Operating manual

pH 7110

pH meter

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pH 7110

Copyright

Weilheim 2011, WTW GmbH

Reproduction in whole - or even in part - is prohibited without the express
written permission of WTW GmbH, Weilheim.
Printed in Germany.

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pH 7110

Contents

pH 7110 - Contents

Overview . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7

1.1

pH 7110 meter. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7

1.2

Sensors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7

Safety. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8

2.1 Safety information . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

2.1.1
Safety information in the operating manual. . . . . . . . . . . . . . . .
2.1.2
Safety signs on the meter . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
2.1.3
Further documents providing safety information . . . . . . . . . . . .

8
8
8
8

2.2 Safe operation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

2.2.1
Authorized use . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
2.2.2
Requirements for safe operation. . . . . . . . . . . . . . . . . . . . . . . .
2.2.3
Unauthorized use . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

9
9
9
9

Commissioning. . . . . . . . . . . . . . . . . . . . . . . . . . . 10

3.1

Scope of delivery . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10

3.2

Power supply . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10

3.3 Initial commissioning . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

3.3.1
Inserting the batteries . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
3.3.2
Connecting the power pack. . . . . . . . . . . . . . . . . . . . . . . . . . .
3.3.3
Mounting the stand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

10
10
11
12

Operation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13

4.1 General operating principles . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13

4.1.1
Keypad . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
4.1.2
Display . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14

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pH 7110

4.1.3
4.1.4

Status information . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14
Socket field . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15

4.2

Switching on the meter. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15

4.3

Switching off the meter. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15

4.4 Navigation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
4.4.1
Operating modes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
4.4.2
Measuring mode (measured value display) . . . . . . . . . . . . . .
4.4.3
Setting mode . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

16
16
16
16

pH value . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18

5.1 Measuring. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18
5.1.1
Measuring the pH value . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18
5.1.2
Measuring the temperature . . . . . . . . . . . . . . . . . . . . . . . . . . 19
5.2 Calibration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
5.2.1
Why calibrate? . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
5.2.2
When to calibrate? . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
5.2.3
Automatic calibration (AutoCal) . . . . . . . . . . . . . . . . . . . . . . .
5.2.4
Manual calibration (ConCal) . . . . . . . . . . . . . . . . . . . . . . . . .
5.2.5
Calibration points . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
5.2.6
Calibration data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

19
19
20
20
22
24
24

ORP . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27

6.1 Measuring. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27
6.1.1
Measuring the ORP . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27
6.1.2
Measuring the temperature . . . . . . . . . . . . . . . . . . . . . . . . . . 27
6.2

Calibration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28

Settings . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 29

7.1 Measurement settings (pH) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

7.1.1
Changing the settings for pH measurements. . . . . . . . . . . . .
7.1.2
Buffer sets for calibration . . . . . . . . . . . . . . . . . . . . . . . . . . . .
7.1.3
Calibration interval . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

29
29
30
31

7.2 Measurement settings (ORP). . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31

7.2.1
Changing the settings for ORP measurements . . . . . . . . . . . 31

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Contents

7.3 Sensor-independent settings . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32

7.3.1
Changing the sensor-independent settings . . . . . . . . . . . . . . 32
7.3.2
Energy saving (battery operation) . . . . . . . . . . . . . . . . . . . . . 32

Reset . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34

8.1

Resetting the calibration values . . . . . . . . . . . . . . . . . . . . . . . . . . . 34

8.2

Resetting the measurement and system settings . . . . . . . . . . . . . 34

Maintenance, cleaning, disposal . . . . . . . . . . . . . 36

9.1 Maintenance. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36
9.1.1
General maintenance activities . . . . . . . . . . . . . . . . . . . . . . . 36
9.1.2
Replacing the batteries . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36
9.2

Cleaning . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37

9.3

Packing. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37

9.4

Disposal . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37

10

What to do if... . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38

10.1 pH. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
10.1.1 No stable measured value . . . . . . . . . . . . . . . . . . . . . . . . . . .
10.1.2 Error message CalError . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
10.1.3 Error message OFL, UFL. . . . . . . . . . . . . . . . . . . . . . . . . . . .

38
38
38
39

10.2 ORP . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39
10.2.1 No stable measured value . . . . . . . . . . . . . . . . . . . . . . . . . . . 39
10.2.2 Error message OFL, UFL. . . . . . . . . . . . . . . . . . . . . . . . . . . . 40
10.3 General information . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
10.3.1 Symbol for calibration evaluation flashes. . . . . . . . . . . . . . . .
10.3.2 [LoBat] display . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
10.3.3 Instrument does not react to keystroke . . . . . . . . . . . . . . . . .
10.3.4 Displaying the software version (meter). . . . . . . . . . . . . . . . .

11

40
40
40
41
41

Technical data . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42

11.1 Measuring ranges, resolution, accuracy. . . . . . . . . . . . . . . . . . . . . 42

11.1.1 Measuring ranges, resolution. . . . . . . . . . . . . . . . . . . . . . . . . 42
11.1.2 Manual temperature input . . . . . . . . . . . . . . . . . . . . . . . . . . . 42

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pH 7110

11.1.3

Accuracy ( 1 digit) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 43

11.2 General data. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 43

12

Glossary. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 46

12.1 pH/ORP . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 46
12.2 General information . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47

13

Index. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49

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pH 7110

Overview

Overview
1.1

pH 7110 meter

The pH 7110 compact digital precision meter enables you to perform pH and
ORP measurements quickly and reliably.
The pH 7110 provides the maximum degree of operating comfort, reliability and
measuring certainty for all applications.

