17L C) 7.00L D) 3.57L E) 4380L Answer: B 43) Agasat5.00atmpressurewasstoredinatankduringthewinterat5.0 C.Duringthesummer,the temperatureinthestorageareareached40.0C.Whatwasthepressureinthegastankthen? A) 0.625atm B) 4.44atm C) 5.63atm D) 40.0atm E) 69.5atm Answer: C 44) Asampleofnitrogengashadavolumeof500.mL,apressureinitsclosedcontainerof740torr,anda temperatureof25C.Whatwasthenewvolumeofthegaswhenthetemperaturewaschangedto50 Candthe newpressurewas760torr? A) 530mL B) 450mL C) 970mL D) 240mL E) 400mL Answer: A 45) AtSTP,whatisthevolumeof4.50molesofnitrogengas? A) 167L B) 3420L C) 101L D) 60.7L E) 1230L Answer: C 46) AtSTP,howmanymolesofheliumwouldoccupy1.00L? A) 2.24moles B) 224moles C) 22.4moles D) 0.446moles E) 0.0446moles Answer: E 47) Ifatmosphericpressureonacertaindayis749mmHg,whatisthepartialpressureofnitrogen,giventhat nitrogenisabout78%oftheatmosphere? A) 165mmHg B) 584mmHg C) 600mmHg D) 749mmHg E) 760mmHg Answer: B

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48) Themathematicalexpressionoftheidealgaslawis A) P1 V 1 =P2 V 2 B) C) P1 T1 P1 V1 = = P2 T2 P2 V2

D) PV=nRT E) PT=P1 +P 2 + P3 Answer: D 49) Asampleofargonat300.Cand50.0atmpressureiscooledinthesamecontainertoatemperatureof0.00 C. Whatisthenewpressure? A) 105atm B) 45.5atm C) 54.9atm D) 23.8atm E) 42.7atm Answer: D 50) AtSTP,whatisthevolumeof1.00moleofcarbondioxide? A) 1.00L B) 44.0L C) 273L D) 22.4L E) 12.2L Answer: D

7.2 BimodalQuestions
1) Thepressureexertedbytheparticlesofvaporabovealiquidiscalledthe________. A) vaporpressure B) barometricpressure C) standardpressure D) molarpressure E) atmosphericpressure Answer: A 2) Inthekineticmoleculartheoryofgasbehavior,thedistancebetweengasmoleculesisassumedtobe________ thediameterofthegasmolecules. A) 22.4times B) smallrelativeto C) dependenton D) approximatelythesameas E) largerelativeto Answer: E 3) Abarometerisadeviceformeasuring________. A) atmosphericpressure B) bloodpressure C) gaspressureinacontainer D) gaspressureinthelung E) vaporpressure Answer: A Page91

7.3 ShortAnswerQuestions
1) Theuseofhigh-pressurechamberstocontroldiseaseprocessesisknownas________. Answer: hyperbaricmedicine 2) Nitrogenmakesupabout________percentoftheatmosphere. Answer: 78 3) Abarometerisusuallyfilledwith________. Answer: mercury 4) Oneatmosphereisthesameas________mmHg. Answer: 760 5) Thepressureunit1mmHgisthesamepressureunitasthepressureunit________. Answer: 1torr

7.4 True/FalseQuestions
1) STPstandsfor0Cand760mmHg. Answer: TRUE 2) Thevolumeof1moleofanygasatSTPis22.4L. Answer: TRUE 3) Theairwebreatheisabout21%oxygen. Answer: TRUE 4) Carbondioxideandwatervaportogetheraccountforabout5%oftheairwebreathe. Answer: FALSE 5) Duringinspiration,weactuallymakeuseof100%oftheoxygenintheairwebreathe. Answer: FALSE 6) Indeoxygenatedblood,thepartialpressureofcarbondioxideisgreaterthanthepartialpressureofoxygenleft. Answer: TRUE 7) GaslawcalculationsnormallyrequiretheuseoftheKelvintemperaturescale. Answer: TRUE 8) At0K,allmotionstops. Answer: TRUE 9) ThepressureexertedbyagasonitscontainerisinverselyrelatedtoitsKelvintemperature. Answer: FALSE 10) ThekineticenergyofagassampleisdirectlyproportionaltotheKelvintemperatureofthegas. Answer: TRUE

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7.5 MatchingQuestions
Indicatetheeffectonthepressureofthefollowingchange. 1) Column1: decreaseinvolume (n,Tconstant) Column2: increases Answer: increases 2) Column1: removingsomemoleculesof gas Column2: decreases Answer: decreases 3) Column1: Thetemperatureisdoubled. Column2: increases Answer: increases 4) Column1: ThevolumeandtheKelvin temperaturearereducedby one-half. Column2: nochange Answer: nochange 5) Column1: Aleakoccursandgasescapes. Column2: decreases Answer: decreases Matchthecorrectformulawiththegaslawnamegiven. 6) Column1: Boyleslaw Column2: P1 V 1 =P2 V 2 Foil: mass/volume Answer: P1 V 1 =P2 V 2 7) Column1: Combinedgaslaw P2 V 2 P1 V 1 = Column2: T2 T1 Answer: P1 V 1 T1 = P2 V 2 T2

8) Column1: Charleslaw V1 V2 Column2: = T1 T2 Answer: V1 T1 = V2 T2 Page93

9) Column1: idealgaslaw Column2: PV=nRT Answer: PV=nRT 10) Column1: Avogadroslaw V2 V1 = Column2: n2 n1 Answer: V1 n1 = V2 n2

11) Column1: Gay-Lussacslaw P1 P2 Column2: = T1 T2 Answer: P1 T1 = P2 T2

12) Column1: Daltonslaw Column2: PT=P1 +P2 +P3 ... Answer: PT=P1 +P2 +P3 ...

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Chapter8 Solutions 8.1 Multiple-ChoiceQuestions

1) TheO-Hbondinwaterispolarbecause A) itisanionicbond. B) oxygenismuchmoreelectronegativethanhydrogen. C) oxygenoccupiesmorespacethanhydrogen. D) hydrogenismuchmoreelectronegativethanoxygen. E) itisahydrogenbond. Answer: B 2) Ahydrogenbondis A) anattractionbetweenahydrogenatomattachedtoN,O,orFandanN,O,orFatom. B) acovalentbondbetweenHandO. C) anionicbondbetweenHandanotheratom. D) abondthatisstrongerthanacovalentbond. E) thepolarO-Hbondinwater. Answer: A 3) Inasolution,thesolvent A) isaliquid. B) canbealiquidorgas. C) canbeasolid,liquid,orgas. D) isneverasolid. E) isthesubstancepresentinthesmallestconcentration. Answer: C 4) Whichofthefollowingmoleculescanformhydrogenbonds? A) CH4 B) NaH C) NH3 D) BH3 E) HI Answer: C 5) Asolutionispreparedbydissolving2gofKClin100gofH2 O.Inthissolution,H2 Oisthe A) solute. B) solvent. C) solution. D) solid. E) ioniccompound. Answer: B 6) Oildoesnotdissolveinwaterbecause A) oilispolar. B) oilisnonpolar. C) waterisnonpolar. D) waterissaturated. E) oilishydrated. Answer: B

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7) WhenKCldissolvesinwater A) theCl- ionsareattractedtodissolvedK+ ions. B) theCl- ionsareattractedtothepartiallynegativeoxygenatomsofthewatermolecule. C) theK+ ionsareattractedtoCl- ionsontheKClcrystal. D) theK+ ionsareattractedtothepartiallynegativeoxygenatomsofthewatermolecule. E) theK+ ionsareattractedtothepartiallypositivehydrogenatomsofthewatermolecule. Answer: D 8) Waterisapolarsolventandhexane(C6 H14)isanonpolarsolvent.Whichofthefollowingcorrectlydescribes thesolubilityofthesolute? A) mineraloil,solubleinwater B) CaCl2 ,solubleinhexane C) NaHCO 3 ,solubleinwater D) CCl4 ,solubleinwater E) octane,solubleinwater Answer: C 9) Inwater,asubstancethationizescompletelyinsolutioniscalleda A) weakelectrolyte. B) nonelectrolyte. C) semiconductor. D) nonconductor. E) strongelectrolyte. Answer: E 10) Anequivalentis A) theamountofionthathasa1+charge. B) theamountofionthathasa1-charge. C) theamountofionthatcarries1moleofelectricalcharge. D) 1moleofanyion. E) 1moleofanioniccompound. Answer: C 11) Howmanyequivalentsarepresentin5.0gofAl3+ ? A) 15Eq B) 0.56Eq C) 0.19Eq D) 0.37Eq E) 3Eq Answer: B 12) Anintravenousreplacementsolutioncontains4.0mEq/LofCa2+ ions.HowmanygramsofCa2+ arein3.0L ofthesolution? A) 0.24g B) 0.80g C) 0.40g D) 240g E) 4.0g Answer: A

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13) Whensomeofthesugaraddedtoicedtearemainsundissolvedatthebottomoftheglass,thesolutionis A) dilute. B) polar. C) nonpolar. D) saturated. E) unsaturated. Answer: D 14) ThesolubilityofKIis50gin100gofH2 Oat20C.If110gramsofKIareaddedto200gramsof H2 O, A) alloftheKIwilldissolve. B) thesolutionwillfreeze. C) thesolutionwillstartboiling. D) asaturatedsolutionwillform. E) thesolutionwillbeunsaturated. Answer: D 15) Anincreaseinthetemperatureofasolutionusually A) increasestheboilingpoint. B) increasesthesolubilityofagasinthesolution. C) increasesthesolubilityofasolidsoluteinthesolution. D) decreasesthesolubilityofasolidsoluteinthesolution. E) decreasesthesolubilityofaliquidsoluteinthesolution. Answer: C 16) WhichoneofthefollowingcompoundswillNOTbesolubleinwater? A) NaOH B) PbS C) K2 SO4 D) LiNO3 E) MgCl 2 Answer: B 17) Whichoneofthefollowingcompoundswillbesolubleinwater? A) AgCl B) Cu(OH)2 C) LiCl D) CaSO4 E) PbCO 3 Answer: C 18) WhensolutionsofKClandPb(NO3 ) 2 aremixed,aprecipitateforms.Whichofthefollowingisthebalanced equationforthedoublereplacementreactionthatoccurs? A) KCl(aq)+Pb(NO3 ) 2 (aq)KNO3 (aq) + PbCl2 (s) B) KNO3 (aq)+PbCl2 (s)KCl(aq)+ Pb(NO3 ) 2 (aq) C) K+ (aq)+NO3 - (aq)KNO3 (aq) D) 2KCl(aq)+Pb(NO3 ) 2 (aq)2KNO3 (aq) + PbCl2 (s) E) KCl(aq)+Pb(NO3 ) 2 (aq)KNO3 (aq) + PbCl(s) Answer: D

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19) Themass/masspercentconcentrationrefersto A) gramsofsolutein1kgofsolvent. B) gramsofsolutein1kgofsolution. C) gramsofsolutein100gofsolvent. D) gramsofsolutein100gofsolution. E) gramsofsolventin100gofsolution. Answer: D 20) Whatistheconcentration,inm/m%,ofasolutionpreparedfrom50.0gNaCland150.0gofwater? A) 0.250% B) 33.3% C) 40.0% D) 25.0% E) 3.00% Answer: D 21) Rubbingalcoholis70.%isopropylalcoholbyvolume.HowmanymLofisopropylalcoholareina1pint(473 mL)container? A) 70.mL B) 0.15mL C) 680mL D) 470mL E) 330mL Answer: E 22) Whatistheconcentration,inm/v%,ofasolutionpreparedfrom50.gNaCland2.5Lofwater? A) 5.0% B) 2.0% C) 0.020% D) 0.050% E) 20.% Answer: B 23) Howmanygramsofglucoseareneededtoprepare400.mLofa2.0%( m/v)glucosesolution? A) 800.g B) 0.0050g C) 8.0g D) 2.0g E) 200.g Answer: C 24) Whatvolume(mL)ofa15%(m/v)NaOHsolutioncontains120gNaOH? A) 18mL B) 0.13mL C) 13mL D) 120mL E) 8.0x102 mL Answer: E

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25) Howmanymillilitersofa25%(m/v)NaOHsolutionwouldcontain75gofNaOH? A) 25mL B) 75mL C) 33mL D) 19mL E) 3.0x102 mL Answer: E 26) A(n)________isatypeofcolloidinwhichaliquidisdispersedinanotherliquidorasolid. A) suspension B) aerosol C) foam D) sol E) emulsion Answer: E 27) Ahomogeneousmixturethatdoesnotsettleoutuponstandingis A) anelement. B) acolloid. C) asuspension. D) homogeneous. E) hydrated. Answer: B 28) Intheprocessknownasosmosis,________movesthroughasemipermeablemembraneintoanareaof ________concentration. A) solute;lowersolute B) solute;highersolute C) solvent;lowersolute D) solvent;lowersolvent E) solvent;highersolvent Answer: D Forthequestion(s)thatfollow,considera4%starchsolutionanda10%starchsolutionseparatedbyasemipermeablemembrane. 29) Whichstarchsolutionwilldecreaseinvolumeasosmosisoccurs? A) 4% B) 10% C) Neitherexertsosmoticpressure. D) Theyexertequalosmoticpressures. E) Theyexertoppositeosmoticpressures. Answer: A 30) Theprocessthatoccursinthissystemis A) filtration. B) hydration. C) neutralization. D) dialysis. E) osmosis. Answer: E

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31) Whichofthefollowingalsooccursinthissystem? A) Waterflowsequallyinbothdirections. B) Thereisanetflowofwaterfromthe4%starchsolutionintothe10%starchsolution. C) Thereisanetflowofwaterfromthe10%starchsolutionintothe4%starchsolution. D) Waterdoesnotcrossthemembraneatall. E) Starchmovesoutofthe10%starchsolutionintothe4%starchsolution. Answer: B 32) Asolutionwiththesameosmoticpressureasthebloodis A) isotonictotheblood. B) hypotonictotheblood. C) hypertonictotheblood. D) nontonictotheblood. E) molartotheblood. Answer: A 33) Asolutionthathasanosmoticpressurelessthanthatofredbloodcellsiscalled A) saturated. B) hypertonic. C) isotonic. D) hypotonic. E) unsaturated. Answer: D 34) Aredbloodcellwillundergocrenationin A) water. B) 0.5%NaCl. C) 3%glucose. D) 5%glucose. E) 7%NaCl. Answer: E 35) Whichsolutionisisotonictoaredbloodcell? A) water B) 0.5%NaCl C) 2%glucose D) 0.9%NaCl E) 10%glucose Answer: D 36) Aredbloodcellwillundergohemolysisin A) water. B) 0.9%NaCl. C) 5%glucose. D) 5%NaCl. E) 10%glucose. Answer: A

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37) Theprocessbywhichasemipermeablemembraneallowswatermolecules,smallmolecules,andionstopass throughwhileretaininglargeparticlesiscalled A) osmoticpressure. B) dialysis. C) solvation. D) dilution. E) hydration. Answer: B 38) Anaqueousmixturecontainingstarch(acolloid),NaCl,glucose,andalbumin(acolloid)isplacedina dialyzingbagandimmersedindistilledwater.Whichofthefollowingcorrectlydescribesthelocationofthe indicatedsubstanceafterdialysis? A) albumin,inside B) starchoutside C) albumininsideandoutside D) waterinsideonly E) starchinsideandoutside Answer: A 39) Whatisthemolarityofasolutionthatcontains17gofNH3 in0.50Lofsolution? A) 34M B) 2.0M C) 0.50M D) 0.029M E) 1.0M Answer: B 40) When200.mLofwaterareaddedto100.mLof12%KClsolutionthefinalconcentrationofKClis(Assumethe volumesadd) A) 12%. B) 4.0%. C) 36%. D) 6.0%. E) 8.0%. Answer: B 41) Themolarity(M)ofasolutionrefersto A) molesofsolute/Lofsolution. B) molesofsolute/Lofsolvent. C) molesofsolute/100mLofsolution. D) gramsofsolute/100mLofsolution. E) gramsofsolute/Lofsolution. Answer: A 42) Whatisthemolarityofasolutioncontaining5.0molesofKClin2.0Lofsolution? A) 2.5M B) 1.0M C) 5.0M D) 10.M E) 2.0M Answer: A

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43) Whatisthemolarityofasolutionwhichcontains58.5gofsodiumchloridedissolvedin0.500Lofsolution? A) 0.500M B) 1.00M C) 1.50M D) 2.00M E) 4.00M Answer: D 44) HowmanymolesofCaCl2 arein250mLofa3.0MofCaCl2 solution? A) 750moles B) 1.3moles C) 83moles D) 0.75mole E) 3.0moles Answer: D 45) Whatvolumeofa1.5MKOHsolutionisneededtoprovide3.0molesofKOH? A) 3.0L B) 0.50L C) 2.0L D) 4.5L E) 0.22L Answer: C 46) Duringtheprocessofdilutingasolution, A) theamountofsolutedoesnotchange. B) theamountofsolventdoesnotchange. C) thereismoresoluteintheconcentratedsolution. D) thevolumeofthesolutiondoesnotchange. E) waterisremovedfromtheconcentratedsolution. Answer: A 47) AccordingtoHenryslaw,thesolubilityofagasinaliquid A) decreasesasthegaspressureabovetheliquidincreases. B) increasesasthegaspressureabovetheliquidincreases. C) remainsthesameasthetemperatureincreases. D) dependsontheliquidpolarity. E) dependsontheliquiddensity. Answer: B 48) Usethereaction:2AgNO3 (aq)+ H2 SO4 (aq) Ag2 SO4 (s) + 2H2 O(l) What volume of 0.123 M AgNO3 (aq) is needed to form 0.657 g of Ag2 SO4 (s)? A) 34.2L B) 17.1mL C) 34.2mL D) 10.7mL E) 53.4mL Answer: C

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8.2 BimodalQuestions
1) Aceticacidcanbeclassifiedasa________. A) gas B) solid C) weakelectrolyte D) strongelectrolyte E) ioniccompound Answer: C 2) Usingakidneymachinetoremovewasteproductsfromthebloodisknownas________. A) osmosis B) osmolysis C) autolysis D) hemolysis E) hemodialysis Answer: E 3) Amixtureinwhichonecomponentsettlesiscalleda(n)________. A) solution B) colloid C) suspension D) electrolyte E) nonelectrolyte Answer: C 4) Themolarityofasolutionof5.0gofKClin100.mLofsolutionis________. A) 0.038M B) 0.067M C) 0.67M D) 0.13M E) 1.3M Answer: C 5) If100.mLofwaterisaddedto25mLof5.0MNaCl,thefinalconcentrationis________. A) 25M B) 1.0M C) 5.0M D) 2.0M E) 1.3M Answer: B

8.3 ShortAnswerQuestions
1) Isbariumsulfate,BaSO4 ,solubleorinsolubleinwater? Answer: insoluble 2) Inthefollowingequation,________willprecipitateoutofwatersolution. NaCl+AgNO3 AgCl+NaNO3 Answer: AgCl

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3) Inthefollowingequation,________willprecipitatefromsolution. BaCl2 +H2 SO4 BaSO4 +2HCl Answer: BaSO4 4) Thenumberofmolesofacompounddissolvedinoneliterofasolutioniscalledthe________. Answer: molarity 5) Asubstancethatcarriesanelectriccurrentwhendissolvedinwateriscalleda(n)________. Answer: electrolyte 6) Asubstancethatproducesonlyasmallnumberofionsinsolutionisknownasa________electrolyte. Answer: weak 7) Asolutionofsodiumcarbonate,Na 2 CO3 ,thathasamolarityof0.0100Mcontains________equivalentsof carbonateperliterofthesolution. Answer: 0.0200 8) Substanceswhoseparticlesinsolutionscatterlightandpassthroughfiltersbutcannotpassthrough semipermeablemembranesarecalled________. Answer: colloids

8.4 MatchingQuestions
Identifythetermdefinedineachdescription. 1) Column1: asolutionthatcontainsthe highestamountofsolutethat dissolvesatagiven temperature Column2: saturated Answer: saturated 2) Column1: themajorattractionbetween watermolecules Column2: hydrogenbonding Answer: hydrogenbonding 3) Column1: theassociationofseveral watermoleculeswithions producedinasolution Column2: hydration Answer: hydration 4) Column1: asolutioninwhichmore solutecanbedissolved Column2: unsaturated Answer: unsaturated

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5) Column1: asolutionthathasahigher osmoticpressurethanthered bloodcellsofthebody Column2: hypertonic Foil: hypotonic Answer: hypertonic Matchthetypeofmixturewiththeappropriatecharacteristics. 6) Column1: amixtureofsodiumchloride inwater Column2: solution Answer: solution 7) Column1: amixturewhoseparticles settleonstanding Column2: suspension Answer: suspension 8) Column1: ahomogeneousmixturein whichsuspendedparticles cannotpassthrougha semipermeablemembrane Column2: colloid Answer: colloid 9) Column1: amixturewhoseparticles cannotbeseparatedbyfilters orsemipermeablemembranes Column2: solution Answer: solution 10) Column1: amixturewhoseparticlescan beseparatedbyfilters Column2: suspension Answer: suspension Comparetheosmoticpressureofthesesolutionstotheosmoticpressureofredbloodcells. 11) Column1: water Column2: hypotonic Answer: hypotonic 12) Column1: 0.5%NaCl Column2: hypotonic Answer: hypotonic

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13) Column1: 7%glucose Column2: hypertonic Answer: hypertonic 14) Column1: 5%glucose Column2: isotonic Answer: isotonic 15) Column1: 0.9%NaCl Column2: isotonic Answer: isotonic Indicatewhethereachofthefollowingcompoundsdissolvesinwatertogiveions,molecules,orboth. 16) Column1: NaCl,astrongelectrolyte Column2: ions Answer: ions 17) Column1: HI,aweakelectrolyte Column2: both Answer: both 18) Column1: CH3 CH2 OH,anonelectrolyte Column2: molecules Answer: molecules 19) Column1: KNO3 ,astrongelectrolyte Column2: ions Answer: ions 20) Column1: glucose,anonelectrolyte Column2: molecules Answer: molecules 21) Column1: H2 CO 3 ,aweakelectrolyte Column2: both Answer: both

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Chapter9 Equilibrium 9.1 MultipleChoiceQuestions

1) Acatalystis A) areactantinachemicalreaction. B) aproductinachemicalreaction. C) asubstancethatspeedsupareactionwithoutbeingconsumedinthereaction. D) asubstancethatincreasestheenergyoftheproducts. E) asubstancethatdecreasestheenergyoftheproducts. Answer: C 2) Whenareactionisatequilibrium, A) allreactionstops. B) nomorereactantsareconvertedtoproducts. C) thereactionisnolongerreversible. D) theforwardandreversereactionsoccuratthesamerate. E) theproductsandreactantshavethesameenergycontent. Answer: D 3) Forthefollowingequilibriumreaction,whichcauseandeffectarecorrectlymatched? CO(g)+2H2 (g)CH3 OH(g)+heat A) addheat,shiftright B) addCO,shiftleft C) removeCH3 OH,shiftleft D) removeheat,nochange E) removeH2 ,shiftleft Answer: E 4) Theactivationenergyofachemicalreactionistheenergythat A) mustberemovedfromthemixture. B) mustbereleasedfromthemixture. C) initiatesthereaction. D) activatesthecatalyst. E) isthedifferenceintheenergiesofthestartingmaterialsandproducts. Answer: C 5) Achemicalreactionhasreachedequilibriumwhen A) theconcentrationsofreactantsandproductsareequal. B) allreactantshavebeenconvertedtoproducts. C) allproductshavebeenremovedfromthereactionmixture. D) thecatalysthasbeenusedup. E) therateoftheforwardreactionequalstherateofthereversereaction. Answer: E 6) Inacatalyzedchemicalreaction,onefunctionofacatalystisto A) increasethenumberofsuccessfulreactantcollisions. B) decreasetheconcentrationofreactants. C) changetheequilibriumconcentrationsoftheproductsandreactants. D) increasetheenergygivenoffduringthereaction. E) increasethetemperatureatwhichthereactioniscarriedout. Answer: A

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7) Inthefollowingreaction,whatistheeffectofaddingmoreNO 2 tothestartingreactionmixture? 2NO 2N2 O4 A) Itwouldmakethereactionmoreendothermic. B) Itwouldmakethereactionmoreexothermic. C) Itwouldslowthereactiondown. D) Itwoulddecreasethefinalquantityofproducts. E) Itwouldincreasethefinalquantityofproducts. Answer: E 8) Thephysiologicalequilibriumsystemthatkeepsthetemperatureofthebodyconstantiscalled________. A) stimulation B) regulation C) metabolism D) homeostasis E) catalysis Answer: D 9) Whenyouopenabottleofasoftdrinkandleaveitopen,thedrinkeventuallygoesflat.Thishappensbecause theequilibriumbetweencarbonicacidandcarbondioxideshiftstoproduce A) morecarbonicacid. B) morewater. C) moreoxygen. D) morecarbondioxide. E) morehydrogenions. Answer: D 10) Ironmetalreactswithoxygengastoproduceiron(III)oxide.Whatwillbetheeffectofincreasingthepressure ofoxygengasinaclosedreactionvessel? A) Lessreactionwilltakeplace. B) Moreironoxidewillbeproduced. C) Thereactionmixturewillcatchfire. D) Thereisnoeffect;acatalystisneeded. E) Therateofproductionofironoxidewillslowdown. Answer: B 11) Inthefollowingreaction,whatistheeffectonthedirectionofthereactionifmoreSO 3 isaddedtothereaction mixture? 2SO 2 +O2 2SO3 A) Theequilibriumshiftstoproducemoreproducts. B) Thepositionoftheequilibriumremainsunchanged. C) Therateofformationofproductsisincreased. D) Theequilibriumshiftstoproducemorereactants. E) Thecatalystforthereactionisusedup. Answer: D

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12) Inthefollowingreaction,Kcismuchlessthan1.Atequilibrium,whichofthefollowingstatementsistrue? COCl 2 CO+Cl 2 A) Theconcentrationofreactantismuchgreaterthantheconcentrationofproducts. B) Theconcentrationofproductsismuchgreaterthantheconcentrationofreactants. C) Theconcentrationsofproductsandreactantsareapproximatelyequal. D) Acatalystwillincreasetheconcentrationofproductsformed. E) Atequilibrium,theconcentrationsofreactantsandproductsareequal. Answer: A 13) Inthereactionofnitrogengaswithoxygengastoproducenitrogenoxide,whatistheeffectofaddingmore oxygengastotheinitialreactionmixture?Thereactionisshownbelow. N2 (g)+O2 (g)2NO(g) A) TheequilibriumshiftstoproducemoreN 2 . B) TheequilibriumshiftstoproducemoreNO. C) Theequilibriumisnotaffected. D) Extracatalystisrequiredtoreachequilibrium. E) Thetemperatureofthereactionmixtureisraised. Answer: B 14) Theequilibriumconstantfortheproductionofcarbondioxidefromcarbonmonoxideandoxygenis Kc=21011.Thismeansthatthereactionmixtureatequilibriumislikelytoconsistof A) mostlystartingmaterials. B) anequalmixtureofproductsandreactants. C) twiceasmuchstartingmaterialasproduct. D) twiceasmuchproductasstartingmaterial. E) mostlyproducts. Answer: E 15) Whichofthefollowingequilibriumconstantsindicatesthereactionthatgivesthesmallestamountofproduct? A) Kc=510-10 B) Kc=510-1 C) Kc=5100 D) Kc=5101 E) Kc=51010 Answer: A

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16) Thereactionofhemoglobinwithoxygencanbewrittenasfollows. Hb+O2 HbO2 Iftheamountofoxygenavailabletotheblooddecreasessignificantly,whathappenstotheindividual involved? A) Hypoxiaresults. B) Anemiaresults. C) Nitrogennarcosisresults. D) Oxygenpoisoningresults. E) Acclimatizationresults. Answer: A 17) Whatisthecorrectformfortheequilibriumconstantforthisreaction? H2(g)+F2(g)2HF (g) A) B) C) D) E) HF H2 F2 HF 2 H2 F2 H2 F2 HF H2 F2 HF 2 H2 F2 2 HF

Answer: B 18) Therateofanychemicalreactioncanbedeterminedbyobserving A) theamountofproductformedinaunitoftime. B) theratioofproductconcentrationtoreactantconcentration. C) thepercentcompositionofthefinalproduct. D) thetheoreticalyieldofthereaction. E) thenumberofchemicalbondsbrokenandremade. Answer: A 19) Inanychemicalreaction,therateofthereactioncanbeincreasedby A) decreasingthetemperature. B) changingthesizeofthecontainer. C) addingwatertothereaction. D) addingproductmoleculestothereactionmixture. E) increasingtheconcentrationsofthereactants. Answer: E

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20) Refrigeratingperishablefoodsaffectsbiochemicalreactionsby A) increasingconcentrationsofantioxidants. B) removingbacteria. C) decreasingtherateofreactionsaffectingspoilage. D) catalyzingtheremovalofharmfulchemicalsfromthefoods. E) improvingtheappearanceofthefoods. Answer: C 21) Inacatalyticconverterinanautomobile,thereactionofcarbonmonoxidewithoxygenproduces________. A) carbondioxide B) carbonandmoreoxygen C) water D) methane E) nitrogenoxide Answer: A 22) Onemetalthatisusedasacatalystinacatalyticconverterinanautomobileis________. A) carbon B) iron C) copper D) platinum E) plutonium Answer: D 23) Areactionthatcanproceedineithertheforwardorthereversedirectionaswritteniscalleda________ reaction. A) reversible B) miniscule C) microscopic D) solidphase E) favored Answer: A 24) Fortheequilibriumreactionofcarbondioxidewithwater,whatistheappropriateequation? A) H2 O+COH2 CO 3 B) H2 O+2CO 2H2 CO 3 C) H2 O+CO2H2 CO 3 D) H2 O+CO2HCO3 E) H2 O+CO2H2 CO 2 Answer: C

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25) Whatisthecorrectformoftheequilibriumconstantforthereactionofhydrogenandoxygentoformwater? Theequationis: 2H2 (g)+O2 (g)H2 O(g) A) Kc= B) Kc= C) Kc= D) Kc= E) Kc= Answer: A 26) Theequilibriumconstantfortheformationofammoniafromnitrogenandhydrogenis1.6 102 .Whatisthe formoftheequilibriumconstant? [NH3 ]2 A) [N2 ][H2 ]3 B) [NH3 ] [N2 ][H2 ]3 [NH3 ]2 [N2 ][H2 ] [NH3 ]2 [N2 ][3H2 ]3 [2NH 3 ]2 [N2 ][H2 ]3 [H2 O] [O 2 ][H2 ]2 [H2 O] [O 2 ][H2 ] [H2 O] [O 2 ][H2 2 ] [H2 O] [O 2 ][2H2 ] [H2 O] 2 [O 2 ][H2 2 ]

C)

D)

E)

Answer: A

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27) ThereactionforthedecompositionofPCl5 tochlorineandPCl3 isshownbelow. PCl5 (g)PCl3 (g)+Cl 2 (g) Iftheequilibriumconcentrationsare[PCl 5 ]=1.0M,[PCl3 ]=0.10M,[Cl2 ]=0.10M,whatisthevalueofthe equilibriumconstant? A) 1.010-2 B) 1.010-4 C) 1010-2 D) 1.0102 E) 2.010-2 Answer: A 28) TheequilibriumforthereactionforthedecompositionofPCl 5 tochlorineandPCl3 is0.042. PCl5 (g)PCl3 (g)+Cl 2 (g) Iftheequilibriumconcentrationsare[PCl3 ]=0.010M,[Cl2 ]=0.10M,whatisthevalueof[PCl 5 ]? A) 0.010M B) 0.0020M C) 0.042M D) 0.024M E) 0.0010M Answer: D 29) PCl5 (g)PCl3 (g)+Cl 2 (g) Forthereactionatequilibrium,ifthevolumeofthecontainerisincreased,theamountof PCl5presentwill A) decrease. B) increase. C) double. D) staythesame. E) triple. Answer: A 30) ThevalueoftheequilibriumconstantforthecombinationofnitrogenandoxygentomakeNOis2 10-9 . Whatdoesthistellyouabouttheconcentrationsofmaterialsintheequilibriummixture? A) Theconcentrationofproductsexceedstheconcentrationofreactants. B) Theconcentrationsofreactantsandproductsareequal. C) Thereactantsaresolids. D) Theconcentrationofreactantsexceedstheconcentrationofproducts. E) Theproductsaresolids. Answer: D

