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Problem Term o

This document contains the work of solving problems involving estimating the fugacity of cyclopentane and 1-butene. Specifically: - It calculates the fugacity coefficient at the vapor pressure for cyclopentane at 110°C and 275 bar to be 0.900 and for 1-butene at 120°C and 34 bar to be 0.76 using provided equations. - It estimates the saturation vapor volume for cyclopentane at 110°C to be 107.546 cm3/mol using provided equations involving the critical volume and temperature. - It then estimates the fugacity of cyclopentane at the given conditions to be 11.78 bar using the calculated fugacity coefficient and saturation vapor pressure.

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AnggiariniMutmainah
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261 views

Problem Term o

This document contains the work of solving problems involving estimating the fugacity of cyclopentane and 1-butene. Specifically: - It calculates the fugacity coefficient at the vapor pressure for cyclopentane at 110°C and 275 bar to be 0.900 and for 1-butene at 120°C and 34 bar to be 0.76 using provided equations. - It estimates the saturation vapor volume for cyclopentane at 110°C to be 107.546 cm3/mol using provided equations involving the critical volume and temperature. - It then estimates the fugacity of cyclopentane at the given conditions to be 11.78 bar using the calculated fugacity coefficient and saturation vapor pressure.

Uploaded by

AnggiariniMutmainah
Copyright
© © All Rights Reserved
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
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ANGGIARINI NURTHASEPTYA M.

1531010196

Question problem 11.

11.19. Estimate the fugacity of one of the following

a. Cyclopentane at 110 oC and 275 bar. At 110 oC the vapour pressure of cyclopentane is 5.267
bar.
b. 1-butene at 120 oC and 34 bar. At 120 oCthe vapour pressure of 1-butene is 25.83 bar.

Answer:

The following vectors contain data for Parts (a) and (b):

(a) = Cyclopentane; (b) = 1-butene

511.8 45.02 0.196 0.273 258 3


= ( ) = ( ) =( ) = ( ) = ( )
420.0 40.43 0.191 0.277 239.3
322.4 383.15 275 5.267
= ( ) =( ) =( ) = ( )
266.9 393.15 34 25.83


0.7486
0.117
= = ( ) = = ( )
0.9361 0.6389

Calculate the fugacity coefficient at the vapour pressure by Eq.(11.68):

(a) PHIB (1 , 1 , , 1) = 0.900

(b) PHIB (2 , , , 2) = 0.76


2

Eq. (3.72), the Racket equation:


0.749
= = ( )
0.936

Eq. (11.44):

2 3
107.546
= [ . (1) ]
7
= ( )
133.299


. ( ) 11.78
= [ ( , , . . [ ])] =( )
. 2029

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