1 Keypad
2 Display
3 Socket field

1.2

Sensors

A measuring system ready to measure consists of the pH 7110 meter and a

suitable sensor.
The pH 7110 can be operated with the following sensors:
pH electrode
ORP electrode
Information on available sensors is given on the Internet and in the
WTW catalog, "Laboratory and field instrumentation".

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Safety

pH 7110

Safety
2.1

Safety information

2.1.1

Safety information in the operating manual

This operating manual provides important information on the safe operation of

the meter. Read this operating manual thoroughly and make yourself familiar
with the meter before putting it into operation or working with it. The operating
manual must be kept in the vicinity of the meter so you can always find the information you need.
Important safety instructions are highlighted in this operating manual. They are
indicated by the warning symbol (triangle) in the left column. The signal word
(e.g. "CAUTION") indicates the level of danger:

WARNING
indicates a possibly dangerous situation that can lead to
serious (irreversible) injury or death if the safety instruction is
not followed.

CAUTION
indicates a possibly dangerous situation that can lead to
slight (reversible) injury if the safety instruction is not
followed.
NOTE
indicates a possibly dangerous situation where goods might be damaged
if the actions mentioned are not taken.

2.1.2

Safety signs on the meter

Note all labels, information signs and safety symbols on the meter and in the
battery compartment. A warning symbol (triangle) without text refers to safety
information in this operating manual.

2.1.3

Further documents providing safety information

The following documents provide additional information, which you should

observe for your safety when working with the measuring system:
Operating manuals of sensors and other accessories
Safety datasheets of calibration or maintenance accessories (such as buffer
solutions, electrolyte solutions, etc.)

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Safety

2.2

Safe operation

2.2.1

Authorized use

This meter is authorized exclusively for pH and ORP measurements in the

laboratory.
Only the operation and running of the meter according to the instructions and
technical specifications given in this operating manual is authorized (see
section 11 TECHNICAL DATA, page 42).
Any other use is considered unauthorized.

2.2.2

Requirements for safe operation

Note the following points for safe operation:

The meter may only be operated according to the authorized use specified
above.
The meter may only be supplied with power by the energy sources
mentioned in this operating manual.
The meter may only be operated under the environmental conditions
mentioned in this operating manual.
The meter may only be opened if this is explicitly described in this operating
manual (example: Inserting the batteries).

2.2.3

Unauthorized use

The meter must not be put into operation if:

it is visibly damaged (e.g. after being transported)
it was stored under adverse conditions for a lengthy period of time (storing
conditions, see section 11 TECHNICAL DATA, page 42).

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Commissioning

pH 7110

Commissioning
3.1

Scope of delivery

pH 7110 meter
4 batteries 1.5 V Mignon type AA
Power pack
Stand
Stand holder
Short instructions
Detailed operating manual (4 languages)
CD-ROM with detailed operating manual

3.2

Power supply

The pH 7110 is supplied with power in the following ways:

Mains operation with the supplied power pack.
Battery operation (4 x alkaline manganese batteries, type AA)

3.3

Initial commissioning

Perform the following activities:

Insert the supplied batteries

Connect the power pack (mains operation)
Mount the stand
Switch on the meter
(see section 4.2 SWITCHING ON THE METER, page 15)

3.3.1

Inserting the batteries

You can operate the meter either with normal batteries or with
rechargeable batteries (Ni-MH).
In order to charge the batteries, an external charging device is
required.

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Commissioning

1.

Open the battery compartment (2) on the underside of the meter.

2.

2
Insert four batteries in the battery compartment.
CAUTION
Make sure that the poles of the batteries are positioned
correctly.
The signs on the batteries must correspond to the signs
in the battery compartment.

3.

Close the battery compartment tightly.

When the batteries are nearly empty, the [LoBat] status indicator is
displayed.

3.3.2

Connecting the power pack

CAUTION
The line voltage at the operating site must lie within the input
voltage range of the original power pack (see section 11 TECHNICAL DATA, page 42).

CAUTION
Use original power packs only (see section 11 TECHNICAL DATA,
page 42).

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1.

Connect the plug of the power pack to the socket for the power pack on
the pH 7110.

2.

Connect the original power pack to an easily accessible power outlet.

11

Commissioning

pH 7110

3.3.3

Mounting the stand

The stand base can be mounted at the right side of the meter.

12

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pH 7110

Operation

Operation
4.1

General operating principles

This section contains basic information on the operation of the pH 7110.

4.1.1

Keypad

In this operating manual, keys are indicated by brackets <..> .

The key symbol (e.g. <ENTER>) generally indicates a short keystroke (under
2 sec) in this operating manual. A long keystroke (approx. 2 sec) is indicated
by the underscore behind the key symbol (e.g. <ENTER__>).

Key

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Symbol

Meaning

<On/Off>
<On/Off__>

Switches the meter on or off

Resets calibration data

<M>
<M__>

Selects the measured parameter

Opens the measurement settings

<CAL>
<CAL__>

Calls up the calibration procedure

Displays the calibration data

<><>
<__><__>

Increments, decrements values

Increments, decrements values continuously

<ENTER>
<ENTER__>

Confirms entries
Opens the menu for system settings

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Operation

pH 7110

4.1.2

Display

UpH
2

1 8 8 8 8F

mV/pH
%

8 8 8 8 C

Time

LoBat

AutoCal DIN

5
TP

CalError

AutoCal TEC ConCal

AR

1 Status information
2 Measured value (with unit)
3 Measured parameter
4 Sensor symbol (calibration evaluation, calibration interval)
5 Measured temperature (with unit)

4.1.3

14

Status information

Display

Meaning

[AutoCal TEC]
[AutoCal DIN]

Calibration with automatic buffer recognition, e.g. with the

buffer set: Technical buffers

[ConCal]

Calibration with any buffers

[CalError]

An error occurred during calibration

[AR]

Stability control (AutoRead) is active

[TP]

Temperature measurement active

[Time]

Setting of calibration interval

[LoBat]

Batteries are almost empty

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Operation

4.1.4

Socket field

1 pH electrode
2 Reference electrode
3 Temperature sensor
4 Power pack
5 Service interface

4.2

Switching on the meter

1.