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31) Carbonmonoxidebindstohemoglobin140timesmorestronglythanoxygendoes.Whatdoesthistellyou abouttheequilibriumconstantsforthetworeactionsofhemoglobinwithcarbonmonoxideandoxygen? A) TheequilibriumconstantforthebindingofCOisgreater. B) Theequilibriumconstantforthebindingofoxygenisgreater. C) Theconcentrationofcarbonmonoxideatequilibriumistwicethatofoxygen. D) Oxygenandcarbonmonoxidehavethesameformulamass. E) Oxygenandcarbonmonoxidereactwithhemoglobinindifferentfashions. Answer: A 32) Treatmentofcarbonmonoxidepoisoningcanbeaccomplishedbytheuseofpureoxygenforbreathing.Thisis anexampleoftheuseof________inaclinicalsetting. A) theidealgaslaw B) LeChateliersprinciple C) Henryslaw D) conservationofmass E) aprecipitationreaction Answer: B 33) Inthereactionofnitrogenandhydrogentogiveammonia,allthereactantsandproductsare________. A) gases B) liquids C) solids D) boiling E) frozen Answer: A 34) Inthereactionofcarbondioxidewithwatertogivecarbonicacid,theonlygaseouscomponentisthecarbon dioxide.Whatwillhappentotheequilibriumconcentrationofcarbonicacidifthepressureofcarbondioxideis increasedinthecontainer? A) Theconcentrationofcarbonicacidwillincrease. B) Thecarbonicacidconcentrationwilldecrease. C) Thecarbonicacidconcentrationwillstaythesame. D) Therewillbetwiceasmuchcarbonicacidascarbondioxide. E) Therewillbemorewateravailableforthereaction. Answer: A 35) Inanexothermicreaction,heatcanbeconsidereda________. A) reactant B) product C) rate D) catalyst E) determinant Answer: B 36) Anequilibriuminwhichallthecomponentsaregasesisa________equilibrium. A) heterogeneous B) liquid C) catalytic D) homogeneous E) reversible Answer: D

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37) Forthereactionofcarbonwithcarbondioxidetomakecarbonmonoxide,thereactionisasfollows. C(s)+CO2 (g)2CO(g) Thisisanexampleofa________equilibrium. A) heterogeneous B) homogeneous C) gas D) catalytic E) irreversible Answer: A 38) Forthereactionofcarbonwithcarbondioxidetomakecarbonmonoxide,thereactionisasfollows.Writethe formoftheKc. C(s)+CO2 (g)2CO(g) A) Kc= B) Kc= C) Kc= D) Kc= E) Kc= [CO] [CO2 ] [2CO]2 [CO2 ] [CO]2 [CO2 ] [CO]2 [C][CO2 ] [2CO] [CO2 ]

Answer: C 39) Forthereactionofcarbonwithcarbondioxidetomakecarbonmonoxide,onesetofconditionsproduceda Kc = 1.210-1 .Atequilibriumatacertaintemperature,theconcentrationofproductwas0.60M.Whatwasthe concentrationofcarbondioxideatthattemperature? C(s)+CO2 (g)2CO(g) A) 3.0M B) 0.60M C) 0.36M D) 3.33M E) 5.0M Answer: A

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40) Forthefollowingreaction,theequilibriumconstantKc is2.0atacertaintemperature.Iftheconcentrationof bothproductsis0.10Matequilibrium,whatistheconcentrationofthestartingmaterial,NOBr? 2NOBr(g)2NO(g)+Br 2 (g) A) 510-4M B) 2.210-4 M C) 510-2 M D) 2.210-2 M E) 2.2M Answer: D 41) Forthefollowingreaction,theequilibriumconstantKc is2.0atacertaintemperature.Thereactionis endothermic.WhatdoyouexpecttohappentotheconcentrationofNOifthetemperatureisdoubled? 2NOBr(g)2NO(g)+Br 2 (g) A) TheconcentrationofNOwillincrease. B) TheconcentrationofNOwilldecrease. C) Therewillbenochangein[NO]. D) Acatalystwillbeneededtomakeachangeinconcentration. E) Thechangeinconcentrationof[NO]willdependonthesizeofthevessel. Answer: A 42) Forthefollowingreaction,theequilibriumconstantKc is2.0atacertaintemperature.Brominecanbeliquefied easilyandremovedfromthereactionvesselasitisformed.Ifthisisdone,howwillitaffecttheequilibrium reaction? 2NOBr(g)2NO(g)+Br 2 (g) A) MoreproductswillbemadeasBr 2 isremoved. B) TherewillbealargerproportionNOBrinthevesselwhenequilibriumisreached. C) LessNOwillbemade. D) Thepressureinthevesselwillincrease. E) Theequilibriumconstantwillchange. Answer: A

9.2 BimodalQuestions
1) Anyreactionthatabsorbs150kcalofenergycanbeclassifiedas________. A) endothermic B) exothermic C) activated D) reduction E) oxidation Answer: A

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2) The________istheenergydifferencebetweenreactantsandproductsinachemicalreaction. A) transitionenergy B) activationenergy C) productenergy D) overallenergy E) heatofreaction Answer: E 3) Whatisthecorrectformoftheequilibriumconstantforthisreaction? 2H2 O2 (g)2H2 O(g)+O2 (g) A) B) H2 O H2 O2 O2 H2 O 2 H2 O 2 2 H2 O 2 H2 O2 H2 O O2 H2 O2

C) D)

Answer: B 4) Forthefollowingreaction,theequilibriumconstantKc is2.0atacertaintemperature.Writetheformofthe equilibriumconstant,Kc. 2NOBr(g)2NO(g)+Br 2 (g) [Br2 ][NO]2 [NOBr]2 [Br2 ][NO] [NOBr]2 [Br2 ][NO]2 [NOBr]

A) B)

C)

[Br2 ][NO] D) [NOBr] [Br][NO] E) [NOBr] Answer: A

9.3 MatchingQuestions
Indicatetheeffectofeachchangeupontherateofareaction. 1) Column1: addingacatalyst Column2: increases Answer: increases

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2) Column1: removingsomereactant Column2: decreases Answer: decreases 3) Column1: Thetemperatureisdoubled. Column2: increases Answer: increases 4) Column1: Theconcentrationofareactant isdecreased. Column2: decreases Answer: decreases 5) Column1: Morecollisionsbetween moleculesoccur. Column2: increases Answer: increases

9.4 True/FalseQuestions
1) Anequilibriumconstantgreaterthan1forareactionindicatesthatthereactionfavorsformationofthe products. Answer: TRUE 2) AnequilibriumconstantKc=1107 forareactionindicatesthatthereactionfavorsproductformation. Answer: TRUE 3) AnequilibriumconstantKc=110-3 forareactionindicatesthatthereactionfavorsproductformation. Answer: FALSE 4) Iftheequilibriumconstantforareactionis110 -5 ,thismeansthatthereactiondoesnotproceedwellto products. Answer: TRUE 5) Activationenergyisalwaysalargeamountofenergy. Answer: FALSE 6) Atequilibrium,theconcentrationsofthereactantsandproductsarealwaysequal. Answer: FALSE 7) Therateofachemicalreactiondependsontemperature. Answer: TRUE 8) Therateofachemicalreactionisnotaffectedbytheconcentrationofreactants. Answer: FALSE 9) Acatalystforachemicalreactionaffectsthemagnitudeoftheequilibriumconstant. Answer: FALSE 10) Oneofthesubstancesacteduponbyacatalyticconverterinanautomobileiscarbondioxide. Answer: FALSE Page118

11) Aheterogeneousequilibriumisoneinwhichthereactantsandproductsarefoundintwoormorephysical states. Answer: TRUE 12) Anexampleofastressonanequilibriumistheincreaseofpressureinaclosedsystemwhenthepressureofa reactantgasisincreasedfrom1.0atmto2.0atm. Answer: TRUE 13) Acatalystlowerstheactivationenergyofachemicalreaction. Answer: TRUE

9.5 ShortAnswerQuestions
1) Theruleorprinciplethatdescribestheeffectofchangingreactionconditionsonanequilibriumisknownas ________principle. Answer: LeChateliers 2) Amixtureatequilibriumthatcontainslessproductthanreactanthasa Kc thatis________than1. Answer: less 3) Writetheequilibriumconstantexpressionforthereactionofnitrogenandhydrogentogiveammonia,N H3 . Answer: NH3 2 N2 H2 3

4) Theequilibriumbetweenhemoglobinandoxyhemoglobininthebloodcanberepresentedbythefollowing reaction.Writetheformoftheequilibriumconstantexpression. Hb+O2HbO2 [HbO 2 ] [Hb][O 2 ]

Answer: Kc=

5) Anequilibriumconstantwithavaluegreaterthan1meansthereactionfavorsthe________. Answer: products

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Chapter10 AcidsandBases 10.1 Multiple-ChoiceQuestions

1) AccordingtotheArrheniusconcept,ifNaOHweredissolvedinwater,itwouldactas A) abase. B) anacid. C) asourceofhydroniumions. D) asourceofH- ions. E) aprotondonor. Answer: A 2) AccordingtotheArrheniusconcept,ifHNO3 weredissolvedinwater,itwouldactas A) abase. B) anacid. C) asourceofhydroxideions. D) asourceofH- ions. E) aprotonacceptor. Answer: B 3) ThenamegiventoanaqueoussolutionofHBris A) hydrogenbromide. B) hydrobromicacid. C) bromicacid. D) bromousacid. E) hypobromousacid. Answer: B 4) ThenamegiventoanaqueoussolutionofHNO3 is A) nitricacid. B) nitrousacid. C) hydrogennitrate. D) hydronitrogenacid. E) hyponitricacid. Answer: A 5) Whichoneofthefollowingischaracteristicofabase? A) producesH3 O+ inwater B) hasasourtaste C) hasaslippery,soapyfeel D) turnsbluelitmusred E) isinsolubleinwater Answer: C 6) AccordingtotheBronsted-Lowrydefinition, A) anacidisaprotonacceptor. B) abaseproducesH+ ionsinaqueoussolutions. C) abaseisaprotondonor. D) abaseisaprotonacceptor. E) anacidactsasthesolvent. Answer: D

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7) IdentifytheBronsted-Lowryacidinthefollowingreaction. H2 O+CO3 2- HCO3 - +OHA) H2 O B) CO 3 2C) HCO3 D) OHE) H2 CO 3 Answer: A 8) Thecorrectformulaforsulfuricacidis A) H2 SO4 . B) H2 SO3 . C) H2 SO4 - . D) H2 SO3 - . E) SO4 2- . Answer: A 9) ThenameofAl(OH) 3 is A) aluminumtrihydroxide. B) monoaluminumtrihydroxide. C) aluminumhydroxide. D) aluminum(III)hydroxide. E) aluminumoxygenhydride. Answer: C 10) Whichofthefollowingstatementscorrectlydescribesthehydronium-hydroxidebalanceinthegivensolution? A) Inacids,[OH- ]isgreaterthan[H3 O+ ]. B) Inbases,[OH- ]=[H3 O+ ]. C) Inneutralsolutions,[H3 O+ ]=[H2 O]. D) Inbases,[OH- ]isgreaterthan[H3 O+ ]. E) Inbases,[OH- ]islessthan[H3 O+ ]. Answer: D 11) ForKw,theproductof[H3 O+ ]and[OH- ]is A) 1.0x10-14. B) 1.0x10-7 . C) 1.0x10-1 . D) 1.0. E) 1.0x1014. Answer: A

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12) Whatisthe[H3 O+ ]inasolutionwith[OH- ]=1x10-12M? A) 1x10-12M B) 1x102 M C) 1x10-7 M D) 1x10-8 M E) 1x10-2 M Answer: E 13) Whatisthe[OH- ]inasolutionthathasa[H3 O+ ]=1x10-6 M? A) 1x10-2 M B) 1x10-6 M C) 1x10-8 M D) 1x10-10M E) 1x10-12M Answer: C 14) Whatisthe[OH- ]inasolutionthathasa[H3 O+ ]=2.0x10-4 M? A) 2.0x10-10M B) 5.0x10-10M C) 1.0x10-10M D) 2.0x10-4 M E) 5.0x10-11M Answer: E 15) AsolutionwithapHof4is A) extremelyacidic. B) moderatelyacidic. C) neutral. D) slightlybasic. E) extremelybasic. Answer: B 16) WhatisthepHofasolutionwith[H3 O+ ]=1x10-9 M? A) 1.0x10-5 M B) -9.0 C) 5.0 D) -5.0 E) 9.0 Answer: E 17) WhatisthepHofasolutionwith[H3 O+ ]=3.0x10-3 M? A) 3.0x10-3 B) 2.52 C) 3.0 D) -2.52 E) 9.0 Answer: B

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18) WhatisthepHofasolutionwith[OH- ]=1x10-4 M? A) 10.0 B) -10.0 C) 4.0 D) -4.0 E) 1.0x10-10 Answer: A 19) WhatisthepHofasolutionwith[OH- ]=2.0x10-10M? A) 9.70 B) -9.70 C) 4.30 D) -4.30 E) 2.0x10-10 Answer: C 20) The[H3 O+ ]ofasolutionwithpH=2is A) 10M. B) -10M. C) 1x102 M. D) 1x10-2 M. E) 1x10-12M. Answer: D 21) InwhichofthefollowingarethepHvaluesarrangedfromthemostbasictothemostacidic? A) 1,3,6,8,11,14 B) 2,5,7,9,10,11 C) 14,10,7,4,3,1 D) 14,10,7,1,3,5 E) 7,10,14,4,3,1 Answer: C 22) Whichofthefollowingisthestrongestacid? A) H3 PO4 B) NH4 + C) NaOH D) H2 CO 3 E) HCl Answer: E 23) Whichofthefollowingisthestrongestbase? A) H3 PO4 B) NH3 C) NaOH D) NaCl E) HCl Answer: C

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24) Whichofthefollowingiscorrectlyidentified? A) NH3 ,strongacid B) NaOH,strongbase C) HCl,weakacid D) H2 CO 3 ,strongacid E) Ca(OH)2 ,weakbase Answer: B 25) Ammoniumhydroxideisaweakbasebecause A) itisadilutesolution. B) itisonlyslightlysolubleinwater. C) itcannotholdontoitshydroxideions. D) itdissociatesonlyslightlyinwater. E) itiscompletelyionizedinaqueoussolution. Answer: D 26) Anacidandbasereacttoformasaltandwaterina(n)________reaction. A) ionization B) dissociation C) oxidation D) neutralization E) reduction Answer: D 27) Inaneutralizationreaction A) twoacidsreacttoformwater. B) waterandasaltreacttoformanacidandabase. C) anacidandasaltreacttoformwaterandabase. D) abaseandasaltreacttoformwaterandanacid. E) anacidandabasereacttoformasaltandwater. Answer: E 28) Whichofthefollowingisthecorrectlybalancedequationforthecompleteneutralizationof H3 PO4 with Ca(OH) 2 ? A) H3 PO4 +Ca(OH)2 CaHPO4 + 2H2 O B) 3H3 PO4 +Ca(OH)2 Ca3 (PO4 )2 + 5H2 O C) H3 PO4 +Ca(OH)2 Ca3 (PO4 )2 + H2 O D) 2H3 PO4 +3Ca(OH)2 Ca3 (PO4 )2 + 6H2 O E) 4H3 PO4 +6Ca(OH)2 2Ca3 (PO4 )2 + 12H2 O Answer: D 29) TheneutralizationreactionbetweenAl(OH) 3 andHNO3 producesthesaltwiththeformula A) H2 O. B) AlNO3 . C) AlH2 . D) Al(NO3 )3 . E) NO3 OH. Answer: D

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30) HowmanymolesofH2 Oareproducedwhen1moleofMg(OH)2 reactswith1moleofH2 SO4 ? A) 1 B) 2 C) 3 D) 4 E) 5 Answer: B 31) Whichofthefollowingisaneutralizationreaction? A) KCl+NaNO3 KNO3 +NaCl B) HNO3 +KOHH2 O+KNO3 C) H2 O+SO3 H2 SO4 D) 4Na+O2 2Na2 O E) 2NO2 2NO+O2 Answer: B 32) Thefunctionofabufferisto A) changecolorattheendpointofatitration. B) maintainthepHofasolution. C) beastrongbase. D) maintainaneutralpH. E) actasastrongacid. Answer: B 33) ThenormalbloodpHisabout A) 6.8. B) 7.0. C) 7.2. D) 7.4. E) 7.6. Answer: D 34) InabuffersystemofHFanditssalt,NaF, A) theHFneutralizesaddedacid. B) theHFneutralizesaddedbase. C) theHFisnotnecessary. D) theF- neutralizesaddedH2 O. E) theF- neutralizesaddedbase. Answer: B 35) Whichofthefollowingisabuffersystem? A) NaClandNaNO3 B) HClandNaOH C) H2 CO 3 andKHCO3 D) NaClandNaOH E) H2 OandHCl Answer: C

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36) Whichofthefollowingcouldbeabuffer? A) NaF B) HF+NaF C) HF+H2 O D) NaF+H2 O E) NaCl+HF Answer: B 37) WhatisthenameofthemedicalconditionofanasthmaticpatientwithabloodpHof7.30? A) respiratoryacidosis B) respiratoryalkalosis C) metabolicacidosis D) metabolicalkalosis E) diabetesmellitus Answer: A 38) Ifaconditionofhypoventilationoccurs,thebloodpHofthepatientisexpectedto A) saturate. B) increase. C) decrease. D) staythesame. E) concentrate. Answer: C 39) Whenhyperventilation(rapidbreathing)causesapatienttoexhalelargeamountsofCO 2 ,thebloodpHrisesin aconditioncalled A) metabolicacidosis. B) metabolicalkalosis. C) respiratoryacidosis. D) respiratoryalkalosis. E) pulmonarydistress. Answer: D 40) WhatisthemolarityofaKOHsolutionif25.0mLneutralizes35.0mLofa0.200MHClsolution? A) 0.267M B) 0.143M C) 0.200M D) 0.280M E) 0.100M Answer: D 41) A25.0mLsampleofH3 PO4 requires50.0mLof1.50MNaOHforcompleteneutralization.Whatisthe molarityoftheacid? H3 PO4 +3NaOHNa3 PO4 +3H2 O A) 0.333M B) 3.00M C) 1.50M D) 1.00M E) 0.750M Answer: D

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42) A25.0mLsampleofH2 SO4 requires20.0mLof2.00MKOHforcompleteneutralization.Whatisthe molarityoftheacid? H2 SO4 +2KOHK2 SO4 +2H2 O A) 2.00M B) 2.50M C) 0.800M D) 1.60M E) 1.25M Answer: C 43) Howmanymillilitersof0.400MNaOHarerequiredtocompletelyneutralize20.0mLof0.200MHCl? A) 50.0mL B) 40.0mL C) 0.100mL D) 20.0mL E) 10.0mL Answer: E 44) Howmanymillilitersof0.200MNaOHarerequiredtocompletelyneutralize5.00mLof0.100M H3 PO4 ? A) 7.50mL B) 2.50mL C) 0.833mL D) 5.00mL E) 15.0mL Answer: A 45) Howmanymillilitersof0.100MBa(OH)2 arerequiredtoneutralize20.0mLof0.250MHCl? A) 100.mL B) 50.0mL C) 25.0mL D) 0.250mL E) 0.50mL Answer: C 46) TheKa forhydrofluoricacidis7.2x10-4 .ThismeansthatHFis A) neutralinwatersolution. B) abletoreactwithHCl. C) aweakacid. D) astrongacid. E) ionic. Answer: C 47) Inasulfuricacidsolution,wherethe H2 SO4 is.005M,whatisthepH? A) pH=12 B) pH=2 C) pH=3 D) pH=11 E) pH=5 Answer: B

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48) Whenapieceofmagnesiummetalisaddedtohydrochloricacid,whatgasisproduced? A) oxygen B) chlorine C) nitrogen D) carbondioxide E) hydrogen Answer: E 49) Thesaltmadefromaweakacidandastrongbaseshouldgiveasolutionof A) highconcentration. B) lowconcentration. C) pH>7. D) pH<7 E) pH=7. Answer: C Fortheproblem(s)thatfollow,considerthereactioninwhichmagnesiumreactswithanHClsolution. Mg(s)+2HCl(aq)MgCl 2 (aq)+H2 (g) 50) If2.00gofMgreactscompletelywith50.0mLofHClsolution,whatisthemolarityoftheHClsolution? A) 1.65M B) 80.0M C) 8.00M D) 0.823M E) 3.29M Answer: E

10.2 ShortAnswerQuestions
1) TheconjugateacidofHPO4 2- is________. Answer: H2 PO4 2) WritetheproperKa expressionfortheionizationofaceticacid,CH3 COOH. Answer: Ka = CH3 COO- H3 O+ / CH3 COOH 3) IfanacidhasaKa <<1,isitclassifiedasaweakacidorastrongacid? Answer: aweakacid 4) Isasolutionofsodiumphosphateinwateracidicorbasic? Answer: basic 5) WhatisthepHofabuffermadewith0.10Maceticacidand0.01Msodiumacetate? Answer: 3.74 6) Inatitrationexperiment,astudentused24.13mLof0.111Msodiumhydroxidetoneutralize20.00mLofa hydrochloricacidsolution.Whatwasthemolarityoftheacidsolution? Answer: 0.134M 7) Astudenthad2.0Lofasodiumhydroxidesolutionthathadaconcentrationof0.4000M.Thestudentneeded tomake500mLofa0.1000Msolution.HowmanymLoftheconcentratedsolutionwasneeded? Answer: 125mL

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8) Astudenthad25.0mLof0.100MH2 SO4 solution.HowmanymLofa0.100MNaOHsolutionwillthe sulfuricacidneutralize? Answer: 50.0mL

10.3 True/FalseQuestions
1) Ifthecarbondioxidelevelinthebloodistoohigh,morecarbonicacidisproduced,andthisresultsinthe conditiontermedacidosis. Answer: TRUE 2) AlkalosisisthebloodconditioninwhichthebloodpHishigherthannormal. Answer: TRUE 3) AbufferisasolutionthattendstomaintainaneutralpH. Answer: FALSE 4) Inanywatersolution, H3 O+ OH- =1.0x10-7 . Answer: FALSE 5) AnammoniumchloridesolutionshouldhaveanacidicpH. Answer: TRUE 6) Magnesiummetalisnotattackedbysulfuricacidsolutions. Answer: FALSE 7) Sodiumcarbonategivesabasicsolutioninwater. Answer: TRUE 8) Formostreactionsofacidswithbases,theresultingproductsareasaltandwater. Answer: TRUE

10.4 MatchingQuestions
Identifyeachofthefollowingcompoundsasanacid,abase,orneither. 1) Column1: HCl Column2: acid Answer: acid 2) Column1: NaOH Column2: base Answer: base 3) Column1: NH3 Column2: base Answer: base 4) Column1: H2 SO4 Column2: acid Answer: acid

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5) Column1: CO 3 2Column2: base Answer: base 6) Column1: NaCl Column2: neither Answer: neither 7) Column1: CNColumn2: base Answer: base 8) Column1: H2 CO 3 Column2: acid Answer: acid Inthefollowingsolutions,isthe[OH - ]greaterthan,lessthan,orequaltothe[H3 O+ ]? 9) Column1: acid Column2: lessthan Answer: lessthan 10) Column1: base Column2: greaterthan Answer: greaterthan 11) Column1: [H3 O+ ]=1.0x10-6 M Column2: lessthan Answer: lessthan 12) Column1: [H3 O+ ]=1.0x10-10M Column2: greaterthan Answer: greaterthan 13) Column1: [H3 O+ ]=1.0x10-7 M Column2: equalto Answer: equalto 14) Column1: pH=2 Column2: lessthan Answer: lessthan

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15) Column1: pH=9 Column2: greaterthan Answer: greaterthan Identifythefollowingasacids,bases,orneutralsolutions. 16) Column1: hasasourtaste Column2: acid Answer: acid 17) Column1: hasapH=4.5 Column2: acid Answer: acid 18) Column1: turnsbluelitmuspaperred Column2: acid Answer: acid 19) Column1: containsmorehydroniumions thanhydroxideions Column2: acid Answer: acid 20) Column1: H2 O Column2: neutral Answer: neutral 21) Column1: [H3 O+ ]=3.4x10-5 M Column2: acid Answer: acid 22) Column1: [OH- ]=2.8x10-2 M Column2: base Answer: base 23) Column1: Ca(OH) 2 Column2: base Answer: base 24) Column1: pH=9.0 Column2: base Answer: base

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25) Column1: [H3 O+ ]=1.0x10-7 M Column2: neutral Answer: neutral

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Chapter11 IntroductiontoOrganicChemistry:Alkanes 11.1 Multiple-ChoiceQuestions

1) Compoundsthathavethesamemolecularformulabutdifferentarrangementsofatomsarecalled A) isomers. B) isotopes. C) indicators. D) isozymes. E) isometrics. Answer: A 2) Whichofthefollowingistrueofnonane,C9 H20,whichhasadensityof0.79g/mL,meltsat-51C,andboilsat 157C? A) Nonaneissolubleinwater. B) Nonaneisagasatroomtemperature. C) Nonaneisasolidatroomtemperature. D) Nonanedoesnotundergocombustion. E) Nonanefloatsonthesurfaceofwater. Answer: E 3) Aformulathatshowsthearrangementofallbondsinamoleculeiscalleda(n) A) molecularformula. B) completestructuralformula. C) condensedstructuralformula. D) condensedmolecularformula. E) isomericformula. Answer: B 4) Inthethree-dimensionalstructureofmethane,CH4 ,thehydrogenatomsattachedtoacarbonatomarealigned A) inastraightline. B) atthecornersofasquare. C) atthecornersofatetrahedron. D) atthecornersofarectangle. E) atthecornersofacube. Answer: C 5) WhichoneofthefollowingisNOTanorganicsubstance? A) anantibiotic B) nylon C) coal D) silk E) salt,sodiumchloride Answer: E 6) Ahydrocarboncontainsonlytheelements A) hydrogenandoxygen. B) carbonandoxygen. C) carbonandhydrogen. D) carbon,hydrogen,andoxygen. E) carbon,hydrogen,andnitrogen. Answer: C

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7) ThefunctionalgroupcontainedinthecompoundCH3 CH2 OHisa(n) A) aldehyde. B) alkene. C) alcohol. D) ketone. E) ether. Answer: C 8) WhattypeofcompoundisCH3 CH2 CH2 Cl? A) alkane B) branchedalkane C) cycloalkane D) haloalkane E) isomer Answer: D 9) Whatisthenameofthiscompound? Cl CH3 - C H-CH2 -CH2 -Cl? A) 1,1-dichlorobutane B) 1,2,-dichlorobutane C) 1,3-dichlorobutane D) 1,4-dichlorobutane E) dichlorobutane Answer: C 10) Thespecialfeaturethatdeterminesthefamilynameandchemicalreactivityoftheorganiccompounditis foundiniscalleda(n) A) functionalgroup. B) organiccompound. C) identifyinggroup. D) ionicbond. E) covalentbond. Answer: A 11) VSEPRtheorypredictsthatsimplecarboncompoundswillformbondsthatare A) asfarapartaspossible. B) asclosetogetheraspossible. C) arrangedinastraightline. D) pointedtothecornersofacube. E) pointedtothecornersofatriangle. Answer: A 12) Amoleculecontainingacarbonatombondedtofourchlorineatomshastheshapeofa A) triangle. B) rhombus. C) square. D) cube. E) tetrahedron. Answer: E Page134

13) Thebondanglesoftetravalentcarbonareallapproximately A) 90 B) 109.5 C) 60 D) 99.5 E) 45 Answer: B 14) Ascarbonbondswithatomsofincreasinglyhigherelectronegativities,thepolarityofthebond A) decreases. B) increases. C) staysthesame. D) reverses. E) becomesinverted. Answer: B 15) CarbontetrachloridehasapolarC-Clbond.Whatistheoverallpolarityofthecarbontetrachloridemolecule? A) weaklypolar B) stronglypolar C) reversedpolarity D) nonpolar E) inversepolarity Answer: D 16) WhichofthefollowingisNOTtypicalofmostorganiccompounds? A) highmeltingpoint B) poorsolubilityinwater C) lowboilingpoint D) covalentbonding E) highflammability Answer: A 17) Afunctionalgroupisacertaingroupofatomsthat A) increaseswatersolubility. B) reactsinapredictablewaywheneverpresent. C) changesthecolorofthemoleculewheneverpresent. D) alwayscontainsoxygenornitrogen. E) nevercontainsahalogen. Answer: B 18) Analkeneisalwaysacarboncompoundthatcontainsa________bond. A) single B) double C) triple D) aromatic E) hydrogen Answer: B

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19) Analkyneisalwaysacarboncompoundthatcontainsa________bond. A) single B) double C) triple D) aromatic E) hydrogen Answer: C 20) ThefunctionalgroupcontainedinthecompoundCH3 CHOisa(n) A) aldehyde. B) alkene. C) alcohol. D) ketone. E) ether. Answer: A 21) Thefunctionalgroupcontainedinthecompound(CH3 CH2 )2 Oisa(n) A) aldehyde. B) alkene. C) alcohol. D) ketone. E) ether. Answer: E 22) ThefunctionalgroupcontainedinthecompoundCH3 CH2 CH=CHCH3 isa(n) A) aldehyde. B) alkene. C) alcohol. D) ketone. E) ether. Answer: B 23) ThefunctionalgroupcontainedinthecompoundCH3 CH2 COOCH3 isa(n) A) thiol. B) carboxylicacid. C) amine. D) ester. E) amide. Answer: D 24) ThefunctionalgroupcontainedinthecompoundCH3 CH2 SHisa(n) A) thiol. B) carboxylicacid. C) amine. D) ester. E) amide. Answer: A

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25) ThefunctionalgroupcontainedinthecompoundCH3 CH2 COOHisa(n) A) thiol. B) carboxylicacid. C) amine. D) ester. E) amide. Answer: B 26) ThefunctionalgroupcontainedinthecompoundCH3 CH2 CONH2 isa(n) A) thiol. B) carboxylicacid. C) amine. D) ester. E) amide. Answer: E 27) ThefunctionalgroupcontainedinthecompoundCH3 CH2 NH2 isa(n) A) thiol. B) carboxylicacid. C) amine. D) ester. E) amide. Answer: C 28) Isomersaremoleculesthatsharethesameformulaandhave A) adifferentshapetothemolecule. B) thesamearrangementofatomswithinthemolecule. C) adifferentarrangementofatomswithinthemolecule. D) identicalboilingpoints. E) thesameshapeineachmolecule. Answer: C 29) Organicchemistryisthestudyofthechemistryofcompoundsof A) oxygen. B) hydrogen. C) livingthings. D) polymers. E) carbon. Answer: E 30) Howdoesamoleculeofavitaminsynthesizedinthelaboratorybehavewhencomparedtothebehaviorofthe samevitaminisolatedfromanaturalsource(e.g.,vitaminCsynthesized,comparedtovitaminCfromrose hips)? A) identicalineveryway B) usuallyidentical C) Someeffectsarethesame. D) Feweffectsarethesame. E) Thenaturalvitaminisbetter. Answer: A

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31) Howmanyvalenceelectronsdoescarbonhave? A) one B) two C) three D) four E) five Answer: D 32) Carbonatomsalwayshavehowmanycovalentbonds? A) one B) two C) three D) four E) five Answer: D 33) Hydrocarbonsaretheprimaryconstituentsof A) drugs. B) foodflavors. C) fossilfuels. D) fruitjuices. E) disinfectants. Answer: C 34) IdentifythefunctionalgroupinthecompoundCH 3 CH2 NH2 . A) amide B) quaternaryamine C) tertiaryamine D) secondaryamine E) primaryamine Answer: E 35) IdentifythefunctionalgroupinthecompoundCH 3 CH2 CHO. A) amide B) ketone C) ester D) secondaryamine E) aldehyde Answer: E 36) IdentifythefunctionalgroupinthecompoundCH 3 CH2 NHCH3 . A) amide B) quaternaryamine C) tertiaryamine D) secondaryamine E) primaryamine Answer: D

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37) IdentifythefunctionalgroupinthecompoundCH 3 CH2 N(CH3 )2 . A) amide B) alcohol C) amine D) ether E) ketone Answer: C 38) Onereasonfortheverylargenumberoforganiccompounds(comparedtothetotalnumberofinorganic compounds)is A) functionalgroups. B) constitutionalisomerism. C) hydrogenbonding. D) theoccurrenceoforganiccompoundsinlivingthings. E) theelectronegativityofcarbon. Answer: B 39) Inamoleculewithasymmetricalarrangementofpolarbonds,theoverallmoleculeis A) highlypolar. B) somewhatpolar. C) nonpolar. D) reversepolar. E) stronglyreversepolar. Answer: C 40) Organiccompoundsthatarepoorlysolubleinwaterbehavethatwaybecausetheyare A) highlypolar. B) moderatelypolar. C) covalentlybonded. D) generallynonpolar. E) ionicallybonded. Answer: D 41) Generally,asolutionofanorganiccompoundinwaterwillbeelectrically A) highlyconductive. B) highlyionized. C) nonconductive. D) insulated. E) charged. Answer: C 42) WhichofthefollowingisNOTarepresentationforacarboxylicacidfunctionalgroup? A) CHO B) COOH C) CO 2 H D) C(=O)OH E) O || -C-OH Answer: A

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43) Inanaminefunctionalgroup,thecentralatomis A) carbon. B) hydrogen. C) oxygen. D) nitrogen. E) sulfur. Answer: D 44) Athiolisafunctionalgroupcontaining A) carbon. B) chlorine. C) oxygen. D) nitrogen. E) sulfur. Answer: E 45) Intheequationforthecombustionofpentane,thecoefficientofcarbondioxideis A) one B) two. C) three. D) four. E) five. Answer: E 46) TheIUPACnameforCH3 -Clis A) methylchloride B) chloromethane. C) methanechlorine. D) chloroethane. E) methanechloride. Answer: B 47) Themajorproductformedwhenbrominereactswithpropaneis A) 1-bromopropane. B) 2-bromopropane. C) 3-bromopropane. D) propylbromide. E) bromopropane. Answer: B 48) WhatistheIUPACnamefor CH3 CH3 -CH2 -CH2 -CH- CH2 -CH3

