Suspended Growth Biological - 43 PDF
Suspended Growth Biological - 43 PDF
Chapter 14
Suspended-Growth Biological
Treatment
1.0
2.0
INTRODUCTION
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2.3.1 Conventional
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PROCESS CONFIGURATIONS
AND TYPES
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2.4 Selectors
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2.2.1 Conventional
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2.6.1 Clarifiers
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2.6.2 Membranes
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2.6.3 Flotation
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3.0
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3.2 Nitrification
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3.3.1 Temperature
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3.3.3 Nutrients
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3.3.5 pH
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4.0
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4.1.2.1 Anaerobic/Oxic
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4.1.3.1 Influent
Characteristics
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4.1.3.4 pH
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4.1.3.6 Temperature
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4.1.3.8 Secondary
Release and
Recycle Load
Management
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4.2.2.1 Single-Sludge
Processes
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4.3.2.2 A /O
4.3.2.3 University of
Cape Town
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4.4.2.4 Two-Stage
Fermenter
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4.4.2.5 Unified
Fermentation
and Thickening
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4.2.1 Baffles
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4.3.2.4 Virginia
Initiative Plant
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4.3.2.5 Johannesburg
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4.3.2.6 PhoStrip II
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4.4.2 Fermentation
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4.4.2.1 Activated
Primary
Sedimentation
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4.4.2.2 Complete-Mix
Fermenter
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4.5.2.1 Blending
Streams
14-122
4.5.2.2 Mechanical
Mixing
Maintaining
Solids in
Suspension
14-123
4.5.2.3 Aeration
Maintaining
Solids in
Suspension
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14-4
4.5.2.4 Degasification
4.5.2.5 Scum/Foam
Control
5.0
6.0
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ANAEROBIC TREATMENT
OF WASTEWATER
14-125
5.1 Introduction
14-125
5.2 Microbiology
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5.4.1 Description
14-128
5.4.2 Installations
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5.4.3.2 Gas/Liquid/
Solids
Separation
14-137
14-140
5.4.3.4 Sludge
Production
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5.4.3.5 Alkalinity
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14-147
14-150
6.3.1.3 Oxygen
Transfer
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6.4 Pretreatment
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MEMBRANE BIOREACTORS
14-142
6.5.1 Mixed-Liquor
Recycle Pumping
14-154
6.1 Introduction
14-142
6.5.2 Mixing
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7.0
8.0
14-159
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14-5
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6.6.1.1 Biological
Process Blowers
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WET-WEATHER
CONSIDERATIONS
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7.1 Introduction
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8.2.3.2 U-Tube
Aeration
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8.2.3.3 Countercurrent
Aeration
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8.5.1.1 Types of
Air-Cleaning
Systems
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8.5.1.3 Design
Considerations
14-189
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OXYGEN-TRANSFER
SYSTEMS
14-169
8.1 Introduction
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8.5.2 Blowers
14-190
8.5.2.1 Turndown
14-191
8.5.2.2 Selection
14-191
8.5.2.3 Control
14-192
14-6
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8.5.5 Pure-Oxygen
Generation
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8.7.1 Equipment
Considerations
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14-200
8.7.3 Transformation of
Clean Water Test Data
to Clean Process
Water Conditions
8.8 Process Water Testing
8.9 Aeration System
Maintenance
9.0
9.2.4.2 Dissolved-Oxygen
Concentration
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9.2.4.3 Selectors
14-212
9.2.4.4 Process
Configuration
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SECONDARY
CLARIFICATION
14-205
9.1 Introduction
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9.3.2.2 Daigger
Approach
14-205
9.3.2.3 Keinath
Approach
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14-208
9.3.2.5 Ekama-Marais
Approach
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9.3.5 Redundancy
14-227
9.2.3 Measures of
Settleability
14-211
9.2.4 Techniques to
Improve Settleability
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9.2.4.1 Food-toMicroorganisms
Ratio Control
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9.5.2 Diameter
14-251
9.4.2 Dimensions
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9.4.2.1 Length
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9.4.2.2 Width
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9.4.2.3 Depth
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9.5.7 Outlets
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9.4.2.10 Stacked
Clarifiers
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9.5.7.2 Cantilevered
Double or
Multiple
Launders
14-276
9.5.7.3 Launders
Suspended from
the Bridge
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9.5.7.4 Submerged
Orifices
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9.5.8.1 Scrapers
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9.5.8.2 Hydraulic
Suction
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9.5.8.3 Hoppers
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9.4.2.15 Submerged
Launders
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9.4.2.16 Sludge
Withdrawal
14-247
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14-8
9.5.9.1 Return
Activated Sludge
Pumping
14-285
9.5.9.2 Algae Control
9.6 Control Strategy and
Facilities Design
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10.5.1 Influent
Characterization
and Fractionation
14-312
10.5.2 Modification of
Decay Rate for
Activated Sludge
Models
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10.5.4 Denitrification
System Design
14-318
10.0 SUSPENDED-GROWTH
BIOLOGICAL TREATMENT
SYSTEM EXAMPLE
14-294
11.0 REFERENCES
14-320
14-345
1.0 INTRODUCTION
Suspended-growth systems are biological treatment processes based on the growth and
retention of a suspension of microorganisms. These microorganisms convert biodegradable, organic wastewater constituents and certain inorganic fractions into new cell mass
and byproducts, both of which then can be removed by settling, gaseous stripping, and
other physical means. Suspended-growth systems for wastewater treatment are predominantly aerobic processes, typically referred to as activated sludge, with a variety
of reactor configurations and flow patterns. Strictly anaerobic suspended-growth
processes for liquid-phase treatment are also in use.
This chapter presents fundamentals of aerobic activated sludge treatment and the
process configurations that can be used. It covers process design for carbon substrate
oxidation and nitrification of ammonia, process modifications and configurations for
FIGURE 14.1
14-9
14-10
14-11
14-12
Complete mix,
Plug flow,
Oxidation ditch, and
Combination (capable of being operated in more than one configuration).
FIGURE 14.2
Complete-mix reactor.
14-13
14-14
FIGURE 14.3
Plug-flow reactor.
The ideal plug-flow configuration has a relatively high organic loading at the influent end of the basin. The food-to-microorganism ratio is reduced over the length of the
basin as organic material in wastewater is assimilated. At the downstream end of the
basin, oxygen consumption shifts increasingly towards endogenous respiration. The
high organic loading at the head end of this process discourages most types of filamentous bacteria growth and results in better sludge settling compared to a complete-mix
reactor if sufficient dissolved oxygen concentrations are maintained. Keeping a low dissolved oxygen level too long, however, may encourage filamentous growth. As discussed elsewhere in this chapter, polysaccharide formation may result from high loading and low dissolved oxygen concentrations at the inlet end.
Whereas a complete-mix reactor is able to handle surges in loading, plug-flow configurations have a superior ability to avoid bleed-through or passage of untreated
substrate during peak flows. Plug-flow reactors also have an advantage where higheffluent dissolved oxygen concentrations are desirable. In a complete-mix configuration, the entire tank contents would have to be maintained at the elevated dissolved
oxygen level to achieve that objective. Control of dissolved oxygen concentrations in a
plug-flow system can be complicated if a wide range of oxygen demands and at multiple locations are expected.
14-15
14-16
(A)
Influent
Return Sludge
Brush-Type
Aerators
Secondary
Clarifier
Effluent
(B)
FIGURE 14.4
Oxidation ditch reactors: (a) simple loop and (b) folded loop.
to maintain tank motion and aerate ditch contents. As mixed liquor passes the aerator,
the dissolved oxygen concentration increases sharply and then declines as the flow traverses the circuit. Oxidation ditches typically operate in an extended aeration mode
with long HRTs (24 hours) and SRTs (20 to 30 days). Depending on the relative location(s) of wastewater inlet, mixed-liquor outlet, sludge return, and aeration equipment
and control, oxidation ditches also can achieve nitrification and denitrification. For BOD
removal or nitrification, the influent typically enters the reactor near the aerator and
the effluent exits the tank upstream of the entrance.
Oxidation ditches have depths ranging from approximately 0.9 to 5.5 m (3 to 18 ft)
and channel velocities from 0.24 to 0.37 m/s (0.8 to 1.2 ft/sec). Ditch geometry must be
compatible with aeration and mixing equipment and should be coordinated with the
manufacturers. Mechanical brushes, surface turbines, and jet devices are used to aerate
and move the liquid flow. Combinations of diffused aeration and submersible mixers
also have been employed (Christopher and Titus, 1983). Several alternative designs of
intrachannel clarifiers have been developed to provide for separation and return of
MLSS to the ditch. The inability to readily modify the return activated sludge (RAS)
FIGURE 14.5
Vertical-loop reactor.
14-17
14-18
FIGURE 14.6
14-19
TABLE 14.1 Key features of phased isolation ditch technologies (Tetreault et al., 1987).
Ditch
typea
Process
modification
Treatment objectives
Number of ditches
2 Oxidation
Sedimentation
3 Oxidation
Sedimentation
3 Oxidation
Denitrification
Sedimentation
2 Oxidation,
Denitrification
2 Oxidation/phosphorus
uptake
Denitrification
VR-
T-
T-
Bio-Denitro
DE-
Bio-Denitro
BOD5, SS, TN
DE-
Bio-Deniphob
with HRTs of one or more days and with clarifiers and sludge return can be used to
create activated sludge processes. Reactor shapes historically were square or rectangular, which is mixing limited, leading to development of oxidation ditches. Horizontal
flow in a ditch keeps particles in suspension at lower energy input than mechanical or
diffused aeration in lagoon reactors.
Another concept is to aerate and mix lagoon-style reactors with less energy by
installing rows of diffused aerators near the bottom and then sequencing them on and
off or suspending them from floating aeration piping. This extended aeration system
FIGURE 14.7 Phased ditch with three parallel runs and movable pivoting wall aerators.
Separate
clarifier
No
No
No
Yes
Yes
14-20
FIGURE 14.8
2.2.1 Conventional
Conventional loading rates apply to plug-flow or CMAS systems with an FM loading
of approximately 0.2 to 0.5 kg BOD/day/kg mixed liquor volatile suspended solids
(MLVSS) (0.20 to 0.5 lb BOD/d/lb MLVSS). These systems can obtain BOD removal
efficiencies in the range of 85 to 95%. Conventional rate system MLSS design concentrations often range from 1 500 to 3 000 mg/L. Design MLSS concentrations have increased
considerably over the years because of improvements in the oxygen-transfer capability
of aeration devices, clarifier performance, and understanding of system concepts.
An important consideration in the design of conventional systems is that nitrification might occur, even when not desired. This often happens with low loading conditions during summer months or high SRTs because of wasting practices. When nitrification occurs, denitrification may occur in the final clarifiers resulting in rising sludge
problems when nitrogen gas buoys and floats the biomass floc. Approaches used to
limit nitrification and unwanted denitrification include reducing the SRT or HRT and
the dissolved oxygen concentration to reduce nitrification or increasing the dissolved
oxygen before clarification. In warm climates, SRT reduction to prevent nitrification
might adversely affect floc formation and secondary clarifier performance.
14-21
Continuous-flow
stirred-tank
reactor
Plug flow
Plug flow
Plug flow
Plug flow
Continuous-flow
stirred-tank
reactor
Plug flow
Continuous-flow
stirred-tank
reactors in
series
Plug flow
Complete-mix
Modified aeration
Contact stabilization
Extended aeration
High-rate aeration
Separate stage
nitrification
Single-stage
nitrification
Sequencing batch
reactor
Oxidation ditch
Kraus process
High purity oxygen
Continuous-flow
stirred-tank
reactors or
plug flow
Continuous-flow
stirred-tank
reactors or
plug flow
Intermittent-flow
stirred-tank
reactor
Plug flow
Plug flow
Conventional
Mechanical aerators,
diffused-air
Mechanical aerators,
diffused-air
Diffused-air
Mechanical aerators
(horizontal axis type)
Diffused-air
Diffused-air
Mechanical aerators
(sparger turbines)
Mechanical aerators
Diffused-air, mechanical
aerators
Diffused-air, mechanical
aerators
Diffused-air
Diffused-air
Diffused-air, mechanical
aerators
Diffused-air, mechanical
aerators
Aeration system
8595
8595
8595
8595
7595
8595
8595
7590
7595
8090
6075
8595
8595
8595
BOD removal
efficiency, %
Remarks
14-22
Step feed
Flow model
Process
modification
TABLE 14.2 Operational characteristics of activated sludge processes (from Metcalf & Eddy, Inc., Wastewater Engineering:
Treatment and Reuse, 4th Ed., R. Tchobanoglous [Ed.], Copyright 2003, with permission from the McGraw-Hill Companies).
515
515
515
0.20.5
515
2030
510
515
310
1030
NA
NI
820
15100
Conventional
Complete-mix
Step feed
Modified aeration
Contact stabilization
Extended aeration
High-rate aeration
Kraus process
High-purity oxygen
Oxidation ditch
Sequencing batch reactor
Deep shaft reactor
Single-stage nitrification
0.050.15
0.41.5
0.30.8
0.251.0
0.050.30
0.050.30
0.55.0
0.100.25
(0.020.15)d
0.0500.20
(0.040.15)d
0.20.4
0.20.6
0.20.4
1.55.0
0.20.6
c, d
Process modification
FM, lb BOD5
applied/d/lb
MLVSSa
2 0003 500
1025
1001 000
40100
100200
530
515
NI
520
39
MLSS, mg/L
1 5003 000
2 5004 000
2 0003 500
2001 000
(1 0003 000)b
(4 00010 000)c
3 0006 000
4 00010 000
2 0003 000
2 0005 000
3 0006 000
1 5005 000d
NI
2 0003 500
2040
50120
4060
75150
6075
Volumetric
loading,
lb BOD5/d/103
cu ft
36
48
35
35
1.53
(0.51.0)b
(36)e
1836
24
48
13
836
1250
0.55
615
V/Qh
0.502.00
0.51.50
1.05.0
0.51.0
0.250.5
0.751.50
NA
NI
0.501.50
0.250.75
0.251.0
0.250.75
0.050.25
0.51.50
Qr /Q
TABLE 14.3 Design parameters for activated sludge processes (from Metcalf & Eddy, Inc., Wastewater Engineering: Treatment
and Reuse, 4th Ed., R. Tchobanoglous [Ed.], Copyright 2003, with permission from the McGraw-Hill Companies).
14-23
14-24
2.3.1 Conventional
Conventional activated sludge design typically would introduce influent to the head
end of a rectangular basin. The RAS could be mixed with the influent before the tank or
be added separately. Keeping the RAS separate facilitates subsequent conversion to
other feed patterns (for example, step feed or contact stabilization), if such flexibility is
important. If RAS is blended with the influent ahead of multiple aeration basins operating in parallel, then care must be taken to ensure that the influent is well mixed before
flow splitting occurs.
14-25
14-26
FIGURE 14.9
Step-feed process.
FIGURE 14.10
Tapered-aeration process.
within an activated sludge process to match the oxygen-demand pattern should, however, is considered for all reactor configurations. The tapered-aeration approach typically is associated with diffused air systems. Plug-flow reactor designs, in particular,
should incorporate tapered aeration for operational control because of the wide range
of oxygen demand along its length. Mixing requirements, in some cases, govern the
minimum air supply rate.
Design parameters for the tapered aeration process are consistent with those for
conventional activated sludge treatment. Adding more air at the influent end of the aeration tank than at the effluent end (for example, by increasing density of diffusers) produces several beneficial results:
Reduced low-dissolved oxygen, fine-bubble-diffuser biofouling at inlet end
where the oxygen demand is high,
Greater operational control, and
Possible inhibition of nitrification (when desired) by reducing dissolved oxygen
concentrations in downstream segments of the aeration basin.
2.4 Selectors
A variety of microorganisms affect settleability of MLSS and environmental conditions
can be altered to favor or select one type of bacteria over others (Jenkins et al., 2003).
Mixed liquors that are low in nutrients, dissolved oxygen, or FM tend to favor growth
of filamentous bacteria that have high surface area-to-volume ratios. Many of these filamentous bacteria, which hinder settling, can be placed at a growth-rate disadvantage
if mixed liquor is subjected to periods of high FM. Organisms with the greatest ability
to rapidly uptake soluble substrate and store it internally for use later during low concentration conditions tend to be those that are more flocculent and settle better.
14-27
14-28
FIGURE 14.11
14-29
Operating at high FM and low dissolved oxygen can lead to formation of polysaccharides, an intermediate product formed by microbes in an attempt to metabolize
BOD. Polysaccharides are not readily biodegradable in digestion and can detrimentally
affect solids dewatering by reducing throughput and dewatering cake solids concentrations. Pilot-scale or plant performance data may be used to further improve selector
design and define expected performance for a given situation.
Table 14.4 summarizes advantages and disadvantages of the three types biological
selectors.
TABLE 14.4
Selector type
Advantages
Disadvantages
Aerobic
Anoxic
Anaerobic
* Recycle stream may not be needed for selector but to extend denitrification (lb/lb kg/kg).
14-30
FIGURE 14.12
14-31
14-32
FIGURE 14.13
FIGURE 14.14
14-33
14-34
A key disadvantage of this process is the need to regenerate PAC for reuse or to purchase virgin PAC if the plant lacks regeneration facilities. As another disadvantage, the
PACT process with PAC regeneration typically requires tertiary filtration.
Most successful applications of PACT have occurred in industrial applications
where the PAC has been used on a single-pass basis without regeneration. Much of the
early work focused on its use for refinery waste treatment in response to stringent U.S.
EPA effluent guideline limits. The oil industry considered PAC augmentation in lieu of
the proposed best available technology of granular activated carbon adsorption following conventional secondary treatment. With the implementation of pretreatment regulations in the United States, many plants currently have less need for carbon addition
to reduce toxicity from industrial discharges and the PACT process is seldom used in
new municipal plants.
2.6.1 Clarifiers
There are many aspects of clarifier design that pertain to making the process effective
for separating suspended solids in the activated sludge process. The technology has
evolved to the point that nearly all such clarifiers are either circular or rectangular, and
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14-36
2.6.2 Membranes
Adding membrane separation technology to the activated sludge process and the
resulting membrane bioreactor (MBR) configuration now can compete with mainstream processes. This is particularly true when filtration or further membrane
treatment would be required for a high-quality effluent, or where a compact footprint is needed.
Advantages of MBR process configuration include a nearly solids-free effluent,
modular configuration with small footprint, reduced downstream disinfection requirements, ability to retrofit existing reactors, and elimination of adverse sludge settling
properties. Disadvantages include capital costs, increased power requirements for aeration, ongoing membrane replacement requirements, and constrained ability to accommodate peak flows.
2.6.3 Flotation
Dissolved-air flotation (DAF) has not seen widespread use as a means of MLSS separation in the activated sludge process, but has been used with deep-shaft reactor designs.
Units are available in either circular or rectangular configurations. Most units used in
municipal applications involve pressurizing the main stream influent or a recycle
stream in a chamber and subsequently releasing the stream into a separation chamber
at atmospheric pressure. The pressure drop causes the release of supersaturated air as
bubbles that attach to particles and cause them to float to the surface where they are
removed by mechanical skimming equipment. Process variables include size and shape
of the separation basin, air-to-solids ratio, nature and concentration of solids in suspension, and skimming mechanisms. Chemical coagulants can be added to increase the
effectiveness of the process.
