REVERSE OSMOSIS

ESSENTIAL USERS GUIDE

1
Index
Introduction to Avista …………………………………. 3
RO/NF Principles …………………………………. 4
Typical RO/NF Flowsheet …………………………………. 5
Membrane Construction …………………………………. 6
Membrane Installation …………………………………. 7
Daily Monitoring Requirements …………………………………. 8
Silt Density Index …………………………………. 9
Turbidity …………………………………. 10
Multi-Media Filter Operation …………………………………. 11
Coagulant Optimisation Tips …………………………………. 12
Determining Scaling Potential …………………………………. 13
Antiscalant Dosing …………………………………. 14
Biocide Optimisation Tips …………………………………. 15
Choosing a Cleaner Combination …………………………………. 16
Offsite Lab Cleaning Study …………………………………. 17
Membrane Cleaning Tips …………………………………. 18
Silt and Colloidal Fouling …………………………………. 19
Organics Fouling …………………………………. 20
Iron & Manganese …………………………………. 21
Sulfate Scale …………………………………. 22
Calcium Carbonate Scale …………………………………. 23
Biological Fouling …………………………………. 24
Backpressure Damage …………………………………. 25
Membrane Telescoping …………………………………. 26
Troubleshooting ………………………………….. 27
Water Calculation Examples …………………………………. 28-30
Useful Unit Conversions …………………………………. 31

2
INTRODUCTION TO AVISTA

Avista Technologies is a specialty chemical company with

its sole focus on providing products and services to help
customers operate reverse osmosis systems more
efficiently and economically.

To this end, we have developed products and services

that focus on the needs of the membrane separations
customer who deserves a technological leader to set the
standard in dynamic chemical formulations.

With extensive and varied experience in the membrane

separations industry, the Avista Technologies employees
offer a tremendous value added resource.

This expertise, combined with cost effective, practical

solutions, allows us to work with our customers to
achieve optimum system performance.

Our formulated chemicals include:

 Antiscalant
 Biocide
 Coagulant
 Cleaner

Our services include:

 Offsite Cleaning
 Membrane Autopsy
 Troubleshooting
 Laboratory Services

www.avistatech.com

3
RO/NF Principles
Reverse Osmosis is a salt separation process
that occurs when pressure is applied to ‘salty
water’ at a semi-permeable membrane. The
pressure drives pure water through the Pressure

membrane (permeate) leaving a more

concentrated salt solution behind
(concentrate or reject). Na+

-
Cl -

Na+
Cl

Cl - Na+ Cl - Na+

Na+

This separation process has been turned into

Na+
-
Cl

Na+ Cl -

-
-
Cl
Cl

a continuous process by using a crossflow

Na+

membrane configuration. semipermeable

membrane

Feedwater passes across a series of Reverse Osmosis: Applied pressure (in excess of
membranes, producing permeate and more osmotic pressure) is used to reverse the natural
concentrated feedwater to the next flow and separate salts from liquids across a
membrane. A feed pump generates the semipermeable membrane.
required pressure and a valve on the reject
stream maintains the pressure across the RO Terms
membrane array.
Permeate = water passing through membrane
The concentration process is continued to Concentrate = reject = solution which is retained on
practical limits. Typically brackish water the feed side of the membrane
systems will be operated at 70-80% recovery TDS = total dissolved solids
and seawater systems at 35-50% recovery.
%Recovery = (Permeate Flow/Feed flow)x100%
The diagram below shows the separation
% Salt Rejection = 100%x[1-(Permeate TDS/Feed TDS)]
process that occurs across a membrane
system operating at 75% recovery.

75% Recovery
4x Concentration
Product
Water
(Permeate)
Feed Water
(3,000mg/l)

Concentrate Water
(12,000mg/l)

4
 RO/NF Typical Flowsheet

Raw Water MMF Permeate

1 - 5 micron
Concentrate
Cartridge Filter
Concentrate

Inlet

Permeate

Coagulant SBS Antiscalant

V2 F P

To System
V1 IH
L

CF

SS

To ensure reverse osmosis membranes perform well over a long period of time the feedwater
must be pre-treated to remove any free chlorine and to reduce the suspended solids content to
an SDI of less than 5 (Silt Density Index, see page 9 for a description of how this is measured).

The suspended solids are typically removed using one of the following pre-treatment filter
combinations:

 Multimedia deep bed filtration, with coagulation (RoQuest) followed by guard cartridge
filtration
 Ultra/Microfiltration membranes
 Clarifier, pre-coat filter, cartridge filter

To prevent the precipitation of sparingly soluble salts that are concentrated up through the RO
process, antiscalant (Vitec) is dosed.

Chlorine is either present in the feedwater (if it is a municipal supply) or it is often added to
prevent biological/marine organism growth in the intake system. This is removed by dosing
sodium bi-sulphite (Anti-Chlor). A non-oxidising biocide (RoCide) is applied downstream of the
SBS to prevent biological growth on the membranes.

A clean in place system is also provided to periodically remove the buildup of any contaminants
that pass through the pre-treatment system and foul or scale the membranes. Cleaning is
achieved by passing a warm solution of cleaning fluid (RoClean) across the membranes.