A) 4-methylhexane. B) 3-methylhexane. C) heptane. D) methylhexane. E) 2-methylhexane. Answer: B

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49) WhatistheIUPACnamefor

CH3

CH2 -CH2 -CH2 -CH3 A) 1-methylbutane. B) 4-methylbutane. C) pentane. D) butane. E) hexane. Answer: C 50) WhatistheIUPACnameforCl-CH2 -CH2 -CH2 -Cl A) 1,3-dichloropropane. B) 1,1-dichloropropane. C) dichloropropane. D) 1,3-dichlorobutane. E) propanedichloride. Answer: A

11.2 True/FalseQuestions
1) Organicchemistryisthestudyofthechemistryofcarboncompounds. Answer: TRUE 2) Nylon,polyester,andmostotherplasticsarecarboncompounds. Answer: TRUE 3) Lipidsarenotorganiccompounds. Answer: FALSE 4) Therearemillionsoforganiccompounds. Answer: TRUE 5) Carbonhassixvalenceelectrons. Answer: FALSE 6) Methanehasatetrahedralstructure. Answer: TRUE 7) Thebondanglesinatetrahedralmoleculeare90. Answer: FALSE 8) Thedifferenceinelectronegativitybetweentwoatomsinamoleculedeterminesthebondpolarity. Answer: TRUE 9) Organiccompoundsarealwayshighlywatersoluble. Answer: FALSE 10) Mostorganiccompoundsareflammable. Answer: TRUE 11) Aminescontaincarbon,hydrogen,andoxygen. Answer: FALSE

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12) Pentanecontainssixcarbonatoms. Answer: FALSE 13) Isomershavethesamemolecularformula. Answer: TRUE 14) Halogenationoccurswhenahalogenatomreplaceshydrogeninanalkane. Answer: TRUE 15) Theproductsofcombustionarecarbondioxideandwater. Answer: TRUE 16) Aminescontainthefunctionalgroup-OH. Answer: FALSE 17) Organicliquidsareoftenlighterthanwater. Answer: TRUE 18) Mostprescriptiondrugsareorganicmolecules. Answer: TRUE 19) Functionalgroupsaregroupsofatomsthatactinpredictableways. Answer: TRUE 20) Functionalgroupsalwayscontainatomsotherthanjustcarbonandhydrogen. Answer: FALSE

11.3 MatchingQuestions
Identifythefollowingasmorecharacteristicofanorganiccompoundoraninorganiccompound. 1) Column1: highmeltingpoint Column2: inorganic Answer: inorganic 2) Column1: flammable Column2: organic Answer: organic 3) Column1: covalentbonds Column2: organic Answer: organic 4) Column1: insolubleinwater Column2: organic Answer: organic 5) Column1: ionicbonds Column2: inorganic Answer: inorganic

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Matchthefollowingorganicstructureswiththeappropriatefamilyname. 6) Column1: CH3 CH2 CH=CH2 Column2: alkene Answer: alkene 7) Column1: O CH3 - C -CH3

Column2: ketone Answer: ketone 8) Column1: CH3 OH Column2: alcohol Answer: alcohol 9) Column1: O CH3 CH2 C OH

Column2: carboxylicacid Answer: carboxylicacid 10) Column1: CH3 CH2 OCH2 CH3 Column2: ether Answer: ether 11) Column1: O CH3 C OCH2 CH3

Column2: ester Answer: ester 12) Column1: CH3 CH2 SH Column2: thiol Answer: thiol 13) Column1: O CH3 CH2 C H

Column2: aldehyde Answer: aldehyde 14) Column1: HCCCH3 Column2: alkyne Answer: alkyne Page143

15) Column1: CH3 CH2 NH2 Column2: amine Answer: amine 16) Column1: O CH3 CH2 C NH2

Column2: amide Answer: amide 17) Column1: Br CH3 C HCH3

Column2: haloalkane Answer: haloalkane

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Chapter12 UnsaturatedHydrocarbons 12.1 Multiple-ChoiceQuestions

1) Ahydrocarbonwithadoublebondisa(n) A) alkane. B) alkene. C) alkyne. D) alcohol. E) saturatedcompound. Answer: B 2) Whichofthefollowingpairsofcompoundsarestructuralisomers? A) Cl Cl CH3 C HCH2 CH3 andCH3 CH2 C HCH3

B) ClCH2 CH2 CH2 CH3 andCH3 CH2 CH2 CH2 Cl C) CH3 CHCH3 andCH3 CHCH2 Cl C H3 C H2 Cl D) Cl CH3 CHCH3 andCH3 C CH3 C H2 Cl C H3 E) and

Answer: D 3) HowmanyisomersarethereforC2 H4 Cl2 ? A) none B) one C) two D) three E) four Answer: C 4) Howmanyisomersaretherefordibromobenzene? A) one B) two C) three D) four E) five Answer: C

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5) Alkenesandalkynesarecalledunsaturatedcompoundsbecause A) theyhavethemaximumnumberofhydrogenatomsattachedtoeachcarboninthecompound. B) theyhavefewerhydrogenatomsattachedtothecarbonchainthanalkanes. C) theyhavemorehydrogenatomsattachedtothecarbonchainthanalkanes. D) theyhavemorecarbonatomsthanalkanes. E) theyhavefewercarbonatomsthanalkanes. Answer: B 6) Whichofthecompoundsisacycloalkene? A) CH2 =CHCH=CH2 B)

C) CH3 C=CH2 D)

E)

Answer: D 7) Anunsaturatedcompoundalways A) isacycloalkane. B) containsadoublebond. C) containsatriplebond. D) containsatleastonedoubleortriplebond. E) isaromatic. Answer: D 8) Whichofthefollowingcompoundsisanalkyne? A) CH3 CH2 CH3 B) C3 H6 C) CH3 CH2 CCH D) H2 C=CHCH=CH2 E) 2-pentene Answer: C 9) Organiccompoundswithdoubleortriplebondsareclassifiedas A) unsaturatedcompounds. B) saturatedcompounds. C) dilutesolutions. D) concentratedsolutions. E) substitutedcompounds. Answer: A

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10) TheIUPACnameofCH3 CH=CHCH3 is A) 2-butene. B) 2-butane. C) 1-butene. D) butene. E) 2-butyne. Answer: A 11) Whennaminganalkene,theparentchainisthelongestcarbonchain A) thatdoesnotcontainthedoublebond. B) regardlessofwhetherornotitcontainsthedoublebond. C) thatcontainsatleastoneofthecarbonatomsofthedoublebond. D) thatcontainsbothatomsofthedoublebond. E) thatcontainsabranch. Answer: D 12) TheIUPACnameforCH3 CH2 CCCH3 is A) 3-pentyne. B) 2-pentyne. C) pentyne. D) 1-methylbutyne. E) 2-propene. Answer: B 13) TheIUPACnameforethyleneis A) ethane. B) cycloethane. C) ethyne. D) ethanene. E) ethene. Answer: E 14) Whichoneofthefollowingcompoundshasthesmallestnumberofhydrogenatoms? A) butyne B) 2-methylpropane C) butene D) 2-methylcyclopropane E) butane Answer: A

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15) WhatistheIUPACnameforthefollowingcompound? CH3 Cl CH3 - C H- C -CH=CH C H3 C H3

A) 4-chloro-4,5-dimethyl-2-hexene B) 3-chloro-1,3,4-trimethyl-1-pentene C) 3-chloro-2,3-dimethyl-4-hexene D) 3-chloro-2,3,5-trimethyl-4-pentene E) 3-chloro-1,3,4,4-tetramethyl-1-butene Answer: A 16) Whatisthecondensedstructuralformulaofthecompoundpropene? A) CH3 CH2 CH3 B) H3 C=CH2 CH3 C) H2 C=C=CH2 D) CH3 CH=CH2 E) HCCCH3 Answer: D 17) Whatisthecondensedstructuralformulaforthecompound3 -hexene? A) CH3 CH3 CH2 C HCH2 CH3 B) CH2 =CHCH2 CH2 CH2 CH3 C) CH3 CH2 CH=CHCH2 CH3 D) CH3 CH2 CH2 CH=CHCH3 E) CH3 CH=CHCH2 CH2 CH3 Answer: C 18) Thecompound1-butynecontains A) allsinglebonds. B) adoublebond. C) atriplebond. D) aringstructure. E) abromineatom. Answer: C

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19) WhichofthefollowingistheIUPACnameforthecompoundbelow?

A) m-bromotoluene B) m-bromomethylcyclohexene C) 1-bromo-3-methylcyclohexene D) 3-bromo-1-methyl-2-cyclohexene E) 2-bromo-6-methylcyclohexene Answer: C 20) Whichofthefollowingisthecorrectstructuralformulafor3-methylcyclohexene? A)

B)

C)

D)

E)

Answer: A

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21) Somealkeneshavecis-transisomersbecause A) thecarbonatomsinthedoublebondcannotrotate. B) eachofthecarbonatomsinthedoublebondhasfourdifferentgroupsattachedtoit. C) oneofthecarbonatomsinthedoublebondhastwoidenticalgroupsattachedtoit. D) thecarbonatomsinthedoublebondarefreetorotate. E) allofthecarbonatomsinthecompoundarerigidandcannotrotate. Answer: A 22) Whichofthefollowingpairsofcompoundsarecis-transisomers? A) and

B) and

C) HCC-CH3 andCH3 -CCH D) and

E) and

Answer: E 23) Whatisthenameofthecompoundshownbelow?

A) 2-pentene B) trans-2-pentene C) trans-3-pentene D) cis-2-pentene E) cis-3-pentene Answer: B 24) Thereactionofhydrogen(H2 )andpropeneusingaplatinumcatalystiscalled A) combustion. B) substitution. C) addition. D) neutralization. E) condensation. Answer: C

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25) Thehydrogenationofanalkenegivesa(n) A) alkane. B) alkene. C) alkyne. D) benzene. E) isomer. Answer: A

26) Whatisthecondensedstructuralformulafortheproductofthehydrogenationof2-buteneusingaplatinum catalyst? A) CH3 CH=CHCH3 Cl CH3 CH2 C HCH3 C) CH3 CH2 CH2 CH3 D) CH3 CH3 C HCH3 E) OH CH3 C HCH3 B)

Answer: C 27) Whatistheproductofthisreaction? CH3 CH2 CH=CHCH3 +Cl2 ? A) CH3 CH2 CH2 CH2 CH3 Cl CH3 CH2 CH2 C CH3 Cl C) Cl Cl CH3 CH2 C H C HCH3 D) Cl CH3 CH2 C CH2 CH3 Cl E) Cl CH3 C CH2 CH2 CH3 Cl Answer: C B)

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28) ThereactionofcyclohexeneandCl2 yields A) 1-chlorocyclohexene. B) 1,2-dichlorocyclohexane. C) 1,3-dichlorocyclohexane. D) 2,3-dichlorocyclohexane. E) 3,4-dichlorocyclohexane. Answer: B 29) ThereactionofpropeneandBr2 yields A) 1-bromopropane. B) 2-bromopropane. C) 1,1-dibromopropane. D) 1,2-dibromopropane. E) 2,2-dibromopropane. Answer: D 30) Thechemicalreactionof2-buteneandHClyieldswhatproduct? A) CH3 CH2 CH2 CH3 B) Cl CH3 CH2 C HCH3

C)

Cl Cl CH3 - C H- C H-CH3 D) CH3 CH3 C HCH3 E) Cl CH3 C CH2 CH3 C H3

Answer: B 31) AccordingtoMarkovnikovsrule,thehydrogeninHCladdstothecarboninthedoublebond A) attachedtotheendcarbon. B) thathasthesmallernumberofhydrogenatomsattached. C) thathasthegreaternumberofhydrogenatomsattached. D) thathasthesmallernumberofcarbonatomsattached. E) thathasthegreaternumberofcarbonatomsattached. Answer: C 32) Themajorproductofthereactionof3-methyl-2-pentenewithHClis A) 4-chloro-3-methylpentane. B) 1-chloro-3-methylpentane. C) 2-chloro-3-methylpentane. D) 3-chloro-3-methylpentane. E) 3-chloro-3-methylpentene. Answer: D

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33) Thereactantsneededtoproducethecompoundchlorocyclopentaneare A) penteneandHCl. B) penteneandCl2 . C) cyclopentaneandCl2 . D) cyclopenteneandHCl. E) cyclopenteneandCl2 . Answer: D 34) Whichsetofreactantswouldgivethiscompound? Cl CH3 -CH2 - C H-CH2 Cl A) CH3 CH2 CH2 CH3 +2HCl B) CH3 CH=CHCH3 +2HCl C) CH3 CH2 CH=CH2 +2HCl D) CH3 CH=CHCH3 +Cl2 E) CH3 CH2 CH=CH2 +Cl2 Answer: E 35) Thereactionofanalkeneandwaterinthepresenceofanacidcatalysttoproduceanalcoholiscalled A) hydrolysis. B) alkoholysis. C) halogenation. D) hydration. E) hydrohydration. Answer: D 36) Whatisthemajorproductofthereactionshownbelow? CH3 -CH2 -CH=CH2 +HOH A) OH OH CH3 -CH2 - C H- C H2 B) OH CH3 -CH2 - C H-CH3 C) CH3 -CH2 -CH2 -CH2 OH D) OH OH CH3 - C H- C H-CH3 E) OH CH3 -CH2 - C =CH2

Answer: B

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37) Long-chainmoleculesthatconsistofmanyrepeatingunitsarecalled A) polymers. B) monomers. C) organiccompounds. D) alkenes. E) alkanes. Answer: A 38) Smallmoleculesthatmakeuptherepeatunitinpolymersarecalled A) monomers. B) alkenes. C) alkynes. D) minipolymers. E) syntheticpolymers. Answer: A 39) Thesyntheticpolymerpolyethyleneisunreactivebecauseitis A) unsaturated. B) ahaloalkane. C) saturated. D) acycloalkene. E) anaromaticcompound. Answer: C 40) WhatisthestartingmonomerforthepolymerTeflon ? F -C F A) F C F F C F F C F

F F- C -F F B) F H- C -H F C) F F F- C - C -F F F D) CF E) F F F- C = C -F Answer: E

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41) Whichofthefollowingisanaturallyoccurringpolymer(notasyntheticpolymer)? A) polypropylene B) DNA C) teflon D) polystyrene E) saran Answer: B 42) Whichofthefollowingwouldresultfromthepolymerizationofethene? A) CH CH 3 3 - C - CH - C - CH 2 2 C H3 C H3 B) CH3 CH3 CH3 CH3 - C - C - C - C H H H H C) H H H H -C=C-C=CD) =C=C=C=C= E) -CH2 -CH2 -CH2 -CH2 Answer: E 43) Thestructuralformulaofbenzeneisoftenrepresentedasa A) ringoffivecarbonatoms. B) ringofsixcarbonatomswithsixdoublebonds. C) ringofsixcarbonatomswithacircleinthecenter. D) cycloalkane. E) cycloalkyne. Answer: C 44) Thecompoundbelowisnamed

A) cyclohexane. B) cyclohexene. C) cyclohexyne. D) benzene. E) cyclobenzene. Answer: D

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45) Whatisthemolecularformulaofbenzene? A) C6 H4 B) C6 H6 C) C6 H8 D) C6 H10 E) C6 H12 Answer: B 46) Whatisthenameofthecompoundbelow?

A) p-chlorotoluene B) o-chlorotoluene C) m-chlorotoluene D) 1-chloro-2-methyltoluene E) 2-chloro-1-methyltoluene Answer: B 47) Thenameofthecompoundshownbelowis

A) o-ethylmethylcyclohexane. B) m-ethylmethylcyclohexane. C) o-ethyltoluene. D) m-ethyltoluene. E) p-ethyltoluene. Answer: D 48) Whenchlorineatomsareattachedtocarbon1andcarbon3inbenzene,thecompoundisnamed A) dichlorobenzene. B) o-dichlorobenzene. C) m-dichlorobenzene. D) p-dichlorobenzene. E) j-dichlorobenzene. Answer: C

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49) Whenbromineatomsareattachedtocarbon1andcarbon4inbenzene,thecompoundisnamed A) dibromobenzene. B) o-dibromobenzene. C) m-dibromobenzene. D) p-dibromobenzene. E) f-dibromobenzene. Answer: D 50) Theodorsyouassociatewithlemons,oranges,roses,andlavenderaredueto A) alkenes. B) alkanes. C) alkynes. D) thiols. E) amines. Answer: A 51) Allofthecarbon-carbonbondsinbenzeneare A) composedofonlytwotypes,singleanddouble. B) identical. C) doublebonds. D) singlebonds. E) circularbonds. Answer: B 52) Whataretheprefixesusedtodesignatesubstituentpositionsondisubstitutedbenzenecompounds? A) ortho-,meta-,andpara-. B) cis-andtransC) syn-andantiD) Alloftheabove. E) Noneoftheabove. Answer: A 53) Whichofthefollowingis(are)substitutionreaction(s)onaromaticrings? A) halogenation B) nitration C) sulfonation D) Alloftheabove. E) Noneoftheabove. Answer: D

12.2 True/FalseQuestions
1) Light-inducedcis-transisomerizationisanimportantstepinvision. Answer: TRUE 2) Propyleneisusedtoinduceripeninginfruits. Answer: FALSE 3) Fragrancesandflavorsareoftencompoundswithmorethanonefunctionalgroup(forexample,analkenethat alsocontainsanaldehyde). Answer: TRUE 4) Inacisalkene,thegroupsareonthesamesideofthedoublebond. Answer: TRUE

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5) Inatransalkene,thegroupsareonthesamesideofthedoublebond. Answer: FALSE 6) Allalkenesshowcis-transisomerism. Answer: FALSE 7) Hydrogenationisusedtoconvertalkenesandalkynestoalkanes. Answer: TRUE 8) Hydrogenationofunsaturatedvegetableoilsraisesthemeltingpointandmakesthemmoresolid. Answer: TRUE 9) Halogenationistheprocessofaddingchlorineorsimilarelementstoanalkeneoralkyne. Answer: TRUE 10) Markovnikovsrulestatesthatwhenahydrogenhalideaddstoadoublebond,theprotonwillbondtothe carbonthathasthegreaternumberofhydrogenatoms. Answer: TRUE 11) Watercanbeaddedtoalkenestoproduceacids. Answer: FALSE 12) Polymersarelargemoleculesconsistingofrepeatingunits. Answer: TRUE 13) Mostproductsmadefrompolymerscanberecycled. Answer: TRUE 14) Oneessentialbuildingblockofaspirin,ibuprofen,andacetaminophenisthebenzenering. Answer: TRUE 15) ThesubstituentgroupC6 H5 CH2 -iscalledaphenylgroup. Answer: FALSE 16) Allpolycyclicaromaticcompoundscausecancer. Answer: FALSE 17) Themostimportantgeneraltypeofreactionforaromaticcompoundsissubstitution. Answer: TRUE

12.3 MatchingQuestions
Matchthefollowingorganicstructureswiththeappropriatefamilyname. 1) Column1:

Column2: aromaticcompound Answer: aromaticcompound

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2) Column1: CH3 CH2 CH2 CH3 Column2: alkane Answer: alkane 3) Column1:

Column2: cycloalkane Foil: alkane Answer: cycloalkane 4) Column1:

Column2: cycloalkene Foil: alkene aromatic Answer: cycloalkene Matcheachofthefollowingreactionswithitsproduct.Assumeanynecessarycatalystsarepresent. 5) Column1: CH3 CH3 C=CH2 +H2 Column2: CH3 CH3 C HCH3 catalyst

Foil: CH3 CH2 CH2 CH3 Answer: CH3 CH3 C HCH3

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6) Column1:

CH3 CH3 C =CH2 +Cl2 CH3 CH3 C CH2 Cl | Cl CH3 CH3 C HCHCl2

Column2:

Foil:

Answer:

CH3 CH3 C CH2 Cl | Cl CH3 CH3 C =CH2 +H2 O CH3 CH3 C CH3 OH CH3 CH3 C HCH2 OH

7) Column1:

Column2:

Foil:

Answer:

CH3 CH3 C CH3 OH

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8) Column1:

CH3 CH3 C =CH2 +HBr CH3 CH3 C CH3 | Br CH3 CH3 C HCH2 Br

Column2:

Foil:

Answer:

CH3 CH3 C CH3 | Br

9) Column1:

+HCl Column2:

Foil:

Answer:

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10) Column1: +H2 O Column2: acid

Foil:

Answer:

11) Column1:

Column2:

Foil:

Answer:

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ChoosethetypeofcompoundfromColumn2thatbestmatcheseachiteminColumn1. 12) Column1: CH3 -CH=CH-CH3 Column2: alkene Answer: alkene 13) Column1: CH4 Column2: alkane Answer: alkane 14) Column1:

Column2: cycloalkane Answer: cycloalkane 15) Column1: CH3 CH2 Cl Column2: haloalkane Answer: haloalkane 16) Column1:

Column2: cycloalkene Answer: cycloalkene 17) Column1: CH3 CH2 CH3 Column2: alkane Answer: alkane

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Selectthecorrectnameforeachfigure. 18) Column1:

Column2: p-chlorotoluene Foil: 1-chloro-3methylcyclohexane Answer: p-chlorotoluene 19) Column1:

Column2: ethylbenzene Foil: toluene Answer: ethylbenzene

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Chapter13 Alcohols,Phenols,Ethers,andThiols 13.1 Multiple-ChoiceQuestions

1) Whichoneofthefollowingcompoundsisanalcohol? A) OH | CH3 -CH-CH3 O CH3 CH2 C H C) CH3 CH=CHCH2 CH3 D) CH3 CH2 OCH2 CH3 E) CH3 SH Answer: A 2) ThecompoundCH3 CH2 -SHisintheorganicfamilyknownas A) ethers. B) thiols. C) alcohols. D) sulfides. E) aminoacids. Answer: B 3) WhatistheIUPACnameforthiscompound? B)

A) methylcyclobutanol B) o-methylcyclobutanol C) 2-hydroxy-1,1-dimethylcyclobutane D) 2-dimethyl-1-cyclobutanol E) 2,2-dimethylcyclobutanol Answer: E

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4) WhichofthefollowingistheIUPACnameforthecompoundbelow?

A) 1,1,4-trimethyl-6-cyclohexanol B) 1,1,4-trimethyl-2-cyclohexanol C) 2,2,5-trimethylcyclohexanol D) 2,2,5-trimethylphenol E) 2-ethyl-5-methylcyclohexanol Answer: C 5) Thecondensedstructuralformulafor2,3-dichloro-4-methylcyclohexanolis A)

B)

C)

D)

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E)

Answer: D 6) WhatistheIUPACnameofthiscompound? OH CH3 - C -CH3 C H3 A) butanol B) propanol C) 2-propanol D) 2-methylbutanol E) 2-methyl-2-propanol Answer: E 7) Whichofthefollowingcompoundsisaweakacid? A) ethanol B) ethanal C) phenol D) cyclohexanol E) acetone Answer: C 8) Whatisthenameforthiscompound?

A) o-bromo-m-ethylphenol B) 2-bromo-5-ethylphenol C) 4-bromo-1-ethyl-5-phenol D) 6-bromo-3-ethylphenol E) 2-bromo-5-methylphenol Answer: B

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9) Thealcoholinthislistthatwouldbemostsolubleinwateris A) ethanol. B) 1-butanol. C) 1-pentanol. D) 1-hexanol. E) 1-heptanol. Answer: A 10) Whatisthenameforthiscompound?

A) cyclopentanol B) cyclohexanol C) cyclobenzenol D) phenol E) glycerol Answer: D 11) Whatisthenameofthiscompound?

A) cyclopentylpropylether B) cyclopentylpropylketone C) 1-cyclopropyl-1-propylalcohol D) propylcyclopentanol E) 3-cyclopentylpropanol Answer: A 12) ThecommonnameforthecompoundCH3 CH2 CH2 - O - CH2 CH3 is A) 3-pentanol. B) ethylpropylether. C) 3-hexanol. D) 3-etherpentane. E) ethylpropylketone. Answer: B 13) ThecommonnameofCH3 CH2 -O-CH2 CH3 is A) dimethylether. B) diethylether. C) 2-etherbutane. D) butylether. E) dibutylether. Answer: B

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14) Whyhasdiethyletherbeenreplacedasageneralanesthetic? A) Itcausesunpleasantsideeffectsinmanypatients. B) Itisslightlypolar. C) Itcanhydrogenbondtowater. D) Itisnotveryreactive. E) Itisslightlysolubleinwater. Answer: A 15) Thedehydrationofanalcoholinthepresenceofastrongacidyields A) analkane. B) analkene. C) aketone. D) analcohol. E) analdehyde. Answer: B 16) ThedehydrationproductofCH3 CH2 CH2 OHinthepresenceofacidis A) CH2 =C=CH2 . B) cyclopropane. C) cyclopropene. D) propene. E) propyne. Answer: D 17) When2-methyl-2-butanolundergoesdehydrationinacid,oneproductis A) 2-methyl-2-butene. B) 2-methylbutanone. C) 2-pentanone. D) 2-methylbutanal. E) hexene. Answer: A

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18) Whatisthestructuralformulaoftheetherformedinthisreaction? CH3 2CH3 C HOH H+ A) CH3 CH3 CH2 CH2 O C HCH3 CH3 CH3 C -O-CH3 H

B)

C) CH3 CH2 CH2 OCH2 CH2 CH3 D) CH3 CH3 CH3 C -O- C CH3 H H

E) CH3 CH2 OCH2 CH3 Answer: D 19) Intheoxidationofanalcoholtoaketone,thereis A) alossofhydrogen. B) alossofoxygen. C) alossofcarbon. D) againofhydrogen. E) againofoxygen. Answer: A

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20) Whichofthefollowingcompoundsisasecondaryalcohol? A) CH3 -CH-O-CH3 C H3 B) CH3 OH C) OH CH3 CH2 C CH3 C H3 CH3 CH3 C CH3 OH

D)

E) CH3 -CH-OH C H3 Answer: E 21) Inatertiaryalcohol,howmanyalkylgroupsareattachedtothecarbonatombondedtothe -OHgroup? A) none B) one C) two D) three E) four Answer: D 22) Whatistheproductwhenthiscompoundundergoesgentleoxidation? CH3 CH3 - C -CH2 -CH2 -OH C H3 A) hexanal B) 2,2-dimethylbutanal C) 2,2-dimethyl-4-butanone D) 3,3-dimethyl-1-butanone E) 3,3-dimethylbutanal Answer: E

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23) Whatclassificationofalcoholundergoesoxidationtoyieldaketone? A) primaryalcohol B) bothprimaryandsecondaryalcohols C) secondaryalcohol D) allclassesofalcohols E) bothsecondaryandtertiaryalcohols Answer: C 24) Tertiaryalcoholscannotbeoxidizedbecause A) therearenooxygenatomstoremovefromthealcoholcarbon. B) therearenohydrogenatomsattachedtothealcoholcarbon. C) thealcoholcarbonisbondedtofourgroupssonooxygencanbeaddedtoit. D) thealcoholcarbonisbondedtofourgroupssonohydrogencanbeaddedtoit. E) thealcoholcarbonistooelectronegativetohavehydrogenremovedfromit. Answer: B 25) Whatclassificationofalcoholisresistanttooxidation? A) primary B) secondary C) tertiary D) quaternary E) none Answer: C 26) Whatistheproductwhenthefollowingcompoundisoxidized? OH CH3 CH2 C HCH2 CH3 A) diethylketone B) 2-pentene C) pentanal D) diethylether E) pentane Answer: A 27) Whichcompoundwillundergooxidationtoyieldcyclopentanone? A) pentanol B) cyclopentane C) cyclopentanol D) methylcyclobutanol E) cyclopentene Answer: C 28) Alcoholscontainwhichfunctionalgroup? A) amine B) amide C) hydroxyl D) thiol Answer: C

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29) Aprimaryalcoholhasahydroxylgroupbondedtoa(n) A) singlysubstitutedorunsubstitutedcarbon. B) disubstitutedcarbon. C) trisubstitutedcarbon. D) aromaticcarbon. Answer: A 30) Asecondaryalcoholhasahydroxylgroupbondedtoa(n) A) singlysubstitutedorunsubstitutedcarbon. B) disubstitutedcarbon. C) trisubstitutedcarbon. D) aromaticcarbon. Answer: B 31) Atertiaryalcoholhasahydroxylgroupbondedtoa(n) A) singlysubstitutedorunsubstitutedcarbon. B) disubstitutedcarbon. C) trisubstitutedcarbon. D) triple-bondedcarbon. E) doublebondedcarbon. Answer: C 32) Aphenolhasan-OHgroupbondedtoa(n) A) singlysubstitutedorunsubstitutedcarbon. B) disubstitutedcarbon. C) trisubstitutedcarbon. D) aromaticcarbon. E) tetrasubstitutedcarbon. Answer: D 33) WhatistheIUPACnameofthiscompound?