FIGURE 14.15 Nomenclature for activated sludge flowsheet (volatile and nonvolatile
represent organic and inorganic solids, respectively).
V
Q
(14.1)
14-37
14-38
SRT
Ynet (So Se )
HRT
(14.3)
Y
1 b SRT
(14.4)
Ynet
Ynet (So Se )
Ynet (So Se )
MwTSS Q
fd b SRT
Zio Zno
fv
fv
X MLSS
Ynet (So Se )
SRT Ynet (So Se )
fd b SRT
Zio Zno
HRT
fv
fv
(14.2)
Qr
X
X TSS
Q X r X X rTSS X TSS
(14.5)
(14.6)
(14.7)
(14.8)
(14.9)
Unit
Range
Typical values
g VSS/g VSSd
g bCOD/m3
g VSS/g bCOD
g VSS/g VSSd
Unitless
3.013.2
5.040.0
0.300.50
0.060.20
0.080.20
6.0
20.0
0.40
0.12
0.15
Unitless
Unitless
Unitless
1.0310.08
1.031.08
1.00
1.07
1.04
1.00
* Adapted from Henze et al., 1987a; Barker and Dold ,1997; and Grady et al., 1999.
14-39
14-40
3.2 Nitrification
Nitrogen contained in municipal raw wastewater occurs predominantly in organic and
ammonia nitrogen forms. Typical concentrations of total nitrogen in domestic wastewaters range from 20 to 85 mg/L, with a medium strength of 40 mg/L (Metcalf and
Eddy, 2003). Approximately 40% of the total occurs as organic and 60% as ammonia.
Typically, less than 1% is present as nitrate or nitrite unless influenced by industrial waste
contributions. Influent nitrogen concentrations, as with other constituents, have trended
upward in areas with increasing water conservation efforts or reduced infiltration and
14-41
14-42
N N ,max
1
N bN
Ne
KN No
DO
K o DO
YN
1 bN SRTdesign
(14.10)
(14.11)
(14.12)
(14.13)
YNnet ( N o N e )
YNnet ( N o N e )
MNTSS Q
fd bN SRTdesign
fv
fv
(14.14)
(14.15)
Where,
SRTNmin minimum SRT for nitrification, time;
N nitrifier specific growth rate, 1/time;
N,max maximum nitrifier specific growth rate, 1/time;
No, Ne influent and effluent oxidizable nitrogen concentrations, respectively,
mass/length3;
KN , Ko half-velocity constants for ammonia and oxygen, respectively,
mass/length3;
YN nitrification yield coefficient, mass/mass;
YNnet net nitrification yield coefficient, mass/mass;
DO reactor dissolved oxygen concentration, mass/length3;
SRTdesign design SRT, time;
SF safety or design factor, dimensionless;
bN endogenous decay coefficient for autotrophs based on biomass in
aerated zone, 1/time;
fd cell debris coefficient, mass/mass;
fv biomass volatile solids content, typically 0.85, mass/mass;
14-43
14-44
Unit
Range
Typical values
g VSS/g VSSd
g NH4/m3
g VSS/g NH4
g VSS/g VSSd
g/m3
0.200.90
0.51.0
0.100.15
0.050.15
0.400.60
0.75
0.74
0.12
0.08
0.50
Unitless
Unitless
Unitless
1.061.123
1.031.123
1.031.08
1.07
1.053
1.04
* Adapted from Henze et al., 1987a; Barker and Dold, 1997; and Grady et al., 1999.
3.3.1 Temperature
Temperature will affect reaction rate, stoichiometric constants, and oxygen-transfer
rates. Most temperature corrections used in biological treatment designs follow the
modified vant Hoff-Arrhenius equation:
KT2 KT1 (T2T1)
(14.16)
Where,
KT1 a specific kinetic, stoichiometric, or mass-transfer coefficient at
temperature T1;
KT2 a specific kinetic, stoichiometric, or mass-transfer coefficient at
temperature T2; and
temperature correction factor, dimensionless.
Tables 14.5 and 14.6 include values for heterotrophic and autotrophic bacterial
kinetics. The range of values for k in aerated lagoons range from 1.06 to 1.12. Note that
temperature correction factors are approximate and should be reviewed for appropriateness. Also, nitrification kinetic coefficients are presented routinely as either 15 or
20C; the basis should be confirmed.
14-45
14-46
3.3.3 Nutrients
An adequate nutrient balance is necessary to ensure an active biomass that settles well.
Nutrients refer to nitrogen, phosphorus, and trace metals that are necessary for biological growth (Metcalf and Eddy, 2003). Systems with higher SRT are expected to require
fewer nutrients in the influent because nutrients released during endogenous respiration become available for growth of active biomass. Because nutrient requirements
depend on SRT, they can be based on excess biomass and cell debris produced. The
minimum nitrogen requirement should be 12% and the phosphorus requirement
should be 2% of the excess biomass and cell debris generated. Normal domestic wastewater typically contains ample nutrients. Wastes with substantial industrial contributions might require nutrient addition.
3.3.5 pH
The pH of mixed liquor should range from 6.5 to 7.5 for optimum cell growth in cBOD
removal systems. Nitrifying systems are more sensitive to system pH because the rate
of growth of these organisms is a function of pH over the range of 6.5 to 7.5 (U.S. EPA,
1993). Pure oxygen systems often depress pH more than air systems because the former lacks nitrogen gas flow to help strip dissolved carbon dioxide (formed in respiration) from the mixed liquor. Unless stripped out by downstream channel aeration or
similar process, at least some carbon dioxide is recirculated through clarifiers and back
to reactors.
To avoid pH reduction, a residual alkalinity of at least 60 mg/L (as calcium carbonate) for either pure oxygen or classical aeration systems should be provided. Operating
at 50 mg/L level is minimal, and a value of 80 to 100 mg/L would better maintain a
stable pH under varying conditions.
14-47
14-48
FIGURE 14.16 Effects of mean cell residence time (MCRT) on the amount of dispersed
growth in activated sludge effluent and the settling velocity (ft/hr 0.304 8 m/h) of
activated sludge mixed liquor.
14-49
14-50
FIGURE 14.17 Design solids retention time for (a) carbonaceous biochemical oxygen
demand removal and (b) single-stage nitrification (toxicity not present, mixed-liquor
suspended solids washout controlled at pH 7.5 to 9.0).
mixed. Although aerated lagoons are similar to an extended aeration system, deposition of solids and partially mixed character result in a complex reactor configuration. As
a result, equations presented previously cannot be applied directly. A common
approach to designing aerated lagoons without secondary clarification and sludge recycle is to assume that the observed BOD removal (either total or soluble BOD) can be
FIGURE 14.18 Design mixed-liquor suspended solids (MLSS) versus sludge volume
index (SVI) and return sludge ratio (high-rate sludge removal mechanism) at a reactor
basin temperature of 20C.
described by first-order kinetics. For a single, completely mixed lagoon, the first-order
equation is (Metcalf and Eddy, 2003):
1
Se
So 1 k1 HRT
(14.17)
Where,
k1 observed BOD removal rate constant (1/t).
Temperature affects reported values of k1, which have ranged from 0.25 to 1.0 d1 for
overall BOD removal (Metcalf and Eddy, 2003). Additional details on aerated lagoon
design are presented elsewhere (Reed et al., 1995).
14-51
14-52
Any precipitates that form from the addition of iron or aluminum salts to the activated
sludge process for phosphorus removal or other purpose also should be included in
this calculation. Figure 14.20 illustrates net secondary treatment system sludge production (to be removed as waste activated sludge and secondary effluent suspended solids)
for the stated waste characteristics, both with and without primary sedimentation.
FIGURE 14.20 Net sludge production versus solids retention time and temperature
(a) with primary treatment and (b) without primary treatment (lb/lb kg/kg).
mated from statistical analyses of data collected for influent loadings (cBOD and
nitrogenous oxygen demand). Spatial variations depend on kinetic relationships
between growth rates of the biomass and substrate removal rates and dissolved oxygen
concentrations. They also depend on the flow regime and HRT of the process. Estimates
of variation can be obtained from process computer models described by WEF (2009) or
literature data. Table 14.7 presents data collected in the United Kingdom for long,
14-53
14-54
Proportion of
demand, %
60
15
10
10
5
Diurnal
range, %
4085
520
515
515
110
Carbonaceous
nitrogenous demand
Proportion of
demand, %
Diurnal
range,%
46
17
14
13
10
3362
1020
1017
1016
713
narrow (plug flow) aeration tanks (L/W is greater than 20) (Boon and Chambers, 1985).
Estimates of nitrogenous demand assumed that nitrification progressed uniformly
along the entire tank length. More details on estimation of oxygen demand can be found
in the references (U.S. EPA, 1989; Water Pollution Control Federation, 1988).
Total oxygen demand for design should be based on peak loadings anticipated. As
a minimum, requirements for a conventional system should be based on the 24-hour
demand of the average day of the peak month. Some designers prefer to use the peak
day or the peak four-hour demand of the average day of the peak month. Basing the
requirement on the peak day demand, plus 50% of the peak four-hour rate for the peak
day has been suggested (Young et al., 1978).
14-55
14-56
Compound/organism
Anaerobic zone
Aerobic zone
Taken up
Used
Stored
Released
Released
Used
Selected
Produce VFAs
Advantages
Limitations
A/O (Phoredox)
SBR
PhoStrip
14-57
14-58
TABLE 14.10
processes.*
Design
parameter/
process
SRT, d
MLSS,
mg/L
Anaerobic
zone
25
525
1025
3 0004 000
3 0004 000
3 0004 000
0.51.5
0.51.5
12
510
2 0004 000
12
Bardenpho
(5-stage)
1020
3 0004 000
0.51.5
PhoStrip
SBR
520
2040
1 0003 000
3 0004 000
812
1.53
A/O
A2/O
UCT
VIP
Anoxic
zone
Aerobic
zone
RAS, % of
influent
13
48
412
25100
25100
80100
12
46
80100
13
(1st stage)
24
(2nd stage)
412
(1st stage)
0.51
(2nd stage)
410
24
50100
100400
200400
(anoxic)
100300
(aerobic)
100200
(anoxic)
100300
(aerobic)
200400
50100
1020
0.51
24
13
Internal recycle
% of influent
readily biodegradable substrate (VFAs) is available (Metcalf and Eddy, 2003). These
modifications typically reduce SBR cycles to three or four per day. If the SBR process is
optimized for nutrient removal, then it can achieve less than 0.7 mg/L total phosphorus on a consistent basis depending on influent characteristics.
While it may be possible to maintain informal but localized anaerobic/oxic zones
within an oxidation ditch or similar looped reactor by carefully controlling dissolved
oxygen levels, the most typically implemented EBPR configuration is shown in Figure
14.23 (WEF et al., 2005). It shows an external anaerobic basin for PAO selection followed
FIGURE 14.22 Sequencing batch reactor for removal of carbonaceous biochemical oxygen demand and phosphorus.
Anoxic
Aerobic
Anaerobic
Basin
Final
Clarifier
RAS
FIGURE 14.23 Oxidation ditch design for enhanced biological phosphorus removal
(RAS return activated sludge).
by the oxidation ditch where phosphorus uptake occurs. This represents the A/O
process described above.
The time-cyclic, phased isolation ditch process configuration developed in Denmark uses a pair of oxidation ditches operated in alternating mode to achieve EBPR.
4.1.2.2 PhoStrip Process
The PhoStrip process, illustrated in Figure14.24, combines biological and chemical phosphorus removal. It diverts part of the phosphorus-rich return activated sludge (approximately 10 to 30% of influent flow) to an anaerobic stripper where phosphorus is released
to solution. The phosphorus-rich stripper supernatant is then precipitated with lime,
while the biomass, stripped of phosphorus, returns to the aeration tank. The PhoStrip
process combines biological and chemical phosphorus removal and is the first patented
commercial system. It is not, however, typically used in modern EBPR facilities.
FIGURE 14.24
14-59
14-60
FIGURE 14.25 Effect of influent TBODTP ratio on effluent TP (TBOD total biochemical oxygen demand and TP total phosphorus) (WEF, 1998).
FIGURE 14.26 Effect phosphorus as a function of the influent TCODTP (TCOD total
chemical oxygen demand and TP total phosphorus) (WEF, 1998).
14-61
14-62
Substrate measure
SubstrateP ratioa
cBOD5
201
sBOD5b
COD
151
451
VFA
rbCODc
71 to 101
151
Remarks
Provides a rough/initial estimate.
Based on typically available plant data.
Better indicator than cBOD5
More accurate than cBOD.
Not measured by all plants.
More accurate than COD.
Involves specialized lab analysis.
Most accurate. Measures VFA formation
potential. Accounts for VFA formation
in the anaerobic zone. Specialized lab
analysis.
Minimum requirements.
Soluble BOD.
c
Readily biodegradable COD.
b
potential (ORP) also can be used to confirm an anaerobic environment. Typical ORP
values for anaerobic conditions are approximately 300 mV or less.
Sources of dissolved oxygen and nitrates that threaten the integrity of the anaerobic zone are listed in Table 14.12. The presence of these two oxygen sources causes a
reduction of the actual anaerobic volume. Consequently, this will decrease anaerobic
contact time between the PAOs and the substrate (VFAs), which could potentially compromise phosphorus removal. In addition, the presence of nitrate and dissolved oxygen
will provide competing organisms access to the substrate. For example, 1.0 mg of
nitrate-N will steal readily biodegradable organics needed for the removal of 0.7 mg of
phosphorus by supporting denitrification. Likewise, the presence of 1.0 mg of dissolved
oxygen will deprive the substrate needed for the removal of 0.3 mg phosphorus by facilitating normal heterotrophic activity (BOD oxidation). In addition, dissolved oxygen in
the anaerobic zone can trigger filamentous growth. Design engineers must take steps to
avoid the introduction of dissolved oxygen and nitrate to the anaerobic zone.
4.1.3.3 Aerobic Zone Impacts
Phosphorus removal occurs in the aerobic zone. Full-scale observations have shed light
on the critical role played by the aerobic zone in achieving reliable EBPR (Narayanan
et al., 2006). Following anaerobic PAO selection, as the MLVSS enters the aerobic zone,
the PAOs are enriched with stored PHA, and the surrounding mixed liquor has high
levels of soluble phosphorus. At this point, if dissolved oxygen is provided in adequate
amounts, then rapid phosphorus uptake kinetics would be assured. Similar findings
reported by Jeyanayagam (2007), shown in Figure 14.27, indicate approximately 75% of
Source
Introduces
Pre-aeration
Influent screw pumps
Free-fall over weirsa
Excessive turbulencea
Aggressive mixing in the anaerobic zone
RAS flow
Backflow from aerobic to anaerobic zone
Internal mixed liquor recycleb
Dissolved oxygen
Dissolved oxygen
Dissolved oxygen
Dissolved oxygen
Dissolved oxygen
Nitrates, dissolved oxygen
Dissolved oxygen
Nitrates and dissolved oxygen
a
b
soluble phosphorus removal occurs in the first 20% of aeration volume and EBPR is
almost in the first half of the aeration basin.
When poor initial phosphorus uptake occurs because of dissolved-oxygen limitation, it may not possible for phosphorus removal to catch up in the subsequent aerobic zones even if adequate dissolved oxygen is maintained. This occurs because two
driving forces, PHA level and bulk liquid soluble-phosphorus concentration, would be
significantly lower resulting in higher effluent soluble-phosphorus levels (Narayanan
et al., 2006). It also was concluded that staging the aerobic zone enhances EBPR due to
improved plug-flow conditions. This may be attributed to higher reaction rates caused
by the concentration gradient.
FIGURE 14.27
14-63
14-64
FIGURE 14.28
mino, 1985).
fAM
0.25
0.20
0.15
0.10
0.05
P removal (mgP/l)
0.04
1 Anaerobic
COD1 250 mgCOD/l
fss = 0.25
fsi,COD1 = 0.07
fxi,COD1 = 0.15
0.03
6
0.02
4
0.01
P removal/influent (mgP/mgCOD)
10
0.0
0
0
10
15
Sludge age (d)
20
25
30
FIGURE 14.29 Predicted phosphorus removal versus sludge age for various anaerobic
functions ( fAN) (Henze et al., 2008; reprinted with permission from IWA Publishing).
14-65
14-66
4.5% P
IN WASTE SOLIDS
6% P
IN WASTE SOLIDS
5.0
10.0
15.0
20.0
25.0
30.0
FIGURE 14.30
phosphorus.
At SRT values greater than four days and at temperatures greater than 15C, nitrification will tend to occur, and process configurations that include anoxic zones for denitrification of nitrate in the recycle flows must be used.
Anaerobic phosphorus release and aerobic uptake must be considered in selecting
the overall system and individual-zone HRT values. The full- and pilot-scale data plotted in the two graphs of Figure 14.31 show that EBPR performance is sensitive to
changes in anaerobic nominal HRT and the substrate: phosphorus ratio in the anaerobic zone. The change in EBPR performance with a change in anaerobic HRT was relatively small when the TCODTP ratio varied from 42 to 68 (phosphorus-limited). However, changes in anaerobic HRT between 0.5 and 2.7 hours had large effects on EBPR
performance when the TCODTP ratio was between 20 and 43 (substrate-limited).
As noted previously, VFA uptake is a relatively rapid reaction, requiring an anaerobic zone SRT of 0.3 to 0.5 days. Most of the time, this corresponds to a nominal anaer-
14-67
14-68
14-69
14-70
FIGURE 14.33 Contribution of the effluent total suspended solids (TSS) to the total
phosphorus in the effluent for different phosphorus contents in the mixed-liquor suspended solids (MLSS) (assuming that the VSS/TSS is 75%) (VSS volatile suspended
solids) (WEF et al., 2005).
TABLE 14.13
Location
Primary clarifier
Anaerobic zone
Anoxic zone
Aerobic zone
Final clarifier
Primary sludge gravity thickener
Sludge storage
Anaerobic digestion
Aerobic digestion
Dewatering
14-71
14-72
FIGURE 14.34 Recycle streams generated at typical wastewater treatment plant solids
handling facilities (WEF et al., 2005).
(WWTP) solids handling facilities. The quantity and quality of these streams vary based
on the technology used in the solids processing operations. For example, anaerobic
digestion is likely to release more phosphorus than aerobic digestion; however, a significant amount of the released phosphorus could potentially be precipitated as struvite,
vivianite, and brushite resulting in less phosphorus in the anaerobic digester liquor.
Sludge thickening using belt-filter dewatering generally generates two times more
recycle flow (filtrate) compared to centrifuge dewatering because of the amount of
washwater used in the dewatering operation. This will affect the recycle hydraulic load
although returned phosphorus mass load will remain unchanged. Total recycle streams
can amount to 20 to 30% of the plant influent phosphorus loading.
