5.0 Indoor Air Pollution
5.0 Indoor Air Pollution
Introduction
Causative agent
Source
Effect
Control method
Legislation
INDOOR AIR QUALITY (IAQ)
Indoor air quality (IAQ) is a term referring to the air
quality within and around buildings and structures,
especially as it relates to the health and comfort of
building occupants
1. COMBUSTION PRODUCTS
2. VOLATILE CHEMICALS & MIXTURES
3. RESPIRABLE PARTICULATES
4. RESPIRATORY PRODUCTS
5. BIOLOGICS & BIOAEROSOLS
6. RADIONUCLIDES
7. ODORS
CAUSATIVE AGENTS AND SOURCES
COMBUSTION PRODUCTS
Causative agents Sources
CARBON MONOXIDE (CO) KEROSENE
HEATERS
OXIDES OF NITROGEN
(NOX) LOADING DOCKS
OXIDES OF SULFUR (SOX) WOOD
CARBON DIOXIDE (CO2) STOVES/UNVENTED
GAS STOVES
POLYAROMATIC
ETIOLOGICAL AGENTS
TOBACCOSMOKE
COMPONENTS
CAUSATIVE AGENTS AND SOURCES
BIOLOGICS & BIOAEROSOLS
RADIONUCLIDES
Causative agents Sources
RADON SOIL
WATER
RADON PROGENY
(DAUGHTERS) BUILDING MATERIALS
NATURAL GAS
Geoscape.nrcan.gc.ca
CAUSATIVE AGENTS
ODORS
ODORS ASSOCIATED WITH ANY INDOOR AIR
CONTAMINANT TYPE
INDEPENDENTLY
IN COMBINATION
SOURCES
PARTICULATE PHASE OF
CIGARETTE SMOKE
4-AMINOBIPHENYL NICKEL
ANATABINE NICOTINE
ANILINE PHENOL
BENZ[A]ANTHRACENE POLONIUM-210
BENZ[A]PYRENE QUINOLINE
BENZOIC ACID SUCCINIC ACID
BUTYROLACTONE 2-TOLUIDINE
NITROSODIETHANOLAMINE CADMIUM
SOURCES
VAPOR PHASE OF
CIGARETTE SMOKE
HYDROGEN CYANIDE ACETALDEHYDE
ACETONE ACROLEIN
1,3-BUTADIENE BENZENE
CARBON MONOXIDE FORMALDEHYDE
DIMETHYLAMINE HYDRAZINE
CARBONYL SULFIDE ETHANE
METHYL CHLORIDE PYRIDINE
AMMONIA FORMIC ACID
HEALTH EFFECTS
Sick building syndrome (SBS)
Condition associated with complaints of
discomfort due to indoor air pollution
Chemical Hazards
Do Not Use Odor as an Indicator of Hazard
Certain Individuals May Be More Susceptible to
Certain Chemicals
All Chemicals Do Not Have a Permissible
Exposure Limit
RADON SUB-SLAB MITIGATION
A. Permeable gravel layer
B. Plastic
C. Seal air infiltration
D. Vent stack (labeled)
E. Junction boxes for
continuous fan
Test after occupancy;
install blower if needed
27
RADON TESTING
Use state or national-certified kits
Test radon levels in lowest habitable rooms
Follow directions on kit carefully
For levels near 4 picocuries/liter, get professional
testing
If levels are well over 4 picocuries/liter, ventilate
home and consider relocation during remediation
28
RADON MITIGATION BLOWERS
29
RADON MITIGATION WITH BLOWER
Basement location pipe
must be well sealed to roof
Blue alcohol manometer
indicates if blower is
working
30
CARBON MONOXIDE
A colorless, odorless, poisonous gas that results from
incomplete combustion of fuels
31
CARBON MONOXIDE
32
HEALTH EFFECTS OF CO LEVELS
Maximum level ASHRAE recommends in an occupied
building is 9 parts per million (ppm)
CO Level (ppm) Symptom
100 Nothing proven
200 Headache, tiredness, dizziness
400 Headaches, life threatening after three
hours
33
VOLATILE ORGANIC COMPOUNDS (VOC)
Organic compounds (contain carbon and
hydrogen) that vaporize (become a gas) at room
temperature
Examples: adhesives, manufactured woods that
release formaldehyde, carpet, cleaning products
Seal cabinets to prevent off-gassing
In laminated wood, prefer exterior glues to
interior glues
Can cause eye, nose, and throat irritations and
some types can cause cancer
34
VOC EXAMPLES
Rhinitis (nasal membrane inflammation): laser printers,
diesel exhaust
Headaches, panic attacks, and kidney problems:
solvents
Heart arrhythmias: aerosol propellants
Balance and memory difficulties connected to
formaldehyde exposure; asthma to carbonless copy
paper, perfume, and tobacco smoke; and connective
tissue diseases to some fuels, vinyl chloride, and hair
dye
35
FORMALDEHYDE IMPACTS
Formula CH2O
Irritation of eyes nose and
throat
Respiratory problems, lungs
Menstrual disorders and
pregnancy problems
Cancer (long term exposure)
36
HOUSEHOLD CHEMICALS
37
WHAT CAN WE DO ABOUT IT?