A) pyran B) tetrahydropyran C) tetrahydrofuran D) furan E) oxycyclopentane Answer: C 34) Thiolshavestructuressimilartoalcoholsexceptthattheycontain A) threealcoholgroups. B) morethanonecarbon. C) sulfurinplaceofoxygeninthefunctionalgroup. D) lithiuminplaceofoxygeninthefunctionalgroup. E) nitrogeninplaceofoxygeninthefunctionalgroup. Answer: C

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35) Whentwomoleculesofmethanolareheatedwithacid,whatistheproduct? A) CH3 -OH B) CH3 -O- CH3 C) CH2 =CH2 D) CH2 E) CH3 -CH2 -OH Answer: B 36) Methanolisusedinallthefollowingexcept A) makingplastics. B) racingfuel. C) alcoholicbeverages. D) solvents. E) paintremover. Answer: C 37) 1,2-ethanediol(ethylenediol)hasusesthatinclude A) antifreeze. B) solventforpaint. C) productionofsyntheticfibers. D) solventforink. E) Alloftheabove. Answer: E 38) Inthedehydrationofanalcoholtoanalkene,whatisproducedinadditiontothealkene? A) water B) hydrogen C) oxygen D) carbondioxide E) carbonmonoxide Answer: A 39) Etherscanbeformedfromthereactionof A) waterandanalkene. B) waterandanalcohol. C) twoalkenes. D) twoalcohols. E) aketoneandanalkene. Answer: D 40) Whenaprimaryalcoholiscompletelyoxidized,theproductis A) anotheralcohol. B) acarboxylicacid. C) analdehyde. D) analkane. E) aketone. Answer: B

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41) Ethyleneglycolandmethanolaretoxicbecausetheyare________bythelivertocarboxylicacids. A) reduced B) protonated C) oxidized D) conjugated E) hydrated Answer: C 42) Secondaryalcoholsareoxidizedto A) carboxylicacids. B) ketones. C) aldehydes. D) esters. E) ethers. Answer: B 43) Tertiaryalcoholsareoxidizedto A) secondaryalcohols. B) ketones. C) aldehydes. D) carboxylicacids. E) Noneoftheabove. Answer: E 44) Thiolscanbegentlyoxidizedto A) disulfides. B) aldehydes. C) ketones. D) carboxylicacids. E) thioethers. Answer: A 45) Thedehydrationproductof OH in the presence of acid is CH3 -CH-CH3

A) CH2 =C=CH2 . B) cyclopropane. C) cyclopropene. D) propene. E) propyne. Answer: D 46) Thiolsarestrong-smellingcompoundsresponsiblefor A) fruityodors. B) sharpodors. C) floweryodors. D) skunkyorbadsmellingodors. E) saltyodors. Answer: D

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47) Whichfunctionalgroupbelowcontainsthemosthighlyoxidizedcarbon? A) alkane B) alcohol C) aldehyde D) ketone E) carboxylicacid Answer: E 48) Whatkindofbondsdoalcoholsformbetweenindividualmolecules? A) oxygenbonds B) hydrogenbonds C) singlebonds D) carbonbonds E) ionicbonds Answer: B 49) WhatistheIUPACnameforCH3 -CH2 -CH2 -SH A) 1-propanethiol B) 2-propanethiol C) 1-butanethiol D) 2-butanethiol E) propylthiol Answer: A 50) Whichoneofthefollowingcompoundsisathiol? A) OH | CH3 -CH-CH3 B) O CH3 CH2 C H

C) CH3 CH=CHCH2 CH3 D) CH3 CH2 OCH2 CH3 E) CH3 SH Answer: E

13.2 True/FalseQuestions
1) Alcohols,ethers,andphenolscontainoxygenwithonlysinglebonds. Answer: TRUE 2) Alcoholscanformhydrogenbonds. Answer: TRUE 3) Asecondaryalcoholcanbeeasilyoxidizedtoacarboxylicacid. Answer: FALSE 4) Cycloalkanolsarestraightchainalcohols. Answer: FALSE Page176

5) Thiolsusuallyhavesweetodors. Answer: FALSE 6) Methanol,2-propanol,andethyleneglycolarealltoxicwheningested. Answer: TRUE 7) 1,2,3-propanetriolisobtainedduringthemanufactureofsoap. Answer: TRUE 8) Glycerinstronglyattractsandholdswater,apropertythatmakesitusefulasaskinsoftenerincosmetics. Answer: TRUE 9) Pyranisacyclicether. Answer: TRUE 10) Heptanolisawatersolublealcohol. Answer: FALSE 11) Ethyletherhasbeenreplacedbyhalogenatedanesthetics,whichhavefewersideeffects. Answer: TRUE 12) Etherscanonlybestraightchaincompounds. Answer: FALSE 13) Furanisanaromaticcompoundthatcontainsoxygeninthering. Answer: TRUE 14) Tertiaryalcoholsareeasilyoxidized. Answer: FALSE 15) Alcoholsformhydrogenbonds;thisaccountsfortheirhigherboilingpointswhencomparedtosimilar -sized alkanes. Answer: TRUE 16) Theoxygenatominalcoholsdecreaseswatersolubilityofthemolecule. Answer: FALSE 17) Phenolsbehaveasweakacidsinwater. Answer: TRUE 18) Alcoholscanbedehydratedtoformalkenes. Answer: TRUE 19) Primaryalcoholscanbeoxidizedtoeitheraldehydesorketones. Answer: FALSE 20) Secondaryalcoholscanbeoxidizedtoketones. Answer: TRUE

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13.3 MatchingQuestions
Identifytheproduct,ifany,thatwouldformineachofthefollowingreactions. 1) Column1: CH3 CH2 CH2 OH Column2: O CH3 CH2 C H [O]

Answer:

O CH3 CH2 C H

2) Column1: CH3 CH2 CHOH C H3 Column2: O CH3 CH2 C CH3

[O]

Foil: Answer: O CH3 CH2 C CH3

Matchthestructuralformulawiththecorrectfunctionalgroup. 3) Column1: CH3 CH2 OH Column2: alcohol Answer: alcohol 4) Column1: CH3 CH2 OCH3 Column2: ether Answer: ether 5) Column1: CH3 CH2 SH Column2: thiol Answer: thiol

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Selectthecorrectnameforthefollowing. 6) Column1: CH3 CH2 CH2 SH Column2: propanethiol Foil: propanesulfide Answer: propanethiol 7) Column1: CH3 CH2 OCH2 CH3 Column2: diethylether Answer: diethylether 8) Column1:

Column2: m-ethylphenol Foil: 1-ethyl-3hydroxycyclohexene Answer: m-ethylphenol Classifythealcoholsshownincolumn1asprimary,secondary,ortertiary. 9) Column1: CH3 CH2 OH Column2: primary Answer: primary 10) Column1: CH3 CH3 C CH2 OH C H3

Column2: primary Answer: primary 11) Column1: OH CH3 C HCH3

Column2: secondary Answer: secondary

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12) Column1:

Column2: secondary Answer: secondary 13) Column1: CH3 CH3 C CH2 CH3 OH

Column2: tertiary Answer: tertiary

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Chapter14 Aldehydes,Ketones,andChiralMolecules 14.1 Multiple-ChoiceQuestions

1) Theadditionofhydrogentoanorganiccompoundorthelossofoxygeniscalled A) reduction. B) oxidation. C) dehydration. D) halogenation. E) hydration. Answer: A 2) Thereductionof3-pentanonewithhydrogeninthepresenceofanickelcatalystwillyield A) pentane. B) 2-pentene. C) diethylalcohol. D) 3-pentanol. E) pentanaldehyde. Answer: D 3) Thehydrogenationof2-methylpropanalgivestheproduct A) 1-butanol. B) 2-methylpropanoicacid. C) 2-methyl-3-propanol. D) 2-methyl-1-propanol. E) 2-methyl-2-propanol. Answer: D 4) Theproductofaddingtwomoleculesofanalcoholtoanaldehydeinthepresenceofacidisa(n) A) acetal. B) ether. C) hemiacetal. D) hemiether. E) hydroxylgroup. Answer: A

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5) Whichofthesecompoundsisthehemiacetalthatformswhenethanolreactswithpropanal? A) OH CH3 CH2 C OCH2 CH3 H B) OH CH3 C OCH2 CH3 H OCH2 CH3 CH3 CH2 C OCH2 CH3 H OCH2 CH3 CH3 C OCH3 H OCH2 CH2 CH3 CH3 C OCH2 CH2 CH3 CH2 CH2 CH3

C)

D)

E)

Answer: A

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6) Whatistheacetalformedwhenpropanonereactswithtwomoleculesofmethanol? A) OH CH3 C CH3 C H3 B) OCH3 CH3 C CH3 O CH3 OCH3 CH3 C OCH3 O CH3 CH3 CH3 CH3 C -O- C CH3 H H OH CH3 C CH3 O CH3

C)

D)

E)

Answer: B

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7) Whichofthefollowingcompoundscontainsaketonefunctionalgroup? A) CH3 CH3 C OH C H3 B) O CH3 C H

C) CH3 CH2 OCH2 CH3 D) O CH3 CH2 C CH3

E) CH3 -O-CH C H3 Answer: D 8) Whichofthefollowingketonesisthemostsolubleinwater? A) O CH3 C CH3 B) O CH3 CH C CH3 C H3 O CH3 CH2 C CH3 O CH3 C CH2 CH2 CH3 O CH3 CH2 C CH2 CH3

C)

D)

E)

Answer: A

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9) WhatistheIUPACnameforthiscompound? O CH3 C H A) methylaldehyde B) 1-ethanaldehyde C) 1-ethanone D) ethanal E) methanal Answer: D 10) WhatistheIUPACnameforthiscompound?

A) methylcyclohexanone B) 2,5-dimethylcyclohexanone C) 1,4-dimethyl-2-cyclohexanone D) cyclohexylmethylketone E) 1,4-dimethyl-3-cyclohexanone Answer: B 11) Whatisthenameofthiscompound? O CH3 C CHCH3 C H3 A) 2-pentanone B) methylpropylketone C) 3-methyl-2-butanone D) 2-methyl-3-butanone E) 2-methyl-3-ketonebutane Answer: C

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12) Threefunctionalgroupsfoundinthiscompoundare

A) alcohol,aromatic,andether. B) alcohol,aldehyde,andether. C) alcohol,ether,andketone. D) aldehyde,ether,andcarboxylicacid. E) cycloalkene,alcohol,andcarboxylicacid. Answer: C 13) Whichofthefollowingpairsofcompoundsareisomers? A) CH3 CH2 CH2 OHandCH3 OCH3 B) O O CH3 CH2 C CH3 andCH3 C CH2 CH3 OH CH3 CH2 OCH2 CH3 andCH3 C CH3 C H3 OH CH3 CH2 CHOHandCH3 C HCH2 CH3 C H3 O CH3 CH2 OHandH C CH3

C)

D)

E)

Answer: C 14) Inallaldehydesexceptformaldehyde,howmanyhydrogenatomsisthecarbonylgroupbondedto? A) one B) two C) three D) four Answer: A

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15) Howmanyhydrogenatomsisthecarbonylgroupinaketonebondedto? A) none B) one C) two D) three E) four Answer: A 16) Thecarbonylgroupconsistsof A) acarbon-oxygen-hydrogenstructure. B) acarbon-oxygensinglebond. C) acarbon-oxygendoublebond. D) acarbon-oxygentriplebond. E) acarbon-oxygen-carbonstructure. Answer: C 17) Theoxygenatominacarbonylgroupis________thecarbonatom. A) moreelectronegativethan B) lesselectronegativethan C) identicalinelectronegativityto D) moreelectropositivethan E) moresolublethan Answer: A 18) Howmanylonepairsofelectronsdoestheoxygeninacarbonylgrouphave? A) None,theyreallbonded. B) one C) two D) three E) four Answer: C 19) IntheIUPACnamingsystem,aketoneisnamedbyreplacingthe -einthecorrespondingalkanenamewith A) yne. B) ene. C) al. D) one. E) ol. Answer: D 20) IntheIUPACnamingsystem,analdehydeisnamedbyreplacingthe -eofthenameofthecorresponding alkanewith A) yne. B) ene. C) al. D) one. E) ol. Answer: C

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21) Whatisthenameofthiscompound?

A) 2-methylbutanone B) 3-methyl-2-butanone C) 2-methyl-3-butanone D) 3-methylbutanone E) pentanone Answer: B 22) Formalinis A) anothernameforformaldehyde. B) aplastic. C) anaqueoussolutionofformaldehyde. D) anexcellentsolvent. E) apolymer. Answer: C 23) Acetoneisaketonecommonlyusedasa A) preservative. B) flavoringagent. C) fuel. D) solvent. E) draincleaner. Answer: D 24) Theflavoringagentfoundinvanillais A) analdehyde. B) aketone. C) ahydrocarbon. D) anester. E) athiol. Answer: A 25) Theincreasedboilingpointofketonescomparedtoalkanesandethersofsimilarmassisdueto A) hydrogenbonding. B) dipole-dipoleinteractions. C) abentchainstructure. D) resonance. E) ionicinteractions. Answer: B 26) Low-molecular-weightketonesaresolubleinwater.Whatistheshortestlengthofthecarbonchainwhere insolubilitybecomesimportant? A) one B) two C) four D) five E) eight Answer: D

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27) Anenantiomeris A) astereoisomerthatisnotamirrorimageofanothermolecule. B) astereoisomerthatisamirrorimageofanothermolecule. C) adiastereoisomer. D) astructuralisomer. E) acis-transisomer. Answer: B 28) Whichofthefollowingwouldnotbewatersoluble? A) acetone B) propanal C) 3-heptanone D) formaldehyde E) 2-butanone Answer: C 29) Chiralityoccurswhenstereoisomershavemirrorimagesthatare A) superimposable. B) thesame. C) notsuperimposable. D) notvisibletooneanother. E) identical. Answer: C 30) Howmanydifferentsubstituentsarerequiredonacarbonatomforittobechiral? A) one B) two C) three D) four E) Anynumberfrom1to4;chiraltydoesnotdependonsubstitution. Answer: D 31) Whichmoleculebelowhasstereoisomerswithdifferentbiologicaleffects? A) carvone B) nicotine C) LSD D) epinephrine E) Alloftheabove. Answer: E 32) Chiraldrugsconsistofonlyoneenantiomer.Thebenefitsofusingapureenantiomer,ratherthanamixture, include A) higherpotency(lowertotaldoseofdrug). B) eliminationofsideeffects. C) reducedchancesofdruginteractions. D) Alloftheabove. E) Noneoftheabove. Answer: D

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33) TheTollenstestmaybeusedtodistinguish A) acidsfromamines. B) estersfromacids. C) ketonesfromalcohols. D) aldehydesfromketones. E) alcoholsfromalkenes. Answer: D 34) Benedictstestrequiresanaldehydeandanadjacent A) saturatedcarbon. B) ketone. C) alcohol. D) phenylring. E) acid. Answer: C 35) Aldehydesandketonesmaybereducedto A) acids. B) alkanes. C) ethers. D) alcohols. E) esters. Answer: D 36) Aldehydesandketonescanreactwithwatertoform A) oxides. B) hydrates. C) hemiacetals. D) esters. E) hemiethers. Answer: B 37) Anacetalisformedfromtwomoleculesofanalcoholanda(n) A) aldehyde. B) ether. C) carboxylicacid. D) alkylether. E) ester. Answer: A 38) Howmanymolesofanalcoholareneededtoreactwith1moleofanaldehydetoformahemiacetal? A) 1 B) 1.5 C) 2 D) 3 E) 3.5 Answer: A

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39) Howdosugarsformcyclichemiacetals? A) Twomoleculesofasugarreactwithoneanother. B) Amoleculeofsugarreactswithanaddedalcohol. C) Amoleculeofsugarreactswithitself. D) Amoleculeofsugarreactswithanaddedaldehyde. E) Asugarmoleculedecomposes. Answer: C 40) TheketonewiththeconstitutionalformulaC5 H10Ocanalsobewrittenas A) CH3 CH2 CH2 COCH 3. B) CH3 COCH 2 CH2 CH3. C) CH3 CH2 COCH 2 CH3. D) Alloftheabove. E) Noneoftheabove. Answer: D 41) WhichofthecompoundswouldgiveapositiveTollenstest? A)

B)

C) D) E) Answer: B 42) Whatarethebondanglesinatypicalcarbonylgroup? A) 45 B) 90 C) 109.5 D) 120 E) 135 Answer: D 43) HowmanyisomersdoestheformulaC 3 H6 Ohave? A) two B) three C) five D) seven E) eight Answer: A

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44) Thecompound2-propanoneisalsoknownas A) acetone. B) 2-propanone. C) dimethylketone. D) -propanone. E) propylone. Answer: A 45) Thecommonnamefor2-butanone,areadilyavailablesolvent,is A) methylacetone. B) methylethylketoneorMEK. C) -butanone. D) butylketone. E) butylether. Answer: B 46) Formaldehydeisusedindustriallytomake A) polymers. B) insulatingmaterials. C) carpeting. D) Alloftheabove. E) Noneoftheabove. Answer: D 47) Acetonecanbeproducedbythebodywhenapersonis A) exercising. B) dietingwithhighproteindiets. C) illwithaflu. D) recoveringfromsurgery. E) sleeping. Answer: B 48) Whichcompoundisusedasbutterflavor? A) acetone B) benzaldehyde C) butanedione D) vanillin E) carvone Answer: C 49) Aldehydeshavehigherboilingpointsthanalkanesofsimilarmassbecauseof A) hydrogenbonding. B) dipole-dipoleinteractions. C) ionicbonding. D) covalentbonding. E) oxygenbonding. Answer: B

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50) Achiralcompoundsarethosewhich A) havenohandedness. B) havedifferentmirrorimages. C) arenon-superimposable. D) havethesameformulabutdifferentstructures. E) arearacemicmixture. Answer: A

14.2 True/FalseQuestions
1) Allaldehydeshaveacarbonylcarbonbondedtoatleasttwohydrogens. Answer: FALSE 2) Manyodorsfromsolvents,paintremovers,andperfumesarederivedfromaldehydesorketones. Answer: TRUE 3) Inaketone,thecarbonylgroupisbondedtotwoothercarbonatoms. Answer: TRUE 4) Thecarbonylgroupconsistsofacarbon-oxygensinglebond,andasecondbondtohydrogen. Answer: FALSE 5) Thecarbonylgroupdoesnothaveadipole. Answer: FALSE 6) Thesuffix-oneindicatesanaldehydeintheIUPACsystemofnaming. Answer: FALSE 7) Thesuffix-alindicatesanaldehydeintheIUPACsystemofnaming. Answer: TRUE 8) AcetonewouldgiveapositiveTollenstest. Answer: FALSE 9) Acetoneisathree-carbonaldehyde. Answer: FALSE 10) Acetoneissometimesproducedinpathologicalconditionssuchasdiabetes. Answer: TRUE 11) Formaldehydeisusedinsolutionasagermicideandpreservative. Answer: TRUE 12) Excessiveexposuretoformaldehydecanirritatetheeyesandrespiratorytract. Answer: TRUE 13) Butyraldehydeispartlyresponsiblefortheflavorofbutter. Answer: FALSE 14) Amajorflavorcomponentofvanillaisanaldehyde. Answer: TRUE 15) Thecarbonylgroupgivesaldehydeshigherboilingpointsthanalkanesofsimilarmass. Answer: TRUE

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16) Thecarbonylgroupgivesketoneslowerboilingpointsthanalkanesofsimilarmass. Answer: FALSE 17) Carbonylcompoundshavingfewerthanfourcarbonatomsareverywatersoluble. Answer: TRUE 18) Hexanalwouldbesolubleinwater. Answer: FALSE 19) Enantiomersaremirrorimagesofeachother. Answer: TRUE 20) Achiralcarbonatomcanhavefewerthanfourdifferentgroupsbondedtoit. Answer: FALSE 21) Enantiomersmayhaveverydifferenttastesorsmells. Answer: TRUE 22) Thebiologicalactivityofoneofasetofenantionmersmaybeverydifferentfromthebiologicalactivityofthe otheropticalisomers. Answer: TRUE 23) TheTollenstestisusedtodistinguishbetweenalcoholsandacids. Answer: FALSE 24) Benedictstestisusedtodeterminewhetheran-hydroxyaldehydefunctionalgroupispresent. Answer: TRUE

14.3 MatchingQuestions
Selectthecorrectnameforthefollowing. 1) Column1: O CH3 CH2 C CH2 CH3

Column2: diethylketone Foil: 3-propanone Answer: diethylketone 2) Column1: O CH3 CH2 C H

Column2: propanal Foil: 1-propanone Answer: propanal

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Matchthestructuralformulawiththecorrectfunctionalgroup. 3) Column1: O CH3 CH

Column2: aldehyde Answer: aldehyde 4) Column1: O CH3 C CH2 CH3

Column2: ketone Answer: ketone Identifytheproduct,ifany,thatwouldformineachofthefollowingreactions. 5) Column1: O [O] CH3 C H O CH3 C OH

Column2:

Answer:

O CH3 C OH

6) Column1:

O Ni CH3 C CH3 +H2 OH CH3 C HCH3

Column2:

Foil: CH3 CH2 CH3 Answer: OH CH3 C HCH3

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7) Column1:

O Ni CH3 C H+H2

Column2: CH3 CH2 OH Foil: CH3 CH3 Answer: CH3 CH2 OH

8) Column1:

O CH3 CH2 C CH3 +CH3 OH H+

Column2:

OCH3 CH3 CH2 C CH3 OH

Foil: noreaction Answer: OCH3 CH3 CH2 C CH3 OH

9) Column1:

O CH3 CH2 CH2 C H+CH3 OH OH CH3 CH2 CH2 C OCH3 H

Column2:

Answer:

OH CH3 CH2 CH2 C OCH3 H

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Identifythefamilyforeachofthefollowingcompounds. 10) Column1: CH3 CH2 OCH3 Column2: ether Answer: ether 11) Column1: O CH3 CH2 C H

Column2: aldehyde Answer: aldehyde

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Chapter15 Carbohydrates 15.1 Multiple-ChoiceQuestions

1) Acarbohydratethatgivestwomoleculeswhenitiscompletelyhydrolyzedisknownasa A) monosaccharide. B) disaccharide. C) polysaccharide. D) starch. E) trisaccharide. Answer: B 2) Whichgroupofcarbohydratescannotbehydrolyzedtogivesmallermolecules? A) monosaccharides B) disaccharides C) trisaccharides D) oligosaccharides E) polysaccharides Answer: A 3) Amonosaccharidethatconsistsof5carbonatoms,oneofwhichisinaketonegroup,isclassifiedasa(n) A) aldotetrose. B) aldopentose. C) aldohexose. D) ketotetrose. E) ketopentose. Answer: E 4) Amonosaccharidethatcontains4carbonatoms,oneofwhichisinanaldehydegroup,isclassifiedasa(n) A) aldopentose. B) aldohexose. C) ketopentose. D) aldotetrose. E) ketotetrose. Answer: D 5) Ribulosehasthefollowingstructuralformula.Towhatcarbohydrateclassdoesribulosebelong? CH2 OH C=O H-C-OH H-C-OH CH2 OH A) aldotetrose B) aldopentose C) ketotetrose D) ketopentose E) ketohexose Answer: D

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6) Thereductionofmonosaccharidesproduces A) sugaralcohols. B) disaccharides. C) trisaccharides. D) sugaracids. E) polysaccharides. Answer: A 7) Inthe L-isomerofaFischerprojectionofamonosaccharide,the-OHgroupfurthestfromthecarbonylis written A) ontheleftofthetopchiralcarbon. B) ontherightofthetopchiralcarbon. C) ontheleftofthemiddlechiralcarbon. D) ontheleftofthebottomchiralcarbon. E) ontherightofthebottomchiralcarbon. Answer: D 8) OnedifferencebetweenD-glucoseandL-glucoseis A) theopen-chainformof L-glucosedoesnotexist. B) itisnotpossibletomake L-glucose. C) L-glucosehasa5-memberedring,andD-glucosehasa6-memberedring. D) onlyD-glucoseisfoundindisaccharidesandpolysaccharides. E) L-glucosecannotformaclosedstructure. Answer: D 9) Thesugaralsoknownasdextroseandbloodsugaris A) glucose. B) galactose. C) fructose. D) lactose. E) sucrose. Answer: A 10) Aglycosidicbondbetweentwomonosaccharidescanalsobeclassifiedasa(n) A) doublebond. B) esterbond. C) etherbond. D) achiralbond. E) alcoholbond. Answer: C 11) Inadisaccharide,twomonosaccharidesarejoinedbywhatkindofbond? A) double B) anomeric C) alcohol D) glycosidic E) rotational Answer: D

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12) Whichofthefollowingcontainsa-1,4-glycosidicbond? A) galactose B) lactose C) maltose D) sucrose E) amylose Answer: B 13) WhichsugarisNOTareducingsugar? A) glucose B) fructose C) galactose D) maltose E) sucrose Answer: E Refertothedisaccharidebelowtoanswerthequestion(s)thatfollow.

14) Inthefigureabove,themonosaccharideunitontheleftisa(n) A) aldopentose. B) ketopentose. C) aldohexose. D) aldoheptose. E) ketohexose. Answer: E 15) Inthefigureabove,themonosaccharideunitontherightisa(n) A) aldopentose. B) ketopentose. C) aldohexose. D) aldoheptose. E) ketohexose. Answer: C

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16) Hydrolysisofthedisaccharideabovegivesthemonosaccharides A) fructoseandribose. B) fructoseandgalactose. C) riboseandglucose. D) riboseandgalactose. E) fructoseandlactose. Answer: B 17) Thedisaccharideabovecontainsa(n)________ -glycosidiclinkage. A) -1,4 B) -1,4 C) -2,4 D) -2,4 E) -2,6 Answer: E 18) Maltoseisa A) monosaccharide. B) disaccharide. C) trisaccharide. D) polysaccharide. E) phosphosaccharide. Answer: B 19) Whichofthefollowingcontains-1,6-branches? A) amylose B) glycogen C) cellulose D) sucrose E) maltose Answer: B 20) Celluloseisnotdigestiblebyhumansbecauseitcontainsglucoseunitslinkedby________ -glycosidicbonds. A) -1,2 B) -1,4 C) -1,6 D) -1,2 E) -1,4 Answer: E 21) Amyloseisaformofstarchwhichhas A) only-1,4-bondsbetweenglucoseunits. B) only-1,4-linksbondsglucoseunits. C) both-1,4-and-1,4-bondsbetweenglucoseunits. D) hemiacetallinksjoiningglucoseunits. E) carbon-carbonbondsjoiningglucoseunits. Answer: B

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22) Humanscannotdigestcellulosebecausethey A) lackthenecessaryenzymestodigest -glycosides. B) areallergicto-glycosides. C) arepoisonedby-glycosides. D) haveintestinalflorawhichuseup -glycosides. E) cannotdigestchlorophyll. Answer: A 23) Aspartame andSaccharinaretwoexamplesof A) disaccharides. B) polysaccharides. C) chlorosaccharides. D) alcoholsweeteners. E) noncarbohydratesweeteners. Answer: E 24) Galactosehasthestructureshownbelow.Itcanbeclassifiedasa(n)

A) ribose. B) ketose. C) disaccharide. D) monosaccharide. E) ketone. Answer: D 25) Galactosemiaisthenameofametabolicdisorder.Inthisdisorder,anenzymeismissingthatisneededto A) makegalactosefromlactose. B) makelactosefromgalactose. C) convertgalactosetoglycogen. D) convertgalactosetoglucose. E) convert-galactoseto-galactose. Answer: D 26) Underacidhydrolysisconditions,starchisconvertedto A) glucose. B) xylose. C) maltose. D) galactose. E) fructose. Answer: A

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27) Maltosecanbeclassifiedasa(n) A) disaccharide. B) polysaccharide. C) ketose. D) pentose. E) oligosaccharide. Answer: A 28) Hyperglycemiaisaconditioninwhich A) theglucoselevelinthebloodisabout100mg/dL. B) theamountofglucoseintheurineislowerthannormal. C) theglucoselevelinthebloodishigherthannormal. D) theglucoselevelinthepancreasislowerthannormal. E) theglucoselevelintheliverislowerthannormal. Answer: C 29) Hypoglycemiaisaconditioninwhich A) theglucoselevelinthebloodisabout100mg/dL. B) theamountofglucoseintheurineishigherthannormal. C) theglucoselevelinthebloodishigherthannormal. D) theglucoselevelinthepancreasishigherthannormal. E) theglucoselevelinthebloodislowerthannormal. Answer: E 30) Duringphotosynthesis,carbondioxideandwaterareconvertedtoglucoseandoxygenby A) largeanimals. B) insects. C) mushrooms. D) greenplants. E) earthworms. Answer: D 31) Thebreakdownofcarbohydratestocarbondioxideandwaterinthebodyiscalled A) reduction B) respiration. C) photosynthesis. D) anabolism. E) mutarotation. Answer: B 32) Photosynthesisuses________asanenergysource. A) glucose B) carbondioxide C) chlorophyll D) oxygen E) sunlight Answer: E

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33) Fructosedoesnotundergohydrolysisbecauseitisa A) aldose. B) hexose. C) reducingsugar. D) monosaccharide. E) disaccharide. Answer: D 34) Galactoseisaproductofenzymatichydrolysisof A) lactose. B) glucose. C) maltose. D) erythrose. E) sucrose. Answer: A

15.2 ShortAnswerQuestions
Statewhethereachofthesestructuresisthe-or-form. 1)

Answer: (alpha) 2)

Answer: (beta) 3)

Answer: (alpha)

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4)

Answer: (alpha) 5)

Answer: (beta)

15.3 True/FalseQuestions
1) Sucroseisadisaccharide. Answer: TRUE 2) AreducingsugargivesaprecipitateofsilvermetalwithBenedictsreagent. Answer: FALSE 3) Sucroseismadeupofglucoseunitsonly. Answer: FALSE 4) Amylopectinisastraight-chainpolysaccharide. Answer: FALSE 5) CellulosewillgiveapositiveBenedictstest. Answer: FALSE 6) Theproductofoxidationofanaldoseisacarboxylicacid. Answer: TRUE 7) Theproductofreductionofmannoseismannicacid. Answer: FALSE 8) Sucroseisareducingsugar. Answer: FALSE

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9) Theproductofreductionofxyloseisxylitol. Answer: TRUE

15.4 MatchingQuestions
Selectthecorrectcarbohydrateforeachdescription. 1) Column1: acarbohydratethatcannotbe digestedbyhumans Column2: cellulose Answer: cellulose 2) Column1: adisaccharidethatoccursasa breakdownproductofstarch Column2: maltose Answer: maltose 3) Column1: acarbohydratethatstores energyinthehumanbody Column2: glycogen Answer: glycogen 4) Column1: acarbohydratethatisusedto buildcellwallsinplants Column2: cellulose Answer: cellulose 5) Column1: amonosaccharidethat combineswithglucosetoform lactose Column2: galactose Answer: galactose 6) Column1: adisaccharidefoundinmilk andmilkproducts Column2: lactose Answer: lactose 7) Column1: adisaccharideconsistingof glucoseandfructose Column2: sucrose Answer: sucrose 8) Column1: adisaccharideconsistingof twoglucosemolecules Column2: maltose Answer: maltose

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9) Column1: amonosaccharidefoundin fruitjuicesandhoney,the sweetestcarbohydrate Column2: fructose Answer: fructose 10) Column1: anunbranchedcarbohydrate thatstoresglucoseinplants Column2: amylose Answer: amylose Indicatethemonosaccharide(s)produceduponhydrolysisofeachcarbohydrate. 11) Column1: amylopectin Column2: glucose Answer: glucose 12) Column1: lactose Column2: glucose+galactose Answer: glucose+galactose 13) Column1: glycogen Column2: glucose Answer: glucose 14) Column1: maltose Column2: glucose Answer: glucose 15) Column1: sucrose Column2: glucose+fructose Answer: glucose+fructose

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Chapter16 CarboxylicAcidsandEsters 16.1 Multiple-ChoiceQuestions

1) Whichfunctionalgroupisacarboxylicacid? A) -OH B) O - C OH O - C -OOH | - C-OH |

C)

D)

E) -CH2 OH Answer: B 2) Thisfunctionalgroupisknownasa(n) O -C-OA) ester. B) carboxylicacid. C) alcohol. D) aldehyde. E) acetal. Answer: A 3) Thefunctionalgroupinaceticacidiscalledthe A) hydroxylgroup. B) aldehydegroup. C) carbonylgroup. D) carboxylgroup. E) estergroup. Answer: D 4) Whichofthefollowingisfoundinvinegar? A) nitricacid B) formicacid C) aceticacid D) propionicacid E) butyricacid Answer: C

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5) Thecommonnameofthecompound O CH3 CH2 CH2 C -OHis A) aceticacid. B) propanoicacid. C) propionicacid. D) butanoicacid. E) butyricacid. Answer: E 6) Inthecompoundbelow,thehydroxylgroupisinwhichposition? O CH3 CH2 CH C -OH OH A) B) C) D) E) Answer: A 7) Thecompoundbelowisnamed

A) benzoicacidamine. B) m-aminobenzoicacid. C) 2-acidaniline. D) benzamide. E) m-benzoicacidaniline. Answer: B

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8) WhatistheIUPACnameforthiscompound? CH3 O CH3 C HCH2 C OH A) pentanoicacid B) -methylbutanoicacid C) 3-methylbutanoicacid D) -methylbutyricacid E) 2-methyl-4-butanoicacid Answer: C 9) Acarboxylicacidispreparedfromanaldehydeby A) oxidation. B) reduction. C) hydrolysis. D) neutralization. E) hydrogenation. Answer: A

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10) Thestructuralformulaofthecarboxylicacidproducedbytheoxidationof 2,2-dimethyl-1-propanolis A) CH3 O CH3 C - C H C H3 B) CH3 O CH3 CH3 C - C -O C CH3 C H3 C H3 O CH3 CH2 CH2 CH2 C OH CH3 O CH3 C - C OH C H3 E) CH3 CH3 C -OH C H3 Answer: D 11) Inwatersolution,howdoesdiluteaceticacidbehave? A) asastrongacid B) asaweakacid C) asastrongbase D) asaweakbase E) asaneutralcompound Answer: B

C)

D)

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12) Whichofthefollowingisthereactionfortheionizationof-hydroxypropanoicacidinwater? A) O OH HOCH2 CH2 C OH+H2 OHOCH2 CH2 CH OH+H+ B) O O HOCH2 CH2 C OH+H2 OHOCH2 CH2 C O- +H3 O+ O O CH3 CH C OH+H2 OCH3 CH C O- +H3 O+ OH D) OH

C)

O O HOCH2 CH2 C OH+2H2 O-OCH2 CH2 C O- +2H3 O+ O O CH3 CH C OH+H2 OCH3 CH C OH+H3 O+ | OH | O-

E)

Answer: B 13) TheneutralizationofformicacidbyNaOHproduces A) sodiumformateastheonlyproduct. B) formateionandhydroniumion. C) sodiumformaldehyde. D) methylalcohol. E) sodiumformateandH2 O. Answer: E 14) Whichofthefollowingcompoundsismostsolubleinwater? A) CH3 CH2 CH3 B) CH3 CH2 CH2 OCH3 C) CH3 CH2 CH2 CH2 OH D) O CH3 CH2 CH2 CH2 C OH O CH3 C OH

E)

Answer: E

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15) Whichofthefollowingisthereactionfortheneutralizationof-hydroxybutyricacidwithNaOH? A) OH O OH O CH3 C HCH2 C OH+NaOHCH3 C HCH2 C O- Na+ +H2 O B) OH O OH O CH3 C HCH2 C OH+NaOHCH3 C C H2 C OH+NaH OH OH O OH O CH3 CH2 C H C OH+NaOHCH3 CH2 C H C O- Na+ +H2 O OH O O- Na+ O CH3 C HCH2 C OH+2NaOHCH3 C HCH2 C O- Na+ +2H2 O O O CH3 CH2 CH C -OH+2NaOHCH3 CH2 CH C O- Na+ +H2 O O H OH

C)

D)

E)

Answer: A 16) Whichcompoundbelowcontainsanesterfunctionalgroup? A) OH CH3 C HCH2 CH3 B) CH3 CH2 -O-CH2 CH3 C) O H C -O-CH2 CH3 O CH3 C CH2 CH3 O CH3 C -OH

D)

E)

Answer: C

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17) Manyofthefragrancesofflowersandtheflavorsoffruitsaredueto A) ethers. B) carboxylicacids. C) esters. D) amines. E) amides. Answer: C 18) Whatisthenameofthiscompound? O CH3 C -O-CH2 CH3 A) ethylmethylester B) diethylester C) ethylmethanoate D) 2-ether-2-butanone E) ethylacetate Answer: E 19) Thereactantsthatwillformanesterinthepresenceofanacidcatalystare A) twocarboxylicacids. B) twoalcohols. C) acarboxylicacidandanalcohol. D) analdehydeandanalcohol. E) twoaldehydes. Answer: C

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20) Whichofthesecompoundsistheesterformedfromthereactionofaceticacidand1 -propanol? A) O CH3 CH2 C OCH2 CH3 B) OH CH3 C OH O CH2 CH2 CH3 C) OH CH3 CH2 C OH O CH2 CH3 D) O CH3 C OCH2 CH2 CH3 O CH3 CH2 CH2 OCH2 C OH

E)

Answer: D 21) Thealcoholandcarboxylicacidrequiredtoformpropylethanoateare A) methanolandpropionicacid. B) ethanolandpropionicacid. C) propanolandpropanoicacid. D) 1-propanolandethanoicacid. E) 2-propanolandethanoicacid. Answer: D 22) Thesplittingapartofanesterinthepresenceofastrongacidandwateriscalled A) hydrolysis. B) saponification. C) neutralization. D) esterification. E) reduction. Answer: A