Return streams often occur intermittently in many facilities causing significant
variation in nutrient loadings and short-term peak loads that could overwhelm the
EBPR process. For example, if dewatering operations occur over one shift, five days per
week, then recycle loading could potentially be four times the loading generated by a
24/7 operation. The complex microbial consortium in a single sludge system has limited ability to respond quickly to influent variations by self-adjusting. The period of
acclimation is directly influenced by SRT, MLSS, and the magnitude and duration of peak
loads. Within limits, higher SRT and MLSS enhance microbial diversity and system
14-73
14-74
Substrate
Formic acid
Acetic acid
Propionic acid
Butyric acid
Isobutyric acid
Valeric acid
Isovaleric acid
Municipal wastewater
Chemical formula
COD equivalent, mg/L
Molecular weight
Description
CH3COOH
1.07 1.07 acetic acid, mg/L
60.05 g/mol
Colorless liquid, strong vinegar odor
Solution strength
Specific gravity
Density, kg/L (lb/gal)
Flash point, C (F)
Freezing point, C (F)
100% (Glacial)
1.051
1.05 (8.76)
42.8 (109)
16.6 (61.9)
56%
1.061
1.06 (8.85)
63.3 (146)
23 (9.4)
20%
1.026
1.03 (8.56)
80.6 (177)
6.5 (20.3)
14-75
14-76
Recycle streams from sludge processing operations could impose significant additional
nutrient loadings, overwhelming the EBPR process. The magnitude of the problem is
dependent on the type of sludge processing and handling operations. The effect of recycle streams could be minimized by:
14-77
14-78
There are many texts and references for more information (Barnes and Bliss, 1983;
Ekama et al., 1984; Grady et al., 1999; McCarty et al., 1969; Parker et al., 1975; Pitter and
Chudoba, 1990; Sharma and Ahlert, 1977; Stensel et al., 1973; Tchobanoglous and Burton, 2003; and U.S. EPA, 1993).
Overall denitrification results that interest the design engineer can be summarized
as follows:
Nitrate is converted to nitrogen gas in a step-wise manner; NO and N2O are also
gaseous and can be released from solution; N2O is of significant concern as a significant source of greenhouse gases from WWTPs.
Oxygen recovery is 2.856 mg O2/mg NO3-N reduced to N2. For the other steps,
the oxygen equivalency is:
(1) NO3-N reduced to NO2-N 1.142 mg O2/mg NO3-N reduced to NO2;
(2) NO2-N reduced to N2 1.713 mg O2/mg NO2-N reduced to N2;
(3) NO2-N reduced to NO-N 0.571 mg O2/mg NO2-N reduced to NO-N;
14-79
14-80
The most critical variables are the type and concentration of carbonaceous substrate
available in the mixed liquor. Two primary substrate conditions have been identified
for suspended-growth denitrification (Grau, 1982):
(1) Denitrification under noncarbon-limiting conditions, and
(2) Denitrification under carbon limiting conditions.
In biological nutrient removal systems, the first set of conditions typically corresponds
with those found in preaeration anoxic tanks (first anoxic or preanoxic tanks); the second set corresponds with conditions in postaeration anoxic tanks (second anoxic tanks)
or RAS endogenous denitrification tanks.
Of the several mathematical models for predicting denitrification rates, the most
common are:
Monod-type relationships, and
Zero-order equations (with respect to nitrate).
FIGURE 14.36
The following equations (based on 20C temperature) list kinetic expressions in common use (Grau, 1982). Table 14.16 summarizes typical values for the Monod kinetic
coefficients.
(1) Monod denitrification rate expression:
1 YH
rv , NO
max, H g
2.86 YH
Ss
SNO
K S K S b , h
NO
NO
s
s
(14.18)
14-81
14-82
Coefficient
Symbol
Typical range
Suggested
maxH
313
4.06.0
YH
KCOD
0.460.69
10180
0.67
1020
KNO
0.060.5
0.20.5
g
0.51.0
0.8
KO,H
0.100.28
0.10.2
CX,B
0.060.12
0.060.086
bH
0.05
Where,
rV,NO reaction rate per unit volume nitrate and nitrite nitrogen, mg
nitrate/nitrite NL/day;
YH biomass yield coefficient;
max,H maximum specific growth rate of heterotrophs;
g correction factor for H under anoxic conditions;
SS soluble biodegradable COD substrate;
KS half-saturation coefficient organic substrate;
SNO soluble material concentration nitrate and nitrite nitrogen;
KNO half-saturation coefficient nitrate-nitrite; and
Xb,h particulate heterotrophic biomass.
(2) Zero-order denitrification rate expression:
rV,NO k
Where,
k reaction rate coefficient.
Selected zero-order rate constants, as reported in the literature, are tabulated in Table 14.17.
The correction factor (g) applied to the specific growth rate of heterotrophs was
proposed to account for observed reductions in the growth of heterotrophs under
mg NO3-N/mg TSSd
Glucose
Modified
LudzackEttinger
plug flow (k1)
Modified
Ludzack-Ettinger
plug flow (k2)
Wuhrmann plug
flow (k3)
Bardenpho
Acclimated plug flow
Bardenpho
Laboratory batch
Various
Laboratory complete
mix
Various
Pilot plant
Pilot plant
Parker (1974)
Mulbarger et al. (1970)
Barnard (1975)
Kang et al. (1990)
Barnard (1975)
Dawson and Murphy (1972)
Parker (1974)
Becarri et al. (1983)
Reference
Type system
* MLVSS mixed liquor volatile suspended solids; TSS total suspended solids; and VSS volatile suspended solids.
Methanol
Methanol
0.0620.070
0.062
0.15
22
20
mg NO3-N/mg VSSd
mg NO3-N/mg
MLVSSd
mg NO3-N/mg
MLVSSd
mg NO3-N/mg VSSd
mg NO3-N/mg VSSd
0.120.60
0.192
Activated sludge
mg NO3-N/mg TSSd
mg NO3-N/mg VSSd
mg NO3-N/mg TSSd
mg NO3-N/mg VSSd
mg NO3-N/mg VSSd
mg NO3-N/mg VSSd
0.086
0.062
0.031
0.68
0.030.11
0.210.32
Endogenous
22.5
1725
22
17-25
20
1527
25
mg NO3-N/mg VSSd
0.072
0.593
mg NO3-N/mg VSSd
0.100 8
Methanol
Activated sludge
1224
mg NO3-N/mg VSSd
0.720
Substrate
20
9
1224
Units*
Temperature
range, C
TABLE 14.17
14-83
14-84
(14.20)
(14.21)
Where,
rX denitrification reaction rate;
Ea activation energy, kJ/mole;
R universal gas constant 8.31 J/mole/K;
T temperature, K or C; and
A0 Arrhenius frequency factor.
ln
rX , 1
rX , 2
(14.22)
Where,
empirical temperature coefficient, and
r
Q10 X ,1
exp[Ea (10)/RT1 (T1 10)]
rX ,2 T10 C
(14.23)
(14.24)
14-85
19 500
19 000
15 300
15 880
3.0
1.74
3.3
3.3
2.0
1.12
1.10
1.06
1.13
1.15
1.08
1.03
1.06
10 000
11 090
1.20
1.07
15 900
Activation
energy,
kJ/mol
1.094
Q10
value
2.5
2.5
2.1
2.0
1.09
values
Barnard (1975)
Suspended growth
Suspended growth
Laboratory batch
Batch activated sludge,
SRT 2 days
Continuous activated sludge
Suspended growth,
SRT 7.6 days
Activated sludge
Separate sludge
Single sludge
Suspended-growth (first anoxic)
(SRT 1025 days)
Suspended-growth (first anoxic)
(SRT 1025 days)
1725
527
1020
1525
1020
1020
Stensel (1970)
Mulbarger et al. (1970)
Barnard (1975)
References
Type of system
625
616
1020
525
515
1020
1725
Temperature
range, C
1020
Wastewater
625
Wastewater
625
Raw and settled wastewater 1224
Methanol
Wastewater
(exogenous
carbon)
Endogenous
(no external
carbon)
Methanol
Methanol
Methanol
Substrate
14-86
TABLE 14.18
14-87
14-88
(14.25)
Where,
temperature coefficient, and
T water temperature (C).
Unit process configurations for biological nitrogen removal can be simulated through
use of process modeling techniques using International Water Association (IWA) type
activated sludge models (ASM). Process modeling is described in detail elsewhere
(Water Environment Federation, 2009). However, there several considerations specific
to nitrogen removal modeling that are noted here.
Key design criteria for nitrogen removal common to biological treatment configurations include SRT, temperature, recycle rates, and dissolved oxygen concentrations
throughout the process. These criteria should be established before use of a process simulator, but can be refined throughout the modeling task as design details are optimized.
For a biological nutrient treatment system, an initial screening for typical process
configurations (for example, Modified LudzackEttinger or Bardenpho) should be completed before using a process simulator. The screening process may refine the number
of configurations to be modeled. The benefit of using a process simulator is that any
number of different configurations can be simulated in a reasonably short period of
time, but an initial screening may result in a more efficient modeling effort. The process
simulator can then be used to optimize the design and help the designer select the
appropriate configuration for the treatment system.
Initial sizing should be based on industry standard criteria (SRT for each reactor,
MLR, etc). This provides a base model for the selected configuration, again improving
the overall efficiency of the modeling task. From the base model, various iterations and
configuration modifications can be evaluated to come up with the optimized design.
Several key wastewater parameters that should be monitored during the design
and evaluation process (presented in terms common to the ASM models):
SO, dissolved oxygenessential in establishing the anoxic or aerobic environments required for total nitrogen removal. The SO profile through the reactor can
be developed and limitations to the configuration can be addressed. Issues such
as high SO levels within the mixed liquor recycle, which can be detrimental to an
anoxic environment, can be quantified and accounted for in design.
SS, soluble biodegradable productsrepresents the associated readily biodegradable COD and VFA concentration available. Most simulators further fractionate
SS into SF and SA to better simulate biological phosphorus removal. With any biological nutrient system, the availability of SS is essential to the performance of the
system. By tracking the concentration of SS, the size of individual zones (or reactors) included in the model can be optimized along with the internal recycle
streams. If SS is not available in the quantities required to meet the treatment
goals, then supplemental carbon sources maybe be warranted. Carbon-limited
conditions can be seen when SS is less than the half saturation value for the substrate in a particular anoxic zone. If this occurs, then process simulation can be
used to identify system deficiencies and optimize supplemental carbon addition.
SNH, soluble ammoniaconcentrations in each zone can be monitored and
adjusted to optimize removal. A SNH profile through the basin will provide valuable information on how it responds to the selected process configuration.
SNO, soluble nitrate/nitrite Nremoval of SNO is essential in a biological nitrogen
removal system, and a process simulator allows design to quantify the level of
removal throughout the process. The anoxic and aerobic reactor will then be
sized accordingly, along with internal recycle rates, to meet treatment goals. Similar to the approach described for SS, availability of SNO in an anoxic zone provides valuable information on how to design the nutrient removal system. For
example, if the SNO levels in an anoxic zone are low (i.e., less than KNO values),
and there is still adequate SS in the system, then further SNO removal can be
achieved by increasing the mixed-liquor recycle rates (to supply more SNO to the
anoxic zones). Conversely, if the anoxic zones are showing higher levels of SNO,
then it may be possible to reduce mixed liquor recycle rates and save power.
SALK, alkalinityavailable alkalinity (or higher pH) is a key requirement for
ammonia removal. A process simulator allows a designer to identify any alkalinity deficiencies within the process and adjust the configuration accordingly. Biological nitrogen removal replenishes system alkalinity as described previously.
XTSS, total suspended solids (MLSS) solids inventory within the process can be
tracked, providing the designer with information on the appropriate size and
associated capacity of the treatment system. Impacts on basin sizing to the XTSS
are easily quantified, and adjustments made to meet treatment goals.
A significant advantage of using a process simulator for the design of a treatment system is the efficiency with which optimization of the treatment configuration can be
achieved. Multiple treatment scenarios and configuration alternatives can be evaluated.
Completing a sensitivity analysis on a basin configuration is a common practice to help
14-89
14-90
FIGURE 14.39 Wuhrmann process for nitrogen removal (RAS return activated sludge
and WAS waste activated sludge).
FIGURE 14.40 LudzackEttinger process for nitrogen removal (WAS waste activated
sludge).
14-91
14-92
FIGURE 14.41 Modified LudzackEttinger process for nitrogen removal (WAS waste
activated sludge).
sludge settling. The process effluent typically will contain between 6 and 10 mg/L of
nitrate nitrogen and is the most common method of achieving nitrogen removal.
4.2.2.1.2 Four-Stage Bardenpho
The four-stage Bardenpho process consists of a series of four anoxic and aerobic
zones with recycling of mixed liquor from the first aerobic zone to the first anoxic zone
at a rate as high as four to six times the influent flow rate (Barnard, 1973a, 1973b, 1974,
1976, 1983a; Ekama et al., 1984; Irvine et al., 1982; Kang et al., 1990). This process (Figure 14.42) is intended to achieve more complete nitrogen removal than is possible with
a two- or three-stage process. Complete denitrification cannot be attained with preaeration anoxic zones because part of the aerobic stage effluent is not recycled through the
anoxic zone. The second anoxic zone provides for additional denitrification using
nitrate produced in the aerobic stage as the electron acceptor and endogenous organic
carbon as the electron donor.
The second (postaeration) anoxic zone is capable of almost completely removing
the nitrate in the aeration tank effluent, provided the size is adequate and supplemental carbon is added. The final aeration stage strips residual gaseous nitrogen (N2) from
solution and minimizes phosphorus release in the final clarifier by increasing the oxygen concentration.
The ability to successfully use the Bardenpho process to achieve an effluent concentration of total nitrogen as low as 2 to 4 mg/L depends on the ratio of oxidizable
FIGURE 14.42 Four-stage Bardenpho process for nitrogen removal (WAS waste
activated sludge).
nitrogen to carbon in the influent to the activated sludge process and on the use of supplement carbon addition. Ekama et al. (1984) report that the total Kjeldahl nitrogen
(TKN):COD ratio must be less than 0.08 to obtain complete denitrification.
4.2.2.1.3 Step-Feed
This process is essentially the same as conventional step-feed where a portion of the
influent to the process is fed to one or more points downstream of the head of the
reactor. The difference in step-feed nitrogen removal is that each of the feed points
has an anoxic zone for nitrogen removal. Step-feed nitrogen removal has been
implemented at several full-scale facilities in a variety of configurations and number of feed points. Figure 14.43 shows a schematic of a three-pass step-feed system
with an additional post anoxic zone (similar to the Bardenpho process) (Johnson
et al., 2003).
The primary benefits of the step-feed configuration include, as in conventional
treatment, capacity improvement for a given volume or reduced reactor volumes for a
specific capacity. In addition, for nitrogen removal, the step-feed process reduces or
eliminates the need to recycle nitrate back to the anoxic zones. Nitrate is supplied to
the anoxic zones from the upstream aerobic reactor directly, except for the first pass.
In the first pass, the only nitrate supply is from the RAS stream. For this reason, nitrified recycle from the end of the first pass to the head of the first pass is sometimes provided to make best use of the available carbon.
14-93
14-94
FIGURE 14.43
zone.
FIGURE 14.44
will vary with time because oxygen uptake and transfer rates will vary with wastewater
quality and flow. Therefore, reliance on this mechanism for denitrification requires a
comprehensive control system to monitor and control dissolved oxygen throughout the
basin. An alternate control mechanism is based on monitoring the reduced form of
nicotinamide adenine dinucleotide (NADH) levels in the system. The NADH levels correspond directly to the degree of nitrification and denitrification and are a more reliable
measurement than dissolved oxygen when operating at low dissolved-oxygen levels.
The energy input for mixing and aeration must be controlled to maintain the mixed
liquor in suspension. This system must afford sufficient operational flexibility with
adjustable weirs, variable speed, or two-speed aerators for varying the oxygen input to
match diurnal and seasonal changes in oxygen demand. Otherwise, during periods of
low loading, necessary anoxic zones will not develop.
The variable levels of oxygen that are present in oxidation ditches can be used to
promote simultaneous nitrification and denitrification or true anoxic zones within a
single ditch. Additionally, oxidation ditches can be configured in series of concentric
reactors with different oxygen levels in each, or simply as an aerobic reactor as
described previously in nitrogen removal processes.
14-95
14-96
14-97
14-98
FIGURE 14.45 Dual-sludge processes for nitrogen removal (WAS waste activated
sludge) (Grady and Lim, 1980).
A third configuration, shown in Figure 14.45c, also eliminates the need for supplemental carbon. In this configuration, the anoxic system precedes the aerobic system, thus
providing sufficient BOD for denitrification. An additional recycle stream supplies
nitrate. This flow scheme offers the possibility of reducing aeration needs because a substantial portion of the BOD can be oxidized in the anoxic system. Although some oxidized nitrogen will be discharged, its magnitude will be related to the recycle flow used.
14-99
14-100
14-101
14-102
FIGURE 14.46 Modified Bardenpho process for phosphorus and nitrogen removal
(WAS waste activated sludge).
required supplemental chemical addition (metal salts and/or carbon) to meet effluent
phosphorus limits of less than 1.0 mg/L. Plants using this process use a variety of aeration methods, tank configurations, pumping equipment, and methods of solids handling. Figures 14.47 to 14.49 present typical effluent nitrogen and phosphorus concentrations from several existing five-stage facilities.
4.3.2.2 A2/O
Figure 14.50 shows the flow schematic of a typical three stage anaerobic anoxic/oxic
(A2/O) process (Deakyne et al., 1984; Irvine et al., 1982; Krichten and Hong, 1981;
Paepcke, 1985). Each stage can be design as completely mixed, plug flow, or a combination. Mixed liquor is recycled from the end of the nitrification (aerobic) stage to the
anoxic stage for denitrification at an internal recycle rate typically ranging from 100 to
400% of the influent flow. Clarifier underflow returns to the first stage of the anaerobic
reactor with the reactor feed.
Typical effluent nitrogen and phosphorus concentrations for two existing facilities
using the A2/O process are shown in Figures 14.51 and 14.52. The Largo phosphorus
and nitrogen data represent monthly average values from January 1984 to November
1987 (CH2M Hill, 1988). The Fayetteville nitrogen data are monthly averages for a 5.5
m3/d (1 gpm) pilot plant operated from January through December 1985; phosphorus
data are daily values from October 1988. Fayetteville typically used an alum dose of
Yes
Yes
228
2 626
230
Second aeration
volume, m3
Total volume, m3
Clarification surface
area, m2
461
41
Yes
Alum
Yes
Vertical
axial flow
Yes
Alum
90 gpda
1 960
1 760
7 920
461
Horizontal
axial flow
Yes
Alum
2040 mg/L
Yes
2 100
21 501
379
2 196
12 643
4 013
2 271
Belt press
dewatering
landfill
No
Carrousel
mechanical
surface
aerators
28 400
Orange
County,
Florida
(phase III)
41
Vertical
turbine
Yes
Alum
50 mg/L
No
3 220
31 200
1 000
4 100
18 900
3 500
3 680
Belt press
dewatering
landfill
No
Carrousel
mechanical
surface
aerators
0.5
41 600
Fort
Myers,
Florida
Central
461
Horizontal
axial flow
Yes
Alum
Yes
2 100
10 500
260
1 300
6 000
1 500
1 440
Belt press
dewatering
landfill
No
Fine-bubble
0.7
7.3
17 000
City of
Cocoa,
Florida
41
Vertical
turbine
Yes
930
12 300
200
2 600
5 800
2 300
1 500
Belt press
dewatering
landfill
No
Carrousel
mechanical
surface
aerators
3.1
6.3
15 100
Tarpon
Springs,
Florida
4.51 to 181
Archimedes
screw
12 350
87 240
8 100
14 400
44 100
14 400
6 240
Anaerobic
digestion of
primary sludge.
