HAZOP
HAZOP
GAS
HAZARD AND OPERABILITY STUDY (HAZOP)
ALBERO Apple Joy, DIAMANTE Ma. Heresa C., EDQUIBAL Kristelle H., GUEVARRA Mark Carlo A., MENDOZA Kinski R., RAMIREZ
Charlyn Joy F.
NO
.
GUIDE
WORD
Element
Deviation
Possible
Causes
Consequences
Safeguards
Comments
Actions required
Actions
Assigned to
Tank 1
Pressure
inside
Above the
set point
Operating
pressure of
the turbine
Explosion of the
storage tank due
to overpressure
Relief valve
1
Operations
Manager /
Supervisor
Flow from
tank 1
Flow rate of
the stream
Above or
below the
set point
Opening of
the valve
Operating
conditions of the
compressor 1
Valve 1 and
manual
valve 1
Operations
Manager/
Supervisor
Heat
Exchanger
1 and 2
Temperatur
e of the
working
fluid
entering the
heat
exchanger
Higher or
lower than
the
standard
temperatur
e level
Unregulated
cold water
entry
Operating
conditions of the
separator
Valve 3 and
valve 9
Valves are
programmed to
address this events
then immediately
sending it to the
control room.
Operations
Manager/
Supervisor
Compressor 1 and
Pressure
inside the
Above or
below the
Fluctuations
of pressure
The compressor
cannot handle
manual
valve 2
Valves are
programmed to
Observe routinely
maintenance of the
Operations
Manager/
compressor
set point
within the
process of
the amount of
fluid inside
and
manual
valve 6
valves
Supervisor
Boiler
Level inside
the Boiler
Above or
below the
set point
Opening of
the valve
Manual
Valve 5
Valves are
programmed to
address this events
then immediately
sending it to the
control room.
Maintenance of the
Operations
valve
Manager/Super
visor
Flow of
fluid to
the
compress
or 2
Flow rate of
the fluid
Above or
below the
set point
Opening of
the valve
Valves are
programmed to
address this events
then immediately
sending it to the
control room.
Maintenance of the
Operations
valve
Manager/Super
visor
Flow from
compress
or 3
Flow rate of
the stream
Above or
below the
set point
Opening of
the valve
Operating
conditions of the
reactor 1
Valve 38
and
manual
valve 23.1
Operations
Manager/
Supervisor
Flow from
heat
exchange
1 and 2
Flow rate of
the stream
Above or
below the
set point
Defective
inlet or
outlet valve
Operating
conditions of the
reactor 1
Valve 4 and
manual
valve 3
Valves are
programmed to
address this events
then immediately
sending it to the
control room.
Observe routinely
maintenance of the
valves
Operations
Manager/Super
visor
10
Reactor 1
Pressure
inside the
Above or
below the
set
Unregulated
pressure
inside the
Operating
conditions of the
Relief valve
5
Valves are
programmed to
address this events
Maintenance of the
Operations
valve
Manager/Super
storage tank
pressure
reactor
reactor 1
then immediately
sending it to the
control room.
visor
11
Reactor 1
Temperatur
e inside the
storage tank
Above or
below the
set
temperatur
e
Unregulated
temperatur
e inside the
reactor
Operating
conditions of the
reactor 1
Manual
valve 3, 8,
and 23.1
Valves are
programmed to
address this events
then immediately
sending it to the
control room.
Maintenance of the
Operations
valve
Manager/Super
visor
12
Reactor 1
Quality
inside the
storage tank
Above or
below the
set ratio
Unregulated
ratio inside
the reactor
Operating
conditions of the
reactor 1
Manual
valve 3, 8,
and 23.1
Valves are
programmed to
address this events
then immediately
sending it to the
control room.
Maintenance of the
Operations
valve
Manager/Super
visor
13
Reactor 1
Levelinside
the storage
tank
Above or
below the
set level
Unregulated
level inside
the reactor
Operating
conditions of the
reactor 1
Control
valve 4
Valves are
programmed to
address this events
then immediately
sending it to the
control room.
