Sec: Sr.

IPLCO
Time: 9.00 AM to 12.00 Noon Max Marks:210

Physics : Total Syllabus

Chemistry : Total Syllabus

Mathematics: Total Syllabus

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2d
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 JEE-ADVANCED-2012-P1-Model
Time: 3:00 IMPORTANT INSTRUCTIONS Max Marks: 210
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec I(Q.N : 1 10) Questions with Single Correct Choice 3 -1 10 30
Sec II(Q.N : 11 15) Questions with Multiple Correct Choice 4 0 5 20

Sec III(Q.N : 16 20) Questions with Integer Answer Type 4 0 5 20

Total 20 70
CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec I(Q.N : 21 30) Questions with Single Correct Choice 3 -1 10 30

Sec II(Q.N : 31 35) Questions with Multiple Correct Choice 4 0 5 20

Sec III(Q.N : 36 40) Questions with Integer Answer Type 4 0 5 20

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Total 20 70
MATHEMATICS:
Section Question Type ay +Ve
Marks
- Ve
Marks
No.of
Qs
Total
marks
Sec I(Q.N : 41 50) Questions with Single Correct Choice 3 -1 10 30
2d
Sec II(Q.N : 51 55) Questions with Multiple Correct Choice 4 0 5 20
bs

Sec III(Q.N : 56 60) Questions with Integer Answer Type 4 0 5 20

Total 20 70
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PHYSICS: Max.Marks : 70
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Advanced Space For Rough Work Page 2

 SECTION I
Single Correct Answer Type
This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which
ONLY ONE is correct.
1. A particle P starts from origin as shown and moves along a semicircular path. Another
particle Q crosses x axis at the instant particle P leaves the origin. Q moves with constant
speed V parallel to y axis and is all the time having y co-ordinate same as that of P.
When P reaches diametrically opposite point A, its average speed is :
Y

V
P X
O Q

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V V
(A) V (B ) (C ) (D ) V
2 2

2. ay
If y 1 5 m m sin t is the equation of oscillation of source S 1 and

y 2 5 m m sin t / 6 be that of S 2 and it takes 1 s and 1/2 s for the transverse waves to
2d
reach point A from sources S 1 and S 2 respectively then the resulting amplitude at point A, is
bs

:
A
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S1 S2
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(A) 5 2 3 m m (B) 5 3 m m (C) 5 mm (D) 5 2 m m

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Advanced Space For Rough Work Page 3

3. The average and effective values for the wave shape (positive half cycles of sine curve)

shown in the figure are :

Vm
(radian)
O
2 3

2 Vm Vm Vm
(A) V m and (B ) and
2 2

2 Vm Vm Vm
(C ) V m and (D ) an d
2

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2 2

4. A smooth tunnel is dug along the radius of the earth that ends at the centre of earth. A ball is
ay
released from the surface of earth along the tunnel. If the coefficient of restitution is 0.2
2d
between the end of tunnel and ball then the total distance travelled by the ball before second
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collision at the centre of earth is

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6 7 9 3
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(A) R (B) R (C) R (D) R

5 5 5 2
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Advanced Space For Rough Work Page 4

5. Two particles execute SHM along x-axis about the origin with same amplitude a and
frequency . At a certain instant, they are found at a distance a/3 from the origin on opposite
sides but their velocities are in the same direction. What is the phase difference between the
two? [Assume that the particles do not collide]
7 5 4 1
(A) cos 1 (B) cos 1 (C) cos 1 (D) cos 1
9 9 9 9

6. A cubical wooden block of side L and relative density 0 .5 is floating on the surface of water

as shown in the figure. A string is attached to it through an ideal pulley fixed to the bottom of

vessel as shown in figure. The graph of tension T in the string vs distance of the bottom of

the block from the free surface of the water when the end A of the rope is slowly pulled up

will be (block is moving very slowly and the vessel is very wider):

