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Sample Calculations:: (0.10 M) (10 ML) 100 ML 0.01 M) (2 ML) 100 ML 0.002 M 2 0

This document contains sample calculations for determining the rate constant (k) of two reactions using linear regression analysis of logarithmic rate data. For the first reaction, the rate constant was calculated to be 0.1270747891 s-1. For the second reaction, with different concentrations and temperatures, the rate constant was calculated to be 3.7563 x 10-3 s-1. An activation energy of 42,671.346 J/mol was also determined from the temperature dependence of the rate constants.

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Arielle Emperador De Guzman
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21 views

Sample Calculations:: (0.10 M) (10 ML) 100 ML 0.01 M) (2 ML) 100 ML 0.002 M 2 0

This document contains sample calculations for determining the rate constant (k) of two reactions using linear regression analysis of logarithmic rate data. For the first reaction, the rate constant was calculated to be 0.1270747891 s-1. For the second reaction, with different concentrations and temperatures, the rate constant was calculated to be 3.7563 x 10-3 s-1. An activation energy of 42,671.346 J/mol was also determined from the temperature dependence of the rate constants.

Uploaded by

Arielle Emperador De Guzman
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
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Sample Calculations:

Case I:
1
87.88

Time (s)

a=

( 0.10 M ) (10 mL)


100 mL

c=

( 0.01 M ) (2 mL)
100 mL

a-

c
2

3
51.03

4
38.95

5
36.54

= 0.01 M

= 0.0002 M

0.002 M
2

0.01 M

= 9.9 x 1 0

c
3
2 ) = log (9.9 x 1 0 ) = -2.0044

log (a -

c
2t

2
63.49

log ( 2 t

0.0002
2( 87.88)

)=

= 1.1379 x 1 0

log (1.1379 x 1 0

) = -5.9439

Linear Regression:
x [ log (a -2.0044
-1.8268
-1.7011
-1.6038
-1.5243
Slope = m = 0.8242

c
2 )]

y [log ( 2 t )]
-5.9439
-5.8027
-5.7078
-5.5905
-5.5628

y-intercept = log

r2

k'
k'

y-intercept = log

-4.2939 = log
'

k'

= -4.2939

= 0.99

k from

'

= -4.2939

k'
5

= 5.0828 x 1 0
n

= k[b

5.0828 x 1 0

= k[0.02

k = 0.1270747891

Case II:
Time (s)

a=

b=

c=

1
169.97

( 0.10 M ) (10 mL)


100 mL
( 0.10 M ) (10 mL)
100 mL
( 0.01 M ) (2 mL)
100 mL

2
114.01

= 0.01 M

= 0.01 M

log (b) = log(0.01) = -2

2x1 0

3
90.97

4
75.72

5
61.87

c
2t

2 x 10
2(169.97)

= 5.8832 x 1 0

log( 2 t ) = log (5.8832 x 1 0

log

k' '

) = -6.2304

= -4.4296

c m

k' '

= k[a -

k' '

= 3.7188 x 1 0
5

3.7188 x 1 0

= k [0.01 -

K = 3.7563 x 1 0

2 x 1 04 1

Linear Regression:
x [ log (b)]

y [log ( 2 t )]
-2
-1.8239
-1.6990
-1.6021
-1.5229
Slope = m = 0.8937
y-intercept = -4.4296

r2

= 0.9987

-6.2304
-6.0569
-5.9589
-5.8792
-5.7915

Effect of Temperature:
1
213.08

Time (s)

a=

( 10 mL ) (0.1 M )
100 mL

= 0.01 M

b=

( 20 mL ) (0.1 M )
100mL

= 0.02 M

c=

( 0.010 M ) (2 mL)
100mL

a-

c
2t

c
2

0.0002
2

= 0.01

= k [b

= 0.0002 M

[a - 2

= 0.009

; n=2, m =1

k = 0.1185
ln(k) = ln(0.1185) = -2.1328

1
T

ln(k) =

1
288.15
Ea
R

= 3.47 x 1 0

( T

) + In(A)

y-intercept = ln(A)
15.6275 = ln(A)
A = 6122615.913
Slope =

Ea
R

= -5132.4689 =

Ea = 42671.346

E a
8.314

3
90.97

4
75.72

5
61.87

Linear Regression:
x[

1
T ]

y [ln(k)]

3.47 x 1 0

-2.1337

3.35 x 1 0

-1.7142

3.30 x 1 0

-1.2455

3.25 x 1 0

-1.0689

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