Switch on the meter with <On/Off>.

The meter performs a self-test.
The meter switches to the measuring mode (measured value display).

2.

Connect the sensor.

The meter is ready to measure.

pH

6992
248

TP

C
AR

4.3
1.

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Switching off the meter

Switch off the meter with <On/Off>.
The meter is switched off.

15

Operation

pH 7110

When the meter is powered by the batteries, it switches itself off

automatically after an adjustable interval to save the batteries (see
section Automatic switch-off function, page 32).

4.4

Navigation

4.4.1

Operating modes

The meter has the following operating modes:

Operating mode

Description

Measuring

The measurement data of the connected sensor are

shown in the measured value display

Calibration

The course of a calibration with calibration information, functions and settings is displayed

Transmitting data

The meter transmits measuring data and calibration

records to a USB-B interface automatically or manually.

Setting

A setting is displayed.

4.4.2

Measuring mode (measured value display)

The following functions are available in the measuring mode (measured value
display):
Change the display in the selected measuring window (e. g. pH <-> mV) by
pressing <M>
To open the measurement settings, press <M__> (long pressure).
To open the system settings, press <ENTER__> (long pressure).

4.4.3

Setting mode

The following functions are available in the setting mode:

To change the current setting, press <><>.
Confirm the setting with <ENTER>.
The next setting is displayed.
The settings are stored.

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Operation

When the last setting is confirmed, the setting menu is automatically quit.
Press <M> to exit the setting mode.

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pH value

pH 7110

pH value
5.1

Measuring

5.1.1

Measuring the pH value

To ensure the high measurement accuracy of the measuring system, always measure with A current calibration (see section 5.2
CALIBRATION, page 19).
1.

Connect the pH electrode to the meter.

2.

When measuring without temperature sensor: Temper the test sample or

measure the current temperature.

3.

If necessary, select the measured parameter (pH) with <M>.

4.

Immerse the pH electrode in the test sample.

The measured value is checked for stability (stability control).
The [AR] status display flashes.

pH

6992
248

TP

C
AR

5.

When measuring without temperature sensor: Enter the temperature of

the buffer with <><>.

6.

Wait for a stable measured value.

The [AR] display indicator no longer flashes.

Stability control (AutoRead )

During the measuring procedure, the stability control function is automatically
activated.
The stability control function (AutoRead) continually checks the stability of the
measured values in the monitored time interval. The stability has a considerable impact on the reproducibility of measured values. The [AR] display indicator flashes until a stable value is measured.

18

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pH 7110

pH value

Stability criteria (AutoRead )

Measured parameter

Time interval

Stability in the time interval

pH value

15 seconds

pH: Better than 0.02

Temperature

15 seconds

T ( C): Better than 0.3

The minimum duration until a measured value is assessed as stable is the

monitored time interval. The actual duration is mostly longer.

5.1.2

Measuring the temperature

For reproducible pH measurements, it is essential to measure the temperature

of the test sample.
You have the following options to measure the temperature:
Automatic measurement of the temperature with the temperature sensor
(NTC30 or Pt1000) integrated in the sensor.
Measurement with an external temperature sensor.
Manual determination and input of the temperature.
The measuring instrument recognizes whether a suitable sensor is connected
and automatically switches on the temperature measurement.
Which type of temperature measurement is active is indicated by the temperature display and the [TP] status indicator:

Temperature
sensor

Resolution
of the temp.
display

Status
indicator

yes

0.1 C

[TP]

Automatic with temperature

sensor

1 C

Manual

Temp. measurement

If you wish to measure (or calibrate) without temperature sensor, proceed as

follows:
1.

Measure the current temperature of the test sample.

2.

Set the temperature value with <><>.

5.2

Calibration

5.2.1

Why calibrate?

When a pH electrode is operated, its zero point (asymmetry) and slope change
with the course of time. As a result, an inexact measured value is displayed.
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19

pH value

pH 7110

Calibration determines and stores the current values of the zero point and
slope. Thus, you should calibrate at regular intervals.

5.2.2

When to calibrate?

When the calibration interval has expired

Routinely within the framework of the company quality assurance
After connecting another combination electrode

5.2.3

Automatic calibration (AutoCal)

Use any one to three buffer solutions of a buffer set (technical buffers or DIN
buffers) in ascending or descending order.
Below, calibration with Technical buffers (TEC) is described. When other buffer
sets are used, other nominal buffer values are displayed. Apart from that, the
procedure is identical.
1.

Start the calibration with <CAL>.

The calibration display for the first buffer appears.

2.

When measuring without temperature sensor: Temper the buffer or

measure the current temperature.

3.

If necessary, press <CAL> to select the buffer set used ([AutoCal TEC],
[AutoCal DIN]).
Ct1 or Cd1 is displayed.

pH

CT1

2 4 8 C

TP

AutoCal TEC

20

4.

Thoroughly rinse the pH electrode with deionized water.

5.

Immerse the pH electrode in the first buffer solution.

