ENTRY TEST MASTER BOOK

Chemical Equilibrium

Part-1

CHEMISTRY

Prepared by Shahbaz Ahmed

1/1/2015
 ENTRY TEST MASTER BOOK 2015

1. Which of the following reactions show same values of Kp and Kc?

(a) 2SO2 + O2  2SO3 (b) N2 + 3H2  2NH3 (c) N2 + O2  2NO (d) All of these

2. Equilibrium constant for the reaction H2 + l2  2HI is given by the expression_____.

(a) [2HI] / [H2] [I2] (b) [HI]2 / [H2] [I2] (c) [H2] [I2] / [HI]2 (d) [H2] [I2] / [2HI]

3. At the equilibrium state all types of motions _____.

(a) Stop (b) Do not stop (c) Available (d) Not available
4. Which of the following is the type of chemical equilibrium?
(a) Static (b) Dynamic (c) Permanent (d) Temporary
5. The equilibrium law was introduced by ____.
(a) Guldberg (b) Schrodinger (c) Waage (d) Both A & C
6. For the following reaction H2(g) + l2(g) 2HI(g)
The equilibrium constant Kp is ____.
(a) Zero (b) Less than Kc (c) Greater than Kc (d) Equal to Kc
7. The equilibrium is a state of reaction at which _____.
(a) No forward or backward reaction takes place (b) The rate of forward reaction is equal to the rate of backward reaction
(c) The reaction is indicated by double headed arrow (d) The reaction will stop
8. A double arrow in a chemical equation indicates which of the following reaction?
(a) Reversible (b) Complete (c) Irreversible (d) Nuclear

9. When
Pr oduct is greater than Kc, then the reaction will move in _____.
[Re ac tan t ]
(a) Forward direction (b) Backward direction (c) Equilibrium (d) All of these
10. Rate of endothermic reaction will increase with increase in _______.
(a) Temperature (b) Volume (c) Pressure (d) None of these
11. The value of Kc for a system will change when ____.
(a) Catalyst is added (b) Pressure is changed (c) Volume is changed (d) None of these
12. The rate of a chemical reaction and product of the active masses of the reacting substances are__.
(a) Indirectly related (b) Directly related (c) Not related (d) Related
13. The term Kp is used for reactions in _____.
(a) Gaseous state (b) Solid state
(c) Liquid state (d) All of above
14. The rate at which a substance reacts depends on its ______________
(a) Atomic weight (b) Equivalent weight (c) Molecular weight (d) Active mass
15. Change in the concentration of reactant and products with time is called ____.
(a) Rate of equilibrium (b) Rate of reaction (c) Forward rate (d) Backward rate
16. In a chemical reaction equilibrium is said to be established when the ____.
(a) Concentration of reactant and products are equal (b) Opposing reaction stop
(c) Velocities of opposing reactions become equal (d) Temperature of opposing reactions is equal
17. The equilibrium constant for 2A + 3B ↔3C + 2D may be calculated as ______.
[C ]3 [ D]2 3[C ]2[ D ] [ A]2 [ B ]3 [C ][ D ]
(a) (b) (c) (d)
[ A]2 [ B ]3 2[ A]3[ B ] [C ]3 [ D]2 [ A][ B ]
18. For the reaction
CO(g) + 2H2 (g) ↔ CH3OH (g)
(a) Kp = Kc (b) Kp > Kc (c) Kp < Kc (d) Kc = 0 but Kp is not zero
19. Active mass of 10gm CaCO3 is ______.
(a) 1 (b) 0.1 (c) 10 (d) 0.5
20. Which of the following value of Kc is used to show maximum product?
(a) Kc = 104 (b) Kc = 10-2 (c) Kc = 10 (d) Kc = 1

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 ENTRY TEST MASTER BOOK 2015

TEST – 1

CORRECT OPTION
QUESTION NO. ANSWER KEY
1. C
2. B
3. B
4. B
5. D
6. D
7. B
8. A
9. B
10. A
11. D
12. B
13. A
14. D
15. B
16. C
17. A
18. C
19. B
20. A

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 ENTRY TEST MASTER BOOK 2015

