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Reduction Half-Reaction E (V) : Neutral or Acid Solution

This document lists reduction half-reactions and their standard reduction potentials (Eo) for both neutral/acidic and basic solutions. In neutral/acidic solutions, common half-reactions include oxygen gas being reduced to water, halogens being reduced to their anion forms, and metals being reduced from cations to the elemental form. In basic solutions, common half-reactions include oxidizing agents like chlorine and bromine being reduced to their anion forms, and metal hydroxides and oxides being reduced to the elemental metal and hydroxide anions. The standard reduction potentials provide a measure of the reducing ability of each half-reaction.

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Eric Fernando
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45 views

Reduction Half-Reaction E (V) : Neutral or Acid Solution

This document lists reduction half-reactions and their standard reduction potentials (Eo) for both neutral/acidic and basic solutions. In neutral/acidic solutions, common half-reactions include oxygen gas being reduced to water, halogens being reduced to their anion forms, and metals being reduced from cations to the elemental form. In basic solutions, common half-reactions include oxidizing agents like chlorine and bromine being reduced to their anion forms, and metal hydroxides and oxides being reduced to the elemental metal and hydroxide anions. The standard reduction potentials provide a measure of the reducing ability of each half-reaction.

Uploaded by

Eric Fernando
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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Neutral or Acid Solution

Eo(V)

Reduction HalfReaction
F2(g) + 2e ! 2F(aq)

2.86

OF2(g) + 2H+ (aq)+ 4e ! H2O(l) + 2F(aq)

2.1

Br2(l) + 2e ! 2Br(aq)

1.065

NO2(g) + 2H+ (aq)+ 2e ! NO(g) + H2O(l)


[AuCl4]

(aq)+

! Au(s) + 4Cl

3e

VO2 (aq )+ 2H

! VO

+e

(aq)

2+

1.03
1.002

(aq)

+ H2O(l)

1.000

! NO(g) + 2H2O(l)

0.956

(aq)

O3(g) + 2H+ (aq)+ 2e ! O2(g) + H2O(l)

2.075

S2O82 (aq) + 2e ! 2SO42(aq)

2.01

Ag2+(aq) + e ! Ag+(aq)

1.98

Co3+(aq) + e ! Co2+(aq)

1.82

H2O2(aq)+ 2H+(aq)+ 2e ! 2H2O(l)

1.763

MnO4 (aq ) + 4H+(aq)+ 3e ! MnO2(s) + 2H2O(l)

1.70

PbO2(s) + SO4 2(aq)+ 4H+(aq) + 2e ! PbSO4(s) + 2H2O(l)

1.69

Au3+(aq) + 3e ! Au(s)

1.52

MnO4(aq ) + 8H+(aq)+ 5e ! Mn2+(aq) + 4H2O(l)

1.51

2HgCl2(s) + 2e ! Hg2Cl2(s) + 2Cl( aq)

0.63

2BrO3 (aq) + 12H+(aq) + 10e !

1.478

MnO4(aq ) + e !

0.56

Br2(l) + 6H2O(l)

PbO2(s) + 4H+ (aq)+ 2e ! Pb2+(aq) + 2H2O(l)

1.455

ClO3 (aq) + 6H+(aq) + 6e !

1.450

Cl(aq)+ 3H2O(l)

NO3 (aq ) + 4H
2+

2Hg

2+

Cu

Hg

Ag

Hg2

(aq)

3+

Fe

(aq)

0.90

(aq)

0.86
0.854

2+

! Fe

(aq)+

2e

! 2I

0.800

2Hg(l)

I2(s) + 2e

2+

! CuI(s)

Cu

+ 2e

+e

(aq)

3e

! Ag(s)

+e

(aq)

(aq)+

! Hg(l)

+ 2e

O2(g) + 2H

(aq)+

! Hg2

+ 2e

+I

(aq)

2+

(aq)

(aq)

2+

0.80

(aq)

0.771

! 2H2O2(aq)

0.695

MnO42(aq)

0.535

(aq)