5
 Membrane Construction
This is an outline of the components of a spiral wound reverse osmosis membrane and
their functions:

Membrane
This material prevents salt passage while allowing water to permeate. The membrane
sheet is typically made from polyamide, with a polysulphone support layer. Multiple
membrane sheets are rolled together to form a ‘spiral wound membrane element’.

Permeate Carrier (Tricot)

Sandwiched between layers of membrane, this material carries permeate water to the
permeate tube.

Permeate Tube
A perforated tube which collects permeate and, upon which, the membrane leaves are
attached. The ends of the permeate tube are profiled to hold interconnectors. These
allow permeate to travel from element to element, and finally to the take-off point on
the pressure vessel.

Anti-telescoping Device (ATD)

This device is fitted over the feed and concentrate end of the membrane sheets. It is
designed to prevent the rolled membrane sheets from elongating ("telescoping") due
to pressure differential from feed to concentrate. It also holds the brine seal.

Feed Spacer (Vexar)

Fitted between membrane leaves, the vexar forms a flow channel for the feed water to
pass over. It is designed to generate turbulence, breaking down boundary layers close
to the membrane and helping to reduce scaling and fouling potential.

Membrane Permeate
Carrier

Feed Spac er
Permeate Tube

Glue Lines
Anti Telesc ope

6
Membrane Installation
Interconnector
Used to connect the permeate tube of one membrane element to
another, or the permeate tube of a membrane element to the end
cap of the pressure vessel (Figure 1). The interconnector uses o-
rings to provide the seal.

Casing or Outer Wrap

Provides a rigid construction to maintain to the shape of the
membrane element under pressure and to prevent membrane
damage during handling. This is generally constructed from fiber
reinforced plastic. Some membrane elements are simply tape
wrapped. The membrane manufacturer model number and serial
number are typically visible on or through the outer wrap.

U-Cup Brine Seal Interconnector

Forms a seal between the membrane element and the pressure
vessel. The design is such that the pressure of the feed water opens
the ‘u-cup” and forms the seal. This ensures that the feed
water passes through the element and not around it.

Pressure Vessel Figure 1

Pressure vessels house the membrane elementss, typically from one
to seven membranes per tube depending on the length of the
vessel. Vessels are typically made of stainless steel or fiberglass
reinforced plastic (FRP).

Loading of Membrane Elements

Membrane elements should be loaded and removed in the same
direction as the water flow. Glycerin (a water-soluble lubricant)
should be used on the U-Cup seals and o-rings during the
installation (see Figure 2). When installing membranes, record the
membrane serial numbers and the location of each membrane
within the vessel.

U-Cup Brine Seal

Figure 2

Xxxxxxxxxxx Xxxxxxxxxxx
8040 STD 8040 STD
No 324231 No 324121

Direction of Flow

7
RO Daily Monitoring/Logging

Record keeping on a membrane system is important for a number of reasons, as it aids

troubleshooting of problems, allows monitoring to schedule cleans and is essential for
warranty claims. Data should be recorded at least once per day.

The minimum records that should be kept for a membrane system are those that are
required to carry out membrane data normalisation. The sample logsheet below details
these parameters.

In addition it is normally useful to record the performance of all pre-treatment equipment

so performance patterns can be identified.

At startup it is useful to complete a log of the permeate conductivity of each pressure vessel
in the system. This baseline data can then be compared against the plant performance if
changes to product quality occur.

SAMPLE REVERSE OSMOSIS LOGSHEET

Site Name Ro Unit

Date
Startu 11/5 12/5 13/5 14/5 15/5
p
Values
Time
SDI
o
Feed Temperature C
Feed Flow m3/hr
Permeate Flow m3/hr
Reject Flow m3/hr
Feed Pressure bar
Interstage Pressure bar
Brine Pressure bar
Permeate Pressure bar
Feed Conductivity S/cm
Permeate Conductivity S/cm

8
Silt Density Index (SDI)
Although the values do not directly correlate to the
fouling potential of a specific water, the Silt Density
Index, or SDI, test is considered to be an industry
standard for measuring the colloidal fouling potential of
spiral wound membranes.

For SDI test results to be accurate, the feed line to the kit
must be connected to the raw water line representative
of the water to be treated by the RO system. It is also
important to ensure that all of the air is purged from the
Filter 1:
apparatus and that the feed pressure is adjusted to 30
SDI pad of the downstream MMF
psig. effluent, no coagulant addition

SDI Test Procedure:

The initial time required to fill a 500 ml graduated
cylinder is measured and recorded as t0. A measure of
the time required to collect 500 ml volumes is noted
again at 5, 10 and 15 minutes after the initial start.
These times are recorded as t5, t10 and t15 respectively.

Calculation of Silt Density Index (SDI) :

The SDI value is then calculated using the following Filter 2:
equation: SDI of an on-site MMF pilot unit with
RoQuest coagulant addition, same
SDI = (1-t0/t15) 100 feedwater in Filters 1 and 2.
T

t0 = Initial time in seconds required to collect a 500 ml

sample.
t15 = Time in seconds required to collect a 500 ml sample
after T fifteen min.
T = Total test time in minutes (up to start of second
sample collection time.

