CMEN 332 - Chemical Engineering Thermodynamics II Winter Quarter 2013-2014

Instructor !aniela Mainardi Associate Professor and Chair of Chemical Engineering E-Mail: [email protected] Office: IfM121 Phone: 257-5126

"##ice $ours %ll in I#M121 Mondays !ednesdays " #ridays '(esdays " 'h(rsdays 2:$%PM - &:$%PM ):$%AM - 11:$%AM

Questions &y e-mail are al'ays 'elcome( I 'ill try to ans'er them as soon as I can Te)t *mith +,M, -,C, .an /ess and A00ott M,M, Introd(ction to Chemical Engineering 'hermodynamics *e+enth edition Mc1ra2--ill 2%%5, "utcomes At the end of the co(rse the st(dents 2ill 0e a0le to: 3se a44ro4riate e5(ations of state 67irial e5(ation of state and c(0ic e5(ations of state s(ch as the 7an der !aals 67d!8 Peng9:o0inson 6P:8 and :edlich-;2ong 6:;88 and ta0(lated 4ro4erties of com4o(nds 2hen sol7ing 4ro0lems in7ol7ing 4(re s4ecies, 3se models for 7a4or-li5(id e5(ili0ri(m s(ch as the :ao(lt<s =a2 modified :ao(lt<s =a2 and the 1amma9Phi form(lation to sol7e 4artic(lar 4ro0lems on 4hase e5(ili0ria, A44ly the ac5(ired >no2ledge on the thermodynamics of gas mi?t(res to inter4ret and sol7e 4ro0lems dealing 2ith real and ideal gases (sing conce4ts s(ch as f(gacities 6f8 and f(gacity coefficients 68, A44ly the ac5(ired >no2ledge on sol(tion thermodynamics to inter4ret and sol7e 4ro0lems dealing 2ith real and ideal li5(id sol(tions (sing conce4ts s(ch as f(gacities 6f8 and acti7ity coefficients 68, *elect and (se local com4osition models s(ch as the Marg(les e5(ation the !ilson e5(ation the .an =aar e5(ation the /:'= e5(ation the 3/I@3AC e5(ation and others to calc(late acti7ity coefficients 68 of li5(ids, A44ly the ac5(ired >no2ledge on thermodynamics to inter4ret and sol7e 4ro0lems dealing 2ith 4hase e5(ili0riaA in 4artic(lar 7a4or-li5(id e5(ili0ri(m 6.=E8 li5(id-li5(id e5(ili0ri(m 6==E8 and solid-li5(id e5(ili0ri(m 6*=E8, Inter4ret and sol7e 4ro0lems on chemical reaction e5(ili0riaA 4artic(larly in7ol7ing calc(lations of heat of the reaction 6 -B8 1i00s #ree energy of the reaction 6 1B8 e?tent of the reaction 68 and e5(ili0ri(m constants 6;8 for single and m(lti-reactions, ,re-re-uisites 'hermodynamics I 6E/1:222C8 Physical Chemistry 6C-EM$11C8 Differential E5(ations 6MA'-2&5C8 and MA'- 2&1-2&& 1PA E 2,%, C 1rade of C or higher re5(ired 0efore ta>ing a co(rse for 2hich this one is a 4rere5(isite, *t(dents 2ho do not meet the 4re-re5(isite re5(irements must N"T ta>e CME/$$2 this 5(arter,

