Scribd
Upload
272 views3 pages

Online Test On Chemical Thermodynamics and Energetic PDF

This document is a chemistry test on chemical thermodynamics and energetic properties. It contains 7 multiple choice questions testing concepts like endothermic reactions, heat of solution, Hess's law, intensive/extensive properties, and the first law of thermodynamics. The test also includes several multi-part questions asking students to calculate enthalpy changes, explain concepts like enthalpy and cyclic processes, derive expressions related to thermodynamics, and solve problems involving work done by gases and ideal gas properties.

Uploaded by

rvignesh2809
Copyright
© Attribution Non-Commercial (BY-NC)
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
272 views3 pages

Online Test On Chemical Thermodynamics and Energetic PDF

This document is a chemistry test on chemical thermodynamics and energetic properties. It contains 7 multiple choice questions testing concepts like endothermic reactions, heat of solution, Hess's law, intensive/extensive properties, and the first law of thermodynamics. The test also includes several multi-part questions asking students to calculate enthalpy changes, explain concepts like enthalpy and cyclic processes, derive expressions related to thermodynamics, and solve problems involving work done by gases and ideal gas properties.

Uploaded by

rvignesh2809
Copyright
© Attribution Non-Commercial (BY-NC)
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 3

Chemistry - Chemical Thermodynamics and energetic

[Time : 90 Mins] SOLUTION OF TEST [Max. Marks : 35]

Note : 1. Chemical Thermodynamics and energetic Properties chapter Weight-age total 8 marks. 2. All questions are compulsory. 3. Draw neat and labelled diagram wherever necessary. 4. Figure to the right indicates full marks. 5. Answer to every new question must begin on a new page.

Q.1
I. I. 1.

Multiple choice questions:[1 mark each]


Objective Type Questions Choose the correct answer: An endotherrnic reaction is one in which heat content of (a) Products is more than that of reactants. (b) Reactants is more than that of products (c) Reactants and products is same (d) None of these

2.

Heat of solution may be defined as (a) Change in heat content of the system when one gram molecule of the solute is dissolved in large excess of water, so that further dilution of solution produces no heat exchange. (b) Heat evolved, when one gram molecule dissolves in large excess of water (c) Heat required to dissolve one gram molecule in large excess of water (d) None of these

3.

According to Hess's Law, the thermal effects of reaction depends on (a) initial conditions of reactants (b) initial and final conditions of reacting substances (c) final conditions of reacting substances (d) intermediate states of a reaction.

4.

Which of the following is an intensive property? (a) Enthalpy (b) Mass

Ideal 21st Century Competitions

www.21stideal.com 1

(c) Temperature 5.

(d) Volume

Which of the following is not the statement of the 'first law of thermodynamics'? (a) Whenever a quantity of one form of energy disappears, its equivalent in other form makes its appearance. (b) Energy can neither be created nor destroyed though it may be converted from one form to another. (c) It is impossible to make a perpetual machine which would produce work without consuming energy. (d) Matter can neither be created nor destroyed.

6.

Internal energy of a system of molecules is determined by taking into account its (a) kinetic energy (b) vibrational movement (c) rotational movement (d) all of these

7.

In a reaction involving only solids and liquids, the heat of reaction at constant volume (a) is equal to the heat of reaction at constant pressure (c) is greater than heat of reaction at constant pressure (c) is less than heat of reaction at constant pressure (d) has no relation with heat of reaction at constant pressure

Q.2 1.

Answer the following question [Attempt any SIX]


For a reaction B2H6(g) + 3O2(g)B2O3(s) + 3H2O(l) E = - 2143.2 kJ at 25C. Calculate the enthalpy change (H) for this reaction. (R = 8.314 JK-1 mol)

2. 3. 4. 5. 6. 7. 8.

What is meant by enthalpy of a system?

Explain that the energy change in cyclic process is zero.


Derive the expression for enthalpy change. Explain enthalpy change in isochoric process and adiabatic process. Show that 'Heat absorbed at constant pressure is nothing but change in enthalpy of a system'. Prove that the change in enthalpy in a process is independent of the path taken.

State the condition when work done by a gas is zero.

Ideal 21st Century Competitions

www.21stideal.com 2

Q.3
1. 2.

Answer the following question [Attempt any THREE]


What are the types of system? In what way internal energy is different from enthalpy? Explain both the terms with the help of examples.

3. 4.

State Kirchoff s equation. What is the importance of Kirchoffs equation? Explain sign conventions of q, W and U.

Q. 4
1.

Two sub-questions of 7 marks each(Attempt any ONE)


Derive the expression for the work obtained in an isothermal reversible expansion of an ideal gas. Derive the expression for maximum work.

2.

Derive a relation, qp = qv + H = U + nRT.

Ideal 21st Century Competitions

www.21stideal.com 3

You might also like