C. Chemical Transformation: Temperature Process 100 100 - 400 400 - 750
C. Chemical Transformation: Temperature Process 100 100 - 400 400 - 750
Chemical transformation
Temperature < 100 100 - 400 400 - 750 600 - 900 900 - 1000 800 - 1300
Process
Drying elimination of free water. Elimination of physical absorbed water. Decomposition of clay with formation of metakaolinite. Removal of structural H2O. Decomposition of metakaolinite to mixture of free reactive oxides. Dissociation of limestone and formation of intermidiate products CS and CA. Binding of lime by CS and CA with formation of C2S, C3A and C4AF. Formation of belite and liquid phase (aluminate and ferrite melt).
1250 - 1450
Further binding of lime by C2S to Form C3S. Completion of reaction and re-crystallization of alite and belite.
1300 - 1240
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TABLE OF CONTENTS
PROCESS
Outlines
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Fuel flow. Material flow. Gases flow. Grate cooler. Firing hood. Pressure & temperatures. Main drives torque. Sintering zone temperature. CO gas percentage.
OPERATION
Action & reactions
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Kiln feed. Kiln speed. Preheater fans speed. Fuel. Auxiliary parameters - Grate speed. - Cooler fans. - Gravel fans dampers. - By pass fan & damper. - Fresh air fans damper.
CALCULATIONS
Process Chemistry Grate cooler Cooler fans Kiln refractory
A. Introduction
- Generally part of chemical processes start to take place in the preheater tower cyclones as the material is heated to 820 C by the hot kiln gas. This is includes the evaporation of free and absorbed water, the initial decomposition of the clay and a decomposition of a part of the carbonates. - The chemical processes taking place at higher temperature after the decomposition of the carbonates are different and more time consuming. They are also accompanied by the melting of apart of material that transforms the dry particles into clinker nodules. - The chemical and physical reactions takes place in the kiln are described in the following from an operational point of view, and relates the various reactions taking place to the zones inside the kiln and production parameters. - In order to obtain a steady flow of clinker with uniform and predictable properties, with minimum energy consumption, and fully utilizing the capacity of the kiln system, it is indispensable to understand the production parameters which influence process. - The chemical reaction determine the formation of the hydraulic minerals alite( C3S) belite (C2S), aluminates (C3A) and ferrite (C4AF). The properties of the cement depends not only on the potential contents of these minerals in the clinker which are determined by the chemical composition of the kiln feed, but also on the degree to which the synthesis of these completed in the kiln. - The clinker formation refers to the physical agglomeration processes which under favorable conditions, result in clinker nodules with diameters of 2-20 mm. - This nodule size is adequate for treatment in the cooler and normally indicates a satisfactory grind ability. - Problems in controlling the clinker formation do not necessarily influence the quality of the final cement, but frequently result in difficulties of kiln and cooler operation and may also result in a product that is difficult to grind.
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1. Calcinig zone
- Generally the calcinations takes place in the preheater tower 90 % and the result happens in the kiln. - It is in the calcining zone (CZ) that the decarbonation of the carbonates in the raw meal takes place. This may also be considerable formation of C2S taking place here. - Carbon dioxide dissociates from the kiln feed and is carried a way by the kiln gases. Kiln feed that is not completelycalcined before it enters the burning zone is difficult to burn and is a major cause of kiln disturbances. Thus a complete calcinations of the kiln feed before it enters the burning zone is required for proper kiln operation. - The overall process of decarbonization requires a great quantity of heat and consequently, the material temperature rises only slowly along the zone in the range 820 - 900 C. However as soon as all the CO2 has been expelled, the temperature rises rapidly.
2. Heating zone
- AT the end of calcining zone the material temperature is a above 900 C. - The heating zone is characterized by a sudden rise in the temperature of the kiln charge, as the calcinations processes comes to completion and formation of the interterm-phases takes place. - Thus, the reactions between CaO and Al2O3 and between CaO and Fe2O3 of the lime and clay particles continue in the heating zone with the formation of several intermediate minerals. Which are stable only within narrow temperature limits. - Since no heat consuming reactions take place, the temperature rises rapidly in this zone. Upon a sufficient increase in temperature normally 1300 -1350 C a significant
amount of liquid phase is suddenly formed a short distance in the kiln thus terminating the heating zone.