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23) Whichofthefollowingisthereactionfortheacidhydrolysisofethylformate? A) O O CH3 C OCH3 +NaOHCH3 C O- Na+ +CH3 OH B) O O CH3 C OCH3 +H2 OCH3 C OH+CH3 OH O O H C OCH3 +H2 OH C OH+CH3 OH O O H C OCH2 CH3 +H2 OH C OH+CH3 CH2 OH O OH H C OCH2 CH3 +H2 OH C OCH2 CH3 OH Answer: D 24) Whichofthefollowingisthereactionforthesaponificationofmethylacetate? A) O O CH3 C OCH3 +NaOHCH3 C OH+CH3 O- Na+ B) O O CH3 C OCH3 +NaOHCH3 C O- Na+ +CH3 OH O O + H C OCH3 +H2 OH C O- +CH3 O H 2 O O H C OCH3 +NaOHH C O- Na+ +CH3 OH O O + CH3 C OCH3 +H2 OCH3 C O- +CH3 O H 2

C)

D)

E)

C)

D)

E)

Answer: B

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25) ThereactionofanesterwithNaOHisknownas A) esterification. B) neutralization. C) saponification. D) reduction. E) oxidation. Answer: C 26) AcarboxylicacidisnamedintheIUPACsystembyreplacingthe -einthenameoftheparentalkanewith A) -oicacid. B) -oic. C) -carboxylicacid. D) acid. E) -oate. Answer: A 27) Whencomparedtosulfuricacid,howstrongarecarboxylicacids? A) stronger B) justasstrong C) weaker D) notacidicatall Answer: C 28) Whatkindoftastedocarboxylicacidshave? A) sweet B) sour C) fruity D) slippery E) oily Answer: B 29) Whatisthecommonnameforethanoicacid? A) butyricacid B) formicacid C) citricacid D) stearicacid E) aceticacid Answer: E 30) Whatistheirritatingacidfoundinantandbeestings? A) aceticacid B) formicacid C) citricacid D) butyricacid E) stearicacid Answer: B 31) Whichorganicacidaccountsfortheodorofrancidbutter? A) propionicacid B) aceticacid C) formicacid D) butyricacid E) ethanoicacid Answer: D Page217

32) Inthecommonnamingconventionforcarboxylicacids,whatisthecorrectGreekletterusedforthecarbon adjacenttothecarboxylgroup? A) B) C) D) E) Answer: A 33) Whattherapeuticuseismadeof-hydroxyacids? A) ulcertreatment B) feverreduction C) antibiotic D) reductionofskinpigmentation E) sunscreen Answer: D 34) Whatsignificantsideeffectisseenwith-hydroxyaciduse? A) UVsensitivity B) increasedthirst C) nausea D) increasedsusceptibilitytoinfection E) gastricirritation Answer: A 35) What-hydroxyacidisfoundpredominantlyingrapes? A) tartaricacid B) citricacid C) lacticacid D) glycolicacid E) benzoicacid Answer: A 36) Whatisthemethodofpreparingcarboxylicacidsfromalcoholsoraldehydes? A) reduction B) hydration C) oxidation D) saponification E) hydrolysis Answer: C 37) Whichcarboxylicacidinthelistbelowisanaromaticcarboxylicacid? A) aceticacid B) benzoicacid C) butyricacid D) benzene E) citricacid Answer: B

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38) Whatkindofintermolecularbondingoccursbetweencarboxylicacids? A) ionicbonding B) nonpolarbonding C) covalentbonding D) hydrogenbonding E) charge-transferbonding Answer: D 39) Whydocarboxylicacidshavehigherboilingpointsthansimilaralcoholsoraldehydes? A) Theyformdimersthatarerelativelystable. B) Theyaremorewatersoluble. C) Theyhavehighermolecularweights. D) Theyhaveanadditionaloxygenatom. E) Thecarboxylicacidchainisnotlinear. Answer: A 40) Whathappenstowatersolubilityaschainlengthincreasesincarboxylicacids? A) Itincreases. B) Itdecreases. C) Itstaysthesame. Answer: B 41) Whatisthecommonuseofmonosodiumglutamate? A) asapreservative B) asadisinfectant C) asananti-pyretic D) asaflavorenhancer E) asaspoilageinhibitor Answer: D 42) Whatcommonuseismadeofsodiumpropionateandsodiumbenzoate? A) flavorenhancer B) preservative C) pHadjuster D) disinfectant E) decongestant Answer: B 43) Whatmetabolicproductofpyruvicacidisformedanaerobicallyduringexercise? A) lacticacid B) citricacid C) malicacid D) aceticacid E) -ketoglutaricacid Answer: A 44) Whichoftheseisanacidformedinthecitricacidcycle? A) aceticacid B) propionicacid C) -ketoglutaricacid D) benzoicacid E) palmiticacid Answer: C

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45) Whatistheproductofthereactionofanalcoholandacarboxylicacidwhenreactedtogetherunderacidic conditions? A) anether B) anester C) asalt D) aketone E) analdehyde Answer: B 46) Derivativesofwhicharomaticcarboxylicacidhavebeenusedasanalgesics,antipyretics,and anti-inflammatoryagents? A) benzoicacid B) anthranilicacid C) naphthenicacid D) p-toluenesulfonicacid E) salicylicacid Answer: E 47) Whichofthesefunctionalgroupsislikelytogiveasourtastetoafood? A) ester B) ether C) ketone D) carboxylicacid E) thiol Answer: D 48) FromwhatcomponentisthefirstpartoftheIUPACnameofanester(suchasmethylanthranilate)derived? A) thecarboxylicacid B) thealcohol C) theether D) theester E) theamide Answer: B 49) Whatchemicalprocessisresponsibleforthesmellofvinegarinanoldbottleofaspirin? A) reduction B) hydration C) hydrolysis D) esterification E) dissolution Answer: C 50) Whatkindofconditionscanproducehydrolysisofanester? A) acidic B) basic C) eitheracidicorbasic D) neitheracidicnorbasic Answer: C

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51) Whichpartofasoapisresponsibleforitsabilitytodissolvefatsandoilydirt? A) thehyrophilicend B) thehydrophobicend C) thecarboxylate D) theionizedoxygen E) thecarbonylgroup Answer: B 52) Whatisthenameofthestructureformedwhenasoapcoatsanoilyparticletomakeitwatersoluble? A) micelle B) cluster C) liposome D) dimer E) lipid Answer: A

16.2 True-FalseQuestions
1) Soapsaresaltsoflongchainfattyacids. Answer: TRUE 2) Carboxylicacidsarestrongacids. Answer: FALSE 3) Estersareformedfromthereactionofanetherwithacarboxylicacid. Answer: FALSE 4) Carboxylicacidsareresponsibleforthesweettasteoffruitsandvegetables. Answer: FALSE 5) Longchaincarboxylicacidsarealsoknownasfattyacids. Answer: TRUE 6) Aspirinthathasasmellofvinegarhasbrokendownbyhydrolysis. Answer: TRUE 7) Themajoracidiccomponentofvinegarisformicacid. Answer: FALSE 8) Alpha-hydroxyacidsshouldbeusedatconcentrationsunder10%inskincareproducts. Answer: TRUE 9) Itisalwayssafetouseanycommercialskincareproductwithoutdoingatestpatchfirst. Answer: FALSE 10) Benzoicacidisanaliphaticcarboxylicacid. Answer: FALSE 11) Carboxylicacidswithmorethanfivecarbonsareverywatersoluble. Answer: FALSE 12) Theboilingpointsofcarboxylicacidsarelowerthanthecorrespondingalcohols. Answer: FALSE

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13) Carboxylicacidswithfourorfewercarbonsareverywatersoluble. Answer: TRUE 14) Sodiumpropionateisacommondisinfectant. Answer: FALSE 15) Mostofthecarboxylicacidinanaqueoussolutionisionized. Answer: FALSE 16) Sodiumbenzoateisacommonpreservative. Answer: TRUE 17) Citricacidisanimportantpartofglycolysis. Answer: FALSE 18) TheKrebscycleisaprocessthatthecellusestoproduceenergy. Answer: TRUE 19) TheKrebscycleandthecitricacidcyclearedifferentprocesses. Answer: FALSE 20) Anesterisderivedfromanalcoholandacarboxylicacid. Answer: TRUE 21) Methylsalicylate(oilofwintergreen)isusedtherapeuticallyasacounter-irritant. Answer: TRUE 22) Polyestersareplasticsthatareusedtomakefabrics,bottles,andmedicaldevicessuchasheartvalves. Answer: TRUE 23) Butylalcoholisoneofthereactantsusedtomakemethylbutyrate. Answer: FALSE

16.3 MatchingQuestions
Identifythefamilyforeachofthefollowingcompounds. 1) Column1: O CH3 C CH3

Column2: ketone Answer: ketone 2) Column1: O CH3 CH2 C OH

Column2: carboxylicacid Answer: carboxylicacid

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3) Column1:

O CH3 CH2 C OCH3

Column2: ester Answer: ester Selectthecorrectnameforthefollowing. 4) Column1: O H C OH

Column2: formicacid Answer: formicacid 5) Column1: O H C -O-CH2 CH3

Column2: ethylformate Answer: ethylformate 6) Column1: O H C O- Na +

Column2: sodiumformate Answer: sodiumformate

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Chapter17 Lipids 17.1 Multiple-ChoiceQuestions

1) WhichstatementisNOTtrue? A) Lipidsarefoundincellmembranes. B) Lipidsaresolubleinorganicsolvents. C) Lipidsvaryincomposition. D) Oxidationoflipidsprovideshalfasmuchenergyasoxidationofcarbohydrates. E) Somehormonesarelipids. Answer: D 2) Lipidsarecompoundsthataresolublein A) distilledwater. B) normalsalinesolution. C) glucosesolution. D) chloroform. E) oxygen. Answer: D 3) Whichofthefollowinglipidswillgiveasinglemoleculeoffattyacidwhenhydrolyzed? A) wax B) fat C) phospholipid D) glycolipid E) cholesterol Answer: A 4) Whichofthefollowinglipidswillgivenofattyacidwhenhydrolyzed? A) wax B) fat C) phospholipid D) glycolipid E) cholesterol Answer: E 5) Apolyunsaturatedfattyacidcontainsmorethanone A) carboxylgroup. B) hydroxylgroup. C) carbonylgroup. D) longcarbonchain. E) doublebond. Answer: E 6) Unsaturatedfattyacidshavelowermeltingpointsthansaturatedfattyacidsbecause A) theyhavefewerhydrogenatoms. B) theyhavemorehydrogenatoms. C) theirmoleculesfitcloselytogether. D) thecisdoublebondsgivethemanirregularshape. E) thetransdoublebondsgivethemanirregularshape. Answer: D

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7) Whichofthefollowingisanunsaturatedfattyacid? A) myristic B) oleic C) palmitic D) stearic E) lauric Answer: B 8) Whichofthefollowingfattyacidsisasolidatroomtemperature? A) palmitoleic B) oleic C) stearic D) linoleic E) linolenic Answer: C 9) Comparedtosaturatedfattyacids,unsaturatedfattyacidshave A) longercarbonchains. B) shortercarbonchains. C) highermeltingpoints. D) lowermeltingpoints. E) greaterintermolecularattraction. Answer: D 10) Waxesarelipidsderivedfrom A) along-chainalcoholandalong-chainfattyacid. B) glycerolandthreefattyacids. C) glycerol,fattyacids,phosphate,andanaminoalcohol. D) sphingosine,fattyacids,phosphate,andanaminoalcohol. E) terpenesandsteroids. Answer: A 11) Atriacylglycerolthatissolidatroomtemperatureiscalleda(n) A) cephalin. B) lecithin. C) oil. D) wax. E) fat. Answer: E 12) Commercially,liquidvegetableoilsareconvertedtosolidfatssuchasmargarineby A) hydrogenation. B) hydrolysis. C) hydration. D) oxidation. E) saponification. Answer: A

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13) Afatoroilbecomesrancidwhen A) itsdoublebondsareoxidized. B) itishydrogenated. C) itishydrolyzed. D) itissaponified. E) itispartiallyhydrogenated. Answer: A 14) Margarinecontainingpartiallyhydrogenatedsoybeanoilissolidbecause A) itcontainsonlysaturatedfats. B) itcontainsonlytransfattyacids. C) someofitsdoublebondshavebeenconvertedtosinglebonds. D) itcontainsonlycisdoublebonds. E) itcontainsonlypolyunsaturatedfattyacids. Answer: C

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15) Palmiticacidisa16carbonacid.Inabalancedequation,theproductsofthesaponificationoftripalmitin (glyceryltripalmitate)are A) O CH2 -OH+3H3 C-(CH2 )14- C -OH | CH-OH | C H2 -OH B) O CH2 -O- Na + +3H3 C-(CH2 )14- C -OH | CH-O- Na + | CH2 -O-Na+ C) O CH2 -OH+3H3 C-(CH2 )14- C -O- Na + | CHOH | CH2 -OH O CH2 -OH+H3 C-(CH2 )14- C -O- Na+ | 3CHOH | CH2 -OH E) O CH2 -OH+2H3 C-(CH2 )14- C -O- Na+ | CHOH | Answer: C 16) Theproductsoftheacidcatalyzedhydrolysisofafatare A) theestersoffattyacids. B) fattyacidsandglycerol. C) saltsoffattyacids. D) saltsoffattyacidsandglycerol. E) phospholipids. Answer: B O

D)

CH2 -OH +H3 C-(CH2 )16 -C-O- Na +

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17) Theproductsofthesaponificationofafatare A) theestersoffattyacids. B) fattyacidsandglycerol. C) saltsoffattyacids. D) saltsoffattyacidsandglycerol. E) phospholipids. Answer: D 18) Glycerolphospholipidscaninteractbothwithotherlipidsandwaterbecausetheycontainboth________and ________. A) singlebonds;doublebonds B) polarregions;nonpolarregions C) glycerol;sphingosine D) saturatedfattyacids;unsaturatedfattyacids E) bilesalts;cholesterol Answer: B 19) Thecomponentsinthefollowingglycerolphospholipidare

| OA) sphingosine,palmiticacid,phosphate,andcholine. B) sphingosine,palmiticacid,phosphate,andserine. C) glycerol,palmiticacid,phosphate,andethanolamine. D) glycerol,palmiticacid,phosphate,andgalactose. E) sphingosine,palmiticacid,phosphate,andethanolamine. Answer: C 20) Themainlipidcomponentsincellularmembranesare A) glycerolphospholipids. B) terpenes. C) steroids. D) triacylglycerols. E) waxes. Answer: A 21) Inthelistbelow,whichlipidtypeismostsolubleinwater? A) triacylglycerols B) glycerophospholipids C) oils D) steroids E) waxes Answer: B

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22) Glycospingolipidsarelipidscomposedof A) along-chainalcoholandafattyacid. B) glycerolandfattyacids. C) glycerol,fattyacids,phosphate,andanaminoalcohol. D) sphingosine,fattyacids,phosphate,andanaminoalcohol. E) sphingosine,fattyacids,aminoalcohol,phosphate,andacarbohydrate. Answer: E 23) WhatphospholipidcontainsfattyacidsbutNOTglycerol? A) lecithin B) glycolipid C) sphingolipid D) cephalin E) corticosteroid Answer: C 24) Whichofthefollowingcompoundsisaglycerolphospholipid? A) jojobawax B) estrogen C) lecithin D) triolein E) cerebroside Answer: C 25) Whichofthefollowingisalipid? A) cholesterol B) nicotine C) aniline D) lactose E) collagen Answer: A 26) WhichofthefollowingisNOTafunctionofglycerophospholipids? A) transportoftriacylglycerols B) regulationofcellularpermeability C) protectnervecells D) aidindigestion E) transportofcholesterol Answer: D 27) Themostcommontypeofgallstonesiscomposedofalmostpure A) cholesterol. B) bilesalts. C) glycerophospholipids. D) calciumsaltsoffattyacids. E) anabolicsteroids. Answer: A

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28) WhichofthefollowingisNOTalipoproteinthatcarriesnonpolarlipidsthroughthebloodstream? A) sphingosine B) LDL C) HDL D) VLDL E) chylomicron Answer: A 29) Thesteroidhormonethatincreasesthebloodglucoseandglycogenlevelsfromfattyacidsandaminoacidsis A) aldosterone. B) progesterone. C) cortisone. D) estrogen. E) prednisone. Answer: C 30) Thesteroidhormonepresentinbirthcontrolpillsis A) aldosterone. B) progesterone. C) cortisone. D) estrogen. E) norethindrone. Answer: E 31) Inthefluid-mosaicmodelthatdescribesplasmamembranes, A) therearethreelayersofglycerophospholipidmolecules. B) twolayersofglycerophospholipidmoleculeshavetheirnonpolarsectionsorientedtotheinsideofthe membrane. C) twolayersofglycerophospholipidmoleculeshavetheirnonpolarsectionsalongtheoutersurfaceofthe membrane. D) Asinglerowofglycerophospholipidmoleculesformsabarrierbetweentheinsideandoutsideofthecell. E) twolayersofproteinsseparatethecontentsinsideacellfromthesurroundingfluids. Answer: B 32) Channelproteinsincellmembranesservewhatfunction? A) Theyaddstrengthandrigiditytothemembrane. B) Theyprovidepathwaysforwaterandelectrolytestomovethroughcellmembranes. C) Theyformthebilayerportionofthemembrane. D) Theyallownonpolarsubstancestomovethroughthemembrane. E) Theypreventinteractionsbetweenthenonpolartailsofthephospholipidswhichgivesthemembraneits fluidity. Answer: B 33) Adoublecheeseburgerwithbaconcontains640kcaland39goffat.Calculatethenumberofkilocaloriesfrom fat.(1gramoffat=9kcal;1gramofcarbohydrateorproteindelivers4kcal.) A) 4.3kcalfromfat B) 39kcalfromfat C) 71kcalfromfat D) 350kcalfromfat E) 640kcalfromfat Answer: D

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34) Adoublecheeseburgerwithbaconcontains640kcaland39goffat.Calculatethepercentageoftotal kilocaloriesduetofat(1gramoffat=9kcal). A) 0.68%oftotalkilocalories B) 6.1%oftotalkilocalories C) 11%oftotalkilocalories D) 55%oftotalkilocalories E) 100%oftotalkilocalories Answer: D Forthequestion(s)thatfollow,identifytheclassoflipidtowhicheachofthefollowingmoleculesbelongs. 35)

A) wax B) triacylglycerol C) glycerolphospholipid D) glycosphingolipid E) steroid Answer: A 36)

A) triacylglycerol B) wax C) glycerolphospholipid D) bilesalt E) steroid Answer: A

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37)

| OA) glycerophospholipid B) triacylglycerol C) glycosphingolipid D) steroid E) wax Answer: A 38)

| OA) sphingolipid B) simplelipid C) bilesalt D) triacylglycerol E) prostaglandin Answer: A

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39)

A) steroid B) glycerophospholipid C) wax D) bilesalt E) prostaglandin Answer: A 40)

A) bilesalt B) triacylglycerol C) prostaglandin D) wax E) sphingolipid Answer: A 41) Accordingtothefluid-mosaicmodelofacellmembrane,themaincomponentofamembraneis A) alipidbilayer. B) amembraneprotein. C) aglycoprotein. D) asteroid. E) aprostaglandin. Answer: A 42) Thetypeoflipidthatgivesacellmembraneitsshapeisa A) triacylglycerol. B) glycerophospholipid. C) prostaglandin. D) bilesalt. E) wax. Answer: B Page233

43) Oneinnercomponentofatypicalcellmembraneis A) glucose. B) cholesterol. C) glycine. D) palmiticacid. E) glycerol. Answer: B 44) Alipoproteinparticlefunctionsto A) dissolvepolarlipidsforexcretion. B) metabolizelipidsintonewsubstances. C) dissolvepolarlipidsinurine. D) transportnonpolarlipidstobodycells. E) storelipidsinthetissues. Answer: D 45) Synthesisofcholesterolandbilesaltstakesplaceinthe A) liver. B) gallbladder. C) smallintestine. D) largeintestine. E) pancreas. Answer: A Answerthequestion(s)thatfollowaboutthediagramshownbelow.

46) Inthisdiagramofacellmembrane,thesmallbranchedobjectlabeled(A)ispartofa A) steroid. B) hydrophobicregion. C) membraneprotein. D) glycerophospholipid. E) glycolipid. Answer: E 47) Inthisdiagramofacellmembrane,thelargeobjectlabeled(E)is A) asteroid. B) ahydrophobicregion. C) anintegralmembraneprotein. D) aphospholipid. E) aglycolipid. Answer: C

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48) Inthisdiagramofacellmembrane,theobjectlabeled(C)isa A) steroid. B) hydrophobicregion. C) phospholipid. D) mitochondrion. E) glycolipid. Answer: B 49) Inthisdiagramofacellmembrane,theobjectlabeled(B)isa A) steroid. B) hydrophobicregion. C) membraneprotein. D) glycerophospholipidbilayer. E) glycolipid. Answer: D 50) Inthisdiagramofacellmembrane,theobjectlabeled(D)ispartofa A) steroid. B) hydrophobicregion. C) peripheralmembraneprotein. D) glycerophospholipid. E) glycosphingolipid. Answer: C

17.2 BimodalQuestions
1) Bilesaltsaresynthesizedfrom________. A) cephalin B) triacylglycerols C) pancreas D) cholesterol E) lecithin Answer: D 2) Cholesterolbelongstothe________groupoflipids. A) phospholipid B) steroid C) prostaglandin D) triacylglycerol E) wax Answer: B 3) Bilesaltsarestoredinthe________. A) liver B) pancreas C) stomach D) gallbladder E) smallintestine Answer: D

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4) Bilesaltsareamongthelipidclassknownas________. A) sphingosides B) prostaglandins C) cerebrosides D) triacylglycerols E) steroids Answer: E 5) Aprecursorofprostaglandinsis________acid. A) oleic B) linoleic C) arachidonic D) tauric E) palmitic Answer: C 6) Inasimplemodelofatherosclerosisandheartdisease,thecompoundthatformsplaquesthatadheretothe wallsofthebloodvesselsis________. A) cholesterol B) carnaubawax C) stearicacid D) glycerol E) sphingosine Answer: A 7) Thenameofthereactionthatoccurswhenafatreactswithsodiumhydroxideandwateris________. A) hydrogenation B) reduction C) hydration D) oxidation E) saponification Answer: E

17.3 True/FalseQuestions
Answer: FALSE

1) ThecatalystneededforsaponificationisH+ ion.

2) Olestraisatriacylglycerol. Answer: FALSE 3) Hydrogenationofadoublebondinatriacylglycerolrequiresacatalyst. Answer: TRUE 4) Mostplantlipidsaresaturatedlipids. Answer: FALSE 5) Theheadofatriacylglycerolisthepolarendofthemolecule. Answer: TRUE 6) Thetailofatriacylglycerolisthenonpolarend. Answer: TRUE 7) Onefunctionofphospholipidsistoprovidestructuretobiomembranes. Answer: TRUE Page236

8) Inthefluid-mosaicmodelofcellmembranes,thelipidmoleculesareorientedwiththeirheadstotheoutsideof themembrane. Answer: TRUE 9) Glycoproteinsarecomponentsofcellmembranes. Answer: TRUE 10) Theinteriorofalipidbilayeristhehydrophilicregion. Answer: FALSE

17.4 MatchingQuestions
Matchthefollowing. 1) Column1: Triacylglycerolsareformed fromglyceroland________. Column2: fattyacids Foil: glycerin Answer: fattyacids 2) Column1: alipidthatcannotbe hydrolyzed Column2: cholesterol Answer: cholesterol 3) Column1: thefunctionalgroupof triacylglycerols Column2: ester Answer: ester 4) Column1: afattyacidwithatleastone doublebond Column2: unsaturated Answer: unsaturated 5) Column1: phospholipidsthatdonot containglycerol Column2: sphingolipids Answer: sphingolipids 6) Column1: theprocessofconverting unsaturatedfatsintosaturated fats Column2: hydrogenation Foil: hydrolysis Answer: hydrogenation

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7) Column1: themeltingpointsofsaturated fatscomparedtounsaturated fats Column2: higher Foil: lower Answer: higher 8) Column1: asourceofmostsaturatedfats Column2: animals Foil: plants Answer: animals 9) Column1: acharacteristiccommonto mostlipids Column2: insolubleinwater Answer: insolubleinwater 10) Column1: theproductofreactinga triacylglycerolwithastrong baseandwater Column2: soap Answer: soap Selectthetypeoflipidthatmatchesthedescription. 11) Column1: triolein Column2: triacylglycerol Answer: triacylglycerol 12) Column1: ganglioside Column2: glycosphingolipid Answer: glycosphingolipid 13) Column1: aldosterone Column2: steroid Answer: steroid 14) Column1: testosterone Column2: steroid Answer: steroid 15) Column1: cephalin Column2: glycerophospholipid Answer: glycerophospholipid

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Identifyeachofthespecifiedregionsonthisphospholipidaspolarornonpolar.

16) Column1: A Column2: nonpolar Foil: neither Answer: nonpolar 17) Column1: B Column2: nonpolar Answer: nonpolar 18) Column1: C Column2: polar Answer: polar

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Chapter18 AminesandAmides 18.1 MultipleChoiceQuestions

1) ThecompoundCH3 CH2 NHCH3 isclassifiedasa A) primaryamine. B) secondaryamine. C) tertiaryamine. D) quaternaryamine. E) hydratedamine. Answer: B 2) WhichofthefollowingcompoundsCANNOTformhydrogenbondswithwater? A) CH3 CH2 CH3 B) CH3 CH2 OH C) O CH3 C OH O CH3 C OCH3

D)

E) CH3 CH2 NH2 Answer: A 3) Whatisthenameofthiscompound?

A) 1-methyl-5-bromoaniline B) N-methyl-3-bromoaniline C) N-methyl-p-bromoaniline D) 1-bromo-3-N-methylaminebenzene E) 1-bromo-3-N-methylaniline Answer: B 4) Aminobenzeneisproperlyknownas A) toluene. B) aniline. C) amidine. D) histidine. E) phenylamine. Answer: B

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5) Whatisthenameofthiscompound? CH3 NCH2 CH3 C H3 A) trimethylamine B) diethylamine C) ethylmethylamine D) ethylmethylnitride E) ethyldimethylamine Answer: E 6) Inresponsetoallergicreactionsorinjurytocells,thebodyincreasestheproductionof A) diphenhydramine. B) antihistamine. C) histamine. D) epinephrine. E) dopamine. Answer: C 7) WhichofthefollowingrepresentsthecompleteneutralizationofN,N-dimethylamine? A) CH3 NH+H2 OCH3 NH2 + +OH C H3 C H3 B) CH3 NH+NaOHCH3 N-Na+ +H2 O C H3 C H3

C) CH3 NH+HClCH3 NH2 + CH3 Cl C H3 D) CH3 NH+H2 OCH3 OH+ CH3 NH2 C H3 E) CH3 NH+HClCH3 NH2 + +Cl C H3 Answer: E 8) Whenethylaminedissolvesinwater,asolutionof_____isproduced. A) ammonia B) ethylammoniumhydroxide C) ethylamine D) ethylhydroxide E) ethylhydroxylate Answer: B Page241 C H3

9) DiethylamineandHClreacttoproduce A) diethylchloride. B) diethylammoniumchloride. C) ethylammoniumchloride. D) ammoniumchloride. E) butylammoniumchloride. Answer: B 10) Theamideformedinthereactionofbenzoicacidandethylamineis A)

B)

C)

D)

E)

Answer: B Page242

11) Whenaceticacidreactswithammonia,NH3 ,thereactioncalledamidationyields A) acetamine. B) ammoniumacetate. C) ethylammoniumhydroxide. D) aminoacetate. E) acetamide. Answer: E 12) Physiologicallyactivenitrogen-containingcompoundsproducedbyplantsarecalled A) aromatics. B) alkaloids. C) esters. D) polymers. E) ethers. Answer: B 13) WhichofthefollowingisNOTanalkaloid? A) nicotine B) caffeine C) diethylamine D) quinine E) cocaine Answer: C 14) Whatisthemajorfunctionalgroupinthefollowingcompound? O CH3 C NHCH3 A) ketone B) carboxylicacid C) ester D) amine E) amide Answer: E 15) Whatisthenameofthiscompound?

