Cathode Ray
Cathode Ray
Contents
Description A beam of cathode rays in a vacuum tube
bent into a circle by a magnetic field
History
generated by a Helmholtz coil. Cathode rays
Gas discharge tubes
are normally invisible; in this tube enough
Cathode rays
residual gas has been left that the gas
Discovery of the electron
atoms glow from fluorescence when struck
Vacuum tubes by the fast moving electrons.
Properties
See also
References
External links
Animations and Simulations
Description
Cathode rays are so named because they are emitted by the negative electrode, or cathode, in a vacuum tube. To release electrons into
the tube, they first must be detached from the atoms of the cathode. In the early cold cathode vacuum tubes, called Crookes tubes,
this was done by using a high electrical potential between the anode and the cathode to ionize the residual gas atoms in the tube; the
ions were accelerated by the electric field and released electrons when they collided with the cathode. Modern vacuum tubes use
thermionic emission, in which the cathode is made of a thin wire filament which is heated by a separate electric current passing
through it. The increased random heat motion of the filament knocks electrons out of the surface of the filament, into the evacuated
space of the tube.
Since the electrons have a negative charge, they are repelled by the negative cathode and attracted to the positive anode. They travel
in straight lines through the empty tube. The voltage applied between the electrodes accelerates these low mass particles to high
velocities. Cathode rays are invisible, but their presence was first detected in early vacuum tubes when they struck the glass wall of
the tube, exciting the atoms of the glass and causing them to emit light, a glow called fluorescence. Researchers noticed that objects
placed in the tube in front of the cathode could cast a shadow on the glowing wall, and realized that something must be travelling in
straight lines from the cathode. After the electrons reach the anode, they travel through the anode wire to the power supply and back
to the cathode, so cathode rays carry electric current through the tube.
The current in a beam of cathode rays through a vacuum tube can be controlled
by passing it through a metal screen of wires (a grid) to which a small negative
voltage is applied. The electric field of the wires deflects some of the electrons,
preventing them from reaching the anode. The amount of current that gets
through to the anode depends on the voltage on the grid. Thus, a small voltage
on the grid can be made to control a much larger voltage on the anode. This is
the principle used in vacuum tubes to amplify electrical signals. The triode
vacuum tube was the first electronic device that could amplify, and is still used
in some applications such as radio transmitters. High speed beams of cathode
rays can also be steered and manipulated by electric fields created by A diagramatic Crookes tube showing the
connections for the high voltage supply
.
additional metal plates in the tube to which voltage is applied, or magnetic
The Maltese cross has no external
fields created by coils of wire (electromagnets). These are used in cathode ray
electrical connection.
tubes, found in televisions and computer monitors, and in electron
microscopes.
Crookes tube Cathode rays travel from the A magnet creates a horizontal
cathode at the rear of the magnetic field through the
tube, striking the glass front, neck of the tube, bending the
making it glow green by rays up, so the shadow of the
fluorescence. A metal cross in cross is higher.
the tube casts a shadow,
demonstrating that the rays
travel in straight lines.
The explanation of these effects was that the high voltage accelerated electrically charged atoms (ions) naturally present in the air of
the tube. At low pressure, there was enough space between the gas atoms that the ions could accelerate to high enough speeds that
when they struck another atom they knocked electrons off of it, creating more positive ions and free electrons in a chain reaction,
known as a Townsend discharge.
The positive ions are attracted to the cathode. When they struck it, they knocked many electrons out of the metal. The free electrons
were all attracted to the anode.
Geissler tubes had enough air in them that the electrons could only travel a tiny distance before colliding with an atom. The electrons
in these tubes moved in a slow diffusion process, never gaining much speed, so these tubes didn't produce cathode rays. Instead, they
produced a colorful glow discharge (as in a modern neon light), caused when the electrons or ions struck gas atoms, exciting their
orbital electrons to higher energy levels. The electrons released this energy as light. This process is calledfluorescence.
Cathode rays
By the 1870s, British physicist William Crookes and others were able to evacuate
tubes to a lower pressure, below 10−6 atm. These were called Crookes tubes.
Faraday had been the first to notice a dark space just in front of the cathode, where
there was no luminescence. This came to be called the "cathode dark space",
"Faraday dark space" or "Crookes dark space". Crookes found that as he pumped
more air out of the tubes, the Faraday dark space spread down the tube from the
cathode toward the anode, until the tube was totally dark. But at the anode (positive)
end of the tube, the glass of the tube itself began to glow
.
What was happening was that as more air was pumped from the tube, the electrons
could travel farther, on average, before they struck a gas atom. By the time the tube
was dark, most of the electrons could travel in straight lines from the cathode to the
anode end of the tube without a collision. With no obstructions, these low mass A Crookes tube. The cathode rays
travel in straight lines from the
particles were accelerated to high velocities by the voltage between the
cathode (left) and strike the right wall
electrodes.These were the cathode rays.
of the tube, making it glow by
fluorescence.
When they reached the anode end of the tube, they were traveling so fast that, although they were attracted to it, they often flew past
the anode and struck the back wall of the tube. When they struck atoms in the glass wall, they excited their orbital electrons to higher
energy levels, causing them to fluoresce. Later researchers painted the inside back wall with fluorescent chemicals such as zinc
sulfide, to make the glow more visible.
Cathode rays themselves are invisible, but this accidental fluorescence allowed researchers to notice that objects in the tube in front
of the cathode, such as the anode, cast sharp-edged shadows on the glowing back wall. In 1869, German physicist Johann Hittorf was
first to realize that something must be traveling in straight lines from the cathode to cast the shadows. Eugen Goldstein named them
cathode rays.