Maintenance of the
Operations
valve
Manager/Super
visor
Turbine 1
Pressure on
the outlet of
the turbine
Above the
set point
Operating
pressure of
the turbine
Operating
conditions of the
separator 1
PT 201, PIC
201
Pressure at the
outlet stream will be
checked and in case
of deviation of
pressure from the
set point, operating
pressure of the
turbine will be
Operations
Manager /
Supervisor
adjusted
2
Flow from
turbine 1
Flow rate of
the stream
Above or
below the
set point
Opening of
the valve
Operating
conditions of the
separator
Valve 11
and
manual
valve 9
Operations
Manager/
Supervisor
Heat
Exchanger
3
Temperatur
e of the
working
fluid
entering the
heat
exchanger
Higher or
lower than
the
standard
temperatur
e level
Unregulated
cold water
entry
Operating
conditions of the
separator
Valve 12
Valves are
programmed to
address this events
then immediately
sending it to the
control room.
Operations
Manager/
Supervisor
Separator
1
Level of fluid
inside the
separator 1
Above the
fluid limit
the
separator 1
can handle
Defective
inlet or
outlet valve
The separator
cannot handle
the amount of
fluid inside
Valve 13
and
manual
valve 11
Valves are
programmed to
address this events
then immediately
sending it to the
control room.
Observe routinely
maintenance of the
valves
Operations
Manager/
Supervisor
Separator
1
Pressure
inside the
separator 1
Above or
below the
set point
Fluctuations
of pressure
within the
process of
the
separator
The separator
cannot handle
the pressure
inside
Relief valve
3
Valves are
programmed to
address this events
then immediately
sending it to the
control room.
Maintenance of the
Operations
valve
Manager/Super
visor
Separator
Temperatur
e of the
Outlet
stream of
the
Above or
below the
set point
Temperatur
e of the hot
fluid
entering the
Operability of the
filter press will
be affected
Valve 17.1
Valves are
programmed to
address this events
then immediately
sending it to the
Maintenance of the
Operations
valve
Manager/Super
visor
separator
separator
control room.
Flow of
fluid to
the filter
press
Flow rate of
the fluid
Above or
below the
set point
Opening of
the valve
Operability of the
filter press will
be affected
Valve 14
and
manual
valve 12
Valves are
programmed to
address this events
then immediately
sending it to the
control room.
Maintenance of the
Operations
valve
Manager/Super
visor
Storage
Tank 4
Level of fluid
inside the
storage tank
Above the
level set
point
Opening of
the valve to
the storage
tank
Capacity of the
storage tank and
it might cause
overflow
Valve 15
and
Manual
valve 13
Valves are
programmed to
address this events
then immediately
sending it to the
control room.
Maintenance of the
Operations
valve
Manager/Super
visor
Turbine 2
Pressure on
the outlet of
the turbine
Above the
set point
Operating
pressure of
the turbine
Operating
conditions of the
separator 2
PT 301, PIC
301
Pressure at the
outlet stream will be
checked and in case
of deviation of
pressure from the
set point, operating
pressure of the
turbine will be
adjusted
Operations
Manager/iSupe
rvisor
Flow from
turbine 2
Flow rate of
the stream
Above or
below the
set point
Opening of
the valve
Operating
conditions of the
separator
Valve 16
and
manual
valve 14
Operations
Manager/
Supervisor
Separator
2
Level of fluid
inside the
Above the
fluid limit
the
Defective
inlet or
The separator
cannot handle
the amount of
Valve17
and
manual
Valves are
programmed to
address this events
Observe routinely
maintenance of the
Operations
Manager/
separator 2
separator
can handle
outlet valve
fluid inside
valve 15
then immediately
sending it to the
control room.
valves
Supervisor
Separator
2
Pressure
inside the
separator 2
Above or
below the
set point
Fluctuations
of pressure
within the
process of
the
separator
The separator
cannot handle
the pressure
inside
Relief valve
4
Valves are
programmed to
address this events
then immediately
sending it to the
control room.
Maintenance of the
Operations
valve
Manager/Super
visor
10
Storage
Tank 5
Pressure
inside the
storage tank
Above the
set
pressure
Unregulated
pressure
inside the
storage tank
Explosion of the
storage tank due
to overpressure
Relief valve
5
Valves are
programmed to
address this events
then immediately
sending it to the
control room.
