Micro- and nanostructured surfaces can fulfill a variety of optical and non-optical functions. They can enhance light trapping in solar cells, light outcoupling in LEDs, and control light direction in displays, daylighting, and lighting. The Fraunhofer Institute for Solar Energy Systems develops micro- and nanostructures through modeling, lithography, replication, and characterization. They assist customers in optimizing structures for applications and new functionalities.
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13 e Flyer Microstructured Surfaces Web
Micro- and nanostructured surfaces can fulfill a variety of optical and non-optical functions. They can enhance light trapping in solar cells, light outcoupling in LEDs, and control light direction in displays, daylighting, and lighting. The Fraunhofer Institute for Solar Energy Systems develops micro- and nanostructures through modeling, lithography, replication, and characterization. They assist customers in optimizing structures for applications and new functionalities.
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F R AUNHOF E R I NS T I T UT E F OR S OL AR E NE R GY S YS T E MS I S E
MICRO- AND NANO-
STRUCTURED SURFACES Micro- and nanostructured surfaces can fulfll a variety of different functions. An important application feld is photon management in optical systems. In solar cells, micro or nano scale structures lead to effcient light trapping, enhanced incoupling and improved radiation conversion. In light sources they enhance light outcoupling and homogenity. In daylighting and artifcial lighting elements they defect light in the desired direction. In display applications they are used for antirefection, polarization management, light control or defned scattering. Micro- and nanostructures also play a role in modifying non-optical properties, such as the wettability, adhesion or the surface friction coeffcient. The advantage of microstructured surfaces is that they can be replicated inexpensively in mass production by processes such as hot embossing, injection molding, casting or nanoimprint lithography. For example, many kilometers of microstructured flms can be manufactured by means of UVrepli- cation in a roller embossing process. The Fraunhofer Institute for Solar Energy Systems ISE advances the fundamental understanding of the optics of micro- structured components, modeling, design, production as well as replication and characterization of large-area micro- and nanostructures. With our wide-ranging expertise, we assist customers to optimally usemicro- and nanostructures in optical and non- optical applications and to exploit new functionalities. 1 Near feld calculation of a micro prism array. The color scheme shows the intensity distribution, the white arrows depict the Poynting vectors. 2 In our interference lithography laboratory areas of up to 1.2 x 1.2 m can be structured homogeneously. 3 SEM image of a hexagonal grating fabricated via interference lithography. This grating has a period of 8 m and a height of 9 m. Fraunhofer Institute for Solar Energy Systems Heidenhofstrasse 2 79110 Freiburg Germany Phone +49 761 4588-0 Fax +49 761 4588-9000 www.ise.fraunhofer.de Dr Benedikt Blsi Phone +49 761 4588-5995 [email protected] Dr Hubert Hauser Phone +49 761 4588-5992 [email protected] June 2013 1 2 3 Replication Microstructures are of particular interest when they can be produced cost effectively and in large quantities using micro- replication processes. We evaluate various replication techniques, each suitable for distinct applications. One option is electroplating to fabricate multiple metal copies of one master structure (so-called shims). These shims can be used e. g. in hot embossing or injection molding processes. They also can be used to pattern UV-curing materials, which is even possible in roll-to-roll processes. Direct replications from a photoresist or a metallic tool are possible in fexible, transparent or opaque materials (soft embossing) by using silicone materials. Structures made from such resilient mate- rials enable special surface functionalities (e. g. the gecko effect) or can be used for further processing steps. In nanoimprint lithography (NIL)high-reso- lution etching masks can bestructured in a high-throughput process. We developed a roller-NIL tool that allows the patterning of such etching masks on uneven, stiff, brittle and opaque substrates (e. g. multicrystal- line silicon) on large areas in a continuous process. Modeling and Design
We make use of various modeling tools covering the entire range of optical effects from wave to ray optics. The objectives are to understand the optical characteristics of micro- and nanostructured materials and to design components or systems with customized functionalities. To this end we provide comprehensive knowledge on the potentials and limitations of the different modeling approaches, the selection of suitable tools and optimized combinations of simulation methods. Interference Lithography In interference lithography, ultraviolet laser beams are split, expanded and superim- posed. A pattern of light and dark areas, the so-called interferogram, is formed in the superposition plane. The interferogram is used to expose photoresist, which is selectively etched in the subsequent development step. A surface relief structure results. With interference lithography we are capa- ble of producing customized, seamless mi- cro- and nanostructures on areas of up to 1.2 x 1.2 m. Depending on requirements, the structure details can be as small as 100nm or as large as 100 m. We provide periodical or stochastical arrangements of structures as well as parabolic, binary or prismatic structure profles. In addition, we can combine different structure geometries and dimensions in one master structure. 4 Roller-NIL-setup for rigid substrates. 5 Metal nanoparticles produced by NIL and lift off (mask not competely removed). 6 Imprinted silicon wafer. 5 Characterization One important aspect of characterizing micro- and nanostructures is measuring their geometry. We provide different measurement methods: n atomic force microscopy (AFM) n scanning electron microscopy (SEM) n optical microscope For optically functional surfaces itisimpor- tant to characterize their optical behaviour. Here a combination of different measure- ment methods is required to ensure a comprehensive evaluation of structured samples. At Fraunhofer ISE we are able to combine several methods: n spectrometry n photogoniometry n spectral ellipsometry Customized Structures for Clients Clients beneft from more than ffteen years of experience in developing customized structures. Our services range from model- ing of production processes and optical functions through to the manufacture and characterization of micro- and nanostruc- tured surfaces. We can provide the whole process chain or just one single part. 6 4