The debate was resolved in 1897 when J. J. Thomson measured the mass of cathode rays, showing they were made of particles, but
were around 1800 times lighter than the lightest atom, hydrogen. Therefore, they were not atoms, but a new particle, the first
subatomic particle to be discovered, which he originally called "corpuscle" but was later named electron, after particles postulated by
George Johnstone Stoney in 1874. He also showed they were identical with particles given off by photoelectric and radioactive
materials.[4] It was quickly recognized that they are the particles that carry electric currents in metal wires, and carry the negative
electric charge of the atom.
Thomson was given the 1906 Nobel prize for physics for this work. Philipp Lenard also contributed a great deal to cathode ray
theory, winning the Nobel prize for physics in 1905 for his research on cathode rays and their properties.
Vacuum tubes
The gas ionization (orcold cathode) method of producing cathode rays used in Crookes tubes was unreliable, because it depended on
the pressure of the residual air in the tube. Over time, the air was absorbed by the walls of the tube, and it stopped working.
A more reliable and controllable method of producing cathode rays was investigated by Hittorf and Goldstein, and rediscovered by
Thomas Edison in 1880. A cathode made of a wire filament heated red hot by a separate current passing through it would release
electrons into the tube by a process calledthermionic emission. The first true electronicvacuum tubes, invented in 1904, used this hot
cathode technique, and they superseded Crookes tubes. These tubes didn't need gas in them to work, so they were evacuated to a
lower pressure, around 10−9 atm (10−4 Pa). The ionization method of creating cathode rays used in Crookes tubes is today only used
in a few specialized gas discharge tubes such as krytrons.
In 1906,Lee De Forest found that a small voltage on a grid of metal wires could control a much larger current in a beam of cathode
rays passing through a vacuum tube. His invention, called the triode, was the first device that could amplify electric signals, and
founded the field of electronics. Vacuum tubes made radio and television broadcasting possible, as well as radar, talking movies,
audio recording, and long distance telephone service, and were the foundation of consumer electronic devices until the 1960s, when
the transistor brought the era of vacuum tubes to a close.
Cathode rays are now usually called electron beams. The technology of manipulating electron beams pioneered in these early tubes
was applied practically in the design of vacuum tubes, particularly in the invention of the
cathode ray tube (CRT) by Ferdinand Braun
in 1897, which was used in television sets and oscilloscopes. It is today employed in sophisticated devices such as electron
microscopes, electron beam lithographyand particle accelerators.
Properties
Like a wave, cathode rays travel in straight lines, and produce a shadow when obstructed by objects. Ernest Rutherford demonstrated
that rays could pass through thin metal foils, behavior expected of a particle. These conflicting properties caused disruptions when
trying to classify it as a wave or particle. Crookes insisted it was a particle, while Hertz maintained it was a wave. The debate was
resolved when an electric field was used to deflect the rays by J. J. Thomson. This was evidence that the beams were composed of
particles because scientists knew it was impossible to deflect electromagnetic waves with an electric field. These can also create
mechanical effects, fluorescence, etc.
Louis de Broglie later (1924) showed in his doctoral dissertation that electrons are in fact much like photons in the respect that they
act both as waves and as particles in a dual manner as Einstein had shown earlier for light. The wave-like behaviour of cathode rays
was later directly demonstrated using a crystal lattice byDavisson and Germer in 1927.
See also
α (alpha) particles
β (beta) particles
Deflection yoke
Electron beam processing
Electron microscope
Electron beam melting
Electron beam welding
Electron beam technology
Electron gun
Electron irradiation
Ionizing radiation
Particle accelerator
Rays:
γ (gamma) rays
n (neutron) rays
δ (delta) rays
ε (epsilon) rays
Sterilisation (microbiology)
CRT screen
References
1. E. Goldstein (May 4, 1876)"Vorläufige Mittheilungen über elektrische Entladungen in verdünnten Gasen"(https://boo
ks.google.com/books?id=7-caAAAAYAAJ&pg=PA279#v=onepage&q&f=false)(Preliminary communications on
electric discharges in rarefied gases),Monatsberichte der Königlich Preussischen Akademie der W issenschaften zu
Berlin (Monthly Reports of the Royal Prussian Academy of Science in Berlin), 279-295. From page 286:13. " Das
durch die Kathodenstrahlen in der Wand hervorgerufene Phosphorescenzlicht ist höchst selten von gleichförmiger
Intensität auf der von ihm bedeckten Fläche, und zeigt oft sehr barocke Muster ." (13. The phosphorescent light that's
produced in the wall by the cathode rays is very rarely of uniform intensity on the surface that it covers, and [it] often
shows very baroque patterns.)
2. Joseph F. Keithley The story of electrical and magnetic measurements: from 500 B.C. to the 1940s
John Wiley and
Sons, 1999 ISBN 0-7803-1193-0, page 205
3. Michael Faraday (1838)"VIII. Experimental researches in electricity
. — Thirteenth series.," (https://books.google.co
m/books?id=ypNDAAAAcAAJ&pg=PA125#v=onepage&q&f=false) Philosophical Transactions of the Royal Society of
London, 128 : 125-168.
4. Thomson, J. J. (August 1901)."On bodies smaller than atoms"(https://books.google.com/books?id=3CMDAAAAMB
AJ&pg=PA323). The Popular Science Monthly. Bonnier Corp.: 323–335. Retrieved 2009-06-21.
General Chemistry (structure and properties of matter) by Aruna Bandara (2010)
External links
The Cathode Ray Tube site
Crookes tube with maltese cross operating
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