Lecture 4

B. Zwiebach
February 18, 2016

Contents
1 de Broglie wavelength and Galilean transformations 1

2 Phase and Group Velocities 4

3 Choosing the wavefunction for a free particle 6

1 de Broglie wavelength and Galilean transformations

We have seen that to any free particle with momentum p, we can associate a plane wave, or a “matter
wave”, with de Broglie wavelength λ = h/p, with p = |jpj. | The question is, waves of what? Well, this
wave is eventually recognized as an example of what one calls the wavefunction. The wavefunction,
as we will see is governed by the Schrödinger equation. As we have hinted, the wavefunction gives us
information about probabilities, and we will develop this idea in detail.
Does the wave have directional or polarization properties like electric and magnetic fields in an
electromagnetic wave? Yes, there is an analog of this, although we will not delve into it now. The
analog of polarization corresponds to spin! The effects of spin are negligible in many cases (small
velocities, no magnetic fields, for example) and for this reason, we just use a scalar wave, a complex
number
2C
Ψ(x, t) ∈ (1.1)
that depends on space and time. A couple of obvious questions come to mind. Is the wavefunction
measurable? What kind of object is it? What does it describe? In trying to get intuition about this,
let’s consider how different observers perceive the de Broglie wavelength of a particle, which should
help us understand what kind of waves we are talking about. Recall that
h h 2π
p= = = ~k, (1.2)
λ 2π λ
where k is the wavenumber. How would this wave behave under a change of frame?
We therefore consider two frames S and S 0 with the x and x0 axes aligned and with S 0 moving to
the right along the +x direction of S with constant velocity v. At time equal zero, the origins of the
two reference frames coincide.
The time and spatial coordinates of the two frames are related by a Galilean transformation, which
states that
x0 = x − vt, t0 = t . (1.3)
Indeed time runs at the same speed in all Galilean frames and the relation between x and x0 is manifest
from the arrangement shown in Fig. 1.
Now assume both observers focus on a particle of mass m moving with nonrelativistic speed. Call
the speed and momentum in the S frame ve and p = mve, respectively. It follows by differentiation with

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Figure 1: The S 0 frame moves at speed v along the x-direction of the S frame. A particle of mass m
moves with speed ve, and thus momentum p = mve, in the S frame.

respect to t = t0 of the first equation in (1.3) that

dx0 dx
= −v, (1.4)
dt0 dt
which means that the particle velocity ve 0 in the S 0 frame is given by

ve 0 = ve − v . (1.5)

Multiplying by the mass m we find the relation between the momenta in the two frames

p0 = p − mv. (1.6)

The momentum p0 in the S 0 frame can be appreciably different from the momentum p in the S frame.
Thus the observers in S 0 and in S will obtain rather different de Broglie wavelengths λ0 and λ! Indeed,
h h
λ0 = = 6= λ, (1.7)
p0 p − mv
This is very strange! As we review now, for ordinary waves that propagate in the rest frame of
a medium (like sound waves or water waves) Galilean observers will find frequency changes but no
change in wavelength. This is intuitively clear: to find the wavelength one need only take a picture
of the wave at some given time, and both observers looking at the picture will agree on the value of
the wavelength. On the other hand to measure frequency, each observers must wait some time to see
a full period of the wave go through them. This will take different time for the different observers.
Let us demonstrate these claims quantitatively. We begin with the statement that the phase
φ = kx − ωt of such a wave is a Galilean invariant. The wave itself may be cos φ or sin φ or some
combination, but the fact is that the physical value of the wave at any point and time must be agreed
by the two observers. The wave is an observable. Since all the features of the wave (peaks, zeroes,
etc, etc) are controlled by the phase, the two observers must agree on the value of the phase.
In the S frame the phase can be written as follows
2π 2πx 2πV
φ = kx − ωt = k(x − ωk t) = (x − V t) = − t, (1.8)
λ λ λ
where V = ωk is the wave velocity. Note that the wavelength is read from the coefficient of x and ω is
minus the coefficient of t The two observers should agree on the value of φ. That is, we should have

φ0 (x0 , t0 ) = φ(x, t) (1.9)

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where the coordinates and times are related by a Galilean transformation. Therefore

2π 2π 0 2π 0 2π(V − v) 0
φ0 (x0 , t0 ) = (x − V t) = (x + vt0 − V t0 ) = x − t. (1.10)
λ λ λ λ
Since the right-hand side is expressed in terms of primed variables, we can read λ0 from the coefficient
of x0 and ω 0 as minus the coefficient of t0 :

