pycnometers

the density analysis of powders,

foams and bulk solids

QUANTACHROME

automatic

A utomatic O pe

Pycnometry
Pycnometry is derived from the Greek word pyknos, which has
long been identified with volume measurements. The pycnometers
from Quantachrome are specifically designed to measure the true
volume of solid materials by employing Archimedes principle of
fluid (gas) displacement and the technique of gas expansion.
Ideally, a gas is used as the displacing fluid since it penetrates the
finest pores assuring maximum accuracy. For this reason helium
is recommended, since its small atomic dimension enables entry
into crevices and pores approaching one Angstrom (10-10m). Its
behavior as an ideal gas is also desirable. Other gases such as
nitrogen can be used, often with no measurable difference.
Applications
Quantachrome pycnometers are used for research, development
and quality control in such diverse industries as carbon black,
catalysts, cement, ceramics, charcoals, cosmetics, desiccants,
fertilizers, fibers, fillers, insulating and structural foams, powdered foods, ion exchange resins, minerals such as alumina,
silica, titania and others, nuclear fuels, petrochemicals, pharmaceuticals and powdered metals. Pycnometry can even determine
the percentage of solids in a slurry.
The PENTAPYCNOMETER and the ULTRAPYCNOMETER 1000
from Quantachrome are the ultimate instruments for measuring
the true volume and density of powders, foams and bulk solids.
A wide range of sample cell sizes are easily interchanged to
accommodate many different samples. Calibration, sample
conditioning, operation of valves and calculation of results are
completely automatic. Samples are quickly and automatically
analyzed as many times as necessary to achieve the user desired
% deviation from mean at the specified number of runs. Should

Sample Cells
Standard sample cells


Optional Microcell
Optional Mesocell
Optional Nanocell
Optional film/fiber
winding spools

Nominal
Volume
135 cm3
50 cm3
10 cm3
4.5 cm3
1.8 cm3
0.25 cm3

Diameter
5.05 cm
4.12 cm
2.54 cm
1.66 cm
1.66 cm
1.66 cm

Length
7.55 cm
3.97 cm
2.41 cm
2.54 cm
2.54 cm
2.54 cm

n/a
n/a

2.54 cm
1.67 cm

2.54 cm
2.40 cm

speed versatility acc

the deviation setting be too narrow, the analysis terminates upon
reaching an operator specified maximum number of runs. The
results are printed automatically, freeing the operator to perform
other laboratory tasks.
The PENTAPYCNOMETER permits up to five samples to be
loaded and then purged simultaneously. Each of the five samples
is then automatically analyzed in sequence with no operator
involvement. Adjustable flow rates for each cell provide maximum flexibility of operation.
For laboratories with lower analytical throughput needs, the
single sample station ULTRAPYCNOMETER 1000 provides
the same ease of operation and high performance as the
PENTAPYCNOMETER.
For measurements that require a fixed, known temperature,
a temperature control operation is available for both the
ULTRAPYCNOMETER 1000 and the pentapycnometer.
For measurements in a hazardous environment, such as a
nuclear hot cell, a remote operation
ULTRAPYCNOMETER 1000 is available.
For measurement of foams, a specialized version called the
UltraFoam pycnometer is available. It is a system for
automatic measurement of open and closed cell content with
automatic functions for the analysis of cell compressibility
and cell fracture according to ASTM D-2856.
For measurements of extremely small amounts of material,
the Micro ULTRAPYCNOMETER provides three interchangeable cell sizes of 4.5 cm3, 1.8 cm3 and 0.25 cm3.

The sample cells listed above are aluminum.

All cells are available in stainless steel for durability.
Non-elutriating cells are available for fine powders.

Gas Input and Vacuum Fittings

Foods and Pharmaceuticals

Catalysts and Ceramics

eration

S eries

curacy reproducibility

Feature Benefits

Automatic Functions - Operating simplicity is achieved by user prompts or instructions which are automatically presented on
the alphanumeric display. Measurements and printout of results are totally automatic. Continuous selfdiagnostics monitor and signal fault conditions that may arise. The transducer is reset to zero prior to
each run. Front panel LEDs display the operational status at all times.
Sample Identification - In the analysis parameters, alphanumerics may be added to uniquely identify the sample.
Temperature Readout - Sample temperature is displayed and printed to 0.1 C. This feature is important for:
(a) verifying operation at the calibration point or,
(b) making corrections when analyzing larger quantities of materials whose density varies
significantly with temperature.
Target Pressure -

The measurement of pressure-deformable cellular foams (insulation) is made possible by this feature.
A user can conveniently reduce the target pressure typically from around 18 psi to as low as 0.5 psi.
A special version, the UltraFoam pycnometer, automatically scans for the optimum pressure and
performs calculations of open and closed cell content with or without ASTM correction for cut cells.