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3. Liquid zone
- This zone begins at temperatures 1300 - 1350 C where the liquid phase is formed. - The liquid phase content depends on the chemical composition and increase very little as the temperature increases. Normally the liquid phase properties do not change as the temperature increases, even though the viscosity decreases a little. - The liquid zone is the most important zone with respect to the nodulization of clinker. The formation of nodules and their size depends on the quantity and the properties of the liquid phase the size distribution of the solid particles in the feed and the residence time of the material in the liquid zone. - Nodulization starts by capillary bounding in which the individual particles are held together by the liquid. As the clinker grows in the size capillary bounding is very quickly succeeded by crystal bounding in all cases where two particles have different chemical composition. Such as one rich in lime (CaO) and one rich in silica C2S. In this process the particles form a solid union by diffusion and crystallization through the fluid bridge which is they replaced by a solid bridge consisting of C3S. - In order to secure a good nodulization, it is of importance that the liquid zone is sufficiently long. The relative length of the zones can be changed by modification of the temperature profile or by changing the characteristics of the raw mix with respect to its burnability.
4. Sintering zone
- At the point where the amount of C3S has reached its highest value, the nodulization stops and the sintering zone (SZ) begins. In this zone which is directly under the illuminated part of flame, the dominant processes are the formation and growth of individual C3S particles and their bounding to each other. - Essentially, this mean that the chemical reactions are limited by diffusion velocity of the reactants in the liquid phase.
5. Cooling zone
- The cooling zone (AZ) begins when the material start to solidify. - The chemical reactions also occur here in the last section of the kiln. The proportion of C3S mineral will always decrease during cooling and the slower the cooling the greater the decrease. Some of this mineral will be converted to C2S with the release of CaO which immediately combines with the unstable C-A minerals form C3S. - The conversion from to C3S to C2S certainly will affect clinker grinding as C2S is more difficult to grind than C3S.
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- During the burning process we may have different behavior resulting from burning the raw mix having concentration of elements higher in their limits than the permissible range. It is therefore necessary to distinguish between the following :
1. Coating
In the cement kiln is the desired protective layer on the refractory lining. Which is formed during the kiln operation under the influence of high temperature from the traveling material on the refractory lining in the transition and sintering zones.
2. Ring Formation
Is an undesired degree of growth coating.
3. Incrustations
Referred to as build ups, are coatings which are formed below 1100 C by alkali salt and which occur particularly in the preheater tower.
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A. Significance of coating
Coating has the following functions to fulfill :
1. Protection of the refractory brick against over heating. 2. Protection of refractory lining against the abrasive effect of the moving clinker bed and dust. 3. Protection of the refractory lining against the chemical attack of clinker constituents, fuel Ash and Gas atmosphere. 4. Reduction of heat radiation and protection of the kiln shell against thermal overloading. 5. Augmenting the mixing effect, improvement of the blending effect of the clinker due to the unevenness of the coating surface. 6. Increasing the retention time inside the kiln.
B. Formation of Coating
Two basic hypothesis are plausible as to the mechanism of coating formation :
1. Formation of clinker melts ( above 1280 C ) and their sticking together with the refractory lining with simultaneous cementing to solid particles. 2. Adhesion of solid crystalline phases on the refractory lining. - In both cases, chemical and / or physical reactions (impregnation / infiltration ) with the upper zone of the brick strengthen the adhesion of the coating.
C. Thickness of Coating
- Usually, the following classification is applied as to the thickness of coating : 30 - 50 cm 20 - 30 cm 0 - 10 cm thick coating normal coating thin coating
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Process
Outlines
1.
Fuel Flow
1. Fuel oil should be hot 70 C at least, to make sure the fuel oil is not viscous, but meanwhile the fuel oil temperature should not exceed 130 C to prevent the fluctuation of the fuel oil high pressure pump. 2.The calorific value of the fuel oil. The calorific value of the fuel oil is the energy that we can get from burning one Kilogram of fuel oil with the needed Oxygen this value is 9600 Kcal / Kg. 3.The heat consumption. It is the quantity of heat that you need to get one kilogram clinker That value is = 850 Kcal / kg clinker. 4.Excess air. It is the air more than the air needed for making sure that you have complete combustion. 5.Excess Fuel. It is phenomena happen when you do not enough air for burning this fuel.
