Carbon Nanotube
Carbon Nanotube
INTRODUCTION
1.1.Nanoparticles:
1.2.Nanotechnology:
Nanotechnology, shortened to "nanotech", is the study of the controlling
of matter on an atomic and molecular scale. Generally nanotechnology deals with
structures of the size 100 nanometers or smaller in at least one dimension, and involves
developing materials or devices within that size. Nanotechnology is very diverse, ranging
from extensions of conventional device physics to completely new approaches based
upon molecular self-assembly, from developing new materials with dimensions on the
nanoscale to investigating whether we can directly control matter on the atomic scale.
1.3.Carbon Nanotubes:
Carbon nanotubes (CNTs) are allotropes of carbon with a cylindrical
nanostructure. Nanotubes have been constructed with length-to-diameter ratio of up to
132,000,000:1, which is significantly larger than any other material. These cylindrical
carbon molecules have novel properties that make them potentially useful in many
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applications in nanotechnology, electronics, optics and other fields of materials science,
as well as potential uses in architectural fields. They exhibit extraordinary strength and
unique electrical properties, and are efficient thermal conductors. Their final usage,
however, may be limited by their potential toxicity and controlling their property changes
in response to chemical treatment.
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He was credited with the first visual impression of the tubes of atoms that
roll up and are capped with fullerene molecules by many scientists in the field. Some
state that his discovery just wasn’t taken very seriously at the time because science did
not know how this discovery could impact scientific research.
It would be in 1993 that Iijima and Donald Bethune found single walled
nanotubes known as buckytubes. This helped the scientific community make more sense
out of not only the potential for nanotube research, but the use and existence of
fullerenes.
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3.1.Single-Walled:
Most single-walled nanotubes (SWNT) have a diameter of close to
1 nanometer, with a tube length that can be many millions of times longer. The structure
of a SWNT can be conceptualized by wrapping a one-atom-thick layer of graphite called
graphene into a seamless cylinder. The way the graphene sheet is wrapped is represented
by a pair of indices (n,m) called the chiral vector. The integers n and m denote the
number of unit vectors along two directions in the honeycomb crystal lattice of graphene.
If m = 0, the nanotubes are called "zigzag". If n = m, the nanotubes are called "armchair".
Otherwise, they are called "chiral".
Single-walled nanotubes are still very expensive to produce, around $1500 per gram as of
2000, and the development of more affordable synthesis techniques is vital to the future
of carbon nanotechnology. If cheaper means of synthesis cannot be discovered, it would
make it financially impossible to apply this technology to commercial-scale applications.
Several suppliers offer as-produced arc discharge SWNTs for ~$50–100 per gram as of
2007.
3.2.Multi-Walled:
Multi-walled nanotubes (MWNT) consist of multiple rolled layers
(concentric tubes) of graphite. There are two models which can be used to describe the
structures of multi-walled nanotubes. In the Russian Doll model, sheets of graphite are
arranged in concentric cylinders, e.g. a (0,8) single-walled nanotube (SWNT) within a
larger (0,10) single-walled nanotube. In the Parchment model, a single sheet of graphite
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is rolled in around itself, resembling a scroll of parchment or a rolled newspaper. The
interlayer distance in multi-walled nanotubes is close to the distance between graphene
layers in graphite, approximately 3.4 Å.
The special place of double-walled carbon nanotubes (DWNT) must be emphasized here
because their morphology and properties are similar to SWNT but their resistance to
chemicals is significantly improved. This is especially important when functionalization
is required (this means grafting of chemical functions at the surface of the nanotubes) to
add new properties to the CNT. In the case of SWNT, covalent functionalization will
break some C=C double bonds, leaving "holes" in the structure on the nanotube and thus
modifying both its mechanical and electrical properties. In the case of DWNT, only the
outer wall is modified. DWNT synthesis on the gram-scale was first proposed in 2003 by
the CCVD technique, from the selective reduction of oxide solutions in methane and
hydrogen.
3.3.Torus:
A nanotorus is theoretically described as carbon nanotube bent into a torus
(doughnut shape). Nanotori are predicted to have many unique properties, such as
magnetic moments 1000 times larger than previously expected for certain specific radii.
Properties such as magnetic moment, thermal stability, etc. vary widely depending on
radius of the torus and radius of the tube.
3.4.Nano Buds:
Carbon nanobuds are a newly created material combining two previously
discovered allotropes of carbon: carbon nanotubes and fullerenes. In this new material,
fullerene-like "buds" are covalently bonded to the outer sidewalls of the underlying
carbon nanotube. This hybrid material has useful properties of both fullerenes and carbon
nanotubes. In particular, they have been found to be exceptionally good field emitters. In
composite materials, the attached fullerene molecules may function as molecular anchors
preventing slipping of the nanotubes, thus improving the composite’s mechanical
properties.