Maintenance of the
Operations
valve
Manager/Super
visor
Distillatio
n Column
Pressure
inside
Higher/Low
er than the
set point
Malfunction
of safety
and control
valve,
malfunction
of FRC (flow
record
control)
Malfunction in
the process,
boiler column
and its function,
inadequate
steam for the
process, delay to
reach desired
time, waste of
time and energy,
coil steam
damages
Relief
Valve 6
PI installation,
regular examine,
PM program
Operations
Manager
Higher/Low
er
Malfunction
in the
Disorder in the
process of
Control
Valve 22
Valve is
programmed to
Operations
Manager
Distillatio
n Column
Temperatur
e inside
Supervisor
Distillatio
n Column
Distillatio
n Column
Reflux
Drum
Reboiler
Reflux
Fluid Flow
Contaminati
on
Cooling
Water Flow
Heating
Water Flow
Fluid Flow
column
distillation
column
Reverse
process
fluid flow
Failure of
process fluid
inlet valve
Contamina
tion of
process
fluid line
Leakage of
tube and
cooling
water goes
in
Contamination of
process fluid
More/Less
cooling
water flow
Failure of
inlet cooling
water valve
to close
Output of
Process fluid
temperature too
low
Control
Valve 24
More/Less
heating
flow
Failure of
valve
Temperature of
process fluid
decrease
Control
Valve 22
Reverse
process
Failure of
process fluid
Control
Valves 25
Control
Valve 18
Manual
Valve 17
pipeline
Supervisor
Valve is
programmed to
address this events
then immediately
sending it to the
control room.
Operations
Manager
Repair of the
pipeline
Proper
maintenance and
operator alert
Operations
Manager
Valve is
programmed to
address this events
then immediately
sending it to the
control room.
Install Temperature
indicator before
and after process
fluid line
Install TAL
Operations
Manager
Valve is
programmed to
address this events
then immediately
sending it to the
control room.
Low Temperature
Alarm
Operations
Manager
Valve is
programmed to
Supervisor
Supervisor
Supervisor
Supervisor
Operations
Drum
Reboiler
Distillatio
n Column
Distillatio
n Column
Distillatio
fluid flow
Fluid Flow
Pressure
inside
Temperatur
e inside
Fluid Flow
inlet valve
& 26
pipeline
Control
Valves 19
& 20
Valve is
programmed to
address this events
then immediately
sending it to the
control room.
Operations
Manager
PI installation,
regular examine,
PM program
Operations
Manager
Valve is
programmed to
address this events
then immediately
sending it to the
control room.
Operations
Manager
Valve is
Operations
Reverse
process
fluid flow
Failure of
process fluid
inlet valve
Higher/Low
er than the
set point
Malfunction
of safety
and control
valve,
malfunction
of FRC (flow
record
control)
Malfunction in
the process,
boiler column
and its function,
inadequate
steam for the
process, delay to
reach desired
time, waste of
time and energy,
coil steam
damages
Relief
Valve 7
Higher/Low
er
Malfunction
in the
column
Disorder in the
process of
distillation
column
Check
Valve 28
Failure of
Check
Reverse
Manager
Supervisor
Supervisor
Supervisor
Supervisor
n Column
Distillatio
n Column
Reflux
Drum
Reboiler
Reflux
Drum
Contaminati
on
Cooling
Water Flow
Heating
Water Flow
Fluid Flow
process
fluid flow
process fluid
inlet valve
Valve 27
Contamina
tion of
process
fluid line
Leakage of
tube and
cooling
water goes
in
Contamination of
process fluid
More/Less
cooling
water flow
Failure of
inlet cooling
water valve
to close
Output of
Process fluid
temperature too
low
Check
Valve 24
More/Less
heating
flow
Failure of
valve
Temperature of
process fluid
decrease
Check
Valve 28
Reverse
process
fluid flow
Failure of
process fluid
inlet valve
Check
Valves 32
& 33
Manual
Valve 19
programmed to
address this events
then immediately
sending it to the
control room.
the pipeline
Manager
Repair of the
pipeline
Proper
maintenance and
operator alert
Operations
Manager
Valve is
programmed to
address this events
then immediately
sending it to the
control room.
Install Temperature
indicator before
and after process
fluid line
Install TAL
Operations
Manager
Valve is
programmed to
address this events
then immediately
sending it to the
control room.