! Cu(s)

+e

0.520

Ce4+(aq) + e ! Ce3+(aq)

1.44

Au3+(aq) + 2e ! Au+(aq)

1.36

Cl2(g) + 2e ! 2Cl(aq)

1.358

Cr2O72 (aq) + 14H+(aq) + 6e ! 2Cr3+(aq) + 7H2O(l)

1.33

MnO2(s) + 4H+ (aq)+ 2e ! Mn2+(aq) + 2H2O(l)

1.23

O2(g) + 4H+(aq) + 4e ! 2H2O(l)

1.229

2IO3 (aq) + 12H+(aq) + 10e ! I2(s) + 6H2O(l)

1.20

ClO4 (aq) + 2H+(aq) + 2e ! ClO3(aq) + H2O( l)

1.19

ClO3 (aq) + 2H+(aq) + e ! ClO2(g) + H2O(l)

1.175

AgCl(s) + e

NO2(g) + H+ (aq)+ e !

1.07

SO42(aq ) + 4H+(aq)+ 2e ! SO2(g) + 2H2O(l)

HNO2(aq)

H2SO3(aq) + 4H
C2N2(g) + 2H
[Fe(CN)6]
2+

Cu

VO

(aq)

2+

(aq)+

(aq)+

(aq)+

(aq)+

[Fe(CN)6]

HAsO2(aq) + 3H

0.449
0.37

(aq)

0.361
0.337

! V

+ H2O(l)

0.337

! PbO(s) + H2O(l)

0.28

0.2676

2e

3+

(aq)

! 2Hg(l) + 2Cl

2HgCl2(s) + 2e

! 2HCN(aq)

2e

! S(s) + 3H2O(l)

4e

! Cu(s)

+ 2H

PbO2(s) + 2H

(aq)+

+ 2e

(aq)

(aq)+

3e

(aq)

! As(s) + 2H2O(l)

! Ag(s) + Cl

(aq)

0.240
0.2223
0.17

Cu2+(aq) + e ! Cu+(aq)

0.159

Na+(aq) + e ! Na(s)

2.713

Sn4+(aq) + 2e ! Sn2+(aq)

0.154

Ca2+(aq) + 2e ! Ca(s)

2.84

S(s) + 2H (aq ) + 2e

! Ag(s) + Br

AgBr(s) + e
2H

Fe

Pb

2+

Sn

! Ag(s) + I

AgI(s) + e
V

3+

(aq)

2+

Ni

! V

+e

+ 2e

(aq)

2+

0.071

0.04

! Sn(s)

+ 2e

(aq)

0.14

0.00

! Pb(s)

+ 2e

(aq)

(aq)

! Fe(s)

+ 3e

(aq)

2+

! H2(g)

+ 2e

(aq)

3+

H2S(g)

(aq)

! H3PO3(aq) + H2O(l)

2e

0.152

0.276

Co2+(aq) + 2e ! Co(s)

0.277

PbSO4(s) + 2e ! Pb(s) + SO42(aq)

0.356

2+

Cd

3+

Cr

2+

Fe

(aq)
(aq)

2+

! Cr

+e

Cr

Zn

(aq)

2+

2+

Cr

(aq)

(aq)

2+

Mn

2+

Ti
U

3+

(aq)

3+

Al

(aq)+

2e

0.424
0.440

! H2C2O4(aq)

0.49

! Cr(s)

0.74

! Zn(s)

0.763

! Cr(s)

0.90

+ 2e
+ 2e

+ 2e

! Mn(s)

1.18

! Ti(s)

1.63

! U(s)

1.66

! Al(s)

1.676

+ 3e

(aq)

(aq)

+ 2e

(aq)

+ 3e

(aq)

0.403

! Fe(s)

+ 2e

2CO2(g) + 2H
3+

! Cd(s)

+ 2e

(aq)

+ 3e

Mg2+(aq) + 2e ! Mg(s)

2.356

Li

+ 2e

+e

+e

+e

! Sr(s)

2.89

! Ba(s)