Sample Purge -

Before analysis, samples are automatically conditioned to remove contaminants and trapped air. The
user has a choice to purge by a continuous flow to prevent elutriation (blowing out) of fine particles, by
a pulse mode more suitable for coarse powders or bulk solids. The PENTAPYCNOMETER purges all
five stations simultaneously, thus requiring no more time than for a single analysis.
The ULTRAPYCNOMETER has the added capability to purge the sample by vacuum for a user
selectable time, (vacuum pump supplied separately).

Repeat Run Mode -

This feature eliminates the need to reenter the same set of analysis parameters prior to each run.
It allows one to quickly change sample weight and sample ID, or simply to rerun a sample by a double
keystroke.

Useful Statistics -

For three or more averaged measurements the % coefficient of variance and the standard deviation of the
volume and the density are printed out. This allows a relative comparison of samples from run-to-run and
a precise assessment of the absolute variation of the sample being measured.

NIST Traceability -

Pycnometer volume calibration spheres can be provided with a formal Report of Calibration from the
National Institute of Standards and Technology.

Computer Software -

To capture printed output, automatic pycnometers are available with Windows based PC software that
provides disk storage (ASCII format) of data along with all user entered information. Archived files
can be recalled for review, printing and importation to other programs.

Balance Port -

Permits interface with configurable analytical balance for automatic transfer of sample weight.
Eliminates risk of transcription error.

Powder Metals and Construction

Foams and Fibers

NIST traceable calibration spheres.

WORLDWIDE Sales
and Service

Quantachrome

Quantachrome Instruments corporate headquarters in Boynton Beach, Florida.

Renowned innovator of ideas for todays porous materials community.

For more than 38 years, Quantachromes
scientists and engineers have revolutionized
measurement techniques and designed
instrumentation to enable the accurate,
precise, and reliable characterization of
powdered and porous materials:

Adsorption/Desorption Isotherms
Surface Area Measurement
Pore Size Distribution
Chemisorption Studies
Water Sorption Behavior
Mercury Porosimetry
True Solid Density
Tapped Density

Not only are Quantachrome products

the instruments of choice in academia,
but the technology conceived and developed by our expert staff is applied
in industrial laboratories worldwide,
where research and engineering of new
and improved porous materials is ongoing.

Manufacturers also rely on porous

materials characterization technology
to more precisely specify bulk materials,
to control quality, and to isolate the
source of production problems with
reater efficiency.
Quantachrome is also recognized as
an excellent resource for authoritative
analysis of your samples in our fully
equipped, state-of-the-art powder
characterization laboratory.

Quantachrome Instruments Application Laboratory.

Quantachrome Instruments' quality
management system is certified to be
in accordance with ISO9001:2000.

CORPORATE HEADQUARTERS
Quantachrome Instruments

EUROPE
Quantachrome UKLimited

1900 Corporate Drive

Boynton Beach, FL 33426 USA
Phone: +1 (561) 731-4999
Fax:
+1 (561) 732-9888
E-mail: [email protected]

Pale Lane Farm, Pale Lane

Hartley Wintney
Hook RG27 8BA, UK
Phone: +44 (0) 1252819719
Fax:
+44 (0) 1252819901

CHINA
Quantachrome Representative Office

EUROPE
Quantachrome GmbH & Co. KG

Rm.1818, Beijing Shougang

International Building
No.60, North Street, Xizhimen,
Haidian District, Beijing 100088, P.R. China
Tel: +86 10 5993 5861
Fax: +86 10 5993 5961

Rudolf-Diesel Str. 12
85235 Odelzhausen, Germany
Phone: +49 (0) 8134/93240
Fax:
+49 (0) 8134/932425

Our policy of continuous development may cause the information and specifications contained herein to change without notice or liability.

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Characterization
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