A) 1-ethylbenzamide B) N,N-dimethylbenzamide C) 2-ethylbenzamide D) N-ethylbenzamide E) ethylaminobenzoicacid Answer: D Page243

16) Onenameforthiscompoundis O CH3 CH2 CNHCH2 CH3 A) N-ethylpropanamide. B) N-ethylacetamide. C) pentanamide. D) N,N-diethylacetamide. E) ethylpropionamide. Answer: A 17) IntheformationofN-ethylacetamide,thereactant(s)is(are) A) aceticacidanddimethylamine. B) diethylamine. C) acetamideandethanol. D) aceticacidandethylamine. E) ethanolandethylamine. Answer: D 18) Thereactionofbutanoicacidanddimethylaminegives A) N-methylbutanamide. B) N-ethylbutanamide. C) N,N-dimethylbutanamide. D) N,N-methylbutanamine. E) N-methylbutanamine. Answer: C 19) WhichofthefollowingisthereactionfortheacidhydrolysisofN-methylacetamide? A) O O CH3 C NHCH3 +H2 OCH3 C NH2 +CH3 OH B) O O H C NHCH3 +H2 OH C NH2 +CH3 OH

C)

O O CH3 C NHCH3 +H2 O+HClCH3 C NH3 + Cl- +CH3 OH D) O O H C NHCH3 +H2 O+HClH C NH3 + Cl- +CH3 OH E) O O CH3 C NHCH3 +H2 O+HClCH3 C OHCH3 NH3 + Cl-

Answer: E

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20) Whichofthefollowingisthereactionforthebasehydrolysisof N-ethylformamide? A) O O H C NHCH2 CH3 +NaOHH C OH+CH3 CH2 NH2 - Na+ B) O O H C NHCH2 CH3 +NaOHH C O- Na+ +CH3 CH2 NH2 O O H C NHCH2 CH3 +NaOHH C O- Na+ +NH3 +CH 3 CH3 O O H C NHCH2 CH3 +NaOHH C O- Na+ +CH3 NHCH3 O H C NHCH2 CH3 +NaOHCH3 CH2 NH2 +NaHCO 2

C)

D)

E)

Answer: B 21) Withthecorrectchoiceofacid,acidhydrolysisofacetamidecouldproduce A) aceticacidandammoniumchloride. B) aceticacidandmethylamine. C) ethanolandammonia. D) acetaldehydeandammoniumhydroxide. E) formicacidandethylamine. Answer: A 22) Withthecorrectchoiceofacid,theproduct(s)oftheacidhydrolysisofN-methylbenzamidecouldbe A) formicacidandaniline. B) methanolandbenzoicacid. C) benzoicacidandethylamine. D) benzoicacidandmethylammoniumchloride. E) formicacid,phenol,andammonia. Answer: D 23) Aminescontaintheelement A) nitrogen. B) oxygen. C) sulfur. D) astatine. E) arginine. Answer: A

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24) Inwhatkindofamineisthenitrogenbondedtotwocarbonatoms? A) primary B) secondary C) tertiary D) quaternary E) amide Answer: B 25) Whichchemicalclassdoesphenobarbitalbelongto? A) ester B) amine C) amide D) alkane E) ether Answer: C 26) Whatfunctionalgroupisalwaysfoundinalkaloids(suchascaffeine,nicotine,anddigitalis)? A) amide B) acid C) ether D) amine E) ester Answer: D 27) WhennamingaminesaccordingtotheIUPACsystem,the-einthecorrespondingalkaneisreplacedwith A) -amide. B) -amine. C) -ine. D) -ide. E) -ane. Answer: B 28) Cycliccompoundsthatcontainanitrogenatomarecalled A) carbocycliccompounds. B) aromaticcompounds. C) heterocycliccompounds. D) homocycliccompounds. Answer: C 29) Anilineisa(n) A) primaryaromaticamine. B) secondaryaromaticamine. C) heterocyclicamine. D) aliphaticamine. E) tertiaryamine. Answer: A

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30) Whatprefixisusedtoshowthatasmallalkylgroupisattachedtothenitrogenofanilineandnottothe aromaticring? A) NB) CC) Romannumerals D) Greekletters E) isoAnswer: A 31) HowmanyalkylsubstituentsdoesN-ethyl-N-methylanilinehave? A) one B) two C) three D) eight E) none Answer: B 32) Diphenhydramine(Benadryl )containsboth________and________functionalgroups. A) ester;acid B) ether;amine C) ester;amine D) ether;amide E) acid;amide Answer: B 33) Whatpharmacologicactivitydoamphetamine,phenylephrine,andmethedrinehaveincommon? A) CNSdepressant B) antidepressant C) appetitestimulant D) CNSstimulant E) sedative Answer: D 34) Whatpharmacologicallyactiveamineisresponsibleforthesignsandsymptomsencounteredinanallergic reaction? A) histamine B) epinephrine C) diphenhydramine D) phenylephrine E) dopamine Answer: A 35) AdeficiencyofwhichamineisresponsibleforthesignsandsymptomsofParkinsonsdisease? A) histamine B) dopamine C) epinephrine D) diphenhydramine E) methedrine Answer: B

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36) Theprefixnor-inadrugnamemeansthatthereis A) onemoreamineinthenewmoleculethanintheoriginal. B) onemoremethylgrouponthenitrogenatominthenewmoleculethanintheoriginal. C) onelessmethylgrouponthenitrogenatominthenewmoleculethanintheoriginal. D) onelessamineinthenewmoleculethanintheoriginal. E) onelessdoublebondinthenewmoleculethanintheoriginal. Answer: C 37) Whatrelationdoestheboilingpointofanaminehavetoasimilarhydrocarbon? A) higher B) lower C) verysimilar Answer: A 38) Aminescanform________bondswithothermolecules. A) oxygen B) hydrogen C) nonpolar D) metallic E) triple Answer: B 39) WhatkindofaminecanNOTformhydrogenbonds? A) primary B) secondary C) tertiary D) aromatic E) substituted Answer: C 40) Aminesare A) Bronsted-Lowrybases. B) Bronsted-Lowryacids. C) neutralinwatersolution. D) unreactive. Answer: A 41) Theodorofanaminecanbeneutralizedwith A) water. B) acids. C) bases. D) detergents. E) solvents. Answer: B 42) Cholineisaquaternaryammoniumcompoundwitha________chargeonthenitrogen. A) positive B) negative C) zero D) neutral E) double Answer: A

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43) Inwhatformareamine-containingdrugsoftenadministered? A) freebase B) sodiumsalt C) aminesalt D) watersolution E) oilsolution Answer: C 44) WhatkindofpharmacologicactivityisfoundintheaminesProcaine andLidocaine ? A) stimulant B) generalanesthetic C) localanesthetic D) disinfectant E) fungicide Answer: C 45) Whatarealkaloids? A) physiologicallyactivenitrogencompoundsderivedfromplants B) anestheticsfoundinplants C) flavoringagentsfoundinfruitsandvegetables D) preservativesfoundinanimaltissue E) naturalsteroids Answer: A 46) Identifytheheterocyclicamineinthechoicesbelow. A) diphenhydramine B) pyrrolidine C) adrenaline D) methylamine E) cholesterol Answer: B 47) Amongthechoicesbelow,identifytheheterocyclicaminefoundinDNA. A) piperidine B) pyridine C) pyrrole D) purine E) imidazole Answer: D 48) Nicotine,coniine,quinine,atropine,andmorphineareallexamplesof A) ethers. B) esters. C) carboxylicacids. D) alkaloids. E) amides. Answer: D

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49) ProcaineandLidocaine weredevelopedbymodifyingthestructureof A) cocaine. B) nicotine. C) harmaline. D) meperidine. E) caffeine. Answer: A 50) Amidesarederivativesof________and________. A) amines;esters B) amines;acids C) alkanes;amines D) acids;alcohols E) alcohols;acids Answer: B 51) Whatkindofcompoundisurea? A) ester B) acid C) amide D) ketone E) amine Answer: C 52) Whatisthechemicalclassificationofthebarbituratesedatives? A) cyclicamides B) cyclicethers C) cyclicamines D) cyclicesters E) cyclicacids Answer: A 53) Valium,firstsynthesizedbyLeoSternbachatHoffman-LaRoche,ischemicallyclassifiedasa(n) A) amine. B) ether. C) heterocyclicamide. D) ester. E) alcohol. Answer: C 54) Amideshavingfewerthan________carbonsaregenerallywatersoluble. A) five B) six C) ten D) eleven E) twelve Answer: A

18.2 True/FalseQuestions
1) Caffeineisanalkaloid. Answer: TRUE

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2) Theamidegroupisoftenfoundinpharmacologicallyactivesubstances. Answer: TRUE 3) Theaminefunctionisrarelyfoundinpharmacologicallyactivecompounds. Answer: FALSE 4) Primaryaminescontaintwocarbon-containinggroupsbondedtothenitrogenatom. Answer: FALSE 5) Heterocyclicaminescontainanitrogenatominaring. Answer: TRUE 6) AnilineistheIUPACapprovednameforaminobenzene. Answer: TRUE 7) Amphetaminesarearylalkylamineswithstimulantactivity. Answer: TRUE 8) Theprefixmeth-meansthatthereisonelessmethylgrouponthenitrogenatomofanamine. Answer: FALSE 9) Aminesdonotformhydrogenbonds. Answer: FALSE 10) Hydrogenbondsinaminesareweakerthanthoseinalcohols. Answer: TRUE 11) Aminesdonotionizeinwater. Answer: TRUE 12) Aminesactasweakacidsbyacceptingprotonsfromwater. Answer: FALSE 13) Aminesaremostlyionizedinwater. Answer: FALSE 14) Aminesaltsareusuallyliquidatroomtemperature. Answer: FALSE 15) Aminesaltsareodorlessandusuallyhighlywatersoluble. Answer: TRUE 16) Crackcocaineisproducedbytheneutralizationandextractionofcocainefromitshydrochloridesalt. Answer: TRUE 17) Quinineisanalkaloidusedfortreatmentofmalaria. Answer: TRUE 18) Atropineandcocaineareusedinthediagnosisofeyediseases. Answer: TRUE 19) PyrimidinederivativesarefoundinDNA. Answer: TRUE

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20) Nicotineisapharmacologicallyactivearomaticamine. Answer: TRUE 21) Meperidineisasyntheticcompounddevelopedfrommorphine. Answer: TRUE 22) Lysergicacidisproducedbyafungus. Answer: TRUE 23) Ureaisoneendproductofproteinmetabolisminhumans. Answer: TRUE 24) Aspartameisasweetenermadefromaminoacidderivatives. Answer: TRUE 25) Aspirinsubstitutesmaycontainamideratherthanesterfunctionalgroups. Answer: TRUE

18.3 MatchingQuestions
Identifythefamilyforeachofthefollowingcompounds. 1) Column1: CH3 CH2 NHCH3 Column2: amine Answer: amine 2) Column1: O CH3 CH2 C NHCH3

Column2: amide Answer: amide 3) Column1: CH3 CH3 CH2 N CH3

Column2: ethyldimethylamine Answer: ethyldimethylamine Selectthecorrectnameforthefollowing. 4) Column1: O H C NHCH2 CH3

Column2: N-ethylformamide Answer: N-ethylformamide

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5) Column1:

CH3 CH3 N CH3

Column2: tertiary Foil: secondary Answer: tertiary 6) Column1: CH3 CH2 CH2 NH2 Column2: primary Answer: primary 7) Column1:

Column2: primary Foil: tertiary Answer: primary 8) Column1: H CH3 N CH2 CH3

Column2: secondary Answer: secondary 9) Column1: CH3 CH3 C HCH2 NH2

Column2: primary Answer: primary

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Chapter19 AminoAcidsandProteins 19.1 Multiple-ChoiceQuestions

1) WhichofthefollowingisNOTafunctionofproteins? A) providestructuralcomponents B) storesthegeneticinformationofalivingorganism C) movementofmuscles D) catalyzereactionsinthecells E) transportsubstancesthroughthebloodstream Answer: B 2) Collagen,aproteinfoundintendonsandcartilage,wouldbeclassifiedasa________protein. A) catalytic B) structural C) transport D) storage E) hormone Answer: B 3) Sucrase,theproteinthatfacilitatesthehydrolysisofsucrose,wouldbeclassifiedasa________protein. A) transport B) hormonal C) catalytic D) structural E) contractile Answer: C 4) ThestructuralformulasofaminoacidsarethesameEXCEPTforthe A) carboxylgroup. B) alphacarbon. C) aminogroup. D) side(R)group. E) hydrogenbonding. Answer: D 5) Thefollowingaminoacidsidechainis - C HCH3 | CH3 A) polar. B) hydrophobic. C) hydrophilic. D) acidic. E) basic. Answer: B

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6) Whichofthefollowingwouldbemostlikelytobedeficientinatleastoneessentialaminoacid? A) eggs B) milk C) beans D) steak E) ham Answer: C 7) Aminoacidsthatarenotsynthesizedinthebodyandmustbeobtainedfromthedietarecalled A) essential. B) polar. C) nonpolar. D) complete. E) incomplete. Answer: A 8) TheRgroupforserineis-CH2 OH.Asazwitterion,serinehasthestructuralformula A) CH2 OH NH2 C HCOOH B) CH2 OH NH2 C HCOOCH2 O+ N H3 C HCOOH CH2 OH + N H3 C HCOOH CH2 OH + N H3 C HCOO-

C)

D)

E)

Answer: E

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9) WhichofthefollowingfunctionalgroupsofanaminoacidwouldbeintheionizedstateathighpH? A) O -COH B) -CH2 OH C) -CH3 D) O -CNH2 E)

Answer: A

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10) WhichofthefollowingisthecorrectstructureforSer-Ala-Asp?Theappropriatesidechainslooklikethis. O Ala:-CH3 ;Ser:-CH2 OH; A) CH H B) 3 3 O OH | CH2 O Asp:-CH2 COH COOH | CH2 O

N+ C H- C -NH- C H- C -NH- C H- C OCOOH | CH2O OH | CH2

CH

H C)

N+ C H- C -NH- C H- C -NH- C H- C OOH | CH2 O COOH | CH2 O

CH

H D)

N+ C H- C -NH- C H- C -NH- C H- C OCOOH | CH2 O OH | CH2

H E)

CH O 3 N+ C H- C -NH- C H- C -NH- C H- C OOH | CH2 COO| CH2O

CH

N+ C H- C -NH- C H- C -NH- C H- C O-

Answer: E 11) Thepeptidebondsthatcombineaminoacidsinaproteinare A) esterbonds. B) etherbonds. C) amidebonds. D) glycosidicbonds. E) sulfidebonds. Answer: C

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12) Thebondsthatareimportantinthesecondarystructureofaproteinare A) hydrogenbonds. B) hydrophobicinteractions. C) disulfidebonds. D) saltbridges. E) peptidebonds. Answer: A 13) Whichofthefollowingisasecondaryproteinstructure? A) -helix B) Ser-Met-Ala-Gly-Ile C) disulfidebond D) saltbridges E) hydrophobicinteractions Answer: A 14) WhichRgroupwouldmostlikelybefoundinahydrophobicareaofthetertiarystructureofaglobular protein? A) -CH2 OH B) -CH2 COOC)

+ D) -CH2 CH2 CH2 CH2 N H3 E) O -CH2 C NH2

Answer: C 15) WhattypeofinteractionwouldyouexpectbetweenthefollowingRgroupsinthetertiarystructureofa protein? O -CH2 C O- and-CH2 CH2 CH2 CH2 NH3 + A) disulfidebonds B) saltbridges C) hydrogenbonds D) hydrophobicinteractions E) peptidebonds Answer: B

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16) WhatkindsofinteractionsareNOTpartoftertiaryproteinstructure? A) peptidebonds B) disulfidebonds C) hydrophilicinteractions D) saltbridges E) hydrophobicinteractions Answer: A 17) Acidsandbasesdenatureaproteinbydisrupting A) peptidebondsandionicbonds. B) amidebondsandalkenebonds C) hydrophobicinteractionsandpeptidebonds. D) ionicbondsandhydrophobicinteractions. E) ionicbondsandhydrogenbonds. Answer: E 18) Heatdenaturesaproteinbydisrupting A) ionicbondsandpeptidebonds. B) hydrophobicbondsandhydrogenbonds. C) peptidebondsandhydrophobicbonds. D) disulfidebondsandpeptidebonds. E) hydrogenbondsanddisulfidebonds. Answer: B 19) Thesecondarystructureofcollagenisdistinguishedby A) single-helixstrands. B) double-helixstrands. C) many-helixeswoundintofibrils. D) abraidedtriplehelix. E) manyglycosidelinks. Answer: D 20) Thefibrousproteinresponsibleforthestructureofhairandwoolis A) keratin. B) collagen. C) endorphin. D) myosin. E) casein. Answer: A 21) InthepeptideAla-Try-Gly-Phe,theN-terminalaminoacidis A) alanine. B) phenylalanine. C) tryptophan. D) asparticacid. E) glycine. Answer: A

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22) InthepeptideSer-Cys-Ala-Gly,theC-terminalendis A) serine. B) serotonin. C) glycine. D) glycerine. E) alanine. Answer: C 23) Apeptidebondcontainswhichkindoffunctionalgroup? A) alcohol B) amine C) amide D) carboxylicacid E) ketone Answer: C 24) Achainmadeofmorethan50aminoacidsisusuallyreferredtoasa(n) A) peptide. B) protein. C) enzyme. D) globulin. E) hormone. Answer: B 25) The-helixofthesecondarystructureofaproteinisheldtogetherby ________betweentwowidelyseparated partsofaproteinchain. A) hydrogenbonds B) disulfidebridges C) saltbridges D) hydrophilicinteractions E) hydrophobicinteractions Answer: A 26) Inthe-pleatedsheetsecondarystructureofaprotein,twoormoreaminoacidsequencesinseparatepartsof theproteinareheldtogether A) inacoil,byhydrogenbonding. B) inrandomorder,duetohydrophobicinteractions. C) inatriplehelix. D) inadoublehelix. E) inazig-zagconformation,byhydrogenbonding. Answer: E 27) Enkephalinsarepolypeptidesthathave A) asweettaste. B) abittertaste. C) extracaloricvalue. D) pain-killingproperties. E) hormoneactivity. Answer: D

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28) Acompletelyvegetariandietwillcontainalltheessentialaminoacidsifitincludes A) wheatandrice. B) riceandbeans. C) almondsandwalnuts. D) cornandbeans. E) wheatandcorn. Answer: B 29) Ininsulin,twopeptidechainsareheldtogetherinasingleunitby A) disulfidebridges. B) hydrogenbonds. C) saltbridges. D) aprostheticgroup. E) a-pleatedsheet. Answer: A 30) Hemoglobinisanexampleofaproteinwith A) primarystructureonly. B) twoproteinchainsheldtogether. C) aglobularstructure. D) primarilya-pleatedsheetstructure. E) primarilyan-helixstructure. Answer: C 31) Thehemeinhemoglobinisa(n) A) proteinchain. B) smallmoleculewithinaprotein. C) helixareainthehemoglobinmolecule. D) pleatedsheetareainthehemoglobinmolecule. E) oxygenmoleculewithinthehemoglobinmolecule. Answer: B 32) Withinhemoglobin,thehemefunctionsas A) adisulfidebridge. B) anoxygencarrier. C) areducingagent. D) ansubunit. E) oneofthefourproteinsubunits. Answer: B 33) Hemoglobinhasatotalof________proteinchainsinitsquaternarystructure. A) one B) two C) three D) four E) five Answer: D

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34) Woolisprimarilymadeupof A) protein. B) carbohydrate. C) globin. D) triacylglycerols. E) enkephalin. Answer: A 35) Thefunctionofmyoglobinisto A) carryvitaminsintheblood. B) carryoxygenintheblood. C) supporttheskeletalmuscles. D) carryoxygeninthemuscle. E) providestrengthincartilage. Answer: D 36) Insickle-cellanemia,thehemoglobinmolecules A) comeapartintoseparatechains. B) enlargetotwicenormalsize. C) clumptogetherintoinsolublefibers. D) dissolveintheplasma. E) undergocrenation. Answer: C 37) Denaturationofaprotein A) changestheprimarystructureofaprotein. B) disruptsthesecondary,tertiary,orquaternarystructureofaprotein. C) isalwaysirreversible. D) hydrolyzespeptidebonds. E) canonlyoccurinaproteinwithquaternarystructure. Answer: B 38) Oneheavymetalthatcancausedenaturationofaproteinis A) silver. B) sodium. C) barium. D) iron. E) calcium. Answer: A 39) Heavymetalsdenatureproteinsby A) releasingaminoacids. B) disruptinghydrophobicinteractions. C) changingthepHoftheproteinsolution. D) changingthetemperatureoftheproteinsolution. E) disruptingdisulfidebonds. Answer: E

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40) Anacidcandenatureaproteinby A) agitatingtheproteinchains. B) disruptinghydrogenbondsbetweensidechains. C) disruptinghydrophobicinteractionswithinaproteinchain. D) removinghelpingmoleculessuchasheme. E) breakingdisulfidebridges. Answer: B 41) Glycineistheonlynaturallyoccurringaminoacidthatis A) negativelycharged. B) positivelycharged. C) neutral. D) intheL-form. E) achiral. Answer: E 42) Inatypicalaminoacidzwitterion,thecarboxylicacidendis A) positivelycharged. B) negativelycharged. C) neutral. D) solubleinanonpolarsolvent. E) attachedtoanamine. Answer: B 43) Methionineisanaminoacidthatcontains A) asulfuratom. B) achlorineatom. C) asodiumatom. D) aphenylring. E) aheterocyclicring. Answer: A 44) Disulfidebondsinaproteinchainconnect A) anamineandacarboxylicacidgroup. B) analcoholandacarboxylicacidgroup. C) tryptophanandalanineresidues. D) twocysteineresidues. E) twoasparagineresidues. Answer: D 45) Thesidechainforhistidineisclassifiedasa________sidechain. A) basic B) neutral C) acidic D) nonpolar E) polar Answer: A

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46) AtapH>9,thezwitterionofglycinewillhave A) anetpositivecharge. B) anetnegativecharge. C) anoverallchargeofzero. D) lowsolubilityinwater. E) anegativechargeonthenitrogen. Answer: B 47) AtapH<5,thezwitterionforalanine(pI= 6)willhave A) anetpositivecharge. B) anetnegativecharge. C) anoverallchargeofzero. D) lowsolubilityinwater. E) anegativechargeonthecarboxylgroup. Answer: A 48) Whatisthestructuralformulaofglutamicacid(pI= 3.2)atpH= 1? A)

B)

C)

D)

E)

Answer: E

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49) Abasicaminoacidhasasidechainthatcontains A) anaminegroup. B) acarboxylgroup. C) amethylgroup. D) analcoholgroup. E) athiolgroup. Answer: A 50) Enkephalins,naturallyproducedopiatesinthebody,arefoundin A) musclesandbonetissue. B) brainandkidneytissue. C) thalamusandspinalcordtissue. D) heartandlungtissue. E) pancreasandlivertissue. Answer: C

19.2 BimodalQuestions
1) Immunoglobulin,aproteinthatstimulatesimmuneresponses,wouldbeclassifiedasa________protein. A) transport B) structural C) storage D) protection E) catalytic Answer: D 2) Inanenzyme,thepolypeptidechainfoldsintoacompactshapeknownasthe________structure. A) pleated B) primary C) secondary D) tertiary E) quaternary Answer: D 3) Whataminoacidshavepolarsidechainsthatareattractedtowater? A) hydrophilic B) hydrophobic C) nonpolar D) aromatic E) hydrocarbon Answer: A 4) AtwhatpHwouldyouexpectvaline,anaminoacidwithaneutralsidechain,tobeinthezwitterionicform? A) 1 B) 4 C) 7 D) 10 E) 14 Answer: C

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5) ConsidertheRgroupsofthefollowingaminoacids: cysteine:-CH2 SH;alanine:-CH3 ;serine:-CH2 OH Thenameforthedipeptideshownbelowis________. CH3 O CH2 OH NH2 C H- C -NH C HCOOH A) alanyl-cysteine B) alanyl-serine C) seryl-alanine D) seryl-cysteine E) serine-alanine Answer: B 6) Whatprocessoccurswhenheat,acids,bases,andheavymetalionscausealossofbiologicalfunctionofa protein? A) denaturation B) saponification C) hydrogenation D) amidation E) esterification Answer: A 7) Indigestion,proteinsarebrokendownintoaminoacidsbya(n)________reaction. A) saponification B) reduction C) hydrolysis D) oxidation E) denaturation Answer: C 8) Whentwoproteinchainscombinetoformanactiveprotein,thestructurallevelis________. A) pleated B) primary C) secondary D) tertiary E) quaternary Answer: E 9) Hydrophobicinteractionshelptostabilizethe________structure(s)ofaprotein. A) primary B) secondary C) secondaryandtertiary D) tertiaryandquaternary E) secondaryandquaternary Answer: D

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10) Thepeptidehormonethatregulatesuterinecontractionsduringlaboris________. A) oxytocin B) vasopressin C) myoglobin D) anendorphin E) anenkephalin Answer: A

19.3 ShortAnswerQuestions
1) Collagencanbeclassifiedasa________protein. Answer: structural 2) Theproteinthattransportsoxygeninthebloodis________. Answer: hemoglobin 3) Proteinsthatstimulateimmuneresponseareknownas________. Answer: immunoglobulins 4) Aminoacidsthatarenotsynthesizedinthebodybutmustbeingestedwiththedietarecalled________amino acids. Answer: essential 5) Allnaturallyoccurringaminoacidsinthehumanbodyarethe________enantiomers. Answer: L6) Azwitterionofanyaminoacidhasanetchargeof________. Answer: zero 7) TheisoelectricpointforanyaminoacidisthepHatwhichtheaminoacidhasanetchargeof________. Answer: zero 8) Electrophoresisisalaboratorytechniqueforseparatingaminoacidsusingtheirdifferent________. Answer: isoelectricpoints 9) Writethezwitterionofglycine. Answer:

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10) Circlethepeptidebondinthisstructure.

Answer:

19.4 MatchingQuestions
Identifythestructurallevelineachprotein. 1) Column1: Theproteinfoldsintoa compactstructurestabilized byinteractionsbetweenR groups. Column2: tertiary Answer: tertiary 2) Column1: thecombinationoftwoor moreproteinmoleculesto formanactiveprotein Column2: quaternary Answer: quaternary 3) Column1: pleatedsheet Column2: secondarystructure Answer: secondarystructure 4) Column1: thepeptidebondsbetweenthe aminoacids Column2: primarystructure Answer: primarystructure

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5) Column1: thestructurallevelachieved whenhydrogenbondsform betweenthecarboxylgroupof oneaminoacidandtheamino groupofadifferentamino acid Column2: secondarystructure Answer: secondarystructure Classifyeachproteinbyfunction. 6) Column1: trypsinforthehydrolysisof protein Column2: catalytic Answer: catalytic 7) Column1: lipoproteinsintheblood Column2: transport Answer: transport 8) Column1: collagenintendonsand cartilage Column2: structural Answer: structural 9) Column1: antibodies Column2: protection Answer: protection 10) Column1: actininmuscle Column2: contractile Answer: contractile Wouldanaminoacidwiththegivensidechainbemostlikelytobefoundinthehydrophobicorhydrophilicregionofaprotein? 11) Column1: -CH2 -CH-CH3 CH3 Column2: hydrophobic Foil: both Answer: hydrophobic

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12) Column1: -CH-CH3 OH Column2: hydrophilic Answer: hydrophilic 13) Column1: -CH3 Column2: hydrophobic Answer: hydrophobic 14) Column1: -CH2 CH2 SCH3 Column2: hydrophobic Answer: hydrophobic 15) Column1: O -CH2 - C -NH2

Column2: hydrophilic Answer: hydrophilic 16) Column1:

Column2: hydrophilic Answer: hydrophilic 17) Column1: -CH-CH2 -CH3 | CH3 Column2: hydrophobic Answer: hydrophobic 18) Column1:

Column2: hydrophobic Answer: hydrophobic Page270

Chapter20 EnzymesandVitamins 20.1 Multiple-ChoiceQuestions

1) Towhatmainclassofenzymesdoestheenzymethatcatalyzestheconversionoflactosetogalactoseand glucosebelong? A) oxidoreductase B) transferase C) hydrolase D) lyase E) isomerase Answer: C 2) Towhatmainclassofenzymesdoestheenzymethatcatalyzesthefollowingreactionbelong? O OH CH3 C COO- CH3 C HCOOA) oxidoreductase B) transferase C) hydrolase D) lyase E) isomerase Answer: A 3) Towhatmainclassofenzymesdoestheenzymethatcatalyzesthefollowingreactionbelong? ser-alaser+ala A) oxidoreductase B) transferase C) hydrolase D) lyase E) isomerase Answer: C 4) Comparedtoanuncatalyzedreaction,anenzyme -catalyzedreaction A) useslesssubstrate. B) producesdifferentproducts. C) occursatafasterrate. D) requiresmoreenergy. E) requiresahighertemperature. Answer: C 5) WhichofthefollowingisNOTastepintheenzyme-catalyzedconversionofasubstratetoproduct? A) Thesubstratechangesitsshapesoitcanbindattheactivesite. B) ThesubstratebindsintheactivesitetoformtheE-Scomplex. C) Theenzymeassistsintheconversionofthesubstratetoproduct. D) Theproductisreleasedfromtheactivesite. E) Anewsubstratemoleculebindstotheenzymeforanewcycle Answer: A

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6) Theformationofanenzyme-substratecomplexisthe________stepinenzymeaction. A) first B) second C) third D) fourth E) last Answer: A 7) Theactivesiteofanenzyme A) isremotefromthesiteofsubstrateattachment. B) isconvertedtoaproduct. C) catalyzesthereaction. D) increasestheenergyofreaction. E) includestheentireenzyme. Answer: C 8) Thewater-solubleBandCvitaminssupply A) essentialaminoacids. B) substratesnecessaryformostofthereactionsinthebody. C) essentialfattyacids. D) coenzymesrequiredbysomeenzymes. E) competitiveinhibitorsneededtoregulateenzymeactivity. Answer: D 9) Theoptimumtemperatureforsucraseactivityis37C.Thehydrolysisofsucroseisslowestatwhich temperatureinthechoicesbelow? A) 0C B) 10C C) 20C D) 25C E) 45C Answer: A 10) WhichofthefollowingisNOTtrueforacompetitiveinhibitor? A) Itoccupiestheactivesite. B) Itcannotbeconvertedtoproducts. C) Ithasastructuresimilartothesubstrate. D) Increasingthesubstrateconcentrationcanreversecompetitiveinhibition. E) Itbindstotheenzymeatasiteremotefromtheactivesite. Answer: E 11) Anoncompetitiveinhibitor A) bindsattheactivesiteoftheenzyme. B) altersthethree-dimensionalstructureoftheenzyme. C) increasestherateoftheenzyme-catalyzedreaction. D) hasastructuresimilartothesubstrate. E) hasitseffectreversedbyaddingmoresubstrate. Answer: B

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12) Thepurposeofthemanychemicalreactionsinourbodiesisto A) storechemicalenergyinthebodyforfutureuse. B) producetheessentialaminoacids. C) producetheessentiallipids. D) releasechemicalenergyfortheproductionofmacromolecules. E) Alloftheabove. Answer: E 13) Thegeneralfunctionofanenzymeinthebodyisto A) catalyzechemicalreactions. B) maintainaneutralpH. C) actasareactantincarbohydratestorage. D) maintainhomeostasis. E) eliminatewasteproductsfromtheblood. Answer: A 14) Theenzymesthatextractenergyfrombiomoleculesforourusearelocatedinthe A) plasma. B) cellmitochondria. C) lymph. D) urine. E) lipoproteins. Answer: B 15) MetalionssuchasZn2+andFe 3+areoftenneededbyenzymesas A) isozymes. B) allosteres. C) inhibitors. D) cofactors. E) substrates. Answer: D 16) Physiologicalconditionsforreactionswithinthebodyareapproximately A) pH3and37C. B) pH7and37C. C) pH7and37F. D) pH8and273C. E) pH7and273K. Answer: B 17) Thehydrolysisofesterbondsintriglyceridesiscatalyzedbya(n) A) lipase. B) lyase. C) isomerase. D) hydrolase. E) oxidoreductase. Answer: A

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18) Mostenzymesare A) fluid-mosaicproteins. B) inducedproteins. C) substrateproteins. D) fibrousproteins. E) globularproteins. Answer: E 19) Inanyreactioncatalyzedbyanenzyme,thereactingmoleculeiscalledthe A) substrate. B) cofactor. C) coenzyme. D) isozyme. E) allostere. Answer: A 20) Whenasubstancebondstoanenzymeforreaction,itsplaceofbindingisthe A) allostericsite. B) primarypocket. C) endpocket. D) primarysite. E) activesite. Answer: E 21) Substancesthatreactundertheinfluenceofanenzymeareusuallyheldtotheenzymeby A) peptidebonds. B) sidechainsofaminoacidsintheenzymeprotein. C) esterbonds. D) pHchanges. E) competitiveinhibition. Answer: B 22) Ureasecatalyzesonlythehydrolysisofurea,andnoothersubstrates.Thislimitedactivityiscalled A) absolutespecificity. B) extremespecificity. C) rigidspecifity. D) noncompetitivespecificity. E) hyperspecificity. Answer: A 23) Thepresenceofenzymestocatalyzebioreactionsinourbodiesallows A) ustoeatnon-nutritioussubstanceswithoutconsequence. B) theactivationenergyofareactiontoberaised. C) therateofadesiredchemicalreactiontoslowdown. D) bioreactionstooccurunderextremeconditionsoftemperatureandpH. E) bioreactionstotakeplaceundermildconditions. Answer: E

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24) PhysiologicalpH,thepHforoptimumactivityformostenzymes,isapHequalto A) 3.0. B) 5.4. C) 7.4. D) 8.6. E) 9.0. Answer: C 25) Hexokinasecatalyzesonlytheadditionofphosphatetoanyhexosesugar.Thistypeofactivityiscalled A) regionalspecificity. B) collateralspecificity. C) groupspecificity. D) noncompetitivespecificity. E) generalspecificity. Answer: C 26) Inthelock-and-keymodelofenzymeaction,theenzymeactivesiteisthoughtofas A) arigid,nonflexibleshapethatfitsthesubstrateexactly. B) anareaoftheenzymethatcanadjusttofitthesubstrateshape. C) akey-likeshapethatfitsintoapocketofthesubstratesurface. D) ahydrophilicareaontheenzymesurface. E) alockthatbarsanoncompetitiveinhibitorfromreacting. Answer: A 27) Intheinduced-fitmodelofenzymeaction,theenzymeactivesite A) staysthesameshapeduringsubstratebinding. B) adjustsshapetoadapttotheshapeofthesubstrate. C) staysthesameshapewhilecausingachangeintheshapeofthesubstrate. D) usesaninhibitortoadjustitsshapeforthesubstrate. E) usesacofactortochangetheshapeofasubstrate. Answer: B 28) Thefunctionoftheenzyme-substratecomplexistoprovideanalternativereactionpathwaythat A) lowerstheenergyoftheproducts. B) lowerstheenergyofthesubstrate. C) changestheconcentrationofthesubstrate. D) decreasestheactivationenergyforthereaction. E) changesthepossibleproductformed. Answer: D 29) Howmanygeneralizedstepsarethereinthereactionofanenzyme(E)withasubstrate(S)toformandrelease theproduct(P)? A) one B) two C) three D) four E) five Answer: B

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30) AnincreaseinconcentrationoftheenzymeLDHinthebloodcanbeusedtodetect A) heartattack. B) kidneydamage. C) anemia. D) uremia. E) bulimia. Answer: A 31) Creatinekinasecanbeusedinthediagnosisof A) hepatitis. B) rickets. C) heartattack. D) prostatitis. E) cancer. Answer: C 32) Mostenzymesaredeactivatedpermanentlyaboveatemperatureofabout A) 25C. B) 37F. C) 40C. D) 45F. E) 50C. Answer: E 33) Thesurfaceofafreshlycutappleturnsbrownbecauseof A) inhibitionofthesurfaceenzymesbynitrogen. B) interactionofthesurfaceenzymeswithoxygen. C) achangeinpHatthesurface. D) anincreaseinsubstrateconcentrationatthecutsurface. E) thepresenceofvitaminCintheapple. Answer: B 34) Inanenzyme-substratereaction,whenexcesssubstrateispresent,increasingtheconcentrationoftheenzyme will A) increasethenumberofsubstratemoleculesavailable. B) inhibittheformationofproducts. C) increasethedecompositionrateoftheenzyme-substratecomplex. D) decreasetheturnoverrateforthesubstrate. E) increasetheamountofreactionoccurring. Answer: E 35) Consideranenzymaticreactioninwhichtheinitialconcentrationofsubstrateislow.Iftheamountofenzyme isheldconstant,buttheamountofsubstrateisincreased,therateofanenzymecatalyzedreactionwill A) increaseinanexponentialfashion. B) decreaseatfirst,thenincreaseinalinearfashion. C) increaseatfirstinalinearfashion,thenremainataconstanthighrate. D) staythesame. E) beinhibitedbythehigherconcentrationsofsubstrate. Answer: C