6.

When measuring without temperature sensor: Enter the temperature of

the buffer with <><>.

7.

Start the measurement with <ENTER> .

The measured value is checked for stability (stability control).
The [AR] status display flashes.
The electrode voltage (mV) or the nominal value of the buffer is displayed
(setting: see section 7.1.1 CHANGING THE SETTINGS FOR PH MEASUREMENTS, page 29).

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pH value

8.

Wait for the measurement with stability control to be completed or terminate the stability control with <ENTER>.
The calibration display for the next buffer appears.
Ct2 or Cd2 is displayed.

pH

CT2

2 4 8 C

TP

AutoCal TEC

9.

If necessary, finish the calibration procedure as a single-point calibration

with <M>.
The calibration record is displayed.
For single-point calibration, the instrument uses the Nernst
slope (-59.2 mV/pH at 25 C) and determines the zero point
of the pH electrode.
or
Continue calibration using the next buffer with <ENTER>.
Continuing with two-point calibration

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10.

Thoroughly rinse the pH electrode with deionized water.

11.

Immerse the pH electrode in the second buffer solution.

12.

When measuring without temperature sensor: Enter the temperature of

the buffer with <><>.

13.

Start the measurement with <ENTER> .

The measured value is checked for stability (stability control).
The [AR] status display flashes.
The electrode voltage (mV) or the nominal value of the buffer is displayed
(setting: see section 7.1.1 CHANGING THE SETTINGS FOR PH MEASUREMENTS, page 29).

14.

Wait for the measurement with stability control to be completed or terminate the stability control and take over the calibration value with
<ENTER>.
The calibration display for the next buffer appears.
Ct3 or Cd3 is displayed.

21

pH value

pH 7110

pH

CT3

2 4 8 C

TP

AutoCal TEC

15.

If necessary, finish the calibration procedure as a two-point calibration

with <M>.
The calibration record is displayed.
or
Continue calibration using the next buffer with <ENTER>.
Continuing with three-point calibration

16.

Thoroughly rinse the pH electrode with deionized water.

17.

Immerse the pH electrode in the third buffer solution.

18.

When measuring without temperature sensor: Enter the temperature of

the buffer with <><>.

19.

Start the measurement with <ENTER> .

The measured value is checked for stability (stability control).
The [AR] status display flashes.
The electrode voltage (mV) or the nominal value of the buffer (setting: see
section 7.1.1 CHANGING THE SETTINGS FOR PH MEASUREMENTS, page 29).

20.

Wait for the measurement with stability control to be completed or terminate the stability control and take over the calibration value with
<ENTER>.
The calibration record is displayed.

5.2.4

Manual calibration (ConCal)

Use any buffer solution for the single-point calibration. The calibration will be
the more accurate the nearer the pH value of the buffer solution is to that of the
test sample.
Use the following buffer solutions for two-point calibration:
one buffer solution with pH 7.0 0.5
any other buffer solution

22

1.

Start the calibration with <CAL>.

The calibration display for the first buffer appears.

2.

When measuring without temperature sensor: Temper the buffer or

measure the current temperature.

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pH 7110

pH value

3.

If necessary, press <CAL> to select the buffer set ([ConCal]).

ASY is displayed.

ASY
248

TP

ConCal

4.

Thoroughly rinse the pH electrode with deionized water.

5.

Immerse the pH electrode in the first buffer solution (pH 7.0 0.5 for
two-point calibration).

6.

When measuring without temperature sensor: Enter the temperature of

the buffer with <><>.

7.

Start the measurement with <ENTER> .

The pH value of the buffer solution is displayed.
The measured value is checked for stability (stability control).
The [AR] status display flashes.

8.

Wait for the measurement with stability control to be completed.

9.

Set the nominal pH value of the buffer solution with <><>.

10.

Accept the calibration value with <ENTER>.

SLO is displayed.

sL O
248

TP

ConCal

11.

If necessary, finish the calibration procedure as a single-point calibration

with <M>.
The calibration record is displayed.
or
Continue calibration using the next buffer with <ENTER>.
Continuing with two-point calibration

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12.

Thoroughly rinse the pH electrode with deionized water.

13.

Immerse the pH electrode in the second buffer solution.

23

pH value

pH 7110

14.

When measuring without temperature sensor: Enter the temperature of

the buffer with <><>.

15.

Start the measurement with <ENTER> .

The pH value of the buffer solution is displayed.
The measured value is checked for stability (stability control).
The [AR] status display flashes.

16.

Wait for the measurement with stability control to be completed.

17.

Set the nominal pH value of the buffer solution with <><>.

18.

Accept the calibration value with <ENTER>.

The calibration record is displayed.

5.2.5

Calibration points

Depending on the number of buffer solutions used, the meter determines the
following values and calculates the calibration line:

Calibration

Values determined

1-point

Asy

Displayed calibration data

Zero point = Asy
Slope = Nernst slope
(-59.2 mV/pH at 25 C)

2-point

Asy
Slo

Zero point = Asy

Slope = Slo
The calibration line goes through both calibration points.

3-point

Asy
Slo

Zero point = Asy

Slope = Slo
The calibration line is calculated by linear
regression.

You can display the slope in the units, mV/pH or % (see section
5.2.6 CALIBRATION DATA, page 24).

5.2.6

Calibration data

Displaying the calibration data

1.

24

Display the calibration data in the measured value display with <CAL__>.
The value for the asymmetry (ASY) is displayed.

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pH 7110

pH value

02

mV

ASy
ConCal

While the zero point is being displayed (ASY) you can switch over the unit
of the zero point with <><>.
2.