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T
L
A

ay
2d

T
bs

T T T

(A) (B) (C) (D)

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Z Z
Z Z
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7. In a bicycle speedometer , a bar magnet is attached to the spokes of the wheel and a coil is
attached to the frame so that the north pole of the magnet moves past it once for every
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Advanced Space For Rough Work Page 5

 rotation of the wheel. As the magnet moves past the coil, a pulse of current is induced in the
coil. A computer then measures the time between consecutive pulses and computes the
bicycles speed. Figure shows the magnet about to move past the coil. Which of the graphs
best represents the resulting current pulse? (Take counter clockwise current in figure to be
positive):
frame

Magnet Plane of coil is

(north pole facing nearest to you than
the viewer) that of magnet

I I I I

(A) t (B) t (C) t (D) t

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8. Consider three closed loops drawn using solid line in the magnetic field (magnetic field lines
are drawn using dotted line) of an infinite current-carrying wire normal to the plane of paper
as shown.
1
ay
2d
2

3
bs
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If a,b and c represent the values of line integrals of the magnetic field along the paths 1,2 and
3 respectively, then :
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(A) a b c (B ) a c b (C ) a b c (D ) c b a
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9. A sample of gas is heated by three different methods from same initial state as shown. In
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each method, heat supplied is same. In method I piston moves up by some amount. In
Advanced Space For Rough Work Page 6
 method II piston moves down and in method III piston does not move. Specific heat of the

gas calculated in each of the methods to be C I , C II and C III respectively. If the piston, walls of

vessel are made of insulators and piston is friction less, then

fixed
(I) (II) (III)
Gas Gas Gas

Heater Heater Heater

(A) C I C II C III (B) C II C I C III (C) C III C I C II (D) C I C III C II

10. A dielectric slab of area A and thickness d is inserted between the plates of capacitor of area
2 A and distance between the plates d, with a constant speed V as shown in figure. The
capacitor is connected to a battery of emf . The current in the circuit varies with time as:
(Current through the cell in the direction of emf is positive)

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E
V
ay
2d
2

I I
I
I
bs

(A) t (B) (C) (D)

t t
t
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SECTION II
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Multiple Correct Answer(s) Type

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This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONE or MORE are correct.
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Advanced Space For Rough Work Page 7

11. Identical dielectric slabs are inserted into two identical capacitors A and B. These capacitors
and a chargeable battery are connected as shown in the figure. Now the slab of capacitor B is
pulled out with battery remaining connected:

A B

a b
(A)During the process, positive charge flows from a to b
(B) Finally, charge on capacitor B will be less than that on A
(C) During the process, positive work is done by the external force F, part of which appears
as heat in the circuit.
(D) During the process, internal energy of the battery increases.
12. The ammeters connected in the following circuits have zero resistance. The voltmeter in

figure (A) has infinite resistance and shows a reading 8V. The value of resistance R has not

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been specified. Which of the following circuit (s) has same current in the ammeter?

20 V
A
20 V
ay 20 V
A
20 V 6
2d
4 8 6
A R V 4
(A) (B) (C) A (D)
6
bs

6
6 6 12 6
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13. On a train moving along east with a constant speed v, a boy revolves a bob with string of
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length on smooth surface of the train, with same constant speed v relative to train. Mark
the correct option (s).
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Advanced Space For Rough Work Page 8

 v v

,
(A) Maximum speed of the bob is 2v in ground frame.
2
4mv
(B) Tension in string connecting the bob is at an instant.
2
mv
(C) Tension in string is at all the moments.
(D) Minimum speed of bob is zero in ground frame.
14. A particle is moving with constant momentum P along line MN as shown in figure. Line
AB is parallel to MN. Mark the correct statements.
y