.ou are e)/ected to 0no' IN !ET%I1 the #ollo'ing cha/ters2sections o# the &oo0 3y *mith and 4an Ness Cha/ters 1 5all67 2 5all67 3 5sections 3817 3827 and 38367 4 5all67 9 5all67 : 5section :8167 ; 5all67 < 5all67 = 5all67 10 5all6 %ttendance E7ery st(dent 2ill sign (4 a class roll gi7en 0y the instr(ctor at the 0eginning of each class, 'here is 9 MIN T"1E>%NCE "N1.????? 'he attendance reg(lations of the =o(isiana Foard of 'r(stees for -igher Ed(cation 2ill 0e o0ser7ed, 'hese are 4osted thro(gho(t the 3ni7ersity and are 4rinted in the 3ni7ersity F(lletin Class attendance is regarded as an o0ligation as 2ell as a 4ri7ilege, All st(dents are e?4ected to attend reg(larly and 4(nct(allyA fail(re to do so may Geo4ardiHe a st(dent<s scholastic standing and may lead to s(s4ension from the (ni7ersity %&sences cannot &e @ 10A o# the total classes 52 classes8, If yo( miss more that 2 classes and yo( do not ha7e a good e?c(se your BIN%1 C>%!E M%. 3E !>",,E! 1A ,E> EDT>% C1%** MI**E!8 %ccommodations #or students 'ith disa&ilities *t(dents needing testing or classroom accommodations 0ased on a disa0ility are enco(raged to disc(ss those needs 2ith me as soon as 4ossi0le, Please hand me a co4y of the letter from the 3ni7ersity stating it, Crading *cale Crading E?am L1MMMMMM,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,25I E?am L2 6in class N ta>e home com4onents8,,,,,,,,,,,,$%I E?am L$MMMMM,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,M,,25I A7erage 1ro(4 2or>MMMMMMMMMMM,MM,,2%I 1%%I Earn e)tra /oints?? $o'EE Fon(s Point com4rehensi7e 4ro0lem 6O4tional8 %&out E)ams %11 e?ams9tests 2ill 0e ",EN &oo07 notes7 and assignmentsA 0(t they 2ill 0e C=O*ED neigh0or C=O*ED cell 4hone and C=O*ED e7erything elseOOO Cell 4hones and other digital media m(st 0e Hi44ed (4 in yo(r 0ac>4ac>94(rse or gi7en to the instr(ctor d(ring e?ams, Missed e)ams2tests cannot &e made u/ (nless the st(dent has a 7alid e?c(se for 3ni7ersity medical or legal reasons 6that is the st(dent is in7ol7ed in 3ni7ersity f(nctions is hos4italiHed on trial or G(ry d(ty or other2ise 4hysically (na0le to 0e in class8, In any other case7 the corres/onding grade 'ill &e an F, The com/rehensi+e &onus /oint /ro&lem is o##ered "NCE 6together 2ith E?am L$8 and 2ill gi7e yo( the o//ortunity to earn F, T" 10 &onus /oints that 2ill 0e added to the grade on either E?am L1 E?am L2 E?am L$ or s4read among the grades on those e?ams, )%I - 1%%I J AA K%I - K)I J FA 7%I - 7)I J C 6%I - 6)I J DA %I - 5)I J #

W%>NINC a&out cheating on E)ams?? *t(dents sho(ld 0e a2are that Pd(ring an e?am referring to information not s4ecifically allo2ed 0y the instr(ctor or recei7ing information from another st(dent or another (na(thoriHed so(rceP is a 7iolation of the honor code and can 0e met 2ith se7ere sanctions against the st(dent, #or details refer to htt4:99222,latech,ed(9doc(ments9honor-code,4df, Cheaters 'ill &e re/orted to the Fni+ersity authorities8

%&out Crou/ Wor0 1ro(4s of no more than 5 st(dents 6each8 2ill 2or> together on home2or> 4ro0lems 65 4ro0lems 4er 1ro(4 !or>8, A0o(t 15 min of in-class gro(4 2or> 2ill 0e dedicated 4er assignment, 'he 2ritten 7ersion of %11 sol+ed /ro&lems MF*T 3E TF>NE! IN 3. E4E>. *INC1E C>"F, MEM3E> 0y the deadline set 0y the instr(ctor, On the day a 1ro(4 !or> is d(e the instr(ctor 2ill anno(nce 1 /articular /ro&lem each grou/ mem&er 'ill &e res/onsi&le #or and that student 'ill ha+e only that /ro&lem graded, -ence "N1. 1 C"M,1ETE 4E>*I"N "B T$E C>"F, W">G WI11 3E C>%!E! ,E> C>"F, and assigned an O.E:A== 1:ADE 6O18, Each st(dent<s contri0(tion to the 1ro(4 !or> 2ill 0e assigned a PA:'IA= 1:ADE 6P18 so each 1ro(4 !or> grade 6O18 2ill 0e the s(m of the 4artial grades 6P18, Incom/lete indi+idual 'ritten solutions 6t(rning in less than 5 #3==Q sol7ed 4ro0lems8 &y each grou/ mem&er 'ill &e /enaliHed 2ith 1%I off 4er missed or 4artially 2or>ed 4ro0lem on the P1, =ate s(0missions 0y each gro(4 mem0er 2ill ca(se 2%I off 4er day on the P1, 'he O1 grade 2ill not 0e directly affected, 'he final grade each st(dent 2ill recei7e 4er 1ro(4 !or> is: %,75?P1 N %,25?O1 Only P1s corres4onding to A and B grades 2ill 0e considered in the calc(lation of the O1,