Press <ENTER> to display further calibration data.

The value for the slope (SLO) is displayed.

- 592

mV/pH

SL O
ConCal

While the slope is being displayed (SLO) you can switch over the unit of
the slope with <><>.
Calibration evaluation (pH)
After calibrating, the meter automatically evaluates the calibration. The zero
point and slope are evaluated separately. The worse evaluation of both is taken
into account. The evaluation appears on the display.

Display

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Zero point [mV]

Slope [mV/pH]

-15 ... +15

-60.5 ... -58.0

-20 ... <-15

or
>+15 ... +20

>-58.0 ... -57.0

-25 ... <-20

or
>+20 ... +25

-61.0 ... <-60.5

or
>-57.0 ... -56.0
25

pH value

pH 7110

Display

[CalError]

Zero point [mV]

Slope [mV/pH]

-30 ... <-25

or
->+25 ... +30

-62.0 ... <-61.0

or
>-56.0 ... -50.0

<-30
or
>+30

<-62.0
or
> -50.0

(see section 10 WHAT TO DO IF..., page 38)

26

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pH 7110

ORP

ORP
6.1

Measuring

6.1.1

Measuring the ORP

1.

Connect the ORP electrode to the meter.

2.

If necessary, call up the measured parameter U with <M>.

3.

Immerse the ORP electrode in the test sample.

The measured value is checked for stability (stability control).
The [AR] status display flashes.

4.

Wait for a stable measured value.

The [AR] display indicator no longer flashes.

4 8 63
213

mV

TP

C
AR

Stability control (AutoRead )

During the measuring procedure, the stability control function is automatically
activated.
The stability control function (AutoRead) continually checks the stability of the
measured values in the monitored time interval. The stability has a considerable impact on the reproducibility of measured values. The [AR] display indicator flashes until a stable value is measured.
Stability criteria (AutoRead )

Measured parameter

Time interval

ORP

15 seconds

6.1.2

Stability in the time interval

mV: Better than 0.3

Measuring the temperature

The temperature measurement is absolutely essential for a reproducible ORP

measurement.

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27

ORP

pH 7110

You have the following options to measure the temperature:

Measurement with an external temperature sensor.
Manual determination and input of the temperature.
The measuring instrument recognizes whether a suitable sensor is connected
and automatically switches on the temperature measurement.
Which type of temperature measurement is active is indicated by the temperature display and the [TP] status indicator:

Temperature
sensor

Resolution of the
temp. display

Temp. measurement

yes

0.1

Automatic with temperature sensor

1 C

Manual

If the measurement is made without a temperature sensor, proceed as follows:

1.

Measure the current temperature of the test sample.

2.

Set the temperature value with <><>.

6.2

Calibration

ORP electrodes are not calibrated. You can, however, check ORP electrodes
using a test solution.

28

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pH 7110

Settings

Settings
The meter has separate setting routines for the measurement settings and
system settings.

7.1

Measurement settings (pH)

7.1.1

Changing the settings for pH measurements

1.

Open the setting menu in the measured value display with <M__>.
The first setting is displayed.

2.

If necessary, indicate the required setting with <ENTER>.

3.

To change the current setting, press <><>.

4.

Confirm the setting with <ENTER>.

The next setting is displayed.

5.

Change or confirm the other settings.

When the last setting is confirmed, the setting menu is automatically quit.

or
Quit the setting menu with <M>.
The settings are stored.
Settings for pH measurements
Default settings are printed in bold.
The settings appear in the following order:

Displayed
(Confirm with
<ENTER>)

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Possible setting
(Change with
<><>)

Description

pH bUFF

pH
U

Display during calibration

Nominal buffer value (pH) or
Electrode voltage (U)

pH SLO

mV/pH
%

Unit of the value for the slope

pH ASY

mV
pH

Unit of the value for the zero point

29

Settings

pH 7110

Displayed
(Confirm with
<ENTER>)

Possible setting
(Change with
<><>)

Description

pH rES

0.000
0.00
0.0

Resolution of pH display

Unit

C
F

Temperature unit

Int.C

1 ... 7... 999 d

Calibration interval

7.1.2

Buffer sets for calibration

You can use the buffer sets quoted in the table for an automatic calibration. The
pH values are valid for the specified temperature values. The temperature
dependence of the pH values is taken into account during the calibration.

The buffer set is selected during calibration (see section 5.2.3

AUTOMATIC CALIBRATION (AUTOCAL), page 20).

No.

Buffer set

pH values

at

TEC
WTW Technical buffers

2.000
4.010
7.000
10.011

25 C

NIST/DIN
DIN buffers according to DIN 19266
and NIST Traceable Buffers

1.679
4.006
6.865
9.180
12.454

25 C

ConCal

1-point
cal.:
Any

any,
adjustable

2-point
cal.:
7.0 0.5
Any

30

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pH 7110

Settings

7.1.3

Calibration interval

The calibration interval is set with the measurement settings (see

section 7.1 MEASUREMENT SETTINGS (PH), page 29).
The calibration evaluation is displayed as a sensor symbol.
The sensor symbol flashes after the adjusted calibration interval has expired.
It is still possible to measure.

To ensure the high measuring accuracy of the measuring system,

calibrate after the calibration interval has expired.

7.2

Measurement settings (ORP)

7.2.1

Changing the settings for ORP measurements

1.

Open the setting menu in the measured value display with <M__>.
The first setting is displayed.

2.

Indicate the required setting with <ENTER>.

3.

To change the current setting, press <><>.

4.

Confirm the setting with <ENTER>.