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Properties
4.1.Physical:
4.1.1.Strength:
Carbon nanotubes are the strongest and stiffest materials yet discovered in
terms of tensile strength and elastic modulus respectively. This strength results
from the covalent sp² bonds formed between the individual carbon atoms. In
2000, a multi-walled carbon nanotube was tested to have a tensile strength of
63 gigapascals (GPa). (This, for illustration, translates into the ability to endure
tension of a weight equivalent to 6300 kg on a cable with cross-section of 1 mm 2.)
Since carbon nanotubes have a low density for a solid of 1.3 to 1.4 g·cm−3, its
specific strength of up to 48,000 kN·m·kg−1 is the best of known materials,
compared to high-carbon steel's 154 kN·m·kg−1.
Under excessive tensile strain, the tubes will undergo plastic deformation,
which means the deformation is permanent. This deformation begins at strains of
approximately 5% and can increase the maximum strain the tubes undergo before fracture
by releasing strain energy.
CNTs are not nearly as strong under compression. Because of their hollow
structure and high aspect ratio, they tend to undergo buckling when placed under
compressive, torsional or bending stress.
4.1.2.Hardness:
Diamond is considered to be the hardest material, and it is well known that
graphite transforms into diamond under conditions of high temperature and high pressure.
One study succeeded in the synthesis of a super-hard material by compressing SWNTs to
above 24 GPa at room temperature. The hardness of this material was measured with a
nanoindenter as 62–152 GPa. The hardness of reference diamond and boron nitride
samples was 150 and 62 GPa, respectively. The bulk modulus of compressed SWNTs
was 462–546 GPa, surpassing the value of 420 GPa for diamond.
4.1.3.Kinetic:
Multi-walled nanotubes, multiple concentric nanotubes precisely nested
within one another, exhibit a striking telescoping property whereby an inner nanotube
core may slide, almost without friction, within its outer nanotube shell thus creating an
atomically perfect linear or rotational bearing. This is one of the first true examples of
molecular nanotechnology, the precise positioning of atoms to create useful machines.
Already this property has been utilized to create the world's smallest rotational motor.
Future applications such as a gigahertz mechanical oscillator are also envisaged.
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4.2.Electrical:
Because of the symmetry and unique electronic structure of graphene, the
structure of a nanotube strongly affects its electrical properties. For a given (n,m)
nanotube, if n = m, the nanotube is metallic; if n − m is a multiple of 3, then the nanotube
is semiconducting with a very small band gap, otherwise the nanotube is a moderate
semiconductor. Thus all armchair (n = m) nanotubes are metallic, and nanotubes (6,4),
(9,1), etc. are semiconducting.
However, this rule has exceptions, because curvature effects in small diameter carbon
nanotubes can influence strongly electrical properties. Thus, (5,0) SWCNT that should be
semiconducting is in fact metallic according to the calculations. And vice versa, zigzag
and chiral SWCNTs with small diameters that should be metallic have finite gap
(armchair nanotubes remain metallic). In theory, metallic nanotubes can carry an
electrical current density of 4 × 109 A/cm2 which is more than 1,000 times greater than
metals such as copper.
4.3.Thermal:
All nanotubes are expected to be very good thermal conductors along the tube,
exhibiting a property known as ballistic conduction, but good insulators laterally to the
tube axis. Measurements show SWNTs room-temperature thermal conductivity about
3500 W/(m·K); compare this to copper, a metal well-known for its good thermal
conductivity, which transmits 385 W·m−1·K−1. The temperature stability of carbon
nanotubes is estimated to be up to 2800 °C in vacuum and about 750 °C in air.
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5.1.Arc Discharge:
Nanotubes were observed in 1991 in the carbon soot of graphite electrodes during
an arc discharge, by using a current of 100 amps, that was intended to produce fullerenes.
However the first macroscopic production of carbon nanotubes was made in 1992 by two
researchers at NEC's Fundamental Research Laboratory. The method used was the same
as in 1991. During this process, the carbon contained in the negative electrode sublimates
because of the high discharge temperatures. Because nanotubes were initially discovered
using this technique, it has been the most widely-used method of nanotube synthesis.
The yield for this method is up to 30 percent by weight and it produces both
single- and multi-walled nanotubes with lengths of up to 50 micrometers with few
structural defects.
5.2.Laser Ablation:
In the laser ablation process, a pulsed laser vaporizes a graphite target in a high-
temperature reactor while an inert gas is bled into the chamber. Nanotubes develop on the
cooler surfaces of the reactor as the vaporized carbon condenses. A water-cooled surface
may be included in the system to collect the nanotubes.