M
B
P

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45
x
O

A
N
ay
2d
(A) Angular momentum of particle about any point on line MN is zero.
(B) With respect to any reference point on line AB, angular momentum vector of the particle
is constant.
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(C) With respect to any reference point in xy - plane in third quadrant, angular momentum
vector of the particle is in positive z -direction.
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(D) With respect to any reference point in xy - plane in third quadrant angular momentum
vector of the particle is in negative z -direction.
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15. In a photoelectric effect experiment, if f is the frequency of radiation incident on the metal
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surface and I is the intensity of the incident radiations, then mark the correct statement(s).
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Advanced Space For Rough Work Page 9

 (A) If f is increased keeping I and work function constant then stopping potential and
maximum kinetic energy of photoelectron increase.
(B) If distance between cathode and anode is only changed then stopping potential remains
same.
(C) If I is increased keeping f and work function constant then stopping potential remains
same and saturation current increases.
(D) Work function is decreased keeping f and I constant then stopping potential and
maximum kinetic energy of photoelectrons increase.
SECTION III
Integer Answer Type
This section contains 5 questions. The answer to each question is single digit integer, ranging from 0 to 9 (both
inclusive).
16. The principal section of glass prism is an isosceles P Q R with P Q P R . The face PR is
silvered. A ray is incident perpendicularly on face PQ and after two reflections, it emerges

from base QR, normal to it. The angle of the prism is given by rad. Find the value of .

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17. A balloon is filled with helium at the atmospheric pressure P0 . The volume of the balloon is
ay
V0 . The balloon is made of the material of density and its mass is m. After being released,
the balloon bursts at an altitude where the atmospheric pressure is P0 / 2 . Just before
2d
bursting, the balloon has a volume of 1.25 V0 . If the maximum stress that the balloon
750
material can withstand is given by P0 , find the value of k. Assume that the temperature
bs

k
of helium remains constant, the balloon remains spherical, thickness of balloon material is
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very small when compared with radius and the density of the material remains virtually
constant. [Take : V 0 8 m 3 , 1500 kg / m 3 , m 18 kg ]
18. Two tuning forks A and B each of natural frequency 85 Hz move with velocity 10m/s
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relative to stationary observer O. Fork A moves away from the observer while the fork B
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Advanced Space For Rough Work Page 10

 moves towards him as shown in the figure. A wind is blowing with a speed 10 m/s in the

direction of motion of fork A. Find the beat frequency measured by the observer in Hz. [Take

speed of sound in air as 340 m/s]

A B

19. The internal energy of a monoatomic ideal gas is 1.5 nR T . One mole of helium is kept in a

.in
cylinder of cross-section 8 .5 cm 2 . The cylinder is closed by a light frictionless piston. The

ay
gas is heated slowly in a process during which a total of 42 J heat is given to the gas. The

temperature rises through 2 0 C . The distance moved by the piston is given as 0 m in

2d

25
bs

scientific notation. Find the value of . [Take R in SI units, atmospheric

3
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pressure=100kPa]

20. Three small balls of equal mass m are connected by light insulating inextensible threads of
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length each and kept on a level smooth non-conducting ground. The balls A and B are
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Advanced Space For Rough Work Page 11

 given charge Q each. The strings are all taut. The string connecting A and B suddenly snaps.

What is the maximum speed (in m/s) of C during the resulting motion? Q 1 C , 1.5m ,

mass m=1g.

Q Q
m A B m

C
m

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2d
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CHEMISTRY: Max.Marks : 70
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SECTION I
Single Correct Answer Type
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This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.
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21. Which of the isomeric compounds would you expect to have the lowest boiling point
Advanced Space For Rough Work Page 12
 O NH O
NH 2
(A) (B) (C) N (D)
NH 2 O O

dry 1. Z
22. X M g Y CH 3 CH 2 CH 2 OH
ether
2. H 3 O

Identify X and Z in the above sequence of reaction

O
CH 3Br and CH 2 CH CH 3
(A) C H 3C H 2 Br and H C H O (B )
(C) CH 3 Br and CH 3CH 2 CHO (D) CH 3 Br and CH 3CHO
23.
FeCl
CH 2 CH 3 Cl2 3
Cl CH 2 CH3

Which of the following is a key intermediate in the reaction shown above.