Zero or No VOC
39
LOW VOC FINISHES
40
LOW VOC FINISHES
41
ISSUES WITH CARPETING
Regular carpet
ingredients
dyes
pesticides
biocides
chemicals
odors
42
CHEMICALS IN CARPETING
Toluene - cough
Benzene - dizziness
Azulene - headaches
43
MORE CHEMICALS
Indene - rash, Dimethyl - sexual
itching dysfunction
Oxarium - muscular
Methylnaphthalene
aches - hair loss, weight
Styrene - unusual
loss or gain
depression
Polyacrylates -
Tetradecene -
respiratory tract abdominal pain
irritation
44
MINERAL ASBESTOS
Pancaketom/Dreamstime
ASBESTOS
Chrysotile Chrysotile
Amosite
Crocidolite
www.enviraz.co.uk
Robert Grieshaber
ASBESTOS
Ship insulation
Mine www.technicaon-asbestos.co.uk
Pipe insulation
Brake pads
Roofing products
oraclesolutionsltd.co.uk Locomotive insulation
HEALTH EFFECTS OF ASBESTOS
Lung cancer: 4800 deaths/yr US
Mesothelioma: 2500/yr Cancer of mesothelial membrane lining lungs
Asbestosis: 1400/yr US: Slow, debilitating lung disease
Gastro-intestinal cancer: 1200 deaths/yr
Reports.ewg.org
LIBBY, MONTANA
Vermiculite mine, which produced 80% of the worlds vermiculite, opened
in 1918. W.R. Grace Co. owned the mine from 1963-1990, during which
192 deaths and 375 lung injuries due asbestos were reported.
www.bitsofnews.com www.home-air-purifier-expert.com
ENVIRONMENTAL TOBACCO SMOKE
Mainstream smoke
Exhaled smoke
Sidestream smoke
Emitted from burning cigarette
Concentrations
One pack of cigarettes 20 mg m-3 of particles in room
over 24 hours. Near smoker, concentrations 500-1000
-3
MAINSTREAM/SIDESTREAM SMOKE
R. Kneschke/Henrischmit/Dreamstime
COMPARISON OF CIGARETTE WITH
AUTOMOBILE EMISSIONS
CO NOx Particles
Avg. cigarette emission (g/cigarette) 0.0464 0.0021 0.058
Table 9.3
INDOOR COOKSTOVE
Kacpura/Dreamstime
INDOOR WORKPLACE STANDARDS
www.ipmsafety.com
INDOOR WORKPLACE STANDARDS
NAAQS apply to outdoor pollution only in the U.S.
Table 9.4
Control Methodologies
CONTROL METHODOLOGIES
PREVENTING IAQ PROBLEMS
DAMAGED MATERIALS
UNSANITARY CONDITIONS
WATER DAMAGE
DRY TRAPS - SEWER GAS
CHEMICAL RELEASE OR OFF-GASING
CONTROL METHODOLOGIES
OTHER SOURCES
ACCIDENTAL EVENTS
SPILLS
FLOODING
FIRE DAMAGE (PCBS)
SPECIAL USE AREAS
SMOKING LOUNGES
LABORATORIES
PRINT SHOPS
ART ROOMS - GRAPHIC DESIGN
EXERCISE ROOMS
BEAUTY SALONS
FOOD PREPARATION AREAS
REDECORATING/REMODELING/REPAIR
NEW FURNISHINGS
DUST & FIBERS FROM DEMOLITION
ODORS & VOCS (PAINT, ETC.)
MICROBIOLOGICALS FROM DEMOLITION
CONTROL METHODOLOGIES
VENTILATION TO MEET OCCUPANT
NEEDS
ASHRAE STANDARDS (ASHRAE 62-
1989)
TEMPERATURE
RELATIVE HUMIDITY
MINIMUM OUTDOOR AIR REQUIREMENTS
CO2 LEVELS BELOW 1000 PPM
ENGINEERING CONTROLS
MODIFY VENTILATION SYSTEM
MODIFY PRESSURE RELATIONSHIPS
FILTERS
ENGINEERING CONTROLS
PRECIPITATORS
ION GENERATORS
CONTROL METHODOLOGIES
OTHER
CONSIDERATIONS
POPULATION DENSITY
LIGHTING
NOISE
ERGONOMICS
MANAGEMENT STYLES
MONITORED WORK
STATIONS
RE-ENTRY CRITERIA
NO NEWS IS GOOD
NEWS
CONTROL OF AIR POLLUTION
Industrial Activities
Scrubbers
Precipitators
Filters
Sulfur Removal
Switchto low-sulfur fuel.
Remove sulfur from fuel before use.
