This safety data sheet provides information on Asphasol Supreme, an oil well drilling fluid additive. It is a powder or dust consisting of 60-100% sulphonated organic residuum. The document outlines its identification, composition, hazards, first aid measures, firefighting measures, accidental release measures, handling and storage, exposure controls and personal protection, physical and chemical properties, stability and reactivity, toxicological information, ecological information, disposal considerations, transport information, and regulatory information.
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Asphasol Supreme
This safety data sheet provides information on Asphasol Supreme, an oil well drilling fluid additive. It is a powder or dust consisting of 60-100% sulphonated organic residuum. The document outlines its identification, composition, hazards, first aid measures, firefighting measures, accidental release measures, handling and storage, exposure controls and personal protection, physical and chemical properties, stability and reactivity, toxicological information, ecological information, disposal considerations, transport information, and regulatory information.
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REVISION DATE: 22-Jul-04
SAFETY DATA SHEET
ASPHASOL SUPREME 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING PRODUCT NAME ASPHASOL SUPREME APPLICATION Oil well drilling fluid additive. M-I Drilling Fluids UK Ltd, SUPPLIER Pocra Quay, Footdee, Aberdeen. AB11 5DQ T -44 (0)1224-584336 F -44 (0)1224-576119 EMERGENCY TELEPHONE 001 281 561 1600 (USA) 2 COMPOSITION/INFORMATION ON INGREDIENTS EC No. CAS-No. Name Content Classification SULPHONATED ORGANIC RESIDUUM 60-100% - The Full Text for all R-Phrases are Displayed in Section 16 3 HAZARDS IDENTIFICATION Not regarded as a health or environmental hazard under current legislation. 4 FIRST-AID MEASURES INHALATION Move the exposed person to fresh air at once. Get medical attention if any discomfort continues. INGESTION First aid is not normally required. Rinse mouth thoroughly. Drink plenty of water. SKIN CONTACT Wash skin thoroughly with soap and water. Remove contaminated clothing. Get medical attention if any discomfort continues. EYE CONTACT Promptly wash eyes with plenty of water while lifting the eye lids. Get medical attention if any discomfort continues. 5 FIRE-FIGHTING MEASURES EXTINGUISHING MEDIA This product is not flammable. Use fire-extinguishing media appropriate for surrounding materials. SPECIAL FIRE FIGHTING PROCEDURES No specific fire fighting procedure given. UNUSUAL FIRE & EXPLOSION HAZARDS High concentrations of dust may form explosive mixture with air. SPECIFIC HAZARDS Asphyxiating gases/vapours/fumes of: Carbon dioxide (CO2). Carbon monoxide (CO). Sulphurous gases (SOx). 6 ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS Wear protective clothing as described in Section 8 of this safety data sheet. ENVIRONMENTAL PRECAUTIONS Do not allow to enter drains, sewers or watercourses. SPILL CLEAN UP METHODS Shovel into dry containers. Cover and move the containers. Flush the area with water. Avoid generation and spreading of dust. /3 1 REVISION DATE: 22-Jul-04 ASPHASOL SUPREME 7 HANDLING AND STORAGE USAGE PRECAUTIONS Avoid spilling, skin and eye contact. Avoid handling which leads to dust formation. Provide good ventilation. Mechanical ventilation or local exhaust ventilation may be required. STORAGE PRECAUTIONS Store at moderate temperatures in dry, well ventilated area. Keep containers tightly closed. 8 EXPOSURE CONTROLS/PERSONAL PROTECTION INGREDIENT COMMENTS This material is considered a nuisance dust, OES TWA 4mg/m3 Respirable Dust, 10 mg/m3 Total Dust. PROTECTIVE EQUIPMENT ENGINEERING MEASURES Provide adequate general and local exhaust ventilation. RESPIRATORY EQUIPMENT Respiratory protection must be used if air contamination exceeds acceptable level. Dust filter P2 (for fine dust). HAND PROTECTION No specific hand protection noted, but gloves may still be advisable. For prolonged or repeated skin contact use suitable protective gloves. Nitrile. or Neoprene. EYE PROTECTION Wear dust resistant safety goggles where there is danger of eye contact. OTHER PROTECTION Wear appropriate clothing to prevent repeated or prolonged skin contact. Provide eyewash station. HYGIENE MEASURES No specific hygiene procedures noted, but good personal hygiene practices are always advisable, especially when working with chemicals. 9 PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE Powder, dust COLOUR Brown Black ODOUR Slight odour Sulphur. SOLUBILITY Soluble in water RELATIVE DENSITY 0.90 - 0.96 @ 25 c pH-VALUE, DILUTED SOLUTION 8.5 @ 2 % 10 STABILITY AND REACTIVITY STABILITY Stable under normal temperature conditions. HAZARDOUS POLYMERISATION Will not polymerise. MATERIALS TO AVOID Strong oxidising substances. HAZARDOUS DECOMPOSITION PRODUCTS High temperatures generate: Oxides of: Carbon. Sulphur. 11 TOXICOLOGICAL INFORMATION INHALATION Dust may irritate respiratory system or lungs. INGESTION May cause discomfort if swallowed. SKIN CONTACT Powder may irritate skin. /3 2 REVISION DATE: 22-Jul-04 ASPHASOL SUPREME EYE CONTACT Particles in the eyes may cause irritation and smarting. 12 ECOLOGICAL INFORMATION ECOTOXICITY Contact M-I's Environmental Affairs Department for ecological information. 13 DISPOSAL CONSIDERATIONS DISPOSAL METHODS Recover and reclaim or recycle, if practical. Dispose of on site landfill area. Dispose of waste and residues in accordance with local authority requirements. 14 TRANSPORT INFORMATION GENERAL The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA, ADR/RID). 14 TRANSPORT INFORMATION 15 REGULATORY INFORMATION RISK PHRASES NC Not classified. SAFETY PHRASES P13 Safety data sheet available for professional user on request. UK REGULATORY REFERENCES The Control of Substances Hazardous to Health Regulations 1988. Chemicals (Hazard Information & Packaging) Regulations. GUIDANCE NOTES Occupational Exposure Limits EH40. 16 OTHER INFORMATION GENERAL INFORMATION HMIS Health - 1 HMIS Flammability - 1 HMIS Physical Hazard - 0 E - Safety glasses, Gloves, Dust Respirator INFORMATION SOURCES Material Safety Data Sheet, Misc. manufacturers. REVISION COMMENTS Revised by Silvia Smart. ISSUED BY Sarah Glover REVISION DATE 22-Jul-04 REV. NO./REPL. SDS GENERATED 1 SAFETY DATA SHEET STATUS Approved. DISCLAIMER MSDS furnished independent of product sale. While every effort has been made to accurately describe this product, some of the data are obtained from sources beyond our direct supervision. We cannot make any assertions as to its reliability or completeness; therefore, user may rely on it only at user's risk. We have made no effort to censor or conceal deleterious aspects of this product. Since we cannot anticipate or control the conditions under which this information and product may be used, we make no guarantee that the precautions we have suggested will be adequate for all individuals and/or situations. It is the obligation of each user of this product to comply with the requirements of all applicable laws regarding use and disposal of this product. Additional information will be furnished upon request to assist the user; however, no warranty, either expressed or implied, nor liability of any nature with respect to this product or to the data herein is made or incurred hereunder. /3 3
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