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(A) C H CH 3 (B) C H CH 3
2d

(C) Cl CH 2 CH 3 (D) Cl CH 2 CH3
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24. A pyranose form is a cyclic hemiacetal with a six-membered ring. Which of the following
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compounds can not exists in pyranose form

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Advanced Space For Rough Work Page 13

 CHO CH2OH
CH2OH CHO
H OH O
O HO H OH
H
H OH H OH
(A) (B) H OH (C) H OH (D)
H OH H OH
H OH H OH H
HO H OH
H OH CH2OH
CH2OH
CH2OH CH2OH

25. The equation of state of a gas is ( P aT 2 / V )V C ( R T b ) where a, b, c and R are

constants. The isotherms can be represented by P AV m BV n where A and B depends

only on temperature and

(A) m c and n 1 (B) m c and n 1

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(C) m c and n 1 (D) m c and n 1

26.
(A) 8 / 9 (B ) 9 / 8 (C ) 4 / 3
ay
A sample of Fe x O contains one Fe(III) for every three Fe(II). Then the value of x will be
(D ) 6 / 5
2d
B C
27. Liquid A undergoes self ionization to form B and C with the equilibrium 2A
bs

for the equilibrium is 10 30 . How many C ions are present per cc of the liquid A
(assuming A behaves like a base).
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(A) 10 8 (B) 10 15 (C) 6.023 10 5 (D) 12.04 10 5

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28. In the following sub questions choose the correct answer from among the following
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possibilities and select correct code of your answers (Answer of P,Q R and S respectively ):

Advanced Space For Rough Work Page 14

 (P) The most stable low valent halide (1) G eX 2 (2) SnX 2 (3) PbX 2

(Q) A non existing halide (1) SnC l 4 (2) PbC l 4 (3) P bI 4

(R) A purely acidic oxide (1) PbO 2 (2) SnO 2 (3) SiO 2

(S) Thermally most stable hydride (1) N H 3 (2) PH 3 (3) AsH 3

(A) 3,2,1,3 (B) 1,3,3,1 (C) 3,3,3,1 (D) 1,1,1,3

2
29. Assume that Fe H 2 O ion is a high spin complex and the enthalpy of hydration of Fe
2
6

ion is -12.4kcal/mole which is higher than that expected in the absence of crystal field

stabilization energy then the estimated value of 0 for this ion is

1 1
(C) 1808.4cm 1 (D) 10850cm 1

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(A) 7234cm (B) 8680cm

0
30. Given the data at 25 C

Ag e Ag ; E 0.800 V
0
ay
2d

A gI e A g I ; E 0.152 V
0
bs

then the value of log K sp for AgI is

(A) -16.13 (B) +8.612 (C) -37.83 (D) -8.12

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SECTION II
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Multiple Correct Answer(s) Type

This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
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which ONE or MORE are correct.

31. Which of the following represents a pair of constitutional isomers?
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Advanced Space For Rough Work Page 15

 and
(A)
(B) CH 3 CH 2 CH CH 2 an d CH 3 CH CH C H 3
Br Br Br H
and
H H Br H
(C )

and
OH O
(D )
32. Some statements are given about following compound
O
CH3 C CH 2 CH OCH 3 2

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Identify correct statements
(A) It gives yellow precipitate with I 2 in aq N aO H Solution
(B) It doest form silver mirror with Tollens reagent ay
(C) One of Hydrolysis products of given compound gives red precipitate with Benedicts
2d
solution
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(D) Both, the given compound and its one of hydrolysis products gives positive test with

2, 4 DNP
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33. Which is incorrectly matched for refining of metals?