Recommended SDI Value:

Depending on the membrane manufacturer, the typical
recommendation is to maintain a SDI value of 3.0 to 5.0
for feedwater to a reverse osmosis system. Figure 3
Photo of a typical
The filter pads shown on the right show the benefits of SDI apparatus
dosing coagulant

9
 Turbidity
Turbidity is an important water quality indicator for
almost any treatment application. Turbidity represents
the presence of dispersed, suspended solids-particles not
in true solution and often includes silt, clay, algae and
other microorganisms, organic matter and minute
particles.

Suspended solids obstruct the transmittance of light

through a water sample and impart a qualitative
characteristic, known as turbidity, to water. Turbidity is Figure 1
not a direct measure of suspended particles in water. Hach Turbidimeter
Instead, it is a measure of the scattering effect such
particles have on light.

The way in which suspended particles scatter light is very

complex. Particle size, shape, and nature all effect
scattering. In addition, colored solutions adsorb light and
can affect turbidity. Very small particles (0.2 microns)
scatter light equally in the forward and backward
direction. Larger particles (1 micron) scatter light
primarily in the forward direction. Forward scattering is
intensified as the concentration of suspended solids
increases.

Turbidity is determined electronically by the apparatus

Figure 2
shown in Figure 1. Light from a tungsten filament
Turbidity vs
(usually) passes through the sample to be measured. Particle Count Graph
Light scattered at an angle of 90 degrees is measured.
Ninety degrees is chosen because it is very sensitive to
light scatter.
Turbidity or particle count data
may provide useful pre-
Dividing scattered light intensity by that transmitted in a treatment effectiveness data. It
forward direction compensates for the affect of sample can be analysed along with SDI
color. An instrument of this type is known as a ratio data and used in pre-treatment
turbidimeter. optimisation.

A turbidity reading of around 0.2 NTU is typical of the

feedwater to membrane systems.

10
 Multi-Media Filter Operation
Turbidity vs. Time
Membrane manufactures typically specify that RO
feedwater should have an SDI (Silt Density Index) of <5.0
and a turbidity value <0.20 NTU. Low SDI and turbidity

Turbidity
values are believed to mean that the potential for
colloidal fouling is reduced. With proper application,
design, and operation, a multi media filter (MMF) can
achieve these goals.

Turbidity – When a MMF is put on-line following a Time

backwash, the turbidity value can sometimes be similar Delta-P vs. Time
to the feedwater turbidity. Over a brief period of time,
the turbidity should drop and stabilize to an acceptable
level. As the system operates, the turbidity rises. When

Delta- P
the turbidity increases by 10%, a backwash should be
initiated. If the MMF is not backwashed, the turbidity in
the effluent may eventually exceed the feedwater
turbidity.
Time
Pressure Drop (delta–P) - It is important to monitor the
delta-P of the MMF. Increases in delta-P signal the filter Turbidity vs. Dosage
is working and removing particles. The MMF should be
backwashed at or before the delta-P reaches ten (10 psi).
Turbidity

Delta-P and Turbidity are Independent – It is important

to understand that delta-P and turbidity breakthrough
can be independent of each other. The MMF should be
backwashed based on whichever occurs first.
Dosage
Turbidity vs. Dosage – When dosing a coagulant, high
turbidity does not always indicate an inadequate dosage.
Both underdosing and overdosing can cause turbidity to
rise. Additionally, significant overdosing can cause the
effluent turbidity to exceed the feedwater NTU. The
optimal dosing range at the bottom of the curve usually
has a spread of 1 to 2 ppm.

Important Operating Tips

 Test MMF feed and effluent turbidity frequently.
 Use a drawdown tube to verify coagulant dosages. Figure 4:
 Use reliable pressure gauges to measure MMF delta-P Photo shows the interior of a failed
 Initiate MMF backwash based on turbidity, delta-P or MMF bed. The garnet, anthracite and
sand are intermixed and the surface
time.
of the bed is cratered.
11
 Coagulant Optimisation Tips
Effective application of coagulant reduces membrane fouling rates
and therefore reduces membrane cleaning frequency and
increases membrane life.

Step 1: Understand Site Feedwater Characteristics

Seasonal factors such as algal blooms, storms and rotting

vegetation may change the nature and level of suspended solids
in the feedwater to an RO plant.

Consideration should be given to these effects during process

design and full evaluation of their effect should be determined
during the first year of plant operation.

Step 2: Study the Effectiveness of Coagulant

To determine the relative effectiveness of the range of membrane

(and antiscalant) compatible coagulants a set of jar tests should
be completed. The jar tests will result in a series of graphs Figure 1: Pilot filters being
relating dose rate and filtrate quality. The most cost effective operated on site to
dosing option should be selected and the dose rate optimised on determine the most effective
the main plant or on pilot scale filtration units using the best jar coagulant dose rate and to
test dose rate as a start point. optimize the filter run time.

