Temperature: By: S K Mondal
Temperature: By: S K Mondal
By: S K Mondal
Chapter 2
2. Temperature
Some Important Notes
Comparison of Temperature scale
100o C
Boiling Point
Test
Temperature
0o C
Q2.1
373K
Freezing Point
Relation:
212oF
32o F
80 o
2 73 K
30 cm
0o
10 cm
C0
F 32
K 273
0
x 10
=
=
=
=
100 0 212 32 373 273 80 0 30 10
The limiting value of the ratio of the pressure of gas at the steam point and at
the triple point of water when the gas is kept at constant volume is found to be
1.36605. What is the ideal gas temperature of the steam point?
(Ans. 100C)
p
= 1.36605
pt
Solution:
( v ) = 273.16
p
pt
= 273.16 1.36605
= 373.15C
Q2.2
50.0
96.4
100
193
200
387
300
582
The numbers are the gas pressures, mm Hg, each pair being taken with
the same amount of gas in the thermometer, but the successive pairs
being taken with different amounts of gas in the thermometer. Plot the
ratio of Sb.p.:H2Ob.p. against the reading at the water boiling point, and
extrapolate the plot to zero pressure at the water boiling point. This
Page 11 of 265
Temperature
By: S K Mondal
Ratio
= 1.928 1.93
Wb.p
1.926
Extrapolating
Solution :
Chapter 2
1.935 1.940
T1 = 100C = 373K
T2 = ?
50
100
200
300
p1
= 1.926
p2
Q2.3
The resistance of a platinum wire is found to be 11,000 ohms at the ice point,
15.247 ohms at the steam point, and 28.887 ohms at the sulphur point. Find the
constants A and B in the equation
R = R0 (1 + At + Bt2 )
And plot R against t in the range 0 to 660C.
Solution:
(3271, 1668628)
36.595
11
R 0 = 11.000
660C
or
... ( i )
3.654110-3 = A + 445B
equation ( ii )
( i ) gives.
B = 6 10 7
A = 3.921 10 3
}
)
R = 11 1 + 3.921 10 3 t 6 10 7 t 2
or
Y = 11 1 + 3.921 10 3 t 6 10 7 t 2
R 660 = 36.595
Page 12 of 265
Temperature
By: S K Mondal
Q2.4
Chapter 2
= at + bt2
Where a = 0.20 mV/deg, and b = - 5.0 10-4 mV/deg2
(a)
(b)
Compute the e.m.f. when t = - l00C, 200C, 400C, and 500C, and
draw graph of against t in this range.
Suppose the e.m.f. is taken as a thermometric property and that a
temperature scale t* is defined by the linear equation.
t* = a' + b'
Solution:
Q2.5
And that t* = 0 at the ice point and t* = 100 at the steam point. Find
the numerical values of a' and b' and draw a graph of against t*.
(c) Find the values of t* when t = -100C, 200C, 400C, and 500C, and
draw a graph of t* against t.
(d) Compare the Celsius scale with the t* scale.
Try please
The temperature t on a thermometric scale is defined in terms of a
property K by the relation
t = a ln K + b
Solution:
or
Q2.6
6.78
a ln
= 100
1.83
a = 76.35
b = a ln 1.83
= 46.143
t = 76.35 ln k 46.143
t* = 76.35 ln 2.42 46.143
= 21.33C
Temperature
By: S K Mondal
Chapter 2
Rt = R0 [1 + 0.00393 t]
Solution:
Q2.7
R0 =
80
= 72.84
1
+
0.00393
25]
[
93 = 72.84 {1 + 0.00393 t}
or
t = 70.425C
Solution:
150 0
N 100
=
100 0
400 100
or N = 550o N
let N= C for x o
C 0
N 100
then
=
100 0
400 100
x
x 100
=
or
300
100
or
or
or
or
Q2.8
x 100
3
3 x = x -100
2 x = -100
x = - 50o C
R = R0 (1 + t + t2 )
10 = R0 (1 + 0 + 02 )
16 = R0 (1 + 100 + 1002 )
30 = R0 (1 + 444.6 + 444.62 )
Solve R0 , & then
R = R0 (1 + 500 + 5002 )
Page 14 of 265