APhO2001 Exp Prob
APhO2001 Exp Prob
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electron
(conduction band)
(valence band) hole Fig. 1 Brief explanations of the terminologies and basic principles are listed below: (1) Short-circuit current (Isc) is the output current of the solar cell when the external circuit is shorted, i.e., zero load resistance. (2) Open-circuit voltage (Voc) is the output voltage of the solar cell when the external circuit is open, i.e., infinite load resistance. Voc is also referred to as photovoltaic voltage. (3) Pm is the maximum output power of the solar cell, i.e., the maximum value of IV. (4) The filling factor (FF) is defined to be Pm/(IscVoc), which represents an important parameter used to evaluate the quality of the solar cell.
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(5)
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Because the photocurrent is produced by photon absorption by the semiconductor, the spectral response of the photocurrent can be used to determine the semiconductor band gap. From the band gap value, one can infer the particular semiconductor material used. Any incident photon with photon energy larger than the semiconductor band gap can contribute to the photocurrent (Iph) of the solar cell, thus
where N( ) is the number of electrons per unit wavelength produced by photons with wavelength , is the cut-off wavelength of the optical filter (see Fig. 2, Fig. 3, and Fig. 4), and o is the longest wavelength capable of producing a photocurrent. Here N( ) is approximately constant in the visible spectral range, and each optical filter provided in this experiment cuts off all light with wavelengths shorter than a certain cut-off wavelength . Therefore, the spectral response of Iph with an optical filter can be simplified to be Iph (o ). The photon energy E is related to the photon wavelength as E = 1240/; the unit for is nm (10-9m) and the unit for E is eV (electron-volt) in this equation. II. Equipments and materials (1) A solar cell in a black box with pre-installed electrical connections (2) Two digital electrical multimeters (3) A set of dry cell batteries (1.5 V 2) (4) One precision variable resistor (0-5 k) (Caution: Do not connect the central connecting lead (the red wire) of the variable resistor directly to the battery, it may damage the resisitor.) (5) A white light source with power supply (6) Two polarizers (Note: these polarizers are less effective for light with wavelengths shorter than that of yellow light,that is the cut-off wavelength of the yellow filter.) (7) Red, orange, and yellow optical filters, one of each (their spectral specifications are shown in Fig. 2, Fig. 3, and Fig. 4) (8) An optical mount for the optical filters or polarizers (Note: optical filters and polarizers can be mounted together on the same optical mount.) (9) One optical bench (10) Wire joining devices: 6 small springs (11) One 45 cm ruler (7)
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(12) Regular graph paper (10 sheets), semi-log graph paper (5 sheets) (13) Two light-shielding boards (Note: To avoid deterioration due to heat, polarizers and filters should be set at a distance as far away from the light source as possible.)
Fig. 2
Fig. 3
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Fig. 4 III. Experimental steps (1) (Question (1) : 3 points) Measure the dark I-V characteristic of the forward biased solar cell. a. Draw a diagram of the electrical circuit you used. b. Plot the I-V curve and determine the values of and Io using the I-V data you obtained.. (2) (Question (2) : 7 points) Measure the characteristics of the solar cell, without electrical bias under white light illumination. (Note: the distance between the light source and the solar cell box should be kept at 30 cm as shown in Fig. 5.) light source solar cell box
30 cm
a.
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(3)
b. Measure the short-circuit current , Isc. c. Measure the open-circuit voltage, Voc. d. Measure the I vs. V relationship of the solar cell with varying load resistance and plot the I-V curve. e. Determine the maximum output power of the solar cell. f. Determine the load resistance for the maximum output power. g. Calculate the filling factor, FF Pm/(IscVoc) (Question (3) : 3.0 points) Assume that the solar cell can be modeled as a device consisting of an ideal current source (light-generated current source), an ideal diode, a shunt resistance Rsh, and a series resistance Rs, a. Draw an equivalent circuit diagram for the solar cell under light illumination. b. Derive the I-V relationship for the equivalent circuit. Express the result in terms of , , Iph (light-generated current), and Id (the current c. passing through the diode). Assuming that = infinity and = 0 and can be neglected, find
the I-V relationship and prove that it can be written in the form as given below:
where Voc is the open-circuit voltage, Isc is the short-circuit current, and I0 , are constants. (4) (Question (4) : 4 points) Find effects of irradiance. a. Measure and plot the Isc vs. relative light intensity curve, and determine the approximate functional relationship between Isc and the relative light intensity. b. Measure and plot the Voc vs. relative light intensity curve, and determine the approximate functional relationship between Voc and the relative light intensity. (Question (5) : 3.0 points) Find the wavelength response of the solar cell. a. Measure and plot the Isc vs. different cut-off wavelengths using the three optical filters. b. Estimate the longest wavelength for which the solar cell can function properly.
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c.
Infer which semiconductor material the solar cell is made of. (Hint: the band gaps for commonly used semiconductors are InAs: 0.36 eV, Ge: 0.67 eV, Si: 1.1 eV, amorphous Si(a-Si : H): 1.7 eV, GaN: 3.5 eV)
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