NOx
VOCs
PM
http://www.osha.gov/pls/oshaweb/owadisp
.show_document?p_table=STANDARDS&
p_id=9992
http://app2.nea.gov.sg/data/cmsresource/20090618385702933220.pdf
HONG KONG
a
8-hour average
Parameter Unit Excellent Class Good Class
b b
Room 20 to < 25.5 < 25.5
Temperature C
c
Relative Humidity 40 to < 70 < 70
%
Air movement m/s < 0.2 < 0.3
d e
Carbon Dioxide < 800 < 1,000
(CO2) ppmv
Carbon Monoxide g/m3 < 2,000 f < 10,000 g
(CO) ppmv < 1.7 < 8.7
f h
Respirable g/m3 < 20 < 180
Suspended 8 hrs!
Particulates
(PM10)
g h
Nitrogen Dioxide g/m3 < 40 < 150
(NO2) ppbv < 21 < 80
f g
g/m3 < 50 < 120
Ozone (O3) ppbv < 25 < 61
f f, g
Formaldehyde g/m3 < 30 < 100
(HCHO) ppbv < 24 < 81
f f
Total Volatile < 200 < 600
Organic g/m3
Compounds < 87 < 261
(TVOC) ppbv
i f
Radon (Rn) Bq/m3 < 150 < 200
j, k j, k
Airborne Bacteria < 500 < 1,000
cfu/m3
http://www.iaq.gov.hk http://www.iaq.gov.hk/tables.html
HIGH PRIORITY "WORST IN CLASS" CHEMICALS
86
HIGH PRIORITY "WORST IN CLASS" CHEMICALS
CONT. 1) Chlorinated building materials:
Polyvinyl chloride (PVC) often referred to as
vinyl"
pipes and conduit
water proofing
siding
roof membranes
door and window frames
resilient flooring
carpet backing
wall covering
signage
window treatments
furniture
wire
cable sheathing
87
HIGH PRIORITY "WORST IN CLASS" CHEMICALS
CONT.
Chlorinated polyethylene (CPE)
Geomembranes
wire and cable jacketing
Chlorinated polyvinyl chloride (CPVC)
water pipes
Chlorosulfonated polyethylene (CSPE)
roof membranes
electrical connectors
sheet membrane for pond liners
Polychloroprene (CR or chloroprene rubber, also brand name Neoprene)
Geomembranes
weather stripping
expansion joint filler
water seals
other gaskets and adhesives
88
HIGH PRIORITY "WORST IN CLASS" CHEMICALS
CONT.
2) PBT based material treatments
Brominated Flame Retardants (BFRs),
particularly PBDE (polybrominated diphenyl
ether)
Furniture foam and fabrics
Perfluorochemicals (PFCs) (most notably
PFOA)
Furniture & dividers - stain and non-stick
treatments, including Scotchguard, Teflon,
Stainmaster, Scotchban, and Zonyl
89
HIGH PRIORITY "WORST IN CLASS" CHEMICALS
CONT.
90
HIGH PRIORITY "WORST IN CLASS" CHEMICALS
CONT.
Lead
flashing
terne, copper and other roof products
solder
wire insulation jacketing (most PVC wiring
but apparently you can now buy even PVC
wire without lead)
Cadmium
Paint (use GreenSeal paints to avoid)
Some PVC products (as a stabilizer)
91
WHAT ALTERNATIVES ARE AVAILABLE?
Untreated chemical-free wool
carpets
no pesticides
no dyes
no biocides
Green Label carpeting
Carpet and Rug Institute program
Green Label Plus carpeting
92
GREEN LABEL CARPETING
Carpets are tested by an independent, certified
laboratory and meet stringent criteria for low
chemical emissions.
Green Label Plus is designed for architects,
builders, specifiers and facility managers who want
assurances that carpet and adhesive products
meet the most stringent criteria for low chemical
emissions.
Green Label Plus represents the fourth time the
carpet industry has voluntarily enhanced the IAQ
standard for its products.
http://www.carpet-rug.org/commercial-customers/green-building-and-the-environment/green-label-plus/index.cfm
93
AVAILABLE ALTERNATIVES
Criteria for GreenSure Designation (Sherwin-
Williams)
Products that offer maximum performance and long-term
durability
Have the highest indoor air quality ratings for low VOC
and low odor
Meet or exceed the GS-11 criteria for coatings used in
LEED-certified buildings (LEED certification means that
certain "green building" standards are met, such as
energy efficiency and indoor environmental quality)
94
THIRD PARTY VERIFICATION ORGANIZATIONS
95
GREEN BUILDING MATERIAL RESOURCES
96
ACTIVITY
Describe
causative agent
Effect on health
Control method
March 2009 UCOP Safety Meeting
Study on Printers:
Ozone Levels: <0.001 ppm to 0.016 ppm
March 2009 UCOP Safety Meeting
www.chemistryland.com www.sispropane.ca
Fireplace
www.vgtrading.com.ar www.cof.orst.edu
www.germes-online.com
Aura.gaia.com
S. Kaulitzki/Dreamstime
Pollen Fungal spores
specialcomment.wordpress.com
www.,materials.drexel.edu
Viruses
Bacteria