ENTRY TEST
1. Chemical reactions that are carried out in closed container at constant temperature are ____.
(a) Reversible reactions (b) Fast (c) Irreversible equilibrium (d) Slow
2. In contact process ______ is used as catalyst.
(a) Fe (b) V2O5 (c) Cu (d) Ni
3. The derivation of Ksp for the reaction CuSO4 ↔ Cu2+ + SO42- is ___.
[Cu 2 ][ SO42 ] CuSO4
(a) [Cu2+] [SO42–] (b) CuSO4 (c) (d)
CuSO4 [Cu 2][ SO42 ]
4. The rate of a chemical reaction and the molar concentration of the reacting species are ____.
(a) Dependent (b) Independent (c) Related (d) Not related
5. The solution in which ionic product becomes equal to solubility product, called ____solution.
(a) Unsaturated (b) Supersaturated (c) Concentrated (d) Saturated
6. When HCl gas is passed through a saturated solution of NaCl, the solubility of NaCl ___.
(a) Increase (b) Decrease (c) Remains constant (d) None of the above
7. A reversible chemical reaction having two reactants are in equilibrium, if the concentration of the reactants
are doubled then the Kc will be _____.
(a) Also be doubled (b) Be halved (c) Become one fourth (d) Remains same
8. The amount of ammonia does not increase in the following reaction because ____.
N2(g) + 3H2(g) 2NH3(g) H = -ve
(a) Pressure is increased (b) Temperature is decreased (c) Pressure is decreased (d) None of above
9. Le Chatelier’s principle is applicable only to a system, which is ___.
(a) At equilibrium (b) Not at equilibrium (c) Homogenous (d) Heterogeneous
10. The change of concentration of reactants or products is called ____.
(a) Rate of reaction (b) Rate of products (c) Rate of reactants (d) A chemical reaction
11. In common ion effect the degree of ionization is suppressed by the addition of ___.
(a) An element (b) A compounds (c) Another electrolyte (d) None of these
12. A common ion reduces the solubility of ____.
(a) An acid (b) A salt (c) A base (d) All of these
13. A stress in an equilibrium system is ____.
(a) Temperature (b) Concentration (c) Pressure (d) All of these
14. From the following values of Ksp predict which compound will be the least soluble in water?
(a) AgBr = 5.0x10–13 (b) AgCl = 1.8x1010 (c) AgF = 11x10–12 (d) AgI = 8.3x10–17
O –10
15. CaSO4 dissolved in water at 25C . its Ksp is 1 x 10 , what is the concentration of Calcium Ion in the
water?
(a) 10-4 M (b) 10-5 M (c) 10-6 M (d) 10-10 M
16. In the Haber’s process N2 + 3H2↔NH3 if the amount of catalyst is increased, which of the following occurs?
(a) More N2 and H2 will form
(b) More NH3 will form
(c) Reaction rate will be decreased

(d) No change will be occurred

17. A solution is said to be unsaturated if its _____________
(a) Ionic product =Ksp (b) Ionic product > Ksp (c) Ionic Product < Ksp (d) (Ionic Product)2 = Ksp
18. According to Le Chatelier’s principle pressure is not applicable to ____.

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 ENTRY TEST MASTER BOOK 2015

(a) Fe (s) + S (s) ↔ FeS (s) (b) H2 (g) + I2 (g) ↔ 2HI (g) (c) N2 (g) + 3H2 (g) ↔ 2NH3 (g) (d) N2 (g) + O2(g)↔ 2NO(g)
19. In a reaction 2HI ↔ H2 + I2 when H2 is added at constant temperature, the ___.
(a) Value of kp decreases (b) Value of kp increases
(c) The degree of dissociation of HI decreases (d) The degree of dissociation of HI increases
20. If the solubility of CaCl2 is 2 x 10-2, the Ksp of CaCl2 is _________.
(a) 4 x 10-8 (b) 4 x 10-12 (c) 3.2 x 10-8 (d) 3.2 x 10-5

CORRECT OPTION
QUESTION NO. ANSWER KEY

21. A

22. B

23. A

24. C

25. D

26. B

27. D

28. C

29. A

30. A

31. C

32. B

33. D

34. D

35. B

36. D

37. C

38. A

39. C

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 ENTRY TEST MASTER BOOK 2015

