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CHE231 Ch7 Differential Method

The document contains experimental data showing the concentration of a substance (C_A) decreasing over time as it undergoes a reaction. A linear regression was performed on the log-transformed concentration and reaction rate data, yielding a first-order rate law with a rate constant of 0.0047 L/mol/min. The linear fit had an R^2 value of 0.9954, indicating the data closely follow first-order kinetics.

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Dominic Giambra
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33 views

CHE231 Ch7 Differential Method

The document contains experimental data showing the concentration of a substance (C_A) decreasing over time as it undergoes a reaction. A linear regression was performed on the log-transformed concentration and reaction rate data, yielding a first-order rate law with a rate constant of 0.0047 L/mol/min. The linear fit had an R^2 value of 0.9954, indicating the data closely follow first-order kinetics.

Uploaded by

Dominic Giambra
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as XLSX, PDF, TXT or read online on Scribd
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Graphica

l
Experimental Data Analysis Processed Data
t (s) C_A (mol/L) dc/dt log C_A log (-dc/dt)
0 10 -0.133333 1 -0.8750612634
20 8 -0.1 0.90309 -1
40 6 -0.07 0.778151 -1.15490196
60 5 -0.05 0.69897 -1.3010299957
120 3 -0.025806 0.477121 -1.5882717068
180 2 -0.012167 0.30103 -1.9148283903
300 1

-0.6

-0.8
f(x) = 1.4716246853x - 2.325607035
-1 R = 0.9954788515

log (- dCA/dt)
-1.2

-1.4

-1.6

-1.8

-2
0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 1.1
log CA
LINEST Regression Regression Key
1.4716247 -2.325607 slope intercept
0.0495879 0.0363715 SE(slope) SE(intercept)
0.9954789 0.029165 r2 SE(y)
35 880.73095 4F DF
0.7491459 0.0034024 SS reg SS resid

From Regression
= 1.47
log k = -2.326 --> k = 0.0047

0.9 1 1.1
dc/dt estimated using
t (min) CBr (mol/L) 2nd order fit 3rd order fit
0 0.3335 -0.0163 -0.0174
2.25 0.2965 -0.0146125 -0.014955375
4.5 0.266 -0.012925 -0.0128145
6.33 0.245 -0.0115525 -0.011297247
8 0.2255 -0.0103 -0.010088
10.25 0.205 -0.0086125 -0.008723375
12 0.191 -0.0073 -0.007872
13.5 0.1794 -0.006175 -0.0072885
log dc/dt
log c_Br 2nd order fi3rd order fit
-0.476904 -1.787812 -1.759451
-0.527975 -1.835275 -1.825203 0.4
-0.575118 -1.888569 -1.892298
0.35
-0.610834 -1.937324 -1.947027
0.3 f(x) = 0.0003747223x^2
-0.646853 -1.987163 -1.996195 R = 0.9997569159
-0.688246 -2.064871 -2.059315 0.25
-0.718967 -2.136677 -2.103915 0.2
-0.746178 -2.209363 -2.137362
0.15

0.1

0.05

0
0 2 4

0.4
f(x) = -0.0661223972
0.35 R = 0.9746710023
f(x)
0.3 = - 1.0026680525608E-0
R = 0.9999015702
0.25

0.2

0.15

0.1

0.05

0
0 2 4
Chart Title

-0.8 -0.75 -0.7 -0.

f(x) = 0.0003747223x^2 - 0.0163480584x + 0.3326069558


R = 0.9997569159
f(x) = 1.543421583
R = 0.9689580576

2 4 6 8 10 12 14 16

Chart Title

f(x) = -0.0661223972 ln(x) + 0.3587537764 -0.8 -0.75 -0.7 -0


R = 0.9746710023
= - 1.0026680525608E-005x^3 + 0.0005769807x^2 - 0.0173585672x + 0.3332969515
0.9999015702

f(x) = 1.42660987
R = 0.999525682

0 2 4 6 8 10 12 14 16
Chart Title
-1.5
-0.75 -0.7 -0.65 -0.6 -0.55 -0.5 -0.45 -0.4
-1.6

-1.7

f(x) = 1.5434215835x - 1.0179651704 -1.8


R = 0.9689580576
-1.9

-2

-2.1

-2.2

-2.3

Chart Title
-1.5
-0.75 -0.7 -0.65 -0.6 -0.55 -0.5 -0.45 -0.4
-1.6

-1.7

f(x) = 1.4266098712x - 1.0750560846 -1.8


R = 0.9995256821
-1.9

-2

-2.1

-2.2

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