Lesson 8
Lesson 8
Aim: 1. To investigate atomic orbitals in terms of their relative energies, shape and symmetry.
2. To investigate the filling of orbitals according to their energy and the pairing of electrons.
Learning Outcomes :
Underlying Principles
Differentiation
Questions in the student notes are designed to enable all students to complete the activity. The pop-up
answers are provided for the students to view when they have considered their responses. Worksheet
questions include questions that require recall, understanding and application of the new concepts learned.
1. Relative energies
1.1 a. i. This states that the orbitals of a subshell must be occupied singly and with parallel spins before
they can be occupied in pairs with opposing spins.
Oxygen : 2p
The electrons in the 2p orbitals are placed in different orbitals of the same energy with parallel
spin before they are paired.
ii. An orbital cannot contain more than two electrons and even then only if they have opposite
spins. Examples are 1s and 2s orbitals of an oxygen atom.
1s 2s
1.2 a. As : 1s22s22p63s23p63d104s24p3
b. As3- because by gaining three electrons, As would have a stable electronic configuration of a
noble gas.
1.3 Fe : 1s22s22p63s23p63d64s2
Fe2+ : 1s22s22p63s23p63d6
1s 2s 2p
b. Al3+
1s 2s 2p
c. Ca
1s 2s 2p 3s 3p 4s
d. H-
1s
e. Co2+
1s 2s 2p 3s 3p 3d
1.5 a. Cations are positive ions formed when atoms lose one or more electrons.
b. 20
c. 1s22s22p63s3p64s2
d. By losing two 4s electrons, atom A would form an ion with a stable electronic
configuration (a full shell).
e. calcium
2.1 a. Orbitals are regions of space around the nucleus where there is a high probability of finding
electrons.
b.
1s 2s
2.2 a.
b. The electronic configuration of chromium is 4s13d5 because the 3d orbitals which are half-filled
with electrons have extra stability.
c. Number of neutrons : 74 – 34 = 40
Electronic configuration : 1s22s22p63s23p63d104s24p4
2.3 a. i. 1s22s22p2
ii. carbon
b. i. 12
ii. 24
c. i. -3
ii. By receiving three more electrons, the nitrogen ion would have a stable full shell
electronic configuration.