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2.
Material Flow
By Pass system
- This system is made to get rid of alkalis from material, these alkalis concentrates as a solid in 900 C, if these alkalis gets into kiln its temperature gets higher than turns from solid state immediately to gases state this phenomena called " Circulation phenomena " - To prevent any circulation in kiln inlet, we take these alkalis out of system and dilute it with fresh air to decrease its temperature. But we do not take all of these alkalis to prevent loosing heat material we take what just make the quantity of the alkalis is stable.
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N.B : - If we do not take these alkalis after a while it will block the kiln inlet ( the narrow cross section ). < 900 C Alkalis is in solid state, acts like material action and goes in the same direction. Alkalis is in gaseous state, acts like gases action and turn back into the preheater tower.
1000 C
- Then the new material got its alkalis with the old ones so, the concentration of alkalis gets higher and blocks kiln inlet and mixing chamber.
3.
Gases Flow
This air is only used to take material from feeding bins of kiln up to feeding pipes in the second stage. On the other hand this air is not hot so we loose some temperature we put it in the system , and we consider it as a load on the preheater fans.
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4.
Grate Cooler
Cooler Hoppers
These hoppers are made to prevent loosing air given by cooler fans, these hoppers have plates from inside like stiffener to prevent the abrasive effect of the fine clinker collected by these hoppers. And on the other hand we never let these hoppers get empty because the fine clinker make a seal to prevent any pressure drop under the grate cooler chambers.
Rules :
1. Pressure reversely proportion to Velocity. 2. Pressure reversely proportion to Volume flow rate. 3. Flow direction. negative pressure more negative pressure 4. Under the grate is the only place in the system that has a positive pressure. 5. Retention Time : time needed for heat transfer 6. Bernoulli equation.
2 2
V1 2g
Z1
P2 y
V2 2g
Z2
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A. First Case
Thick Clinker Bed : 1. The retention time will be longer so the air passing through the clinker bed takes longer time for heat transfer ( by conviction ), so the hot air in cooler will have higher heat. 2. When the bed of clinker gets higher the air under the grate that wants to pass through that clinker bed will face bigger resistance to pass through. That mean that if we made a set point of 55000 m3 / hr in the fan 1 not all this air will pass. So : a. Air pressure inside the cooler ( P1 ) will be lower. b. The volume flow rate ( Q1 ) of air in the cooler will be smaller. c. Air pressure under the grate ( P2 ) will be higher. d. The volume flow rate ( Q2 ) of air under the grate will be smaller. Then after that, the flowmeter of this fan will feel that and gives a command to open a little more the damper of that fan to give more air to achieve the set point.
B. Second Case
Thin Clinker Bed : 1. The retention time will be shorter so the air passing through clinker bed takes shorter time for heat transfer so the hot air over the grate will have less heat. 2. When the air is passing through the thin clinker bed it will face less resistance, then the volume flow rate ( Q1- Q2 ) will be over and under the grate bigger. The pressure over the grate ( P1 ) will be over the normal. The pressure under the grate ( P2 ) will be lower. N.B : The clinker bed has another task to protect cooler plates from the heat and abrasion.
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5.
Firing hood
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6.
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The relation between the calciner temperature and the Pressure inside the preheater tower
1. When the temperature gets higher, the pressure also goes up then the velocity of gases goes down so, the quantity of material carried by gases is less than ever. 2. The material now is less so, the volume flow rate of gases is low so, the pressure goes down and velocity of gases now is higher so, the gases carries more material. This circulation is going on and till temperature in the preheater tower goes down. # When the material ( not carried by gases ) goes down so, the heat transfer of this material is not completed. So , the calination degree is less than ever so, the material needs a lot of heat to be clinker. So the kiln gets cold. # The decrease of preheater fans speed can help in this case.
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7.
N.B :
KA of main drives is not actually the torque but it is the power consumption of these drives.