Yes
Mechanical
surface
aerators
150 000
Johannesburg,
South Africa
(Goudkoppies)
Ratio
Intrenal recycle
Type
Chemical addition
Type
Dose
Yes
17 600
496
Second anoxic
volume, m3
Filtration
2 640
1 060
Aeration volume, m3
3 520
614
1 760
228
DAFb thicken
WAScland
application
gravity
thicken
primary
Anaerobic
digestion for
primary
sludge
Submerged
turbines
1
Submerged
turbine
Anaerobic volume, m3
Sludge handling
Primary settling
Aeration mode
22 500
5 300
Palmetto,
Florida
Kelowna,
British
Columbia,
Canada
Parameter
TABLE 14.19
14-103
14-104
FIGURE 14.47 Frequency curves for total effluent phosphorus from modified Bardenpho process.
FIGURE 14.48 Frequency curves for total effluent nitrogen from modified Bardenpho process
(three plants).
FIGURE 14.49 Frequency curves for total effluent nitrogen from modified Bardenpho process (four
plants).
Downloaded from Digital Engineering Library @ McGraw-Hill (www.accessengineeringlibrary.com)
Copyright 2009 The McGraw-Hill Companies. All rights reserved.
Any use is subject to the Terms of Use as given at the website.
FIGURE 14.50
sludge).
approximately 15 mg/L for effluent polishing during this period. The A2/O process
is quite popular. It can attain secondary effluent total phosphorus concentrations as low
as 1 to 2 mg/L and total nitrogen concentrations as low as 8.0 mg/L. Typical design
parameters for existing A2/O systems are contained in Table 14.20.
FIGURE 14.51
14-105
14-106
FIGURE 14.52
Not in use
Occasional
Alum
Varies
Yes
2 920
21 950
26 690
2 370
2 370
Aerobic
digestion belt
press land
application
Yes
Mechanical
2S, 5W
1
65 900
A /O
11
No
Chemical addition
Type
Typical dose
Internal recycle
First anoxic
Anaerobic
934
Yes
6 689
9 940
Aeration volume, m3
Total
Filtration
1 298
Clarification surface
area, m2
1 953
Sludge handling
Anoxic volume, m3
Yes
Belt press
dewatering
pelletization
Primary settling
Anaerobic volume, m3
Slow-speed
mechanical
aerators
18
9
Aeration mode
51 100
A /O
Largo, Florida
Fayetteville,
Arkansas
11
No
No
883
7 086
7 359
136
136
Incineration
Yes
Fine bubble
3S, 9W
No limit
32 200
A /O
Montgomery
County,
Pennsylvania
Design flow, m /d
Process type
Parameter
TABLE 14.20
11
No
No
2 191
11 148
13 458
1 540
770
11
Yes
Caustic
for pH
No
19 006
9 814
12 906
1 437
1 954
Anaerobic
digestion
centrifuge
landfill
Yes
Fine bubble
Fine bubble
Yes
10 (NO3)
1S, 3W
2.0
30 900
A2/O
No limits
30 300
A2/O
Newark, Ohio
Warminster,
Pennsylvania
11
11
No
No
5 700
26 500
41 100
7 300
7300
Centrifuge
incineration
Yes
Fine buble
151 400
VIP
Lamberts
Point,
Virginia
14-107
14-108
FIGURE 14.53 University of Cape Town process for phosphorus and nitrogen removal
(WAS waste activated sludge).
In the modified UCT process, the anoxic zone is divided into two reactors. Return
sludge enters the first reactor, and internal recycle from the aeration tank enters the second anoxic reactor. Internal recycle to the anaerobic zone comes from the first anoxic reactor. The modified UCT process was intended to eliminate nitrate recycle to the anaerobic
tank while limiting the actual hydraulic retention time in the anoxic zone to one hour.
4.3.2.4 Virginia Initiative Plant
The Virginia initiative plant (VIP) process, shown in Figure 14.55, is a further refinement of the UCT process (Daigger et al., 1988; Grady et al., 1999). As in the MUCT
process, the anoxic zone is split into two reactors. The RAS and mixed-liquor recycle is
returned to the first anoxic zone, but instead of returning denitrified mixed liquor from
the first anoxic zone to the anaerobic zone (as in the UCT and MUCT processes), the
anaerobic return is taken from the second anoxic zone.
FIGURE 14.54 Modified University of Cape Town process for phosphorus and nitrogen
removal (WAS waste activated sludge).
FIGURE 14.55
4.3.2.5 Johannesburg
The Johannesburg (JHB) process, shown in Figure 14.56, also was developed in South
Africa (Nicholls et al., 1987). The distinguishing feature of this process is the RAS denitrification zone before the anaerobic zone. The concept behind this process is that
endogenous respiration within the RAS provides the carbon needed to denitrify the
RAS before it enters the anaerobic zone. Although endogenous respiration is a relatively slow process, increased RAS thickness in the denitrification zone increases the
rates enough to get good NOX removal. This process has three primary benefits when
compared to other combined removal systems: (1) anaerobic zone mixed liquor is at
full concentration; (2) using endogenous respiration for nitrogen removal does not
require carbon from the feed, thus resulting in efficient carbon usage; and (3) denitrified
mixed liquor recycle stream is eliminated.
FIGURE 14.56
14-109
14-110
FIGURE 14.57 PhoStrip II process for phosphorus and nitrogen removal (WAS
waste activated sludge).
FIGURE 14.58 Sequencing batch reactor for carbon oxidation and phosphorus and
nitrogen removal.
14-111
14-112
TABLE 14.21
Carbon source
Chemical formula
Methanol
Ethanol
Acetic acid
(100% solution)
Acetic acid
(20% solution)
Sugar (sucrose)
(50% solution)
MicroC, MicroCm,
MicroCg
UnicarbDN
MicroCglycerine
Primary sludge
fermentate
Specific gravity
CH3OH
CH3CH2OH
CH3COOH
0.79
0.79
1.05
1 188 000
1 649 000
1 121 000
CH3COOH
1.026
219 000
C12H22O11
1.22
685 000
Proprietary products,
include 5% methanol
Glycerine based
1.161.22
VFAs
(primarily acetic and
propionicacids)
1.09
1.18
1.0
TABLE 14.22 Selected denitrification kinetics and stoichiometric coefficients for alternate carbon
source (deBarbadillo et al., 2008).
Maximum specific denitrifier growth rate
Carbon source
(a)
Methanol
Methanol(b)
Methanol(d)
Methanol(e)
mmax, 1/d
Temp, C
0.5
1.0
1.3
13
19
20
(developed Arrhenius
coefficient of 1.13)
10
20
20
(developed Arrhenius
coefficient of 1.13)
0.52
1.86
1.25
Methanol(f)
Acetate(a)
Acetate(b)
Acetate(c)
Acetate(f)
1.3
3.7
4.0
13
19
20
Yield, Y
(g biomass COD/g
substrate COD)
COD/NO3-N Ratio
0.38
4.6
0.4
4.79
0.45
5.2
(calculated)
3.5
1.18
0.192
0.18
3.6
3.5
(calculated)
14-113
14-114
FIGURE 14.59
4.4.2 Fermentation
Fermentation of primary or waste activated sludge results in conversion of particulate
material into soluble VFAs. Fermentate is typically a mixture of acetic and propionic
acids and is a carbon source for phosphorus and nitrogen removal. The benefit of using
fermentate for these two applications is that, once the capital investment is made, fermentation has a low operating cost compared to purchasing an external carbon source.
In addition, because it is derived from the facilitys influent load, it has no net carbon
addition on the system. This reduces overall sludge production compared to adding an
external carbon source. Note that the overall sludge production will be slightly higher
as a result of the additional WAS load, which typically exhibits less degradability in
digestion, created by diverting the fermentate to the suspended-growth process.
A disadvantage of RAS fermentate is that it typically contains some level of both
ammonia and soluble phosphorus. This prevents its use in secondary anoxic zones
14-115
14-116
FIGURE 14.61
14-117
14-118
FIGURE 14.62
FIGURE 14.63
FIGURE 14.64
14-119
14-120
FIGURE 14.65
14-121
14-122
4.5.2 Mixing
The purpose of mixing is to blend streams, keep solids in suspension, or degas the
mixed liquor before settling.
The mixer and the shape/baffling of the tank cannot be considered separately.
Mixer selection and position should be done in cooperation with a qualified vendor.
The mixers should be positioned so that they do not induce localized back flow into the
preceding zones. The mixers should not entrain oxygen into the mixed liquor.
4.5.2.1 Blending Streams
Combining of two streams requires mixing. In some situations, it is important that the
two streams are mixed before entering a zone. The two most common situations are
when VFAs are added before an anaerobic zone and when the sewage feed and the RAS
(14.26)
Where,
G root mean square velocity gradient (sec1);
Q airflow rate (m3/min);
liquid specific weight (N/m3);
h water depth above diffusers (m);
60 conversion from minutes to seconds;
V volume of tank (m3); and
w absolute viscosity (N/secm2).
14-123
14-124
(14.27)
Effluent suspended solids concentration tends to rise once G exceeds 125 sec1 and disintegrates above 260 sec1. In normal aeration systems, the activated sludge will remain
in suspension with G values between 20 and 75 sec1.
In racetrack systems, some manufacturers use a mechanical mixer to maintain mixing and the aeration grid to provide aeration. In order to prevent the air bubbles interfering with the mixing pattern, a minimum distance between the mixer and the downstream aeration grid must be maintained. The mixer or diffuser vendor may provide
this to the designer. Typical values are either the width of the channel or the water
depth depending on the size of the racetrack.
4.5.2.4 Degasification
When an aeration tank depth exceeds 8 m, a degasification zone often is provided. This
zone is mixed either by air or mechanical means to strip dissolved gases from the MLSS
before it enters the clarifier. For a fine-bubble diffused air denitrifying plant, this is typically done using a shallower zone that is either aerated or mixed. A typical retention
time at average flow is 20 minutes.
4.5.2.5 Scum/Foam Control
Baffles within a reactor should promote, or not restrict to the extent possible, movement
of scum or foam through the reactor to a point where it can be wasted from the system
by either a scum/foam wasting weir or selective wasting. A scum/foam wasting weir
requires an underflow baffle that traps the scum while allowing flow to pass under the
baffle. The depth of this baffle should be at least 1 m below the water surface to prevent
scum from being drawn down with the flow. The purpose of scum and foam control is
to waste floating biomass from the process to the limit accumulation of filamentous
organisms that would otherwise adversely affect system performance and lessen floating materials requiring manual removal.
There are two types of systems: (1) a dedicated system removes only enough MLSS
to remove the scum and (2) a selective wasting system removes enough MLSS to main-
14-125
14-126
5.2 Microbiology
As with anaerobic sludge stabilization processes, anaerobic processes for wastewater
treatment rely on a consortium of facultative and anaerobic bacteria to degrade organic
materials. In anaerobic treatment processes, a series of reactions convert organic materials in the wastewater to carbon dioxide, methane, and additional biomass. As illustrated in Figure 14.66, four major groups of biological reactions comprise anaerobic
decomposition: (1) hydrolysis, (2) acidogenesis, (3) acetogenesis, and (4) methanogenesis. In hydrolysis, strictly anaerobic and facultative anaerobic bacteria convert the
biodegradable COD (large organic polymers including proteins, carbohydrates, and
lipids) to simpler, soluble monomeric compounds like amino acids, sugars, and longchain fatty acids. In acidogenesis, there is a further breakdown into VFAs. Following
hydrolysis and acidogenesis, fermentative bacteria convert hydrolysis products to
acetate, carbon dioxide, and hydrogen. In the final step, methanogens convert the
acetate to methane, carbon dioxide, and water. More information on the details of
anaerobic decomposition can be found in several references (Grady et al., 1999; Henze
et al., 2008; Jordening and Winter, 2005; Pavlostathis and Giraldo-Gomez, 1991; Speece,
1996; Vaccari et al., 2006).
14-127
14-128
Carbohydrates
Sugars
Fats
Fatty acids
Proteins
Amino acids
Carbonic acids
and alcohols
Hydrogen
Carbon dioxide
Ammonia
Hydrogen
Acetic acide
Carbon dioxide
Methane
Carbon dioxide
FIGURE 14.67 Schematic illustrations of several types of anaerobic reactor configurations: (a) upflow sludge blanket; (b) biofilm fluidized bed; (c) expanded granular sludge
bed; (d) anaerobic baffled reactor; (e) internal circulation; and (f) anaerobic hybrid reactor (Nicolella, 2000).
14-129
14-130
FIGURE 14.68 Schematic illustration of upflow anaerobic sludge blanket (UASB) reactor (van Lier, 2003).
5.4.2 Installations
Gatze Lettinga and coworkers at the University of Wageningen (Wageningen, The
Netherlands) first developed the UASB process in the 1970s as a unique anaerobic treatment technology. Between 1983 and 1992, UASBs were studied at laboratory scale and
later at demonstration scale. Initially the UASB process was developed for full-scale use
in industrial applications because the process is well suited for treating warm, soluble,
high COD wastewaters. The UASB reactors proved to be successful for high-strength
14-131
14-132
27
78
38
2.6
108
0.4
India
India
India
India
India
India
India
India
India
Mexico
Mexico
Mexico
Sonipat
Gurgaon
Panipat
Yamunanagar
Karnal
Ghaziabad
Noida
Agra
Saharanpur
Tapeyanco
Atlamaxac. Tlaxcala
Fideicomiso Alto Rio
Blanco. Istaczoquitlan
Ezperanza
40
56 and70
25 and10
30
30
35 and 10
20, 45 and 50
India
36
0.20.6
0.6
0.228
0.7
28
14
5
Faridabad
Colombia
Brazil
Brazil
Brazil
Brazil
India
India
Cali
Campina Grande
Sumare
Sao Paulo
Recife
Mirzapur
Kanpur
3147
India
Colombia
Bucaramanga
Kanpur
Country
Design
Flow
(MLD)
1995
1994
5 16 740
135
1999
1998
2000 and
1999
2000 and
2002
2000
2002 and
2002
2000
2004
2000
1990
1998, 1998
and 1999
1994
7 000,
16 000 and
18 000
11 000
11 000
13 000 and
10 000
9 000 and
3 500
14 000
20 000 and
26 000
14 000
10 000
28 000
2 200
1 200
19831989
1989
1992
19861991
1997
1994
1989
1990
3 3 300
64
160
67.5
120
810
Start-up
Date
(year)
Reactor
Volume
(m3)
Plant
TABLE 14.23
Comments
14-133
14-134
estimation of sludge and biogas production, design of the flow distribution, odor control, provisions for scum removal, and materials selection.
5.4.3.1 Reactor Sizing
As with any biological suspended-growth treatment process, expected bacterial growth
rates control reactor biomass inventory, while minimum biomass settling velocities dictate the surface area for the solids separator and, for UASB reactors, the cross-sectional
area of the reactor. For anaerobic process, the controlling growth rates are those of the
slowest growing methanogens with maximum specific growth rates on the order of 0.12
day1. Because of low growth rates and difficulty in predicting the minimum growth
rate for the diverse consortium of microorganisms in the sludge blanket, recommended
safety factors on SRT for anaerobic processes are high, at approximately 3 to 10 (Henze,
2008; Speece, 1996). Figure 14.69 provides an estimate of the required SRT as a function
of temperature for treating domestic wastewater in a UASB reactor. Operating experience gained from demonstration and full-scale UASBs, rather than explicit measurements of sludge settling velocities, provides the basis for current guidelines for sizing
of reactors and GLS separators.
For domestic wastewater, sizing the reactor based on HRT provides a practical
approach because for low-strength wastewater (COD 1 000 mg/L) the hydraulic load
limits the design (Chernicharo, 2007; Henze, 2008). An average HRT for a single-stage
UASB treating domestic wastewater is approximately six hours. Values reported in the
literature range from 4 to 10 hours. Current design criteria for HRT for UASB reactors
are provided in Table 14.25. Regardless of the method used to size the reactor, the
expected SRT must still be estimated to ensure adequate design.
Use of the organic loading rate (OLR) is appropriate for high strength domestic
wastewaters because the organic load rather than the hydraulic load limits design. Care
must be taken, however, in defining and applying the OLR as the term can apply to the
applied load, removed load, or the converted load (van Haandel and Lettinga, 1994).
FIGURE 14.69 Required solids retention time (SRT) for domestic wastewater treatment
as a function of temperature (Henze et al., 2008; reprinted with permission from IWA
Publishing).
For domestic wastewater, constraints imposed by biomass settling velocities will limit
the OLR to 1.5 to 3.0 kg CODapplied/m3d. The OLRs for high-strength wastewaters with
a significant amount of particulate COD are listed in Table 14.26 and are presented as
an example of the OLR limits of the process.
Until mathematical models for anaerobic treatment become more advanced, prediction of effluent water quality must be done using empirical relationships between
HRT and performance (Table 14.27 and Figure 14.70) (Chernicharo, 2007; van Haandel
et al., 2006). Careful judgment must be exercised in the use of these empirical relationTABLE 14.25 Recommended hydraulic detention times for UASB reactors treating
domestic sewage (Lettinga and Hulshoff Pol, 1991; reprinted from Water Science and
Technology, with permission from the copyright holders, IWA).
Hydraulic detention time (hour)
Sewage temperature (C)
Daily average
16 to 19
20 to 26
26
10 to 14
6 to 9
6
14-135
14-136
ships, as considerable scatter exists in the limited performance data from full-scale
facilities (see Figure 14.71), and data are only available for operation under tropical
conditions.
For domestic wastewater, current criteria call for superficial upflow velocities to be
maintained below approximately 1.0 m/h with average velocities in the range of 0.4 to
0.8 m/h. A design value of 0.75 m/h has been widely used for UASB reactors in India.
UASB reactor dimensions and upflow velocities are interrelated. Typical reactor heights
range from 3 to 5.0 m with a common value of 4.5 m. Greater heights may be required,
however, for wastewaters with high suspended solids concentrations (Wiegant, 2001).
Settler compartments comprise 1.5 to 2.0 m of this total height.
Successful UASB operation depends on proper hydraulic distribution of the feed
flow to prevent channeling of the wastewater through the sludge blanket and to avoid
the formation of dead corners in the reactor. Flow must be divided proportionately to
each reactor and then uniformly distributed to the numerous feed points located
across the bottom of the sludge blanket. The recommended density of feed inlet points
is currently approximately one for every 2.0 m2. Higher densities are recommended
TABLE 14.27 Empirical equations for estimating UASB reactor performance and effluent
water quality (Chernicharo, 2007; reprinted with permission from IWA Publishing).
Parameter
Empirical equation*
Ceff So
E So
100
90
80
70
UA
S
er
ilt
f
ic
ob
r
ae
An
50
30
0
1
10
20
50
100
for low influent concentrations of organics where low gas production increases the
risk of channeling and short circuiting. Table 14.28 presents guidelines on influent
flow distribution. Table 14.29 presents summary guidelines for the main hydraulic criteria and Table 14.30 provides other design criteria for UASB reactors treating domestic
wastewater.
5.4.3.2 Gas/Liquid/Solids Separation
As with any suspended-growth biological treatment process, retention of solids in the
UASB process is critical. In UASB reactors, the need to separate gas and solids from the
liquid stream complicates settler designs. Suggested guidelines for the GLS are to provide a minimum slope for the settler bottom of 45 to 60, to provide an overlap of 10 to
20 cm for the deflectors under the entrance to the settling zones, to provide a surface
area for the openings between the gas collectors of 15 to 20% of the reactor surface area,
and to provide a gas collector height of 1.5 to 2.0 m (van Lier, 2003).