Step 3: Continuously Monitor Performance

During operation the level of suspended solids in the feed and

filtrate of the MMF’s should be measured using SDI and other
relevant parameters such as turbidity or TOC. If a drop off in Figure 2: Jar test equipment
solids removal is noted the following should be checked/carried
out:

 Filter backwash frequency is correct

 Filter run profile as expected
 Re-optimised by jar test or
direct dose variation

12
Determining Scaling Potential
Conversion Factors
An accurate feedwater analysis is critical to
determine the scaling potential of a reverse ION Symbol
Ion to CaCO3
osmosis application. CaCO3 to ion

Calcium Ca 2.49 0.40

The conversion chart in Table 1 outlines the Magnesium Mg 4.12 0.24
ions that must be known in order to Sodium Na 2.18 0.46
complete an antiscalant projection. A Potassium K 1.28 0.78
complete analysis should also include the Strontium Sr 1.14 0.88
pH of the water at the time of sampling. Barium Ba 0.73 1.37
Iron (Ferric) Fe3+ 2.69 0.37
For ions such as Aluminum, Barium, Iron, Iron (Ferrous) Fe 2+ 1.79 0.56

and Strontium, it is important to ensure Manganese Mn 1.82 0.55

Aluminum Al 5.56 0.18
that the testing methods can detect ion
Bicarbonate HcO3 0.82 1.22
levels in the range of 0.01 ppm.
Chloride Cl 1.41 0.71
Sulfate SO4 1.04 0.96
Fluoride F 2.66 0.38
The Avista AdvisorTM computer program Nitrate NO3 0.81 1.24
allows the user to enter site-specific Silica SiO2 0.83 1.2
feedwater and system data to:
Table 1:
List of ions required to complete an antiscalant
 Recommend an antiscalant and dosage
projection.
for a specific application.

 Determine the scaling potential of a

feedwater.

 Calculate chemical injection rates

 Determining maximum system recovery

based on scaling potential.

 System troubleshooting tool.

Figure 2:
Data input screen for Avista Advisor
Antiscalant projection program.

13
 Antiscalant Dosing
Determining Required Dosage and Pump Flowrate:

1) Identify the optimum ppm (mg/l) dosage of the

appropriate Avista antiscalant. This can be found on the
Avista Advisor Dosing Report (both mg/l dose rate and %dilution required = 100 x 100% strength l/hr
pump flowrate are calculated). If this dose rate gives you a l/hr required
flowrate too low for your dosing pumps calculate a
workable antiscalant dilution using the equation on the
right. (Avista Advisor can do this calculation for you.)
Percent Chem 1000
Remember 1mg/l = 1ppm = 1g/m3 Dilution Volume litres of
litres of
Chemical
v/v Factor Water
2) For example, if you determine that you need a 30% 1% 0.01 990 10
dilution to bring the flow into the pump range then use the 10% 0.1 900 100
details in figure 1 to make up the dilute solution. The table 20% 0.2 800 200
provides details of chemical and water volumes for 1000 30% 0.3 700 300
litres of dilute solution and a column providing a 0.4
40% 600 400
multiplication factor if you wish to make up different
50% 0.5 500 500
volumes. For example, to make up 400 litres of a 30%
60% 0.6 400 600
dilution:
70% 0.7 300 700
Calculate the chemical volume to add by multiplying the 80% 0.8 200 800
total volume by the chemical volume factor, ie 400 x 0.3 = 90% 0.9 100 900
120 litres. Neat Solution,
100%
Calculate the water volume by subtracting the chemical no dilution required
volume from the total ie 400 – 120 = 280 litres. Figure 1
To RO
Add the chemical to the dosing tank and top up with the DI
or RO permeate water. Note: 10% is the maximum
recommended dilution for all antiscalants except Vitec Drawdown Tube
Chemical Pump

3000 which can go to 1%.

Dosage Confirmation

Using a drawdown assembly (as shown in Figure 2), verify Chemical Feed Tank

that the proper ml/minute dosage is being delivered to the

system. If there is no drawdown tube, calibrate the pump
by placing the pump suction line into a graduated cylinder
filled with the solution to be pumped. Measure the drop
in solution over a one-minute period to verify the ml per
Figure 2
minute injection rate. Adjust the pump accordingly until it
is correct.

14
Biocide Optimisation Tips

Controlling the growth of biofilm on RO membranes will minimise energy costs, contribute
to reduced cleaning frequency and ensure good product quality and membrane life.

It should be noted that the application of membrane compatible non-oxidising biocides

may be limited depending on the product water usage.

Tip – Understand the Characteristics of the Site

Seasonal factors such as algal blooms and rotting vegetation may change the nutrient and
bacteria level in the feedwater to an RO plant.

Consideration should be given to these effects during process design and full evaluation of
their effect should be determined during the first year of plant operation.

It should be noted that continuous chlorination/dechlorination can contribute to

significant biological aftergrowth in feedwaters rich in organic matter. Intermittent
chlorination should be considered if at all possible.

Tip – Take Plant Uptime into Account

Intermittent biocide can be dosed while the RO is online or during shutdown flushing. If
the plant is to be left dormant for any length of time ensure the biocide applied remains
active in the system during that period.

Tip – Ongoing Monitoring

Biological activity can be monitored simply by monitoring differential pressure and by

visual inspection of feed and brine piping. More accurate information can be obtained by
feed and permeate sampling of both biofilm studs and water samples. However the
situation is monitored it is essential to vary the biocide dose rate and frequency until the
levels are steady. Seasonal changes in feedwater quality may require modification of the
biocide dosing level/frequency.