This process was developed by Dr. Richard Smalley and co-workers at Rice
University, who at the time of the discovery of carbon nanotubes, were blasting metals
with a laser to produce various metal molecules. When they heard of the existence of
nanotubes they replaced the metals with graphite to create multi-walled carbon
nanotubes. Later that year the team used a composite of graphite and metal catalyst
particles (the best yield was from a cobalt and nickel mixture) to synthesize single-walled
carbon nanotubes.
The laser ablation method yields around 70% and produces primarily single-
walled carbon nanotubes with a controllable diameter determined by the reaction
temperature. However, it is more expensive than either arc discharge or chemical vapor
deposition.
During CVD, a substrate is prepared with a layer of metal catalyst particles, most
commonly nickel, cobalt, iron, or a combination. The metal nanoparticles can also be
produced by other ways, including reduction of oxides or oxides solid solutions. The
diameters of the nanotubes that are to be grown are related to the size of the metal
particles. This can be controlled by patterned (or masked) deposition of the metal,
annealing, or by plasma etching of a metal layer. The substrate is heated to approximately
700°C. To initiate the growth of nanotubes, two gases are bled into the reactor: a process
gas (such as ammonia, nitrogen or hydrogen) and a carbon-containing gas (such as
acetylene, ethylene, ethanol or methane). Nanotubes grow at the sites of the metal
catalyst; the carbon-containing gas is broken apart at the surface of the catalyst particle,
and the carbon is transported to the edges of the particle, where it forms the nanotubes.
This mechanism is still being studied. The catalyst particles can stay at the tips of the
growing nanotube during the growth process, or remain at the nanotube base, depending
on the adhesion between the catalyst particle and the substrate.
Of the various means for nanotube synthesis, CVD shows the most promise for
industrial-scale deposition, because of its price/unit ratio, and because CVD is capable of
growing nanotubes directly on a desired substrate, whereas the nanotubes must be
collected in the other growth techniques. The growth sites are controllable by careful
deposition of the catalyst. In 2007, a team from Meijo University demonstrated a high-
efficiency CVD technique for growing carbon nanotubes from camphor. Researchers at
Rice University, until recently led by the late Dr. Richard Smalley, have concentrated
upon finding methods to produce large, pure amounts of particular types of nanotubes.
Their approach grows long fibers from many small seeds cut from a single
nanotube; all of the resulting fibers were found to be of the same diameter as the original
nanotube and are expected to be of the same type as the original nanotube. Further
characterization of the resulting nanotubes and improvements in yield and length of
grown tubes are needed.
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Current Applications
The strength and flexibility of carbon nanotubes makes them of potential use in
controlling other nanoscale structures, which suggests they will have an important role in
nanotechnology engineering. The highest tensile strength of an individual multi-walled
carbon nanotube has been tested to be is 63 GPa. Carbon nanotubes were found in
Damascus steel from the 17th century, possibly helping to account for the legendary
strength of the swords made of it.
6.1.Structural:
Because of the carbon nanotube's superior mechanical properties, many structures
have been proposed ranging from everyday items like clothes and sports gear to combat
jackets and space elevators. However, the space elevator will require further efforts in
refining carbon nanotube technology, as the practical tensile strength of carbon nanotubes
can still be greatly improved.
The first nanotube integrated memory circuit was made in 2004. One of the main
challenges has been regulating the conductivity of nanotubes. Depending on subtle
surface features a nanotube may act as a plain conductor or as a semiconductor. A fully
automated method has however been developed to remove non-semiconductor tubes.
Another way to make carbon nanotube transistors has been to use random networks of
them. By doing so one averages all of their electrical differences and one can produce
devices in large scale at the wafer level. This approach was first patented by Nanomix
Inc. (date of original application June 2002 ). It was first published in the academic
literature by the United States Naval Research Laboratory in 2003 through independent
research work. This approach also enabled Nanomix to make the first transistor on a
flexible and transparent substrate.
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Large structures of carbon nanotubes can be used for thermal management of electronic
circuits. An approximately 1 mm–thick carbon nanotube layer was used as a special
material to fabricate coolers, this materials has very low density, ~20 times lower weight
than a similar copper structure, while the cooling properties are similar for the two
materials.
6.2.Paper Battery:
A paper battery is a battery engineered to use a paper-thin sheet of cellulose
(which is the major constituent of regular paper, among other things) infused with aligned
carbon nanotubes. The nanotubes act as electrodes; allowing the storage devices to
conduct electricity. The battery, which functions as both a lithium-ion battery and a
supercapacitor, can provide a long, steady power output comparable to a conventional
battery, as well as a supercapacitor’s quick burst of high energy—and while a
conventional battery contains a number of separate components, the paper battery
integrates all of the battery components in a single structure, making it more energy
efficient.