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(A) S i , G e from impurities zone refining method

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Advanced Space For Rough Work Page 16

 (B) Copper refined from its metaloxide cupellation method

(C) Al from impurities Hoops method

(D) Z n , C d from impurities with high boiling point liquation

34. In the aqueous solution of soaps above CMC :

(A) the cations associate to form the aggregates and not directed towards water.

(B) the anions associate to form the clusters of colloidal dimension

(C) the polar ends of the ions forming the clusters are directed towards water

(D) the non-polar (hydrocarbon) ends are directed towards water

35. Which of the following reactions give the same nitrogen containing gaseous product?
(A) Heating of N H 4 N O 2

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(B) By passing N H 3 over heated C u O
(C) Heating of Ba ( N 3 ) 2 ay
(D) C u cold and dilute H N O3
2d
SECTION III
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Integer Answer Type

This section contains 5 questions. The answer to each question is single digit integer, ranging from 0 to 9 (both
inclusive).
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36. The enthalpy of monoatomic gas at 27 0 C is 300 y calorie then the value of y is
37. How many of the following would be expected to give a positive test with Benedicts
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reagent?
D-Galactose D-Fructose Sucrose D-ribose
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Lactose Gluconic acid Maltose

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38. Number of chlorine atoms present in a molecule of organic product of following reaction
Advanced Space For Rough Work Page 17
 Cl O

+ CCl3 C H
H 2SO4

Chlorobenzene Trichloroacetaldehyde
39. The no of the possible orbitals (upto n = 3) which fulfill all the following conditions
C ase I having only one radial node
C ase II having XY plane as angular node
C ase III having only two maxima if a curve is plotted between radial
distribution function vs radial distance

A certain reaction Bn+ is getting converted to B

n 4
40. in solution. The rate constant of this

reaction is measured by titrating a known volume of the solution with a reducing agent which

.in
reacts only with Bn+ and B(n + 4)+. In this process it converts

n - 2 and B n 4 n 1
B
n
to B to B ay
. At, t 0 , the volume of reagent consumed is
2d
25 ml and at t = 10 minute, the volume used is 32 ml. If the rate constant for the conversion

of B n of B
4
is x 10 2 m in 1 , then the value of x is (Near by Integer)
n
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MATHEMATICS: Max.Marks : 70
SECTION I
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Single Correct Answer Type

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This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.
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Advanced Space For Rough Work Page 18

 n n
n 1
41. If tr
8
( n 1)( n 2)( n 3) then tr

r 1 r 1
n ( n 1) n ( n 1) n ( n 1) n ( n 3)
(A) (B ) (C ) (D
( n 2)( n 3) 2( n 2)( n 3) ( n 1)( n 2) 2( n 1)( n 2)
p
32 10 2 r 2 r

42. (3 p 2 ) sin i co s =
11 11
p 1 r 1
(A) 4 8i (B) 1 6 (1 i ) (C) 4 8(1 i ) (D) 1 6 ( i 1)
n 2
43. If 1 x C 0 C1 x C 2 x 2 ........ C n x n then Ci Cj
0i j n

(A) n 1 2 n c 2 2 n (B ) n 2 n c 22n
n n

(C ) n 1 2 n c 2 n (D ) n 2 n c 2 n
n n

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44. If two small squares of selected at random from a chess board then the probability that they
have exactly one common vertex is

(A)
144
1
(B )
7
72
(C )
72
1
ay (D )
144
7
2d
n 3
r 8
45. lim
n r 3 r 3 8
bs

1 2 3 4
(A) (B ) (C ) (D )
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7 7 7 7

2
n
46. The largest term of the sequence a n is
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3
n 200
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(A) a 6 (B ) a 7 (C ) a 8 (D ) a 9
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Advanced Space For Rough Work Page 19

47. The range of values of for which the line 2 y gx is a normal to the circle

2 2
x y 2 gx 2 gy 2 0 for real values of g is

(A) [1, ) (B) [ 1, ) (C) (0,1) (D) ( ,1]