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36) Ureaisconvertedtoammoniaandcarbondioxidebytheactionofurease.Whatwillbetheeffectontherateif thetemperatureofthereactionisloweredfrom37C(theoptimumtemperature)to27C? O urease 2NH3 +CO 2 NH2 - C -NH2 +H2 O A) Therewillbenoeffect. B) Theratewillslowdown. C) Theratewilldouble. D) Theratewilltriple. E) Theratewillslowdown,thenspeedupagain. Answer: B 37) Acompetitiveinhibitorisonethat A) bindstotheenzymeatasitefarfromtheactivesite. B) bindstotheactivesiteinplaceofthesubstrate. C) destroysthesubstrate. D) bindstotheallostericsiteonanenzyme. E) formsacomplexwiththesubstrate. Answer: B 38) Anirreversibleinhibitorisonethat A) formshydrogenbondswiththesubstrate. B) bindstotheenzymewithhydrophobicinteractions. C) reactscovalentlywiththesubstrate. D) bindscovalentlytotheenzymeactivesite. E) reactscovalentlywithacofactor. Answer: D 39) Anoncompetitiveinhibitorhasastructurethat A) doesnotresemblethesubstratestructure. B) resemblestheactivesiteoftheenzyme. C) canbindtotheactivesiteoftheenzyme. D) doesnotinterferewiththeenzyme-substratecomplexformation. E) causesachangeintheshapeofthesubstrate. Answer: A 40) Penicillinfunctionsasanantibioticby A) poisoningbacteriawithtoxins. B) raisingthetemperatureofabacterium. C) bondingtometalionsinbacterialelectrontransportsystems. D) inhibitingtheenzymesforcellwallformationinbacteria. E) actingasanacetylcholinesteraseinhibitor. Answer: D 41) Acompoundthatbindstothesurfaceofanenzyme,andchangesitsshapesothatasubstratecannotenterthe activesite,iscalleda(n) A) irreversibleinhibitor. B) proenzyme. C) cofactor. D) noncompetitiveinhibitor. E) competitiveinhibitor. Answer: D Page277

42) Someinsecticideskillinsectsbyinhibitingtheenzyme A) alcoholdehydrogenase. B) acetylcholinesterase. C) creatinekinase. D) lipase. E) penicillinase. Answer: B 43) Penicillin-resistantbacteriacansurvivetreatmentwithpenicillinbecausetheyproducetheenzyme A) sucrase. B) penicillinkinase. C) penicillinase. D) bacteriase. E) phosphatelyase. Answer: C 44) Pepsinogenisanexampleofa(n) A) coenzyme. B) cofactor. C) isoenzyme. D) allostericenzyme. E) zymogen. Answer: E 45) Whenanendproductfromanenzyme-mediatedsequenceisalsoaninhibitorforanearlierstepinthereaction sequence,theprocessisreferredtoas A) feedbackcontrol. B) competitiveinhibition. C) irreversibleinhibition. D) negativecatalysis. E) concentrationcontrol. Answer: A 46) Allostericenzymescancontroltheiroutputofproductby A) bindingthesubstrateatasiteawayfromtheactivesite. B) bindinganirreversibleinhibitorattheactivesite. C) bindingapositiveornegativeregulatoratanoncompetitivesite. D) changingthepHintheactivesite. E) reversibleinhibitionusingtheproductastheinhibitor. Answer: C 47) Whenacofactorisasmallorganicmolecule,itisknownasa(n) A) isoenzyme. B) vitamin. C) zymogen. D) coenzyme. E) regulator. Answer: D

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48) Iron(II)andiron(III)ionsareusedinthefunctioningof A) urease. B) alcoholdehydrogenase. C) creatinekinase. D) thecytochromeoxidasesystem. E) pepsin. Answer: D 49) TheBvitaminsareexamplesof A) water-solublevitamins. B) essentialaminoacids. C) essentialminerals. D) oilsolublevitamins. E) vitaminsthatarestoredintheliver. Answer: A 50) Coenzymessuchaswater-solublevitaminsareneededinonlysmallamountsbecause A) onlysmallamountsofenzymesarepresentineachcell. B) onlysmallamountsofsubstratesareavailableatanyonetime. C) theycanbeeliminatedintheurine. D) eachvitaminmoleculecanbereusedmanytimesasacofactor. E) theycanbestoredintheliverforfutureuse. Answer: D

20.2 BimodalQuestions
1) Abiologicalcatalystiscalleda(n)________. A) lipid B) enzyme C) cofactor D) coenzyme E) substrate Answer: B 2) Anothernameforazymogenisa(n)________. A) cofactor B) coenzyme C) prostheticgroup D) isozyme E) proenzyme Answer: E 3) ThefullnameoftheenzymeLDHis________. A) lactatedehydrogenase B) liverdecompensationhexase C) lactatedehydrase D) liverdihydrogenkinase E) lipasedehydrogenase Answer: A

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4) Thenamesofmanyenzymescanberecognizedbythesuffix________. A) -ate B) -ite C) -ose D) -ine E) -ase Answer: E 5) Anenzymethatconvertsacisdoublebondtoatransdoublebondisclassifiedasa(n)________. A) oxidoreductase B) transferase C) hydrolase D) lyase E) isomerase Answer: E 6) Enzymesthatcatalyzethesamereactionsbuthaveslightlydifferentstructuresarecalled________. A) coenzymes B) cofactors C) isoenzymes D) competitive E) noncompetitive Answer: C 7) Differentformsofanenzymethatcatalyzethesamereactionindifferenttissuesarecalled________. A) isomers B) allosteres C) coenzymes D) prozymes E) isoenzymes Answer: E 8) TheoptimumpHfortheactivityofpepsinisabout________. A) 2.0 B) 4.0 C) 6.5 D) 7.4 E) 7.6 Answer: A 9) OnedeficiencydiseasethatcanbetracedtoinsufficientintakeofvitaminDis________. A) scurvy B) rickets C) beriberi D) pellagra E) perniciousanemia Answer: B

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10) AdietverylowinvitaminCcanleadovertimetothecondition________. A) rickets B) scurvy C) cancer D) carpaltunnelsyndrome E) anorexianervosa Answer: B

20.3 ShortAnswerQuestions
1) vitaminB6 Answer: watersoluble 2) vitaminA Answer: fatsoluble 3) pantothenicacid Answer: watersoluble 4) ascorbicacid Answer: watersoluble 5) vitaminE Answer: fatsoluble 6) vitaminK Answer: fatsoluble 7) niacin Answer: watersoluble 8) folicacid Answer: watersoluble 9) vitaminD Answer: fatsoluble 10) riboflavin Answer: watersoluble

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20.4 MatchingQuestions
Identifyeachofthedesignatedregionsontheenergydiagramfortheconversionofasubstratetoproductwithandwithoutanenzyme.

1) energyofthesubstrate Answer: A 2) energyoftheproduct Answer: D 3) activationenergywithouttheenzyme Answer: B 4) activationenergywiththeenzyme Answer: C Matchthecorrectterminenzymeactionwitheachdescription. 5) Column1: thetemporarycombinationof anenzymewiththe compoundonwhichitacts Column2: enzyme-substratecomplex Answer: enzyme-substratecomplex 6) Column1: anorganiccompoundthatis sometimesneededtocomplete anenzyme Column2: coenzyme Answer: coenzyme

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7) Column1: theportionofanenzyme moleculewherecatalytic activityoccurs Column2: activesite Answer: activesite 8) Column1: aninorganicsubstancesuchas Mg 2+ requiredbysome enzymesforactivity Column2: cofactor Answer: cofactor 9) Column1: onetheorythataccountsfor theunusualspecificityofan enzyme Column2: lock-and-keytheory Answer: lock-and-keytheory Identifytheeffectofthefollowingontheactivityofmaltase,anenzymethathydrolyzesmaltose. 10) Column1: decreasingtheconcentration ofmaltose Column2: decreases Foil: hasnoeffect Answer: decreases 11) Column1: adjustingthetemperatureto theoptimumtemperature Column2: increases Answer: increases 12) Column1: raisingthepHto11.0 Column2: decreases Answer: decreases 13) Column1: increasingtheconcentrationof maltase(enzyme)whenthe enzymeissaturatedwith substrate Column2: increases Answer: increases 14) Column1: loweringthepHto1.0 Column2: decreases Answer: decreases

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Identifythetypeofinhibitionineachdescription. 15) Column1: aninhibitorthatresemblesthe structureofthesubstrate Column2: competitive Answer: competitive 16) Column1: aninhibitorthatformsa covalentbondwithaside chainintheactivesite Column2: competitive Answer: competitive 17) Column1: addingmoresubstratedoes notreversetheeffectofthis inhibitor. Column2: noncompetitive Answer: noncompetitive 18) Column1: Theinhibitioncanbereversed byincreasingthe concentrationofsubstrate. Column2: competitive Answer: competitive 19) Column1: Theinhibitordoesnot resemblethesubstrate. Column2: noncompetitive Answer: noncompetitive Matchthevitaminnamewithitscorrespondingchemicalname. 20) Column1: vitaminB3 Column2: niacin Foil: cholecalciferol Answer: niacin 21) Column1: vitaminB2 Column2: riboflavin Answer: riboflavin 22) Column1: vitaminB1 Column2: thiaminepyrophosphate Answer: thiaminepyrophosphate

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23) Column1: vitaminC Column2: ascorbicacid Answer: ascorbicacid 24) Column1: vitaminB12 Column2: cobalamin Answer: cobalamin 25) Column1: vitaminB6 Column2: pyridoxine Answer: pyridoxine

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Chapter21 NucleicAcidsandProteinSynthesis 21.1 Multiple-ChoiceQuestions

1) A________consistsofanitrogen-containingbaseandasugar. A) nucleoside B) basepair C) nucleotide D) complementarybase E) pyrimidine Answer: A 2) A________consistsofanitrogen-containingbase,asugar,andaphosphategroup. A) nucleoside B) basepair C) nucleotide D) complementarybase E) purine Answer: C 3) WhichofthefollowingcanNOTbefoundinanucleotideofRNA? A) purine B) pyrimidine C) phosphate D) ribose E) deoxyribose Answer: E 4) WhichofthefollowingisfoundinRNAbutnotinDNA? A) thymine B) uracil C) guanine D) cytosine E) deoxyribose Answer: B 5) WhichofthefollowingwillnotbefoundinDNA? A) adenine B) thymine C) guanine D) cytosine E) ribose Answer: E 6) WhichofthefollowingcanbefoundinDNA? A) ribose B) GMP C) uracil D) deoxyadenosine E) FMN Answer: D

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7) ThenucleotidesinthebackboneofDNAareheldtogetherby________bonds. A) hydrogen B) peptide C) phosphodiester D) glycosidic E) ionic Answer: C 8) ThebondsthatlinkthebasepairsintheDNAdoublehelixare A) ionicbonds. B) peptidebonds. C) hydrogenbonds. D) hydrophobicbonds. E) esterbonds. Answer: C 9) ThebasesequenceofthestrandofDNAcomplementarytothesegment 5-T-G-G-C-A-A-C-3is: A) 3-T-G-G-C-A-A-C-5 B) 3-A-C-C-G-T-T-G-5 C) 3-A-C-C-G-U-U-G-5 D) 3-U-C-C-G-T-T-G-5 E) 3-A-C-G-C-T-U-G-5 Answer: B 10) WhichofthefollowingisnotastepinDNAreplication? A) Hydrogenbondsbreak,allowingthetwoDNAstrandstoseparatecompletely. B) AbaseontheDNApairswithitscomplementarybasefreeinsolution. C) DNApolymeraseformsbondsbetweena5-phosphateofonenucleotideanda3-hydroxylofanother. D) OnonestrandtheDNAissynthesizedcontinuously. E) DNAligaseconnectsshortsegmentsofDNAononestrand. Answer: A 11) ThetwonewDNAmoleculesformedinreplication A) arecomplementarytotheoriginalDNA. B) bothcontainonlytwonewdaughterDNAstrands. C) bothcontainonlytheparentDNAstrands. D) containoneparentandonedaughterstrand. E) areidentical,withonecontainingbothparentstrands,andtheothercontainingbothdaughterstrands. Answer: D 12) WhatistheprocessinwhichtheDNAdoublehelixunfolds,andeachstrandservesasatemplateforthe synthesisofanewstrand? A) transcription B) complementation C) translation D) replication E) restriction Answer: D

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13) WhenDNAduplicatesitself,thecorrectplacementofthenucleotidesisaccomplishedby A) complementarybasepairing. B) polymerase. C) enzymematching. D) basematching. E) transcription. Answer: A 14) WhenDNAreplicates,aguanineformsabasepairwith A) uracil. B) adenine. C) guanine. D) thymine. E) cytosine. Answer: E 15) WhichofthefollowingtypesofRNAcarriesthegeneticinformationfromDNAinthenucleustothecytoplasm forproteinsynthesis? A) mRNA B) histoneRNA C) rRNA D) tRNA E) sRNA Answer: A 16) Translationistheprocesswhereby A) DNAissynthesizedfromDNA. B) DNAissynthesizedfrommRNA. C) proteinissynthesizedfromDNA. D) proteinissynthesizedfrommRNA. E) mRNAissynthesizedfromDNA. Answer: D 17) Intranscription A) themRNAproducedisidenticaltotheparentDNA. B) adoublehelixcontainingoneparentstrandandonedaughterstrandisproduced. C) uracilpairswiththymine. D) bothstrandsoftheDNAarecopied. E) themRNAproducediscomplementarytoonestrandoftheDNA. Answer: E 18) WhichofthefollowingisasectionofmRNAproducedfromtheDNAtemplatebelow? 3-A-T-A-G-C-T-A-5 A) 5-A-T-A-G-C-T-A-3 B) 5-A-U-A-G-C-U-A-3 C) 5-U-A-U-C-G-A-U-3 D) 5-U-U-U-G-C-U-U-3 E) 5-T-A-T-C-G-A-T-3 Answer: C

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19) WhichoneofthefollowingbasepairsisfoundinDNA? A) adenine-thymine B) adenine-guanine C) cytosine-thymine D) adenine-uracil E) guanine-uracil Answer: A 20) WhichoneofthesebasepairsisfoundinRNA? A) guanine-cytosine B) adenine-cytosine C) adenine-thymine D) adenine-guanine E) guanine-thymine Answer: A 21) InthesynthesisofmRNA,anadenineintheDNApairswith A) uracil. B) adenine. C) guanine. D) thymine. E) cytosine. Answer: A 22) ADNAtemplatehavingthebasesequence3 -A-G-A-T-G-A-5wouldproduceamRNAwithabase sequenceof A) 5-A-G-A-T-G-A-3. B) 5-U-C-U-A-C-U-3. C) 5-T-C-T-U-C-T-3. D) 5-T-C-T-A-C-A-3. E) 5-A-C-A-U-C-A-3. Answer: B 23) Codonsarebasepairsequencesthat A) signalthestartofDNAsynthesis. B) signaltheendofDNAsynthesis. C) codeforaminoacids. D) signalthestartofRNAsynthesis. E) codeforoneormorebasesinmRNA. Answer: C 24) WhenmRNAissynthesizedusingtheinformationfromDNA,theprocessiscalled A) transportation. B) transposition. C) transcription. D) translation. E) transliteration. Answer: C

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25) Whichofthefollowingisnotastepinproteinsynthesis? A) activationoftRNA B) initiation C) elongation D) termination E) unwindingoftwostrandsofmRNA Answer: E 26) Thecodonisfoundon________,andtheanticodonisfoundon________. A) mRNA;tRNA B) tRNA;mRNA C) rRNA;tRNA D) ribosomes;tRNA E) mRNA;rRNA Answer: A 27) Theanticodonis A) identicaltothecodononDNA. B) complementarytothecodononDNA. C) identicaltothecodononmRNA. D) complementarytothecodononmRNA. E) complementarytothecodonontRNA. Answer: D 28) AtRNAisactivatedwhenit A) attachestomRNA. B) attachestoitsspecificaminoacid. C) attachestotheribosome. D) leavestheribosome. E) releasesitsspecificaminoacid. Answer: B 29) Duringproteinsynthesis,thecodonforanaminoacidisfoundon A) DNA. B) rRNA. C) tRNA. D) mRNA. E) sRNA. Answer: D 30) TheanticodonofU-A-Gis A) A-T-C. B) U-A-G. C) A-A-C. D) A-U-C. E) G-A-U. Answer: D

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31) WhichofthefollowingisusedinthepreparationofrecombinantDNA? A) RNApolymerase B) DNApolymerase C) repressorprotein D) restrictionenzyme E) enzymeinduction Answer: D 32) TheinsertionofnewDNAintotheplasmidDNAofabacteriumproduces A) viralDNA. B) DNAfingerprints. C) recombinantDNA. D) ribosomes. E) restrictionenzymes. Answer: C 33) Thepolymerasechainreactionisusedin A) preparingrecombinantDNA. B) transcription. C) DNAfingerprinting. D) translation. E) replication. Answer: C 34) Mutationsaretheresultof A) alterationsinthephosphateoftheDNAbackbone. B) exposuretowaterinutero. C) physicaltraumainthemotherschildhood. D) alterationsinthesugarcomponentoftheDNAbackbone. E) alterationsintheDNAbasesequence. Answer: E 35) TheresultofadefectiveenzymecausedbyamutationintheDNAnucleotidesequenceis A) ageneticdisease. B) AIDS. C) HIV. D) recombinantDNA. E) translocation. Answer: A 36) AsetofdirectionsintheDNAbasesequenceforthesynthesisofaproteinisa(n) A) structuralgene. B) promotor. C) operator. D) codon. E) regulatorygene. Answer: A

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37) Intheenzymeinductionmodelofcellularcontrol, A) cofactorscontrolproteinsynthesis. B) thesubstratecontrolsproteinsynthesis. C) thesubstratecombineswithaproteintoformarepressor. D) theenzymeforthesubstrateisalwayssynthesizedbythegene. E) thesubstraterepressestheoperator. Answer: B 38) Smalllivingparticles,with3to200genes,thatcannotreplicatewithoutahostcellarecalled A) recombinantDNAs. B) viruses. C) bacteria. D) tumors. E) plasmids. Answer: B 39) AvirusthatcontainsRNAasitsgeneticmaterialisa A) geneticallyengineeredvirus. B) bacteria. C) recombinantDNA. D) retrovirus. E) vaccine. Answer: D 40) Proteaseinhibitors,whichareeffectiveanti-HIVdrugs, A) arenucleosideanalogs. B) preventreversetranscription. C) preventsynthesisofviralproteins. D) preventmRNAsynthesis. E) preventactivationoftRNA. Answer: C 41) SomesectionsofaDNAmoleculedonotcodeforproteinsynthesis.Thesesegmentsarecalled A) codons. B) anticodons. C) Okazakifragments. D) introns. E) exons. Answer: D 42) Guanineisoneexampleofanitrogenbasethatisa A) cofactor. B) 5-carbonsugar. C) phosphodiester. D) pyrimidine. E) purine. Answer: E

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43) ThetwostrandsofthedoublehelixofDNAareheldtogetherby A) hydrogenbonds. B) covalentbonds. C) dipole-dipoleinteractions. D) ionicbonds. E) sugar-to-phosphatebonds. Answer: A 44) Arestrictionenzymefunctionsto A) preventtheDNAfromleavingthenucleus. B) limitthenumberofreplicationsaDNAmoleculecanachieve. C) cutalargeDNAdoublehelixintosmallerfragments. D) stoptheelongationstepofproteinsynthesis. E) eliminateavirusfromacell. Answer: C 45) WhenamutationoccursbyeliminationofonebaseinaDNAsequence,thismutationiscalleda A) frame-shiftmutation. B) retrovirusinsertion. C) substitutionmutation. D) translocationmutation. E) viralmutation. Answer: A 46) Inthestudyofgenetics,theabbreviationPCRrefersto A) purinechainrepression. B) pyrimidinecomplementrestriction. C) purinecodedribose. D) proteincombinationandreplication. E) polymerasechainreaction. Answer: E 47) RecombinantDNAtechnologyrequirestheuseofbacterial A) plasmids. B) mitochondria. C) endoplasmicreticulum. D) ribosomes. E) cellwalls. Answer: A 48) OnetherapeuticproductnowavailableduetorecombinantDNAtechnologyis A) measlesvaccine. B) penicillin. C) humangrowthhormone. D) sulfamethoxazole. E) tamoxifen. Answer: C

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49) DNAfingerprintinguses________toproduceDNAfragmentsthatcanbeseparatedandscreenedforthe presenceofgeneticdiseases. A) extracellularDNA B) restrictionenzymes C) bacterialplasmids D) anticodons E) codons Answer: B 50) Thepurposeofthehumangenomeprojectwasto A) identifygenesresponsiblefornoninheritablediseases. B) determinehowtoclonehumanDNA. C) identifysubstratesforthepolymerasechainreaction. D) learnhowtoclonebacterialDNA. E) mapthelocationsofallthegenesinhumanDNA. Answer: E

21.2 True/FalseQuestions
1) Adenineisapurine. Answer: TRUE 2) Uracilisapyrimidine. Answer: TRUE 3) AZTisadrugusedinthetreatmentofcancer. Answer: FALSE 4) HumanDNAcontainsmanynucleotidesthatarenotusedingenes. Answer: TRUE 5) HumaninsulincanbemadewiththeuseofrecominantDNAtechnology. Answer: TRUE 6) AretrovirususesDNAasitsgeneticmaterial. Answer: FALSE 7) DNAfingerprintingisnotyetbeusedtodetectgenesforcancersusceptibility. Answer: FALSE 8) Anucleotideconsistsofonlyabaseandasugar. Answer: FALSE 9) Downsyndromeisanacquireddisease,notageneticdisease. Answer: FALSE 10) MessengerRNAcarriesproteinsynthesisinformationfromthenucleustothemitochondrion. Answer: TRUE 11) TheDNAcomplementofthesequence5-GCCAT-3 is3-GCCAT-5. Answer: FALSE 12) DNAisaprotein. Answer: FALSE

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13) RNAcontainsnophosphate. Answer: FALSE 14) DNAdiffersfromRNAinthesugaritcontains. Answer: TRUE 15) IntheDNAdoublehelix,apurinecanonlybondwithapyrimidine. Answer: TRUE

21.3 MatchingQuestions
Matchthefollowing. 1) Column1: picksupthespecificamino acidsforproteinsynthesis Column2: tRNA Answer: tRNA 2) Column1: synthesizedbytheDNAto carrythegeneticmessageto theribosomes Column2: mRNA Answer: mRNA 3) Column1: containswithinthenucleusof thecelltheinformationforthe synthesisofprotein Column2: DNA Answer: DNA 4) Column1: thenucleicacidthatcontains thecodonsfortheaminoacids ofaprotein Column2: mRNA Answer: mRNA 5) Column1: themostabundantnucleic acidintheribosomes Column2: rRNA Answer: rRNA 6) Column1: thenucleicacidthatcontainsa singleanticodonforaspecific aminoacid Column2: tRNA Answer: tRNA

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Matchthecorrecttermwiththestatement. 7) Column1: theportionofagenethatturns thesynthesisofaspecific mRNAonoroff Column2: operator Answer: operator 8) Column1: agroupofgeneswhose transcriptioniscontrolledby thesameregulatorygene Column2: operon Answer: operon 9) Column1: theportionofthecontrolsite thatregulatesDNAsynthesis Column2: promotor Answer: promotor 10) Column1: aproteinthatinteractswith theoperatorgenetoprevent mRNAsynthesis Column2: repressor Answer: repressor 11) Column1: thatportionofthegenethat, whenrepressed,prevents mRNAsynthesis Column2: operator Answer: operator Matchthetypeofcellularcontrolwiththedescription. 12) Column1: Thesubstrateinducesthe synthesisofitsownmetabolic enzymes. Column2: enzymeinduction Answer: enzymeinduction 13) Column1: Theendproductofareaction combineswiththeregulatorto producearepressormolecule thatturnsofftheoperator gene. Column2: enzymerepression Answer: enzymerepression

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14) Column1: Whensubstrateispresentin thecell,thestructuralgene producesmRNAforenzyme synthesis. Column2: enzymeinduction Answer: enzymeinduction 15) Column1: Theendproductofareaction pathwaycontrolsprotein synthesis. Column2: enzymerepression Answer: enzymerepression 16) Column1: Thesubstrateofareaction pathwaycontrolsprotein synthesis. Column2: enzymeinduction Answer: enzymeinduction

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Chapter22 MetabolicPathwaysforCarbohydrates 22.1 Multiple-ChoiceQuestions

1) Whichofthefollowingistrueforprokaryoticcells? A) Theyaremorecomplexthaneukaryoticcells. B) Theyarelargerthaneukaryoticcells. C) Theycontainmitochondria. D) Theyarefoundinanimals. E) Theydonotcontainanucleus. Answer: E 2) Acompoundthatisformedinametabolicoxidationiscalleda(n) A) product. B) enzyme. C) metabolite. D) food. E) cofactor. Answer: C 3) WhichofthefollowingdoesnotrequireenergyfromATPhydrolysis? A) digestion B) musclecontraction C) transportacrosscellmembranes D) sendingnervesignals E) synthesisofanenzyme Answer: A 4) Whichcoenzymeistheelectronacceptorinthefollowingreaction? H H | | - C - C --C=C| | | | A) FAD B) NAD+ C) FMN D) NADH E) FADH2 Answer: A

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5) Whichcoenzymeistheelectronacceptorinthefollowingreaction? OH O | - C -- C | H A) FAD B) NAD+ C) FMN D) NADH E) FADH2 Answer: B 6) Whichofthefollowingmetabolicpathwayscanoccurintheabsenceofoxygen? A) electrontransport B) oxidativephosphorylation C) citricacidcycle D) glycolysis E) -oxidation Answer: D 7) Instep7ofglycolysis,ATPisgeneratedwhenaphosphategroupistransferreddirectlyfrom 1,3-diphosphoglyceratetoADPinaprocessknownas A) oxidation. B) substratelevelphosphorylation. C) reduction. D) transamination. E) oxidativephosphorylation. Answer: B 8) Thecompoundsformedwhenfructose-1,6-diphosphateissplitare A) pyruvicacidandlacticacid. B) ethanolandacetylCoA. C) dihydroxyacetonephosphateandpyruvicacid. D) dihydroxyacetonephosphateandglyceraldehyde3-phosphate. E) glyceraldehyde3-phosphateandpyruvicacid. Answer: D 9) Whenoneglucosemoleculeundergoesglycolysisitgenerates A) 6ATP. B) 6ATPand2NADH. C) 2ATPand2NADH. D) 2ATPand4NADH. E) 12ATP. Answer: C

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10) Theprocessbywhichcomplexmoleculesarebrokendownintosimpleronesforthebodysuseiscalled A) metabolism. B) catabolism. C) anabolism. D) glucogenesis. E) gluconeogenesis. Answer: B 11) Theprocessofbuildingupnewmoleculesinthecelliscalled A) metabolism. B) catabolism. C) anabolism. D) glycolysis. E) transamination. Answer: C 12) Overall,catabolicreactions A) releaseenergy. B) takeinenergy. C) occurmainlyintheliver. D) occuroutsidethecellmembrane. E) takeplaceinthenucleusofthecell. Answer: A 13) Anabolicreactionsarereactionsthat A) useoxidationbutnotreduction. B) breakdownlargemoleculesintosmallerones. C) takeplaceinthemitochondria. D) useenergy. E) giveoffenergy. Answer: D 14) Howmanymainstagesofcatabolismarethere? A) one B) two C) three D) four E) five Answer: C 15) Thefirststageofcatabolismis A) thecitricacidcycle. B) productionofpyruvate. C) productionofacetylCoA. D) buildupofmacromoleculesfrommonomers. E) digestionoflargemolecules. Answer: E

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16) Themiddlestageofcatabolismisthepointatwhich A) acetylCoAisproduced. B) monomersareproducedfrommacromolecules. C) macromoleculesaremadefrommonomers. D) glycogenisconvertedtoglucose. E) excessnutrientsarestoredasfats. Answer: A 17) Proteinsynthesistakesplace A) inthemitochondria. B) ontheendoplasmicreticulum. C) inthenucleus. D) ontheribosomes. E) inthecytosol. Answer: D 18) Thesynthesisofglycogencanbeclassifiedasa(n) A) catabolicreaction. B) anabolicreaction. C) digestionreaction. D) phosphorylationreaction. E) -oxidationreaction. Answer: B 19) Themaincompoundusedtoreleaseenergyformetabolismis A) sucrose. B) glucosephosphate. C) adenosinetriphosphate. D) ribonucleicacid. E) NAD+ . Answer: C 20) ThecomponentsofATPare A) adenosine,ribose,andtriphosphate. B) anilineandtriphosphate. C) alanine,ribose,andtriphosphate. D) adenine,ribose,andtriphosphate. E) adenosine,deoxyribose,andtriphosphate. Answer: D 21) ThehydrolysisofATPtoADPis A) endothermic. B) exothermic. C) isothermic. D) anoxidation. E) areduction. Answer: B

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22) ThesymbolPistandsfor A) inorganicphosphate. B) inertpyrophosphate. C) insolublephosphate. D) isomersofphosphate. E) irreversiblephosphorylation. Answer: A 23) ThereleaseofpyrophosphatefromATPtogiveAMPandPP i,followedbythehydrolysisofthe pyrophosphate,releasesapproximatelythesameamountofenergyas A) sucrosebreakdown. B) proteindigestion. C) glucoseoxidation. D) glycogenproduction. E) ATPADP+Pi Answer: E 24) ThereactionofglucosewithATPtoproduceADPandglucose -6-phosphateisanexampleofa(n) A) endothermicreaction. B) coupledreaction. C) decompositionreaction. D) oxidationreaction. E) reductionreaction. Answer: B 25) Musclecontractionrequires A) copperionandATP. B) iron. C) calciumionandATP. D) lipidhydrolysis. E) carbondioxide. Answer: C 26) Musclecontractionisanexampleofa(n) A) anabolicprocess. B) catabolicprocess. C) glucosestorageprocess. D) proteindegradationprocess. E) lipidhydrolysisprocess. Answer: B 27) Thefinalproductsofcatabolicreactionsare A) carbondioxide,water,andammonia. B) glucose,lipids,andglycogen. C) lipids,oxygen,andwater. D) RNAandDNA. E) lipidsandcarbohydrates. Answer: A

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28) Inbiochemicalsystems,thetermreduction oftenrefersto A) alossofhydrogenorelectronsbyacompound. B) againofhydrogenorelectronsbyacompound. C) againinoxygen. D) alossofelectrons. E) anenergy-releasingreaction. Answer: B 29) NAD+ standsforthecoenzyme A) niacinadeninedinucleotide. B) nicotinicaciddiphosphate. C) nicotinamidediphosphate. D) nicotineadenosinedinucleotide. E) nicotinamideadeninedinucleotide. Answer: E 30) NAD+ participatesinreactionsthatproduce A) aCH2 group. B) aC=Obond. C) phosphorylation. D) ADPfromATP. E) aC-Cbond. Answer: B 31) FADstandsfor A) flavinadenosinedinucleotide. B) folicaciddiphosphate. C) fumaratealcoholdehydrogenase. D) folateadenosinediphosphate. E) flavinadeninedinucleotide. Answer: E 32) FADisacoenzymewhichusuallyparticipatesin A) oxidationofalcoholstoaldehydes. B) formationofcarbon-carbondoublebonds. C) decarboxylationreactions. D) phosphorylationreactions. E) -oxidationreactions. Answer: B 33) CoenzymeAisamoleculewhosefunctionisto A) activateenzymeA. B) undergophosphorylation. C) provideenergyforthecitricacidcycle. D) activateacylgroupsforreaction. E) helpbreakdownmacromolecules. Answer: D

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34) Anacylgroupcontainsatleast________carbonatom(s). A) one B) two C) three D) four E) five Answer: B 35) TheportionofCoenzymeAthatreactswithpotentialsubstratesis A) anacidgroup. B) anaminogroup. C) aC=Ogroup. D) analcoholgroup. E) athiolgroup. Answer: E 36) Digestionofcarbohydratesbeginsinthe A) mouth. B) stomach. C) pancreas. D) smallintestine. E) largeintestine. Answer: A 37) Anenzymethatcanfacilitatethebreakdownofstarchintosmallerunitsis A) glucosephosphatase. B) alcoholdehydrogenase. C) amylase. D) lactase. E) maltase. Answer: C 38) Lactoseintoleranceoccursdueto A) anexcessofgalactoseintake. B) adeficiencyof-galactosidase. C) adeficiencyoflactase. D) anoverabundanceofglucose. E) overproductionofamylase. Answer: C 39) Glycolysisisa(n)________process. A) aerobic B) anaerobic C) anabolic D) one-step E) five-step Answer: B

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40) Intheprocessofglycolysis,glucoseisconvertedto A) pyruvate. B) citrate. C) sucrose. D) oxaloacetate. E) ribose. Answer: A 41) Theoverallprocessofglycolysis A) requiresoxygen. B) usesup4ATPmolecules. C) requiresacetylCoA. D) isananabolicpathway. E) produces2ATPmolecules. Answer: E 42) Theprocessofglycolysisisregulatedby A) cellrequirementsforpyruvate. B) allostericcontrol. C) ATPneeds. D) feedbackinhibition. E) Alloftheabove. Answer: E 43) Underaerobicconditions,pyruvateproducedinglycolysiscanbeconvertedto A) glyceraldehyde-3-phosphate. B) lacticacid. C) glucose-6-phosphate. D) fructose-6-phosphate. E) acetylCoA. Answer: E 44) Underanaerobicconditions,lactateisproducedfrom A) acetylCoA. B) pyruvate. C) ATP. D) carbondioxide. E) NAD+ . Answer: B 45) Glycogenisnormallystoredin A) heartandlung. B) liverandmuscle. C) spleenandbone. D) pancreasandmuscle. E) fatcellsandmuscle. Answer: B