The next setting is displayed.

5.

Change or confirm the other settings.

When the last setting is confirmed, the setting menu is automatically quit.

or
Quit the setting menu with <M>.
The settings are stored.
List of the settings for ORP measurements
The settings for ORP measurements are in the same setting routine as the
settings for pH measurements.
Default settings are printed in bold.

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31

Settings

pH 7110

Displayed
(Confirm with
<ENTER>)

Possible setting
(Change with
<><>)

Description

U rES

0.0
0

Resolution of the voltage display

Unit

C
F

Temperature unit

7.3

Sensor-independent settings

7.3.1

Changing the sensor-independent settings

1.

Open the menu for the sensor-independent settings with <ENTER__>.

The first setting is displayed.

2.

To change the current setting, press <><>.

3.

Confirm the setting with <ENTER>.

The settings are finished.
The meter switches to the measuring mode.

List of sensor-independent settings

Default settings are printed in bold.

Displayed
(Confirm with
<ENTER>)

10, 20, 30, 40, 50 min,

1, 2, 3, 4, 5, 10, 15, 20, 24 h

t.Off

7.3.2

Possible setting
(Change with
<><>)

Description
Switch-off interval (see section Automatic switch-off
function, page 32)

Energy saving (battery operation)

Automatic switch-off function

The meter has an automatic switch-off function to avoid unnecessary power
consumption during battery operation.
The energy saving feature switches off the meter during battery operation if no
key is pressed during the adjusted interval.
The automatic switch-off function is not active when the power pack is
connected.

32

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pH 7110

Settings

The switch-off interval is set with the system settings (see section 7.3
SENSOR-INDEPENDENT SETTINGS, page 32).

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33

Reset

pH 7110

Reset
You can erase the calibration values and reset (initialize) the measurement and
system settings.

8.1

Resetting the calibration values

1.

Press <On/Off__> to open the menu for the reset of the calibration data.
InIt.C is displayed.

2.

Use <><> to display no or YES.

3.

YES: Reset the calibration values

no: Retain the calibration values.

Confirm with <ENTER>.

The menu is finished. The meter switches to the measuring mode.
The calibration values are reset to default. All other meter
settings are retained.
Recalibrate after performing a reset.

Calibration values to be reset

Calibration value
Zero point (ASY )

0 mV (pH 7.000)

Slope (SLO )

-59.16 mV/pH (100 %)

8.2

Resetting the measurement and system settings

1.

Switch on the meter with <On/Off>.

The display test appears briefly on the display.

2.

During the display test, press <M> to open the menu for the reset of the
meter settings.
Init is displayed.

3.

Use <><> to display no or YES.

4.

34

Default settings

YES: Reset the meter settings.

no: Retain the meter settings.

Confirm with <ENTER>.

The settings are reset. The menu is finished.
The meter switches to the measuring mode.

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pH 7110

Reset

The following settings are reset to the delivery condition (default):

Measurement settings
System settings
Calibration data
Recalibrate after performing a reset.
Measurement and system settings that can be reset

Measurement settings

Default

Display during calibration (bUFF )

pH (nominal buffer value)

Unit of the value for the slope (SLO )

mV/pH

Unit of the value for the zero point

(ASY )

mV

Measured value resolution (pH rES)

0.000

Measured value resolution (U rES)

0.0

Unit of the measured temperature

value (Unit )

Calibration interval (Int.C )

7d

System settings
Switch-off interval (t.Off )

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Default
1h

35

Maintenance, cleaning, disposal

pH 7110

Maintenance, cleaning, disposal

9.1

Maintenance

9.1.1

General maintenance activities

The only maintenance activity required is replacing the batteries.

See the relevant operating manuals of the sensors for instructions

on maintenance.

9.1.2

Replacing the batteries

You can operate the meter either with normal batteries or with
rechargeable batteries (Ni-MH).
In order to charge the batteries, an external charging device is
required.
1.

Open the battery compartment (2) on the underside of the meter.

2.

2
Remove the old batteries.

3.

Place four batteries (type AA) in the battery compartment.

CAUTION
Make sure that the poles of the batteries are positioned
correctly.
The signs on the batteries must correspond to the signs in
the battery compartment.

36

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pH 7110

Maintenance, cleaning, disposal

4.

Close the battery compartment tightly.

When the batteries are nearly empty, the [LoBat] status indicator is
displayed.

Dispose of used batteries according to the local regulations of

your country.
End users within the European Union are obligated to return used
batteries (even ecologically compatible ones) to a collection point
set up for recycling purposes.
Batteries are marked with the crossed-out waste container
symbol. Therefore, they may not be disposed with the domestic
waste.

9.2

Cleaning

Occasionally wipe the outside of the measuring instrument with a damp,

lint-free cloth. Disinfect the housing with isopropanol as required.

CAUTION
The housing is made of synthetic material (ABS). Thus, avoid
contact with acetone or similar detergents that contain
solvents. Remove any splashes immediately.

9.3

Packing

This meter is sent out in a protective transport packing.

We recommend: Keep the packing material. The original packing protects the
meter against damage during transport.

9.4

Disposal

At the end of its operational lifetime, the meter must be returned to the
disposal or return system statutory in your country. If you have any questions,
please contact your supplier.

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37

What to do if...

10

pH 7110

What to do if...
10.1

pH

More information and instructions on cleaning and exchange of

sensors are given in the documentation of your sensor.

