Traditional Building Materials and Fibre Reinforced Polymer Composites. A Sustainability Approach in Construction Sector
Traditional Building Materials and Fibre Reinforced Polymer Composites. A Sustainability Approach in Construction Sector
Publicat de
Universitatea Tehnică „Gheorghe Asachi” din Iaşi
Tomul LIX (LXIII), Fasc. 2, 2013
Secţia
CONSTRUCŢII. ARHITECTURĂ
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Corresponding author: e-mail: [email protected]
56 Sebastian George Maxineasa and Nicolae Ţăranu
1. Introduction
3.1. Concrete
expect the pollution levels from cement production to double about every 5
years. It is estimated that from the chemical reaction and the combustion of
fossil fuels for generating heat necessary to manufacture a ton of cement is
produced a ton of CO2. Recent studies have shown that the cement production is
Bul. Inst. Polit. Iaşi, t. LIX (LXIII), f. 2, 2013 59
responsible for 5%...7% of all CO2 generated around the world. Therefore, in
order to reduce the environmental impact of concrete, we must reduce the
amount of cement used in concrete.
The cement producers chose to optimize the cement mixture by adding
complementary cementing materials, like fly ash (a pozzolanic by-product of
coal-fired electricity generation) and blast-furnace slag (a pozzolanic by-product
of steel blast furnaces). There are two benefits for using this pozzolanic by-
products: the environmental impact is reduced because of the replacement of
cement with carbon-neutral by-products and these by-products are diverted
from the landfills. The Portland Cement Association has developed some
recommendations for the quantity of cement replacement with fly ash and blast-
furnace by weight. Another environmental problem of the cement and concrete
is the dust that is generated in the production stage. Thus, the Environmental
Protection Agency has limited the quantity of dust that is released into the
atmosphere. The concrete impact over the environment can be reduced by
replacing the natural aggregates with recycled materials like: brick, glass,
granulated plastics, waste fibreglass, and crushed blast furnace slag (Heede &
Belie, 2012; Estrada et al., 2012).
The techniques used by the cement industry for reducing its carbon-
footprint will result in a more durable concrete with a much longer service life
and lower overall cost. This concrete will possess lower embodied energy,
lower carbon emissions, lower environmental impact and an increased diversion
of by-product materials from landfills.
3.2. Steel
Typically, the following two methods are used in the production of this
material: electric-arc furnace (EAF) or basic oxygen furnace (BOF). Each of
these methods uses a different amount of recycled materials; the steel produced
by the EAF can have up to 100% recycled content and the one produced by the
BOF method contains 10%...25% recycled content. Another difference between
these two methods is the type of energy being used in the production process;
EAF uses electricity and BOF uses coal or natural gas. Adding that the most
structural steel used in construction is produced using the EAF process, we can
say that EAF is the most friendly environmental method.
Steel has a unique property: it is 100% recyclable (a highly recyclable
material), which means that steel can be recycled multiple times without any
degradation of its mechanical properties. Increasing the use of recycled steel
and changing the production process have led to a drastically decrease over the
past 30 years of the CO2 emissions and the amount of raw materials and energy
used. The environmental thinking in steel industry took place in the 1970s and
1980s, when the manufacturers started to recycle steel and they switched from
coal burning furnaces to electricity. Steel has a relatively small carbon-footprint,
60 Sebastian George Maxineasa and Nicolae Ţăranu
3.3. Timber
energy in fired clay bricks is almost three times higher than in concrete bricks
(Table 2). Being a fired material, the process of manufacturing clay bricks
requires a large amount of energy. Therefore, this material has a large amount
of embodied energy and a significant carbon footprint. The environmental
impact of concrete bricks is the same as the one of the regular concrete.
Table 2
Embodied Energy in Masonry Materials
(Volz & Stovner, 2010a; Estrada et al., 2012)
Material Embodied energy, [MBtu/yd3]
Concrete brick 0.946
Fired clay brick 3.28
Fly ash brick 0.492
In order to reduce the level of the embedded energy and the carbon
footprint of fired clay bricks, the masonry industry has developed the fly ash
brick which has comparable mechanical properties with fired clay brick but the
level of embedded energy in fly ash brick is much lower. For concrete brick, the
manufactures have minimized the carbon footprint and the embedded energy by
substituting cement with complementary cementing materials, like fly ash
(Estrada et al., 2012; Volz & Stovner, 2010b).
