0% found this document useful (0 votes)
69 views

Tutorial 02

The document discusses concepts related to ionic conductivity in solid electrolyte materials. It describes how ionic conductivity is affected by increasing the concentration of charge carriers like dopant ions or acceptor atoms. The ionic conductivity increases with higher concentrations of these charge carriers up to a point, but then decreases at very high concentrations as the ions begin to interact and interfere with each other's motion. Proper doping levels must be achieved to maximize conductivity in solid electrolyte materials.

Uploaded by

Mohab Sameh
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
0% found this document useful (0 votes)
69 views

Tutorial 02

The document discusses concepts related to ionic conductivity in solid electrolyte materials. It describes how ionic conductivity is affected by increasing the concentration of charge carriers like dopant ions or acceptor atoms. The ionic conductivity increases with higher concentrations of these charge carriers up to a point, but then decreases at very high concentrations as the ions begin to interact and interfere with each other's motion. Proper doping levels must be achieved to maximize conductivity in solid electrolyte materials.

Uploaded by

Mohab Sameh
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 7

q !

--
o
Nqruffdrd,s(-s
rCui"n o-[ 3

d . .
cxtf instc nemi(ondufhrs

rnolaa tho:rn '"'"sL ''r'too.ir,,-0


-- [he p-oper[ 9{ ao*^;c"^*^cfor dra't-
B -;f;on!o*o*t Jror,rcoo-,.od,of Jfi!i'"c"'"i-cBJ{ rno;b"
ir-br'.d#J. qlr^,rb''d-.t..?'.r^S"'e- -b crSsfalL)tDtJta-

'l-ho. colhro\te-d. imgrri[toz lo o-semriovr'd'rrlar (s'c)


iocoo, e{ addr^2
1qlenoun as gspq-,
Irre qvnarnt-oPtr-piqlUenb added- !o irkinstc s." wu'o'rb
.Ald o{cD"A,clarq---- dT"A S'c .^,' cqeaA czMnsic S-c'

dopnts o'e clnaa.f<i-dos' 2dorv's


.L 6ercrotr \ A<captors

ja smfl1 63 orcaLo^ o$ eorri ets


. S" ; dog'"g qrocoad T"-,".
i r''.pur it'r-oaanc introdr'^ced,
,b t.,".nr.t- con dr chvtb , dh4t!!- 1^1hen
o.dA^horn4LQ-!^11Q,ur1- criF^d. i'n enerql ba"d Shrudtrre- t,suolQ ttrlfhtn\'u
r-,\ oo J
-L) onors g
+irnprrrfhl zrnqh,r';*i. +^6t (34.!rt/" 9 u{ p'cd^t Tabl.o
Q,As,Sb)

-yTnlro ducoo *tj f" con&ptin'' b"" d $ lto/


OurL "<n6vra'o,r
tuiVh e\achrons4f O K.
-\!,.rmn\
--- V"rl Qifrlc <r !./\ti .^j, r^ellrr'r4L G e+")- egu]'rot:
b L6.

I
Si ojo. ce{d 0
abm
f bt Hs cond..<bLn eQ4cttort3
oJ N &rcr olaas

'f c
E.-go
\+ d.r.. tevel .
Eo
fnko&.!rd lau.l

conducliq
) '
et4cVovr

g
a"'-
Ev

(co"&ci,l"nl -0't- -"'0oni&'srnoll biodntrj


.S,$fA ofuchron *d"*t)
betamto"o- cDtdnclion
u- 'iiJlnro t;'tr'/- &AA
er"t/t* ond- c-a'
of a w'odero'te bevnpevotur<-'
e-l.l#on
roomtemp'
-D"out g.g. rli Fh dono{- c'fDmI hos n >> ni 'Q of
.
'ddihono}nc3ohve
id -U* o{ s'c' is c'$.d' jo+.id.,ob
C-horq<- <4{d'{'

*3gP'-- yr 4 q| f"-* t"u- (Ct,]i


,-^-.^0[^o"ncs&r,"
mareria-l'
G inD.triqa tt
l 6
sel 'Ea
noan- ' ttttd[
Vq'\a'n<au"nd-
-+T^v"flt* 4t''"1f1 -Ol'd-
a.F oK.

.- \erq -lrHir-Tntt,.^!- !t-ft1 .,b -'u1ur'"ul l" <'aifo d b


A,.lf!." -Qo,el. , -Iao,'n{ ff'P5 behrad '
\7

L-
cc

?r."+od

Tov"a,aA ft<a-par larl


Ev
In4Dbt le \ Ev
i?i'.'.i;--*.
(l-hortes

rntznq- 4oles d.r-a.G N


On$ l-h ret- Vqtcnc_a.
e ,to con*;ro4ft, acccPbr afoms
b &"qbnt- B".d =; 4 {veeshte
"' cmq\\ "T* ^nt "of *^l- br on d l,o rrrqnsRr
t" U^,b-!r^{.
+ -$4n(!- .a hopgrnX{."- b"d to .Lurd.
{aco,tt-

. D'P" orcrphor otums hq>


a. c .rr.r-,\i^.,
? >) nc l vr o,l_roo.r, fernp.

"rfu {1o ofls.c.u *ro-d---q4g; du-t" o.Ad.bo,ol


posrf'.,-
.afn'erS.
C-lua-g<,

dVo\g
\,{" *&" -b -stnq\\ no- a L \oles un n Eo<- o.s minocltry cafriers
ul
or,rL ^r^efairw& [a1qe v1o-g-{- et<cw-oros
.^ C'8. aa {hq/p.;14-
0 { - {
C-oJwiet6.