14-137
14-138
FIGURE 14.71 Experimental data on chemical oxygen demand (COD) removal efficiency in upflow anaerobic sludge blanket (UASB) reactors as a function of hydraulic
retention time (van Haandel et al., 2006).
TABLE 14.28 Preliminary guidelines for flow distributors in UASB reactors (Lettinga
and Hulshoff Pol, 1991; reprinted from Water Science and Technology, with permission
from the copyright holders, IWA).
Sludge Type
Relatively dense and flocculent
(concentration 2040 kg TSS/m3)
Dense and flocculent
(concentration 40 kg TSS/m3)
Granular
OLR
(kg CODapplied/m3/d)
1.0 to 2.0
3.0
1.0
1.0 to 2.0
3.0
2.0
2.0 to 4.0
4.0
Influent area of
each distributor
(m2)
1.0 to 2.0
2.0 to 5.0
0.5 to 1.0
1.0 to 2.0
2.0 to 3.0
0.5 to 1.0
0.5 to 2.0
2.0
For Qave
For Qmax
For Qpeaka
4.0
6 to 9
0.5 to 0.7
2.0 to 2.3
0.3 to 0.8
1.5 to 2.0
6.0
4 to 6
0.9 to 1.1
4.0 to 4.2
1.2
1.0
7.0
3.5 to 4
1.5
5.5 to 6.0
1.6
0.6
TABLE 14.30 Other design criteria for UASB reactors treating domestic sewage
(Chernicharo, 2007; reprinted with permission from IWA Publishing).
Criterion/parameter
Influent Distribution
Diameter of the influent distribution tube (mm)
Diameter of the tube exit mouth (mm)
Distance between the top of the distribution tube and the water
level in the settler (m)
Distance between the exit mouth and the bottom of the reactor (m)
Influence area of each distribution tube (m2)
Biogas Collector
Minimum biogas release rate (m3/m2/h)
Maximum biogas release rate (m3/m2/h)
Methane concentration in the biogas (%)
Range of values
75 to 100
40 to 50
0.20 to 0.30
0.10 to 0.15
2.0 to 3.0
1.0
3.0 to 5.0
70 to 80
Settler Compartment
Overlap of the gas deflectors in relation to the opening of the settler
Minimum slope for settler walls ()
Optimum slope of the settler walls ()
Depth of the settler compartment (m)
0.10 to 0.15
45
50 to 60
1.5 to 2.0
Effluent Collector
Submergence of the scum baffle or the perforated collection tube (m)
Number of triangular weirs (units/m2 of the reactor)
0.20 to 0.30
1 to 2
0.10 to 0.20
0.11 to 0.23
2 to 5
1 020 to 1 040
100 to 150
25 to 50
14-139
14-140
(14.28, 14.29)
Where,
CODM COD converted into methane (kg COD/d);
CODT,O influent total COD concentration (kg COD/m3);
CODT,e effluent total COD concentration (kg COD/m3);
CODR change in COD inventory in the reactor (kg COD/m3);
Q average flow (m3/d);
Yobs coefficient of solids production in terms of COD
0.11 to 0.23 kg CODsludge/kg CODapplied;
VR volume of sludge blanket in reactor (m3); and
XR change in reactor solids concentration (kg/m3).
The waste sludge term (YobsQSo) only applies if solids are wasted separately. If solids
are wasted in the effluent, then this term is not necessary. When evaluating operating
facilities, attention must also be given to the net change in the solids inventory in the
reactor. For design purposes, steady-state operation ( XR 0) is assumed.
The volume of a mole of methane at reactor operating conditions of temperature
and pressure can be calculated from the ideal gas law:
Vm
nRT
P
(14.30)
Where,
Vm volume of one mole of gas (m3);
n number of moles of gas 1;
P pressure (atm);
R universal gas constant;
8.20574587 105 atm-m3/mol-K; and
T operating temperature (K).
The volume of methane produced is then calculated from the COD equivalence of
methane:
QM COD M
Vm
K COD
(14.31)
14-141
14-142
Aerobic
RAS/Recycle
WAS
FIGURE 14.72
14-143
14-144
14-145
14-146
TABLE 14.31
Parameter
Units
Values
mg/L
mg/L
mg/L as N
mg/L
mg/L
5
1
1
10
3
cBOD5
TSS
Ammonia
Total nitrogen (with pre-anoxic zone)
Total nitrogen (with pre- and postanoxic zones)
Total phosphorus (with chemical addition)
mg/L
mg/L
NTU
Log removal
Log removal
0.2
(typical) 0.05
(achievable)
0.5
0.2
Up to 6 log (99.9999%)
Up to 3 log (99.9%)
14-147
14-148
2
Aerobic/ Effluent
Membrane
Influent
Aerobic
2-4Q
MLR (RAS)
FIGURE 14.73
Influent
Anoxic
Aerobic
3
Aerobic/ Effluent
Membrane
2-4Q
MLR (RAS)
FIGURE 14.74
Primary
Effluent
Ferric
1-2Q
1-2Q
1
Anaerobic
Anoxic
Aerobic
Aerobic
6
Aerobic/
Aerobic Membrane
5
Effluent
4Q
MLR (RAS)
FIGURE 14.75 Traverse City membrane bioreactor design for nitrogen and phosphorus
removal.
Supplemental addition of an external carbon source such as methanol to a
postanoxic zone to further enhance denitrification can be effective, particularly
in plants required to reduce total nitrogen to less than 5 mg/L.
The addition of chemicals for phosphorus removal can be practiced with MBRs
in a similar manner as for CAS processes. Because virtually all the particulate
phosphorus is removed in an MBR, the metal salt dosage required to achieve a
certain treatment objective may be lower with MBRs. Occasionally, metal salts
for phosphorus removal has had a beneficial effect on membrane permeability,
as increasing the size of the flocs makes for more easily filtered mixed liquor,
and reduces membrane fouling. Maximum chemical doses may be limited by the
membrane equipment.
Biological phosphorus removal can be achieved using many of the processes
proven to support the growth of PAOs. In this case, the preservation of soluble
organic material is even more important than for nitrogen removal, and the
Alum
1-2Q
1-2Q
Primary
Effluent
Anaerobic
Anoxic
Aerobic
Aerobic
Alum
6
Aerobic/
Aerobic Membrane
5
Effluent
4Q
MLR (RAS)
FIGURE 14.76
14-149
14-150
FIGURE 14.77 Impact of MLSS concentration on aeration alpha factor (WERF, 2002;
reprinted with permission of the Water Environment Research Foundation).
14-151
14-152
Depending on the manufacturer, however, membranes also may differ in pore size,
composition, cassette configuration, operating procedures, and maintenance requirements. Details on specific products must be obtained directly from the manufacturer.
(Note: In this manual, the term cassette refers to the largest membrane assembly removable by a crane. Depending on the manufacturer, this also may be referred to as a rack
or module.)
6.4 Pretreatment
6.4.1 Fine Screens
It is normal practice that fine screening equipment with a maximum of 1- to 2-mm
openings is provided to protect membranes from debris and fibrous materials. Typically, these screens are installed downstream of 6-mm screens, either at the headworks
or following primary clarification. Additional measures include placing covers over the
membrane tanks, or fine screening a portion of the mixed liquor as it is returned from
the membrane tanks to the bioreactor.
14-153
14-154
FIGURE 14.78
14-155
14-156
6.5.2 Mixing
The unaerated zones in the bioreactor typically are equipped with a dedicated mixer in
each zone to keep the solids in suspension. Unaerated zones may include deaeration
(or de-oxygenation) zones, preanoxic and postanoxic zones, and anaerobic zones.
Although submersible mixers are common, vertical shaft fixed-mounted mixers also
can be used. The mixers ensure adequate mixing within each zone for proper contact
between biomass, substrate, and oxygen source (nitrate or oxygen) and complete volume use without short circuiting across any zone.
FIGURE 14.79
There are many possible configurations for permeate pumping systems and many
different types of permeate pumps. The simplest configuration is a dedicated permeate
pump per membrane train (Figure 14.80). Permeate pumps can be end-suction centrifugal or positive displacement rotary lobe type. Each membrane train is equipped with a
permeate header that connects all the membrane cassettes within the train. When endsuction centrifugal pumps are used, some means of removing entrained air from the permeate needs to be included to prevent the pumps from losing prime. An air separator
connected to a vacuum pump or a venturi system can be used to remove entrained air.
Because rotary lobe pumps can handle a higher percentage of entrained air, the
permeate header typically is connected directly to the suction side of a self-priming
rotary lobe pump without any air separator.
A feature of rotary lobe pumps is that they can reverse the direction of flow by
reversing the direction of lobe rotation. When rotary lobe pumps are used in MBR systems, they most often serve double duty as both the permeate and backwash pumps.
14-157
14-158
FIGURE 14.80
The permeate pump typically is equipped with a variable frequency drive (VFD).
A dedicated magnetic flow (mag) meter and turbidimeter typically are located downstream of each permeate pump.
All permeate pumps discharge into a common permeate collection header for
downstream disinfection (optional) and discharge.
A schematic of the major unit processes (components) of a complete membrane bioreactor facility is shown in Figure 14.81. The equipment described in this section will be
limited to the MBR process equipment, specifically the equipment used in the bioreactor and in the membrane filtration system.
14-159
14-160
FIGURE 14.81 Process flow diagram of a typical membrane bioreactor facility (courtesy
of CH2M Hill).
individual diffuser grids in each aerobic zone. The process aeration blowers typically
are separate from air scour blowers, although the two systems may share a common
standby.
6.6.1.2 Air Scour Blowers
The membrane air scour blower system typically is designed as a common group of
blowers with installed standby units. Positive displacement or centrifugal blowers are
used (Figure 14.82). All blowers discharge into a common membrane air manifold that
delivers air to the air header above each membrane tank (train). Each membrane cassette is connected to the air header above each membrane tank using flexible hose or
rigid piping.
Membrane manufacturers dictate the design airflow rate of the air scour blowers.
Once the airflow rate per membrane cassette is specified, the air scour blower is sized
based on the maximum cassette spaces in the tank and the maximum possible liquid
level in the membrane tank. To supply the proper airflow rate for the number of membrane cassettes initially installed, the blower airflow rates could be reduced by adjusting the VFD, inlet control valves, or inlet control vanes or by resheaving the blowers.
This approach oversizes the blowers, but it provides the flexibility to add membranes
FIGURE 14.82
(if required) without having to add blower capacity. It also allows sufficient air to the
membranes and keeps them in production under the unlikely event that the liquid levels in the membrane tanks exceed normal operating level.
Air may be supplied to the membranes continuously or intermittently (sometimes
referred to as cyclic aeration). When intermittent aeration is used, the blowers are operated continuously at a fixed speed and airflow to independent aeration headers, or to
portions of the membrane assemblies, using either actuated valves or air-accumulation
and release devices. This enables air flows to vary between trains, groups of cassettes
within a train, or portions of a cassette.
The air scour blowers may form a part of the jet aeration system, where a twophase jet system is located at the bottom of each membrane module introducing both air
14-161
14-162
FIGURE 14.83
permeate from the backpulse tank is backpulsed through the membrane at a specified
flow rate, and the appropriate chemical is injected directly into the permeate header
using the chemical metering pumps to achieve the desired chemical concentration. In
some cases, the backpulse storage tank is equipped with a heating system to allow hotwater cleaning.
Separate chemical metering systems are used for each cleaning chemical used,
which include sodium hypochlorite and citric acid. Each metering station is equipped
with an appropriate chemical holding tank, a pair of chemical dosing pumps (one duty,
one online standby), and a calibration column. The chemical metering stations are
designed to deliver chemical for the following functions:
Sodium hypochlorite for maintenance cleaning, recovery cleaning, and to flush
the CIP/backpulse tank to prevent contamination and biogrowth in the tank; and
Citric acid for maintenance and recovery cleaning.
14-163
14-164
14-165
14-166
FIGURE 14.84 Aeration tank settling (Nielsen et. al, 2000; reprinted from Water Science
and Technology, with permission from the copyright holders, IWA).
14-167
14-168
FIGURE 14.85 Aeration tank settling potential to treat peak flows (n Vesilind coefficient
calculated using the Daigger sludge volume index [SVI] correlation with an SVI of 150).
and a lower concentration at the end. This minimizes the solids loading applied to the
secondary clarifiers and provides a greater solids inventory and larger SRT for a given
tank volume. The step-feed configuration becomes a contact stabilization process when
all the influent flow is added to a zone at the end of the aeration tank. With a contact stabilization mode of operation, a balance must be maintained between clarifier capacity
increase and reduced process performance as the contact zone volume is decreased.
Although process performance might suffer, the solids retained in the aeration tanks
facilitate rapid process recovery after the high flows subside.
Research and full-scale implementation of step-feed for control of wet-weather
flows has demonstrated that secondary treatment standards can be met while switching between conventional and step-feed modes of operation (WEF et al., 2005). Switching to a step-feed mode can be difficult for BNR process configurations that need to
retain nitrification and EBPR capabilities. The ease and cost of modifying an existing
CAS process to be able to switch to a step-feed configuration during peak flows
depends on the design of each facility. Care must be taken to provide adequate aeration
capacity in zones not originally designed to receive influent flow. Likewise, the effect of
transient solids load on the final clarifiers when switching to and from step-feed must
be accommodated.
14-169
U-tube
Others
jets
Nonporous diffusers
Diffused air
Porous diffusers
Equipment type
Ceramic, plastic,
flexible
membranes,
dome, disk, panel
tube, plate
configurations,
total floor grids,
single or dual
roll, fine bubble
Fixed orifice;
perforated pipe,
sparger, slotted
tube, valved
orifice, static
tube; coarse
bubble; typically
single or dual
roll; some total
floor grids
Compressed air and
pumped liquid
mixed in nozzle
and discharged
fine bubble
Equipment
characteristics
High-rate;
conventional,
extended, step,
contact stabilization,
activated sludge
systems
Limited
geometry
clogging of
nozzles;
requires
blowers and
pumps;
primary
treatment
required; low
SAE
Limited
geometry;
typically
effective for
strong waste
Good mixing
properties
high SOTE
High efficiency
because
driving force
is increased
Low oxygen
transfer
efficiency;
high initial
cost
Disadvantages
Do not typically
clog easy
maintenance;
high alpha
High-efficiency:
good
operational
flexibility;
turndown
approximately
5.1
Advantages
2.23.5
NA
NA
1.31.9
1.96.6
SAE, kg/kWhb
1524
913
1545
SOTE, %
14-170
TABLE 14.32 Characteristics of aeration equipment (Arora et al., 1985; Boyle, 1996; Goronsky, 1979; Groves et al., 1992;
and Wilford and Conlon, 1957).
Units contain a
low-speed
turbine and
provide
compressed air to
diffuser rings,
open pipe, or air
draft; fixedbridge
application; may
employ draft tube
Same as axial flow;
high speed
Horizontal rotor
Submerged turbine
Aerated lagoons;
temporary
installations
Oxidation ditch,
applied either as an
aerated lagoon or as
an activated sludge
Same as axial
flow, high
speed
Low cost
flexible
operation
Good mixing;
high capacity
input per unit
volume; deep
tank
application;
operational
flexibility; no
icing or
splash
Moderate initial
cost; good
maintenance
accessibility
Aerosols some
icing in cold
climates;
initial cost
higher than
axial flow
aerators; gear
reducer may
cause
maintenance
problems
Some icing in
cold climates;
poor
maintenance
accessibility;
mixing
capacity may
be inadequate
Subject to
operational
variable,
which may
affect
efficiency;
tank geometry
is limited
Require both
gear reducer
and blower;
high total
power
requirements;
high cost
Tank design
flexibility,
high pumping
capacity
0.50.8
1.12.1
(Typical)
2.03.0 (Drain
tube turbine)
1.52.1
1114
1521
Manufacturers data in clean water at standard conditions; diffused air units expressed as SOTE and SAE mechanical devices as SAE. Range of values accounts for different equipment, geometry,
gas flow, power input, and other factors (SAEwire-to-water).
b
Wire-to-water SAE for diffused air calculated from ??? compression relationship where ambient temperature = 30C, submergence = 4.3, barometric pressure 100 ha (1 atm), and blower/motor
efficiency 70%.
Asparating
Mechanical surface
Radial flow, low
speed (20100
r/min)
14-171
14-172
14-173
14-174
FIGURE 14.86
Selected porous diffusers: (a) disks, (b) dome, and (c) perforated membrane.
FIGURE 14.87
membrane.
Selected porous tubes: (a) rigid plastic and (b) flexible perforated
The dome, developed in 1954, is typically a 180-mm (7-in.) diameter disk with downturned edges. The dome, consisting of a ceramic material, is mounted on a polyvinyl
chloride (PVC) saddle attached by a center bolt. The disk, which has essentially
replaced the dome, varies in diameter from approximately 180 to 240 mm (7.0 to 9.5 in.)
for ceramic and porous plastic materials and from 180 to 500 mm (7 to 20 in.) for
14-175
14-176
FIGURE 14.88
14-177
14-178
FIGURE 14.89 Selected nonporous diffusers: (a) static tube, (b) orifice, and (c) tube (in.
25.4 mm).
FIGURE 14.90 Jet diffusers: (a) bender-type, (b) plan of radial-type, and (c) elevation of
radial-type (in. 25.4 mm and ft 0.304 8 m).
14-179
14-180
14-181
14-182
FIGURE 14.91
Aspirating device.
14-183
14-184
FIGURE 14.92
FIGURE 14.93
Submerged turbine aerators: (a) axial flow and (b) radial flow.
14-185
14-186
FIGURE 14.94
reported in CMAS to range from 0.56 to 0.8 kg O2/MJ (3.3 to 5.0 lb O2/hph) (Updegraff
and Boyle, 1988). In total barrier oxidation ditch configurations, however, draft tube
turbines produced low clean water wire-to-water SAEs ranging from 0.24 to 0.3 kg/MJ
(1.4 to 2.0 lb/hph) (Boyle et al., 1989).
14-187
14-188
14-189
14-190
8.5.2 Blowers
The term blower typically applies to air-conveying equipment that generates pressures
up to approximately 210 kPa (30 psi). As shown in Figure 14.95, many different types
of blowers are available. Two types of blowers used for single-stage and multistage
aeration are rotary positive displacement and centrifugal units. High-speed, lowcapacity turbine blowers have become available only recently and do not have a longterm record.
Positive displacement blowers are constant-volume devices capable of operating
over a wide range of discharge pressures. They have a low initial cost and require relatively simple control schemes. They are, however, the least efficient. In addition, they
are more difficult to operate at variable airflow rates (although variable capacity may be
provided through multiple machines with multispeed motors), require more maintenance, and can be noisy. Centrifugal blowers, considered as constant-pressure machines,
FIGURE 14.95
Blower selection.
14-191
14-192
14-193
14-194
FIGURE 14.96
FIGURE 14.97
[50 psig]) and at or near ambient room temperatures (10 to 27C [50 to 80F]). The
VSA/PSA process relies on swings in pressure to cycle zeolite molecular beds from an
absorption stage (high pressure) to a desorption and regeneration stage (low pressure)
and then back to an absorption stage (high pressure).