Low Temperature
Alarm
Operations
Manager
Valve is
programmed to
address this events
then immediately
sending it to the
control room.
Supervisor
Supervisor
Supervisor
Supervisor
Operations
Manager
Supervisor
Reboiler
Distillatio
n Column
Distillatio
n Column
Distillatio
n Column
Fluid Flow
Pressure
inside
Temperatur
e inside
Fluid Flow
Reverse
process
fluid flow
Failure of
process fluid
inlet valve
Higher/Low
er than the
set point
Malfunction
of safety
and control
valve,
malfunction
of FRC (flow
record
control)
Higher/Low
er
Reverse
process
fluid flow
Check
Valves 29
& 3o
Valve is
programmed to
address this events
then immediately
sending it to the
control room.
Operations
Manager
Malfunction in
the process,
boiler column
and its function,
inadequate
steam for the
process, delay to
reach desired
time, waste of
time and energy,
coil steam
damages
Relief
Valve 6
PI installation,
regular examine,
PM program
Operations
Manager
Malfunction
in the
column
Disorder in the
process of
distillation
column
Control
Valve 22
Valve is
programmed to
address this events
then immediately
sending it to the
control room.
Operations
Manager
Failure of
process fluid
inlet valve
Control
Valve 18
Valve is
programmed to
address this events
then immediately
sending it to the
Operations
Manager
Supervisor
Supervisor
Supervisor
Supervisor
control room.
1
Distillatio
n Column
Reflux
Drum
Reboiler
Contaminati
on
Cooling
Water Flow
Heating
Water Flow
Contamina
tion of
process
fluid line
Leakage of
tube and
cooling
water goes
in
Contamination of
process fluid
Manual
Valve 17
More/Less
cooling
water flow
Failure of
inlet cooling
water valve
to close
Output of
Process fluid
temperature too
low
Control
Valve 24
More/Less
heating
flow
Failure of
valve
Temperature of
process fluid
decrease
Control
Valve 22
Repair of the
pipeline
Proper
maintenance and
operator alert
Operations
Manager
Valve is
programmed to
address this events
then immediately
sending it to the
control room.
Install Temperature
indicator before
and after process
fluid line
Install TAL
Operations
Manager
Valve is
programmed to
address this events
then immediately
sending it to the
control room.
Low Temperature
Alarm
Operations
Manager
Supervisor
Supervisor
Supervisor
Stripper
Level of fluid
inside the
stripper
above the
standard
height
Defective
inlet or
outlet valve
Irregular
performance of
the stripper
FC 603,
M20, M21
and M22
valve
Valves are
programmed to
address this events
then immediately
sending it to the
control room.
Operations
Manager/iiSupe
rvisor
Stripper
Pressure of
fluid inside
the stripper
Higher
than the
standard
pressure
Increase in
Temperatur
e
Explosion of
pipes or the
stripper
Relief
Valve 8
Always regulate
the pressure inside
the vessel or
always make sure
that the pressure
Operations
Manager/
Supervisor
level
1
Stripper
Temperatur
e inside the
stripper
Higher or
lower than
the
standard
pressure
level
Unregulated
steam entry
Irregular
performance of
the stripper
control room.
sensors are
working.
Valve 39
Operations
Manager/
Supervisor
Or Explosion of
pipes and the
stripper
Separator
Level of fluid
inside the
separator
Above the
fluid limit
the
stripper
can handle
Defective
inlet or
outlet valve
Valve 37
and Valve
36
Valves are
programmed to
address this events
then immediately
sending it to the
control room.
Observe routinely
maintenance of the
valves
Operations
Manager/
Supervisor
Fire
Heater
Temperatur
e and Level
inside the
fire heater
The water
may be
higher than
the desired
level of
water.
Defective
inlet and
outlet valve.
Adjust the
heat
produced
by the fire
heater.
Valves are
programmed to
address this events
then immediately
sending it to the
control room.
Assign an
operator that
would always
check the fire
heater
Operator
Valve 38.2
The
Temperatu
re is higher
than what
the vessel
can handle.
1
Flow from
storage
Flow rate of
the stream
Above or
below the
Defective
fire
controller.