40. D

1. Chemical reactions that are carried out in closed container at constant temperature are ____.
(a) Reversible reactions (b) Fast (c) Irreversible equilibrium (d) Slow
4. In contact process ______ is used as catalyst.
(a) Fe (b) V2O5 (c) Cu (d) Ni
5. The derivation of Ksp for the reaction CuSO4 ↔ Cu2+ + SO42- is ___.
[Cu 2 ][ SO42 ] CuSO4
(a) [Cu2+] [SO42–] (b) CuSO4 (c) (d)
CuSO4 [Cu 2][ SO42 ]
4. The rate of a chemical reaction and the molar concentration of the reacting species are ____.
(a) Dependent (b) Independent (c) Related (d) Not related
5. The solution in which ionic product becomes equal to solubility product, called ____solution.
(a) Unsaturated (b) Supersaturated (c) Concentrated (d) Saturated
6. When HCl gas is passed through a saturated solution of NaCl, the solubility of NaCl ___.
(a) Increase (b) Decrease (c) Remains constant (d) None of the above
7. A reversible chemical reaction having two reactants are in equilibrium, if the concentration of the reactants
are doubled then the Kc will be _____.
(a) Also be doubled (b) Be halved (c) Become one fourth (d) Remains same
8. The amount of ammonia does not increase in the following reaction because ____.
N2(g) + 3H2(g) 2NH3(g) H = -ve
(a) Pressure is increased (b) Temperature is decreased (c) Pressure is decreased (d) None of above
9. Le Chatelier’s principle is applicable only to a system, which is ___.
(a) At equilibrium (b) Not at equilibrium (c) Homogenous (d) Heterogeneous
10. The change of concentration of reactants or products is called ____.
(a) Rate of reaction (b) Rate of products (c) Rate of reactants (d) A chemical reaction
11. In common ion effect the degree of ionization is suppressed by the addition of ___.
(a) An element (b) A compounds (c) Another electrolyte (d) None of these
12. A common ion reduces the solubility of ____.
(a) An acid (b) A salt (c) A base (d) All of these
13. A stress in an equilibrium system is ____.
(a) Temperature (b) Concentration (c) Pressure (d) All of these
14. From the following values of Ksp predict which compound will be the least soluble in water?
(a) AgBr = 5.0x10–13 (b) AgCl = 1.8x1010 (c) AgF = 11x10–12 (d) AgI = 8.3x10–17
O –10
15. CaSO4 dissolved in water at 25C . its Ksp is 1 x 10 , what is the concentration of Calcium Ion in the
water?
(a) 10-4 M (b) 10-5 M (c) 10-6 M (d) 10-10 M
16. In the Haber’s process N2 + 3H2↔NH3 if the amount of catalyst is increased, which of the following occurs?
(a) More N2 and H2 will form
(b) More NH3 will form
(c) Reaction rate will be decreased

(d) No change will be occurred

17. A solution is said to be unsaturated if its _____________
(a) Ionic product =Ksp (b) Ionic product > Ksp (c) Ionic Product < Ksp (d) (Ionic Product)2 = Ksp

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 ENTRY TEST MASTER BOOK 2015

18. According to Le Chatelier’s principle pressure is not applicable to ____.

(a) Fe (s) + S (s) ↔ FeS (s) (b) H2 (g) + I2 (g) ↔ 2HI (g) (c) N2 (g) + 3H2 (g) ↔ 2NH3 (g) (d) N2 (g) + O2(g)↔ 2NO(g)
19. In a reaction 2HI ↔ H2 + I2 when H2 is added at constant temperature, the ___.
(a) Value of kp decreases (b) Value of kp increases
(c) The degree of dissociation of HI decreases (d) The degree of dissociation of HI increases
20. If the solubility of CaCl2 is 2 x 10-2, the Ksp of CaCl2 is _________.
(a) 4 x 10-8 (b) 4 x 10-12 (c) 3.2 x 10-8 (d) 3.2 x 10-5

CORRECT OPTION
QUESTION NO. ANSWER KEY

41. A

42. B

43. A

44. C

45. D

46. B

47. D

48. C

49. A

50. A

51. C

52. B

53. D

54. D

55. B

56. D

57. C

58. A

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59. C

60. D