15
 Choosing a Cleaner Combination
Step 1 – Understand the Characteristics of the Site
Identify the site location to understand the feedwater source and constituents, evaluate
any pretreatment issues, and review the existing cleaning procedures performed on the
membranes.

Step 2 – Complete a Visual Inspection of the Membranes

Look for clues on the membrane exterior. If there is enough foulant on the outside of the
element, a small sample can be removed and tested to determine its constituents.
Cleaning procedures specific to that foulant can then be evaluated. The weight of an
element can also indicate the extent of fouling.

Step 3 – Review Pre-Test Data

Review the pre-test data to determine the cleanability and health of the membrane. This
is useful in selecting the appropriate cleaning chemicals and to help set performance
expectations for the membranes after they’ve been cleaned.

Polyamide or Equivalent
Membranes
Cellulose Acetate Cleaner Selection
Membranes

Metals Scale Organics

Iron, Silt
Product Name Manganese
Calcium Sulfate Non-
and Biological
Carbonate Scales Biological
Aluminum
RoClean L211  ** * *

RoClean L403   * **

RoClean L607  * * *

RoClean L811  * **

RoClean P111  * ** **

RoClean P303   * *

RoClean P507  * * *

DB20 & Low pH   **

RoClean P112  * *

RoClean P703   **

RoClean P911  **
* Acceptable Chemical(s) Choice ** Ideal Chemical(s) Choice

16
Offsite Laboratory Cleaning Study
Avista laboratory personnel routinely perform cleaning studies on fouled
membranes provided to us by our customers. Cleaner selection and site-specific
cleaning procedures are determined using this analysis. The results are then
duplicated by the customer on-site to achieve a significantly higher rate of
success.

The element(s) is dissected and membrane samples are cut to size and placed in
a closed cell test loop. A variety of cleaning solutions are recirculated across the
membrane surface, simulating actual on-site cleaning characteristics (cross flow,
flux, etc). A range of variables are applied including:

1. RoClean type and order of use

2. Solution temperature
3. Recirculation time
4. Soaking

The cleaner(s) and procedure that provided the most significant foulant removal
and which restored overall membrane performance are then recommended to
the customer for use on-site.

17
 Membrane Cleaning Tips
Effective membrane cleaning involves proper
procedures combined with chemistry that is
specifically formulated to remove the target foulant.
One without the other can result in ineffective
cleaning.

Use proper chemical dilutions - When diluting

cleaners, take into consideration the total volume of
water in the system including: tanks, pipes and/or
hoses and vessels. Table 1 gives a guide to
membrane vessel volumes.

Use proper flow rates – The velocity of the solution

across the membrane surface is critical. Clean 4” Figure 1:
membranes at 10 to 12 gpm and 8” membranes at Photo of Avista Test Skid
35 to 40 gpm. Full-fit membranes require higher
flow rates, 60 gpm for an 8” element.

Always clean membranes in parallel –

If necessary, separate the vessels to achieve this.
Never clean the vessels in series as it is difficult to
ensure proper flow rates and pressures.

Minimize cleaning pressure - Clean at pressures less

than 60 psig. This will minimize or eliminate foulants
being pulled down to the membrane surface by
water permeating during the cleaning procedure. TABLE 1
Pressure Vessel Volume
Heat the cleaning solution - Heat to the maximum
Volume of Volume of
temperature allowed by the membrane water per 4" Water per 8"
Number
manufacturer. (Extreme over temperature may of Diameter Diameter
result in the kind of ATD damage shown in the membranes Vessel Vessel
photo.) per vessel
Gal Liters Gal Liters

Additional Tips – 1) Use only DI or RO permeate 1 2 8 6 23

water to dilute cleaning solutions. 2) Reduce cleaner 2 4 15 12 45
foaming by placing return lines below the water level 3 6 23 18 68
in the CIP tank. 3) Use a combination of low and
4 8 30 24 91
high pH cleaning solutions. 4) Recirculate the
5 10 38 30 114
cleaning solution for a minimum of 45 minutes.
6 12 45 36 136

7 14 53 42 159

18
 Particulate and Colloidal Fouling
Flow rates and good chemistry are the critical factors in
successfully cleaning membranes fouled by colloidal
material. The RoClean L211 contains dispersants that
help push particles away from each other and away
from the membrane surface, allowing a more effective
clean.

The following are symptoms or indicators of silt and

colloidal fouling:

 High pressure differential on elements.

 Surface water feed supply to system. Figure 1:
Silt particles removed
 High turbidity in feedwater.
from a membrane
 Element telescoping.
 Discoloration of the membranes.

Cleaning Approach

 Low pH clean with either RoClean P303 or L403

followed by a high pH clean with RoClean L211.

 Consider reverse flow and air sparging during

cleaning procedure.