Opening of
the valve
Operating
conditions of the
Operations
Manager/
tank 7
set point
pump 12
control devices
Supervisor
Mixer
Level inside
Above or
below the
set level
Unregulated
pressure
inside the
reactor
Operating
conditions of the
mixer
Valve 37.1
Valves are
programmed to
address this events
then immediately
sending it to the
control room.
Operations
Manager /
Supervisor
Flow from
pump 12
to reactor
2
Flow rate of
the stream
Above or
below the
set point
Opening of
the valve
Operating
conditions of the
reactor 2
Control
Valve 39
Operations
Manager/
Supervisor
Reactor 2
Pressure
inside the
reactor
Above or
below the
set
pressure
Unregulated
pressure
inside the
reactor
Operating
conditions of the
reactor 2
Relief valve
9
Valves are
programmed to
address this events
then immediately
sending it to the
control room.
Maintenance of the
valve
Operations
Manager/
Supervisor
Reactor 2
Temperatur
e inside the
reactor
Above or
below the
set
temperatur
e
Unregulated
temperatur
e inside the
reactor
Operating
conditions of the
reactor 2
Manual
valve25
Valves are
programmed to
address this events
then immediately
sending it to the
Maintenance of the
Operations
valve
Manager/Super
visor
Reactor 2
Quality
inside the
reactor
Above or
below the
set ratio
Unregulated
ratio inside
the reactor
Operating
conditions of the
reactor 1
Manual
valve25
Valves are
programmed to
address this events
then immediately
sending it to the
Maintenance of the
Operations
valve
Manager/Super
visor
control room.
7
Reactor 2
Level inside
the reactor
Above or
below the
set level
Unregulated
level inside
the reactor
Operating
conditions of the
reactor 1
Control
valve 39
Valves are
programmed to
address this events
then immediately
sending it to the
control room.
Maintenance of the
Operations
valve
Manager/Super
visor
Flow to
pump 14
Flow rate of
the stream
Above or
below the
set point
Opening of
the valve
Operating
conditions of the
separator
Control
Valve 46
Operations
Manager/
Supervisor
Separator
4
Level of fluid
inside the
separator 4
Above the
fluid limit
the
separator 4
can handle
Defective
inlet or
outlet valve
The separator
cannot handle
the amount of
fluid inside
Control
valve 41
Valves are
programmed to
address this events
then immediately
sending it to the
control room.
Observe routinely
maintenance of the
valves
Operations
Manager/
Supervisor
10
Separator
4
Pressure
inside the
separator 4
Above or
below the
set point
Fluctuations
of pressure
The separator
cannot handle
the pressure
inside
Relief valve
10
Valves are
programmed to
address this events
then immediately
sending it to the
control room.
Maintenance of the
Operations
valve
Manager/Super
visor
11
Storage
tank 8
Level inside
the tank
Above the
level set
point
Opening of
the valve to
the storage
tank
Capacity of the
storage tank and
it might cause
overflow
Control
valve 42
Valves are
programmed to
address this events
then immediately
sending it to the
Maintenance of the
Operations
valve
Manager/Super
visor
control room.
12
Flow from
pump 15
to reactor
3
Flow rate of
the fluid
Above or
below the
set point
Opening of
the valve
Operability of the
reactor 2
Control
valve 43
Valves are
programmed to
address this events
then immediately
sending it to the
control room.
Maintenance of the
Operations
valve
Manager/Super
visor
13
Storage
tank 9
Pressure
inside the
storage tank
Above the
set
pressure
Unregulated
pressure
inside the
storage tank
Explosion of the
storage tank due
to overpressure
Relief valve
12
Valves are
programmed to
address this events
then immediately
sending it to the
control room.
Maintenance of the
Operations
valve
Manager/Super
visor
14
Flow of
fluid to
compress
or 4
Flow rate of
the fluid
Above or
below the
set point
Opening of
the valve
Operability of the
compressor be
affected
Control
valve 44
Valves are
programmed to
address this events
then immediately
sending it to the
control room.
Maintenance of the
Operations
valve
Manager/Super
visor
15
Compress
or 4
Pressure of
the
compressor
Above or
below the
set point
Unregulated
pressure
Operability of the
compressor be
affected
PIC 772
Valves are
programmed to
address this events
then immediately
sending it to the
control room.