The process starts by providing ambient air through an intake filter to a blower or
compressor. Pressurized air is then sent through an aftercooler and onto zeolite beds
where the molecular sieve material absorbs nitrogen, carbon dioxide, water vapor, and
any residual hydrocarbons that may be present. The remaining oxygen gas passes
through the zeolite beds and is stored in a collection pressure vessel before being transported to the point of use.
The primary difference between VSA and PSA systems is that VSA systems operate at a lower pressure, in some cases, because of the proprietary nature of the molecular sieve. Vacuum swing absorption systems use a vacuum blower to remove nitrogen
and other gases from the zeolite media. This vacuum condition provides for slightly
faster and more efficient purge (or desorption) of the nitrogen rich bed.
The VSA system typically uses backup liquid oxygen (LOX) storage tanks for emergency situations or for peak periods when additional oxygen is required. Onsite LOX
14-195
14-196
14-197
14-198
TABLE 14.33 Correction factors and the source for transforming clean water
information to process conditions.
Factor
Source of information
C
F
14-199
14-200
SOTR V
KL a20 i C * 20 i
i1
(14.32)
Frequently, the SAE is calculated as the SOTR divided by power input. The standard
oxygen transfer efficiency (SOTE) in percent also can be estimated for diffused air systems by:
SOTE
SOTR
100
WO2
(14.33)
Where,
WO2 mass flow of oxygen in the gas feed stream.
It is important to use consistent definitions during aeration testing, subsequent data
analysis, and final result reporting. A consistent nomenclature has been established
with more logical and understandable terminology, which will eliminate much of the
difficulty in interpreting aeration literature (ASCE, 1992). Standard conditions for oxygen-transfer tests are defined as water temperature of 20C, barometric pressure of
100 kPa (1 atm), and dissolved oxygen concentration of 0.
*
(
C20
C)
*
C20
(14.34)
Where,
OTRf oxygen-transfer rate estimated for the system operating under process
conditions, mass/time;
SOTR standard oxygen-transfer rate of new diffuser, mass/time;
average process water KLa/average clean water KLa (both with new
diffusers);
14-201
14-202
14-203
14-204
TABLE 14.34 Assumptions necessary to develop equations for continuous steadyand non-steady-state tests (ASCE, 1997; Doyle and Boyle, 1985; and U.S. EPA, 1983b
and 1989).
Assumptions
Test conditions
Influent DO is constant
14-205
TABLE 14.35 Assumptions necessary to develop equations for steady- and non-steady-state batch
(ASCE, 1997; Doyle and Boyle, 1985; and U.S. EPA, 1983 and 1989).
Assumptions
Test conditions
tem. Factors under the control of staff, however, can affect long-term operations and
maintenance costs. An excellent summary of operations and maintenance for fine-pore
diffusers is found in other references (U.S. EPA, 1989; WPCF, 1988).
14-206
Factors
Tank configuration
Surface area
Depth
Flow distribution
Turbulence in conveyance structure
Site conditions
Sludge characteristics
MLSS concentration
Sludge age
Flocculation, settling and thickening characteristics
Type of biological process
* ADWF average dry weather flow, PDWF peak dry weather flow, and PWWF peak wet weather flow.
tling, occurs with concentrated suspensions that settle at lower velocities because water
is displaced as suspension settles. The result is clear liquid above the settling zone and
settling velocities that decrease with increasing concentration. Type III settling of the
sludge blanket is the most important for clarifier design and represents the behavior of
the sludge blanket wherein concentration increases with depth although solids are continuously removed as RAS at underflow concentration. In Type IV, or compression settling, particles are in contact and further settling can only occur by compression. Type
IV can exist in the sludge zone at the tank bottom.
Work by Coe and Clevenger (1916), Dick and Ewing (1967), Dick and Young
(1972), and Yoshioka et al. (1957) advanced the solids flux approach to clarification.
For a clarifier operating at a steady state, a constant flux of solids is moving downward (Figure 14.99). The total mass flux of solids is the sum of the mass flux resulting
from hindered settling due to gravity and the mass flux resulting from bulk movement
FIGURE 14.99 Settling basin at steady state (ub bulking downward velocity, m/h or
ft/hr, and A required area, m2 or sq ft) (from Metcalf & Eddy, Wastewater Engineering:
Treatment and Reuse, 4th ed. Copyright 2003, The McGraw-Hill Companies, New York,
N.Y., with permission).
14-207
14-208
(14.35)
Where,
SFg solids flux resulting from gravity, kg/m2h (lb/h/sq ft),
Xi solids concentration at point in question, g/m3 (lb/cu ft), and
Vi settling velocity of solids at concentration X, m/h (ft/hr).
The solids flux resulting from underflow is:
SFu XiUb
(14.36)
Ub Qu/A
(14.37)
SFu XiQu/A
(14.38)
And,
Yielding,
Where,
SFu
Ub
Qu
A
The total solids flux, SFt, in kg/m2h (lb/h/sq ft), is the sum of these two components:
SFt XiVi XiUb
(14.39)
The total solids flux represents the maximum rate that solids can be continually applied
to a clarifier for a given underflow rate, MLSS concentration, and characteristic settling
velocity at concentration Xi. The characteristic settling velocity is, in turn, a function of
the settleability of solids.
FIGURE 14.100 Effect of filamentous organisms on activated sludge structure: (a) ideal,
nonbulking floc, (b) pinpoint floc, and (c) filamentous, bulking (Ekama et al., 1997;
reprinted with permission from the copyright holders, IWA).
14-209
14-210
FIGURE 14.101
14-211
14-212
14-213
14-214
FIGURE 14.103 Chlorine dosing points for bulking control (Jenkins et al., 2003;
reprinted with permission from IWA Publishing).
reported that, following chlorine inhibition, nitrification recovered faster than EBPR
after chlorine addition was stopped.
To improve flocculation, addition of cationic polymers at concentrations of less
than 1 mg/L has been shown to improve mixed-liquor settleability. In rare instances,
alum also has been used. The selection of inorganic salts, polymers, or other flocculent
aids should be based on laboratory studies, including jar tests.
9.2.4.7 Energy Gradient Optimization
Energy gradient optimization is important to grow MLSS floc or protect it in transit
from the aeration tank to the settling zone of the clarifier. As mixed liquor leaves the
aeration basin, the floc may be well formed if gentle mixing, such as that achieved with
fine-bubble aeration, is used in the reactor. Use of jets, high- or low-speed mechanical
aeration, or submerged turbines can tear up floc. Reformation should be achieved
before mixed liquor enters the quiescent zone of the clarifiers for settling. This may be
achieved by adequate detention time in aerated mixed liquor conveyance channels.
If flow splitting over weirs is used, then fall height requires attention. Falls of as
much as one meter have not destroyed some mixed liquors, but the nature of the floc
may affect the result.
Within the clarifier, inlets must dissipate influent mixed-liquor energy, distribute
flow evenly, reduce density short circuiting and current effects, minimize blanket disturbances, and promote flocculation. Das et al. (1993) demonstrated that velocities in
excess of 0.6 m/s (2 ft/sec) would cause deflocculation. The incoming energy can be
used to promote flocculation, as discussed later.
Flow
average
Peak
a
b
Rectangular clarifiers
Range
Average
Range
Average
168119
(400700)
1.702.72
(1 00016 000)
0.95
???
2.09
(12.30)b
???1.19
(400 7000)
170272
(1 00016 000)
0.???
???
210
(12.30)
14-215
14-216
Hydraulic condition
0.091 CWZ
0.182 CWZ2
potential improvements in the design of inlet and outlet structures, depth, sludge collectors, and sludge removal that have been shown to increase allowable rates. It is projected that fully optimized clarifier designs will have 15 to 20% higher hydraulic capacity than pre-1970 clarifier designs having the same side water depth (WEF, 1998).
A correlation between effluent suspended solids and SOR developed for several
plants, indicates that an effluent TSS of less than 20 mg/L can be achieved at SORs ranging from 1.0 to 2.0 m/h (Figure 14.104). Such correlations can be misleading because
they do not account for the effects of temperature, peaking factors, SVIs, geometrical
details, RAS flowrate, and RAS concentration. Because the literature is limited, designs
for specific sites should be conservative or based on experimental testing (Tekippe and
Bender, 1987). Unbalanced load testing (loading multiple clarifiers at different rates to
evaluate performance) at existing plants undergoing expansion is encouraged. If such
testing is not feasible, column settling investigations can be undertaken to help establish design criteria.
14-217
2.0
1.5
Fail
Safe
XF 3.5 g/l
D
1.0
XF 4.5 g/l
Fail
Safe
14-218
B
Criterion I boundary
0.5
C
Safe conditions region
0
0.5
1.0
1.5
2.0
FIGURE 14.105 Design and operating chart for secondary settling tanks (SSTs) based on
the flux procedure and the semilog expression linking the stirred zone settling velocity
(SZSV) and solids concentration for sludge with Vo 5.93 m/h and n 0.43 m3/kg.
The solids capacity Criteria I and II boundaries are shown for selected feed concentrations (XF 2.5, 3.5, and 4.5 g/L). For a feed concentration of 3.5 g/L, if the overflow rate
(horizontal) and recycle ratio (vertical) lines intersect inside, on, or outside the Criterion
I and II bounded area, then operating conditions are safe, critical, or overloaded, respectively. The underflow rate of qR is the product of the recycle ratio (R) and overflow rate
(qA) operative at any particular point in the chart; constant qB is represented by hyperbolae in the chart, which is the dotted line (Ekama et al., 1997; reprinted with permission from IWA Publishing).
RAS flow rates into the model. It can be used to assess different design and operating
conditions.
Figure 14.106 illustrates the components of the state point analysis. By definition,
the state point is the point of intersection of the clarifier overflow rate (OFR) and underflow rate (UFR). As summarized in Table 14.39, the position of the state point and the
FIGURE 14.106
TABLE 14.39
Location of
state point
Location of
underflow line
Condition
of clarifier
Potential
corrective action
Underloaded
None
Critically loaded
Overloaded
Critically loaded
Overloaded
Overloaded
14-219
14-220
FIGURE 14.107
FIGURE 14.108
Overloaded clarifier.
FIGURE 14.109
FIGURE 14.110
Overloaded clarifier.
14-221
14-222
FIGURE 14.111
Overloaded clarifier.
FIGURE 14.112
14-223
14-224
FIGURE 14.113
sents the required SOR, provided that it is adjusted, where appropriate, for temperature,
volatile solids content, and chemical addition. The relationships of this approach are:
Rmin SSV/(103 SSV)
(14.40)
(14.41)
Where,
Rmin minimum RAS rate (%),
ISV initial settling velocity (m/h),
SSV 30-minute settled volume (mL/L), and
V0 sludge settling characteristic velocity (m/h).
(14.42)
(14.43)
A CSF value of less than 1.0 indicates clarifier overload. If CSF and RSF are both greater
than 1.0, then the clarifier is underloaded. If CSF is more than 1.0 and RSF is less than
1.0, then the clarifier is most likely overloaded and the operating condition should be
confirmed using other methods, such as the Daigger approach.
FIGURE 14.114
14-225
2.5
2.0
1.5
Fail
Safe
XF 3.5 g/l
D
1.0
XF 4.5 g/l
Fail
Safe
14-226
B
Criterion I boundary
0.5
C
Safe conditions region
0
0.5
1.0
1.5
2.0
FIGURE 14.115 Design and operating chart. Graphs based on suspension with Vo
5.93 m/h and n 0.43 m3/kg (Ekama et al., 1984).
9.3.5 Redundancy
All activated sludge clarifiers should be able to be taken out of service for periodic
maintenance and repair. Not all tank designs are equivalent in this regard. Rectangular
tanks with one or multiple sets of chain-and-flight mechanisms are considered more
problematic and require more frequent servicing. Circular designs, in contrast, have
drives that are accessible from the surface and may include options in which the collector blades and support members can be winched to the surface.
14-227
14-228
14-229
14-230
9.3.8 Shapes
The current consensus of design engineers is that there are no significant shape advantages between circular and rectangular clarifiers if all of the design details are well done
and in accordance with modern guidelines such as those of the Water Environment
Federation MOP FD-8 (2005a).
Design engineers consider two basic shapes viable: longitudinal and crossflow. By
far, the most common is the longitudinal design (WEF, 2005).
Most design engineers and operators prefer circular clarifiers for activated sludge
and specialty suspended-growth systems treating municipal wastewater. The reliability of the mechanisms for circular tanks typically is cited as the primary reason. Extensive details and text on these designs are given in a following section of this chapter
and in Water Environment Federation MOP FD-8 (2005a).
Except for a few square designs, square, hexagon, and octagon shapes are designed
with center or peripheral feed to establish an internal radial flow pattern. Some square
tanks may be loaded on one side and effluent taken off on the opposite side, but these
are rare.
For square designs with radial flow, sweeping sludge from the corner area is a
problem. Corner sweep mechanisms exist, but many of them have had mechanical
problems and have fallen into disfavor. In recent years, changes to eliminate corner
sweeping have become common. Fillets in the corners to enable simple circular sweeps
have been used in some and new, circular inner vertical walls have been used in others.
Hexagonal and octagonal tanks typically have adequate corner filleting to accommodate simple circular mechanisms.
All designs in this radial flow, noncircular category have an issue with launder
shape. If they are made circular, then corner areas that are difficult to skim are created.
If the weirs are placed along the straight walls, then the flow patterns are distorted and
automated brushing for algae control is not possible. In view of all these considerations,
tanks in this category have become highly unpopular.
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14-232
FIGURE 14.116 Rectangular clarifier design features and nomenclature (hopper locations may vary)
(Ekama et al., 1997; reprinted with permission from IWA Publishing).
liquid stream reverses itself, it is referred to as a folded flow pattern. Rectangular clarifiers placed on top of each other are referred to as stacked clarifiers; one arrangement
incorporates a folded flow pattern in a vertical arrangement.
Longitudinal flow is a pattern in which the influent flow proceeds in a direction
parallel to the longitudinal of the tank. The flow pattern closely resembles plug flow in
theory, althoughsedimentation is taking place along the vertical axis. Dye studies have
shown that the rectangular design does not achieve ideal plug flow because of some
short circuiting.
In the transverse flow design, the influent flow enters from a channel along the
long side of a rectangular tank. Effluent weirs are placed on the opposite long side of the
tank to give a conventional crossflow pattern (Figure 14.117). If the effluent weirs are
located along the influent side of the tank, then this becomes a folded flow pattern. In
transverse clarifier designs, sludge withdrawal is accomplished by a traveling suction
mechanism, making the provision of sludge hoppers unnecessary. Or, hoppers can be
placed approximately 10 m (33 ft) apart along the short width of the tank where an
embedded collection header with orifices can be placed.
Stacked clarifiers consist of settling tanks, located one above the other, operating in
parallel, often with a common water surface. In this sense, they become modular units.
Stacking increases the clarifier surface area without increasing facility footprint. They
are also called tray clarifiers and can be double-decked or even triple-decked. Most
stacked clarifier designs are similar to conventional rectangular clarifiers in terms of
influent and effluent flow patterns and solids collection and removal. Stacked clarifiers
are covered in more detail in Chapter 12 and later in this section.
FIGURE 14.117
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14-234
9.4.2 Dimensions
Once the area and number of tanks needed for redundancy and normal size constraints have been established, specific tank geometric details can be defined. There
are acceptable minimum ratios of length-to-width that effectively limit the maximum
size of rectangular tanks. The length-to-width ratios of longitudinal rectangular clarifiers may range from 1.51 to 151. A minimum length-to-width ratio of 31 was recommended to prevent short circuiting, but it is typically greater than 51 (U.S. EPA,
1974a). Some references recommend that the length of the rectangular clarifier should
not exceed 10 to 15 times the depth (Metcalf and Eddy, 2003). However, this lengthto-depth ratio has been exceeded with success at larger plants. The length, width, and
depth dimensions should be proportioned so that horizontal flow velocities are not
excessive.
9.4.2.1 Length
Rectangular clarifiers are seldom greater than about 100 m (300 ft) in length and are
typically 30 to 60 m (100 to 200 ft) long. In small clarifiers, such as those used in package plants, a minimum flow length of 3 m (10 ft) from inlet to outlet should be used to
prevent short circuiting (U.S. EPA, 1974a). There is concern for possible suspended
solids carryover with the increased hydraulic flow at the weir as the clarifier length is
shortened. The ultimate length of a tank is limited by stress on the collection mechanism
and need to transport sludge the entire length of the tank. For long tanks and for tanks
with midtank hoppers, multiple collector systems can be used.
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14-236
14-237
A
Return sludge
Distribution
flume
Feed line
A
Plain view
FIGURE 14.118
D = 550
D = 550
L = 1.5D
L = 1.5D
Note: two basins supplied
from same feed line
Sludge
pocket
0
5m
Section A-A
Inlet design of Larsen (1977) to avoid floc breakup (note that D is in millimeters).
FIGURE 14.119 Secondary clarifier inlet used by the Los Angeles County Sanitation Districts (1 in.
52.54 cm; 1 ft 0.304 8 m).
14-238
FIGURE 14.120 Distribution channel with funnel-shaped floor (Krauth, 1993) with a Stuttgart inlet
(Popel and Weidner, 1963).
of the head of the tank produced the best results. Data by Stahl and Chen (1996) show
that excellent effluent quality is obtained at several shallow concurrent flow clarifiers
equipped with only the impingement inducing diffusers (Figure 14.119). These findings were published before the modern testing protocols outlined in the WERF report
(2001); therefore, the degree of floc formation in each case was not quantified. Stahl and
Chen reported on fine-bubble aeration plants with low-velocity aerated channel transport of mixed liquor to the clarifiers. It is probably, therefore, that the floc was well
FIGURE 14.121 Aerated distribution channel (Krauth, 1993) with two staggered slotted baffles to dissipate inlet energy.
14-239
FIGURE 14.122 Aerated distribution channel with horizontal slab deflecting inlet flow
energy from a sludge hopper at the inlet end (Krebs et al., 1995).
formed. This suggests that if the floc entering the tank is well formed, then impingement diffusers may give excellent results. If, however, the floc are not well formed, then
a separate baffled area, such as recommended by Krebs et al. (1995) and Barnard et al.
(2007) (Figure 14.125), would be cost-effective.
For concurrent-flow tanks, density current problems can be minimized by positioning the inlet lower in the tank without placing it in the thickening zone, which is
typically reserved for the bottom 1 m (3 ft) of the tank. Locating the inlet too low may
scour the solids on the bottom and lead to resuspension. Inlet apertures should be positioned from approximately 2 m (6.5 ft) depth to midtank depth. Krebs et al. (1995) provide a method to calculate an inlet height.
FIGURE 14.123 Flocculator inlet zone with paddles. Sludge is withdrawn near the inlet and one-third
down the length of the tank (Kalbskopf and Herter, 1984).
14-240
FIGURE 14.124 Improvement of effluent transparency with flocculation zone (Kalbskopf and Herter, 1984).
Overflow Elevation
Established based
on Maintaining
Acceptable Headloss
2
2
Baffle
Type
Scale 1 10
FIGURE 14.125
14-241
14-242
FIGURE 14.126
14-243
FIGURE 14.127 Stacked rectangular clarifier; parallel-flow type showing double-sided weirs at same
water surface elevation.
14-244
FIGURE 14.128
end wall equal to the tank depth (ATV, 1991). Alternatively, deflection baffles can be
installed below the weirs to deflect the upwelling caused by the density current.
