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ANSWER-CARBON COMPOUND PAPER 2

1 (a) alkane 1
(b) (i) 58 1
3
(ii) No. of mole of CO2 = 120cm3
24000cm3
= 0.005 mol.
No. of mole of C4H10 = 0.005
4
= 0.00125 mol.

(c) (i) Butene / But-2-ene. 1

(ii) C = C/ Double bond between carbon atoms. 1
(d) Accept any one of the isomers. 1
(e) (i) Hydration 1
(ii) Catalyst phosphoric acid 1
Temperature - 300C
Pressure 60 atom.
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2 (a) Formula that shows the actual number of atom of each 1 1

element in a compound.
(b) (i) 6O2 4H2O 1 2

(ii) 0.8 1

(c) (i) H H H H H H H H 1 3
H C C C C H or H C C C C H

H H H OH H H OH H

or or

H CH 3 H H CH 3 H

H C C C H or H C C C H

H OH H H H OH
(ii) 1. Functional apparatus and heat 2
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2. Correct label : butanol, glass wool, name of dehydrating

agent
a: other correct dehydrating agent e.g porcelain chip / porous
pot / aluminium oxide / ceramic
a: dehydrating agent using concentrated sulphuric acid

butanol soaked
with glass wool Alumina

Heat

(d) (i) Acidified potassium dichromate(VI) solution 1 2

(ii) Colourless liquid 1
(e) (i) Butyl butanoate 1 2
(ii) Two layers are formed 1
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3 (a) Alkene 1 1
(b) CH3 CH CH3 H CH CH2 CH3 1 1
or
OH OH

(c) (i) 2C3H6 + 9O 6CO2 + 6H2O 1

(ii) Gas is bubbled through lime water. 2 3

Lime water turns cloudy

(d) Correct set up apparatus 1 1

Label

(e) Acidified potassium dichromate (VI) solution 1 1

(f) (i) C2H5COOC3H5 Label C2H5COOC3H5 2

(ii) Float on the water 1 3

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4 (a) (i) Compound contains carbon and hydrogen only. 1 5

(ii) C8H18 1
(iii) C4H9 1
(iv) 1. Correct formula of reactant and product. 1
2. Balance the equation. 1
Answer:
C8H18 + 25/2O2 8CO2 + H2O//
2C8H18 + 25O2 16CO2 + 18H2O.
(b) (i) Two or more compound with the same molecular formula 1 5
and different structural formula.

(ii) But-1-ene 1

(iii) H 1

H C H
H

H C C C H

H H

(iv) 1. Butan-2-ol 1
1
2. Alcohol

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5 (a) (i) Process 2 Stripping the fruits from bunches. 1 5

Process 9 Drying the oil 1
(ii) palm kernel oil 1
(iii) To avoid the fruits from become spoilt 1
(iv) Contain high amount of natural antioxidants// does not 1
contain cholesterol// contain omega-6 fatty acid easily.
(b) (i) Saponification 1 2

(ii) Sodium hydroxide 1

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(c) (i) Carboxylate ion 1 2

(ii) O 1

COO- // -C O-
(d) Forms scum in hard water. 1 1
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6 (a) (i) C4H9OH 1 4

(ii) 1. H H H H 2. H H H H 1
1
H C C C C H H C C C C H

O H H H H O H H

H H
(iii) Ethyl butanoate 1
(b) (i) Carbon dioxide 1 3
(ii) C4H10 + 13/2O2 4CO2 + 5H2O // 2
2C4H10 + 13O2 8CO2 + 10H2O
(c) 2 2
Glass wool
soaked with Porcelain
butanol chips
Butene

Water
Heat Heat

(d) 1. Butene is unsaturated hydrocarbon // has double bond 1 2

2. Butane is saturated hydrocarbon // has single bond 1
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7 (a) (i) H H O 1 3

H C C C OH

H H
(ii) Carboxylic acid 1
(iii) Food preservative/Flavouring/To make esters 1
(b) (i) CnH2n+1OH 1 4
(ii) Oxidation 1
(iii) C3H7OH + 2[O] C2H5COOH + H2O 2
(c) (i) As a catalyst 1 3
(ii) Propyl propanoate 1
(iii) Sweet/Fragant/Fruity smell 1
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8 (a) H H H H 1 1
H C C C C H

O H H H

(b) (i) C4H8 1 3

(ii) 1. Insoluble in water // Soluble in organic solvent 1
2. Low melting/ boiling point 1
(c) (i) Acidified potassium dichromate (VI) solution // 1 2
Acidified potassium manganate (VII) solution
(ii) Orange to green // Purple to colourless 1
(d) (i) H O H H H H 2 4

H C C O C C C C H

H H H H H H

Butyl ethanoate
Butil etanoat
(ii) Act as catalyst // dehydrating agent 1
(iii) As flavouring agent // To make cosmetics 1
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9 (a) CnH2n+1OH 1 1
(b) (i) Ethanoic acid 1 4
(ii) 1. Add Magnesium / zinc / marble chips / calcium carbonate 1+1
into compound P in a test tube,
2. Gas bubbles produced
(iii) Sodium hydroxide 1
(c) (i) Esterification 1 4
(ii) Colourless liquid // sweet fruity smell // less dense than water // 1+1
does not dissolve in water. (any 2)
(iii) O 1

CH 3 C O CH2 CH2 CH3

(d) 1+1 2
Physical properties Uses
Colourless / volatile / As a solvent in perfumes /
miscible with water / good cosmetics / toiletries // As a
organic solvent thinner in varnish / ink // As a
cleaner for compact disk /
video cassette // As
Volatile / highly flammable / As a fuel
high heat content
Volatile / miscible with As a raw material to make
covalent compound / pharmaceutical products in
antiseptic antiseptic / cough syrup /
rubbing alcohols.
Chemically reactive As a raw material in the
manufacture of vinegar / fibre
/ explosive.
Any pair - correct
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10 (a) Alcohol 1 1
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(b) Propene 1

H H H 1 2

H C C C H

(c) Hot propanol of passed through hot porcelain chips 1

Propene gas/ Compound Q produced is collected in test tube 1 2

through water displacement method.

Glass wool Porcelain Propene gas

soaked with chips
p rop anol

Heat Water
1. Functional diagram
2. Labeled diagram
(d) C3H6 / Compound Q
3(12)
%C = 3(12) 6(1) x 100% //
= 85.7%
1

C3H8 / Compound R
3(12)
%C = 3(12) 8(1) x 100% //
1 2
= 81.8%
(e) Sootiness produced by propene/ compound Q is greater than 1
propane/ compound R.
Percentage of carbon by mass of propene/ compound Q is 1 2
higher.

(f) Catalyst: Niekel 1

Temperature: 180 C 1 2
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11 (a) Homologous series is a set of organic compounds in which

the formula of each one fifer from the previous one by an
extra -CH2- groups of atoms.
(b) A and E
They are unsaturated compounds which contain C=C bond in
their molecules.

(c) Addition of aqueous bromine into liquid A would produce

colourless liquid B.
(d) (i) C2H2OH + CH3COOH CH3COOOC2H5 + H2O
(ii) Ethyl ethanoate water.
(iii) A little concentrated sulphuric acid is added. It acts as a
catalyst.
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