 Heat cleaning solution to maximum allowed by the

membrane manufacturer.
Figure 2:
Steps to preventing silt and colloidal fouling: Element severely fouled
With filter sand
 Conduct SDI (Silt Density Index) and turbidity testing
to determine colloidal fouling potential
 Conduct laboratory testing to determine fouling
potential as well as filterability of the water.
 Consider a multi media pilot filter study.
 Inspect SDI pads under a microscope to identify the
colloidal material.
 Use properly designed multi media filtration and
consider the need for air scour or surface wash.
 Consider the use of a coagulant to increase the Figure 3:
effectiveness of the multi media filter. Colloidal fouling
 Use clarifiers or other filtration equipment for high Of a membrane surface
turbidity waters.
19
 Organic Fouling (non-biological)
The following are symptoms of organics fouling:

 Membrane discoloration.
 Low flow on individual membrane test data.
 Possible high pressure differential on individual
membrane test data.

The recommended cleaning approach is:

 A low pH clean using either RoClean P303 or L403, Figures 1,2 – Membranes
followed by a high pH clean using either RoClean heavily fouled with organic
P111 or, for severe cases, RoClean P112 or L212. and humic acid substances

The combination of a low pH clean followed by the high

pH solution is extremely effective in removing organics.
The low pH cleaner helps break the bridge between the
organics and the membrane. The high pH solution then
lifts the foulant off the membrane surface. This is why
there is sometimes a color discharge only when using
the high pH cleaner. Don’t be misled though, the low
pH clean was a vital step in the cleaning regime.

Steps to preventing organic fouling include:

 Remove the organics from the RO feedwater with a

properly designed multimedia filter with coagulant
addition. Metal salts blended with a polymer are
usually the most effective coagulant for high organic
waters.

Notes:

Figure 3 is an example of a spent cleaning solution

where the foulant was humic acid , dissolved by the
formulated cleaners.

Figure 3

20
 Iron & Manganese
The following are symptoms of iron and manganese fouling:

 Discoloration of membranes.
 Poor salt rejection on individual membrane test data.
 Low flow on individual membrane test data.
 Possible high pressure differential on individual membrane
test data.
 High iron or manganese values reported in feedwater.
 High pressure differential reported on first array.

The recommended cleaning approach is a low pH clean

(RoClean P703) followed by a high pH clean (RoClean P111 or
L211). Results can be further improved by heating the cleaning
solution to the maximum allowed by the membrane
manufacturer.

Steps to preventing iron and manganese fouling include:

 Conduct a complete and accurate water analysis.
 If the water supply contains a high amount of ferrous iron,
it is important to prevent it from oxidizing. Oxidation can
be caused by exposure to chlorine or aeration of the water
(which occurs in the multimedia filter or other similar
Figures 1 and 2:
equipment).
Iron fouled membrane
 Iron and manganese can be removed using a greensand
filter regenerated with potassium permanganate.
However, if potassium permanganate is overdosed or is not
properly rinsed from the greensand filter, it will oxidize the
membrane surface.
 Iron can be removed by chlorinating the water then
removing the oxidized iron or manganese with a
multimedia filter.

Additional Notes:
Iron in water can be found as ferrous or ferric. Ferrous iron is
dissolved iron that has not precipitated. Exposure to air turns
ferrous iron into ferric (oxidized) iron, which essentially, has Figures 3:
become rust. Initially, the foulant was a
Mystery, but it was later
Ferrous iron can exist in relatively high levels and not Determined to be Manganese
precipitate so long as it is not oxidized. It becomes a filtration
issue if it becomes oxidized. Ferric iron fouling can be removed
using RoClean P703.
21
 Sulfate Scale
Symptoms of sulfate scale include:

 Material extruding from the downstream end of the

last membranes in the system.
 Foulant will not dissolve when introduced to a
dilute hydrochloric acid solution.
 Poor salt rejection, low flow, and/or high pressure
differential on individual test data.
 8” x 40” element weight exceeds 40 pounds.
 Site reports interruption in the antiscalant or acid
injection.
 Site reports scale in the last vessel or piping of the
concentrate stream.

The recommended cleaning approach varies:

 If some of the material dissolved in a dilute

hydrochloric solution, begin the clean with a low pH
product such as RoClean L403.

 If none of the material dissolved in a dilute Figures 1 and 2:

hydrochloric solution, then skip the low pH clean SEM Photographs of
and use only a high pH solution, RoClean L811. Barium sulfate scale,
Including a magnified view
 If possible, heat the cleaning solution to the Of one of the crystals
maximum temperature allowed by the membrane
manufacturer.

Additional Notes:
Barium sulfate scale on a membrane, pressure vessel,
or pipe feels like fine grit sandpaper. This abrasiveness
can cause damage to a membrane surface during
system operation. When the system is started and
stopped, the vexar (feedspacer) material shifts slightly.
This shifting can cause the barium sulfate scale to
scratch the membrane surface causing permanent
damage and resulting in a loss of rejection.

22
 Calcium Carbonate Scale

Symptoms of calcium carbonate scale include:

 Scale extruding out of the downstream end of

the last membranes in the system.
 All of the scale dissolves when introduced to a
dilute hydrochloric acid solution.
 Poor salt rejection, low flow, and or, high
pressure differential on individual membrane
test data.
Figure 1
 8” x 40” Element weight exceeds 45 pounds. Severe CaCO3 scale on a
 Site reports interruption in the antiscalant or membrane surface.
acid injection.
 Site reports scale in the last vessel or piping of
the concentrate stream.