Torque performance
At the steady state, nothing have be changed nothing have be increased or decreased
First Case :
Bending stress Thermal stress This case is rare ( PPM of kiln not suitable to feed ) ( heat consumed by raw meal inside kiln )
heat for this quantity of material is big but we have not increase the fuel so the heat remaining inside the kiln will be distributed on the material so, the material is not hot enough so, we can see that the sintering zone will decrease. When the thermal stress is higher due to the heat content of material inside the kiln. The material is well calcined and the heat needed to complete the calcinations is available and more so the material got what it wants and more the figure of heat content so, the kiln heat is higher. The sintering zone will increase. Bending S. and Thermal S. S.Z and S.Z equal ??
We know that any stress beat the other by the difference of S.Z temperature but the torque will increase any way. Tq
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Second Case :
Bending stress Thermal stress This case is the contrary of the last one. S.Z Tq ?
Third Case :
Bending stress Thermal stress S.Z Tq This case level of material is higher than should be.
Fourth Case :
Bending stress Thermal stress S.z Tq
Because of :
1. Hard to burn material. 2. Coarse material. 3. High Silica content. 4. LSF high.
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8.
The temperature is a result of all what happens in the system and it may tell us what to do to prevent any damage. This indication has an effect on properties of the product ( clinker ). This indication mainly is an indication of heat transfer. The range of this temperature is 1300 C - 1400 C with an optimum of 1350 C.
9.
CO % ( Carbon monoxide )
The gas analyzer that give us this value is between the preheater fan and the preheater tower. Tells us the quantity of CO in the whole system. If this gas was from preheater tower when us increase the fuel in the precalciner burners only the CO will increase but if it was from the kiln when you increase the precalciner fuel the calciner temperature and the CO % will both increase.
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Operation
Actions & Reactions
1.
Kiln Feed
Cases of increasing kiln feed :
The preheater temperature should preferably be higher than the usual temperature about 20 C. The cooler fans dampers should be as usual state of operation to prevent any thermal shocks on the grate cooler plates. At the cooler, as there is no clinker bed so there is no heat transfer between air from cooler fans and clinker, the air going to the tertiary air duct and to the kiln ( as secondary air for burners ) will be cold, so we must increase fuel more than the normal case. The kiln speed should be more than the usual speed according to the kiln feed because we want to sure that thermal stresses is the main increasing stresses on the main drives torque not bending stresses. The preheater fans speed should be more than normal speed according to the kiln feed to prevent the appearance of CO % gas inside the system, and to have higher suction than normal to prevent any accumulation to material inside the preheater tower ( narrow ducts ). Generally preheater fans speed should be 75 - 80 %.
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d) Easy to burn material. We can use this way by using the easy material from the storage silo, but this may make an unbalanced state inside the kiln like heating it up which may cause the case of the fallen coat so it is not preferred in several cases and this material is not always available. e) Firing hood pressure increasing. We can increase the firing hood pressure that gives you big response in system at the smallest change this way is not preferred when the system is not very balanced. # Sintering zone temperature - we prefer that this temperature would be in it is upper range 1400 - 1450 C. if it is in the lower range ( 1350 - 1400 C ) So, no way to increase the kiln feed. # Main drives torque # Level of material : should be stable should not fall down by thermal stresses. this step should be the first one in the way of increasing the kiln feed to make any problem from this increasing action, it should be checked up visually first . ( should not exceed 17 % ).
# Increasing the feed must be proportional to gained conditions inside the system.
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in the preheater tower and the kiln. In the rate condition, sintering zone temperature is getting high and the torque getting down which means that the level of the material is getting lower, the preheater tower temperatures must be stable.
Action :
First : increasing the feed by certain amount corresponding the changing of conditions inside the kiln. Second : controlling preheater temperature ( fuel - preheater fan speed ). # When the litter weight gets over 1250 - 1300 g / Lt. then there is availability to increase the kiln feed.
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N.B : A. Silica This component have nothing to do with calcinations degree which is CaCo3 Silica ratio CaO + CO2
SR
= Al2O3
SiO2 +
B. Aluminum This component make the burnability higher but on the other hand more ( AR ) make balls and rings inside the kiln.
AR
Al2O3 Fe2O3
C. Lime Saturation Factor This value gives a figure of the entire composition of the kiln feed.
LSF
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Range 90 - 105 Less than 90 gives us C3S % low More than 105 gives us less burnability
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Action :
1. Decrease fuel in the main burner. 2. Decrease preheater fan speed. 3. Making the firing hood pressure more negative. 4. Increase the flow of V1 - V2 - V3
Normally the overheated case happens after starting the feeding of kiln.
