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04 Halogen Containing Compounds Set Test Final E

1. Preparation of alkyl halides in the laboratory is least preferred through direct halogenation of alkanes because it produces a mixture of mono-, di-, tri-, and tetrahalogenated products that are difficult to separate. 2. The order of reactivity of alkyl halides for SN2 reactions is R-I > R-Br > R-Cl > R-F. The order of C-X bond polarity is CH3Cl > CH3Br > CH3I. 3. Benzene hexachloride is prepared from benzene and chlorine through an addition reaction using sunlight.

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84 views

04 Halogen Containing Compounds Set Test Final E

1. Preparation of alkyl halides in the laboratory is least preferred through direct halogenation of alkanes because it produces a mixture of mono-, di-, tri-, and tetrahalogenated products that are difficult to separate. 2. The order of reactivity of alkyl halides for SN2 reactions is R-I > R-Br > R-Cl > R-F. The order of C-X bond polarity is CH3Cl > CH3Br > CH3I. 3. Benzene hexachloride is prepared from benzene and chlorine through an addition reaction using sunlight.

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mridul
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1194 Halogen Containing Compounds

1.

Preparation of alkyl halides in laboratory is least preferred


by

8.

known is
(a) 6
(c) 8

(a) Halide exchange


(b) Direct halogenation of alkanes
(c) Treatment of alcohols

9.

(d) Addition of hydrogen halides to alkenes


2.

(c)

AIIMS 2001]

3.

(c) Dehydrohalogenation

(d) Elimination

10.

5.

SN 2 reaction is

(a) Longer and weaker

(b) RF RBr RCl RI

(b) Shorter and weaker

(c)
11.

(a)

NO 2 ion

(b) NO 3 ion

(c)

Br ion

(d) I ion

RCl RBr RF RI

(d) RI RBr RCl RF


Which of the following reactions doesnt give benzene
boiling

(a) C6 H 5 N 2 Cl

H 2O

(b) C6 H 5 N 2 Cl
(c)

The following reaction belongs to


[AIEEE 2002]

(a) Elimination reaction

(b) Substitution reaction

(c) Free radical reaction

(d) Displacement reaction

The order of reactivities of methyl halides in the formation of


Grignard reagent is
[KCET 2003]

[IIT-JEE (Screening) 2000]

[RPMT 2003]

A salt solution is treated with chloroform drops. Then it is


shaked with chlorine water. Chloroform layer becomes
violet. Solution contains
[CPMT 1982]

12.

13.

C H5OH
2

C6 H5 N 2Cl H 3 PO2 H 2O

(d) All of these


Benzene hexachloride is prepared from benzene and
chlorine in sunlight by
(a) Substitution reaction
(b) Elimination reaction
(c) Addition reaction
(d) Rearrangement
Carbon-halogen bond is strongest among the following
[MP PMT 1995]

(a) CH 3 I CH 3 Br CH 3 Cl

(a) CH 3 Cl

(b) CH 3 Br

(b) CH 3Cl CH 3 Br CH 3 I

(c)

(d) CH 3 I

(c)

14.

CH 3 Br CH 3 Cl CH 3 I

(d) CH 3 Br CH 3 I CH 3 Cl
7.

The order of reactivities of the following alkyl halides for a


(a) RF RCl RBr RI

H2O
(CH 3 )3 C Br
(CH 3 )3 C OH

6.

CH 3Cl CH 3 Br CH 3 I

The C Cl bond in chlorobenzene as compared with


[MP PMT 1995]
C Cl bond in methyl chloride is

(d) Longer and stronger

Identify Z in the following series


Br2
Alco. KOH
KCN
C2 H 5 I
X
Y
Z

15.

[AIIMS 1983; AFMC 1998; MP PET 1997]

CH 2 CN

(a) CH 3 CH 2 CN

(b)
CH 2 CN

(c)

BrCH 2 CH 2 CN

(d) BrCH CHCN

[RPMT 2000]

(d) CH 3Cl CH 3 I CH 3 Br

(c) Shorter and stronger


4.