Heavy cross winds on open tanks can easily cause sloshing and surging of water
over the weirs. To counteract this, fiberglass launders can either be substantially braced
or covered or the weir area can be provided with more freeboard to shelter it. Concrete
launders with fiberglass weir plates also can be used. Bridge-type mechanisms can pass
between the launders and then be supported from the floor.
Adjustable weir plates should be used with launders so that they can be accurately
leveled with the outlet weir of other clarifiers in parallel (Institute of Water Pollution
14-245
14-246
FIGURE 14.129
14-247
14-248
FIGURE 14.130 (a) Gould tank type I with sludge hopper at outlet end and (b) Gould tank type II with
sludge hopper at midpoint (Ekama et al., 1997; reprinted with permission from IWA Publishing).
rectangular tank may have two or more withdrawal hoppers, each equipped with a
withdrawal pipe. Separate controls for each hopper are absolutely necessary.
The effluent end hopper design conceptually provides a more ideal solution for
minimizing the breakup of the biological flocs because the sludge transport now takes
place in the same direction as the bottom density current. The sludge is kept out of the
relatively turbulent region of the inlet. Furthermore, the longer sludge detention time,
resulting from the effluent end hopper arrangement, can enhance the flocculation and
the dynamic filtration effects on the flocculent particles. Wahlberg et al. (1993) showed
that rectangular tanks with effluent end sludge collection can perform exceptionally
well up to SORs of 3.4 m/h (2 000 gpd/sq ft).
Effluent end hoppers result in a large amount of solids transported into the effluent region, which increases the potential of solids washout. In addition, bulk horizontal flow through the tank consists of the both the effluent and RAS; increasing RAS rates
to remove additional sludge can be self-defeating.
In rectangular tanks exceeding 40 m (130 ft) in length, the sludge hopper can be situated one-half to two-thirds of the way towards the end wall. This is referred to as a
Gould Tank-Type II. Two chain-and-flight mechanisms move sludge in the direction
of flow in the first half of the tank and against the direction of flow in the second half
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14-250
FIGURE 14.131
internal velocities is important to prevent them from becoming excessive and scour
solids from the sludge blanket, degrading effluent quality.
9.5.2 Diameter
Clarifier diameter is a function of total area required and number of units. Mechanisms
are available more than 70 m (200 ft) in diameter although the upper limit is considered
to be 50 m (150 ft). For larger diameter clarifiers, wind can create surface currents that
upset the radial flow pattern and concentrate scum downwind.
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14-252
TABLE 14.40
clarifiers.
Minimum
Suggested
3 (10)
3.3 (11)
3.7 (12)
4 (13)
4.3 (14)
3.7 (12)
3.7 (12)
4 (13)
4.3 (14)
4.6 (15)
* Note: ft ???.
FIGURE 14.132 Performance response curves for conventional and flocculator clarifiers (gpd/sq ft 0.001 698 4 m3/m2h) (Tekippe and Bender, 1987; Parker and Stenquist, 1986).
14-253
14-254
FIGURE 14.133 Effect of clarifier depth and flocculator center well on effluent suspended solids (gpd/sq ft 0.001 698 4 m3/m2h) (Parker, 1983).
although some designs may leave the top several centimeters of the ports exposed.
Instead of ports, another popular feed-pipe opening is to connect two segments of pipe
with four vertical structural steel channels welded to each pipe exterior.
For peripheral feed tanks, some designs have a raceway with multiple ports at its
bottom. Others have an open raceway in which tangential dispersion of influent is
achieved by introducing a directional spiral feed pattern. For those inlets with multiple
ports, the port spacing and size is performed by equipment manufacturers that have
computerized hydraulic models for this purpose. Most design engineers specify, for a
given range, that relative flows leaving different ports do not vary by more than 5% (or
such value) from the total flow divided by the number of ports.
FIGURE 14.134 Various conventional center-feed inlet designs: (a) side feed, (b) vertical pipe feed, and (c) slotted, vertical pipe feed.
14-255
14-256
FIGURE 14.135
FIGURE 14.136
14-257
14-258
FIGURE 14.137
liquor flow.
For activated sludge clarifiers, the bottom elevation of the center feedwell has a
significant effect on performance. The relative level of the sludge blanket surface must
then be considered in both design and operation of the clarifier. Sorenson (1979) examined the strategy of maintaining a deep sludge blanket within the clarifier. His data
indicated that maintenance of a high blanket using an automatic operator control produced better effluent quality compared to a tank with manual control. Crosby (1980)
showed that better performance could be obtained with a center feedwell bottom that
is either well above the sludge blanket or somewhat below the top of the sludge blanket. A shallow blanket separated from the well bottom is considered optimal for
sludges that settle well, but not for sludges that settle poorly. In the latter case, it may
be possible for an operator to improve performance by carrying a relatively thick blanket that provides some degree of solids filtration and settling. Operating with the bottom of the feedwell at nearly the same elevation as the top of the sludge blanket was
discouraged.
In many plant designs, mixed-liquor suspensions arriving at the clarifiers are not
fully flocculated. Performance can be improved, however, by using a separate flocculation zone. Simply increasing the size of the center feedwell is one approach. Some
have provided mechanical flocculators within this zone, whereas others have provided an energy-dissipating inlet (EDI) to distribute the flow into the flocculation
zone (Figure 14.138).
Kinnear (1998), Wahlberg et al. (1994), Parker et al. (1971), and others have studied
sizing of the flocculation centerwell. It is been shown that a detention time of approximately 20 minutes achieves well over 90% of the obtainable degree of floc formation.
Therefore, a rule of thumb has been to size the flocculation well to obtain 20 minutes of
residence time at average dry weather flow with an additional allowance of 50% for
RAS flow. A simpler approach is to set it equal to 30 to 35% of the clarifier diameter. If
the well is too large, then influent can plunge and short circuit the well.
FIGURE 14.138
Depth of projection into the clarifier by the flocculation well also is an important
design criterion. Many design engineers have arbitrarily set this at a value equal to
approximately one-half of the tank depth at the location of the baffle. With a sloped
floor, this would be a little deeper than one-half of the side water depth. In more recent
designs supported by results from computational fluid dynamic modeling, shallower
flocculation baffle penetrations have been used. Some of these are less than one-half of
the side water depth. If the baffle is too shallow, then some residual jets from the EDI
could fall below the bottom of the flocculation baffle and disturb the quiescence zone
of settling.
In some early designs, several slow-moving, pitch-blade vertical turbines were provided to obtain floc formation. Parallel operation of such systems has shown that equivalent results can be obtained with the mixers on or off. In recent years, EDIs have been
used to obtain adequate mixing within the flocculation zone, and mechanical mixers
are rarely, if ever, used.
14-259
14-260
FIGURE 14.139
14-261
14-262
FIGURE 14.141 Los Angeles, California, energy-dissipating inlet (EDI) patent drawing
and plan view.
FIGURE 14.142
14-263
14-264
FIGURE 14.143
FIGURE 14.144
into the flocculation zone without feed pipe ports. A center-drive mechanism is used
and its torque is transmitted through vertical bars into the concrete cone. Effluent TSS
in the range of 5 to 7 mg/l has been observed at overflow rates of 2.0 to 2.2 m/hr (1 200 to
1 300 gpd/sq ft).
To prevent odors and unsightliness (Figure 14.146), it is important to move floatables out of the flocculation zone. In early years of design, the top elevation of the flocculation baffle was set to project above the water surface at all flowrates. This design
resulted in confinement of foam and other floatables even though scum ports were provided. At other sites, the top elevation was lowered to equal that of the bottom of the
FIGURE 14.145
Side outlet low energy (SOLE) stilling well (Barnard et al., 2007).
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14-266
FIGURE 14.146
v-notch effluent weirs. This allowed floatables to pass over the top of the flocculation
baffle, but directed most of the flow downward on the inside. At high flows, however,
supernatant would flow into the flocculation zone over the baffle. This, of course,
would dilute the contents of the flocculation zone and shorten detention time of the
incoming flow.
To avoid this problem, some facilities have designed the flocculation baffle to be
adjustable upward. This allows an operator to raise its level so that it projects above
the water surface but, at high flows, can be topped to flush the floatables out into the
tank proper. In some designs, it was most cost-effective to mount the flocculation baffle in a rigid position and bolt an adjustable plate at the top. Careful adjustment of this
plate would allow the flocculation baffle to overflow only at the desirable peak flow
periods. Some designers also are altering spray nozzle design to move the scum
through the ports more effectively or providing a scum removal mechanism inside of
the flocculation baffle if it is set high enough to prevent overtopping.
Several center-feed clarifiers are designed to release flow into a zone near the bottom of a tank. In some designs, a baffle with vertical slots has been used. In others, rotating arms with several portal openings have been used to distribute the incoming flow
just above the sludge zone. These designs, however, have been rarely used in the
United States and are not discussed further.
FIGURE 14.147
14-267
14-268
FIGURE 14.148
Several model and full-scale dye tests have been conducted on peripheral feed clarifiers (Dague, 1960). Results have indicated that peripheral feed tanks have a higher
hydraulic efficiency than center-feed models. Specifically, full-scale, activated sludge
tests conducted at Sioux Falls, South Dakota, showed that in addition to better
hydraulic efficiency, peripheral feed tanks also achieved higher suspended solids
removal than existing-center feed design. The latter, however, did not employ the flocculation centerwell concept developed in more recent years.
In some designs, a headloss across the orifices of approximately 25 mm (1 in.) at
average flow was used to obtain reasonably uniform distribution of flow around the
perimeter of the tank. For plants with large peaking factors, some maldistribution of
flow and solids occurred. Design criteria were changed to provide more headloss
(approximately 60 mm, or 2.5 in.) for better distribution at average flow. Peaks of more
than 3-to-1 accommodated the higher loss. At low flows, headlosses across the orifices
can be low and do not achieve good distribution. Under these conditions, however,
overflow rates are low and clarifier performance may still be satisfactory. Minimum
flow distribution, therefore, typically is not considered a limiting design criterion. For
plants with extreme peaking factors, a special overflow provision in the baffle wall or
tank wall can be added (Figure 14.147b).
For these inlet designs, the feed channel/zone is baffled off from the body of the
settling liquid. As such, floatables can accumulate on the inlet zone surface and generate odors and objectionable aesthetics if not removed. Provisions for this are discussed
below in the section on skimming systems.
FIGURE 14.149 Baffles provided to reduce effect of outer wall rebound and upflow
(note that a tank typically would not have more than one such baffle).
14-269
14-270
(e)
(f)
FIGURE 14.150 Alternative peripheral baffle arrangements: (a) Stamford, (b) unnamed,
(c) McKinney (Lincoln), (d) interior trough, (e) cantilevered, and (f) cantilever with
deflectors.
weir. Water Environment Federation (1998) presented a formula by Albertson (1995)
that gave minimum dimensions for the shelf bottom The author has since changed the
equations to the following:
Minimum shelf bottom, mm 460 mm (25 mm/m)(diameter 9 m)
[Minimum shelf bottom, mm 18 in (0.3 in/ft)(diameter 30 ft)]
The concept is that if the trough bottom was sufficiently wide, no inward projecting
shelf (horizontal baffle) is needed. Eliminating the shelf would simplify the formwork
in construction and eliminate the objectionable settlement of solids on the shelf. Some
14-271
14-272
FIGURE 14.151
and thereby obtain full radius skimming. For shorter scum troughs, a system is provided to move the floatables toward the outer scum baffle. A fixed, flexible antirotation
baffle, supported from the bridge and extended down to the surface of the tank, is used.
The baffle is placed at an angle to the skimmer arm that intersects the tank water surface. The resulting scissors-like movement pushes the scum outward.
Another method of moving floatables out toward the scum baffle is using of water
surface sprays. It is a good idea to locate the fixed scum beach on the downwind side of
FIGURE 14.152 Alternative skimming designs for circular clarifiers: (a) revolving skimmers and fixed scum trough and (b) rotary ducking skimmers (Ekama et al., 1997;
reprinted with permission from IWA Publishing).
a tank. Yard piping arrangements may or may not make this option economically
attractive.
Another skimming concept, known as the ducking skimmer, is shown in Figure
14.152b. In this design, a skimmer board is connected to the sludge removal mechanism
through a hinged, counter-weighted assembly. It pushes the floatables toward a fixed,
rotating trough that turns into position as the skimmer board approaches and trips a
trigger switch. When the board reaches the rotating trough, it ducks under the trough,
and its counterweights return it to the surface to continue rotation around the tank. This
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14-274
9.5.7 Outlets
Outlets for most circular center-feed clarifiers consist of a single perimeter v-notch weir
that overflows into an effluent trough. Alternatives to this include cantilevered or suspended double weir troughs and submerged-orifice collector tubes.
For peripheral-feed designs, a singular perimeter weir is used in one concept.
Another includes provisions of a square, octagonal, or circular double-sided launder
suspended from the bridge or other structural support near the center of the tank.
In many states, regulations allow the weir loading that results from simply building
a perimeter weir. In others, regulations include a weir loading limit expressed in
flowrate divided by length of weir. For example, the Ten States Standards limit weir
FIGURE 14.153 Plan and elevation of effective variable width influent channel skimming design for peripheral feed clarifiers.
loading to 250 m3/m2d (20 000 gpd/ft) for plants with average flows less than 0.04 m3/s
(1 mgd) and to 375 m3/m2d (30 000 gpd/ft) for larger plants (GLUMRB, 2004).
9.5.7.1 Peripheral Weir
There are two common designs for peripheral weir outlets for circular tanks. In the first,
a concrete trough is constructed on the inside of the tank wall. The weir plate is then
14-275
14-276
14-277
14-278
FIGURE 14.155 Effect of sludge blanket depth on effluent suspended solids (ESS) at pure
oxygen activated sludge plant; sludge volume index 51 to 166 mL/g, with an average
of 86 mL/g (Ekama et al., 1997; reprinted with permission from IWA Publishing).
14-279
14-280
FIGURE 14.156
FIGURE 14.156
(continued).
14-281
14-282
FIGURE 14.157
(detail A) shows a design with the seals located several inches above the floor to reduce
the problem of grit abrasion.
9.5.8.3 Hoppers
Traditionally, most U.S. activated sludge clarifiers using scraper mechanisms were
equipped with trapezoidal hoppers (Figure 14.158a). Depending on tank size, these
hoppers are typically a few meters deep and have walls with slopes of at least 50 above
horizontal. Other types of hoppers have been developed to prevent ratholing and
dilution of the RAS. One type consists of deep conical or annular sludge hoppers as
shown in Figure 14.158b. The rotating mechanism has stirrups that reach into the annular hopper to prevent bridging.
Another design concept was to make the sludge hopper and longer and narrower
and extend radially outward a distance of up to 25% of the tank radius. A plate with
FIGURE 14.158 Circular clarifier with (a) trapezoid and (b) annular sludge hopper alternatives.
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14-284
FIGURE 14.159 The (a) sludge ring and (b) sludge drum to remove solids from activated sludge final clarifiers.
14-285
14-286
Online measurement of effluent suspended solids or turbidity can be provided for individual or multiple clarifiers for real-time monitoring of performance
Strategies and equipment used to measure and make adjustments, where possible,
to these variables are covered below. In some cases, management of certain variables
merely consists of monitoring and rarely making adjustments unless warnings are given.
14-287
14-288
TABLE 14.41
equipment.
Typical applications
Accuracy
Notes
0.5% of full
instrument span
0.5% of full
instrument span
0.5% to 1% of full
instrument span
Nuclear analyzers
Sludge with solids concentrations
greater than 4% and lower than
15% solids.
14-289
14-290
14-291
14-292
14-293
14-294
37 850 m3/d
45 420 m3/d
75 700 m3/d
140 mg/L
5 299 kg/d
6 124 kg/d
90 mg/L
3 405 kg/d
3 946 kg/d
30 mg/L
1 135 kg/d
1 361 kg/d
7 mg/L
265 kg/d
318 kg/d
Analysis of historic data indicates the following conditions are applicable to the
system:
Influent BOD has a BODultBOD5 ratio of 1.46.
Influent TSS is 80% volatile solids.
Influent VSS is 40% nonbiodegradable under the SRT conditions anticipated.
Design SVI is 150 mL/g.
Process temperatures are 15C average, 20C maximum week, and 12C minimum week. Historic data indicates maximum month conditions can occur in
either the warm or cold season.
For the diffused aeration system under consideration at appropriate diffuser
submergence conditions, refer to Table 14.42.
14-295
14-296
Diffuser density,
diffuser/m2 (diffusers/100 ft2)
SOTE, %
0.850 (0.5)
1.94 (18)
2.58 (24)
3.23 (30)
4.84 (45)
29
32
34
38
1.699 (1.0)
1.94 (18)
2.58 (24)
3.23 (30)
4.84 (45)
27
28
30
32
2.55 (1.5)
1.94 (18)
2.58 (24)
3.23 (30)
4.84 (45)
1.94 (18)
26
27
28
30
26
* Based on US Standard Conditions of temperature of 23C (68F) and absolute pressure of 101 kPa (14.7 psia)
with a resulting air density of 1.205 kg/m3 (0.075 lb/cf).
Over the aeration basin, F, values of 0.3, 0.4, and 0.7 are anticipated at the first,
middle, and final aeration zones, respectively. In addition, 45% of the total oxygen demand is exerted in the first zone, 35% in the second, and 20% in the final.
A
value of 0.98, pressure of 100 kPa (1 atm), and a C*20 of 10.5 mg/L are appropriate for the wastewater and site.
In the base case, the facility has the following effluent requirements, which are not anticipated to change over the planning period:
Maximum monthly BOD5
Maximum weekly BOD5
20 mg/L
30 mg/L
20 mg/L
30 mg/L
3 mg/L
5 mg/L
The goal of the analysis of the base case is to provide initial estimates for aeration basin
volume, aeration system capacity, and secondary clarifier size for the new suspendedgrowth biological treatment system.
1 bh SRT
1 (0.11)(10)
20
SRT ( h bh ) 1
10 (3.5 0.11) 1
14-297
h
KS
Yaut
baut
fd
ibm,ThOD
ibm,N
ibm,P
iX???,ThOD
iX???,N
iX???,P
ibm,FSS
iX???,FSS
KO
Yh
bh
aut
KN
Description
Symbol
gVSS/gNH4-N
1/d
gVSS/gVSS
g ThOD/g VSS
gN/gVSS
gP/gVSS
gThOD/gVSS
gN/gVSS
gP/gVSS
gFSS/gVSS
gFSS/gVSS
mgO2L
gVSS/gBODult
1/d
gVSS/gVSS d
mgN/L
gVSS/gVSS d
mgBODult/L
Unit
0.15
0.10
0.15
1.42
0.12
0.024
1.42
0.12
0.024
0.176
0.176
0.50
0.40
0.15
0.75
1.0
6.0
20
Value at 20C
0.15
0.06
0.15
1.42
0.12
0.024
1.42
0.12
0.024
0.176
0.176
0.50
0.40
0.11
0.44
0.66
3.5
20
Value at 12C
14-298
TABLE 14.43
1 (0.06)(10)
1 baut SRT
(0.66)
2
SO 2
10 0.44
0.006 1
SRT aut
baut 1
0.5 2
K S
O2
Px , Xha
Yh (Mass BOD ult in Mass BOD ultout ) 0.4(6 124 1.46 59)
1 bh SRT
1 (0.11)(10)
Px , Xh , i
Px , Xh , i
14-299
14-300
Px , Xhni
Px , Xhni
The fixed solids created through and associated with nitrifier activity is:
PX,Xn,FSS ibm,FSS Px,Xna ii,FSS Px,Xn,i
PX,Xn,FSS (0.176 103) (0.176 9)
PX,Xn,FSS 19 kg FSS/d
VMLSS
Px
This volume corresponds to an HRT of 11.4 hours based on average influent flow. A
review of typical activated sludge design parameters listed in Table 14.3 suggest this
value is somewhat greater than that provided at typical CAS systems.