W%>NINC a&out cheating on the Crou/ Wor0OO Cheaters 'ill &e re/orted to the Fni+ersity authorities8 E7en 2hen st(dents are allo2ed to 2or> together in gro(4s they are e?4ected to t(rn in indi+idual 2ritten 1ro(4 !or> If the instr(ctor finds o(t that there are N st(dents t(rning in identically sol7ed 4ro0lems 6no matter i# the /ro&lems are graded or not8 the cheater9s and the one9s 2ho allo2ed their 2or> to 0e co4ied 2ill recei7e Hero /oints on their ,C, 'his 2ill a44ly to st(dents 2ithin the same gro(4 or st(dents in different gro(4s, No a/ologies 'ill &e acce/ted or reconsideration o# /enalty, 'hose P1s 2ill 0e a(tomatically discarded for the calc(lation of the O1A so the rest of the gro(4 is not affected 0y the cheating incident, :e4orted sol7ed 4ro0lems are considered identical 2hen st(dents: o (se same 2ording e7en 2hen the hand2riting is different o 4lace e5(ations in e?actly same 4lace on 4a4er o 4resent same 4lot 2ith same scale same font siHe9ty4e same sym0ols9colors or o sho2 any other s(s4icio(s 6highly similar8 matter -ence after 2or>ing on a 4ro0lem together in gro(4 try to s(mmariHe the information in yo(r o2n 2ords 64ara4hrasing8A ty4e the form(las needed 2ith 4ersonaliHed comments ne?t to them and 4re4are yo(r o2n 4lots 'here is an online /re+ention and detection system a7aila0le to the instr(ctor to identify cheating iss(es so do not try to tric0 your instructor, Cheaters 'ill &e re/orted to the Fni+ersity authorities8

Tentati+e *chedule o# Classes and E)ams Cha/ter 38 4olumetric ,ro/erties o# ,ure Bluids 52 lectures7 1 Crou/ Wor06 - P(re s(0stances - E5(ations of *tate Cha/ter :8 Thermodynamic ,ro/erties o# Bluids 52 lectures7 1 Crou/ Wor06 - 'hermodynamic 4otentials for li5(ids and gases - :esid(al 4ro4erties ED%M I1 Cha/ter :8 Thermodynamic ,ro/erties o# Bluids 51 lecture6 - '2o 4hase systems: 7a4or 4ress(re e5(ations Cha/ter 118 *olution Thermodynamics Theory 53 lectures7 1 Crou/ Wor06 - Chemical 4otential and 4hase e5(ili0ria - #(gacities and f(gacity coefficients: P(re s4ecies - #(gacities and f(gacity coefficients: *4ecies in sol(tion - E?cess 4ro4erties Cha/ter 128 *olution Thermodynamics %//lications 53 lectures7 1 Crou/ Wor06 - Models for the E?cess 1i00s Energy - Acti7ity coefficients Cha/ter 148 To/ics in ,hase E-uili&ria 51 lectures6 - .a4or-li5(id e5(ili0ri(m 6.=E8 ED%M I2 Cha/ter 148 To/ics in ,hase E-uili&ria 52 lectures7 1 Crou/ Wor06 - =i5(id-li5(id e5(ili0ri(m 6==E8 - *olid-li5(id e5(ili0ri(m 6*=E8 Cha/ter 138 Chemical >eaction E-uili&ria 53 lectures7 1 Crou/ Wor06 - :eaction coordinate - M(lti-reaction stoichiometry - *tandard 1i00s and Enthal4y of a reaction - Effect of tem4erat(re on the e5(ili0ri(m constant ED%M I3 J "/tional com/rehensi+e &onus /oint /ro&lem Be& 29 Be& 4 !ec 1=