The correct order of C X bond polarity is


(b) CH 3 I CH 3 Br CH 3 Cl

[EAMCET 1980; CBSE PMT 1997; BHU 1999;

(b) Substitution

(b) 7
(d) None of these

(a) CH 3 Br CH 3 Cl CH 3 I

An alkyl halide may be converted into an alcohol by

(a) Addition

The total number of stereoisomeric forms of C6 H 6 Cl 6

16.

CH 3 F

Which of these do not undergo Wurtz reaction


(a) C2 H 5 F

(b) C2 H 5 Br

(c)

(d) C2 H 5 I

C2 H 5 Cl

When ethyl bromide reacts with sodium acetylide the main


product is
[Pb. CET 2002]
(a) 1-butane
(b) 1-butene
(c) 1-butyne
(d) 2-butene
[Pb. PMT 2004]
C 2 H 5 I and Ag 2 O reacts to produce
(a) C 2 H 6
(c)

C2 H 5 O C2 H 5

(b) C2 H 5 C2 H 5
(d) C2 H 5 CH 3

Halogen Containing Compounds

1195

(SET -25)
1.

(b) Direct halogenation of alkenes is not preferred because


in it a mixture of monohalogen, dihalogen, trihalogen and
tetrahalogen substituted product is obtained which is
difficult to separate.
Cl

Cl

2
2
e.g. CH 4

CH 3Cl
CH 2Cl 2

Cl

8.

(c)

9.

(c) The C X bond polarity order are as under


CH 3Cl CH 3 Br CH 3 I

10.

(d) The order of reactivity of alkyl holides for SN 2 reaction


is

Cl

2
2

CHCl 3
CCl 4

2.

(b)

Addition
reaction

R CH 2 CH 2 X

Not shown by alkyl halide


(saturated compound)
Dehydrohalogenation R CH CH HX
R CH CH 2 HX

Elimination
Alc.KOH
aq.KOH
Substitution

Alkene

H2O

Cl

12.

(c)

Sunlight

Cl

3Cl 2

Addition reaction

Cl

Cl
BHC

(d) 2NaI Cl 2 2NaCl I 2 (Dissolves in CHCl 3 to give


violet colour)
Chlorine displaces iodine from salt. The iodine get
dissolve in CHCl 3 or CCl 4 to produce violet colour.

CH 3 F CH 3Cl CH 3 Br CH 3 I

13.

(c)

14.

(a) C2 H5 F 2 Na FC2 H5 No reaction

15.

(c)

Dry

ether

H2O
(b) (CH 3 )3 C Br
(CH 3 )3 C OH

C2 H 5 Br NaC CH C2 H 5 C CH NaBr
sodium
Ethyl bromide sodium acetylide
1- butyne
bromide
Thus in this reaction 1-butyne is main product.

Here Br substitute by OH group.

16.

(a) Reactivity towards grignard reagent are as under


CH 3 I CH 3 Br CH 3Cl
alc. KOH

Cl

Alcohol

4.

7.

Boiling
(a) C6 H5 N 2Cl

C6 H5 OH N 2 HCl

Cl

(c) In chlorobenzene C Cl bond acquires partial double


bond character because of resonance.

6.

11.

R CH 2 CH 2 OH HX

3.

5.

R I R Br R Cl R F

Alkene

Alc.KOH

Alkyhalide

C6 H6 Cl 6 has 8 stereoisomer.

Br

Br

C2 H5 I and Ag2O reacts as below

2C2 H5 I Ag2O C2 H5OC2 H5 I 2


ether

Thus, C2 H5 O C2 H5 is produced.

Br

2
(b) C2 H 5 I
C2 H 4
CH 2 CH 2

(c)

KCN

CH 2 CH 2
|

CN

CN

Butene-1, 4 - dinitrile

***

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