2.92

! Cs(s)
! K(s)

+e

(aq)

(aq)

(aq)

+ 2e

(aq)

(aq)

0.137

0.257

(aq)+

Cs

! Ni(s)

H3PO4(aq) + 2H

Ba

(aq)

2+

Rb

0.255

Sr

0.125

(aq)

2+

2.923
2.924

! Rb(s)

2.924

! Li(s)

3.04

AsO2(aq ) + 2H2O(l)+ 3e ! As(s) + 4OH(aq)

Basic Solution

Eo(V)

Reduction HalfReaction
O3(g) + H2 O(l)+ 2e ! O2(g) + 2OH(aq)

1.246

ClO(aq) + H 2O(l)+ 2e ! Cl(aq) + 2OH(aq)

0.890

HO2 (aq)+ H2O(l) + 2e ! 3OH(aq)

0.88

BrO(aq) + H 2O(l)+ 2e ! Br(aq) + 2OH(aq )


ClO3(aq ) + 3H2O(l)+ 6e ! Cl (aq) + 6OH(aq)
2AgO(s) + H2O(l ) +2e !

Ag2O(s) + 2OH(aq)

ClO2 (aq ) + H2O(l)+ 2e

! ClO

! Br

BrO3 (aq ) + 3H2O(l)+ 6e


IO

(aq)

! I

+ H 2O(l)+ 2e

(aq)

+ 2OH

(aq)

+ 6OH

(aq)

+ 2OH

0.49

(aq)

BrO
IO

(aq)

(aq)

! Br2(l) + 4OH

+ 2H 2O(l)+ 2e

! I2(s) + 4OH

+ 2H 2O(l)+ 2e

O2(g) + 2H2 O(l)+ 4e

! 4OH

0.455

(aq)

0.42

(aq)

0.401

(aq)

! ClO2

ClO3 (aq ) + H2O(l)+ 2e

0.48

(aq)+

2OH (aq )

0.35

2Ag2O(s) + H2 O(l)+ 2e ! 2Ag(s) + 2OH(aq)

0.342

Co(OH)3(s) + e ! Co(OH)2(s) + OH(aq)

0.17

! ClO3

ClO4 (aq ) + H2O(l)+ 2e

! NO2

NO3 (aq ) + H2O(l)+ 2e


2

HPbO2

(aq)+

+2OH (aq )

AsO4 ( aq) + 2H2O(l)+ 2e

(aq)

+ 4OH

0.01

! AsO2

0.13

0.59
0.66

(aq)

(aq)+

(aq)

0.54

(aq)

CH3OH(aq) + 2OH(aq)

! S(s) + 6OH

0.17

! Pb(s) + 3OH

H2O(l) + 2e

SO3 (aq ) + 3H2O(l)+ 4e


3

(aq)

2OH (aq )

! [Cr(OH)4]

HCHO(aq) + 2H2O(l )+ 2e !
2

(aq)+

CrO4 ( aq) + 4H2O(l)+ 3e

4OH (aq )

! CN

OCN (aq ) + H2O(l)+ 2e

As(s) + 3H2O(l ) + 3e
[Zn(OH)4]

(aq)+

(aq)

+ 2OH

AsH3(g) + 3OH

! Zn(s) + 4OH

2e

0.67

Mg(OH)2(s) + 2e

0.68
0.828

(aq)

SbH3(g) + 3OH

Mg(s) + 2OH

(aq)

(aq)

(aq)

0.97
1.21
1.285

(aq)

0.622

0.584

Ni(OH)3(s) + e ! Ni(OH)2(s) + OH(aq)

[Al(OH)4] (aq)+ 3e ! Al(s) + 4OH(aq)

0.59

(aq)

! H2(g) + 2OH

Sb(s) + 3H2O(l ) + 3e

0.60

(aq)

2H2O(l) + 2e

0.766

0.604

MnO4(aq ) + 2H2O(l)+ 3e ! MnO2(s) + 4OH(aq)

(aq)

1.338
2.310
2.687

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