1 Types of Explosive
1 Types of Explosive
(ICI 1997).
a) Relative effective energy
Manufacturers tend to use their own methods for determining explosive energies
and it can be
misleading to compare quoted values from different suppliers. A more useful
indication of the
strength of an explosive is the relative effective energy.
Relative weight effective energy (RWEE). RWEE is defined as the effective energy of
an explosive
compared to the effective energy of an equal weight of standard ANFO (i.e. 94% AN,
6% FO,
density = 0.8 g/cm3). RWEE is expressed as a percentage, with hat of ANFO being
100%.
b) Shock and heave energy
Energy is delivered by an explosive in two main forms, shock energy and heave
energy. At
detonation, the rapidly expanding gases compress the rock around the charge and
cause a shock
wave to travel through the surrounding rock mass. The gases continue to expand,
forcing their
way into fractures created by the shock wave, and displace the fractured rock
outwards. This latter
effect of the expanding gases is termed heave. The mechanism by which an
explosive breaks rock is
explained in more detail in section 4.
3.2 Velocity of Detonation (VOD)
The velocity of detonation (VOD) is the rate at which the detonation wave travels
along an
explosive column. The greater the VOD the greater the power or shattering effect
of an explosive.
High VOD explosives are more suitable in hard rock and low VOD in softer rock.
Generally,
explosives with a lower VOD tend to release gas over a longer period and
consequently have more
heave. The VOD range in commercial explosives is 2500-7500 m/s.
3.3 Density
The density of a explosive determines the charge weight per meter of hole.
3.4 Detonation pressure---------------------------------------------------------EXPLOSIVES:
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Detonation pressure is the pressure in the reaction zone as an explosive detonates.
It is a
significant indicator of the ability of an explosive to produce good fragmentation. A
high
detonation pressure is one of the desirable characteristics in a primer (Atlas 1987).
3.5 Sensitivity
Sensitivity is a measure of the ease with which an explosive can be detonated by
heat, friction or
shock and of its ability to propagate that detonation. As described in section 3.1.2,
modern
commercial explosives can be grouped into two main categories according to their
sensitivity,
detonator sensitive explosives and blasting agents. Some explosives with very high
sensitivity,
such as pure nitroglycerin or dynamite, can be detonated by mechanical impact or
friction.
The sensitivity of an explosive has other operational implications. If the sensitivity is
too low, the
detonation within a blast hole can be interrupted if there are gaps or obstacles
between the
charges. An explosive that is too sensitive can result in propagation of a detonation
from one blast
hole to another (sympathetic detonation). There are various measures of sensitivity
(Atlas 1987).
Minimum Booster The smallest detonator or primer charge that will produce
detonation.
Gap Sensitivity The ability of an explosive to propagate across an air gap. The test is
of the eyes and respiratory system. At a concentration in the air of 100 ppm,
coughing may
commence and a concentration of 200 ppm is likely to be fatal (McPherson 1993,
p382).
Fortunately, even under extreme conditions, the concentrations of these gases in
explosive fumes
are very small (of the order of 0.1%). Their effects are minimised by:
After blasting, wait a set time before re-entering the area to allow fumes to clear.
Provide sufficient ventilation to disperse the fumes.
3.7 Storage properties
Explosives deteriorate and shelf life is particularly affected by both climate and
magazine
conditions. Statutory authorities in each State and Territory are responsible for the
approval and
licensing of magazines used for storing explosives. The maintenance of explosives
magazines is
also subject to Statutory Regulations. Explosive manufacturers specify the storage
properties or
shelf life of their products, based on normal magazine conditions (ICI 1997).
Nitroglycerin products are the most susceptible to deterioration during storage.
Dynamite
undergoes a normal aging process which rarely affects the energy output but can
affect the
appearance and sensitivity.
3.8 Water resistance
Blasting often takes place in wet conditions, even underwater for special tasks. In
these cases, the
water resistance of an explosive is a very important consideration. ANFO has no
water resistance
whilst emulsions and slurries have excellent water resistance. The water resistance
of an explosive
can be classified by testing its ability to detonate after exposure to water for certain
time periods
(Atlas 1987).
Note: the orange fumes sometimes seen in open pit blasting indicate that there is
water in the
blastholes. The water desensitises a proportion of the fuel, upsetting the oxygen
balance and
resulting in the production of nitrous oxides.
4.1 ANFO
a) Description
Ammonium nitrate is relatively insensitive, and wasnt even recognized as an
explosive until
some decades after it began to be used as fertilizer. Major disasters which have
been blamed,
retrospectively, on ammonium nitrate include the Galveston Harbour and Halifax
explosions.
Sadly, the North Americans hadnt learned from an earlier disaster at Oppau,
Germany, in 1921.
There, the ammonium nitrate was considered so safe it was stacked outdoors. It
would cake from
the rain, and set hard. When loading became a problem, the stack was broken up
using
dynamite . There is now a lake and a plaque where the town stood.