Maintenance of the
Operations
valve
Manager/Super
visor
16
Flow from
compress
or 4 to
Flow rate of
the stream
Above or
below the
set point
Opening of
the valve
Operating
conditions of the
reactor 2
Control
Valve 45
Operations
Manager/
Supervisor
reactor 3
stream
17
Reactor 3
Pressure
inside the
storage tank
Above or
below the
set
pressure
Unregulated
pressure
inside the
reactor
Operating
conditions of the
reactor 2
Relief valve
11
Valves are
programmed to
address this events
then immediately
sending it to the
control room.
Maintenance of the
valve
18
Reactor 3
Temperatur
e inside the
storage tank
Above or
below the
set
temperatur
e
Unregulated
temperatur
e inside the
reactor
Operating
conditions of the
reactor 2
Manual
valve 29
Valves are
programmed to
address this events
then immediately
sending it to the
Maintenance of the
Operations
valve
Manager/Super
visor
19
Reactor 3
Quality
inside the
storage tank
Above or
below the
set ratio
Unregulated
ratio inside
the reactor
Operating
conditions of the
reactor 1
Manual
valve 29
Valves are
programmed to
address this events
then immediately
sending it to the
control room.
Maintenance of the
Operations
valve
Manager/Super
visor
20
Reactor 2
Level inside
the storage
tank
Above or
below the
set level
Unregulated
level inside
the reactor
Operating
conditions of the
reactor 1
Control
valve 43
Valves are
programmed to
address this events
then immediately
sending it to the
control room.
Maintenance of the
Operations
valve
Manager/Super
visor
21
Flow to
pump 16
Flow rate of
the stream
Above or
below the
set point
Opening of
the valve
Operating
conditions of the
separator
Control
Valve 47
Operations
Manager/
Supervisor
Operations
Manager/
Supervisor
22
Separator
5
Level of fluid
inside the
separator 5
Above the
fluid limit
the
separator 4
can handle
Defective
inlet or
outlet valve
The separator
cannot handle
the amount of
fluid inside
Control
valve 48
Valves are
programmed to
address this events
then immediately
sending it to the
control room.
Observe routinely
maintenance of the
valves
23
Separator
5
Pressure
inside the
separator 1
Above or
below the
set point
Fluctuations
of pressure
within the
process of
the
separator
The separator
cannot handle
the pressure
inside
Relief valve
1
Valves are
programmed to
address this events
then immediately
sending it to the
control room.
Maintenance of the
Operations
valve
Manager/Super
visor
24
Flow to
pump 17
Flow rate of
the stream
Above or
below the
set point
Opening of
the valve
Operating
conditions of the
separator
Valve 34
25
Heat
exchange
8
Temperatur
e of the heat
exchanger
Above or
below the
standard
temperatur
e of the
heat
exchanger
Unregulated
cold water
entry
Operating
conditions of the
heat exchanger
Control
valve 49
26
Storage
tank 10
Level inside
the tank
Above the
level set
point
Opening of
the valve to
the storage
tank
Capacity of the
storage tank and
it might cause
overflow
Control
valve 51
Valves are
programmed to
address this events
then immediately
sending it to the
control room.
Operations
Manager/
Supervisor
Operations
Manager/
Supervisor
Maintenance of the
Operations
valve
Manager/Super
visor
27
Flow to
pump 18
Flow rate of
the stream
Above or
below the
set point
Opening of
the valve
Operating
conditions of the
separator
Manual
valve 35
Operations
Manager/
Supervisor
28
Heat
exchange
9
Temperatur
e of the
working
fluid
entering the
heat
exchanger
Higher or
lower than
the
standard
temperatur
e level
Unregulated
cold water
entry
Operating
conditions of the
separator
Control
valve 50
Valves are
programmed to
address this events
then immediately
sending it to the
control room.
Operations
Manager/
Supervisor
29
Storage
tank 11
Level inside
the tank
Above the
level set
point
Opening of
the valve to
the storage
tank
Capacity of the
storage tank and
it might cause
overflow
Control
valve 52
Valves are
programmed to
address this events
then immediately
sending it to the
control room.
Maintenance of the
Operations
valve
Manager/Super
visor