The recommended cleaning approaches are:

 Low pH clean with RoClean L403

 In severe cases, add hydrochloric acid to the
cleaning solution to maintain a pH of 3.0.

Testing for calcium carbonate scale: Figure 2

Calcium carbonate scale is not always as white as Element fouled with
CaCO3 scale
shown in Figures 1 and 2. But, a quick test can be
conducted to see if the foulant is comprised solely
of calcium carbonate.

In a glass beaker, mix a small solution containing ½

DI water and ½ Hydrochloric acid (36%). Drop a
small sample of the foulant into the solution. If the
foulant contains calcium carbonate, it will bubble.
Continue adding acid until the bubbling stops or
until the scale disappears.
Figure 3
If the beaker contains residual material after the An acid test is used to determine
bubbling has stopped, then the foulant consists of if a foulant is comprised of
more than just calcium carbonate. CaCO3 scale.

23
 Biological Fouling
Symptoms of biological fouling include:

 Visible slime on the feed side of the membrane.

 Site reports slime in the cartridge filter housing and
piping.
 Site reports high pressure differential in the first
array
 Individual membrane test data reports high
pressure differentials.
 Membranes are telescoped. Figure 1
Membrane fouled with
The recommended cleaning approaches are: biological material

 Add DB-20 biocide to a low pH cleaning solution

(RoClean L403 or P303).
 Follow the low pH clean with RoClean P111 (for
severe cases, consider P112)
 Heat the high pH solution (If P112 is used,
temperature range is 90o – 100oF)

Steps to prevent biological fouling include:

 Properly dose sodium bisulfite

 Clean and sanitize the pretreatment equipment and
Figure 2
piping. Algae fouled membranes
 Consider an intermittent biocide treatment.
 Evaluate the necessity of a continuous injection
biocide.

Additional Notes:
Figure 1 is a membrane sample that was taken from a
single 8” x 40” element. The first 20” of both the
membrane and vexar (feedspacer) were plugged with
biological slime while the last 20” were free of the
foulant.
Figure 3
This picture is a good demonstration of how biological Biological fouling of membrane
fouling typically occurs in the front end of a system and and vessel interior
how it may only affect the first one or two membranes.

24
 Backpressure Damage ‘Delamination’)
Backpressure is cause for concern because it can
cause delamination of reverse osmosis membranes.

Delamination is a separation of the membrane from

the backing material. This type of damage is caused
by backpressure from the permeate side of the
membrane and results in a loss of rejection.

Backpressure can be caused by restrictions in the

line such as valves, resin beds, or elevated piping. It
Figure 1
can also be caused by improper relief of product
pressure in a product staged (double pass) RO
system

Figure 1 shows an example of severe backpressure

damage where the pattern of the feedspacer
(vexar) is clearly visible.

The bubbling of the membrane shown in Figure 2 is

sometimes subtle and difficult to detect.

Figure 3 shows the membrane envelope, comprised

of two sheets of membrane and one sheet of tricot Figure 2
(permeate carrier) between.

The yellow arrow is the tricot, the red arrow is the

backing material and the blue arrows are the
membrane that was pulled away from the backing
material.

Delamination allowed easy separation of the

membrane material from the backing material.
This separation would not be possible on an
undamaged element.

Figure 3

25
 Membrane Telescoping
Telescoping of a membrane is caused by excessive
differentials between the feed pressure and the
concentrate pressure.
Figure 3
The maximum pressure differential for a single 40”
long membrane is 10 psi. When this pressure is
exceed, damage to the membrane and its materials
of construction can occur.

Consequences of Telescoping:
Figures 1:
 Damage to the fiberglass outer wrapping allows Telescoped element
water to flow on the outside of the element.
This will reduce the crossflow across the
membrane surface and increase the fouling
potential.
 If the feed spacer (vexar) moves within the
membrane area, it can scratch the membrane
surface and cause permanent damage.
 Glue lines can be stressed and fail.
 Flow patterns will be disrupted, resulting in
channeling over the membrane surface and
uneven fouling. Figures 2 and 3:
Vexar protruding from the
 The membrane crease will be stressed and element .
failure can occur at these points near the
permeate tube.

Prevention:

 Monitor pressure differentials across the entire

system as well as across each array.
 If the fiberglass is damaged, repair with vinyl
tape or place the brine seals on the opposite
end if the fiberglass and ATD are not damaged
on that end.
 Clean the system before pressures exceed 10 psi
per membrane element and correct any
excessive fouling problems.

26
 PRODUCT SALT DP DIRECT CAUSE INDIRECT CAUSE CORRECTIVE ACTION
FLOW REJECTION

Decreasing Dec Inc 2nd stage Scaling Lack of antiscalant Carry out mass balance, check antiscalant present in
Excessive recovery concentrate and ensure shutdown flush operating to
(or Feed Pressure determine source of problem. Clean plant.
Increasing,
depending on Inc 1st stage Colloidal Poor pre-treatment Clean
control system Fouling Improve pre-treatment performance
logic)

Compaction Poor pre-treatment and Stop train and clean before DP increases beyond 3.6 bar.
operating outwith Improve pre-treatment, as colloidal fouling on front end
allowed limits membrane normally accompanies first element compaction.