Ammonium nitrate fuel oil (ANFO) consists of small granules of ammonium nitrate
(AN) called
prills, coated with a special grade of fuel oil (FO). There are 3 types of ingredient.
Oxidiser Ammonium nitrate
Fuel Fuel oil/distillate
Sensitiser Entrapped air
ANFO can not be initiated on its own by heat, shock or by a detonator. It must be
detonated by a
primer, a cartridge of high explosive with detonator and the detonation pressure of
the primer
should be greater than that of the ANFO.
b) Mixing
One of the great advantages of ANFO is that it is convenient and inherently safe to
use. ANFO can
supplied pre-mixed in 10-25 kg bags, which are simply poured into blastholes
(Figures 3.2 & 3.3).
In large surface operations, quantities of correctly proportioned and mixed ANFO are
charged
quickly and efficiently by bulk ANFO mix trucks. The AN prills are blown out of a
tank by means
of a compressed air, through a nozzle at which fuel oil is added from a separate
small tank, and
into the blast hole (Figure 3.3). For small operations a hand-operated concrete mixer
can even be
used. In large underground mines, special charge-up vehicles are fitted with a AN
tank (kettle)
and compressed air supply. To distinguish between a mixed ANFO and straight AN,
the fuel oil is
often coloured blue or pink with a dye.
Mixing of ANFO constitutes the manufacture of an explosive and a license or permit
must be
obtained from the appropriate statutory
authority.---------------------------------------------------------EXPLOSIVES:
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c) Properties
Fuel oil content The proportion of FO is 5.5-6.0% by weight, a mix that gives
maximum
energy and VOD. Too much FO increases the production of carbon monoxide
and too little increases the proportion of oxides of nitrogen. The most
efficient, perfectly oxygen-balanced mix is at 5.7% FO
(Atlas 1987, ICI 1997).
Density Loose-poured ANFO has a density of 0.8 to 0.85 g/cm3. This low density
means that the bulk strength is relatively low. The density can be increased
up to about 1.0 g/cm3 by pneumatic loading (blow-loading). Blow loading
High energy explosives have been developed specifically for the efficient initiation
of blasting
agents. Their composition is based on military high explosive compounds such as
TNT
(trinitrotoluol) and PETN (pentaerythritol tetranitrate).
The ICI range of such explosives is named
Anzomex and the primers are made principally
of cast pentolite, a mixture of TNT and PETN.
The explosive is packaged in rigid plastic
containers that are usually cylindrical in shape
(Figure 3.10). These plastic containers generally
incorporate a some form of hollow tube or
attachment for the connection of a detonator,
detonating cord or shock tube (see section 3.6).
ICI Anzomex products have a density of
around 1.65 g/cm3, a VOD of about 7500 m/s
(ICI 1997) and a shelf life of about 5 years. Cast
primers must be handled very carefully; for
example, they can detonate if dropped from 15
m onto sharp rocks (Bellairs 1999). At present,
Orica has the only cast booster plant in
Australia, which manufactures the same
product for both Orica and Dyno Nobel labels.
Xxxx
Fig. 10: Cast primers and boosters
6 Initiating explosives
Initiating explosives are designed to safely activate larger explosive charges at a
controlled time
and in a pre-determined sequence (delay blasting). Initiating explosives can be
broadly classified
into electric and non-electric types. In electric systems, a device that can generate
or store ---------------------------------------------------------EXPLOSIVES:
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electrical energy transmits that energy to the initiating explosives via a circuit of
insulated
conductors. Blast sequences can be controlled by means of electric timing systems
but delay
timing is usually achieved through pyrotechnic delay elements incorporated inside
detonators.
Non-electric initiating systems use reactive chemicals to store and transmit energy
by controlled
burning, detonation, or shock waves. (ICI 1997.)
6.1 Detonators
Detonators are compact devices that are designed to safely initiate and control the
performance of larger explosive
charges. They contain relatively sensitive high explosives which can be initiated by
electrical or shock energy from an
external source. All detonators contain components that can be initiated by
sufficient impact, heat, friction or electrical
energy. These characteristics make them the most dangerous explosive products in
industrial application and they must
be stored, transported, handled and used according to set procedures, specified in
codes and regulations.
6.3 Electric detonators
a) Construction
Electric detonators are widely used to initiate blast sequences but are rarely now
used inside the
blastholes themselves (ICI 1997). Electrical energy is introduced into the detonator
from the
exploder (battery, hand-driven magneto or charged capacitor) via a primary circuit
wire (shotfiring
cable) and detonator leads. In the detonator (Figure 3.11), the current heats up a
high resistance
wire which then ignites a fusehead (similar to a match). The resulting flash ignites a
delay element
which burns through to a primer charge that detonates the base charge. The timing
of the
pyrotechnic delay element is accurate to within 8 ms (White 1999).