10.1.1

No stable measured value

Cause
Junction of the electrode contaminated

Clean the junction

Glass membrane of the electrode

contaminated

Clean the glass membrane

Cause

Remedy

pH value of the test sample not

stable

Measure with air excluded if

necessary

Temperature of the test sample

not stable

Adjust temperature if necessary

10.1.2

Error message CalError

Cause

38

Remedy

Remedy

The values determined for zero

point and slope of the electrode
are outside the allowed limits.

Recalibrate

Junction contaminated

Clean the junction

pH electrode broken

Replace the pH electrode

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pH 7110

What to do if...

Cause
The used buffer solutions do not
agree with the set buffer set

Remedy
Set different buffer set
or
Use different buffer solutions

Buffer solutions too old

Use only once.

Note the shelf life

Buffer solutions depleted

10.1.3

Change solutions

Error message OFL, UFL

The measured value is outside the measuring range.

The measured value is obviously incorrect.

Cause

Remedy

Cable broken

Replace the electrode

Gel electrolyte dried out

Replace the electrode

Air bubble in front of the junction

Remove the air bubble

Air in the junction

Extract air or moisten the junction

10.2

ORP

More information and instructions on cleaning and exchange of

sensors are given in the documentation of your sensor.

10.2.1

No stable measured value

Cause

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Remedy

Junction contaminated

Clean the junction

Pt-ORP electrode contaminated

Clean the Pt-ORP electrode

39

What to do if...

pH 7110

Cause

Remedy

ORP value not stable

Measure with air excluded if

necessary

Temperature not stable

Adjust temperature if necessary

10.2.2

Error message OFL, UFL

The measured value is outside the measuring range of the meter.

The measured value is obviously incorrect.

Cause
Cable broken

Replace the electrode

Gel electrolyte dried out

Replace the electrode

Air bubble in front of the junction

Remove the air bubble

Air in the junction

Extract air or moisten the junction

10.3

General information

10.3.1

Symbol for calibration evaluation flashes

Cause
Calibration interval expired

10.3.2

Remedy
Recalibrate the measuring system

[LoBat] display

Cause
Batteries almost empty

40

Remedy

Remedy
Replace the batteries (see section
3.3.1 INSERTING THE BATTERIES,
page 10)

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pH 7110

What to do if...

10.3.3

Instrument does not react to keystroke

Cause
Operating condition undefined or
EMC load unallowed

10.3.4

E. g., a question by the service

department

12/2011

Processor reset:
Press the <ENTER> and
<On/Off> key simultaneously

Displaying the software version (meter)

Cause

ba75925e02

Remedy

Remedy
Switch on the meter.
During the display test, display
the software version with
<ENTER>.

41

Technical data

11

pH 7110

Technical data
11.1

Measuring ranges, resolution, accuracy

11.1.1

Measuring ranges, resolution

Parameter

Resolution

pH

- 2.0 ... + 20.0

- 2.00 ... + 20.00
- 2.000 ... + 19.999

0.1
0.01
0.001

U [mV]

- 1200.0 ... + 1200.0

- 2000 ... + 2000

0.1
1

T [C]

- 5.0 ... + 105.0

0.1

T [F]

+ 23.0 ... + 221.0

0.1

11.1.2

Manual temperature input

Parameter

42

Measuring range

Range

Increment

Tmanual [C]

- 25 ... + 130

Tmanual [F]

-13 ... + 266

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pH 7110

Technical data

11.1.3

Accuracy ( 1 digit)

Parameter

Temperature of the
test sample

Accuracy

pH / range *
- 2.0 ... + 20.0
- 2.00 ... + 20.00
- 2.000 ... + 19.999

0.1
0.01
0.005

+ 15 C ... + 35 C
+ 15 C ... + 35 C
+ 15 C ... + 35 C

U [mV] / range
- 2000 ... + 2000
-1200.0 ... +1200.0

1
0.3

+ 15 C ... + 35 C
+ 15 C ... + 35 C

T [C] / temperature sensor

NTC 30
PT 1000

0.1
0.1

* when measuring in a range of 2 pH around a calibration point

11.2

General data

Dimensions

Approx. 240 x 190 x 80 mm

Weight

Approx. 1.0 kg

Mechanical
structure

Type of protection IP 43

Electrical
safety

Protective class III

Test certificates

CE, cETLus

Ambient
conditions

Storing: - 25 C ... + 65 C
Operation: +5 C ... + 55 C
With the power pack connected:
+5 C ... + 40 C
Allowable relative humidity
Yearly mean: < 75 %
30 days/year: 95 %
Other days: 85 %

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43

Technical data

pH 7110

Power supply

Batteries: 4 x 1.5 V alkali-manganese batteries, type

AA
Operating time: Approx. 2500 h (operating hours)
Rechargeable batteries: 4 x 1.2 V NiMH rechargeable
batteries, type AA
(no charging function)
Power pack: Ktec KSAC 0900110W1UV-1
Input: 100 ... 240 V ~ / 50 ... 60 Hz / 270 mA
Output: 9 V = / 1.1 A
Connection max. Overvoltage category II
Primary plugs included in the scope of delivery: Euro,
US, UK and Australian.

Sensor input

Input resistance: > 5 * 1013 ohm

Input current: < 1 * 10-12 A

Service interface

This interface can be used for service purposes only.