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5. Fluctuation of kiln speed is higher than it should. - Electrical problem ( dosing schenck ). - Production problem : Air left ( Aeration ). 6. Fluctuation of precalciner fuel higher than it should.
B. In the kiln
1. High fluctuation in fuel of main burner. 2. Main burner position and the flame shape ( Axial air - Radial air ). 3. Firing hood pressure. 4. Under grate pressure. 5. High fluctuation of kiln feed. 6. Fluctuation of raw mix. Composition ( LSF ).
Action :
1. Decrease kiln feed. 2. Decrease preheater fans speed. 3. Decrease kiln speed. 4. Decrease cooler fans speed. 5. Preheater tower check up and cleaning ( Cyclones - Tipping flaps ). 6. By - Pass system check up and cleaning ( kiln inlet - mixing chamber ). 7. Kiln check up visually ( level of material ).
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the volume flow rate of gases gets higher so the retention time will be shorter than the last case so, the transfer will be bad ( material do not take from gases ). The firing hood pressure fluctuate, Sintering zone temperature fluctuate and the under grate pressure also fluctuate.
So, the under grate every time acts a different action caused by the weight of this clinker so the under grate pressure fluctuates.
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2.
Kiln Speed
I.
A. Steady state : 1. When the litter weight is high. 2. When the kiln is getting hot. 3. When we have heavy coat. 4. When the level of material is getting high. 5. When the coat is falling. 6. When we have a ball ( in steady state ). B. Unsteady state : 1. When the kiln is filled. 2. When we have a ball. 3. When we have a ring.
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II.
A. Steady state : 1. The litter weight is low. 2. The kiln is getting cold. 3. Hard to burn material. B. Unsteady state : 1. When the under grate pressure fluctuating we decreases the kiln speed to extend the time needed to regulate the clinker bed on the grate. 2. When the kiln is getting cold we decrease the speed to increase the retention time and decrease the flow rate of material.
3.
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Kiln Start up :
The minimum speed should be 75 - 80 % to prevent any blockage in the cyclones and we increase the preheater fans speed according to the appearance of the CO %.
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4.
Fuel
Main burner fuel
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Flame Shape
2. Axial Air :
Open : Long Flame Close : Short Flame
2. Secondary Fuel :
Open : Narrow Long Flame Close : Wide Short Flame
N.B :
Adjustment by air is more effective than the fuel. Adjustment by by fuel is for fine tuning. Primary fuel is proportional to the secondary fuel.
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Flame Shape
1. When we make the flame wide and short ?
a) If we want to make coat in first 10 meter in the kiln. b) If we want to heat up kiln hood. c) If we want to loose the coat inside the kiln 20 m. d) If we want to decrease the main drives torque.
N.B :
We never want to loose the kiln hood coat because its unstable coat. For the fine adjustment we might use the secondary and primary fuel. Also, we can remove the sintering zone by changing the carriage position ( not recommended ).
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Precalciner Fuel
A. Increasing the fuel
At the steady / unsteady state : 1. To heat up the preheater. 2. To increase the calcinations degree. 3. To increase the main drive torque.
N.B :
Calciner temperature should not exceed 850 C.
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5.
Auxiliary Parameters
1. Grates Speed
We control it as a set point of the under grate pressure. The normal cases to have an automatic control on the grates speed.
2. Cooler Fans
Generally we increase the cooler fans to cool the clinker. V1 , V2 , V3 These fans are quenching fans and have a direct effect on the under grate pressure and the quality of clinker ( C3S % ). The increase of the flow of these fans increases the under grate pressure and vice versa. End fans in cooler for cooling clinker only.
N.B :
How to slow down the speed of grates without changing the set point of the under grate pressure ?
We can decrease the first cooler fan V1 , V2 , V3 then the under grate pressure decreases ( actual value ) so, the grates speed slow down.
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N.B :
The main task of the gravel fans is to get rid of the not needed air and to make the negative pressure in the system. The gravel filter is installed to collect the fine dust of clinker going with the air of the cooler fans.
to change the suction inside the kiln. The conditioning tower inlet temperature should not exceed 450 C.