6.3.Solar Cell:
Solar cells developed at the New Jersey Institute of Technology use a carbon
nanotube complex, formed by a mixture of carbon nanotubes and carbon buckyballs
(known as fullerenes) to form snake-like structures. Buckyballs trap electrons, although
they can't make electrons flow. Add sunlight to excite the polymers, and the buckyballs
will grab the electrons. Nanotubes, behaving like copper wires, will then be able to make
the electrons or current flow.
6.4.Ultra-Capacitors:
MIT Laboratory for Electromagnetic and Electronic Systems uses nanotubes to
improve ultracapacitors. The activated charcoal used in conventional ultracapacitors has
many small hollow spaces of various size, which create together a large surface to store
electric charge. But as charge is quantized into elementary charges, i.e. electrons, and
each such elementary charge needs a minimum space, a significant fraction of the
electrode surface is not available for storage because the hollow spaces are not
compatible with the charge's requirements. With a nanotube electrode the spaces may be
tailored to size—few too large or too small—and consequently the capacity should be
increased considerably.
6.5.Water Filters:
Carbon Nanotube based sponges are hydrophobic that is they absorb everything
but water. Hence these sponges will absorb toxic sludges present in water thus filtering it.
6.6.Nanotube Membrane:
Nanotube membrane is either a single, open-ended nanotube or a film composed
of open-ended nanotubes that are oriented perpendicularly to the surface of an
impermeable film matrix like the cells of a honeycomb. 'Impermeable' is essential here to
distinguish nanotube membrane with traditional, well known porous membranes. Fluids
and gas molecules may pass through the membrane en masse.
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Future Possibilities
Carbon nanotubes, have potential in fields such as nanotechnology, electronics,
optics, materials science, and architecture. Over the years new discoveries have led to
new applications, often taking advantage of their unique electrical properties,
extraordinary strength, and efficiency in heat conduction.
7.1.Bucky Papers:
Buckypaper is a thin sheet made from an aggregate of carbon nanotubes. The
nanotubes are approximately 50,000 times thinner than a human hair. Originally, it was
fabricated as a way to handle carbon nanotubes, but it is also being studied and developed
into applications by several research groups, showing promise as an armor in vehicle
armor and personal armor.
7.2.Space Elevator:
A space elevator is a proposed structure designed to transport material from a
celestial body's surface into space. Many variants have been proposed, all of which
involve traveling along a fixed structure instead of using rocket powered space launch.
The concept most often refers to a structure that reaches from the surface of the Earth on
or near the Equator to geostationary orbit (GSO) and a counter-mass beyond.
For this endeavor the material of choice would be Carbon Nanotube based
structures as these have very high tensile strength and is rigid enough to withstand huge
amount of forces.
7.3.Nano-Radio:
A nanoradio, a radio receiver consisting of a single nanotube, was demonstrated
in 2007. In 2008 it was shown that a sheet of nanotubes can operate as a loudspeaker if an
alternating current is applied. The sound is not produced through vibration but
thermoacoustically.
7.4.Artificial Muscle:
Electroactive Polymers or EAPs are Carbon Nanotube based polymers whose
shape is modified when a voltage is applied to them. They can be used as actuators or
sensors. As actuators, they are characterized by being able to undergo a large amount of
deformation while sustaining large forces. Due to the similarities with biological tissues
in terms of achievable stress and force, they are often called artificial muscles, and have
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the potential for application in the field of robotics, where large linear movement is often
needed.
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Conclusion
The future for nanotube looks very bright: Nanotubes are interesting model
systems for fundamental studies of one-dimensional systems, but they are equally well
(or even more) attractive for applied researchers and industry due to the wide variety of
their potential applications. They offer lot of creativity in material preparation. Besides
the variety of different structures one can fill the hollow core with semiconducting
metallic, or ferromagnetic materials etc. Along these lines, the latest "breaking news" is a
single wall nanotube filled with C60 molecules.When a few years ago David Luzzi from
the University of Pennsylvania first reported such "peapods", one thought of an "exotic
bird", very nice, but without any importance for future studies. Today, several
laboratories have developed methods for complete filling SWNTs with fullerenes, raising
the possibility of creating an almost one-dimensional superconducting wire of C60 inside
of a nanotube.
Furthermore, since nanotubes are very user-friendly, very robust, they can also act
as excellent model systems for learning manipulation at a nanometer scale, which is the
scale of biological macromolecules like DNA, microtubules and proteins.
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