48. ( x 1)( y 2 ) 5 and ( x 1) 2 ( y 2 ) 2 r 2 intersect in the points A,B,C,D and the

centroid of the triangle ABC lies on the line y 3 x 4 . Then the locus of D is

(A) y 3 x (B ) x 2 y 2 3 x 1 0

(C ) 3 y x 1 (D ) y 3 x 1

49. The position vectors of the point A,B,C are respectively

i j 3 k , 2 i j 2 k and 5 i 2 j 6 k . If the internal angular bisector of A in A B C

.in
meet BC at D then the length of AD is

(A)
1
(B )
11
(C )
15
ay (D )
3 10
4 2 2 4
2d
50. The number of roots of the equation cos 7 x sin 4 x 1 in the interval , is
bs

(A) 4 (B ) 3 (C ) 2 (D ) 1
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SECTION II
Multiple Correct Answer(s) Type
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This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONE or MORE are correct.
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Advanced Space For Rough Work Page 20

 dx
51. =
1 x 1 x x
2

2 2
1 2 1 x x 1 1 x x 1
(A) cos C (B) 2 tan C
5 ( x 1) 2

3x 1 3x 1
(C) sin 1 C (D) sin 1 C
5( x 1) 5 ( x 1)

52. The tangent at a point P on a curve meets X-axis in A. If the area of the triangle O A P (O is

origin) is a 2 (a constant), then the equation of the curve is

2 2 2 2
a a a a
(A) x cy (B) y cx (C) x cy (D) y cx
y x y x

If the roots of the equation x 2 ax b 0 ( a , b R ) have absolute value less than 1, then

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53.

(A) b 1 (B ) a b 1 (C ) b a 1 (D ) a b 0

54.
ay
Let A,B,C be square matrices of same order and I is the unit matrix of same order such that
2d
A B C AB BC CA . Consider the following statements

(i) A B C A C C A (ii) B C A B A A B (iii) C A B C B B C

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(A) (i) and (ii) are equivalent (B) (ii) and (iii) are equivalent
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(C) (i) and (iii) are equivalent (D) (i) , (ii) and (iii) are equivalent
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55. Which of the following statement is / are correct

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Advanced Space For Rough Work Page 21

 1 1 3
(A)The number of solutions of equation T an 1
x
T an belonging to the
2 3
1 x x 4

interval (0,1) is 2

(B) T a n 1 1 T a n 1 1 T a n 1 1
Tan
1 1
....
to n terms is
2 8 18 32

1 1
T an
4 2n 1

(C) If 0 x 1 and sin 1 x cos 1 x tan 1 x , then
4 2

4 1 7
(D) The value of Sin 1 sin C os cos is
3 6 2

SECTION III
Integer Answer Type

.in
This section contains 5 questions. The answer to each question is single digit integer, ranging from 0 to 9 (both
inclusive).

56. ay
The letter of the word MOTHER are arranged in all possible ways and the resulting words
2d
are arranged as in DICTIONARY. If the rank of the word is K, then the number of positive

integral divisors of K is
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57. In the triangle ABC, points K and L are taken on the segments AB and BC such
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that A K : K B 1 : 2 and B L : L C 1 : 2 . Let P be the point of intersection of the lines A L and

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CK . If the area of B C P is 2 square units then twice the area of triangle ABC is
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Advanced Space For Rough Work Page 22


2 x (1 sin x )
58. If I 2
dx , then the integral part of I is

1 cos x

2 2
x y
59. If the tangent to the ellipse 1 at the point a cos , b sin meets the auxiliary
2 2
a b
circle in two points A,B such that the chord AB subtends a right angle at the centre, then the
1
eccentricity of the ellipse is where ( ) 2
2
sin

tanA tan B cb
60. In triangle ABC, then 2 tan 2 A
tan A tan B c

.in
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2d
bs
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Advanced Space For Rough Work Page 23