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Structure of Atom

The document discusses rules for filling electrons in atoms with multiple electrons, specifically in degenerate orbitals. It explains: 1) Pauli's exclusion principle states that no two electrons can have the same quantum numbers. Electrons pair up with opposite spins. 2) Aufbau principle states that electrons fill the lowest available orbitals in order of increasing energy until the total number equals the atomic number. 3) Hund's rule states that electrons occupy separate degenerate orbitals with the same spin before pairing up electrons.

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vuppalasampath
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121 views

Structure of Atom

The document discusses rules for filling electrons in atoms with multiple electrons, specifically in degenerate orbitals. It explains: 1) Pauli's exclusion principle states that no two electrons can have the same quantum numbers. Electrons pair up with opposite spins. 2) Aufbau principle states that electrons fill the lowest available orbitals in order of increasing energy until the total number equals the atomic number. 3) Hund's rule states that electrons occupy separate degenerate orbitals with the same spin before pairing up electrons.

Uploaded by

vuppalasampath
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
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Tenth Physical Science

Structure of Atom
Electromagnetic waves can have a wide variety of wavelengths. The entire range
of wavelengths is known as the electromagnetic spectrum.
Q: What are the rules to be followed while filling the electrons in atoms which
contains more than one electron? How do you fill the electrons in
degenerate orbitals? Explain.
(4 Marks)
A: We follow the following principles while filling the electrons in degenerate
orbitals of an atom. a) Pauli's Exclusion Principle b) Aufbau Principle and c)
Hund's Rule.
a) Pauli's Exclusion Principle: "No two electrons of the same atom can have all
the four quantum numbers the same".
If n, l, and ml are the same for two electrons then ms must be different. In the
Helium atom the spins must be paired.
Electrons with paired spins are denoted by ''. One electron has m s
1
1
= + and the other has m s = . They have anti-parallel spins. so
2
2
electronic configuration of Helium atom is
1s2
b) Aufbau Principle: In the ground state the electronic configuration can be
build up by placing electrons in the lowest available orbitals until the total
number of electrons added is equal to the atomic number. This called Aufbau
principle.
Thus orbitals are filled in the order of increasing energy.
Electrons are assigned to orbitals in order of increasing value of (n + l)
For sub-shells with the same value of (n + l), electrons are assigned first to the
sub-shell with lower 'n'.
c) Hund's Rule: Electron pairing in orbitals starts only when all empty orbitals
of the same energy (degenerate orbitals) are singly occupied.
The configuration of Carbon (C) atom (Z = 6) is 1s2 2s2 2p2
The first four electrons go into 1s and 2s orbitals. The next two electrons go

into separate 2p orbitals, with both electrons having the same spin.

2s2 2p1x 2p1y


Prakash said that 'In an atom electrons occupy stationary orbits of fixed
energy at different distances from the nucleus'. Which model of the atom
gave this information? Write the postulates and limitations of that model of
the atom.
(4 Marks)
1s2

Q:

A:

Bohr's model of the atom gave this information.


Niels Bohr proposed the following postulates:
a) Electrons in an atom occupy stationary orbits of fixed energy at different
distances from the nucleus.
b) When an electron 'Jumps' from a lower energy state (ground state) to higher
energy states (excited states) it absorbs energy or emits energy when such a
Jump occurs from a higher energy state to lower energy state.
c) The energies of an electron in an atom can have only certain values E1, E2, E3
....., that is the energy is quantised.
The states corresponding to these energies are called stationary states and the
possible values of the energy are called energy levels.
Limitations: 1) Bohr's model failed to account for splitting of line spectra.
This model failed to account for the atomic spectra of atoms of more than one
electron.

Q:

Give an example of visible spectrum in nature. Explain what is a visible


spectrum.
(2 Marks)

A: The familiar example of the visible spectrum in nature is the formation of a


rainbow.
Each colour in a rainbow is characterized by a specified wavelength from red
(higher wavelength) to violet (shorter wavelength).
These colours (wavelengths), that the human naked eye is sensitive to, are
called visible light.
The range of wavelengths covering red colour to violet colour is called the
visible spectrum.

Q: What is the significance of Planck's proposal?

(1 Mark)

A: The significance of Planck's proposal is that electromagnetic energy can be


gained or lost in discrete values and not in a continuous manner.
Q: What is an orbital? How is it different from Bohr's orbit.
A:

Orbital

The region or space


around the nucleus
where the probability
of finding the eletron
is maximum is called
an orbital.

(2 Marks)

Bohr's Orbit
It has a definite bounary
and fixed energy at
diferent distances from
the nucleus.

The shape of each This orbit is circular in


orbital is different.
shape.
An
orbital
can This orbit can accomaccommodate only 2 modate a maximum of
electrons.
2n2 eletrons.
Q:

How do the vibrating electric and magnetic fields around the charge become
a wave that travel through space?
(1 mark)

A:

A vibrating electric charge creates a change in the electric field. The changing
electric field creates a changing magnetic field.
This process continues, with both the created fields being perpendicular to
each other and at right angles to the direction of propagation of the wave.

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