λ0 = λ (1.11)
2π 2πV  v  v
ω0 = (V − v) = 1− =ω 1− . (1.12)
λ λ V V
This confirms that, as we claimed, for a physical wave propagating in a medium, the wavelength is a
Galilean invariant and the frequency transforms.
So what does it mean that the wavelength of matter waves change under a Galilean transforma-
tion? It means that the Ψ waves are not directly measurable! Their value does not correspond to a
measurable quantity for which all Galilean observers must agree. Thus, the wavefunction need not be
invariant under Galilean transformations:

Ψ(x, t) 6= Ψ0 (x0 , t0 ) , (1.13)

where (x, t) and (x0 , t0 ) are related by Galilean transformations and thus represent the same point and
time. You will figure out in Homework the correct relation between Ψ(x, t) and Ψ0 (x0 , t0 ).

What is the frequency ω of the de Broglie wave for a particle with momentum p? We had

p = ~k (1.14)

which fixes the wavelength in terms of the momentum. The frequency ω of the wave is determined by
the relation
E = ~ω , (1.15)
which was also postulated by de Broglie and fixes ω in terms of the energy E of the particle. Note
that for our focus on non-relativistic particles the energy E is determined by the momentum through
the relation
p2
E = . (1.16)
2m
We can give three pieces of evidence that (1.15) is a reasonable relation.

1. If we superpose matter waves to form a wave-packet that represents the particle, the packet
will move with the so called group velocity vg , which in fact coincides with the velocity of the
particle. The group velocity is found by differentiation of ω with respect to k, as we will review
soon:
dω dE d  p2  p
vg = = = = = v. (1.17)
dk dp dp 2m m
2. The relation is also suggested by special relativity. The energy and the momentum components
of a particle form a four-vector:  
E
,p (1.18)
c

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 Similarly, for waves whose phases are relativistic invariant we have another four-vector
ω 
,k (1.19)
c
Setting two four-vectors equal to each other is a consistent choice: it would be valid in all Lorentz
frames. As you can see, both de Broglie relations follow from
 
E ω 
,p = ~ ,k . (1.20)
c c

3. For photons, (1.15) is consistent with Einstein’s quanta of energy, because E = hν = ~ω.

In summary we have
p = ~k, E = ~ω . (1.21)

These are called the de Broglie relations, and they are valid for all particles.

2 Phase and Group Velocities

To understand group velocity we form wave packets and investigate how fast they move. For this we
will simply assume that ω(k) is some arbitrary function of k. Consider a superposition of plane waves
ei(kx−ω(k)t) given by Z
ψ(x, t) = dk Φ(k)ei(kx−ω(k)t) . (2.22)

We assume that the function Φ(k) is peaked around some wavenumber k = k0 , as shown in Fig. 2.

Figure 2: The function Φ(k) is assumed to peak around k = k0 .

In order to motivate the following discussion consider the case when Φ(k) not only peaks around
k0 but it also is real (we will drop this assumption later). In this case the phase ϕ of the integrand
comes only from the exponential:
ϕ(k) = kx − ω(k)t . (2.23)
We wish to understand what are the values of x and t for which the packet ψ(x, t) takes large values.
We use the stationary phase principle: since only for k ∼ k0 the integral over k has a chance to give a
non-zero contribution, the phase factor must be stationary at k = k0 . The idea is simple: if a function
is multiplied by a rapidly varying phase, the integral washes out. Thus the phase must have zero
derivative at k0 . Applying this idea to our phase we find the derivative and set it equal to zero at k0 :
dϕ  dω 
= x −  t = 0. (2.24)
dk k0 dk k0


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This means that ψ(x, t) is appreciable when x and t are related by
dω 
x =  t, (2.25)
dk k0
showing that the packet moves with group velocity
dω 
vg =  . (2.26)
dk k0

| iφ(k) . Find the new version of (2.25) and show that

Exercise. If Φ(k0 ) is not real write Φ(k) = |jΦ(k)je
the velocity of the wave is not changed.
Let us now do a more detailed calculation that confirms the above analysis and gives some extra
insight. Notice first that Z
ψ(x, 0) = dk Φ(k)eikx . (2.27)

We expand ω(k) in a Taylor expansion around k = k0


dω 
+ O (k − k0 )2 .


ω(k) = ω(k0 ) + (k − k0 ) (2.28)
dk k0


Then we find, neglecting the O((k − k0 )2 ) terms

Z
dk |
jk0 t
−i(k−k0 ) dω
ψ(x, t) = dk Φ(k) eikx e−iω(k0 )t e . (2.29)

It is convenient to take out of the integral all the factors that do not depend on k:
Z
dk |
jk0 t dk j
|k0 t
−iω(k0 )t+ik0 dω −ik dω
ψ(x, t) = e dk Φ(k)eikx e
Z   (2.30)
|k0 t
dk j |k0 t
dk j
−iω(k0 )t+ik0 dω ik x− dω
=e dk Φ(k)e .