Fig. 11: Construction of electric detonator (Hustrulid 1999)
b) Electric circuits ---------------------------------------------------------EXPLOSIVES:
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The simplest and most convenient way to connect electric detonators is in series. If
one or more
detonator connections are faulty then the entire circuit will not fire, eliminating the
possibility of
having explosive in the broken rock after firing. Connection in series allows the
entire circuit to be
tested for continuity and resistance from a safe place. In a parallel circuit, in which
each detonator
is connected across two common wires, each detonator is independent of the
others. The circuit
resistance is lower but even if one connection of faulty the remainder will fire,
resulting in
unexploded charges in the muck pile. Each individual detonator must be tested for
continuity.
When connecting a round of charged blastholes, the ends of the detonator leads are
coupled in
series and the two free ends of the detonator circuit coupled to a firing cable, often
via a short
length of twin twist wire. The recommended minimum firing current is 1.5 amps DC
or 2.5 amps
AC for each series circuit (ICI 1997) and it is often necessary to calculate the circuit
resistance to
Detonating (figure 3.12) cord is a strong, flexible linear explosive which consists of a
continuous
core of high explosive, covered by a plastic jacket and is often overwrapped with
textiles (ICI
1997). The high explosive used is PETN, at a content of 3.6 to 70 g/m. When
initiated, detonating
cord will detonate along its entire length at a VOD of between 6.0 and 7.5 km/s and
with very
high shock energy. This shock energy is sufficient to initiate a detonator-sensitive
explosive or a
signal tube (see section 3.6.5). Cord is usually initiated by means of an electric
detonator. ---------------------------------------------------------EXPLOSIVES:
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Fig. 12: Detonating cord
The great advantage of detonating cord is that it is an effective, but violent, means
of transmitting
energy for explosives initiation. Detonating cord trunklines can be laid out between
rows of holes,
with signal tube connection to individual blastholes or to a single row of blastholes.
Delays can be introduced into det cord lines by means of millisecond connectors
(MSCs). MSCs
consist of two plastic blocks, each containing an identical delay detonator, linked by
a short length
of signal tube.
6.5 Signal (shock) tube
The signal tube system consists of narrow plastic tubes coated on the inside surface
with a very
thin layer of high explosive, typically HMX or PETN (Figure 3.13). One kilometer of
tube will
contain about a teaspoon of HMX. Signal tube can be initiated by an electric
detonator, detonator
cord or mechanical shot shell starter device. The resulting shock wave travels at
high speed (
2000 m/s) down the tube and sets off a detonator at the other end. (Because of the
way in which
the tube works it is sometimes known as shock tube.) The explosive shock wave
in the tube is
not sufficient to break the tube, indeed, a length of tube can safely be held in the
hand when it is
initiated.
The main advantages of this initiation system
are (ICI 1997):
it is not susceptible to stray electric
currents
separate lengths of signal tube cannot
initiate each other through direct contact,
knots or other simple connections
the tube is robust, having a high tensile
strength and abrasion resistance
it is very difficult to kink
the initiation is virtually non-violent
compared to detonating cord and is hence
much safer to use ---------------------------------------------------------EXPLOSIVES:
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Fig. 13: Shock tubes, with detonators and
connectors
6.6 Electronic systems
The latest development in explosive technology is the electronic delay detonator
(EDD) (Russell
7.3 Magazines
a) Licenses
A Magazine license is required to store detonators and explosives. The license is
subject to the
construction and location of the proposed magazine being granted approval. There
are
regulations governing operation, including separate storage of detonators, and
keeping of records.
Ammonium nitrate and bulk emulsion are relatively harmless until mixed with a
sensitiser. They
are also used in very large quantities. Construction of storage facilities is, therefore,
subject to less
stringent Regulations.
7.4 Transportation ---------------------------------------------------------EXPLOSIVES:
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The specifications relating to explosive transportation depend mainly on the type
and quantity of
explosive. The Australian Explosives Code details requirements relating to:
transportation
licenses, documentation, personnel (driver, person in charge, passengers), vehicle,
warning signs
and fire extinguishers.
References
Atlas Powder Company, 1987, Explosives and Rock Blasting, Atlas Powder Company
Field
Technical Operations, Dallas.
Bellairs, P, 1999, Modern bulk high explosives, presentation to the AusIMM Adelaide
Branch 1/7/99.
Technical Development Manager, Dyno Nobel Asia Pacific Limited.
Hustrulid W, 1999, Blasting Principles for Open Pit Mining, Vol. 1, Balkema,
Rotterdam.
ICI Technical Services, 1995, ICI Explosives Blasting Guide, ICI Australia Operations.
ICI Technical Services, 1997, Safe and Efficient Blasting in Underground Metal Mines,
ICI Australia
Operations.
Jimeno, C.L. and Jimeno, E.L., 1995, Drilling and Blasting of Rocks, A.A. Balkema,
Rotterdam.
Mather, W., 1997, Bulk Explosives, Mining Technology, vol. 79, no. 914, pp. 251254.
Russell, E., 1997, More bang for your buck with todays explosives, Tunnels and
Tunnelling,
January 1997.
White, TE, 1999, 'Tunnel blasting - recent developments', International Mining &
Minerals, vol. 2,
No. 17 (May 1999), IMM, Doncaster, England.