& Oppo6iEP-. ?gp"_.


A,/oacb4eneraG, S.c.
.o---------.(--
:> When nrp(( No,Nv
4t@eIqtqlg+----- E - 9 - L vo r L " - E p , < 3 K T

-ronieed
Ait {o*. imguclh'eso"re
i...U-L.oqr'*'o"tJ *q!- -n.e h t" b' io.id' $
,-to 3..4b
"L^ T..fd-B
a*Jn-" l='"d '
,-rno'e La c4orheF
(
, 'h
-

-* AT rocrn Letap ,flvo- .r. .!auo-00l{


=o^n,Zt^fhmvnal-^ay 1",
"".iLe brirzql4oL.-':

":, Sqrn,nur, ber oQ dor-r of,orng wi tl \c<- C-old,{I_o,t, e\Lc,fY or'ts


(Qroui dc-d- t n Csn d.,^db^ Band.
-\ Vo) : ND +c-,.pton- <an,a,r,o-

$rm,\o.!& . , P r . ,{\\ accl$ur- intpurvils o/c '''nl trd aL c*tn {e'ng

=) ( ,lv6 = N o ) o itt^tzatro"
Wb

Cqrrl "" ccrrc en kof*c,*

qfi6E).,=
*a
N" u-(fuEd
o.s n iocreq:es- Es-Eg .,,i\\ decreasc,
c^Jhich rrea.ma Jfio-ts 5tro11"n-enz{g\t W\g^<s- &tw<erL-
RRr-i.Qc"Oo"d b.^d,r.ib "-ua'tL -

io&cato- -fhal-
tnjlrr;cn n>?
or. hgha-" d' c-onc ' th-o"u- \acl-o-cor,.c-'
P(e) h(e)
NCE)

C.>-" -. Ee ncar c- ---> n(E) I >> pfS)


Wrooctva

x 3i-'ln' t1 ;9. P8* -,^rhl"*- (!g -E.,,) uri\\ dacre-rl" __5.


Ep opgroochesEv.

* LbtrDensqlId s.L.
t _

:> fP b6\h do^oc & occophorim?''rcihles q-tra gresenb simultoruovsla.


'r
ttrc ,ingdq raritVr, gvea&-t-, c-o^carr.tfth:on &bevrr...--eo t,h--
"d co"-"L.n'uih rzn.sc.
tfa
- .^"{0, adffbtrtud+ 'b pceserrx-cnargL
-T:i!**
,neu.trojl_u[q \r
o-

Oio&- S.c' iS rreu,hq\ Q o dde_oLd.Qont- a_tO,rnS


qre ytsujrql).,. j*&rL
n qP" *
?%Pq s.c- G n<rl-fro\.,Ntrjch rnsa.s +habI

=-tefq{-?*,hL.X.l.-
charge
I1 :S*

,},o{ru<*:'eE>.-----,ro''i"d doh6.

lj-\6 -- P*
r + rr'i;*
vD I t \

tute
Rr <o."p\.ba ioni46666, Ni= Nn
, No*= No
+ n -- Ng ,Le"-so/rr
-(Er-E")/rr
* p -- Nv
Ge-rc)/rr
f\ = V11 -

.t( ni
?= e(Ec-EF)/Lr

+ = nitl m q s sact.ou\aul -- 2 5,t/Alrd Sr iol-f,nsfc4extvinsic


Serhi@'4duc6r onder-
Une'rmql .c.l,r-. ti br"rr'"'.

+ = t- -tl rg{Echo{ae
mrrko\
F;N--

* -ttt l -L\ t r J = I
Er^l - d'cocdsl{ !4-
,l + c^ l e r Q l <, qr*"UU1 apf'.dr,6 6 ct Energ5
E.

, . .(E-Ee)/pr Cqohdd\ .l 8"lo*U .r.rnoco.pr'ezl:tafe obF'435E'

(\b.I!) ',1(No-NO'-+ t+ni"


*
e &
& ? = ( N*-tJo) . V(No-nto)'*-ang-
Q 4

4 f99r-"1irn qbc'v1s
-.f-l--

to. Np_Nn >) n r N9- 5lg


6 R N + - N o > ) ni pI N+-No

abo''s
@3 AJoI t'>kd numberoF dor,""
D,/.b,b;t I! tVlo.t d"'"-' \"w[ iP
Mor = No Ir.fJI_') -7
r (
\cr .
)r4DrU
J
* T" Rnd nlr,mnn^ sl i 6hi.d o{ca?h,rs"" NR. lorot nu.r.*,, o.-fla.
{
o
otofns

qs o -P.,-nch.b*

cortler c.D.1L

Tntr,htic
-!-

&tt zu"'c-
intriasic co(riev-
codPoo'lct b
e*.
Scl
, c,o.ren
dolor/oc<pror
il^a G;ra -
r=rba.

T-lvr^^le*rq, T
.r-t ""1pr*Al n = N6,+=l\,l5
p ,onife all Tn trirnrc car6.r)>
rnptrt tri. Cc*,fl46'i srizoiian
u,furw- .6 <_sxaolrohira
Trpunb con..-
l6t<,Vo fornq,;yrol*r- sa1yl_a_ -'- S.c- behq rg
ftr trliAe temp r+nge. aS on tnh 0si-.e .c .

i'.

You might also like