Comparing with (2.27) we realize that the integral in the above expression can be written in terms of
the wavefunction at zero time:

dk j
−iω(k0 )t+ik0 dω |k0 t
 dω  
ψ(x, t) = e ψ x− t . (2.31)
dk k0

The phase factors in front of the expression are not important in tracking where the wave packet is.
In particular we can take the norm of both sides of the equation to find

  dω  
|
jψ(x, t)j| = ψ x − t, 0 . (2.32)
 
dk k0


|
If ψ(x, 0) peaks at some value x0 it is clear from the above equation that jψ(x, t)j| peaks for
 
dω  dω 
x− t = x0 ! → x = x0 + t, (2.33)
dk k0
 dk k0
dω
showing that the peak of the packet moves with velocity vgr = dk , evaluated at k0 .

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3 Choosing the wavefunction for a free particle
What is the mathematical form of the wave associated with a particle a particle with energy E and
momentum p? We know that ω and k are determined from E = ~omega and p = ~k. Let’s suppose
that we want our wave to be propagating in the +x̂ direction. All the following are examples of waves
that could be candidates for the particle wavefunction.

1. sin (kx − ωt)

2. cos (kx − ωt)

3. ei(kx−ωt) = eikx e−iωt - time dependence ∝

/ e−iωt

4. e−i(kx−ωt) = e−ikx eiωt - time dependence ∝

/ e+iωt

In the third and fourth options we have indicated that the time dependence could come with either
sign. We will use superposition to decide which is the right one! We are looking for a wave-function
which is non-zero for all values of x.

Let’s take them one by one:

1. Starting from (1), we build a superposition in which the particle has equal probability to be
found moving in the +x and the −x directions.

Ψ(x, t) = sin (kx − ωt) + sin (kx + ωt) (3.1)

Expanding the trigonometric functions this can be simplified to

Ψ(x, t) = 2 sin(kx) cos(ωt) . (3.2)

But this result is not sensible. The wave function vanishes identically for all x at some special
times
ωt = π2 , 3π 5π


2 , 2 , ... (3.3)
A wavefunction that is zero cannot represent a particle.

2. Constructing a wave function from (2) with a superposition of left and right going cos waves,

Ψ(x, t) = cos(kx − ωt) + cos(kx + ωt) = 2 cos(kx) cos(ωt) . (3.4)

This choice is no good, it also vanishes identically when ωt = π2 , 3π

2 , ...

3. Let’s try a similar superposition of exponentials from (3), with both having the same time
dependence

Ψ(x, t) = ei(kx−ωt) + ei(−kx−ωt) (3.5)

ikx −ikx −iωt
= (e +e )e (3.6)
−iωt
= 2 cos kx e . (3.7)

This wavefunction meets our criteria! It is never zero for all values of x because e−iωt is never
zero.

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 4. A superposition of exponentials from (4) also meets our criteria

Ψ(x, t) = e−i(kx−ωt) + e−i(−kx−ωt) (3.8)

ikx −ikx iωt
= (e +e )e (3.9)
iωt
= 2 cos kx e . (3.10)

This is never zero for all values of x

Since both options (3) and (4) seem to work we ask: Can we use both (3) and (4) to represent a
particle moving to the right (in the +x̂ direction)? Let’s assume that we can. Then, since adding a
state to itself should not change the state, we could represent the right moving particle by using the
sum of (3) and (4)
Ψ(x, t) = ei(kx−ωt) + e−i(kx−ωt) = 2 cos(kx − ωt) . (3.11)
This, however, is the same as (2), which we already showed leads to difficulties. Therefore we must
choose between (3) and (4).
The choice is a matter of convention, and all physicists use the same convention. We take the free
particle wavefunction to be

Free particle wavefunction : Ψ(x, t) = ei(kx−ωt) , (3.12)

representing a particle with

p = ~k , and E = ~ω . (3.13)
In three dimensions the corresponding wavefunction would be

Free particle wavefunction : Ψ(x, t) = ei(k·x−ωt) , (3.14)

representing a particle with

p = ~k, and E = ~ω . (3.15)

Andrew Turner and Sarah Geller transcribed Zwiebach’s handwritten notes to create the first LaTeX
version of this document.

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8.04 Quantum Physics I

Spring 2016

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