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By-Pass flow
By-Pass gases= Cooling air flow.[T mixing chamber- Tambient] / [Tkiln inlet- Tmixing chamber]
Rate of By-Pass
Eng:Elwathig Ahmed
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filling degree
feed 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135 speed 1.341 1.49 1.639 1.788 1.937 2.086 2.235 2.384 2.533 2.682 2.831 2.98 3.129 3.278 3.427 3.576 3.725 3.874 4.023 fillingspeed/feed ratio 12 0.0298 12 0.0298 12 0.0298 12 0.0298 12 0.0298 12 0.0298 12 0.0298 12 0.0298 12 0.0298 12 0.0298 12 0.0298 12 0.0298 12 0.0298 12 0.0298 12 0.0298 12 0.0298 12 0.0298 12 0.0298 12 0.0298
1)
2)
speed 1.287 1.43 1.573 1.716 1.859 2.002 2.145 2.288 2.431 2.574 2.717 2.86 3.003 3.146 3.289
filling 12.5 12.5 12.5 12.5 12.5 12.5 12.5 12.5 12.5 12.5 12.5 12.5 12.5 12.5 12.5
ratio 0.0286 0.0286 0.0286 0.0286 0.0286 0.0286 0.0286 0.0286 0.0286 0.0286 0.0286 0.0286 0.0286 0.0286 0.0286
3)
speed 1.2375 1.375 1.5125 1.65 1.7875 1.925 2.0625 2.2 2.3375 2.475 2.6125 2.75 2.8875 3.025 3.1625 3.3 3.4375 3.575 3.7125
filling 13 13 13 13 13 13 13 13 13 13 13 13 13 13 13 13 13 13 13
ratio 0.0275 0.0275 0.0275 0.0275 0.0275 0.0275 0.0275 0.0275 0.0275 0.0275 0.0275 0.0275 0.0275 0.0275 0.0275 0.0275 0.0275 0.0275 0.0275
4)
speed 1.1925 1.325 1.4575 1.59 1.7225 1.855 1.9875 2.12 2.2525 2.385 2.5175 2.65 2.7825 2.915 3.0475 3.18 3.3125 3.445 3.5775
filling 13.5 13.5 13.5 13.5 13.5 13.5 13.5 13.5 13.5 13.5 13.5 13.5 13.5 13.5 13.5 13.5 13.5 13.5 13.5
ratio 0.0265 0.0265 0.0265 0.0265 0.0265 0.0265 0.0265 0.0265 0.0265 0.0265 0.0265 0.0265 0.0265 0.0265 0.0265 0.0265 0.0265 0.0265 0.0265
5)
feed 45 50 55 60 65 70 75 80 85 90 95 100
speed 1.1475 1.275 1.4025 1.53 1.6575 1.785 1.9125 2.04 2.1675 2.295 2.4225 2.55
filling 14 14 14 14 14 14 14 14 14 14 14 14
ratio 0.0255 0.0255 0.0255 0.0255 0.0255 0.0255 0.0255 0.0255 0.0255 0.0255 0.0255 0.0255
14 14 14 14 14 14 14
6)
speed 1.4625 1.625 1.7875 1.95 2.1125 2.275 2.4375 2.6 2.7625 2.925 3.0875 3.25 3.4125 3.575 3.7375 3.9 4.0625 4.225 4.3875
filling% 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11
ratio 0.0325 0.0325 0.0325 0.0325 0.0325 0.0325 0.0325 0.0325 0.0325 0.0325 0.0325 0.0325 0.0325 0.0325 0.0325 0.0325 0.0325 0.0325 0.0325
6)
speed 1.395 1.55 1.705 1.86 2.015 2.17 2.325 2.48 2.635 2.79 2.945 3.1 3.255 3.41 3.565 3.72 3.875 4.03 4.185
filling% 11.5 11.5 11.5 11.5 11.5 11.5 11.5 11.5 11.5 11.5 11.5 11.5 11.5 11.5 11.5 11.5 11.5 11.5 11.5
ratio 0.031 0.031 0.031 0.031 0.031 0.031 0.031 0.031 0.031 0.031 0.031 0.031 0.031 0.031 0.031 0.031 0.031 0.031 0.031
we found the optimum filling2) degree for our kiln between the range (13-14%) by operations experiments