The masonry industries have made progress in order to reduce the
carbon footprint and the level of embedded energy in fired clay and concrete
bricks, which are two of the most used building materials worldwide. For the
future, brick’s manufacturers are expected to reduce more the environmental
impact of their products by trying to minimizing the amount of cement used in
concrete bricks, replacing fired clay bricks with fly ash bricks and trying to
recycle and reuse the masonry construction waste.
high mechanical properties (high specific strength and high specific stiffness),
lightweight, noncorrosive, durability and can be manufactured to satisfy specific
performance requirements. FRP composites can be used for rehabilitation of
existing structures, increasing the life span of the structures, or can be included
in new constructions (Ţăranu et al., 2012; Lee et al., 2012; Estrada et al., 2012).
The fabrication stage of the constituent materials for FRP composites
have an important environmental impact. If we consider only the large amount
of energy necessary for manufacturing the fibres and the primary resources used
for obtaining the polymers, it appears that it is irrational to use FRP composite
materials for a sustainable development in the construction sector. In the
following sections there is presented an overview of the most used FRP
composite constituent materials and their implications in a sustainable
construction development.
4.1. Glass Fibres
The advantages of carbon fibres are: high tensile strength, high modulus
of elasticity, and high tolerance to high temperatures and corrosive
environments. Due to their tolerance to corrosive environments, the carbon
fibres can be used for applications in marine environments. They are petroleum-
based and in the manufacturing stage there are reached temperatures above
1,600ºC. This type of fibres has a big environmental impact because, like in the
case of glass fibres, a large amount of nonrenewable energy is required in the
manufacturing stage. The environmental impact of carbon fibres can be reduced
due to their mechanical properties. Thus, in a construction application it can be
used a lower quantity of carbon fibres to achieve the same performance given
by a larger quantity of glass or aramid fibres (Lee et al., 2012; Hollaway,
2011).
64 Sebastian George Maxineasa and Nicolae Ţăranu
Aramid fibres are often used for applications which require a high
impact resistance. Because this fibres have a low axial compression strength,
poor transverse properties and low shear modulus, they are usually used in
construction applications as a composite hybrid material which is obtained by
combining the aramid fibres with other fibres, such as carbon fibres. Unlike the
glass and carbon fibres, the maximum value of temperature for manufacturing
aramid fibres is around 200ºC. The main advantageous properties of aramid
fibres are: a very low density, high tensile strength and stiffness (Hollaway,
2011; Stoian et al., 2004).
Compared with other polymers, epoxy resins are more expensive, but
are used in many construction applications due to their advantageous properties,
like high mechanical strength, low viscosity, low shrinkage rates and durability.
In order to initiate and accomplish the crosslinking, almost all epoxies used in
composite applications require an increased and well controlled temperature and
the use of curing agents (hardeners) and accelerators. Most hardeners used in
epoxy systems are highly toxic and cause severe irritation if are touched or
inhaled. Additionally, it is known that some of them are carcinogens and can
cause damage to the liver and kidneys (Lee et al., 2012; Strong, 2008).
Polyester resins are the most widely used thermosetting resins. Their
main advantages are: high corrosion resistance, uncomplicated manufacturing
process and low cost. The price of unsaturated polyesters is about 33%...50%
less than epoxies and about 25% less than vinylesters. Like in the case of epoxy
resins, the crosslinking agents and the catalysts used for the polymerization
reaction of polyester resins have high levels of toxicity and can create serious
health problems. For example, styrene is a crosslinking agent used in polyester
resins, which easily evaporates and has an important negative impact over the
human’s health in the mixing and applications stage. Other disadvantages of
polyester resins are low temperature tolerance and shrinkage from crosslinking
(Lee et al., 2012; Strong, 2008).
expensive than polyesters. Compared with polyesters, the vinylester resins have
superior toughness and corrosion resistance to water and organic solvents. Still
the vinylester resins have weaker properties than the epoxy resins. The
vinylesters have another advantage with respect to the polyesters, namely the
lower quantity of styrene used for vinylesters manufacturing. Therefore, the
impact of the styrene emissions over the human’s health is reduced (Lee et al.,
2012; Strong, 2008).
fired clay bricks with fly ash bricks. All the steps already taken and the ones
planned for the future have the declared scope of reducing the carbon-footprint.
Even if the production stage of FRP composite materials has negative
impacts over the environment, the aspects of sustainability can be achieved in
constructions sector by using the previously mentioned. The main advantage is
that the life span of an existing structure is extended through FRP composite
applications. Thus, we can avoid all the environmental implications of
demolishing and constructing a new building.
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(Rezumat)
Este deja cunoscut faptul că domeniul construcţiilor reprezintă unul dintre cele
mai poluante activităţi economice, folosindu-se cantităţi semnificative de materiale şi
68 Sebastian George Maxineasa and Nicolae Ţăranu