Incompatible Using non approved Review chemical compatibility

Chemicals products or carryover Clean plant

Biofouling Ineffective biociding Carry out bacterial survey.

programme Disinfect/clean whole system. Increase biocide programme
and continue monitoring until system shown to be under
control.

No Change No change Organic fouling Oil, polyelectrolyte Investigate source water and improve pre-treatment
Troubleshooting Guide

carryover

Inc No change Compaction Very high pressure, Replace elements and work at lower pressures, rebalance
uneven flux flows

Increasing Dec NC Oxidation Free chlorine or Replace elements ( or treat with ReSize 3000 for temporary
damage incompatible cleaner relief)
use

Membrane Product backpressure, Remove source of backpressure/vacuum

Fault or vacuum, abrasion, Improve pre-treatment
installation damage of
premeate tube

O-ring leak Novement or improper Replace o-rings, shim vessel.

installation Make startup/shutdown smoother

27
Water Calculation Examples
1. Calculating Reverse Osmosis system recovery.

Calculation: (Permeate /Feed ) (100) = % Recovery

Example: (75 GPM/100 GPM) (100) = 75% Recovery

2. Calculating Reverse Osmosis Salt Rejection:

Calculation: % rejection = (1 - (permeate TDS/feed TDS)) x 100

Example: (1- (20/1000)) 100 = 98%

3. Calculating the Concentration Factor

A. Recovery Based Concentration Factor:

Calculation: 1 / (1-recovery, expressed as a fraction)

Example: 1 / (1-0.75) = 4

B. Conductivity Based Concentration Factor

Calculation: (Concentrate Conductivity – Permeate Conductivity) = Conc. Factor

(Feed Conductivity – Permeate Conductivity)

Example: (4000 us – 3 us) = 4

(1000 us – 3 us)

4. Calculating Chemical Dilutions

Creating a 10% dilution of Vitec 3000:

Reason: If your dosing pump flowrate is higher than that required to dose the
product into the system then pumping a higher volume of a lower concentration is
just as good.

Procedure: Make up a 100 litre tank of 10% Vitec 3000.

Add 10 litres Vitec 3000 (ie 12.5kg) to the tank, top up to 100 litres
with demineralised water or RO permeate.

28
Water Calculation Examples
5. Calculating Chemical injection rates in litres/hr or ml/min

Calculation:

System Feed Flow (m3/hr) x Chem dose (mg/l) = chemical injection rate (litres/hr)
Specific Gravity x 1,000,000

Example:

Vitec doserate required = 3ppm (=mg/l)

System feed flow = 500m3/hr
Vitec 3000 specific gravity = 1.25 (Equivalent to 1,250g/l and 1,250 kg/m3)

Vitec doserate = 3 mg/l x 500,000 l/hr

= 1500 g/hr
=1500g/hr/1250g/l
= 1.2 l/hr
= 20 ml/min

29
Water Calculation Worked Examples

Question: The water temperature is 80 deg F. What is the temperature in Deg C?

Answer: 26.68 deg C

Question: The water temperature is 15 deg C. What is the temperature in deg F?

Answer: 59 deg F

Question: You want to create a 2%w/w concentration of RoClean L211 in a Clean in

Place system that contains 5m3 (5,000 litres) of water. The bulk RoClean L211
has a specific gravity of 1.1 kg/litre. How many litres of RoClean L211 do you
need to add to make a 2%w/w dilution?

Answer: 100kg or 91 litres of RoClean L211

Question: You’ve been advised to inject 3 ppm of Vitec 3000 into a system feed flow of
50m3/hr. Vitec 3000 has a specific gravity of 1.25. What ml/min dose rate is
required?

Answer: 2 ml/min.

Question: A storage tank contains 3m of water. What is the head pressure at the
bottom?

Answer: 3m or 0.3 bar

30
Useful Unit Conversions
Quantity Equals
Volume 1 US gallon 3.785 litres = 3785 ml
1m3 264.17 US gallons
219.97 UK gallons
1 barrel (oil) 159 lites
6.289 barrels 1m3

Flow 1UK gpm 0.2727m3/hr, 4.5lpm

1 USgpm 0.228m3/hr, 3.8lpm

Membrane 1 gfd 1.7 lmh

Flux 0.58 gfd 1 lmh

Filter Flows 1USgpm/ft2 2.935m/hr

Weights 1kg 2.2 lb

Volume 1ft3 0.0283m3

35.3147ft3 1m3

Density 1kg/m3 0.06243 lb/ft3

16.0185 kg/m3 1 lb/ft3

Pressure 1 bar 14.5 psi

100kPa

1 psi 2.3ft water

Temperature x C = (1.8x+32) F = 5/9 (y-32)oC
o o

Hardness 1 grain hardness 17.1ppm

1 French Degree 10mg/l as CaCO3
Water 1 UG gallon 8.34 lbs
Phosphorus to P tp PO4 P x 3.06
phosphate
Silicon to silica Si to SiO2 Si x 2.14
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Rev 9 3/15