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Problem

The gas burned is 40% CH4, 40% CO, and 20% H2 with 300% excess air at 25°C. Using stoichiometric calculations and Hess's Law, the theoretical adiabatic flame temperature is determined to be: 726.985°C. The temperature is calculated through interpolation between temperatures that produce heat changes of 11J and -72,906.3J from the combustion reactions. Stoichiometric calculations are used to determine the amounts of reactants and products. Hess's Law is then applied to calculate the heat of reaction (∆H) at different temperatures and interpolate to find the adiabatic flame temperature.

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Dina Adelina
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110 views6 pages

Problem

The gas burned is 40% CH4, 40% CO, and 20% H2 with 300% excess air at 25°C. Using stoichiometric calculations and Hess's Law, the theoretical adiabatic flame temperature is determined to be: 726.985°C. The temperature is calculated through interpolation between temperatures that produce heat changes of 11J and -72,906.3J from the combustion reactions. Stoichiometric calculations are used to determine the amounts of reactants and products. Hess's Law is then applied to calculate the heat of reaction (∆H) at different temperatures and interpolate to find the adiabatic flame temperature.

Uploaded by

Dina Adelina
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as DOCX, PDF, TXT or read online on Scribd
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PROBLEM

CHAPTER 5

5.131

INDRA KUSTRIWAHYUHANANTO 2315106001

BAMBANG WISNU AJI 2315106002

DINA ADELINA 2315106003


5.131.

A gas is burned with 300% excess air with the gas and air entering the combustion
chamber at 25C. What is the theoretical adiabatic flame temperature achieved in C?

F P
CH440% Gas 25C
T?
CO40% FURNACE
H220%
300% excess air

A
21 % O2
79 % N2

Solution :

Basis : 1 gmol F

Reaksi I :

CH4 + 2O2 CO2 + 2H2O

Mula 0.4

Reaksi 0.4 0.8 0.4 0.8

Sisa -

Reaksi II :

CO + O2 CO2

Reaksi 0.4 0.2 0.4


Reaksi III :

H2 + O2 H2O

Reaksi 0.2 0.1 0.2

O2 yang bereaksi = 0.8 + 0.2 + 0.1 = 1.1 gmol

Mencari O2 yang masuk

O2 masuk O2 teoritis
Excess= x 100
O2 teoritis

0.21 A1.1
300 = x 100
1.1

A = 20.95 gmol

O2 yang masuk = 0.21 x 20.95

= 4.4 gmol

N2 yang masuk = 0.79 x 20.95

= 16.55 gmol

ACC = in-out+gen-kon
1. CH4 out = CH4 in + CH4 gen - CH4 kons
= 0.4 + 0 0.4
=0
2. CO out = CO in + CO gen CO kons
= 0.4 + 0 0.4
=0
3. H2 out = H2 in + H2 gen - H2 kons
= 0.2 + 0 0.2
=0
4. O2 out = O2 in + O2 gen - O2 kons
= 4.4 + 0 1.1
= 3.3 gmol
5. N2 out = N2 in + N2 gen - N2 kons
= 16.55 + 0 0
= 16.55 gmol
6. CO2 out = CO2 in + CO2 gen - CO2 kons
= 0 + 0.8 0
= 0.8 gmol
7. H2O out = H2O in + H2O gen - H2O kons
=0+10
=1
CH4 + 2O2 CO2 + 2H2O
25C 25C T T
H1 H2 H4

Tref=25C Tref=25C H3

CH4 + 2O2 CO2 2H2O

H Reaksi = Hfp - Hr

Reaktan pada 298 K (25C)

H
Hf H=(H+Hf) . gmol
Komponen gmol (J/gmol
(J/gmol) (J)
)
CH4 0.4 - -74,840 -29,936
CO 0.4 728- -110,520 -44,208
728
H2 0.2 718- 0 0
718
O2 0.4 732- 0 0
732
N2 16.55 728- 0 0
728
-74,144

Produk pada 1000 K (727C)

Komponen gmol H Hf H=(H+Hf) . mol


CO2 0.8 34,308-912 -393,510 -288,091
H2O 1 26,823-837 -241,826 -215,840
O2 3.3 23434-732 0 74,916.6
N2 16.55 22171-728 0 354,881.7
-74,133

H = H produk - H reaktan

= -74,133-(-74,144)

= 11 J

Produk pada 900 K (627C)

Komponen gmol H Hf H=(H+Hf) . mol


CO2 0.8 28936-912 -393,510 -292,389
H2O 1 22760-837 -241,826 -219,903
O2 3.3 19970-732 0 63,485.4
N2 16.55 18961-728 0 301,756.2
-147,050
H = H produk - H reaktan

= -147,050-(-74,144)

= -72,906.3 J

Menghitung suhu dengan cara interpolasi :

0(72,906.3)
T =900+
11(72,906.3) x100

T =999.985 K

T =726.985

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