At this point, it may worthwhile to investigate the potential basin volume reduction possible with MBR technology. If the design MLSS concentration is 8 000 mg/L
MLSS in the above sizing calculation, then rather than 2 500 mg/L, the basin volume is
5 628 m3 and HRT is based on average influent flow of 3.6 hours.
14-301
14-302
14-303
14-304
SOTR
4 896 kg O 2 /d
20 400 kg O 2 /d;
0.24
Middle zone,
SOTR
3 809 kg O 2 /d
11 903 kg O 2 /d; and
0.32
Final zone,
SOTR
2 176 kg O 2 /d
3 886 kg O 2 /d;
0.56
For this condition, diffuser flux equals 1.699 standard m3/h per diffuser. A diffuser density of 4.84 diffusers/m2 is selected for the first zone (SOTE of 32%); 3.23 diffuser/m2 for
the middle zone (SOTE of 30%); and 1.94 diffuser/m2 for the final zone (SOTE of 27%).
The required airflow to each zone is then calculated as follows.
First zone,
9 584 m3/h (standard conditions)
1 kg air
1 1
1
qs (20 400 kg O 2 /d)
0.23
kg
O
1
.
205
4
kg
/
m
24 0.27
2
2 164 m3/h (standard conditions)
The number of diffusers can then be calculated as follows.
First zone,
Diffusers
9 584 m 3 /h
5 641 diffusers
1.699 m 3 /h/diffuser
Diffusers
5 965 m 3 /h
3 511 diffusers
1.699 m 3 /h/diffuser
Diffusers
2 164 m 3 /h
1 274 diffusers
1.699 m 3 /h/diffuser
Middle zone,
Final zone,
At a liquid depth of 6.0 m, the floor area of each zone is 1 000 m2.
The chosen diffuser density can then be checked as follows.
First zone,
5 641
5.64 diffusers/m 2
1 000
Middle zone,
3 511
3.51 diffusers/m 2
1 000
Final zone,
1 274
1.24 diffusers/m 2
1 000
14-305
14-306
1 000 L
1 m 3 1.3 L/m 2 s
Middle zone,
(3 511 diffusers) (0.85 m 2 /h/diffusers)
(1 000 m 2 ) (3 600 s/h)
1 000 L
1 m 3 0.82 L/m 2 s
1 000 L
1 m 3 0.33 L/m 2 s
The first and middle zones indicate that mixing should not be a controlling concern. In
the final zone, mixing requirements may play a role in the minimum aeration rate.
14-307
14-308
14-309
14-310
722 kg N/dremoved
6 124 kg BOD 5/d
0.03
0.029 1.06(1220)
3
3
Vanoxic 1.925 kg VSS/m
Vanoxic 1.925 kg VSS/m
Vanoxic
This volume equals an HRT of 11.0 hours based on average influent flow and reflects the
low denitrification rate associated use of slowly biodegradable substrate and biomass
decay reported as the basis of the equation (Grady et al., 1999). This is a large volume that,
if implemented as an unaerated zone before the aerated zone of the base case, would
affect kinetic and mass balance calculations results for the base case. While this calculation
illustrates the possible significance of a new total nitrogen limit, it should be used as an
indicator of the gravity of the situation and not as the final design or planning value.
Designers also can use the heterotrophic growth rate expression to estimate
potential maximum rate of denitrification at an optimum point in the preanoxic zone.
Previous calculations generated 922 mgVSS/L of active heterotrophic biomass (i.e.,
2 500 mg/L 1 662 kgVSS/d active biomass/4 505 kgTSS/d total 922 mgVSS/L of
active heterotrophic biomass). A version of Equation 14.18 appropriate to the parameter unit basis can be used to estimate the optimal point rate of nitrate use by the het-
ryNO , 12 oC
Yh ibm, ThOD 1
Ko , h
Sb
SNO3 -N
h
X ha
2.86 Yh
K s Sb K NO3 -N SNO3 -N K o , h So
0.4 1.42 1
0.5 3.5 (1) (1) (1) (922 mg/L) 605 mg NO 3 N/Ld
2.86 0.4
The negative result indicates nitrate is being used because concentration is decreasing.
This value represents a potential maximum value that might be achieved. The comparable value nitrate use rate from the Refling-Stensel equation computed above is 45
mg NO3-N/Ld. This exercise illustrates the potential for process configuration optimization that can be developed with use of more sophisticated modeling tools.
A final, simple calculation that can be used to investigate the implications of preanoxic denitrification is the possible effect on oxygen requirement and aeration system. As
noted previously, when the nitrogen (III) oxidation state is taken as the reference, nitrate
has a 4.57 mg ThOD/mg N equivalency. In denitrification, neglecting any minor assimilative nitrate use, dinitrogen is produced in kind with nitrate consumption and dinitrogen has a 1.71 mg ThOD/mg N equivalency. Thus the net theoretical oxygen demand
change with nitrate consumption in the denitrification process is 2.86 mg ThOD/mg N.
The 722 kg N/d of nitrate removal considered in these calculations to achieve a 10 mg
N/L total effluent nitrogen is equivalent to 2 065 kg ThOD/d. In the base case without
denitrification, it was determined the aeration system would have to provide 10 822 kg
O2/d for design situation considered. If pre anoxic denitrification were implemented it
might reduce the oxygen requirement and aeration system usage by approximately 20%.
As noted above, complex models are required for a thorough analysis of nutrient
removal systems. The following paragraphs illustrate the principals of modeling. For
this example, the ASM 1 model will be used (Henze et al., 2000). The ASM models differ in some fundamental ways from the hand calculations described above:
(1) It is a death/regeneration model. This means the decay rates and fraction of particulate decay products used are lower than the conventional Monod approach.
(2) It is used for single, completely stirred tank reactors (CSTRs). Thus, for long
length to width tanks, or tanks in series, multiple ASM models must be run to
characterize the performance.
14-311
14-312
6 124 kg/d
3 946 kg/d
80%
40% of the VSS
1.46
1.42 g COD/g VSS
5% of the total COD
60%
Based on these parameters, the VSS (on a mass basis) is made up of the following
fractions:
Total VSS
Biodegradable VSS
Non-biodegradable VSS
3 157 kg/d
1 894 kg/d
1 263 kg/d
1
8. Hydrolysis of
entrapped
organic nitrogen
7. Hydrolysis of
entrapped organics
1
1fp
5. Decay of
autotrophs
6. Ammonification
of soluble
organic nitrogen
1fp
4. Decay of
heterotrophs
3. Aerobic growth
of autotrophs
1
1
fp
(4.57YH)/
YH
1/YA
1
1
iXB
1/YA
iXB
1
1
iXB
fpixp
iXB
fpixp
1.
SI
mg COD/L
fp
2.
SS
mg COD/L
1
3.
XI
mg COD/L
(1YH)/
2.86YH
4.
XS
mg COD/L
1
5.
XB,H
mg COD/L
1/YH
6.
XB,A
mg COD/L
2. Anoxic growth
of heterotrophs
7.
XP
mg COD/L
1/14
13,3
13,2
XB/14
8.
SO
mg COD/L
iXB
9.
SNO
mg N/L
(1YH)/
YH
10.
SNH
mgN/L
1
11.
SND
mg N/L
1/YH
13.
SALK
12.
XND
mg N/L
1. Aerobic growth
of heterotrophs
Processes (j):
meq/L
TABLE 14.44 Activated sludge model no. 1 stoichiometry matrix (Henze et al., 2000; reprinted with permission from
IWA Publishing).
14-313
14-314
TABLE 14.45 Activated sludge model no. 1 process rate expressions (Henze et al., 2000; reprinted
with permission from IWA Publishing).
Process
Units
Rate Equation
1. Aerobic growth
of heterotrophs
mgCOD/L/d
2. Anoxic growth
of heterotrophs
mgCOD/L/d
3. Aerobic growth
of autotrophs
mgCOD/L/d
4. Decay of
heterotrophs
mgCOD/L/d
bH*XB,H
5. Decay of
autotrophs
mgCOD/L/d
bA*XB,A
6. Ammonification
of soluble
organic nitrogen
mgN/L/d
ka*SND*XB,H
7. Hydrolysis of
entrapped organics
mgCOD/L/d
8. Hydrolysis of
entrapped
organic nitrogen
mgN/L/d
BOD 5
1
BOD 5
CODT
Xi
1 YH fd
1 f si
14-315
TABLE 14.46 Activated sludge model no. 1 parameters and typical values at neutral pH (Henze et al.,
2000; reprinted with permission from IWA Publishing).
Symbol
Unit
Stoichiometric parameters
YA
YH
fP
iXB
iXP
Kinetic parameters
H
KS
KO,H
KNO
bH
g
h
kh
KX
A
KNH
KO,A
bA
ka
Day1
mg COD L1
mg O2L1
mg NO3-N L1
Day1
Dimensionless
Dimensionless
mg slowly biodegradable COD (mg cell COD*day)1
mg slowly biodegradable COD (mg cell COD)1
Day1
mg NH3-N L1
mg O2 L1
Day1
L (mgCOD*day)1
Value at 20C
Value at 10C
0.24
0.67
0.08
0.086
0.06
6.0
20.0
0.20
0.50
0.62
0.8
0.4
3.0
0.03
0.80
1.0
0.4
0.05 to 0.15
0.08
0.24
0.67
0.08
0.086
0.06
3.0
20.0
0.20
0.50
0.20
0.8
0.4
1.0
0.01
0.3
1.0
0.4
0.05 to 0.15
0.04
14-316
795 kg/d
57 kg/d
200 kg/d
38 kg/d
45 kg/d
The ASM 1 model does not explicitly handle the non-biodegradable nitrogen fractions. Soluble non-biodegradable nitrogen simply passes through the CSTR and is
added to the effluent TKN. The particulate non-biodegradable nitrogen is associated
with the particulate non-biodegradable COD and can be handled as a fraction of that
material.
The ASM 1 model does not use loads in calculations, which means that this must
be converted to concentrations. The maximum month flow of 45 420 m3/d results in
the values shown in Table 14.47.
TABLE 14.47
Component
Units
Value
Units
Value
3
XB,H
XB,A
XP
Heterotrophic organisms
Autotrophic organisms
Particulate products
kg/COD/d
kg/COD/d
kg/COD/d
0
0
0
g COD/m
g COD/m3
g COD/m3
0.0
0.0
0.0
Xi
XS
SS
Inert particulates
Particulate organics
Soluble organics
kg/COD/d
kg/COD/d
kg/COD/d
1 793
5 664
4 462
g COD/m3
g COD/m3
g COD/m3
39.5
124.7
98.2
SNH
SNO
SND
Soluble ammonia N
Soluble nitrate/nitrite N
Soluble organic N
kg N/d
kg N/d
kg N/d
795
0
200
g N/m3
g N/m3
g N/m3
XND
SO
SALK
kg N/d
kg O2/d
moles/d
57
0
220
g N/m3
g O2/m3
moles/m3
17.5
0.0
6.2
1.3
0.0
4.8
14-317
fD (1 YH )
1 fD YH
b
1 YH (1 fD )
#1
Secondary
effluent
XB,H
XB,A
XP
Heterotrophic organisms
Autotrophic organisms
Particulate products
g COD/m3
g COD/m3
g COD/m3
0.0
0.0
0.0
1 077
74
510
8.6
0.6
4.1
Xi
XS
SS
Inert particulates
Particulate organics
Soluble organics
g COD/m3
g COD/m3
g COD/m3
39.5
126.3
100.6
954
15
3.8
7.6
0.1
3.8
SNH
SNO
SND
Soluble ammonia N
Soluble nitrate/nitrite N
Soluble organic N
g N/m3
g N/m3
g N/m3
17.5
0.0
6.2
0.37
15
0.4
0.37
14.9
0.4
XND
SO
g N/m3
g O2/m3
1.3
0.0
0.9
2.0
0.0
2.0
SALK
VSS
Alkalinity
Volatile suspended solids
moles/m3
g/m3
4.8
2.6
1 850
2.6
14.8
TSS
BOD5
g/m3
g O2/m3
2 501
20.0
7.5
mg/L/hr
kg/day
23
10 367
Oxygen requirements
Oxygen uptake rate
Actual oxygen demand (AOR)
Total
10 367
14-318
#1
#2
#3
#N/A #N/A
Secondary
effluent
XB,H
XB,A
XP
Heterotrophic organisms
Autotrophic organisms
Particulate products
g COD/m
g COD/m3
g COD/m3
0.0
0.0
0.0
1 098
74
499
1 089
74.7
503
1 068
74.9
508
8.6
0.6
4.1
Xi
XS
SS
Inert particulates
Particulate organics
Soluble organics
g COD/m3
g COD/m3
g COD/m3
39.5
126.3
100.6
954
30
7.4
953.8
12.3
2.7
953.8
8.9
2.0
7.7
0.1
2.0
SNH
SNO
SND
Soluble ammonia N
Soluble nitrate/nitrite N
Soluble organic N
g N/m3
g N/m3
g N/m3
17.5
0.0
6.2
2.65
11
0.6
0.3
13.9
0.4
0.1
15.2
0.3
0.10
15.2
0.3
XND
SO
g N/m3
g O2/m3
1.3
0.0
1.3
2.0
0.9
2.0
0.8
2.0
0.0
2.0
SALK
VSS
Alkalinity
Volatile suspended solids
moles/m3
g/m3
4.8
3.2
1 868
2.9
1 853
2.8
1 839
2.8
14.8
TSS
BOD5
g/m3
g O2/m3
2 524
2 504
2 486
20.0
6.4
mg/L/hr
kg/day
40
6 009
18
2 675
12
1 790
Oxygen requirements
Oxygen uptake rate
Actual oxygen demand (AOR)
Total
10 475
14-319
system SRT must go up by the same proportion. The nitrified mixed-liquor return rate
of 132% of the influent flow remains the same; by trial-and-error, the anoxic volume
was increased until the desired 8 mg/L TN was achieved. The resultant anoxic volume
was 3000 m3 compared to 17 000 m3 calculated in the design example, and MLSS was
calculated to be approximately 2400 mg/L at a total SRT of 11.2 days. Table 14.50 shows
the results of this simulation. For comparison purposes, the three nitrate uptake rates
are shown below:
Refling-Stensel 45 mg NOX-N/L/d
Second method 605 mg NOX-N/L/d
ASM 1 model 149 mg NOX-N/L/d
Table 14.50 provides the reduced overall AOR (9 500 kg/d versus 10 500 kg/d) as a
result of the denitrification; the AOR requirement distribution has flattened out in the
three aerobic reactors to 50%, 31%, and 19% because of the soluble uptake in the
anoxic zones.
TABLE 14.50
#1
#2
#3
#4
#N/A
Secondary
effluent
XB,H
XB,A
XP
Heterotrophic organisms
Autotrophic organisms
Particulate products
g COD/m3
g COD/m3
g COD/m3
0.0
0.0
0.0
961
70
527
977
70.4
529
977
70.7
531
969
70.8
534
6.0
0.4
3.3
Xi
XS
SS
Inert particulates
Particulate organics
Soluble organics
g COD/m3
g COD/m3
g COD/m3
39.5
126.3
100.6
954
58
15.4
953.8
27.8
5.5
953.8
14.0
3.2
953.8
9.3
2.3
5.9
0.1
2.3
SNH
SNO
SND
Soluble ammonia N
Soluble nitrate/nitrite N
Soluble organic N
g N/m3
g N/m3
g N/m3
17.5
0.0
6.2
6.68
0.7
0.6
2.2
3.8
0.4
0.4
5.7
0.4
0.1
6.4
0.3
0.12
6.4
0.3
XND
SO
g N/m3
g O2/m3
1.3
0.0
2.0
0.0
1.4
2.0
1.0
2.0
0.8
2.0
0.0
2.0
SALK
VSS
Alkalinity
Volatile suspended solids
moles/m3
g/m3
4.8
5.1
1 809
4.6
1 801
4.3
1 792
4.2
1 785
4.2
11.1
TSS
BOD5
g/m3
g O2/m3
2 444
2 433
2 422
2 413
15.0
5.0
31
4 736
19
2 915
12
1 848
Oxygen requirements
Oxygen uptake rate
Actual oxygen demand (AOR)
Total
mg/L/hr
kg/day
9 500
14-320
TABLE 14.51
#1
#2
#3
#4
#N/A
Secondary
effluent
XB,H
XB,A
XP
Heterotrophic organisms
Autotrophic organisms
Particulate products
g COD/m3
g COD/m3
g COD/m3
0.0
0.0
0.0
964
69
528
976
69.3
530
976
69.7
531
970
69.8
533
6.0
0.4
3.3
Xi
XS
SS
Inert particulates
Particulate organics
Soluble organics
g COD/m3
g COD/m3
g COD/m3
39.5
126.3
100.6
954
49
12.6
953.8
25.6
5.2
953.8
14.0
3.2
953.8
9.6
2.4
5.9
0.1
2.4
SNH
SNO
SND
Soluble ammonia N
Soluble nitrate/nitrite N
Soluble organic N
g N/m3
g N/m3
g N/m3
17.5
0.0
6.2
5.48
1.0
0.6
2.0
3.6
0.4
0.4
5.2
0.4
0.1
5.8
0.4
0.13
5.8
0.4
XND
SO
g N/m3
g O2/m3
1.3
0.0
1.8
1.4
2.0
1.0
2.0
0.8
2.0
0.0
2.0
SALK
VSS
Alkalinity
Volatile suspended solids
moles/m3
g/m3
4.8
5.1
1 804
4.6
1 798
4.4
1 791
4.4
1 785
4.4
11.1
TSS
g/m3
2 438
2 429
2 420
2 412
15.0
BOD5
Oxygen requirements
Oxygen uptake rate
Actual oxygen demand (AOR)
g O2/m
5.1
Total
mg/L/hr
kg/day
30
4 558
20
2 955
13
1 912
9 424
In this particular system, the denitrification rate is limited by the available nitrate
in the anoxic zone. The nitrate level of 0.4 mg N/L in the anoxic zone is close to the half
saturation value (KNO 0.5) for nitrate. Therefore, additional denitrification could be
obtained by increasing the nitrified recycle rate (NRCY). In Table 14.51, the NRCY was
increased until the anoxic zone nitrate reached approximately 1 mg/L, resulting in an
NRCY rate of 190% of the influent flow rate. This resulted in a drop in the effluent total
nitrogen to 7.4 mg/L. The AOR also dropped to 9 400 kg/d.
11.0 REFERENCES
Abufayed, A. A.; Schroeder, E. D. (1986) Kinetics and Stoichiometry of SBR Denitrification with a Primary Sludge Carbon Source. J. Water Pollut. Control Fed., 58,
398405.
Abu-gharrah, Z. H.; Randall, C. W. (1991) The Effect of Organic Compounds on Biological Phosphorus Removal. Water Sci. Technol., 23, 585.
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