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Alkylphenol Ethoxylates (APEO) in Textiles

The document discusses alkylphenol ethoxylates (APEO), specifically nonylphenol ethoxylates (NPEO) and octylphenol ethoxylates (OPEO), which are detergent properties often found in textiles and leather. APEO are toxic to aquatic life and hormone disrupting. While the EU has banned APEO concentrations over 0.1% since 2005, testing still finds them in textiles due to production in non-EU countries without bans. Eurofins offers reliable testing for APEO in textiles down to 0.2 ppm using HPLC/MS methods.

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96 views

Alkylphenol Ethoxylates (APEO) in Textiles

The document discusses alkylphenol ethoxylates (APEO), specifically nonylphenol ethoxylates (NPEO) and octylphenol ethoxylates (OPEO), which are detergent properties often found in textiles and leather. APEO are toxic to aquatic life and hormone disrupting. While the EU has banned APEO concentrations over 0.1% since 2005, testing still finds them in textiles due to production in non-EU countries without bans. Eurofins offers reliable testing for APEO in textiles down to 0.2 ppm using HPLC/MS methods.

Uploaded by

juli_rad
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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The most important APEO or alkylphenol
ethoxylates for the textile industry are
NPEO (nonylphenol ethoxylates) and
OPEO (octylphenol ethoxylates) due to
their detergent properties. About 90% of
the produced APEO are in fact NPEO.
The compounds are used in detergents,
cleaning agents, or chemicals used for
textile or leather production.
Toxicological characteristics are their hor-
mone disruptive properties and the fact
that they are toxic to aquatic organisms.
Furthermore, APEO are very persistent
and diffcultly degradable in nature.
These are all problem areas for waste-
water treatment and discharging of
wastewater into surface waters.
Alkylphenol ethoxylates (APEO)
in textiles
Analyses for APEO have been a fast growing
issue for Eurofins over the last years.
Surprisingly to the producers, APEO have been
detected in rather high amounts in textiles and
leather. Eurofins offers reliable analyses for
APEO
[email protected]
Denmark
[email protected]
+45 70 22 42 76
France
[email protected]
+33 144 62 79 16
China
[email protected]
+852 2636 3288
Germany
[email protected]
+49 40 492 94 328
Italy
[email protected]
+39 02 250 715.1
Thailand
[email protected]
+66 2 716 85 30
Netherlands
[email protected]
+31 3 42 40 06 06
Spain
[email protected]
+34 93 403 4555
United Kingdom
[email protected]
+44 161 868 76 00
USA
[email protected]
+1-925-275-0242
Legislation and
labelling
Since 1998 use of APEO in
detergents has been forbidden
in Germany - and since January
2005 the EU directive 2003/53/
EG has forbidden the use of
NPEO in higher concentrations
than 0.1% in formulations. These
compounds will often end in the
wastewater and consequently
form a problem in the environ-
ment - e.g. in rivers, lakes, etc.
Although forbidden in the EU
many companies have production
sites or suppliers outside Europe,
where the use of NPEO is not
forbidden. This is the reason why
some European companies have
established their own require-
ments with strict threshold values
for NPEO and OPEO.
Textile eco-labels as the EU
fower and ko-Tex 1000 have
also forbidden the use of APEO.
Testing method
In 2002 Eurofns Product Test-
ing A/S established a method for
determining even traces of APEO
in textiles and since then Eurofns
has performed several thousand
analyses.
This makes Eurofns Product
Testing A/S one of the most expe-
rienced and respectable labora-
tories as regards APEO testing.
Round Robin tests in 2005 show
that results from Eurofns Prod-
uct Testing A/S are reliable and
precise.
The sample of textile, fabric,
carpet or leather is extracted.
The extract is analysed with
combined high performance
liquid chromatography and
mass spectrometry with posi-
tive mode electro spray ionisa-
tion (HPLC/MS).
The analyses include the octyl-
and nonylphenol ethoxylates
from 3 to 15 ethoxy groups.
With this method even traces
of NPEO and OPEO can be
detected. Detection limit for
textile samples is 0.2 ppm
(mg/kg).
06.07.2009
Alkylphenol ethoxylates (APEO) in textiles
Only small amounts of sample are required for the analyses:
30 x 30 cm of textile, fabric, carpet, or leather
50 g of wool, yarn, or fbre
50 ml of liquid samples (chemicals, detergents, or agents)
For further information please contact:
Eurofns Product Testing A/S
Smedeskovvej 38
DK-8464 Galten
Tel. : +45 70 22 42 66
Fax: +45 70 22 42 55
email: [email protected]

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