Applicable
directives and
standards

EMC:
EC directive 2004/108/EC
EN 61326-1
EN 61000-3-2
EN 61000-3-3
FCC Class A
Instrument safety:
EC directive 2006/95/EC
EN 61010-1
ANSI/UL 61010-1
CAN/CSA-C22.2 No. 61010-1
IP type of protection:
EN 60529

44

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pH 7110

Technical data

FCC Class A Equipment Statement

Note: This equipment has been tested and found to comply with the limits
for a Class A digital device, pursuant to Part 15 of the FCC Rules. These
limits are designed to provide reasonable protection against harmful
interference when the equipment is operated in a commercial
environment. This equipment generates, uses, and can radiate radio
frequency energy and, if not installed and used in accordance with the
instruction manual, may cause harmful interference to radio
communications. Operation of this equipment in a residential area is likely
to cause harmful interference in which case the user will be required to
correct the interference at his own expense.
Changes or modifications not expressly approved by the manufacturer
could void the users authority to operate the equipment.

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45

Glossary

12

pH 7110

Glossary
12.1

pH/ORP

Specialist
term

46

Description

Asymmetry

see zero point

Diaphragm

The junction is a porous body in the housing wall of reference electrodes or electrolyte bridges. It arranges the
electrical contact between two solutions and makes the
electrolyte exchange more difficult. The expression, junction, is also used for ground or junction-less transitions.

Electromotive
force of an
electrode

The electromotive force U of the combination electrode is

the measurable electromotive force of an electrode in a
solution. It equals the sum of all the galvanic voltages of
the electrode. Its dependency on the pH results in the
electrode function, which is characterized by the parameters, slope and zero point.

ORP

The ORP is caused by oxidizing or reducing substances

dissolved in water if these substances become effective
on an electrode surface (e. g. a gold or platinum surface).

pH value

The pH value is a measure of the acidic or basic effect of

an aqueous solution. It corresponds to the negative
decadic logarithm of the molal hydrogen ions activity
divided by the unit of the molality. The practical pH value is
the value of a pH measurement.

Slope

The slope of a linear calibration function.

Zero point

The zero point of a pH combination electrode is the pH

value at which the electromotive force of the pH combination electrode at a specified temperature is zero. Normally,
this is at 25 C.

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pH 7110

Glossary

12.2

General information

Specialist term

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Description

Adjusting

To manipulate a measuring system so that the relevant

value (e. g. the displayed value) differs as little as possible from the correct value or a value that is regarded
as correct, or that the difference remains within the
tolerance.

AutoRange

Name of the automatic selection of the measuring

range.

Calibration

Comparing the value from a measuring system (e. g.

the displayed value) to the correct value or a value that
is regarded as correct. Often, this expression is also
used when the measuring system is adjusted at the
same time (see adjusting).

Measured parameter

The measured parameter is the physical dimension

determined by measuring, e. g. pH, conductivity or
D.O. concentration.

Measured value

The measured value is the special value of a measured

parameter to be determined. It is given as a combination of the numerical value and unit (e. g. 3 m; 0.5 s;
5.2 A; 373.15 K).

Molality

Molality is the quantity (in Mol) of a dissolved substance in 1000 g solvent.

Potentiometry

Name of a measuring technique. The signal (depending on the measured parameter) of the electrode is the
electrical potential. The electrical current remains constant.

Reset

Restoring the original condition of all settings of a measuring system.

Resolution

Smallest difference between two measured values that

can be displayed by a meter.

Stability control
(AutoRead )

Function to control the measured value stability.

47

Glossary

48

pH 7110

Specialist term

Description

Standard solution

The standard solution is a solution where the measured

value is known by definition. It is used to calibrate a
measuring system.

Temperature
function

Name of a mathematical function expressing the temperature behavior of a test sample, a sensor or part of a
sensor.

Test sample

Designation of the test sample ready to be measured.

Normally, a test sample is made by processing the original sample. The test sample and original sample are
identical if the test sample was not processed.

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pH 7110

13

Index

Index
Stability control . . . . . . . . . . . . . . . . . . 18, 27

A
AR . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14
AutoCal . . . . . . . . . . . . . . . . . . . . . . . . . . . 20
Automatic switch-off function . . . . . . . . . . . 32
AutoRead . . . . . . . . . . . . . . . . . . . . . . . 18, 27

Z
Zero point (pH electrode) . . . . . . . . . . . 19, 24
Zero point, pH . . . . . . . . . . . . . . . . . . . . . . 25

B
Battery compartment . . . . . . . . . . . . . . 11, 36
Buffer sets (pH) . . . . . . . . . . . . . . . . . . . . . 30

C
Calibration evaluation (pH) . . . . . . . . . . . . 25
Calibration interval (pH) . . . . . . . . . . . . . . . 31
ConCal . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22

D
Default (calibration values) . . . . . . . . . . . . 34
Default (measurement settings) . . . . . . . . . 35
Default (system settings) . . . . . . . . . . . . . . 35
Display . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14

I
Initial commissioning . . . . . . . . . . . . . . . . . 10
Initialize . . . . . . . . . . . . . . . . . . . . . . . . . . . 34

K
Keys . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13

M
Measured value display . . . . . . . . . . . . . . . 16
Measuring (ORP) . . . . . . . . . . . . . . . . . . . . 27
Measuring (pH) . . . . . . . . . . . . . . . . . . . . . 18

R
Reset . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34
Resolution setting . . . . . . . . . . . . . . . . . . . 32

S
Safe operation . . . . . . . . . . . . . . . . . . . . . . . 9
Scope of delivery . . . . . . . . . . . . . . . . . . . . 10
Single-point calibration (pH, AutoCal) . . . . 21
Slope (pH electrode) . . . . . . . . . . . . . . 19, 24
Slope, pH . . . . . . . . . . . . . . . . . . . . . . . . . . 25
Socket field . . . . . . . . . . . . . . . . . . . . . . . . 15

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Index

50

pH 7110

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Wissenschaftlich-Technische Werksttten GmbH

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