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46) Whenasmuchglycogenisstoredaspossibleinthebody,excessglucoseisconvertedto A) triacylglycerols. B) fructose. C) sucrose. D) CoenzymeA. E) ATP. Answer: A 47) Thesynthesisofglycogenfromglucoseiscalled A) glyceration. B) gluconeogenesis. C) glucogenesis. D) glycogenesis. E) glycolysis. Answer: D 48) Glycogenesisobtainsenergyfrom A) ADP. B) UTP. C) Pi. D) pyrophosphate. E) pyruvate. Answer: B 49) Whenglycogenisbrokendownintoglucose,theprocessiscalled A) glycogenesis. B) glycogenolysis. C) gluconeogenesis. D) lactateproduction. E) glucagonproduction. Answer: B 50) Theprimaryenergysourceforthebrainis A) lactate. B) triacylglycerols. C) aminoacids. D) fructose. E) glucose. Answer: E

22.2 BimodalQuestions
1) Thisisthetermthatreferstoallofthechemicalreactionsinlivingcells. A) glycolysis B) -oxidation C) metabolism D) anabolism E) catabolism Answer: C

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2) Theenergyformostenergy-requiringreactionsinthecellsofthebodyisobtainedbythehydrolysisof ________. A) ATP B) ADP C) AMP D) cyclicAMP E) GTP Answer: A 3) Tworeactionsoccurringtogether,oneprovidingtheenergyfortheotheronetooccur,areknownas________. A) sequentialreactions B) stackedreactions C) seriesreactions D) concomitantreactions E) coupledreactions Answer: E 4) Hydrolysisofsucrosetakesplaceprimarilyinthe________. A) mouth B) stomach C) pancreas D) smallintestine E) largeintestine Answer: D 5) Thenetenergyproductioninanaerobicglycolysisis________. A) 2ATP B) 4ATP C) 6ATP D) 8ATP E) 12ATP Answer: A 6) Mostoftheenergyinthetypicalanimalcellisproducedinthe________. A) cytosol B) nucleus C) mitochondria D) lysosomes E) endoplasmicreticulum Answer: C 7) Theproductionofethanolfromglucoseistermed________. A) fermentation B) glycolysis C) gluconeogenesis D) -oxidation E) dehydrogenation Answer: A

22.3 True/FalseQuestions
1) Energyproductioninthecelloccursprimarilyinthenucleus. Answer: TRUE

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2) Thecytosolisanaqueoussolutionofsaltsandenzymes. Answer: TRUE 3) Reactionsinthemitochondriaproducemostofthecellsenergy. Answer: TRUE 4) Lysosomesdigestandrecycleoldcellstructures. Answer: TRUE 5) Digestionofapolysaccharideisananabolicprocess. Answer: FALSE 6) Theproductionofcarbondioxideandwaterinthebodyisananabolicprocess. Answer: FALSE 7) ATPistheprimaryenergysourceforthecell. Answer: TRUE 8) CatabolicreactionsprovideenergytogenerateATPinthecell. Answer: TRUE 9) TheconversionofATPtoADPandinorganicphosphateproduces7.3kcal/moleofenergy. Answer: TRUE 10) ThereactionofglucosewithATPtoproduceADPandglucose -6-phosphateisanexampleofacoupled reaction. Answer: TRUE 11) Oxidationinvolvesthegainofelectronsforasubstance. Answer: FALSE 12) NAD+ actsasahydrogenacceptorinmetabolicreactions. Answer: TRUE 13) FADH2 istheoxidizedformofFAD. Answer: FALSE 14) PantothenicacidisapartofNADH Answer: FALSE 15) ATPcontainsribose. Answer: FALSE

22.4 MatchingQuestions
Identifyeachofthefollowingmetabolicpathways. 1) Column1: anaerobicglycolysis Column2: theconversionofglucoseto lacticacid Answer: theconversionofglucosetolacticacid

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2) Column1: fermentation Column2: theconversionofpyruvicacid toethanolandCO 2 Answer: theconversionofpyruvicacidtoethanolandCO 2 3) Column1: glycogenesis Column2: thesynthesisfromglucoseof glycogenforstorage Answer: thesynthesisfromglucoseofglycogenforstorage 4) Column1: gluconeogenesis Column2: theproductionofglucosefrom othersmallmolecules Answer: theproductionofglucosefromothersmallmolecules 5) Column1: theCoricycle Column2: theflowoflactateandglucose betweenmuscleandliver Answer: theflowoflactateandglucosebetweenmuscleandliver 6) Column1: digestion Column2: breakingdownof macromolecules Answer: breakingdownofmacromolecules 7) Column1: triacylglycerolhydrolysis Column2: lipidmetabolism Answer: lipidmetabolism

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Chapter23 MetabolismandEnergyProduction 23.1 Multiple-ChoiceQuestions

1) Whencombinedwiththeelectrontransportchain,oneturnofthecitricacidcycleproduces________ATP. A) 24 B) 12 C) 11 D) 14 E) 2 Answer: B 2) WhatisthecorrectcoefficientforATPinthecompletecombustionofglucose? C6 H12O6 +6O2 6CO 2 +_____ATP+6H2 O A) 6 B) 12 C) 18 D) 24 E) 36 Answer: E 3) Intheabsenceofoxygeninmuscles,pyruvateisconvertedto A) glycogen. B) glucose. C) ethanol. D) lactate. E) glyceraldehyde-3-phosphate. Answer: D 4) Underanaerobicconditions,thereisanetproductionof________ATPduringglycolysis. A) zero B) two C) four D) six E) eight Answer: B 5) Inordertoenterthecitricacidcycle,pyruvateisfirstconvertedto A) ate. B) acetaldehyde. C) citrate. D) acetylCoA. E) ethanol. Answer: D 6) Inyeastcells,energyisobtainedwhenpyruvateisconvertedtoethanol (C 2 H5 OH)andcarbondioxide(CO2 ). Whatisthenameofthisprocess? A) aerobicglycolysis B) reduction C) fermentation D) oxidativedecarboxylation E) oxidativephosphorylation Answer: C Page310

7) WhichofthefollowingisNOTapossibleproductofpyruvateunderanaerobicconditions? A) lactate B) acetaldehyde C) fumarate D) ethanol E) CO 2 Answer: C 8) Thecitricacidcycleisusedintheoxidationof A) glucoseonly. B) glucoseandfattyacidsonly. C) fattyacidsonly. D) glucose,fattyacids,andproteins. E) proteinsonly. Answer: D 9) Whatelectronacceptor(s)is(are)usedinthecitricacidcycle? A) FADonly B) NAD+ only C) NADH+FADH2 +CoASH D) FMN E) NAD+ +FAD Answer: E 10) Whichofthefollowingcompoundsinthecitricacidcycleundergoesoxidativedecarboxylation? A) citrate B) isocitrate C) succinate D) fumarate E) succinylCoA Answer: B 11) Whichofthefollowingisthenetreactionforoneturnofthecitricacidcycle? A) Acetyl-S-CoA+3NAD+ +FAD+GDP+Pi +H 2 O2CO 2 +3NADH+3H+ +FADH2 +HS-CoA+ GTP B) Pyruvate+3NAD+ +FAD+GDP+Pi2H 2 O3CO 2 +3NADH+3H+ +FADH2 +GTP C) Acetyl-S-CoA+NAD+ +FAD+GDP+Pi2CO 2 +NADH+H+ +FADH2 +HS-CoA+GTP D) Glucose+2NAD+ +2GDP+2Pi+2H 2 O2Pyruvate+2NADH+2H+ +GTP E) Glucose+2GDP+2Pi2Lactate+ 2GTP Answer: A 12) Thecitricacidcycleoperatesonlyunderaerobicconditionsbecause A) oxygenisareactantinthecitricacidcycle. B) oxygenisaproductofthecitricacidcycle. C) CO 2 isaproductofthecitricacidcycle. D) theNADHandFADH2 producedbythecitricacidcyclecanonlybereoxidizedbytheelectrontransport chain. E) theNAD+ andFADproducedbythecitricacidcyclecanonlybereducedbytheelectrontransportchain. Answer: D

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13) Inthechemiosmoticmodelofoxidativephosphorylation,ATPissynthesizedas A) OH- flowsthroughATPsynthase. B) electronsflowthroughATPsynthase. C) Ca2+ flowsthroughATPsynthase. D) H+ flowsthroughATPsynthase. E) Na+ flowsthroughATPsynthase. Answer: D 14) ThecomponentsoftheelectrontransportchaindoNOTinclude A) oxygen(O 2 ). B) cytochromes. C) FMN. D) CoQ. E) acetylCoA. Answer: E 15) Intheelectrontransportchain,thesynthesisofATPfromADP+ Pi iscalled A) glycolysis. B) fermentation. C) oxidativephosphorylation. D) isomerization. E) hydrolysis. Answer: C 16) Intheelectrontransportchain,thethreeproteincomplexes(I,III,andIV) A) actasprotonpumps,whichgenerateaprotongradient. B) transferelectronsfromNAD+ toO2 . C) transferelectronsfromFADtoO2 . D) actaselectronpumps,whichgenerateanelectrongradient. E) actasCa2+ pumps,whichgenerateaCa2+ gradient. Answer: A 17) Intheelectrontransportchain,theoxidizedproductfromthereactionofFMN+NADH+H+ is A) CoQ. B) FMNH2 . C) FADH. D) FAD. E) NAD+ . Answer: E 18) Inthelaststepoftheelectrontransportchain,waterisproducedwhenprotonsandelectronsaretransferredto oxygen(O 2 )from________. A) cyta3 B) cytb C) cytc D) cytc1 E) cyta Answer: A

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19) Theelectroncarrier________providestwoATPviatheelectrontransportchain. A) FADH2 B) NADH C) NADPH D) CoASH E) FNMH2 Answer: A 20) Whenoxygenisinplentifulsupplyinthecell,pyruvateisconvertedto A) CoA. B) acetylCoA. C) glucose. D) lactate. E) fructose. Answer: B 21) Theprocesswhichrequiresoxygentoproducecarbondioxideandwateriscalled A) fermentation. B) reduction. C) decomposition. D) oxidation. E) respiration. Answer: E 22) Whichofthethreemajorstagesofmetabolismincludesthecitricacidcycle? A) Stageone B) Stagetwo C) Stagethree Answer: C 23) Thecitricacidcycletakesplaceinthe A) mitochondria. B) cytosol. C) cytoplasm. D) Golgiapparatus. E) endoplasmicreticulum. Answer: A 24) Instagethreeofmetabolism,theoverallresultistorelease A) glucoseandwater. B) lactateandacetylCoA. C) lactateandglucose. D) glycogenandwater. E) carbondioxideandenergy. Answer: E 25) Mostoftheenergyreleasedinthecitricacidcycleisusedtoproduce A) glucose. B) acetylCoA. C) NADHandFADH2 . D) carbondioxideandwater. E) citricacid. Answer: C Page313

26) Theelectrontransportchainisalsocalled A) thecitricacidcycle. B) -oxidation. C) transamination. D) therespiratorychain. E) fermentation. Answer: D 27) Intheelectrontransportchain,NADHandFADH2 areusedtoprovide A) oxygen. B) electronsandhydrogenions. C) carbonatoms. D) waterandcarbondioxide. E) thiolgroups. Answer: B 28) Theenergyreleasedduringtheelectrontransportchainisusedtoproduce A) glucose. B) citricacid. C) carbondioxide. D) ATP. E) NADH. Answer: D 29) Anothernameforthecitricacidcycleis A) theelectrontransportchain. B) glycolysis. C) thetricarboxylicacidcycle. D) glucolysis. E) thetransaminationpathway. Answer: C 30) Anothernameforthecitricacidcycleis A) theKrebscycle. B) gluconeogenesis. C) glucosehydrolysis. D) oxidativephosphorylation. E) thechemiosmoticpump. Answer: A 31) Inthefirstreactionofthecitricacidcycle A) glucosebecomespyruvate. B) ATPisproduced. C) NADHisproduced. D) acetylCoAreactswithoxaloacetatetogivecitrate. E) pyruvatebecomesCO2 andH2 O. Answer: D

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32) Duringthefirstreactioninthecitricacidcycle, A) freeCoAisreleased. B) acetylCoAismade. C) adecarboxylationoccurs. D) adecompositionoccurs. E) ATPissynthesized. Answer: A 33) Thetransformationofcitratetoisocitrateinthecitricacidcyclerquirestwo________reactions. A) oxidation B) reduction C) hydrolysis D) decarboxylation E) dehydration-hydration Answer: E 34) ThecitricacidcyclestepthatremovesthefirstCO 2 moleculeisa(n) A) oxidativedecarboxylation. B) reduction. C) carbonylation. D) hydrolysis. E) combination. Answer: A 35) Inthethirdmajorstepofthecitricacidcycle,NAD+ isconvertedto A) NAS- . B) NAD2+ . C) NADH2. D) NAD. E) NADH. Answer: E 36) Step5ofthecitricacidcycleisthehydrolysisofsuccinylCoA.Inthisreaction A) theenergyreleasedisusedtomakeGTP. B) theenergyreleasedisusedtomakeATP. C) carbondioxideisreleased. D) -ketoglutarateisreleased. E) theenzymeaconitaseisneeded. Answer: A 37) InthehydrolysisofsuccinylCoAinstep5ofthecitricacidcycle,CoAisreleasedas A) CoA-SH. B) CoA-OH. C) CoA-O- . D) CoA-S-. E) CoA-COO- . Answer: A

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38) TheGTPformedinstep5ofthecitricacidcycleisusedtomake A) carbondioxide. B) oxygen. C) water. D) CoA. E) ATP. Answer: E 39) Inthedehydrationofsuccinatetofumarateinthecitricacidcycle,thecoenzymeusedis A) CoA. B) acetylCoA. C) NAD+ . D) NADH. E) FAD. Answer: E 40) Instep7ofthecitricacidcycle,fumarateisconvertedtomalatebya________reaction. A) hydrolysis B) dehydrogenation C) hydrogenation D) hydration E) dehydration Answer: D 41) Thelaststepinthecitricacidcycleconvertsmalateto A) citrate. B) isocitrate. C) succinate. D) fumarate. E) oxaloacetate. Answer: E 42) Overall,oneturnofthecitricacidcycleproduces A) threeCO 2 molecules. B) threeNADHmolecules. C) twoFADH2 molecules. D) 6ATP. E) 2GTP. Answer: B 43) Onemethodofregulationofthecitricacidcycleis A) allostericcontrol. B) osmosis. C) temperaturecontrol. D) carbondioxideproduction. E) waterconcentration. Answer: A

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44) ThecompoundsintherespiratorychainthatrermovehydrogenionsandelectronsfromNADHareclassified as A) oxidativetransporters. B) osmoticcarriers. C) electroncarriers. D) phosphorylators. E) citrates. Answer: C 45) Oneexampleofanelectroncarrierintherespiratorychainis A) ATP. B) GTP. C) coenzymeQ. D) citrate. E) water. Answer: C 46) WhichisthebestchoicefortheboxlabeledAnswerintheillustrationbelow?

A) oxidizedcarrierB B) carbondioxide C) OHD) reducedcarrierBH2 E) energy Answer: D 47) Intheelectrontransportchain,intheiron-sulfurproteins, A) thesulfuristheelementthatcarriestheelectrons. B) theproteincomplexiseitheroxidizedorreduced. C) ironalternatesbetweenthe+2and+3state. D) FADiscarriedtocoenzymeQ. E) oxygeniscarriedtowater. Answer: C 48) Intheelectrontransportchain,cytochromescontain A) FMN. B) heme. C) lymph. D) iron-sulfurclusters. E) CoQ. Answer: B

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49) Cyanideionandcarbonmonoxideinhibit A) cytochromecoxidase. B) ATPproduction. C) antibioticactivity. D) CoQformation. E) CoAformation. Answer: A 50) Inthechemiosmoticmodel,protonscirculatethroughaproteincomplexcalled A) iron-sulfurclusters. B) FMA. C) CoA. D) CoQ. E) ATPsynthase. Answer: E 51) Inglycolysis,glucoseproduces2pyruvatemoleculesandatotalof________ATPmolecules. A) 2 B) 4 C) 6 D) 8 E) 12 Answer: C 52) Thecompleteoxidationofglucoseproduces________ATPmolecules. A) 2 B) 8 C) 12 D) 24 E) 36 Answer: E

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23.2 ShortAnswerQuestions
Inthisfiguretakenfromyourtext,identifythemetabolicsubstancenumbered.

1) substance1 Answer: proteins 2) substance2 Answer: carbohydratesorpolysaccharides 3) substance3 Answer: lipids 4) substance4 Answer: pyruvate 5) substance5 Answer: acetylCoA 6) substance6 Answer: carbondioxide Page319

7) substance7 Answer: ATP 8) substance8 Answer: oxygen 9) process9 Answer: citricacidcycleorKrebscycleortricarboxylicacidcycle 10) process10 Answer: electrontransport 11) process11 Answer: oxidativephosphorylation Inthisfiguretakenfromyourtext,identifythesubstancesshown.

12) substance12 Answer: acetylCoA 13) substance13 Answer: citrate 14) substance14 Answer: carbondioxide 15) substance15 Answer: -ketoglutarate 16) substance16 Answer: carbondioxide

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17) substance17 Answer: succinylCoA 18) substance18 Answer: oxaloacetate

23.3 MatchingQuestions
IndicatetheamountofATPproducedwheneachofthefollowingreactionsoccurs. 1) Column1: completeoxidationofglucose Column2: 36ATP Answer: 36ATP 2) Column1: AcetylCoA2CO 2 Column2: 12ATP Answer: 12ATP 3) Column1: glucose2pyruvateunder aerobicconditions Column2: 6ATP Answer: 6ATP 4) Column1: glucose2lactate Column2: 2ATP Answer: 2ATP 5) Column1: pyruvate acetate+CO 2 Column2: 3ATP Answer: 3ATP Matchthetermswiththefollowingdescriptions. 6) Column1: theprocessthatmakesATP usingenergyfromtheelectron transportchain Column2: oxidativephosphorylation Answer: oxidativephosphorylation 7) Column1: thecarrierofacetyl (two-carbon)groups Column2: coenzymeA Answer: coenzymeA

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Identifyeachofthefollowingmetabolicpathways. 8) Column1: theconversionofglucoseto pyruvicacid Column2: glycolysis Answer: glycolysis 9) Column1: theseriesofreactionsthat convertsacetylCoAtocarbon dioxideandwater Column2: citricacidcycle Answer: citricacidcycle 10) Column1: theseriesofreactionsthat produceswater Column2: electrontransportchain Answer: electrontransportchain 11) Column1: theseriesofreactionsthatuses electroncarriers Column2: electrontransportchain Answer: electrontransportchain

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Chapter24 MetabolicPathwaysforLipidsandAminoAcids 24.1 Multiple-ChoiceQuestions

1) Intheactivationofafattyacid,energyfromthehydrolysisofATPisusedto A) formadoublebondinanoxidationreaction. B) jointhefattyacidtoCoA. C) addamoleculeofwateracrossadoublebondtogiveahydroxylgrouponthe -carbon. D) oxidizethehydroxylgrouponthe-carbon. E) causeaunitofacetylCoAtoseparatefromthefattyacidchain. Answer: B 2) Thecoenzyme(s)usedinfattyacidsynthesisis(are)________. A) NADH B) FADH2 C) NADPH D) NADHandNADPH E) FADH2 andNADH Answer: C 3) TheseriesofreactionsthatproducesenergybyhydrolyzingfatstounitsofacetylCoAiscalled A) transamination. B) -oxidation. C) hydration. D) hydrolysis. E) -reduction. Answer: B 4) Whichstepisfoundinthebreakdownofafat? A) anactivationthatrequires2ATP. B) anoxidationwithacytochrome. C) anoxidationwithCoQ. D) directsubstratephosphorylation. E) productionofpyruvate. Answer: A 5) DuringcompleteoxidationofthefattyacidCH3 (CH2 )18COOH,________moleculesofacetylCoAare produced,andthefattyacidgoesthroughthe-oxidationcycle________times. A) ten;ten B) nine;ten C) nine;nine D) nine;eight E) ten;nine Answer: E 6) WhatisthetotalnumberofATPmoleculesproducedfromthelauricacid(C 12H24O2 )foundincoconutoil? A) 72ATP B) 90ATP C) 100ATP D) 97ATP E) 95ATP Answer: E

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7) ThecompleteoxidationofCH3 (CH2 ) 8 COOHproduces________moleculesofATP. A) 80 B) 78 C) 82 D) 74 E) 76 Answer: B 8) Whencarbohydratesarenotavailabletomeetenergyneeds,lessacetylCoAentersthecitricacidcyclebecause A) acetylCoAisconvertedtoketonebodiestoprovideenergyforthebrain. B) lessNADHisavailable. C) acetylCoAisconvertedtoglucose. D) oxaloacetateisconvertedtoglucose,solessisavailableforthecitricacidcycle. E) theelectrontransportchaincannotreoxidizeNAD+ andFADasrapidlyastheyareproducedin -oxidation. Answer: D 9) Ina(n)________reaction,NH 4 + isproducedwhenglutamateisconvertedto-ketoglutarate. A) dehydrogenation B) transamination C) oxidativedeamination D) reduction E) hydration Answer: C 10) Allofthenonessentialaminoacidscanbesynthesizedinthebodybytransamination,usinganaminogroup from A) glutamicacid. B) -ketoglutaricacid. C) pyruvicacid. D) oxaloacetate. E) lacticacid. Answer: A 11) WhichofthefollowingdoesNOTrequireNAD+ ? A) glycolysis B) transamination C) citricacidcycle D) -oxidation E) oxidativedeamination Answer: B 12) Inmammals,theammoniumionproducedinoxidativedeaminationis A) excretedinthefeces. B) storedintheliver. C) convertedtouricacid,whichisexcretedintheurine. D) convertedtourea,whichisexcretedintheurine. E) convertedtouricacid,whichisexcretedbytheliver. Answer: D

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13) Thedigestionofproteinbeginsinthe A) mouth. B) stomach. C) smallintestine. D) largeintestine. E) pancreas. Answer: B 14) Theinitialdigestionofproteiniscatalyzedbyanenzymecalled A) chymotrypsin. B) peptidase. C) pepsin. D) amylase. E) trypsin. Answer: C 15) Thedigestionoffatsbeginsinthe A) mouth. B) stomach. C) smallintestine. D) gallbladder. E) largeintestine. Answer: C 16) Thedigestionoffatsbeginswhenthefatglobulesare A) emulsifiedbybilesalts. B) attackedbyproteaseenzymestoformsmallerfatglobules. C) convertedtolipoproteinsforgreatersolubility. D) hydrolyzedtoglucoseandaminoacids. E) hydrolyzedtoglycerolandfattyacids. Answer: A 17) TheprimaryfuelforthesynthesisofATPis A) protein. B) lactate. C) ammonia. D) GTP. E) glucose. Answer: E 18) Fattyacidsandglycerolareproducedfromthemetabolismof A) lipids. B) proteins. C) carbohydrates. D) aminoacids. E) glucose. Answer: A

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19) Mostoftheenergystoredinthehumanbodyisintheformof A) glycogen. B) glucose. C) muscletissue. D) triacylglycerols. E) theaminoacidpool. Answer: D 20) Fatcellsareknownas A) lysosomes. B) adipocytes. C) glycerides. D) isletcells. E) monoacylglycerols. Answer: B 21) Thesmalldropletsoffatthatarethefirststepinthedigestionofdietaryfatsarecalled A) emulsions. B) detergents. C) biledrops. D) lipoproteins. E) micelles. Answer: E 22) Theactionofpancreaticlipaseontriacylglycerolsproduces A) emulsions. B) micelles. C) monoacylglycerolsandfreefattyacids. D) high-densitylipoproteins. E) low-densitylipoproteins. Answer: C 23) Achylomicronisa A) lipase. B) digestiveenzyme. C) triacylglycerol. D) transportlipoprotein. E) storageprotein. Answer: D 24) Fattyacidsarenotasourceofenergyforthebrainbecause A) theycannotdiffuseacrosstheblood-brainbarrier. B) thecitricacidcycledoesnotoperateinthebrain. C) chylomicronsaretoolargeforabsorptionbybraincells. D) theyaremetabolizedbeforetheygetasfarasthebrain. E) thereisnolipaseinthebrain. Answer: A

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25) Thesourceofenergyforredbloodcellsis A) aminoacids. B) fattyacids. C) glycerol. D) glucose. E) lactate. Answer: D 26) Heartmusclesprimarysourceoffuelis A) glucose. B) fattyacids. C) aminoacids. D) glycogen. E) lactate. Answer: B 27) Redbloodcellsdonotmetabolizefattyacidsbecausetheyhave A) nonucleus. B) acellwall. C) acellmembrane. D) nomitochondria. E) noDNA. Answer: D 28) Fatstoresinthebodyaremobilizedwhen A) adipocyteconcentrationsarehigh. B) bloodglucoselevelsarehigh. C) glucagonproductionislow. D) insulinproductionishigh. E) glucoseandglycogenstoresarelow. Answer: E 29) Theenzymesthatbreakdowntriacylglycerolsintofattyacidsandglycerolarecalled A) lyases. B) aconitases. C) lipases. D) hydrolases. E) oxidoreductases. Answer: C 30) Mostoftheglycerolproducedbyfattyacidbreakdowngoestothe A) pancreas. B) gallbladder. C) liver. D) smallintestine. E) brain. Answer: C

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31) Mostoftheglycerolproducedbyfattyacidbreakdownisconvertedeventuallyto A) glucose. B) protein. C) fat. D) lactate. E) aminoacids. Answer: A 32) Theremovalof2-carbonsegmentsofafattyacidforfurthermetabolismiscalled A) -oxidation. B) transamination. C) deglyceration. D) dehydration. E) decarboxylation. Answer: A 33) The2-carbonsegmentsremovedfromafattyacidduringmetabolismareusedtoform A) glucose. B) pyruvate. C) lactate. D) CoA. E) acetylCoA. Answer: E 34) The2-carbonunitsobtainedbydegradationofafattyacidarefurthermetabolizedin A) gluconeogenesis. B) thecitricacidcycle. C) -oxidation. D) glycolysis. E) transamination. Answer: B 35) ThefunctionoffattyacylCoAisto A) activateafattyacidformetabolism. B) producea2-carbonsegmentformetabolism. C) isomerizecisfattyacids. D) crosstheblood-brainbarrier. E) producealipoprotein. Answer: A 36) FattyacylCoAcannotcrossintothemitochondrialmatrixuntil A) itiscutinto2-carbonsegments. B) thecitricacidcyclehasbegun. C) -oxidationhastakenplace. D) themitochondrialmembraneundergoesamodification. E) itbindswithachargedcarriermoleculecalledcarnitine. Answer: E

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37) Beta-oxidationtakesplaceinthe A) nucleus. B) cytosol. C) cytoplasm. D) mitochondrialmatrix. E) Golgibody. Answer: D 38) Myristicacid,aC14fattyacid,produces________acetylCoAwhencompletelymetabolized. A) 2 B) 5 C) 7 D) 12 E) 14 Answer: C 39) Myristicacid,aC14fattyacid,undergoesthe -oxidationcycle________times. A) 2 B) 4 C) 6 D) 7 E) 14 Answer: C 40) Theenergyreleasedbythe-oxidationofa cisfattyacidis A) slightlymorethanthatobtainedfroma transfattyacid. B) slightlylessthanthatobtainedfroma transfattyacid. C) thesameasthatobtainedfromatransfattyacid. D) lessthanthatobtainedfromoneglucosemolecule. E) usedimmediatelytoformATP. Answer: B 41) Fatsarehigherincaloricvaluethancarbohydratesbecause A) 1gramoffatproducessignificantlymoreATPthan1gramofglucose. B) fatscanmakeuseofthecitricacidcycle. C) fatsmakeuseof-oxidation. D) 1gramofglucoseweighsmorethan1gramoffat. E) 1gramofglucosecontainsmoremolesthan1gramoffat. Answer: A 42) Leptinis A) adigestiveenzyme. B) acofactorforfattyacidoxidation. C) anobesitygene. D) azymogen. E) ahormonestoredinfatcells. Answer: E

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43) EachacetylCoAproduces________ATPinthecitricacidcycle. A) 2 B) 6 C) 10 D) 12 E) 24 Answer: D 44) WhenexcessacetylCoAaccumulatesintheliver,apathwaycalled________isinitiated. A) transamination B) glycolysis C) gluconeogenesis D) emulsification E) ketogenesis Answer: E 45) Ketosisisaconditionthatcanoccurif A) ketonebodiescannotbecompletelymetabolized. B) toomanyketonesareingested. C) toomuchproteinisavailableinthediet. D) thebrainisstarvedofglucose. E) lowfatintakeoccurs. Answer: A 46) InTypeIIdiabetesmellitus, A) bloodglucoselevelsaretoolow. B) glucoseintakeistoolow. C) birthofababyrestoresnormalpancreaticfunction. D) sufficientinsulinisproduced,butcannotbeused. E) thepancreasproducesinsufficientinsulin. Answer: D 47) KetosiscanlowerthebloodpHbelow7.4,producingthecondition A) anemia. B) hyponatremia. C) hypokalemia. D) acidosis. E) alkalosis. Answer: D 48) Theproductionofnewfattyacidsiscalled A) gluconeogenesis. B) -oxidation. C) transesterification. D) oxidation. E) lipogenesis. Answer: E

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49) Acylcarrierproteinisusedin A) -oxidation. B) lipogenesis. C) gluconeogenesis. D) acetylCoAproduction. E) fattyaciddegradation. Answer: B 50) InTypeIdiabetesmellitus, A) bloodglucoselevelsaretoolow. B) glucoseintakeistoolow. C) birthofababyrestoresnormalpancreaticfunction. D) sufficientinsulinisproduced,butcannotbeused. E) thepancreasproducesinsufficientinsulin. Answer: E 51) MalonylCoAcontainsa3-carboncompoundusedin A) lipogenesis. B) acetylCoAformation. C) gluconeogenesis. D) glycogenolysis. E) thecitricacidcycle. Answer: A 52) ThelettersACPstandfor A) acetylCoenzymeP. B) aconitateproteincomplex. C) acetylcondensingprotein. D) acylcarrierprotein. E) acetylCoA-palmitate. Answer: D 53) Fattyacidsynthesistakesplaceprimarilyin A) livercells. B) intestinalcells. C) braincells. D) musclecells. E) adipocytes. Answer: E 54) Thenitrogenfornucleotidesynthesiscomesfrom A) carbohydrates. B) fats. C) proteins. D) DNA. E) RNA. Answer: C

24.2 True/FalseQuestions
1) Acylcarrierproteinisusedinfattyacidsynthesis. Answer: TRUE 2) Theproductionofnewtriacylglycerolsistermedketogenesis. Answer: FALSE Page331

3) Fattyacidscanbeusedinthebrainasanenergysource. Answer: FALSE 4) Redbloodcellshavemitochondria,whichserveasanenergyproductionsite. Answer: FALSE 5) Chylomicronsconsistofbilesaltsandlipids. Answer: FALSE 6) Nonessentialaminoacidscanbemadeinthebodyusingthetransaminationpathway. Answer: TRUE 7) Ammoniumionsandcarbondioxideproduceureaintheureacycle. Answer: TRUE 8) Theureacycleisthemajorpathwayforeliminatingtheexcessnitrogenfromaminoaciddegradation. Answer: TRUE 9) Theoverallprocessofsynthesizingandbreakingdownproteinsiscalledproteinturnover. Answer: TRUE 10) Proteindigestionbeginsinthesmallintestine. Answer: FALSE 11) Someaminoacidscanbeconvertedintoothersviatransamination. Answer: TRUE

24.3 MatchingQuestions
Matchthefollowing. 1) Column1: compoundsproducedwhen thereislittleorno carbohydratemetabolismand asubsequentincreaseinfat metabolism Column2: ketonebodies Answer: ketonebodies 2) Column1: acarrierofelectronstothesite ofATPproduction,from oxidationreactionsinvolving carbon-carbondoublebonds Column2: FAD Answer: FAD 3) Column1: lipoproteinsformedfrom triacylglycerolsandprotein Column2: chylomicrons Answer: chylomicrons

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4) Column1: anaminoacidthatisnot synthesizedinthebody Column2: essentialaminoacid Foil: transaminatedaminoacid Answer: essentialaminoacid 5) Column1: amajorstepinfattyacid degradation Column2: -oxidation Answer: -oxidation 6) Column1: anaminoacidproducing carbonsforglucoseproduction Column2: aglucogenicaminoacid Foil: aketogenicaminoacid Answer: aglucogenicaminoacid 7) Column1: aconditionoflowbloodpH Column2: acidosis Foil: alkalosis Answer: acidosis 8) Column1: theproductsofketogenesis Column2: ketonebodies Answer: ketonebodies 9) Column1: themainsourceofenergyin thebody Column2: ATP Foil: GTP Answer: ATP 10) Column1: acarrierof2-carbonunitsin fattyaciddegradation Column2: CoenzymeA. Answer: CoenzymeA. Identifyeachofthefollowingmetabolicpathways. 11) Column1: theconversionoffattyacidsto 2-carbonunitsofacetyl CoenzymeA Column2: -oxidation Answer: -oxidation

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12) Column1: theconversionofanamino acidtoan-ketoacid Column2: transamination Answer: transamination 13) Column1: thecombinationof2-carbon unitsofacetylCoAtoform fattyacids Column2: lipogenesis Answer: lipogenesis 14) Column1: theremovalofanamino groupasNH 4 + fromglutamic acidtoyield-ketoglutaric acid Column2: oxidativedeamination Answer: oxidativedeamination 15) Column1: theproductionofketone bodies Column2: ketogenesis Answer: ketogenesis

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